JPH02273169A - Filter material for tobacco - Google Patents
Filter material for tobaccoInfo
- Publication number
- JPH02273169A JPH02273169A JP9615889A JP9615889A JPH02273169A JP H02273169 A JPH02273169 A JP H02273169A JP 9615889 A JP9615889 A JP 9615889A JP 9615889 A JP9615889 A JP 9615889A JP H02273169 A JPH02273169 A JP H02273169A
- Authority
- JP
- Japan
- Prior art keywords
- phenolic resin
- activated carbon
- pref
- gas
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 21
- 241000208125 Nicotiana Species 0.000 title abstract description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 title abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 65
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 239000005011 phenolic resin Substances 0.000 claims abstract description 15
- 239000006260 foam Substances 0.000 claims abstract description 13
- 239000002657 fibrous material Substances 0.000 claims abstract description 10
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 9
- 239000011148 porous material Substances 0.000 claims description 19
- 235000019504 cigarettes Nutrition 0.000 claims description 16
- 238000000034 method Methods 0.000 abstract description 13
- 239000011134 resol-type phenolic resin Substances 0.000 abstract description 7
- 230000004913 activation Effects 0.000 abstract description 4
- 230000003213 activating effect Effects 0.000 abstract description 3
- 238000010000 carbonizing Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 20
- 238000001179 sorption measurement Methods 0.000 description 14
- 230000001590 oxidative effect Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 4
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004088 foaming agent Substances 0.000 description 4
- 229960002715 nicotine Drugs 0.000 description 4
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000008282 halocarbons Chemical class 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 2
- 229940099364 dichlorofluoromethane Drugs 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- SLGOCMATMKJJCE-UHFFFAOYSA-N 1,1,1,2-tetrachloro-2,2-difluoroethane Chemical compound FC(F)(Cl)C(Cl)(Cl)Cl SLGOCMATMKJJCE-UHFFFAOYSA-N 0.000 description 1
- MHTDCCPJYMZHSK-UHFFFAOYSA-N 1,1-dibromo-1,2,2-trifluoroethane Chemical compound FC(F)C(F)(Br)Br MHTDCCPJYMZHSK-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- ZZJVDYQPZOHNIK-UHFFFAOYSA-N 2,6-dihydroxybenzenesulfonic acid Chemical compound OC1=CC=CC(O)=C1S(O)(=O)=O ZZJVDYQPZOHNIK-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical compound CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229960000443 hydrochloric acid Drugs 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 229960004838 phosphoric acid Drugs 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 229940032330 sulfuric acid Drugs 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- -1 z-tanolamine Chemical compound 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、煙草または煙草用パイプに設けられるフィル
ター材料に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Field of Application> The present invention relates to a filter material for cigarettes or tobacco pipes.
〈従来技術とその問題点〉
近年、喫煙の害、例えばニコチン、タール分による肺癌
の可能性が喧伝されて以来、フィルター付きの煙草が一
般的になってきている。<Prior art and its problems> In recent years, since the harmful effects of smoking, such as the possibility of lung cancer caused by nicotine and tar, have been publicized, cigarettes with filters have become popular.
また、フィルターパイプを使用する人も増加している。Also, the number of people using filter pipes is increasing.
更に最近では、香喫味をマイルドにするために、活性
炭を混在させたフィルターが使われ始めている。 し
かし、従来使用されている活性炭は、いやな香りの成分
、特にアセトアルデヒドの吸着性能、とりわけ吸着速度
が遅いという問題があり、その性能の向上が望まれてい
た。Furthermore, recently, filters containing activated carbon have begun to be used to make the flavor milder. However, conventionally used activated carbon has the problem of slow adsorption performance, particularly slow adsorption speed, for components with unpleasant aromas, particularly acetaldehyde, and there has been a desire to improve this performance.
