JPH02207893A - Sewage treatment - Google Patents

Sewage treatment

Info

Publication number
JPH02207893A
JPH02207893A JP1028592A JP2859289A JPH02207893A JP H02207893 A JPH02207893 A JP H02207893A JP 1028592 A JP1028592 A JP 1028592A JP 2859289 A JP2859289 A JP 2859289A JP H02207893 A JPH02207893 A JP H02207893A
Authority
JP
Japan
Prior art keywords
carrier
wettability
fluid state
improve
microorganisms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1028592A
Other languages
Japanese (ja)
Other versions
JPH0455757B2 (en
Inventor
Hiroshi Goga
伍賀 洋
Yuichi Fuchu
裕一 府中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Ebara Research Co Ltd
Original Assignee
Ebara Research Co Ltd
Ebara Infilco Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Research Co Ltd, Ebara Infilco Co Ltd filed Critical Ebara Research Co Ltd
Priority to JP1028592A priority Critical patent/JPH02207893A/en
Publication of JPH02207893A publication Critical patent/JPH02207893A/en
Publication of JPH0455757B2 publication Critical patent/JPH0455757B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Biological Treatment Of Waste Water (AREA)
  • Treatment Of Biological Wastes In General (AREA)

Abstract

PURPOSE:To improve the wettability of a carrier surface to improve the fluid state of a carrier stuck with microorganisms as well as to rapidly maintain a stationary state to improve a treating capacity without degrading the treating capacity by adding wettability agents essentially consisting of higher alcohol, fatty acid ester, etc., at the time of putting the above-mentioned carrier into a fluid state and treating sewage. CONSTITUTION:The carrier stuck with the microorganisms is put into the fluid state and/or >=2 kinds of the wettability improving agents essentially consisting of the higher alcohol, fatty acid ester or silicone oil are added thereto to improve the wettability of the carrier surface and to prevent the floating of the carrier, by which the ideal fluid state of the carrier is maintained and the sewage is effectively treated without secondary pollution. The rate of the above- mentioned wettability improving agents to be added is about 0.5 to 5g/l, more preferably about 1 to 4g/l in the case of adding one kind and is in an about 0.2 to 3g/l, more preferably about 0.4 to 2g/l range in total in the case of adding >=2 kinds.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、下水、し尿、産業廃水などの有機性汚水を生
物学的に好気的あるいは嫌気的に処理する方法に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for biologically aerobically or anaerobically treating organic wastewater such as sewage, human waste, and industrial wastewater.

(従来の技術) 有機性汚水を生物学的に好気的処理する方法は、大きく
二つに大別される。第1は活性汚泥法に代表される浮遊
汚泥法であり、第2は散水炉床法。
(Prior Art) Methods for biologically aerobically treating organic wastewater can be broadly classified into two types. The first is the floating sludge method, typified by the activated sludge method, and the second is the sprinkler hearth method.

浸漬が床法等に代表される生物膜処理法である。Immersion is a biofilm treatment method typified by the bed method.

これらの違いは、前者が浮遊状態の微生物群によっで浄
化作用を発揮させるのに対し、後者は担体を用いて該担
体の表面に付着する生物膜を利用することにある。
The difference between these is that the former uses a group of microorganisms in suspension to exert its purifying effect, whereas the latter uses a carrier and utilizes a biofilm attached to the surface of the carrier.

近年−生物膜処理法は、生物付着担体の開発に伴い様々
な方法が開発され、脚光をあびている技術である。なか
でも、担体を流動状態で用いるものは、生物膜処理法の
最大の欠点である担体の目詰まりを解決する方法として
注目を集めている。
In recent years, biofilm treatment is a technology that has been in the spotlight as various methods have been developed along with the development of bioadhesive carriers. Among these, methods that use carriers in a fluid state are attracting attention as a method for solving carrier clogging, which is the biggest drawback of biofilm treatment methods.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかしながら、微生物を付着させた担体を流動状態で用
いる従来の生物膜処理法では、処理開始時や長期間運転
を休止したあとなどでは、反応槽内の担体が水になじま
ず、比重1以上にもかかわらず、担体内部に保留される
気泡のために浮上してしまうことがあった。特に、担体
としてウレタンフオームなどを用いた場合のように、担
体自体の中に空間を有するものにおいては顕著であった
However, in conventional biofilm treatment methods that use microorganism-attached carriers in a fluidized state, the carriers in the reaction tank do not absorb water and have a specific gravity of 1 or more at the start of treatment or after a long period of suspension of operation. However, there were cases where the carrier floated to the surface due to air bubbles retained inside the carrier. This was particularly noticeable when the carrier itself had a space, such as when urethane foam was used as the carrier.

