JPH02222701A - Chlorofluorohydrocarbon-based solvent for removing sticking water - Google Patents
Chlorofluorohydrocarbon-based solvent for removing sticking waterInfo
- Publication number
- JPH02222701A JPH02222701A JP4158289A JP4158289A JPH02222701A JP H02222701 A JPH02222701 A JP H02222701A JP 4158289 A JP4158289 A JP 4158289A JP 4158289 A JP4158289 A JP 4158289A JP H02222701 A JPH02222701 A JP H02222701A
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- chloro
- water
- alcohol
- dichloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000002904 solvent Substances 0.000 title claims abstract description 20
- 150000005827 chlorofluoro hydrocarbons Chemical class 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 10
- 150000001298 alcohols Chemical class 0.000 claims abstract description 5
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 150000002576 ketones Chemical class 0.000 claims abstract description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- QODDDPGGYAJEDT-UHFFFAOYSA-N 1,1-dichloro-2,2,3,3-tetrafluorocyclobutane Chemical compound FC1(F)CC(Cl)(Cl)C1(F)F QODDDPGGYAJEDT-UHFFFAOYSA-N 0.000 claims description 2
- BSERHUYXVAIRSG-UHFFFAOYSA-N 1-chloro-1,1,3,3-tetrafluorobutane Chemical compound CC(F)(F)CC(F)(F)Cl BSERHUYXVAIRSG-UHFFFAOYSA-N 0.000 claims description 2
- XOSZOEXJQZFWKW-UHFFFAOYSA-N 1-chloro-1,1-difluorobutane Chemical compound CCCC(F)(F)Cl XOSZOEXJQZFWKW-UHFFFAOYSA-N 0.000 claims description 2
- DRNMSWBRUAIIJO-UHFFFAOYSA-N 2,3-dichloro-1,1,1,4,4,4-hexafluorobutane Chemical compound FC(F)(F)C(Cl)C(Cl)C(F)(F)F DRNMSWBRUAIIJO-UHFFFAOYSA-N 0.000 claims description 2
- PREWBNUKNNTMHC-UHFFFAOYSA-N 2-chloro-1,1,1,4,4,4-hexafluorobutane Chemical compound FC(F)(F)CC(Cl)C(F)(F)F PREWBNUKNNTMHC-UHFFFAOYSA-N 0.000 claims description 2
- PVAWBKMTZYLVNR-UHFFFAOYSA-N 3-chloro-1,1,1-trifluorobutane Chemical compound CC(Cl)CC(F)(F)F PVAWBKMTZYLVNR-UHFFFAOYSA-N 0.000 claims description 2
- SZBKCQKJQAYJJN-UHFFFAOYSA-N 4-chloro-1,1,1,2,2,3,3-heptafluorobutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)CCl SZBKCQKJQAYJJN-UHFFFAOYSA-N 0.000 claims description 2
- IDWBKVPBXORSNS-UHFFFAOYSA-N 4-chloro-1,1,2,2,3,3-hexafluorocyclobutane Chemical compound FC1(F)C(Cl)C(F)(F)C1(F)F IDWBKVPBXORSNS-UHFFFAOYSA-N 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- MGFUNRHKNTXQRX-UHFFFAOYSA-N 3,4-dichloro-1,1,1,2,2,3-hexafluorobutane Chemical compound FC(F)(F)C(F)(F)C(F)(Cl)CCl MGFUNRHKNTXQRX-UHFFFAOYSA-N 0.000 claims 1
- JZTOHBFNNYFPIP-UHFFFAOYSA-N 3-chloro-1,1,2,2-tetrafluorocyclobutane Chemical compound FC1(F)CC(Cl)C1(F)F JZTOHBFNNYFPIP-UHFFFAOYSA-N 0.000 claims 1
- FRAAFLQSUCATRS-UHFFFAOYSA-N 4,4-dichloro-1,1,1,2,2,3,3-heptafluorobutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(Cl)Cl FRAAFLQSUCATRS-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 229920001971 elastomer Polymers 0.000 abstract description 5
- 239000000806 elastomer Substances 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract description 5
- 229920003023 plastic Polymers 0.000 abstract description 5
- 239000004033 plastic Substances 0.000 abstract description 5
- -1 2.5-dimethylhexane Chemical compound 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- FLTJDUOFAQWHDF-UHFFFAOYSA-N 2,2-dimethylhexane Chemical compound CCCCC(C)(C)C FLTJDUOFAQWHDF-UHFFFAOYSA-N 0.000 description 3