ところで、上記アセトアルデヒドの吸着性能を向上させ
るには、活性炭の粒径を小さくして表面積を増加する方
法、あるいは活性炭の量を増加する方法がある。 と
ころが、この方法では、フィルターの圧力損失が増加す
る、喫煙者の口内に活性炭が入り込む恐れがある等の問
題があり、その粒径の調整および増量は自ずから制限が
あった。By the way, in order to improve the adsorption performance of acetaldehyde, there is a method of increasing the surface area by reducing the particle size of activated carbon, or a method of increasing the amount of activated carbon. However, this method has problems such as an increase in the pressure loss of the filter and the risk of the activated carbon getting into the smoker's mouth, and there are inherent limitations in adjusting the particle size and increasing the amount.
本発明は、上記のような従来技術に伴う問題点の解決を
しようとするものであって、従来よりも、いやな香りの
主成分であるアセトアルデヒドの吸着性能に優れたフィ
ルター材料を提供することを目的とするものである。The present invention aims to solve the above-mentioned problems associated with the conventional technology, and aims to provide a filter material that has better adsorption performance for acetaldehyde, which is the main component of unpleasant fragrance, than before. The purpose is to
〈課題を解決するための手段〉
すなわち本発明は、フェノール樹脂発泡体が炭化、賦活
されてなり、嵩密度が０．０５〜０．５ｇ／ｃｍ’
炭素含有率が８５〜９５％、比表面積が５００ｍ’／ｇ
以上である炭素多孔体の粉砕物と繊維状物とからなるこ
とを特徴とする煙草用フィルター材料である。<Means for Solving the Problem> That is, the present invention is made by carbonizing and activating a phenolic resin foam, and having a bulk density of 0.05 to 0.5 g/cm'.
Carbon content is 85-95%, specific surface area is 500m'/g
This is a cigarette filter material characterized by comprising the above-mentioned pulverized carbon porous material and a fibrous material.
本発明のフィルター材料に用いられる前記炭素多孔体の
粉砕物は、従来フィルター材料の脱臭剤として使用され
ている活性炭より嵩密度が小さいため、外表面積が大き
く、その結果、煙草等に含有されるニコチン、タール分
等の有害成分やいやなにおいの成分を、極めて速く吸着
でき、且つ吸着量も多い。The pulverized carbon porous material used in the filter material of the present invention has a smaller bulk density than the activated carbon conventionally used as a deodorizing agent in filter materials, so it has a large outer surface area, and as a result, it can be contained in cigarettes, etc. It can adsorb harmful components such as nicotine and tar and components with unpleasant odors extremely quickly, and also has a large amount of adsorption.
従って、前記炭素多孔体の粉砕物は、フィルター材料と
して少量混合すれば済むので、フィルター材料の圧力損
失が少なくなる。Therefore, a small amount of the pulverized carbon porous material needs to be mixed as a filter material, so that the pressure loss of the filter material is reduced.
以下、本発明に係わる煙草用フィルター材料について、
具体的に説明する。Below, regarding the cigarette filter material according to the present invention,
I will explain in detail.
本発明に係わるフィルター材料を構成するのは、前記炭
素多孔体の粉砕物と、繊維状物である。 本発明に係わ
る煙草用フィルター材料の一成分たる炭素多孔体は、フ
ェノール樹脂発泡体を炭素化し、次いで賦活して得られ
る。The filter material according to the present invention is composed of the pulverized carbon porous material and the fibrous material. The carbon porous body, which is one component of the cigarette filter material according to the present invention, is obtained by carbonizing a phenolic resin foam and then activating it.
このフェノール樹脂発泡体は、フェノール樹脂を発泡硬
化させることにより得られ、このようなフェノール樹脂
としては、レゾール型フェノール樹脂が用いられる。This phenol resin foam is obtained by foaming and curing a phenol resin, and a resol type phenol resin is used as such a phenol resin.
レゾール型フェノール樹脂は、公知の方法に従って、フ
ェノール類とアルデヒド類とをアルカリ触媒の存在下で
反応させることにより得られる。A resol type phenolic resin is obtained by reacting phenols and aldehydes in the presence of an alkali catalyst according to a known method.
