CN104562708A - Preparation method for antistatic terylene tablecloth - Google Patents
Preparation method for antistatic terylene tablecloth Download PDFInfo
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- CN104562708A CN104562708A CN201510009288.3A CN201510009288A CN104562708A CN 104562708 A CN104562708 A CN 104562708A CN 201510009288 A CN201510009288 A CN 201510009288A CN 104562708 A CN104562708 A CN 104562708A
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- tablecloth
- solution
- modified dacron
- aqueous solution
- terylene
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Abstract
The invention discloses a preparation method for an antistatic terylene tablecloth, and belongs to the technical field of textile materials. The preparation method comprises the following steps: carrying out continuous modification treatment on the terylene tablecloth sequentially through the mixed solution composed of Na2CO3 solution, N-(2-aminoethyl)-3-aminopropyl trimethoxy-silane and vinyl trimethoxy silane, and ammonium persulphate solution, then impregnating the terylene tablecloth in the mixed conjugated monomer solution composed of phenylamine and p-aminothiophenol, and carrying out polymerization reaction, washing and drying to prepare the antistatic terylene tablecloth under the synergistic effect of perchloric acid, 4-thiacalixarene sulfonated sodium and phenol red sodium salt. The antistatic terylene tablecloth prepared by the method disclosed by the invention has an electrical conductivity of 8.5*10<-3> to 3.6*10<-2> S.cm<-1>; the preparation method disclosed by the invention has the following characteristics that the preparation method is simple, and the product is excellent in antistatic performance, wide in applicability and the like.
Description
Technical field:
The invention belongs to textile material technical field, be specifically related to a kind of preparation method of the anti-electrostatic polyester tablecloth.
Background technology:
Electrostatic phenomenon is common in all kinds of textiles.Eliminate electrostatic phenomenon, obtain anti-static function is one of focus of textile material research field (Youyi Xia always, Yun Lu. " Fabrication and properties of conductive conjugatedpolymers/silk fibroin composite fibers ", " Compostie Science and Technology ", 2008,68,1471-1479).
The tablecloth is that a class is covered on platform, desktop in order to antifouling or increase textiles attractive in appearance.As the high-grade tablecloth of one, the terylene class tablecloth is widely used in furnishings, dinner party, dining etc.But, because the polyester fiber hydrophily forming the terylene class tablecloth is poor, cause its electrostatic phenomenon very serious, thus in processing and use procedure, often cause serious fluffing, pilling effect, blast, disaster hidden-trouble (Liu Yuqiang etc. also can be produced under particular surroundings, " nano zine oxide-iron oxide mixed sols is to the antistatic effect of dacron ", " textile journal ", 2013,34,17-23).Therefore, the anti-static function of the endowing terylene class tablecloth is a problem demanding prompt solution.
Carrying out modification in textile surface, is the common methods solving electrostatic phenomenon.Compared to all kinds of antistatic additive, conjugative monomer, in the polymerization of fiber surface, because it is convenient, nontoxic, has therefore developed into the new methods preparing antistatic textile.As Chinese patent CN103468541A discloses a kind of simple preparation process of antistatic surface dacron, the method carries out aniline polymerization in dacron surface, obtains anti-static fabric; Chinese patent CN102943388A discloses a kind of method that home position polymerization reaction prepares Antistatic polyester fabric, and the method adopts home position polymerization reaction to also obtain a class anti-static fabric.Though application said method can obtain the terylene class tablecloth of certain antistatic behaviour, but, also there is the problems such as resistance is bigger than normal, antistatic behaviour is not good enough.
Summary of the invention:
The present invention is directed in the existing anti-electrostatic polyester tablecloth and there is technical problem, provide a kind of preparation method of the anti-electrostatic polyester tablecloth.
The preparation method of a kind of anti-electrostatic polyester tablecloth provided by the invention, its concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C.
(2) described modified dacron tablecloth A is placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B, the mass ratio of described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) described modified dacron tablecloth B is placed in mass fraction be 10% ~ 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D; The molar concentration of described mixing conjugative monomer in described solution D is 0.05 ~ 0.2molL
-1, the mol ratio of described aniline and p-Mercaptoaniline is (10 ~ 15): 1, and the molar concentration of described perchloric acid in described mixed aqueous solution is 0.5molL
-1, the molar concentration of described 4-sulfo group Thiacalixarene sodium salt in described mixed aqueous solution is 1mmolL
-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmolL
-1.
(5) described modified dacron tablecloth C is placed in described solution D, leaves standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry the obtained anti-electrostatic polyester tablecloth; The mass ratio of described modified dacron tablecloth C and described solution D is 1:20.