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 3
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- BZHMBWZPUJHVEE-UHFFFAOYSA-N 2,4-dimethylpentane Chemical compound CC(C)CC(C)C BZHMBWZPUJHVEE-UHFFFAOYSA-N 0.000 description 2
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 2
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 2
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- KUMXLFIBWFCMOJ-UHFFFAOYSA-N 3,3-dimethylhexane Chemical compound CCCC(C)(C)CC KUMXLFIBWFCMOJ-UHFFFAOYSA-N 0.000 description 2
- DUPUVYJQZSLSJB-UHFFFAOYSA-N 3-ethyl-2-methylpentane Chemical compound CCC(CC)C(C)C DUPUVYJQZSLSJB-UHFFFAOYSA-N 0.000 description 2
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical compound CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 description 2
- HTSABYAWKQAHBT-UHFFFAOYSA-N 3-methylcyclohexanol Chemical compound CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 2
- VLJXXKKOSFGPHI-UHFFFAOYSA-N 3-methylhexane Chemical compound CCCC(C)CC VLJXXKKOSFGPHI-UHFFFAOYSA-N 0.000 description 2
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical group CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- WGECXQBGLLYSFP-UHFFFAOYSA-N (+-)-2,3-dimethyl-pentane Natural products CCC(C)C(C)C WGECXQBGLLYSFP-UHFFFAOYSA-N 0.000 description 1
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 1
- FDHDUXOBMHHFFJ-UHFFFAOYSA-N 1-pentylnaphthalene Chemical compound C1=CC=C2C(CCCCC)=CC=CC2=C1 FDHDUXOBMHHFFJ-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
- BODRLKRKPXBDBN-UHFFFAOYSA-N 3,5,5-Trimethyl-1-hexanol Chemical compound OCCC(C)CC(C)(C)C BODRLKRKPXBDBN-UHFFFAOYSA-N 0.000 description 1
- GIEZWIDCIFCQPS-UHFFFAOYSA-N 3-ethyl-3-methylpentane Chemical compound CCC(C)(CC)CC GIEZWIDCIFCQPS-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical compound CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Extraction Or Liquid Replacement (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分卦コ
本発明は、レンズ、液晶表示装置部品、電子部品、精密
機械部品等の付着水除去用溶剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Applications] The present invention relates to a solvent for removing water adhered to lenses, liquid crystal display device parts, electronic parts, precision mechanical parts, etc.
[従来の技術]
レンズ、液晶表示装置部品、電子部品、精密機械部品等
の水洗処理後、水が付着したままでは製品とならない場
合が多い、従って、通常このような部品の仕上げ工程で
は、有機溶剤を用いて水の除去を行なっている。その有
機溶剤として次に掲げるような種々の利点から、 1,
1.2−トリクロロ−1、2,2−トリフルオロエタン
(以下R113という)が広く使われている。[Prior Art] After washing lenses, liquid crystal display parts, electronic parts, precision mechanical parts, etc., products often cannot be manufactured with water still attached to them. Therefore, in the finishing process of such parts, organic Water is removed using a solvent. Because of the various advantages listed below as an organic solvent, 1.
1,2-Trichloro-1,2,2-trifluoroethane (hereinafter referred to as R113) is widely used.
R113は、不燃性で毒性が低く安定性も優れている。R113 is nonflammable, has low toxicity, and has excellent stability.
しかも、金属、プラスチック、エラストマー等の基材を
侵さず付着水を除去することができる。Moreover, adhering water can be removed without damaging base materials such as metals, plastics, and elastomers.
一般に、付着水除去を行なう被処理物は金属、プラスチ
ック、エラストマー等からなる複合部品が多く、従って
この点かへもR113が有利であった。In general, many of the objects to be treated from which attached water is removed are composite parts made of metals, plastics, elastomers, etc., and therefore R113 was advantageous in this respect as well.
