JPH0455757B2 - - Google Patents

Info

Publication number
JPH0455757B2
JPH0455757B2 JP1028592A JP2859289A JPH0455757B2 JP H0455757 B2 JPH0455757 B2 JP H0455757B2 JP 1028592 A JP1028592 A JP 1028592A JP 2859289 A JP2859289 A JP 2859289A JP H0455757 B2 JPH0455757 B2 JP H0455757B2
Authority
JP
Japan
Prior art keywords
carrier
acid esters
resin
wettability
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP1028592A
Other languages
Japanese (ja)
Other versions
JPH02207893A (en
Inventor
Hiroshi Goga
Juichi Fuchu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Ebara Research Co Ltd
Original Assignee
Ebara Research Co Ltd
Ebara Infilco Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Research Co Ltd, Ebara Infilco Co Ltd filed Critical Ebara Research Co Ltd
Priority to JP1028592A priority Critical patent/JPH02207893A/en
Publication of JPH02207893A publication Critical patent/JPH02207893A/en
Publication of JPH0455757B2 publication Critical patent/JPH0455757B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Biological Treatment Of Waste Water (AREA)
  • Treatment Of Biological Wastes In General (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 本発明は、下水,し尿,産業廃水などの有機性
汚水を生物学的に好気的あるいは嫌気的に処理す
る方法に関するものである。 〔従来の技術〕 有機性汚水を生物学的に好気的処理する方法
は、大きく二つに大別される。第1は活性汚泥法
に代表される浮遊汚泥法であり、第2は散水床
法,浸漬床法等に代表される生物膜処理法であ
る。これらの違いは、前者が浮遊状態の微生物群
によつて浄化作用を発揮させるのに対し、後者は
担体を用いて該担体の表面に付着する生物膜を利
用することにある。 近年、生物膜処理法は、生物付着担体の開発に
伴い様々な方法が開発され、脚光をあびている技
術である。なかでも、担体を流動状態で用いるも
のは、生物膜処理法の最大の欠点である担体の目
詰まりを解決する方法として注目を集めている。 〔発明が解決しようとする課題〕 しかしながら、微生物を付着させた担体を流動
状態で用いる従来の生物膜処理法では、処理開始
時や長期間運転を休止したあとなどでは、反応槽
内の担体が水になじまず、比重1以上にもかかわ
らず、担体内部に保留される気泡のために浮上し
てしまうことがあつた。特に、担体としてウレタ
ンフオームなどを用いた場合のように、担体自体
の中に空間を有するものにおいては顕著であつ
た。担体が浮上したままであると、水中における
十分な流動状態が得られず、反応槽での処理能力
が低下し、さらに浮上した担体の一部が嫌気的に
なり、悪臭を発生させるなどの二次公害の問題も
発生しかねなかつた。 本発明は、前記担体の浮上を防止し、反応槽内
で理想的な担体の流動状態を保ち、処理能力の低
下や悪臭発生などの二次公害を防止することがで
きる方法を提供しようとするものである。 〔課題を解決するための手段〕 本発明は、微生物を付着させた担体を流動状態
にして汚水を処理する方法において、高級アルコ
ール,脂肪酸エステル又はシリコン油を主成分と
する担体ぬれ性改良剤の1種もしくは2種以上を
添加することを特徴とする汚水処理方法である。 〔作用〕 本発明の最も重要な点は、微生物を付着させた
担体を流動状態にして汚水を処理する場合に、担
体表面の「ぬれ性」を改良して担体の浮上を防止
し、理想的な担体の流動状態を得るように工夫し
たことである。 具体的には、担体ぬれ性改良剤を添加すること
によつて、担体表面の「ぬれ性」を改良し、担体
に保留されている気泡を放出させ、担体の流動状
態を良好にすることである。この担体ぬれ性改良
剤としては、種々の実験の結果、 高級アルコールを主成分とするもの、脂肪酸エ
ステルを主成分とするもの、シリコン油を主成分
とするものが効果的であり、これらは、1種類で
も効果的であるが、2種以上組み合わせた場合に
は相乗効果が生じ、使用量が少なく、より効果的
である。 高級アルコールを主成分とする担体ぬれ性改良
剤の例としては、エイコシルアルコール,エイコ
セノール,ステアリルアルコール,ソルビルアル
コール,ウラリルアルコール,リノレニルアルコ
ール,リノレイルアルコール等がある。 脂肪酸エステルを主成分とする担体ぬれ性改良
剤の例としては、オレイン酸エステル,アラキン
酸エステル,エイコセン酸エステル,グリセリン
酸エステル,ステアリン酸エステル,ソルビン酸
エステル,ウラリン酸エステル,リノレン酸エス
テル,リノール酸エステル,リシノール酸エステ
ル,パルチミン酸エステル等がある。 シリコン油を主成分とする担体ぬれ性改良剤の
例としては、有機基を持つジメチルシリコンオイ
ルなどのオルガノポリシロキサンや、オルガノポ
リシロキサンと疎水性シリカあるいは親水性シリ
カとの混合物がある。 さらに、処理開始時から定常状態に達するまで
の馴致期間においては種汚泥(活性汚泥等)を添
加することが行われるが、担体ぬれ性改良剤によ
り理想的な担体の流動状態が得られるために、従
来では予期できないほどの短時間で定常運転に達
する。この種汚泥添加率は0.1〜1g/、好ま
しくは0.2〜0.6g/とする。 本発明で流動化させる微生物付着用の担体とし
ては、プラスチツク担体が好ましく、その材質
は、ポリスチレン,ポリ塩化ビニル,ポリエチレ
ン,ポリプロピレン,ポリウレタン,フエノール
樹脂,ユリヤ樹脂,エポキシ樹脂,シリコン樹
脂,ポリエステル,含水ポリエステル,メラミン
樹脂,ジアリルフタレート樹脂,アクリル樹脂,
スチロール樹脂,ABS樹脂,塩化ビニル樹脂,
ポリカーボネート,ポリフエニレンオキサイド,
ナイロン6,ポリアセタール,ポリエチレンテレ
フタレート,四ふつ化エチレン樹脂がよく、スポ
ンジ(フオーム),ビーズ等の形状で市販されて
いるものを利用できる。 担体の形状は、立方体,直方体,円筒体,球体