フェノール類としては、具体的には、フェノール、クレ
ゾール、キシレノールおよびレゾルシンなどが用いられ
る。Specifically, phenols include phenol, cresol, xylenol, resorcinol, and the like.
アルデヒド類としては、具体的には、ホルムアルデヒド
、アセトアルデヒドおよびフルフラールなどが用いられ
る。Specifically, formaldehyde, acetaldehyde, furfural, and the like are used as the aldehydes.
アルカリ触媒としては、具体的には、
ＫＯＨ，ＮａＯＨ，ＮＨ３、ＮＨ４ＯＨ，ｚタノールア
ミンおよびエチレンジアミンなどが用いられる。As the alkali catalyst, specifically, KOH, NaOH, NH3, NH4OH, z-tanolamine, ethylenediamine, etc. are used.
レゾール型フェノール樹脂を発泡させるための発泡剤と
しては、従来公知の種々の分解型発泡剤および蒸発型発
泡剤を用いることができる。 このうち、蒸発型発泡剤
が好ましく、具体的には、パラフィン系炭化水素類、ア
ルコール類、エーテル類、ハロゲン化炭化水素類等を例
示できるが、なかでも、ハロゲン化炭化水素類を最も好
ましく用いることができる。As the foaming agent for foaming the resol type phenolic resin, various conventionally known decomposition type foaming agents and evaporation type foaming agents can be used. Among these, evaporative blowing agents are preferred, and specific examples include paraffinic hydrocarbons, alcohols, ethers, halogenated hydrocarbons, etc. Among them, halogenated hydrocarbons are most preferably used. be able to.
ハロゲン化炭化水素類としては、具体的には、クロロホ
ルム、四塩化炭素、トリクロロモノフルオロメタン（フ
ロンガスＲ１１）、ジクロロモノフルオロメタン（同Ｒ
２１）、テトラクロロジフルオロエタン（同Ｒ１１２）
、トリクロロトリフルオロメタン（同Ｒ１１３）、ジク
ロロテトラフルオロエタン（同Ｒ１１４）、ジブロモト
リフルオロエタン（同Ｒ１１４Ｂ２）などがあげられ、
好適に用いられる。Specifically, halogenated hydrocarbons include chloroform, carbon tetrachloride, trichloromonofluoromethane (Freon gas R11), dichloromonofluoromethane (Freon gas R11), and dichloromonofluoromethane (Freon gas R11).
21), tetrachlorodifluoroethane (same R112)
, trichlorotrifluoromethane (R113), dichlorotetrafluoroethane (R114), dibromotrifluoroethane (R114B2), etc.
Suitably used.
これらのうち、特に、フロンガスＲ１１、同Ｒ１１３、
同Ｒ１１４Ｂ２のような常温ないしそれより若干高い温
度に沸点を有するものが好ましく用いられる。 発泡剤
は、レゾール型フェノール樹脂１００重量部に対し、１
〜２０重量部を用いることが好ましい。Among these, especially fluorocarbon gas R11, fluorocarbon gas R113,
Those having a boiling point at room temperature or slightly higher temperature, such as R114B2, are preferably used. The blowing agent is 1 part by weight per 100 parts by weight of the resol type phenolic resin.
It is preferable to use ~20 parts by weight.
レゾール型フェノール樹脂を発泡硬化させるために、発
泡剤とともに硬化剤が用いられるが、このような硬化剤
としては、従来公知の種々の硬化剤が、プレポリマーの
種類に応じて選択され、使用される。 具体的には、硫
酸、塩酸、リン酸、フェノールスルホン酸、ベンゼンス
ルホン酸、トルエンスルホン酸、メタクレゾールスルホ
ン酸、レゾルシノールスルホン酸、ブチルスルホン酸、
プロピルスルホン酸などがあげられる。In order to foam and cure resol type phenolic resin, a curing agent is used together with a foaming agent. As such curing agents, various conventionally known curing agents are selected and used depending on the type of prepolymer. Ru. Specifically, sulfuric acid, hydrochloric acid, phosphoric acid, phenolsulfonic acid, benzenesulfonic acid, toluenesulfonic acid, metacresolsulfonic acid, resorcinolsulfonic acid, butylsulfonic acid,
Examples include propylsulfonic acid.
