JPH03249272A - Electrically conductive textile product and its production - Google Patents
Electrically conductive textile product and its productionInfo
- Publication number
- JPH03249272A JPH03249272A JP2046832A JP4683290A JPH03249272A JP H03249272 A JPH03249272 A JP H03249272A JP 2046832 A JP2046832 A JP 2046832A JP 4683290 A JP4683290 A JP 4683290A JP H03249272 A JPH03249272 A JP H03249272A
- Authority
- JP
- Japan
- Prior art keywords
- pyrrole
- textile product
- sulfonic acid
- polyamide
- acid group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 92
- 239000000835 fiber Substances 0.000 claims abstract description 38
- 239000000178 monomer Substances 0.000 claims abstract description 24
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 19
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 19
- 239000004952 Polyamide Substances 0.000 claims abstract description 17
- 229920002647 polyamide Polymers 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 239000002019 doping agent Substances 0.000 claims abstract description 14
- 239000012985 polymerization agent Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims description 25
- 230000001590 oxidative effect Effects 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 abstract description 7
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- 230000000379 polymerizing effect Effects 0.000 abstract description 5
- 239000000980 acid dye Substances 0.000 abstract description 4
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Chemical class O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 abstract description 3
- 239000000982 direct dye Substances 0.000 abstract description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- -1 pyrrole compound Chemical class 0.000 description 15
- 239000000975 dye Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 239000004745 nonwoven fabric Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 9
- 229920001778 nylon Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004677 Nylon Substances 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 5
- 235000011130 ammonium sulphate Nutrition 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021381 transition metal chloride Inorganic materials 0.000 description 2
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
- KHUFHLFHOQVFGB-UHFFFAOYSA-N 1-aminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2N KHUFHLFHOQVFGB-UHFFFAOYSA-N 0.000 description 1
- FEKWWZCCJDUWLY-UHFFFAOYSA-N 3-methyl-1h-pyrrole Chemical compound CC=1C=CNC=1 FEKWWZCCJDUWLY-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- RBWNDBNSJFCLBZ-UHFFFAOYSA-N 7-methyl-5,6,7,8-tetrahydro-3h-[1]benzothiolo[2,3-d]pyrimidine-4-thione Chemical compound N1=CNC(=S)C2=C1SC1=C2CCC(C)C1 RBWNDBNSJFCLBZ-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- SWDGQFQKNKEWHK-UHFFFAOYSA-N B(F)(F)F.[Ag] Chemical compound B(F)(F)F.[Ag] SWDGQFQKNKEWHK-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- HOPSCVCBEOCPJZ-UHFFFAOYSA-N carboxymethyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)=O HOPSCVCBEOCPJZ-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- LHOWRPZTCLUDOI-UHFFFAOYSA-K iron(3+);triperchlorate Chemical compound [Fe+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O LHOWRPZTCLUDOI-UHFFFAOYSA-K 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002794 monomerizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野］ 本発明は導電性繊維製品及びその製造方法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a conductive textile product and a method for manufacturing the same.
ＩＣ製造工場や引火性物質を取り扱う場所において、衣
類に静電気が帯電していると静電気の放電によってＩＣ
を破損したり、放電の火花が引火性物質に引火して爆発
事故や火災を起こす等の危険がある。このためＩＣ製造
工場や引火性物質を取り扱う場所では、作業者は静電気
が帯電しないように導電性を付与した衣類を着用するの
が普通である。In IC manufacturing factories and other places where flammable materials are handled, if clothing is charged with static electricity, the IC may be damaged due to electrostatic discharge.
There is a danger that the sparks from the discharge may ignite flammable materials, causing an explosion or fire. For this reason, in IC manufacturing factories and places where flammable substances are handled, workers usually wear conductive clothing to prevent static electricity from building up.
従来衣服等の繊維製品に導電性を付与するには、直径１
０〜１５ＩＩＭ程度の極細のステンレス繊維を折り込ん
だり、表面を硫化銅で被覆した１５〜３０ｎ程度のアク
リル繊維を用いる等の方法が知られている。しかしなが
ら極細のステンレス繊維を折り込んだ繊維製品は、非屈
曲状態での耐久性に優れるものの製織が煩雑であり、ま
た耐屈曲性に劣る等の欠点があり、硫化銅で被覆したア
クリル繊維よりなるものは、色相が限定されるとともに
、アクリル繊維自体の耐溶剤性が不充分であるという欠
点があった。Conventionally, in order to impart conductivity to textile products such as clothing, a diameter of 1
Methods such as folding in ultrafine stainless steel fibers of about 0 to 15 IIM or using acrylic fibers of about 15 to 30 nm coated with copper sulfide are known. However, although fiber products made by folding ultra-fine stainless steel fibers have excellent durability in the unbent state, they are complicated to weave and have poor bending resistance. However, there were disadvantages in that the hue was limited and the solvent resistance of the acrylic fiber itself was insufficient.
一方、ピロール系化合物を重合して繊維と複合化せしめ
ることにより導電性を付与する方法は、気相法や湿式法
共に多くの方法が提案されている。On the other hand, many methods have been proposed for imparting electrical conductivity by polymerizing a pyrrole compound and compositing it with fibers, including both gas phase methods and wet methods.
