JPH02307886A - Production of green rock crystal - Google Patents
Production of green rock crystalInfo
- Publication number
- JPH02307886A JPH02307886A JP12807989A JP12807989A JPH02307886A JP H02307886 A JPH02307886 A JP H02307886A JP 12807989 A JP12807989 A JP 12807989A JP 12807989 A JP12807989 A JP 12807989A JP H02307886 A JPH02307886 A JP H02307886A
- Authority
- JP
- Japan
- Prior art keywords
- crystal
- crystals
- raw materials
- pressure
- green
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract description 8
- 239000011034 rock crystal Substances 0.000 title abstract 3
- 239000013078 crystal Substances 0.000 claims abstract description 55
- 239000000654 additive Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 3
- 238000004040 coloring Methods 0.000 claims description 13
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 8
- 229960004887 ferric hydroxide Drugs 0.000 claims 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 12
- 239000002904 solvent Substances 0.000 abstract description 6
- 235000017550 sodium carbonate Nutrition 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract description 2
- 238000005216 hydrothermal crystallization Methods 0.000 abstract 2
- 238000012856 packing Methods 0.000 abstract 2
- 239000011435 rock Substances 0.000 abstract 2
- 239000003086 colorant Substances 0.000 abstract 1
- FLTRNWIFKITPIO-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe] FLTRNWIFKITPIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- 239000011038 green quartz Substances 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000010975 amethyst Substances 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、装飾用の宝石として広く用いられている緑色
水晶の製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing green crystal, which is widely used as a decorative jewel.
本発明は、装飾品として有用な緑色水晶を人工的に合成
できる製造方法において、Ｎａ２ＣＯ３水溶液を溶媒と
して用い、着色用添加剤としてＦｅ（ＯＨ）＊を用い、
所定の温度、圧力を与え、種子結晶上に結晶を育成する
水熱合成法により、装飾品として使用でき、かつ工業化
できる緑色水晶を育成するものである。The present invention is a manufacturing method that can artificially synthesize green crystals useful as decorative items, using Na2CO3 aqueous solution as a solvent and Fe(OH)* as a coloring additive.
By applying a predetermined temperature and pressure to grow crystals on seed crystals, a hydrothermal synthesis method is used to grow green crystals that can be used as ornaments and can be industrialized.
従来、水熱合成法においては、人工水晶の育成について
の研究開発および量産化が最も盛んであり、水熱合成法
における結晶育成としては、最も成功した例であるとい
える。現在までに人工水晶に関してはほとんど量産化技
術が確立している。Conventionally, in the hydrothermal synthesis method, research and development and mass production of artificial quartz crystals have been most active, and this can be said to be the most successful example of crystal growth using the hydrothermal synthesis method. To date, mass production technology has been established for most of the artificial quartz crystals.
また、この製造技術を生かした着色水晶の製造方法につ
いても紫水晶、黄水晶など各種着色水晶について研究開
発がなされている。現在の着色水晶は溶媒として、炭酸
カリウム（ＫｚＣＯｓ）水溶液等を使用し、温度範囲３
００〜４００℃、圧力１０００〜１５００ｋｇ ／ ｃ
ｊの条件で育成が行われている。着色用添加剤としては
、各種金属塩が使用されている。Furthermore, research and development is being conducted on various colored crystals such as amethyst and yellow quartz regarding a method for producing colored crystal that utilizes this manufacturing technology. Current colored crystals use potassium carbonate (KzCOs) aqueous solution as a solvent, and the temperature range is 3.
00~400℃, pressure 1000~1500kg/c
The cultivation is carried out under the conditions of j. Various metal salts are used as coloring additives.
従来の緑色水晶の水熱合成においては、結晶が育成でき
るものの以下のような問題点があった。In conventional hydrothermal synthesis of green crystals, although crystals can be grown, there are the following problems.
従来の着色用添加剤を使用した場合、育成結晶中に濃く
着色された部分と、薄く着色された部分ができてしまう
といった色むらの問題があった。When conventional coloring additives are used, there is a problem of color unevenness in which darkly colored parts and lightly colored parts are formed in the grown crystal.
また、育成部分の着色が不十分であるといった、色あい
の問題も生じていた。In addition, there was also a problem of color tone, such as insufficient coloring of the growing part.
従来の水熱合成法による着色水晶の育成についての色あ
り、色むら、透明度、あるいはクランクの発生といった
課題については、着色用添加剤の選択に起因している。Problems with the growth of colored crystals using conventional hydrothermal synthesis methods, such as color, uneven color, transparency, or occurrence of cranks, are caused by the selection of coloring additives.
着色用添加剤についてはさまざまな種類があるが、上記
課題を解決するために最適な着色用添加剤としてＦｅ（
Ｏ）ｌ）３を見出した。There are various types of coloring additives, but Fe(
O)l)3 was found.