このような硬化剤は、通常、レゾール型フェノール樹脂
１００重量部に対し、３〜３０重量部の割合で用いられ
る。Such a curing agent is usually used in an amount of 3 to 30 parts by weight per 100 parts by weight of the resol type phenolic resin.
また、本発明においては、必要に応じてさらに他の成分
、たとえば整泡剤や充填剤を併用してもかまわない。Further, in the present invention, other components such as foam stabilizers and fillers may be used in combination as necessary.
上記のようなレゾール型フェノール樹脂、発泡剤および
硬化剤からのフェノール樹脂発泡体の製造は、これらの
原料を一挙にもしくは逐次に混合攪拌して得られた、ク
リーム状のフェノール樹脂プレポリマー組成物を、たと
えば保温された金型内もしくは２重帯状コンベアー上に
供給し、フェノール樹脂プレポリマー組成物を発泡、硬
化させて行われる。 得られた樹脂発泡体は、必要に応
じて切断してもよい。The production of a phenolic resin foam from a resol-type phenolic resin, a blowing agent, and a curing agent as described above involves mixing and stirring these raw materials all at once or sequentially to produce a creamy phenolic resin prepolymer composition. The phenol resin prepolymer composition is foamed and cured by supplying the phenol resin prepolymer composition, for example, into a heated mold or onto a double belt conveyor. The obtained resin foam may be cut as necessary.
このようにして得られたフェノール樹脂発泡体の成形体
は、そのまま直接か、もしくは切断して板状体としたの
ち、非酸化性又は微酸化性雰囲気下で焼成され、炭素化
される。The molded phenolic resin foam thus obtained is carbonized by being fired in a non-oxidizing or slightly oxidizing atmosphere, either directly or after being cut into a plate-shaped body.
すなわち、減圧下またはＡｒガス、Ｈｅガス、Ｎ２ガス
、ハロゲンガス、アンモニアガス、水素ガス、−酸化炭
素等の中で、好ましくは５００℃〜１２００℃、特に好
ましくは６００〜９００℃の温度で焼成する。 このよ
うにして、発泡体は炭素化され、炭素多孔体が得られる
。That is, firing under reduced pressure or in Ar gas, He gas, N2 gas, halogen gas, ammonia gas, hydrogen gas, -carbon oxide, etc., preferably at a temperature of 500°C to 1200°C, particularly preferably 600 to 900°C. do. In this way, the foam is carbonized and a porous carbon body is obtained.
焼成時の昇温速度は、特に制限はないものの、一般に樹
脂の分解が開始される２００〜６００℃付近にかけては
、徐々に行うほうが好ましい。Although there is no particular restriction on the temperature increase rate during firing, it is preferable to increase the temperature gradually around 200 to 600°C, where decomposition of the resin generally starts.
このようにして得られた炭素多孔体は、さらに、酸化性
ガス雰囲気下で７００〜１０００℃の温度で加熱される
賦活処理により、活性化される。The carbon porous body thus obtained is further activated by an activation treatment in which it is heated at a temperature of 700 to 1000°C in an oxidizing gas atmosphere.
酸化性ガスとしては、活性炭の賦活処理に使用される従
来公知の各種酸素含有気体が用いられ、酸素または水蒸
気などの酸化性ガスと不活性ガスとの混合気体などが好
ましく用いられる。As the oxidizing gas, various conventionally known oxygen-containing gases used in the activation treatment of activated carbon are used, and a mixed gas of an oxidizing gas such as oxygen or water vapor and an inert gas is preferably used.