担体が浮上したままであると、水中における十分な流動
状態が得られず、反応槽での処理能力が低下し、さらに
浮上した担体の一部が嫌気的になり、悪臭を発生させる
などの二次公害の問題も発生しかねなかった。
If the carriers remain floating, sufficient fluidity in the water cannot be obtained, reducing the processing capacity of the reaction tank, and furthermore, some of the floating carriers may become anaerobic, causing unpleasant odors and other problems. Further pollution problems could have arisen.

本発明は、前記担体の浮上を防止し、反応槽内で理想的
な担体の流動状態を保ち、処理能力の低下や悪臭発生な
どの二次公害を防止することができる方法を提供しよう
とするものである。
The present invention aims to provide a method that can prevent the carrier from floating, maintain an ideal fluid state of the carrier in the reaction tank, and prevent secondary pollution such as a decrease in processing capacity and the generation of bad odors. It is something.

【課題を解決するための手段〕[Means to solve the problem]

本発明は、微生物を付着させた担体を流動状態にして汚
水を処理する方法において、高級アルコール、脂肪酸エ
ステル又はシリコン油を主成分とする担体ぬれ性改良剤
の1種もしくは2種以上を添加することを特徴とする汚
水処理方法である。
The present invention provides a method for treating wastewater by making a carrier attached with microorganisms into a fluidized state, in which one or more carrier wettability improvers whose main components are higher alcohols, fatty acid esters, or silicone oil are added. This sewage treatment method is characterized by:

〔作 用〕[For production]

本発明の最も重要な点は、微生物を付着させた担体を流
動状態にして汚水を処理する場合に、担体表面の「ぬれ
性」を改良して担体の浮上を防止し、理想的な担体の流
動状態を得るように工夫したことである。
The most important point of the present invention is that when treating wastewater by using a carrier with microorganisms attached in a fluid state, it is possible to improve the "wettability" of the carrier surface and prevent the carrier from floating, thereby creating an ideal carrier. This was devised to obtain a fluid state.

具体的には、担体ぬれ性改良剤を添加することによって
、担体表面の「ぬれ性」を改良し、担体に保留されてい
る気泡を放出させ、担体の流動状態を良好にすることで
ある。この担体ぬれ性改良剤としては、種々の実験の結
果、 ■ 高級アルコール R+  0  (RsO)nH ただし、R,j高級アルコール R1:ΦC*H*、■CxH6,■CaH*■ 脂肪酸
エステル R2−C−0(RsO)nfl ただし、R1:脂肪酸 R3:■CtHa、■Cs1li、■CJs■ シリコ
ン油 を主成分とするものが効果的であり、これらは、1種類
でも効果的であるが、2種以上組み合わせた場合には相
乗効果が生じ、使用量が少なく、より効果的である。
Specifically, by adding a carrier wettability improver, the "wettability" of the carrier surface is improved, air bubbles retained in the carrier are released, and the fluidity of the carrier is improved. As a result of various experiments, the carrier wettability improver is: ■ Higher alcohol R+ 0 (RsO) nH where R,j Higher alcohol R1: ΦC*H*, ■CxH6, ■CaH*■ Fatty acid ester R2-C -0(RsO)nfl However, R1: Fatty acid R3: ■CtHa, ■Cs1li, ■CJs■ Those whose main component is silicone oil are effective, and although one type of these is effective, two types When the above combinations are used, a synergistic effect occurs, the amount used is small, and it is more effective.

高級アルコールの例としては、エイコシルアルコール、
エイコモノール。ステアリルアルコール。
Examples of higher alcohols include eicosyl alcohol,
Eikomonol. stearyl alcohol.

ツルビルアルコール、ラウリルアルコール、リルニルア
ルコール、リルイルアルコール等がある。
Examples include turuvyl alcohol, lauryl alcohol, lilunyl alcohol, and lilyl alcohol.

脂肪酸エステルの例としては、オレイン酸エステル、ア
ラキン酸エステル、エイコセン酸エステル、グリセリン
酸エステル、ステアリン酸エステル、ソルビン酸エステ
ル、ラウリン酸エステル。
Examples of fatty acid esters include oleic acid esters, arachic acid esters, eicosenoic acid esters, glyceric acid esters, stearic acid esters, sorbic acid esters, and lauric acid esters.

リノール酸エステル、リノール酸エステル、リシノール
酸エステル、パルチミン酸エステル等がある。
There are linoleic acid esters, linoleic acid esters, ricinoleic acid esters, palmitic acid esters, etc.