[発明が解決しようとする課題]
従来使用されていたR113が種々の利点を有するにも
かかわらず、対流圏内での寿命が長く、拡散して成層圏
に達し、ここで太陽光線により分解して塩素ラジカルを
発生し、このラジカルがオゾンと連鎖反応を起こし、オ
ゾン層を破壊するとのことから、R113の使用を規制
することとなった。[Problems to be solved by the invention] Despite the fact that conventionally used R113 has various advantages, it has a long lifetime in the troposphere and diffuses into the stratosphere, where it is decomposed by sunlight and becomes chlorine. The use of R113 has been regulated because it generates radicals that cause a chain reaction with ozone and destroy the ozone layer.
このため、本発明は、これらの問題を解決すべく、R1
13と同様の水の除去が行える新規の付着水除去用溶剤
を提供することを目的とするものである。Therefore, in order to solve these problems, the present invention provides R1
It is an object of the present invention to provide a new solvent for removing adhered water that can remove water similar to No. 13.
[課題を解決するための手段]
本発明は前述の目的を達成すべくなされたものであり、
炭素数が4である塩素化弗素化炭化水素を有効成分とし
て含有する付着水除去用溶剤を提供するものである。[Means for Solving the Problems] The present invention has been made to achieve the above-mentioned objects, and
The present invention provides a solvent for removing adhered water containing a chlorinated fluorinated hydrocarbon having 4 carbon atoms as an active ingredient.
本発明の塩素化弗素化炭化水素としては、1−クロロ−
1,1−ジフルオロブタン(b、 P、 55.5℃)
、3−クロロ−1,1,1−トリフルオロブタン(b、
p、 66℃)、1−クロロ−1,1,3,3−テト
ラフルオロブタン (b、p。The chlorinated fluorinated hydrocarbon of the present invention includes 1-chloro-
1,1-difluorobutane (b, P, 55.5℃)
, 3-chloro-1,1,1-trifluorobutane (b,
p, 66°C), 1-chloro-1,1,3,3-tetrafluorobutane (b, p.
70°C)、2−クロロ−1,1,1,4,4,4−ヘ
キサフルオロブタン(b、p、51℃)、4−クロロ−
1,1,1,2,2,3,3−ヘプタフルオロブタン(
b、 p、 54℃〉、 3.4−ジクロロ−1、1,
1,2,2,3−ヘキサフルオロブタン(b、 p、
72℃)、2.3−ジクロロ−1,1,1,4,4,4
−ヘキサフルオロブタン(b、 9.78℃)、4,4
−ジクロロ−1,1,l、 2.2.3.3−ヘプタフ
ルオロブタン(b、 p、 76、5℃)、 1−クロ
ロ−2゜2.3.3−テトラフルオロシクロブタン(b
、p、73℃)、1.1−ジクロロ−2,2,3,3−
テトラフルオロシクロブタン(b、 p、 84℃)、
1−クロロ−2,2,3,3,4,4−ヘキサフルオロ
シクロブタン(b、 p、 40°C)等の含水素塩素
化弗素化炭化水素から選ばれる1種叉は2種以上の混合
物が好ましい。70°C), 2-chloro-1,1,1,4,4,4-hexafluorobutane (b, p, 51°C), 4-chloro-
1,1,1,2,2,3,3-heptafluorobutane (
b, p, 54°C〉, 3.4-dichloro-1,1,
1,2,2,3-hexafluorobutane (b, p,
72°C), 2,3-dichloro-1,1,1,4,4,4
-hexafluorobutane (b, 9.78°C), 4,4
-dichloro-1,1,l, 2.2.3.3-heptafluorobutane (b, p, 76, 5°C), 1-chloro-2°2.3.3-tetrafluorocyclobutane (b
, p, 73°C), 1,1-dichloro-2,2,3,3-
Tetrafluorocyclobutane (b, p, 84°C),
One type or a mixture of two or more types selected from hydrogen-containing chlorinated fluorinated hydrocarbons such as 1-chloro-2,2,3,3,4,4-hexafluorocyclobutane (b, p, 40°C) is preferred.
本発明の付着水除去用溶剤には、各種の目的に応じてそ
の他の各種成分を含有させることができる0例えば、付
着水除去効果を高めるために、炭化水素類、アルコール
類、ケトン類、叉は、ハロゲン化炭化水素類等の有機溶
剤あるいは界面活性剤類から選ばれる少なくとも1種を
含有させることができる。これらの有機溶剤の付着水除
去用溶剤中の含有割合は、0〜50重量%、好ましくは
10〜40重景%、さらに好ましくは20〜30重量%
である9本発明の塩素化弗素化炭化水素類と有機溶剤と
の混合物に共沸組成が存在する場合には、その共沸組成
での使用が特に好ましい。The solvent for removing adhered water of the present invention may contain various other components depending on various purposes. For example, in order to enhance the effect of removing adhered water, hydrocarbons, alcohols, ketones, or can contain at least one selected from organic solvents such as halogenated hydrocarbons and surfactants. The content of these organic solvents in the solvent for removing adhered water is 0 to 50% by weight, preferably 10 to 40% by weight, and more preferably 20 to 30% by weight.