不活性ガスと酸化性ガスとの混合比は、処理温度に応じ
て決定されるが、作業性を考慮すると、不活性ガス１モ
ルに対し、酸化性ガスは０．０１〜０． ５千ｋ、好ま
しくは０．１モル〜０．３モルの割合で混合される。The mixing ratio of the inert gas and the oxidizing gas is determined depending on the processing temperature, but considering workability, the mixing ratio of the oxidizing gas to 1 mole of the inert gas is 0.01 to 0. 5,000 k, preferably 0.1 mol to 0.3 mol.
上記のような賦活処理に要する時間は、前述した酸化性
ガスの濃度に応じて変化するが、作業性を考慮すると、
通常１分間〜２４時間の範囲であることが好ましい。The time required for the above activation treatment varies depending on the concentration of the oxidizing gas mentioned above, but considering workability,
Usually, it is preferable that the time is in the range of 1 minute to 24 hours.
このようにして得られた活性化炭素多孔体は、嵩密度が
０．０５〜０．５ｇ／ｃｍ’の範囲にある。The activated carbon porous body thus obtained has a bulk density in the range of 0.05 to 0.5 g/cm'.
この範囲内の嵩密度を有する活性化炭素多孔体は、機械
的強度が高いと共に、比表面積が大きい。An activated carbon porous body having a bulk density within this range has high mechanical strength and a large specific surface area.
また、活性化炭素多孔体の比表面積は５００ｍ ２７８
以上であり、この範囲の比表面積を有する活性化炭素多
孔体は、アセトアルデヒド吸着能力が極めて優れている
。In addition, the specific surface area of the activated carbon porous material is 500 m278
The activated carbon porous material having a specific surface area within this range has extremely excellent acetaldehyde adsorption ability.
なお、本発明における比表面積は、ＢＥＴ法によるＮ２
の等温吸着曲線より求めた値である。Note that the specific surface area in the present invention is determined by the BET method.
This value was determined from the isothermal adsorption curve.
さらに、活性化炭素多孔体の炭素含有率は８５〜９５％
、好ましくは８８〜９２％の範囲であり、この範囲の多
孔体のみが、脱臭性能が極めて優れている。Furthermore, the carbon content of the activated carbon porous material is 85 to 95%.
, preferably in the range of 88 to 92%, and only porous bodies in this range have extremely excellent deodorizing performance.
本発明のフィルター材料に用いるのは、上記方法で得た
活性化炭素多孔体の粉砕物である。The filter material of the present invention is a pulverized activated carbon porous material obtained by the above method.
粉砕物の粒径は、適度な範囲にあることが必要であり、
好ましくは１０μｍ〜１ｍｍ、さらに好ましくは５０〜
３００μｍの範囲である。The particle size of the pulverized material must be within an appropriate range,
Preferably 10 μm to 1 mm, more preferably 50 to 1 mm
The range is 300 μm.
前記活性化炭素多孔体の粉砕方法としては、例えば、ボ
ールミル、ハンマーミル等の通常使用される粉砕機等を
用いる方法があげられ、この方法により、容易に上記粒
径とすることができる。Examples of the method for pulverizing the activated carbon porous material include a method using a commonly used pulverizer such as a ball mill or a hammer mill, and by this method, the above particle size can be easily obtained.
本発明の煙草用フィルター材料の主成分として用いられ
る繊維状物とは、公知のごとく、天然または合成樹脂の
繊維状物であり、従来よりフィルターに用いられている
ものであり、例えば、酢酸セルロース繊維、バルブ繊維
等を挙げることができる。The fibrous material used as the main component of the cigarette filter material of the present invention is, as is well known, a fibrous material of natural or synthetic resin that has been conventionally used in filters, such as cellulose acetate. Examples include fibers, bulb fibers, and the like.
本発明の煙草用フィルター材料は、前記炭素多孔体の粉
砕物と前記繊維状物であるが、その割合は、繊維状物１
００重量部に対し、炭素多孔体の粉砕物０．１〜１００
重量部、好ましくは５〜３０重量部の範囲である。The cigarette filter material of the present invention is composed of the pulverized carbon porous material and the fibrous material, and the ratio of the fibrous material to the fibrous material is 1 to 1.