シリコン油としては、有機基を持っジメチルシリコンオ
イルなどのオルガノポリシロキサンや、オルガノポリシ
ロキサンと疎水性シリカあるいは親木性シリカとの混合
物がある。
Examples of silicone oils include organopolysiloxanes having organic groups such as dimethyl silicone oil, and mixtures of organopolysiloxanes and hydrophobic silica or wood-philic silica.

さらに、処理開始時から定常状態に達するまでの馴致期
間においては種汚泥(活性汚泥等)を添加することが行
われるが、担体ねれ性改良剤により理想的な担体の流動
状態が得られるために、従来では予期できないほどの短
時間で定常運転に達する。この種汚泥添加率は0.1−
1g/J、好ましくは0.2〜0.6g/lとする。
Furthermore, seed sludge (activated sludge, etc.) is added during the acclimatization period from the start of treatment until a steady state is reached; In addition, steady state operation is achieved in a short time that could not previously be expected. This type of sludge addition rate is 0.1-
1 g/J, preferably 0.2 to 0.6 g/l.

本発明で流動化させる微生物付着用の担体としては、プ
ラスチック担体が好ましく、その材質は、ポリスチレン
、ポリ塩化ビニル、ポリエチレン。
The carrier for attaching microorganisms to be fluidized in the present invention is preferably a plastic carrier, and the material thereof is polystyrene, polyvinyl chloride, or polyethylene.

ポリプロピレン、ポリウレタン、フェノール、ユリャ、
エポキシ、シリコン、ポリエステル、含水ポリエステル
、メラミン、ジアリルフタレートアクリル、スチロール
、ABS、塩化ビニル、ポリカーボネート、ポリフェニ
レンオキサイド、ナイロン6、、illアセタール、ポ
リエチレンテレフタレート、四ふり化エチレンがよ(、
スポンジ(フオーム)、ビーズ等の形状で市販されてい
るものを利用できる。
polypropylene, polyurethane, phenol, yurya,
Epoxy, silicone, polyester, hydrous polyester, melamine, diallylphthalate acrylic, styrene, ABS, vinyl chloride, polycarbonate, polyphenylene oxide, nylon 6, ill acetal, polyethylene terephthalate, ethylene tetrafluoride.
Commercially available products in the form of sponges (foam), beads, etc. can be used.

担体の形状は、立方体、直方体1円筒体2球体その他の
不定形でよく、特に限定されるものではなく、寸法は流
動性を考慮して、その−辺又は直径をt−1oo鶴、好
ましくは10〜50鶴とする。
The shape of the carrier may be a cube, rectangular parallelepiped, 1 cylinder, 2 spheres, or other amorphous shapes, and is not particularly limited.The dimensions of the carrier are preferably t-10 mm, taking fluidity into consideration. 10 to 50 cranes.

担体ぬれ性改良剤の添加率は、1種類添加の場合は0.
5〜5g/l、好ましくは1〜4g/lとし、2種以上
添加の場合は合計で0.2〜3g/l、好ましくは0.
4〜2g/lとする0例えば、ポリエステルとシリコー
ン油を組み合わせて添加すると、単独の場合に比べて添
加率は半減し、経済的である。なお、処理中に何らかの
原因で担体が浮上した場合には、さらに適宜な量の担体
ぬれ性改良剤を追加して添加すればよい。
The addition rate of the carrier wettability improver is 0.0 when one type is added.
The amount is 5 to 5 g/l, preferably 1 to 4 g/l, and when two or more types are added, the total amount is 0.2 to 3 g/l, preferably 0.
For example, when polyester and silicone oil are added in combination, the addition rate is halved compared to when they are added alone, which is economical. If the carrier floats up for some reason during the treatment, an appropriate amount of carrier wettability improver may be added.

〔実施例〕〔Example〕

団地下水を原水とし、径400mx高28500の曝気
槽(3系列)によって、本発明、比較例1.比較例2の
実験をそれぞれ行った。それぞれ処理開始時の処理条件
を表1に示した0本発明での担体ぬれ性改良剤は、脂肪
酸エステルとしてオレイン酸エステルを主成分とするも
のと、シリコン油としてオルガノポリシロキシサンを主
成分とするものとを、2二8の割合で混合したものを使
用した。
The present invention, Comparative Example 1. The experiment of Comparative Example 2 was conducted respectively. The treatment conditions at the start of each treatment are shown in Table 1. The carrier wettability improver of the present invention is one whose main component is oleic acid ester as fatty acid ester, and one whose main component is organopolysiloxane as silicone oil. A mixture of 2:2 and 8:1 was used.

以下余白 処理開始時には、担体に生物膜が付着していない、そこ
で、生物付着量の増加程度を調査することから、定常状
態への移行程度を判断することにした。
At the start of the margin treatment, there was no biofilm attached to the carrier, so we decided to investigate the degree of increase in the amount of biofouling to determine the degree of transition to a steady state.