9 When the mixture of the chlorinated fluorinated hydrocarbon and the organic solvent of the present invention has an azeotropic composition, it is particularly preferable to use the azeotropic composition.
界面活性剤類の付着水除去用溶剤中の含有割合は、0〜
10重景%、好ましくは0.1〜5重景%、さらに好ま
しくは0.2〜2重量%である。The content ratio of surfactants in the solvent for removing adhered water is 0 to 0.
The amount is 10% by weight, preferably 0.1 to 5% by weight, and more preferably 0.2 to 2% by weight.
炭化水素類としては、炭素数1〜15の直鎖叉は環状の
飽和叉は不飽和炭化水素類が好ましく、n−ペンタン、
イソペンタン、n−ヘキサン、イソヘキサン、ネオヘキ
サン、2.3−ジメチルブタン、3−メチルベンタン、
n−へブタン、イソへブタン、3−メチルヘキサン、2
,4−ジメチルペンタン、n−オクタン、2−メチルへ
ブタン、3−メチルへブタン、4−メチルへブタン、2
,2−ジメチルヘキサン、2.5−ジメチルヘキサン、
3,3−ジメチルヘキサン、2−メチル−3−エチルペ
ンタン、3−メチル−3−エチルペンタン、2.3.3
− トリメチルペンタン、2.3.4−トリメチルペン
タン、2.2.3− トリメチルペンタン、イソオクタ
ン、ノナン、2.2.5−トリメチルヘキサン、デカン
、ドデカン、■−ペンテン、2−ペンテン、1−ヘキセ
ン、1−オクテン、1−ノネン、1−デセン、シクロペ
ンクン、メチルシクロペンタン、シクロヘキサン、メチ
ルシクロヘキサン、エチルシクロヘキサン、ビシクロヘ
キサン、シクロヘキセン、α−ピネン、ジペンテン、デ
カリン、テトラリン、アミレン、アミルナフタレン等か
ら選ばれるものである。より好ましくはn−ペンタン、
ネオヘキサン、2.3〜ジメチルブタン、n−ヘキサン
、シクロペンタン、シクロヘキサン、n−へブタン等で
ある。The hydrocarbons are preferably linear or cyclic saturated or unsaturated hydrocarbons having 1 to 15 carbon atoms, such as n-pentane,
Isopentane, n-hexane, isohexane, neohexane, 2,3-dimethylbutane, 3-methylbentane,
n-hebutane, isohebutane, 3-methylhexane, 2
, 4-dimethylpentane, n-octane, 2-methylhebutane, 3-methylhebutane, 4-methylhebutane, 2
, 2-dimethylhexane, 2.5-dimethylhexane,
3,3-dimethylhexane, 2-methyl-3-ethylpentane, 3-methyl-3-ethylpentane, 2.3.3
- Trimethylpentane, 2.3.4-trimethylpentane, 2.2.3-trimethylpentane, isooctane, nonane, 2.2.5-trimethylhexane, decane, dodecane, ■-pentene, 2-pentene, 1-hexene , 1-octene, 1-nonene, 1-decene, cyclopenkune, methylcyclopentane, cyclohexane, methylcyclohexane, ethylcyclohexane, bicyclohexane, cyclohexene, α-pinene, dipentene, decalin, tetralin, amylene, amylnaphthalene, etc. It is something. More preferably n-pentane,
Neohexane, 2.3-dimethylbutane, n-hexane, cyclopentane, cyclohexane, n-hebutane, etc.