しかしながらこれらの方法は多くの場合、繊維表面に対
するピロール系重合体の均一重合性が悪かったり、重合
法そのものが非実用的であったりする等の問題があり、
例えばピロール系化合物を電解酸化重合して繊維製品と
複合化せしめる方法では複雑な装置を必要とし製造コス
トが高くつくとともに連続生産性が悪いという問題があ
った。However, these methods often have problems such as poor homogeneous polymerization of the pyrrole polymer onto the fiber surface or the polymerization method itself being impractical.
For example, a method in which a pyrrole compound is electrolytically oxidized and polymerized to form a composite with a textile product requires complicated equipment, resulting in high manufacturing costs and poor continuous productivity.
本発明は上記の点に鑑みなされたもので、上記従来技術
の欠点を解決し得る導電性繊維製品及びその製造方法を
提供することを目的とする。The present invention has been made in view of the above points, and an object thereof is to provide a conductive textile product and a method for manufacturing the same that can solve the drawbacks of the above-mentioned prior art.
即ち本発明は、
（１）スルホン酸基を有する有機化合物で処理されたポ
リアミド含有繊維製品の表面がピロール系重合体で被覆
されているか、或いは上記繊維製品にピロール系重合体
の一部又は全部が含浸されていることを特徴とする導電
性繊維製品。That is, the present invention provides the following features: (1) The surface of a polyamide-containing textile product treated with an organic compound having a sulfonic acid group is coated with a pyrrole polymer, or the textile product is coated with a part or all of the pyrrole polymer. A conductive textile product characterized by being impregnated with.
（２）ポリアミド含有繊維製品をスルホン酸基を有する
有機化合物で処理した後、ピロール系モノマーと接触さ
せて酸化重合剤の存在下にピロール系モノマーを重合せ
しめ、ポリアミド含有繊維製品にピロール系重合体を複
合化せしめて導電性を付与することを特徴とする導電性
繊維製品の製造方法。(2) After treating a polyamide-containing textile product with an organic compound having a sulfonic acid group, it is brought into contact with a pyrrole-based monomer to polymerize the pyrrole-based monomer in the presence of an oxidative polymerization agent, thereby forming a pyrrole-based polymer into a polyamide-containing textile product. 1. A method for manufacturing a conductive fiber product, characterized by imparting conductivity to the product by compositing it.
（３） ピロール系モノマーを酸化重合剤及びドーパ
ントの存在下に重合せしめてポリアミド含有繊維製品に
ピロール系重合体を複合化せしめることを特徴とする請
求項１記載の導電性繊維製品の製造方法。(3) The method for producing a conductive textile product according to claim 1, characterized in that the pyrrole-based monomer is polymerized in the presence of an oxidative polymerization agent and a dopant to compound the pyrrole-based polymer into the polyamide-containing textile product.
を要旨とするものである。The main points are as follows.
本発明においてポリアミド含有繊維製品の形態は、後述
するスルホン酸基を存する有機化合物が付着（或いは吸
着、含浸、化学結合等）し得るものであればいかなる形
態であっても良く、例えばステープルファイバー、マル
チフィラメント、紡績糸、織布、不織布、編布等、いず
れの形態でも良い。上記のうち不織布は、ニードルバン
チング法、スパンボンド法、メルトブロー法、スパンボ
ンド法、抄紙法のいずれの方法で得られたものでも良い
。上記ポリアミドとしては、６−ナイロン、６．６−ナ
イロン、１２−ナイロン等が挙げられる。本発明におい
て繊維製品はポリアミド単独で構成されるものの他に、
ポリエチレンテレフタレート、カチオン可染性ポリエス
テル、ビニロン、セルロース、ウール、シルク、綿、ポ
リエチレン、ポリプロピレン、アクリル等の繊維を含む
ものでも良いが、ポリアミドを含むことが必要であり、
特にポリアミドの含有量が５０重量％以上のものが好ま
しい。更に繊維自体の形態も単一組成の繊維であっても
、海島型繊維、芯鞘型繊維、分割型繊維、サイドバイサ
イド型繊維、交互配列型繊維等の複合繊維であっても良
い。In the present invention, the polyamide-containing fiber product may be in any form as long as it can be attached (or adsorbed, impregnated, chemically bonded, etc.) with an organic compound having a sulfonic acid group, which will be described later, such as staple fiber, It may be in any form such as multifilament, spun yarn, woven fabric, nonwoven fabric, knitted fabric, etc. Among the above, the nonwoven fabric may be obtained by any of the needle bunching method, spunbond method, melt blow method, spunbond method, and papermaking method. Examples of the polyamide include 6-nylon, 6.6-nylon, 12-nylon, and the like. In the present invention, the textile products are not only composed of polyamide alone, but also include:
It may contain fibers such as polyethylene terephthalate, cationic dyeable polyester, vinylon, cellulose, wool, silk, cotton, polyethylene, polypropylene, acrylic, etc., but it is necessary to contain polyamide.
Particularly preferred is one having a polyamide content of 50% by weight or more. Further, the form of the fiber itself may be a single composition fiber, or a composite fiber such as a sea-island type fiber, a core-sheath type fiber, a split type fiber, a side-by-side type fiber, or an alternate arrangement type fiber.