結果は第1図に示す通りであり、本発明では処理開始日
より担体はよく流動し、3日目には、はぼ定常状態に達
した。一方、比較例1でははじめの数日味流動状態が思
わしくないこともあったが、約lθ8目には本発明とほ
ぼ同様な状態になった。
The results are as shown in FIG. 1. In the present invention, the carrier flowed well from the start of the treatment, and reached a steady state on the third day. On the other hand, in Comparative Example 1, although the fluidity state was unsatisfactory for the first few days, the state became almost the same as that of the present invention at about lθ8.

また、比較例2では良好に流動しはしめるまでに約2週
間を要し、その後も時々一部の担体が浮上するなどの問
題はあったが、約40日後には本発明とほぼ同様になっ
た。
In addition, in Comparative Example 2, it took about two weeks to get good fluidity, and even after that, there were problems such as some of the carriers occasionally floating up, but after about 40 days, it was almost the same as the present invention. became.

このように、本発明では穫めて短時間で定常状態に達す
ることは勿論のこと、種汚泥の添加率が、比較例1のわ
ずか40%で十分となる0通常、種汚泥はタンクローリ
等で近くの活性汚泥施設より輸送するのが一般的であり
、その費用や作業量はばく大なものとなるが、本発明で
は種汚泥の量を少なくすることもできるため、極めて経
済的であ(発明の効果) 以上述べたように本発明によれば、次に列記するような
極めて顕著な効果を得ることができる。
In this way, in the present invention, not only can a steady state be reached in a short time after harvesting, but also the addition rate of seed sludge is only 40% of that of Comparative Example 1. Generally, the activated sludge is transported from a nearby activated sludge facility, which increases the cost and workload, but the present invention can reduce the amount of seed sludge, making it extremely economical. (Effects) As described above, according to the present invention, extremely remarkable effects as listed below can be obtained.

■ 微生物を付着させた担体の流動状態を理想的にし、
もし何らかの原因で担体が浮上した場合でも、速やかに
良好な流動状態に戻すことができ、処理能力の低下、悪
臭発生などの二次公害の恐れがない。
■ Make the fluidity of the carrier to which microorganisms are attached ideal,
Even if the carrier floats up for some reason, it can be quickly returned to a good fluid state, and there is no risk of secondary pollution such as a decrease in processing capacity or the generation of bad odors.

■ 処理開始時等の馴致期間においては、従来の種汚泥
添加率を低減でき、かつ短期間で定常運転に導くことが
できる。
■ During the acclimatization period such as at the start of treatment, the conventional seed sludge addition rate can be reduced, and steady operation can be achieved in a short period of time.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明と比較例における流動する担体への生
物付着量と経過日数との関係を示す線図である。
FIG. 1 is a diagram showing the relationship between the amount of biofouling on a flowing carrier and the number of days elapsed in the present invention and a comparative example.

Claims (1)

【特許請求の範囲】[Claims] (1)微生物を付着させた担体を流動状態にして汚水を
処理する方法において、高級アルコール、脂肪酸エステ
ル又はシリコン油を主成分とする担体ぬれ性改良剤の1
種もしくは2種以上を添加することを特徴とする汚水処
理方法。
(1) In a method of treating wastewater by making a carrier to which microorganisms are attached to a fluid state, a carrier wettability improver whose main component is higher alcohol, fatty acid ester, or silicone oil is used.
A sewage treatment method characterized by adding a species or two or more species.
JP1028592A 1989-02-09 1989-02-09 Sewage treatment Granted JPH02207893A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1028592A JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1028592A JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Publications (2)

Publication Number Publication Date
JPH02207893A true JPH02207893A (en) 1990-08-17
JPH0455757B2 JPH0455757B2 (en) 1992-09-04

Family

ID=12252866

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1028592A Granted JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Country Status (1)

Country Link
JP (1) JPH02207893A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009220079A (en) * 2008-03-18 2009-10-01 Inoac Corp Water treatment carrier
JP2010119979A (en) * 2008-11-21 2010-06-03 Inoac Corp Microorganism carrier for water treatment
CN102627373A (en) * 2011-06-29 2012-08-08 兰州理工大学 Micro-polluted water resource pollution treatment method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009220079A (en) * 2008-03-18 2009-10-01 Inoac Corp Water treatment carrier
JP2010119979A (en) * 2008-11-21 2010-06-03 Inoac Corp Microorganism carrier for water treatment
CN102627373A (en) * 2011-06-29 2012-08-08 兰州理工大学 Micro-polluted water resource pollution treatment method

Also Published As

Publication number Publication date
JPH0455757B2 (en) 1992-09-04

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