The electrical conductivity of the anti-electrostatic polyester tablecloth prepared by the present invention is: 8.5 × 10
-3~ 3.6 × 10
-2scm
-1(test of standard four point probe), antistatic behaviour is good.The inventive method, given full play to the concertedness of the conductive compositions produced after aniline is polymerized with mercaptoaniline, impel the terylene tablecloth to have higher electrical conductivity, thus antistatic behaviour is good.In addition, because early stage has carried out effective process to the terylene tablecloth, therefore conducting polymer particle can grow at terylene tablecloth fiber surface securely, thus good stability.Preparation technology of the present invention is simple, products obtained therefrom antistatic property is excellent, applicability is wide.
Detailed description of the invention:
Embodiment 1: electrical conductivity is 8.5 × 10
-3scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
1.
(2) by modified dacron tablecloth A
1be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
1, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
1be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
1.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
1; Mixing conjugative monomer is in solution D
1in molar concentration be 0.05molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 10:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
1with solution D
1mass ratio be 1:20, by modified dacron tablecloth C
1be placed in solution D
1in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 8.5 × 10
-3scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 2: electrical conductivity is 1.0 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
2.
(2) by modified dacron tablecloth A
2be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
2, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
2be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
2.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
2; Mixing conjugative monomer is in solution D
2in molar concentration be 0.08molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
2with solution D
2mass ratio be 1:20, by modified dacron tablecloth C
2be placed in solution D
2in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 1.0 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 3: electrical conductivity is 1.4 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
3.
(2) by modified dacron tablecloth A
3be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
3, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
3be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
3.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
3; Mixing conjugative monomer is in solution D
3in molar concentration be 0.1molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 12:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
3with solution D
3mass ratio be 1:20, by modified dacron tablecloth C
3be placed in solution D
3in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 1.4 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 4: electrical conductivity is 2.0 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
4.
(2) by modified dacron tablecloth A
4be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
4, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
4be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
4.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
4; Mixing conjugative monomer is in solution D
4in molar concentration be 0.12molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
4with solution D
4mass ratio be 1:20, by modified dacron tablecloth C
4be placed in solution D
4in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 2.0 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 5: electrical conductivity is 2.8 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
5.
(2) by modified dacron tablecloth A
5be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
5, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
5be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
5.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
5; Mixing conjugative monomer is in solution D
5in molar concentration be 0.15molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
5with solution D
5mass ratio be 1:20, by modified dacron tablecloth C
5be placed in solution D
5in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 2.8 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 6: electrical conductivity is 3.6 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
6.
(2) by modified dacron tablecloth A
6be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
6, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
6be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
6.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
6; Mixing conjugative monomer is in solution D
6in molar concentration be 0.2molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
6with solution D
6mass ratio be 1:20, by modified dacron tablecloth C
6be placed in solution D
6in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 3.6 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Claims (1)
1. a preparation method for the anti-electrostatic polyester tablecloth, is characterized in that these preparation method's concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C;
(2) described modified dacron tablecloth A is placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B, the mass ratio of described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4;
(3) described modified dacron tablecloth B is placed in mass fraction be 10% ~ 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C;
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D; The molar concentration of described mixing conjugative monomer in described solution D is 0.05 ~ 0.2molL
-1, the mol ratio of described aniline and p-Mercaptoaniline is (10 ~ 15): 1, and the molar concentration of described perchloric acid in described mixed aqueous solution is 0.5molL
-1, the molar concentration of described 4-sulfo group Thiacalixarene sodium salt in described mixed aqueous solution is 1mmolL
-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmolL
-1;
(5) described modified dacron tablecloth C is placed in described solution D, leaves standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry the obtained anti-electrostatic polyester tablecloth; The mass ratio of described modified dacron tablecloth C and described solution D is 1:20.
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Cited By (5)
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|---|---|---|---|---|
| CN105463833A (en) * | 2015-12-02 | 2016-04-06 | 马鞍山金姿纺织装饰用品有限公司 | Preparation method of antistatic polyester fabric |
| CN106480752A (en) * | 2016-12-01 | 2017-03-08 | 西南大学 | Colouring method of the sulfuretin to dacron |
| CN106676720A (en) * | 2016-11-25 | 2017-05-17 | 威海恒基伟业信息科技发展有限公司 | Antistatic cloth production method |
| CN108677525A (en) * | 2018-05-06 | 2018-10-19 | 邳州易萨新型材料有限公司 | A kind of preparation method of novel antistatic polyester fabric |
| CN115948816A (en) * | 2023-02-14 | 2023-04-11 | 无锡聚新科技股份有限公司 | Method for manufacturing white polyester composite conductive fiber |
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| CN106480752A (en) * | 2016-12-01 | 2017-03-08 | 西南大学 | Colouring method of the sulfuretin to dacron |
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| CN115948816A (en) * | 2023-02-14 | 2023-04-11 | 无锡聚新科技股份有限公司 | Method for manufacturing white polyester composite conductive fiber |
| CN115948816B (en) * | 2023-02-14 | 2023-09-05 | 无锡聚新科技股份有限公司 | Manufacturing method of white polyester composite conductive fiber |
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|---|---|
| CN104562708B (en) | 2016-05-11 |
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