スルホン酸基を有する有機化合物は、ポリアミド含有繊
維製品への吸着、繊維内部への分散性等の点で低分子量
のものが好ましく、一般には染料として使用されるもの
を用いることが好ましいが、低分子量で繊維への吸着性
、繊維内部への分散性等を有するものであれば染料とし
て使用されているものに限られない。例えば染料として
用いられているスルホン酸基含有化合物としては、Ｃ，
１，Ａｃ１ｄ Ｂｌｕｅ １２０ （日本化薬社製）
、Ｃ，１，八ｃｉｄＢｌｕｅ １１６ （日本化薬
社製） 、Ｃ，１，Ａｃ１ｄ Ｏｒａｎｇｅ７ （日本
化薬社製）、等の酸性染料、Ｃ，１，Ａｃ１ｄＶｉｏｌ
ｅｔ ５６ （日本化薬社製） 、１ｌｌｃｉｄ Ｃｏ
ｍｐｌｅｘＶｉｏｌｅｔ ３Ｒ（日本化薬社製） 、Ａ
ｉｚｅｎ ０ｐａｌν１ｏｌｅｔ ３ＲＬ （保土谷
化学工業社製）、八ｃｉｄＣｏｍｐｌｅｘ Ｖｉｏｌｅ
ｔ ４Ｒ（日本化薬社製）Ｃ，Ｉ、Ａｃ１ｄ Ｖｉｏｌ
ｅｔ ５８ （日本化薬社製） 、Ｃ，１，八ｃｉｄＧ
ｒｅｅｎ ３５ （日本化薬社製）のクロム錯体等の
酸性染料の金属錯体等が挙げられる。染料の構造として
はアミノアントラキノン系、アゾ系、その他何れのもの
でも使用できる。更に染料以外ではｐトルエンスルホン
酸や紫外線吸収剤として知られている２−ヒドロキシ−
４−メトキシベンゾフェノン−５−スルホン酸、２−ヒ
ドロキシ４−ｎオクトキシベンゾフェノン−５−スルホ
ン酸、２−ヒドロキシ−４−ｎ−ドデシロキシベンソフ
ェノンー５−スルホン酸、２−ヒドロキシ−４ヘンシロ
キシベンゾフェノン−５−スルホン酸等を用いることも
できる。The organic compound having a sulfonic acid group is preferably one with a low molecular weight in terms of adsorption to polyamide-containing textile products and dispersibility inside the fiber, and it is generally preferable to use a compound used as a dye. It is not limited to those used as dyes, as long as the molecular weight has adsorption to fibers, dispersibility inside fibers, etc. For example, sulfonic acid group-containing compounds used as dyes include C,
1, Ac1d Blue 120 (manufactured by Nippon Kayaku Co., Ltd.)
, C,1,Ac1dBlue 116 (manufactured by Nippon Kayaku Co., Ltd.), C,1,Ac1d Orange7 (manufactured by Nippon Kayaku Co., Ltd.), etc., C,1,Ac1dViol
et 56 (manufactured by Nippon Kayaku Co., Ltd.), 1llcid Co
mplexViolet 3R (manufactured by Nippon Kayaku Co., Ltd.), A
izen 0palν1olet 3RL (manufactured by Hodogaya Chemical Industry Co., Ltd.), 8cidComplex Viole
t 4R (manufactured by Nippon Kayaku Co., Ltd.) C, I, Ac1d Viol
et 58 (manufactured by Nippon Kayaku Co., Ltd.), C,1,8cidG
Examples include metal complexes of acidic dyes such as the chromium complex of Reen 35 (manufactured by Nippon Kayaku Co., Ltd.). As for the structure of the dye, aminoanthraquinone type, azo type, or any other type can be used. In addition to dyes, p-toluenesulfonic acid and 2-hydroxy-, which is known as an ultraviolet absorber,
4-Methoxybenzophenone-5-sulfonic acid, 2-hydroxy 4-n-octoxybenzophenone-5-sulfonic acid, 2-hydroxy-4-n-dodecyloxybenzophenone-5-sulfonic acid, 2-hydroxy-4 Hensyloxybenzophenone-5-sulfonic acid and the like can also be used.
上記スルホン酸基を有する有機化合物による処理する方
法としては、通常上記有機化合物の水溶液に繊維製品を
浸漬する方法が採用されるが、酸性染料、カチオン染料
を用いる場合には処理液のｐＨを酢酸等により酸性側に
調整して行う。ｐＨの調整に使用する酸として、塩酸、
硫酸、蟻酸、Ｐ−トルエンスルホン酸、サリチル酸、過
塩素酸等を用いることもでき、これらは後述するドーパ
ントとしての作用をも有するため好ましい。またＰ−ト
ルエンスルホン酸は上記したスルホン酸基を有する有機
化合物としての作用をも有する。酸性染料、カチオン染
料の場合、処理液における染料濃度は０．０１〜２％程
度が好ましく、処理液のｐＨは１〜７が好ましい。浸漬
条件は特に限定されず、通常の染色条件と同様で良いが
、繊維に対して所定量が正確に均一に吸尽されているこ
とが好ましい。As a method for treating with the above organic compound having a sulfonic acid group, a method is usually adopted in which textile products are immersed in an aqueous solution of the above organic compound, but when using acidic dyes or cationic dyes, the pH of the treatment solution is adjusted to etc. to make it more acidic. Hydrochloric acid,
Sulfuric acid, formic acid, P-toluenesulfonic acid, salicylic acid, perchloric acid, etc. can also be used, and these are preferred because they also have the function of a dopant as described below. Furthermore, P-toluenesulfonic acid also functions as an organic compound having the above-mentioned sulfonic acid group. In the case of acidic dyes and cationic dyes, the dye concentration in the treatment liquid is preferably about 0.01 to 2%, and the pH of the treatment liquid is preferably 1 to 7. The dipping conditions are not particularly limited and may be the same as normal dyeing conditions, but it is preferable that a predetermined amount of dipping be applied to the fibers accurately and uniformly.