アルコール類としては、炭素数1〜17の鎖状叉は、環
状の飽和叉は不飽和アルコール類が好ましく、 メタノ
ール、エタノール、n−プロピルアルコール、イソプロ
ピルアルコール、n−ブチルアルコール、イソブチルア
ルコール、38C−ブチルアルコール、tert−ブチ
ルアルコール、ペンチルアルコ−ル、5ec−アミルア
ルコール、1−エチル−1−プロパツール、2−メチル
−1−ブタノール、イソペンチルアルコール、tert
−ペンチルアルコール、3−メチル−2−ブタノール、
ネオペンチルアルコール、1−ヘキサノール、2−メチ
ル−1−ペンタノール、4−メチル−2−ペンタノール
、2−エチル−1−ブタノール、1−ヘプタツール、2
−ヘプタツール、3−ヘプタツール、1−オクタツール
、2−オクタツール、2−エチル−1−ヘキサノール、
1−ノナノール、3.5.5− トリメチル−1−ヘキ
サノール、l−デカノール、l−ウンデカノール、l−
ドデカノール、アリルアルコール、プロパルギルアルコ
ール、ベンジルアルコール、シクロヘキサノール、l−
メチルシクロヘキサノール、2−メチルシクロヘキサノ
ール、3−メチルシクロヘキサノール、4−メチルシク
ロヘキサノール、α−テルピネオール、アとニチノール
、2,6−シメチルー4−ヘプタツール、トリメチルノ
ニルアルコール、テトラデシルアルコール、ヘプタデシ
ルアルコール等から選ばれるものである。より好ましく
は、メタノール、エタノール、イソプロピルアルコール
等であ1〜9の飽和叉は不飽和炭化水素基)のいずれか
の一般式で示されるものが好ましく、アセトン、メチル
エチルケトン、2−ペンタノン、3−ペンタノン、2−
ヘキサノン、メチルブチルケトン、メチルイソブチルケ
トン、2−ヘプタノン、4−ヘプタノン、ジイソブチル
ケトン、アセトニルアセトン、メシチルオキシド、ホロ
ン、メチル−〇−アミルクトン、エチルブチルケトン、
メチルへキシルケトン、シクロヘキサノン、メチルシク
ロヘキサノン、イソホロン、2.4−ペンタンジオン、
ジアセトンアルコール、アセトフェノン、フェンチョン
等から選ばれるものである。より好ましくは、アセトン
、メチルエチルケトン等である。The alcohols are preferably chain or cyclic saturated or unsaturated alcohols having 1 to 17 carbon atoms, such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, 38C- Butyl alcohol, tert-butyl alcohol, pentyl alcohol, 5ec-amyl alcohol, 1-ethyl-1-propanol, 2-methyl-1-butanol, isopentyl alcohol, tert
-pentyl alcohol, 3-methyl-2-butanol,
Neopentyl alcohol, 1-hexanol, 2-methyl-1-pentanol, 4-methyl-2-pentanol, 2-ethyl-1-butanol, 1-heptatool, 2
- heptatool, 3-heptatool, 1-octatool, 2-octatool, 2-ethyl-1-hexanol,
1-nonanol, 3.5.5-trimethyl-1-hexanol, l-decanol, l-undecanol, l-
Dodecanol, allyl alcohol, propargyl alcohol, benzyl alcohol, cyclohexanol, l-
Methylcyclohexanol, 2-methylcyclohexanol, 3-methylcyclohexanol, 4-methylcyclohexanol, α-terpineol, atonitinol, 2,6-dimethyl-4-heptatool, trimethylnonyl alcohol, tetradecyl alcohol, heptadecyl It is selected from alcohol, etc. More preferably, methanol, ethanol, isopropyl alcohol, etc., represented by any one of the general formulas (1 to 9 saturated or unsaturated hydrocarbon groups), acetone, methyl ethyl ketone, 2-pentanone, 3-pentanone , 2-
Hexanone, methylbutylketone, methylisobutylketone, 2-heptanone, 4-heptanone, diisobutylketone, acetonylacetone, mesityl oxide, holon, methyl-〇-amilctone, ethylbutylketone,
Methylhexylketone, cyclohexanone, methylcyclohexanone, isophorone, 2,4-pentanedione,
It is selected from diacetone alcohol, acetophenone, fenchen, etc. More preferred are acetone, methyl ethyl ketone and the like.