その他の不定形でよく、特に限定されるものでは
なく、寸法は流動性を考慮して、その一辺又は直
径を1〜100mm、好ましくは10〜50mmとする。 担体ぬれ性改良剤の添加率は、1種類添加の場
合は0.5〜5g/、好ましくは1〜4g/と
し、2種以上添加の場合は合計で0.2〜3g/、
好ましくは0.4〜2g/とする。例えば、ポリ
エステルとシリコーン油を組み合わせて添加する
と、単独の場合に比べて添加率は半減し、経済的
である。なお、処理中に何らかの原因で担体が浮
上した場合には、さらに適宜な量の担体ぬれ性改
良剤を追加して添加すればよい。 〔実施例〕 実施例 1 団地下水を原水とし、径400mm×高2850mmの曝
気槽(3系列)によつて、本発明、比較例1、比
較例2の実験をそれぞれ行つた。それぞれ処理開
始時の処理条件を表1に示した。本発明での担体
ぬれ性改良剤は、肪肪酸エステルを主成分とする
ものとしてオレイン酸エチルエステルと、シリコ
ン油を主成分とするものとしてオルガノポリシロ
キシサンとを、2:8の割合で混合したものを使
用した。
[Industrial Application Field] The present invention relates to a method for biologically aerobically or anaerobically treating organic wastewater such as sewage, human waste, and industrial wastewater. [Prior Art] Methods for biologically aerobically treating organic wastewater can be broadly classified into two types. The first is a floating sludge method, typified by the activated sludge method, and the second is a biofilm treatment method, typified by the sprinkled bed method, soaked bed method, and the like. The difference between these is that the former uses a group of microorganisms in suspension to exert its purification effect, whereas the latter uses a carrier and utilizes a biofilm attached to the surface of the carrier. In recent years, biofilm treatment is a technology that has been in the spotlight as various methods have been developed along with the development of bioadhesive carriers. Among these, methods that use carriers in a fluid state are attracting attention as a method for solving carrier clogging, which is the biggest drawback of biofilm treatment methods. [Problem to be solved by the invention] However, in the conventional biofilm treatment method that uses carriers with microorganisms attached in a fluid state, the carriers in the reaction tank tend to deplete at the start of treatment or after a long period of suspension of operation. It was not compatible with water, and even though it had a specific gravity of 1 or more, it sometimes floated to the surface due to air bubbles retained inside the carrier. This was particularly noticeable when the carrier itself had a space, such as when urethane foam was used as the carrier. If the carriers remain floating, sufficient fluidity in the water cannot be obtained, reducing the processing capacity of the reaction tank, and furthermore, some of the floating carriers may become anaerobic, causing unpleasant odors and other problems. Further pollution problems could have arisen. The present invention aims to provide a method that can prevent the carrier from floating, maintain an ideal fluid state of the carrier in the reaction tank, and prevent secondary pollution such as a decrease in processing capacity and the generation of bad odors. It is something. [Means for Solving the Problems] The present invention provides a method for treating wastewater by making a carrier to which microorganisms are attached into a fluidized state, using a carrier wettability improver containing higher alcohol, fatty acid ester, or silicone oil as a main component. This is a wastewater treatment method characterized by adding one or more kinds. [Function] The most important point of the