直接染料、分散染料により処理を行う場合も酸性染料と
同様の条件を採用できる。更に染料以外のスルホン酸基
含有有機化合物により処理する場合も該有機化合物が繊
維に吸尽される条件であれば特に限定はされない。The same conditions as for acid dyes can be used when processing with direct dyes or disperse dyes. Furthermore, when treating with an organic compound containing a sulfonic acid group other than dyes, there are no particular limitations as long as the conditions are such that the organic compound is exhausted by the fibers.
尚、必要により上記処理液中に酢酸アンモニウム、硫酸
アンモニウム、均染剤等の助剤を添加することもできる
。Incidentally, if necessary, auxiliary agents such as ammonium acetate, ammonium sulfate, and leveling agent may be added to the above-mentioned treatment liquid.
上記スルホン酸基含有有機化合物による処理液にはメタ
ノール、エタノール、プロパツール、ブタノール等のア
ルコール類を添加しても良く、アルコール類を添加する
と処理温度を低下できる効果があり、また有機化合物の
繊維製品への浸透性も向上される。Alcohols such as methanol, ethanol, propatool, and butanol may be added to the treatment solution using the above-mentioned sulfonic acid group-containing organic compound. Penetration into the product is also improved.
上記の如くスルホン酸基含有有機化合物による処理を施
された繊維製品は、ピロール系モノマーと接触せしめ、
酸化重合剤の存在下に該千ツマ−を重合せしめて繊維製
品と複合化させる。ピロール系モノマーとしてはピロー
ル、３−メチルピロール、Ｎ−メチルピロール等が挙げ
られる。また酸化重合剤としては、過マンガン酸、過マ
ンガン酸カリウム等の過マンガン酸或いは過マンガン酸
塩、三酸化クロム酸等のクロム酸類、硝酸銀等の硝酸塩
類、塩素、臭素等のハロゲン類、過酸化水素、過酸化ベ
ンゾイル等の過酸化物、ベルオクソ二硫酸等のベルオク
ソ酸（又はその塩）、次亜塩素酸ナトリウム等の酸素酸
（又はその塩）、塩化第二鉄等の遷移金属塩化物、或い
は硫酸第二鉄１、過硫酸カリウム、過硫酸アンモニウム
、過塩素酸第二鉄等が挙げられる。The textile product treated with the sulfonic acid group-containing organic compound as described above is brought into contact with a pyrrole monomer,
The polymer is polymerized in the presence of an oxidative polymerization agent to form a composite with a textile product. Examples of the pyrrole monomer include pyrrole, 3-methylpyrrole, and N-methylpyrrole. Examples of oxidative polymerization agents include permanganic acid or permanganates such as permanganic acid and potassium permanganate, chromic acids such as chromic acid trioxide, nitrates such as silver nitrate, halogens such as chlorine and bromine, and permanganates such as permanganate and potassium permanganate. Hydrogen oxide, peroxides such as benzoyl peroxide, peroxo acids (or their salts) such as peroxodisulfuric acid, oxygen acids (or their salts) such as sodium hypochlorite, transition metal chlorides such as ferric chloride , or ferric sulfate 1, potassium persulfate, ammonium persulfate, ferric perchlorate, and the like.
ピロール系モノマーを重合せしめるに際し、導電性を更
に向上せしめるためにドーパントを併用することができ
る。ドーパントとしては丘部化リン等のルイス酸、塩化
水素、硫酸等のプロトン酸、過塩素酸銀、弗化ホウ素銀
等の遷移金属化合物等が挙げられる。更に前記酸化重合
剤のうち、ノ＼ロゲン類、ベルオクソ酸（塩）、遷移金
属塩化物もドーパントとして機能するため、酸化重合剤
としてこれらを用いた場合に、敢えて上記ドーパントと
併用する必要はないが、上記ドーパントを併用すると更
に導電性を向上することができる。When polymerizing the pyrrole monomer, a dopant can be used in combination to further improve the conductivity. Examples of dopants include Lewis acids such as phosphorus chloride, protonic acids such as hydrogen chloride and sulfuric acid, and transition metal compounds such as silver perchlorate and silver boron fluoride. Furthermore, among the oxidative polymerization agents, norogens, beroxo acids (salts), and transition metal chlorides also function as dopants, so when these are used as oxidative polymerization agents, there is no need to use them together with the above dopants. However, when the above dopants are used in combination, the conductivity can be further improved.