水熱合成法においては、適当な温度と圧力のもとで出発
原料を適当な溶媒の水溶液に溶解させ、徐冷するまたは
温度差を利用して養分を輸送することにより、結晶を種
結晶上に育成する。これにより着色用添加剤は水溶液中
で金属イオンとなり、結晶中に取り込まれる。この着色
用添加剤として、Ｆｅ （ＯＨ） ３を用いた。これに
より、緑色水晶を得ることができる。In the hydrothermal synthesis method, starting materials are dissolved in an aqueous solution of an appropriate solvent at appropriate temperature and pressure, and crystals are grown on seed crystals by slow cooling or by transporting nutrients using the temperature difference. to develop. As a result, the coloring additive becomes a metal ion in the aqueous solution and is incorporated into the crystal. Fe (OH) 3 was used as the coloring additive. In this way, green crystal can be obtained.
以下、実施例に従い詳しく説明する。Hereinafter, a detailed explanation will be given according to examples.
第１図に本実施例の構成を模式的に表す断面図を示す。 FIG. 1 shows a sectional view schematically showing the configuration of this embodiment.
圧力容器本体１はシールリング２を介してカバー３によ
り圧力シールがされている。以上の構成の圧力容器にお
いて、圧力容器本体の底部に育成用原料４を設置する。The pressure vessel main body 1 is pressure-sealed by a cover 3 via a seal ring 2. In the pressure vessel configured as described above, the raw material for growth 4 is installed at the bottom of the pressure vessel main body.
この育成用原料４としては、天然水晶原石（ラス力）を
適当な大きさに砕いたものを使用した。次に種結晶支持
枠５を介して種結晶６が育成用原料４の上に配置されて
いる０種結晶としては天然あるいは人工の光学グレード
の水晶の例えばＺ板を用いる。育成する単結晶の欠陥の
原因とならないように特に内部のインクルージヨン、転
位などの少ない種結晶が必要である。このように育成用
原料４及び種結晶６を配置し、その間に同じく種結晶支
持枠５を介してパンフル板７が設置されている。また圧
力容器内部へ着色用添加剤を入れる。このような構成の
圧力容器の内部に媒体としてＮａｚＣＯ３水溶液を所定
の温度で所定の圧力が得られるような充填率で充填する
。As the raw material 4 for growth, a natural crystal raw stone (rath force) crushed into an appropriate size was used. Next, a seed crystal 6 is placed on the growth raw material 4 via a seed crystal support frame 5. As the zero seed crystal, for example, a Z plate of natural or artificial optical grade quartz is used. In order to avoid causing defects in the single crystal to be grown, a seed crystal with few internal inclusions, dislocations, etc. is required. The raw material for growth 4 and the seed crystal 6 are arranged in this way, and a breadboard 7 is placed between them via the seed crystal support frame 5 as well. Also, add a coloring additive to the inside of the pressure vessel. The pressure vessel having such a structure is filled with a NazCO3 aqueous solution as a medium at a filling rate such that a predetermined pressure is obtained at a predetermined temperature.
以上の設定で水熱合成を行う。すなわち、以下の通りで
ある。Perform hydrothermal synthesis with the above settings. That is, as follows.
（実施例ａ）
種結晶６の温度−−−−−−−・・−３２０℃育成用原
料４の温度−・−３４０℃
？容媒 −容器−・−−−−−０、５モル−Ｎａ２ＣＯ
＊水ン容ン夜着色用添加剤−−−−Ｆｅ（０１））ｔ
１ｗｔ％圧力−−−−−−−−−４０００ｋｇ ／ ｃ
ｄ育成期間 〜−−−−−１０日間
この結果、種結晶６の上に緑色水晶が育成された。以下
にその結果、性質を示す。(Example a) Temperature of seed crystal 6: -320°C Temperature of growing raw material 4: -340°C? Container -Container----0, 5 mol-Na2CO
*Additive for water coloring---Fe(01))t
1wt% pressure---4000kg/c
d Growth period: 10 days As a result, green crystal was grown on the seed crystal 6. The results and properties are shown below.
成長した層の厚み＝−３，３ｍ
成長速度 ・・−−−−一−−・・−・・−３８０ｍ／
日成長した層の性質 −・−・−緑色水晶（Ｘ線回折に
より同定）。従来の緑色水晶と比較して、含有物および
クラック等の欠陥の非常に少ない完全性の高い結晶が得
られた。Thickness of grown layer = -3.3m Growth rate ・・・−−−−−−・・−・・−380m/
Nature of diurnal growth layer - - Green quartz (identified by X-ray diffraction). Compared to conventional green quartz crystals, highly complete crystals with very few defects such as inclusions and cracks were obtained.