0.1 to 100 parts by weight of pulverized carbon porous material
parts by weight, preferably in the range from 5 to 30 parts by weight.
炭素多孔体の粉砕物の割合が少なすぎると、炭素多孔体
の粉砕物の配合による効果が得られ難く、一方、配合量
が多すぎると、フィルターの圧力損失が大きくなり、且
つフィルタ一部の形状保持性が劣る。If the proportion of the pulverized carbon porous material is too small, it will be difficult to obtain the effect of the pulverized carbon porous material. On the other hand, if the proportion of the pulverized carbon porous material is too large, the pressure loss of the filter will increase, and some parts of the filter may be damaged. Poor shape retention.
前記炭素多孔体の粉砕物の前記繊維状物への混合、添着
は、従来の活性炭の混合、添着と同様の公知の方法によ
り、行うことができる。Mixing and impregnation of the pulverized carbon porous material to the fibrous material can be performed by a known method similar to the conventional mixing and impregnation of activated carbon.
また、フィルターとしての形状の成型も、従来の公知の
方法により、行うことができる。Moreover, molding into a shape as a filter can also be performed by a conventionally known method.
本発明の煙草用フィルター材料は、従来の活性炭配合フ
ィルターに於いて、活性炭として特定の炭素多孔体を用
いたものであり、従来のフィルターより、ニコチン、タ
ール分、煙草のいやなにおい等の成分の吸着量が多く、
もって、煙草によりマイルドな感じもたさせることが出
来るものである。The cigarette filter material of the present invention uses a specific porous carbon material as the activated carbon in conventional activated carbon-containing filters, and contains components such as nicotine, tar, and unpleasant odors of cigarettes, compared to conventional filters. has a large amount of adsorption,
As a result, it is possible to give a milder feeling to the cigarette.
本発明のこのような効果は、本発明で用いる特定の炭素
多孔体の吸着速度が、従来使用されている活性炭より大
きいことに起因する。 この理由は必ずしも明確ではな
いが、本発明で用いる特定の炭素多孔体は、嵩密度が従
来の活性炭より小さく、従って単位重量当りの外表面積
が大きいので、このことが、煙草用フィルターのごとく
、瞬時の吸着性能を要求される用途において、吸着速度
の差となって表われるものと考えられる。Such effects of the present invention are due to the fact that the specific porous carbon material used in the present invention has a higher adsorption rate than conventionally used activated carbon. The reason for this is not necessarily clear, but the specific porous carbon material used in the present invention has a smaller bulk density than conventional activated carbon and therefore has a larger external surface area per unit weight. In applications that require instantaneous adsorption performance, this is thought to be manifested as a difference in adsorption speed.
〈実施例〉
次に、実施例を挙げて本発明の効果を更に具体的に説明
するが、本発明は、その要旨を越えない限り、これらの
実施例になんら制約されるものではない。<Examples> Next, the effects of the present invention will be explained in more detail with reference to Examples, but the present invention is not limited to these Examples in any way unless the gist thereof is exceeded.
（実施例１）
［活性化炭素多孔体の製造］
レゾール１００重量部、硬化剤としてのパラトルエンス
ルホン酸１０重量部および発泡剤としてのフロンガス（
フレオン１１）２重量部を高速ミキサーで充分に攪拌・
混合した後、該混合物を木型内に流し込み、蓋をし、８
０℃のエアーオーブン内に３０分放置することにより、
嵩密度０．１５ｇ／ａｍ’のフェノール樹脂発泡体を得
た。(Example 1) [Production of activated carbon porous material] 100 parts by weight of resol, 10 parts by weight of para-toluenesulfonic acid as a hardening agent, and chlorofluorocarbon gas (as a blowing agent)
Thoroughly stir 2 parts by weight of Freon 11) with a high-speed mixer.