繊維製品をピロール系モノマーと接触させて酸化重合剤
の存在下にピロール系モノマーを重合させる方法として
は、■ピロール系モノマーと酸化重合剤及び必要により
ドーパントを添加した溶液に、千ツマ−が実質的に重合
する以前に繊維製品を浸漬して処理する方法、■酸化重
合剤と必要によりドーパントを添加した溶液と、ピロー
ル系モノマーを含有する溶液とに繊維製品を順次浸漬し
て処理する方法、■酸化重合剤と必要によりドーパント
を添加した溶液に繊維製品を浸漬して処理した後、この
処理液中にピロール系モノマーを添加して処理する方法
等が挙げられる。これら処理液において酸化重合剤の濃
度は、ピロール系モノマーの当量数の２倍以上が必要で
あり、ピロール系モノマーの濃度は付与する導電性の程
度にもよるが繊維当たり０．０１〜５重量％程度が好ま
しいまたドーパントを用いる場合、ドーパント濃度はピ
ロール系モノマーのモル数に対して１／２〜当量が好ま
しく、この程度の濃度となるように処理液を調整するこ
とが好ましい。上記方法の中でも■、■の方法で、先ず
酸化重合剤を含む溶液に繊維製品を２０〜６０分浸漬処
理した後、ピロール系モノマーと接触させることが好ま
しい。ピロール系モノマーと接触させる際の処理液の温
度は、優れた導電性を得るためには０〜４０℃、特に０
〜５°Ｃが好ましい。またピロール系モノマーを含む処
理液への浸漬時間はピロール系モノマーや酸化重合剤の
濃度、所望する導電性の程度、繊維製品の材質、形態等
によっても異なるが、通常１分〜３時間程度である。The method of polymerizing the pyrrole monomer in the presence of an oxidative polymerization agent by bringing the textile product into contact with the pyrrole monomer is as follows. A method in which textile products are immersed and treated before being polymerized; ■ A method in which textile products are sequentially immersed in a solution containing an oxidative polymerization agent and, if necessary, a dopant, and a solution containing a pyrrole monomer; (2) A method in which a textile product is immersed in a solution containing an oxidative polymerization agent and, if necessary, a dopant, is then treated, and then a pyrrole monomer is added to the treatment solution. In these treatment solutions, the concentration of the oxidative polymerization agent must be at least twice the number of equivalents of the pyrrole monomer, and the concentration of the pyrrole monomer is 0.01 to 5% by weight per fiber, depending on the degree of conductivity imparted. When a dopant is used, the concentration of the dopant is preferably 1/2 to an equivalent amount based on the number of moles of the pyrrole monomer, and it is preferable to adjust the treatment liquid so that the concentration is about this level. Among the above methods, in methods (1) and (2), it is preferable to first immerse the textile product in a solution containing an oxidative polymerization agent for 20 to 60 minutes, and then contact it with the pyrrole monomer. The temperature of the treatment liquid when bringing it into contact with the pyrrole monomer should be 0 to 40°C, especially 0 to 40°C, in order to obtain excellent conductivity.
~5°C is preferred. The immersion time in the treatment solution containing the pyrrole monomer varies depending on the concentration of the pyrrole monomer and oxidative polymerization agent, the desired degree of conductivity, the material and form of the textile product, etc., but it is usually about 1 minute to 3 hours. be.
上記酸化重合剤、ピロール系モノマー ドーパント等を
含有する処理液における溶媒としては、通常水が用いら
れるが、脂肪族アルコール類、脂肪族ケトン類、エーテ
ル類、ハロゲン化炭化水素類、エステル類、脂肪族炭化
水素類、芳香族炭化水素類等を用いることもできる。Water is usually used as a solvent in the treatment liquid containing the oxidative polymerization agent, pyrrole monomer dopant, etc., but aliphatic alcohols, aliphatic ketones, ethers, halogenated hydrocarbons, esters, aliphatic Group hydrocarbons, aromatic hydrocarbons, etc. can also be used.
以上のようにして得られる本発明の導電性繊維製品は、
繊維製品の表面をピロール系重合体が被覆しているか、
或いはピロール系重合体の一部又は全部が繊維製品内部
に含浸された構成を有する。The conductive fiber product of the present invention obtained as described above is
Is the surface of the textile product coated with pyrrole polymer?
Alternatively, the fiber product has a structure in which part or all of the pyrrole polymer is impregnated inside the textile product.
以下、実施例を挙げて本発明を更に詳細に説明する。 Hereinafter, the present invention will be explained in more detail with reference to Examples.
実施例１
１．５デニール、繊維長５１肛の６−ナイロン繊維をニ
ードルパンチングして得た２ ５０ ｇ／ｒｄの不織布
を、３ｇ／！濃度のデイアダビン（バイエル製）で、６
０°Ｃにで３０分間充分に洗浄して帯電防止剤、油剤等
を完全に除去した後、スルホン酸基含有有機化合物とし
て、酸性染料のクロム錯体（Ｋａｙａｋａｌａｎ ０１
ｉｖｅ ＧＬ ：日本化薬製）１．５重量％、硫酸アン
モニウム５重量％含む９５℃の処理液に３０分間浸漬し
て処理した。次いでイオン交換水で充分に洗浄した後、
８０°Ｃで乾燥した。次にピロール０．０１モル／ｋｇ
、塩化第二鉄０．０２５モル／ｋｇを含む水溶液（液温
５°Ｃ）に１８０分間浸漬した後、充分に水洗し、８０
“Ｃで乾燥した。Example 1 A 250 g/rd nonwoven fabric obtained by needle-punching 6-nylon fibers of 1.5 denier and 51 fiber length was 3 g/! With a concentration of Deidavin (manufactured by Bayer), 6
After thoroughly washing at 0°C for 30 minutes to completely remove antistatic agents, oils, etc., a chromium complex of acid dye (Kayakalan 01) was added as an organic compound containing a sulfonic acid group.
ive GL (manufactured by Nippon Kayaku) and 5% by weight of ammonium sulfate at 95° C. for 30 minutes. Then, after washing thoroughly with ion-exchanged water,
It was dried at 80°C. Next, 0.01 mol/kg of pyrrole
, immersed in an aqueous solution (liquid temperature 5°C) containing 0.025 mol/kg of ferric chloride for 180 minutes, thoroughly washed with water,
"Dried at C.