ハロゲン化炭化水素類としては、炭素数1〜4の飽和叉
は不飽和のハロゲン化炭化水素類が好ましく、ジクロロ
メタン、四塩化炭素、クロロホルム、1.1−ジクロロ
エタン、1.2−ジクロロエタン、1、1.1− )ジ
クロロエタン、1.1.2−トリクロロエタン、1.1
.1.2−テトラクロロエタン、1.1.2.2−テト
ラクロロエタン、ペンタクロロエタン、1.1−ジクロ
ロエチレン、trans−1,2−ジクロロエチレン、
cis−1,2−ジクロロエチレン、トリクロロエチレ
ン、テトラクロロエチレン、1−クロロプロパン、2−
クロロプロパン、1−ブロモプロパン、2−ブロモプロ
パン等から選ばれるものである。より好ましくは、ジク
ロロメタン、1.1.1− )ジクロロエタン、tra
ns−1,2−ジクロロエチレン、cis−1,2−ジ
クロロエチレン、トリクロロエチレン、テトラクロロエ
チレン、2−ブロモプロパン等である。The halogenated hydrocarbons are preferably saturated or unsaturated halogenated hydrocarbons having 1 to 4 carbon atoms, such as dichloromethane, carbon tetrachloride, chloroform, 1.1-dichloroethane, 1.2-dichloroethane, 1, 1.1-) dichloroethane, 1.1.2-trichloroethane, 1.1
.. 1.2-tetrachloroethane, 1.1.2.2-tetrachloroethane, pentachloroethane, 1.1-dichloroethylene, trans-1,2-dichloroethylene,
cis-1,2-dichloroethylene, trichlorethylene, tetrachlorethylene, 1-chloropropane, 2-
It is selected from chloropropane, 1-bromopropane, 2-bromopropane, etc. More preferably dichloromethane, 1.1.1-) dichloroethane, tra
These include ns-1,2-dichloroethylene, cis-1,2-dichloroethylene, trichlorethylene, tetrachlorethylene, 2-bromopropane, and the like.
界面活性剤類としては、付着水除去用として通常用いら
れる各種のものから選択可能であるが、好ましくは、ポ
リオキシエチレンアルキルエーテル、ポリオキシエチレ
ンポリオキシプロピレンアルキルエーテル、ポリオキシ
エチレンアルキルエステル、ポリオキシエチレンポリオ
キシプロビレンアルキルエステル、ポリオキシエチレン
アルキルフェノール、ポリオキシエチレンポリオキシプ
ロビレンアルキルフェノール、ポリオキシエチレンソル
ビタンエステル、ポリオキシエチレンポリオキシプロピ
レンソルビタンエステル、カプリル酸カプリルアミン、
ポリオキシエチレンアルキルアミド等から選ばれるもの
である。より好ましくは、カプリル酸カプリルアミン、
ポリオキシエチレンアルキルアミド等である。The surfactant can be selected from various types commonly used for removing adhered water, but preferably polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl ester, polyoxyethylene alkyl ether, Oxyethylene polyoxypropylene alkyl ester, polyoxyethylene alkylphenol, polyoxyethylene polyoxypropylene alkylphenol, polyoxyethylene sorbitan ester, polyoxyethylene polyoxypropylene sorbitan ester, caprylic acid caprylamine,
It is selected from polyoxyethylene alkylamides and the like. More preferably caprylic acid caprylamine,
Polyoxyethylene alkylamides and the like.
本発明の付着水除去用溶剤による付着水除去方法として
は、スプレーやシャワーによる方法あるいは、冷浴、温
浴、蒸気浴叉は超音波浴による浸漬法あるいはこれらの
浴を組み合わせる浸漬法等を採用することができる。As a method for removing adhered water using the solvent for removing adhered water of the present invention, a method using a spray or a shower, an immersion method using a cold bath, a hot bath, a steam bath or an ultrasonic bath, or an immersion method combining these baths, etc. are adopted. be able to.
[実施例]
実施例1〜21
下記第1表に示す付着水除去用溶剤を用いて付着水の除
去試験を行なった。[Examples] Examples 1 to 21 A test for removing adhered water was conducted using the solvents for removing adhered water shown in Table 1 below.
30rnmX 181nmX 5mrn厚のガラス板を
純水に浸漬後、付着水除去用溶剤中に20秒浸漬して水
切りを行ない、取り出したガラス板を無水メタノール中
に浸漬してその水分増加量から付着水の除去状況を調べ
た。その結果を第1表に示す。After immersing a glass plate with a thickness of 30 nm x 181 nm x 5 mrn in pure water, immersing it in a solvent for removing adhered water for 20 seconds to drain the water, and removing the glass plate, immerse it in anhydrous methanol and remove the adhered water from the increased amount of water. We investigated the removal status. The results are shown in Table 1.