After mixing, pour the mixture into a wooden mold, cover it, and
By leaving it in an air oven at 0℃ for 30 minutes,
A phenolic resin foam having a bulk density of 0.15 g/am' was obtained.
この発泡体から、縦３ ＣＩｎ ｓ横３ｃｍ、厚さ１ｃ
ｍの板を切り出し、次いで、この板を、内径５０ ｍ
ｍの石英製カラムに入れ、該カラム内の雰囲気をＮ、に
置換後、外部からヒーターで昇温速度６０℃／分で温度
８００℃まで昇温した。 次いで、同温度で、Ｎ２ガス
と水蒸気との混合ガス（混合モル比が０．８：０．２）
を流速１０１／分で流し、３０分間賦活処理した後、冷
却し、炭素含有率９０％、嵩密度０．１４ｇ／ｃｍ’
比表面積１２００ｍ’／ｇの活性化炭素多孔体を得
た。 この炭素多孔体を粉砕機で粉砕後、２００メツシ
ユの篩でふるい、平均粒径６５μｍのものを用いた。From this foam, length 3 CIn s width 3 cm, thickness 1 c
Cut out a plate with an inner diameter of 50 m.
After the atmosphere in the column was replaced with N, the temperature was raised to 800°C at a heating rate of 60°C/min using an external heater. Next, at the same temperature, a mixed gas of N2 gas and water vapor (mixed molar ratio 0.8:0.2)
was flowed at a flow rate of 101/min, activated for 30 minutes, cooled, and the carbon content was 90% and the bulk density was 0.14 g/cm'.
An activated carbon porous body having a specific surface area of 1200 m'/g was obtained. This porous carbon material was ground with a grinder and then sieved with a 200 mesh sieve to obtain a material with an average particle size of 65 μm.
［吸着テスト］
内径１０ｍｍのカラムに、上記方法で得た炭素多孔体粉
砕物２０重量部と酢酸繊維素繊維１００重量部とからな
る混合物を、厚さ１ｃｍ（重量１００ｍｇ）充填後、煙
草の煙のいやなにおいの主成分とされるアセトアルデヒ
ド５００ｐｐｍを含む空気を流速３ｍ１／秒で流し、１
分経過後に、フィルター下流の空気のアセトアルデヒド
濃度を測定した。 結果を表１に示す。[Adsorption test] After filling a column with an inner diameter of 10 mm with a mixture consisting of 20 parts by weight of the pulverized carbon porous material obtained by the above method and 100 parts by weight of cellulose acetate fibers to a thickness of 1 cm (weight 100 mg), cigarette smoke was added. Air containing 500 ppm of acetaldehyde, which is the main component of unpleasant odors, was flowed at a flow rate of 3 m1/sec.
After a few minutes had elapsed, the acetaldehyde concentration in the air downstream of the filter was measured. The results are shown in Table 1.
（実施例２）
炭素多孔体粉砕物と酢酸繊維素繊維の配合比を１０重量
部／９０重量部とする以外は、実施例１と同様に行った
。 結果を表１に示す。(Example 2) The same procedure as in Example 1 was carried out except that the blending ratio of the pulverized carbon porous material and cellulose acetate fiber was 10 parts by weight/90 parts by weight. The results are shown in Table 1.
（比較例１）
やし殻活性炭粉砕物（２００メツシュパス品）２０重量
部と酢酸繊維素繊維１００重量部とからなる混合物を用
いる以外は、実施例１と同様に吸着テストを行った。
結果を表１に示す。(Comparative Example 1) An adsorption test was carried out in the same manner as in Example 1, except that a mixture consisting of 20 parts by weight of pulverized coconut shell activated carbon (200 mesh pass product) and 100 parts by weight of cellulose acetate fibers was used.
The results are shown in Table 1.
す、煙草によりマイルドな感じをもたせることができる
と共に、ニコチンやタール分等の有害成分の摂取量の低
減を図ることができる。This makes it possible to give the cigarette a milder feel and to reduce the intake of harmful components such as nicotine and tar.