得られた不織布は暗緑色であった。処理後の不織布の表
面抵抗値は３８０Ωであり、耐光テスト（ブラックパネ
ル温度６３°Ｃ）を２００時間行った後の表面抵抗値は
１．５Ｘ１０’Ωであった。The obtained nonwoven fabric was dark green. The surface resistance value of the nonwoven fabric after treatment was 380Ω, and the surface resistance value after conducting a light resistance test (black panel temperature 63°C) for 200 hours was 1.5×10′Ω.
実施例２
６−ナイロン２５％、ポリエチレンテレフタレート７５
％からなる２００デニール、繊維長７５フイートの工２
分割型繊維の綾織物（１５０ｇ／ｒｒｒ）を、３３％水
酸化ナトリウム水溶液に浸漬して減量しながら分割して
極細繊維とした。この時点でのポリエチレンテレフタレ
ートと６−ナイロンとの比率は４２：２５であった。Example 2 6-nylon 25%, polyethylene terephthalate 75
200 denier, 75 feet fiber length consisting of 2
A twill fabric (150 g/rrr) of splittable fibers was immersed in a 33% aqueous sodium hydroxide solution to reduce the weight and split into ultrafine fibers. At this point, the ratio of polyethylene terephthalate to 6-nylon was 42:25.
次いでスルホン酸基含有有機化合物として、含クロム錯
体型酸性染料（Ａｃｉｄｏｌ Ｇｒｅｅｎ ＭＦＧＬ）
１．０重量％、硫酸アンモニウム５重量％を含有する
９５°Ｃの処理液に３０分間浸漬して処理した。イオン
交換水で充分洗浄し、１２０°Ｃで乾燥した後、ピロー
ル０．０１モル／ｋｇ、塩化第二鉄０．０２５モル／ｋ
ｇを含む水溶液（液温５°Ｃ）に１８０分間浸漬した後
、充分に水洗し１２０°Ｃで乾燥した。得られた綾織物
は暗緑色であった。処理後の織物の表面抵抗値は２６０
Ωであった。また実施例１と同様の耐光テストを行った
後の表面抵抗値は３×１０５Ωであった。Next, as a sulfonic acid group-containing organic compound, a chromium-containing complex type acid dye (Acidol Green MFGL) was used.
It was treated by immersing it in a 95°C treatment solution containing 1.0% by weight and 5% by weight of ammonium sulfate for 30 minutes. After thorough washing with ion-exchanged water and drying at 120°C, pyrrole 0.01 mol/kg, ferric chloride 0.025 mol/k
After immersing the sample in an aqueous solution containing g for 180 minutes (liquid temperature: 5°C), it was thoroughly washed with water and dried at 120°C. The obtained twill fabric was dark green. The surface resistance value of the fabric after treatment is 260
It was Ω. Further, the surface resistance value after conducting the same light resistance test as in Example 1 was 3×10 5 Ω.
実施例３
１．５デニール、繊維長５１ｍｍの６−ナイロン繊維を
ニードルパンチングして得た２ ５０ ｇ ／ ｒｒＴ
の不織布を充分に洗浄し、帯電防止剤、油剤を除去した
後、２−ヒドロキシ−４−メトキシヘンシフエノン−５
−スルホン酸を１重量％、硫酸アンモニウムを５重量％
含む９５°Ｃの処理液に３０分浸漬して処理した。次い
でピロール０．０１モル／ｋｇ、過硫酸カリウムＯ，Ｏ
ｌ ２５モル／ｋｇを含む水溶液（１７°Ｃ）に１８０
分浸漬した後、充分に水洗して乾燥した。得られた不織
布は真黒色であった。Example 3 250 g/rrT obtained by needle punching 6-nylon fiber of 1.5 denier and fiber length of 51 mm
After thoroughly washing the nonwoven fabric and removing the antistatic agent and oil, 2-hydroxy-4-methoxyhensiphenone-5
- 1% by weight of sulfonic acid, 5% by weight of ammonium sulfate
The sample was immersed in a 95°C treatment solution for 30 minutes. Then pyrrole 0.01 mol/kg, potassium persulfate O, O
180 in an aqueous solution (17°C) containing 25 mol/kg
After soaking for a few minutes, it was thoroughly washed with water and dried. The obtained nonwoven fabric was pure black.
また処理後の表面抵抗値は２９０Ωであり、耐光テスト
後の表面抵抗値は１．５ＸＩＯ’Ωであった。The surface resistance value after treatment was 290Ω, and the surface resistance value after the light resistance test was 1.5XIO'Ω.
実施例４
Ｉ、５デニール、繊維長５１ｍｍの６−ナイロン不ｍ布
（５００ｇ／ｒｒｆ）をＰ−）ルエンスルホン酸１重量
％、硫酸アンモニウム５重量％を含む９５°Ｃの処理液
に３０分間浸漬して処理した後、ピロール０．０１モル
／ｋｇ、過硫酸アンモニウム０．０１２５モル／ｋｇを
含む水溶液（液温１７°Ｃ）に１８０分間浸漬した。充
分に水洗し乾燥して得られた不織布の表面抵抗値は４５
０Ωであった。また耐光テスト後の表面抵抗値は３Ｘ１
０’Ωであった。Example 4 A 6-nylon non-woven fabric (500 g/rrf) with I, 5 denier and fiber length of 51 mm was immersed for 30 minutes in a treatment solution at 95°C containing 1% by weight of P-) luenesulfonic acid and 5% by weight of ammonium sulfate. After that, it was immersed for 180 minutes in an aqueous solution (liquid temperature: 17°C) containing 0.01 mol/kg of pyrrole and 0.0125 mol/kg of ammonium persulfate. The surface resistance value of the nonwoven fabric obtained by thorough washing with water and drying is 45.