（実施例ｂ）
種結晶６の温度 −−一・−３４０℃
育成用原料４の温度−−３６０’Ｃ
溶媒 −−−−−−−０、５−Ｆ−／Ｌ／ Ｎ ａ ｔ
Ｃｏ ３水溶液着色用添加剤−−−−−−−４ｅ（Ｏ
ｆ（） ｓ １ｉｆｔ％圧力 −−−−−１０００ｋｇ
／ ｄ育成期間−・・−−−−１０日間
この結果、種結晶６の上に緑色水晶が育成された。以下
にその結果、性質は以下の通りである。(Example b) Temperature of seed crystal 6 ---1.-340°C Temperature of growing raw material 4 --360'C Solvent ---0, 5-F-/L/Nat
Additive for coloring Co3 aqueous solution---4e(O
f() s 1ift% pressure -----1000kg
/d Growth period: 10 days As a result, green crystal was grown on the seed crystal 6. The results and properties are as follows.
成長した層の厚み −−−−−・・−４，５−１成長速
度・・・−・・−・・・−−−−・−４５０μｌ／日成
長した層の性質・・−一−−−−緑色水晶（Ｘ線回折に
より同定）。従来の緑色水晶と比較して、含有物および
クラック等の欠陥の非常に少ない完全性の高い結晶が得
られた。Thickness of the grown layer -------4,5-1 Growth rate ---450μl/day Properties of the grown layer ---1-- --Green quartz (identified by X-ray diffraction). Compared to conventional green quartz crystals, highly complete crystals with very few defects such as inclusions and cracks were obtained.
（実施例Ｃ）
種結晶６の温度−・−−３６０℃
育成用原料４の温度−−−−−３８０’Ｃ溶媒−−−−
−−−０ 、５ モ／ｌ／ Ｎ ａ ｚ ＣＯ３水溶液
着色用添加剤−・−・−・−一−−−・・・・Ｆｅ（０
）１）＊ １ｉｉＬ％圧力−−−−−−・１０００ ｋ
ｇ ／ ｃｄ育成期間 −−−−−一−・−−−４０日
間この結果、種結晶６の上に緑色水晶が育成された。以
下にその結果、性質は以下の通りである。(Example C) Temperature of seed crystal 6---360°C Temperature of growth raw material 4---380'C Solvent----
---0, 5 mo/l/N az CO3 aqueous solution coloring additive --------1---...Fe(0
)1)*1iiL%pressure----1000k
g/cd Growth period -------40 days As a result, green crystal was grown on the seed crystal 6. The results and properties are as follows.
成長した層の厚み −・・・４．８讃■成長速度−−−
−−−−−−−−−−・−・４８０ｕ＋／日成長した層
の性質 −−−一緑色水晶（Ｘ線回折により同定）。従
来の緑色水晶と比較して、含有物およびクラック等の欠
陥の非常に少ない完全性の高い結晶が得られた。Thickness of grown layer ---4.8 ■Growth speed ---
----------·-480u+/day grown layer properties ---monogreen quartz (identified by X-ray diffraction). Compared to conventional green quartz crystals, highly complete crystals with very few defects such as inclusions and cracks were obtained.
以上詳述したように、本発明によれば従来の緑色水晶と
比較して、含有物およびクラック等の欠陥の非常に少な
い完全性の高い結晶の育成が可能である。また、装飾品
としての価値を充分に持った緑色水晶の育成が可能とな
り、その効果は極めて大きい。As described in detail above, according to the present invention, it is possible to grow highly complete crystals with very few defects such as inclusions and cracks compared to conventional green crystals. In addition, it becomes possible to grow green crystals that have sufficient value as ornaments, and the effect is extremely large.
第１図は本発明に用いる圧力容器の構造を表す断面図で
ある。
１・・・圧力容器本体
２・・・シールリング
３・・・カバー
４・・・育成用原料
５・・・種結晶支持枠
６・・・種結晶
７・・・パンフル板
８・・・着色用添加剤
以上FIG. 1 is a sectional view showing the structure of a pressure vessel used in the present invention. 1...Pressure vessel body 2...Seal ring 3...Cover 4...Raw material for growth 5...Seed crystal support frame 6...Seed crystal 7...Panful plate 8...Coloring additives for
Claims (2)
所定の温度、圧力を与える水熱合成法によって緑色水晶
を育成したことを特徴とする緑色水晶の製造方法。(1) A method for producing green crystal, characterized in that the green crystal is grown by a hydrothermal synthesis method in which a predetermined temperature and pressure are applied in an aqueous sodium carbonate (Na_2CO_3) solution.
として水酸化第二鉄Ｆｅ（ＯＨ）＿３を用いたことを特
徴とする請求項１記載の緑色水晶の製造方法。(2) The method for producing green crystal according to claim 1, characterized in that in the method for producing green crystal, ferric hydroxide Fe(OH)_3 is used as a coloring additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12807989A JPH02307886A (en) | 1989-05-22 | 1989-05-22 | Production of green rock crystal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12807989A JPH02307886A (en) | 1989-05-22 | 1989-05-22 | Production of green rock crystal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02307886A true JPH02307886A (en) | 1990-12-21 |
Family
ID=14975904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12807989A Pending JPH02307886A (en) | 1989-05-22 | 1989-05-22 | Production of green rock crystal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02307886A (en) |
-
1989
- 1989-05-22 JP JP12807989A patent/JPH02307886A/en active Pending
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