第1表
第1表(続き)
[発明の効果コ
本発明の付着水除去用溶剤は、実施例から明らかなよう
に付着水の除去効果の優れたものである。Table 1 Table 1 (Continued) [Effects of the Invention] The solvent for removing adhered water of the present invention has an excellent effect of removing adhered water, as is clear from the Examples.
又、従来使用されていたR113と同様、金属、プラス
チック、エラストマー等を侵す作用が少ないことから、
これらからなる複合部品に悪影響を与えることなく、付
着水を除去することができる。Also, like the conventionally used R113, it has little effect on attacking metals, plastics, elastomers, etc.
Adhering water can be removed without adversely affecting composite parts made of these components.
Claims (1)
として含有する付着水除去用溶剤。 2、塩素化弗素化炭化水素が1−クロロ−1,1−ジフ
ルオロブタン、3−クロロ−1,1,1−トリフルオロ
ブタン、1−クロロ−1,1,3,3−テトラフルオロ
ブタン、2−クロロ−1,1,1,4,4,4−ヘキサ
フルオロブタン、4−クロロ−1,1,1,2,2,3
,3−ヘプタフルオロブタン、3,4−ジクロロ−1,
1,1,2,2,3−ヘキサフルオロブタン、2,3−
ジクロロ−1,1,1,4,4,4−ヘキサフルオロブ
タン、4,4−ジクロロ−1,1,1,2,2,3,3
−ヘプタフルオロブタン、1−クロロ−2,2,3,3
−テトラフルオロシクロブタン、1,1−ジクロロ−2
,2,3,3−テトラフルオロシクロブタン、1−クロ
ロ−2,2,3,3,4,4−ヘキサフルオロシクロブ
タンである請求項1に記載の付着水除去用溶剤。 3、付着水除去用溶剤中に、炭化水素類、アルコール類
、ケトン類、ハロゲン化炭化水素類、叉は界面活性剤類
から選ばれる少なくとも1種が含まれている請求項1に
記載の付着水除去用溶剤。[Claims] 1. A solvent for removing adhered water containing a chlorinated fluorinated hydrocarbon having 4 carbon atoms as an active ingredient. 2. The chlorinated fluorinated hydrocarbon is 1-chloro-1,1-difluorobutane, 3-chloro-1,1,1-trifluorobutane, 1-chloro-1,1,3,3-tetrafluorobutane, 2-chloro-1,1,1,4,4,4-hexafluorobutane, 4-chloro-1,1,1,2,2,3
, 3-heptafluorobutane, 3,4-dichloro-1,
1,1,2,2,3-hexafluorobutane, 2,3-
Dichloro-1,1,1,4,4,4-hexafluorobutane, 4,4-dichloro-1,1,1,2,2,3,3
-heptafluorobutane, 1-chloro-2,2,3,3
-tetrafluorocyclobutane, 1,1-dichloro-2
, 2,3,3-tetrafluorocyclobutane, and 1-chloro-2,2,3,3,4,4-hexafluorocyclobutane. 3. The adhesion according to claim 1, wherein the solvent for removing adhesion water contains at least one selected from hydrocarbons, alcohols, ketones, halogenated hydrocarbons, or surfactants. Solvent for water removal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4158289A JPH02222701A (en) | 1989-02-23 | 1989-02-23 | Chlorofluorohydrocarbon-based solvent for removing sticking water |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4158289A JPH02222701A (en) | 1989-02-23 | 1989-02-23 | Chlorofluorohydrocarbon-based solvent for removing sticking water |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02222701A true JPH02222701A (en) | 1990-09-05 |
Family
ID=12612432
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4158289A Pending JPH02222701A (en) | 1989-02-23 | 1989-02-23 | Chlorofluorohydrocarbon-based solvent for removing sticking water |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02222701A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007016359A2 (en) * | 2005-07-28 | 2007-02-08 | Great Lakes Chemical Corporation | Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers |
-
1989
- 1989-02-23 JP JP4158289A patent/JPH02222701A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007016359A2 (en) * | 2005-07-28 | 2007-02-08 | Great Lakes Chemical Corporation | Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers |
WO2007016359A3 (en) * | 2005-07-28 | 2008-11-27 | Great Lakes Chemical Corp | Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers |
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