It was 0Ω. In addition, the surface resistance value after the light resistance test is 3X1
It was 0'Ω.
比較例１
実施例１で使用したと同様の不織布を実施例１と同様に
デイアダビンで洗浄した後、ピロール０゜０１モル／ｋ
ｇ、塩化第二鉄０．０２５モル／ｋｇを含む水溶液（液
温５”Ｃ）に１８０分間浸漬して処理し、水洗、乾燥し
た。得られた不織布の表面抵抗値は８５０Ωであり、ま
た耐光テストを２００時間行った後の表面抵抗値は８．
５Ｘ１０’Ωであった。Comparative Example 1 A nonwoven fabric similar to that used in Example 1 was washed with Deidavin in the same manner as in Example 1, and then pyrrole 0°01 mol/k was added.
The nonwoven fabric obtained had a surface resistance of 850 Ω, The surface resistance value after 200 hours of light resistance test was 8.
It was 5×10′Ω.
本発明の導電性繊維製品は、被処理繊維製品としてポリ
アミドを含有する繊維製品を用いることと、繊維製品を
ピロール系モノマーと接触させ、酸化重合剤の存在下に
ピロール系モノマーを重合させてピロール系重合体と繊
維製品とを複合化するに先立って、まず繊維製品をスル
ホン酸基を含む有機化合物で処理したことにより、スル
ホン酸基を含む有機化合物による処理を行わずにピロー
ル系重合体と複合化したものに比べて導電性が更に向上
され、しかも優れた耐光性を有し、紫外線等を浴びても
導電性の低下が従来のものに比して少ない。更にスルホ
ン酸基を含む有機化合物として染料を用いた場合、染料
の色とピロール系重合体の色との重なり合いによってバ
ラエティ−に冨んだ色調の繊維製品が得られる。また本
発明方法によれば簡単な設備で効率良く優れた導電性繊
維製品を得ることができる効果を有する。The conductive fiber product of the present invention is produced by using a fiber product containing polyamide as a fiber product to be treated, and by bringing the fiber product into contact with a pyrrole monomer and polymerizing the pyrrole monomer in the presence of an oxidative polymerization agent. Prior to compositing the pyrrole-based polymer and the textile product, the textile product was first treated with an organic compound containing a sulfonic acid group. Its conductivity is further improved compared to composite materials, and it also has excellent light resistance, with less decrease in conductivity than conventional materials even when exposed to ultraviolet rays. Furthermore, when a dye is used as the organic compound containing a sulfonic acid group, textile products with a wide variety of colors can be obtained due to the overlap between the color of the dye and the color of the pyrrole polymer. Furthermore, the method of the present invention has the advantage that excellent conductive fiber products can be obtained efficiently and with simple equipment.
Claims (3)
リアミド含有繊維製品の表面がピロール系重合体で被覆
されているか、或いは上記繊維製品にピロール系重合体
の一部又は全部が含浸されていることを特徴とする導電
性繊維製品。(1) The surface of a polyamide-containing textile product treated with an organic compound having a sulfonic acid group is coated with a pyrrole polymer, or the textile product is impregnated with part or all of the pyrrole polymer. A conductive fiber product characterized by:
有機化合物で処理した後、ピロール系モノマーと接触さ
せて酸化重合剤の存在下にピロール系モノマーを重合せ
しめ、ポリアミド含有繊維製品にピロール系重合体を複
合化せしめて導電性を付与することを特徴とする導電性
繊維製品の製造方法。(2) After treating a polyamide-containing textile product with an organic compound having a sulfonic acid group, it is brought into contact with a pyrrole-based monomer to polymerize the pyrrole-based monomer in the presence of an oxidative polymerization agent, thereby forming a pyrrole-based polymer into a polyamide-containing textile product. 1. A method for manufacturing a conductive fiber product, characterized by imparting conductivity to the product by compositing it.