表 １
〈発明の効果〉
本発明により、煙草のいやなにおいの成分であるアセト
アルデヒド等を、速い吸着速度でしかも量多く吸着でき
る煙草用フィルター材料が提供される。Table 1 <Effects of the Invention> The present invention provides a filter material for cigarettes that is capable of adsorbing acetaldehyde, etc., which are components of the unpleasant odor of cigarettes, at a high adsorption rate and in large amounts.
Claims (1)
嵩密度が０．０５〜０．５ｇ／ｃｍ＾３、炭素含有率が
８５〜９５％、比表面積が５００ｍ＾２／ｇ以上である
炭素多孔体の粉砕物と繊維状物とからなることを特徴と
する煙草用フィルター材料。(1) The phenolic resin foam is carbonized and activated,
It consists of a pulverized carbon porous material and a fibrous material having a bulk density of 0.05 to 0.5 g/cm^3, a carbon content of 85 to 95%, and a specific surface area of 500 m^2/g or more. Characteristic cigarette filter material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9615889A JPH02273169A (en) | 1989-04-14 | 1989-04-14 | Filter material for tobacco |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9615889A JPH02273169A (en) | 1989-04-14 | 1989-04-14 | Filter material for tobacco |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02273169A true JPH02273169A (en) | 1990-11-07 |
Family
ID=14157551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9615889A Pending JPH02273169A (en) | 1989-04-14 | 1989-04-14 | Filter material for tobacco |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02273169A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004508470A (en) * | 2000-09-18 | 2004-03-18 | ロスマンズ、ベンソン アンド ヘッジズ インコーポレイテッド | Low sidestream cigarette with flammable paper |
| JP2010051319A (en) * | 2002-01-09 | 2010-03-11 | Philip Morris Products Sa | Cigarette filter with beaded carbon |
| JP2011155902A (en) * | 2010-02-01 | 2011-08-18 | Daicel Chemical Industries Ltd | Cigarette filter containing magnesium metasilicate aluminate |
| WO2019106798A1 (en) * | 2017-11-30 | 2019-06-06 | 日本たばこ産業株式会社 | Flavor inhalation article |
| TWI732974B (en) * | 2017-11-30 | 2021-07-11 | 日商日本煙草產業股份有限公司 | Fragrance inhaling article |
-
1989
- 1989-04-14 JP JP9615889A patent/JPH02273169A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004508470A (en) * | 2000-09-18 | 2004-03-18 | ロスマンズ、ベンソン アンド ヘッジズ インコーポレイテッド | Low sidestream cigarette with flammable paper |
| JP4890729B2 (en) * | 2000-09-18 | 2012-03-07 | ロスマンズ、ベンソン アンド ヘッジズ インコーポレイテッド | Low sidestream smoke cigarette with combustible wrapping paper |
| JP2010051319A (en) * | 2002-01-09 | 2010-03-11 | Philip Morris Products Sa | Cigarette filter with beaded carbon |
| JP2013233153A (en) * | 2002-01-09 | 2013-11-21 | Philip Morris Products Sa | Cigarette filter with beaded carbon |
| JP2011155902A (en) * | 2010-02-01 | 2011-08-18 | Daicel Chemical Industries Ltd | Cigarette filter containing magnesium metasilicate aluminate |
| US8978662B2 (en) | 2010-02-01 | 2015-03-17 | Daicel Chemical Industries, Ltd. | Tobacco filter containing magnesium aluminometasilicate |
| WO2019106798A1 (en) * | 2017-11-30 | 2019-06-06 | 日本たばこ産業株式会社 | Flavor inhalation article |
| JPWO2019106798A1 (en) * | 2017-11-30 | 2020-09-03 | 日本たばこ産業株式会社 | Flavor suction goods |
| TWI732974B (en) * | 2017-11-30 | 2021-07-11 | 日商日本煙草產業股份有限公司 | Fragrance inhaling article |
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