の存在下に重合せしめてポリアミド含有繊維製品にピロ
ール系重合体を複合化せしめることを特徴とする請求項
１記載の導電性繊維製品の製造方法。(3) The method for producing a conductive textile product according to claim 1, characterized in that the pyrrole-based monomer is polymerized in the presence of an oxidative polymerization agent and a dopant to compound the pyrrole-based polymer into the polyamide-containing textile product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2046832A JP3007896B2 (en) | 1990-02-27 | 1990-02-27 | Conductive fiber product and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2046832A JP3007896B2 (en) | 1990-02-27 | 1990-02-27 | Conductive fiber product and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03249272A true JPH03249272A (en) | 1991-11-07 |
| JP3007896B2 JP3007896B2 (en) | 2000-02-07 |
Family
ID=12758309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2046832A Expired - Fee Related JP3007896B2 (en) | 1990-02-27 | 1990-02-27 | Conductive fiber product and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3007896B2 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08243066A (en) * | 1995-01-13 | 1996-09-24 | Japan Vilene Co Ltd | Cleaning material |
| JPH09168497A (en) * | 1995-12-20 | 1997-06-30 | Japan Vilene Co Ltd | Cleaning material |
| JP2007146322A (en) * | 2005-11-28 | 2007-06-14 | Toray Ind Inc | Fiber structure |
| JP2007169824A (en) * | 2005-12-22 | 2007-07-05 | Tayca Corp | Method for producing low-dust emitting electroconductive fiber sheet |
| JP2007169823A (en) * | 2005-12-22 | 2007-07-05 | Tayca Corp | Low-dust emitting electroconductive fiber sheet |
| JP2009155765A (en) * | 2007-12-27 | 2009-07-16 | Tayca Corp | Low-dusting conductive yarn and process for producing the same |
| JP5255281B2 (en) * | 2006-10-24 | 2013-08-07 | 三菱レイヨン株式会社 | Method for imparting conductivity, method for producing conductive material, and conductive material |
| CN104562708A (en) * | 2015-01-08 | 2015-04-29 | 马鞍山金姿纺织装饰用品有限公司 | Preparation method for antistatic terylene tablecloth |
| JP2015140493A (en) * | 2014-01-28 | 2015-08-03 | 東レ株式会社 | Multifilament yarn and fiber structure prepared using the same |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160325523A1 (en) | 2007-11-05 | 2016-11-10 | Owens Corning Intellectual Capital, Llc | Antislip sheet material with twisted tapes |
| US10124557B2 (en) | 2007-11-05 | 2018-11-13 | Owens Corning Intellectual Capital, Llc | Antislip sheet material with twisted tapes |
-
1990
- 1990-02-27 JP JP2046832A patent/JP3007896B2/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08243066A (en) * | 1995-01-13 | 1996-09-24 | Japan Vilene Co Ltd | Cleaning material |
| JPH09168497A (en) * | 1995-12-20 | 1997-06-30 | Japan Vilene Co Ltd | Cleaning material |
| JP2007146322A (en) * | 2005-11-28 | 2007-06-14 | Toray Ind Inc | Fiber structure |
| JP2007169824A (en) * | 2005-12-22 | 2007-07-05 | Tayca Corp | Method for producing low-dust emitting electroconductive fiber sheet |
| JP2007169823A (en) * | 2005-12-22 | 2007-07-05 | Tayca Corp | Low-dust emitting electroconductive fiber sheet |
| JP4621134B2 (en) * | 2005-12-22 | 2011-01-26 | テイカ株式会社 | Manufacturing method of low dust generation conductive fiber sheet |
| JP5255281B2 (en) * | 2006-10-24 | 2013-08-07 | 三菱レイヨン株式会社 | Method for imparting conductivity, method for producing conductive material, and conductive material |
| JP2009155765A (en) * | 2007-12-27 | 2009-07-16 | Tayca Corp | Low-dusting conductive yarn and process for producing the same |
| JP2015140493A (en) * | 2014-01-28 | 2015-08-03 | 東レ株式会社 | Multifilament yarn and fiber structure prepared using the same |
| CN104562708A (en) * | 2015-01-08 | 2015-04-29 | 马鞍山金姿纺织装饰用品有限公司 | Preparation method for antistatic terylene tablecloth |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3007896B2 (en) | 2000-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0302590B1 (en) | Method for making electrically conductive materials | |
| US4975317A (en) | Electrically conductive textile materials and method for making same | |
| KR840002109B1 (en) | Electrically conducting fiber and method of making same | |
| JPH03249272A (en) | Electrically conductive textile product and its production | |
| US4374893A (en) | Textiles with improved conducting properties and processes for their manufacture | |
| US5833884A (en) | Method of enhancing the stability of conductive polymers | |
| JP4825772B2 (en) | Conductive animal hair fiber sliver and production method thereof, conductive spun yarn obtained from the sliver, and fiber product using the conductive spun yarn | |
| US1717483A (en) | Textile material and method of treating the same | |
| JPH03294580A (en) | Electrically conductive fiber | |
| JPH03294579A (en) | Electrically conductive fiber | |
| He et al. | Preparation of polyaniline/nylon conducting fabric by layer‐by‐layer assembly method | |
| JPH0465577A (en) | Production of conductive fiber | |
| JPH03234871A (en) | Electrically conductive woven fabric and its preparation | |
| EP1915481B1 (en) | Process for printing and finishing on fabrics partially or totally containing aramidic fibre, in the form of filament and/or flock | |
| JPH0559671A (en) | Electrically conductive cellulosic fiber and its production | |
| JPH06184944A (en) | Electrically conductive vinylon fiber and its production | |
| US5773372A (en) | Coated polyester fiber fabric and a production process therefor | |
| JP2874334B2 (en) | Conductive fiber and method for producing the same | |
| JP2969494B2 (en) | Method for producing short flat fiber product, and glove having uniform dyeability and conductivity | |
| JP3202812B2 (en) | Manufacturing method of conductive clothing | |
| JPS61282479A (en) | Conductive fiber product and its production | |
| JPH08260286A (en) | Woven fabric excellent in flame retardance | |
| KR100301594B1 (en) | Polyester fiber coated fabric and manufacturing method | |
| JPS62170581A (en) | Production of organometal composite fiber | |
| JPS61138780A (en) | Dyeing of aromatic polyamide fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20071203 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081203 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091203 Year of fee payment: 10 |
|
| LAPS | Cancellation because of no payment of annual fees |