present invention is that when treating wastewater by making the carrier with microorganisms attached into a fluid state, it improves the "wettability" of the carrier surface and prevents the carrier from floating, making it ideal. This was devised to obtain a fluid state of the carrier. Specifically, by adding a carrier wettability improver, the "wettability" of the carrier surface is improved, air bubbles retained in the carrier are released, and the fluidity of the carrier is improved. be. As a result of various experiments, it has been found that effective carrier wettability improvers include those containing higher alcohol as the main component, fatty acid ester as the main component, and silicone oil as the main component. Although one type is effective, when two or more types are combined, a synergistic effect occurs, the amount used is small, and it is more effective. Examples of carrier wettability improvers containing higher alcohol as a main component include eicosyl alcohol, eicosenol, stearyl alcohol, sorbyl alcohol, uralyl alcohol, linolenyl alcohol, and linoleyl alcohol. Examples of carrier wettability improvers containing fatty acid esters as main components include oleic acid esters, arachidic acid esters, eicosenoic acid esters, glyceric acid esters, stearic acid esters, sorbic acid esters, uraric acid esters, linolenic acid esters, and linoleic acid esters. There are acid esters, ricinoleic acid esters, palmitic acid esters, etc. Examples of carrier wettability improvers containing silicone oil as a main component include organopolysiloxanes such as dimethyl silicone oil having organic groups, and mixtures of organopolysiloxanes and hydrophobic or hydrophilic silica. Furthermore, seed sludge (activated sludge, etc.) is added during the acclimatization period from the start of treatment until a steady state is reached; , steady state operation is achieved in a short time that could not previously be expected. The addition rate of this type of sludge is 0.1 to 1 g/, preferably 0.2 to 0.6 g/. As the carrier for attaching microorganisms to be fluidized in the present invention, a plastic carrier is preferable, and the materials thereof include polystyrene, polyvinyl chloride, polyethylene, polypropylene, polyurethane, phenolic resin, urea resin, epoxy resin, silicone resin, polyester, water-containing resin, etc. Polyester, melamine resin, diallyl phthalate resin, acrylic resin,
Styrene resin, ABS resin, vinyl chloride resin,
polycarbonate, polyphenylene oxide,
Nylon 6, polyacetal, polyethylene terephthalate, and tetrafluoroethylene resins are preferred, and those commercially available in the form of sponges (foam), beads, etc. can be used. The shape of the carrier may be a cube, a rectangular parallelepiped, a cylinder, a sphere, or any other amorphous shape, and is not particularly limited.The size of the carrier is 1 to 100 mm on one side or in diameter, preferably 10 to 100 mm, taking fluidity into consideration. The length shall be 50mm. The addition rate of the carrier wettability improver is 0.5 to 5 g/, preferably 1 to 4 g/in the case of adding one type, and 0.2 to 3 g/in total in the case of adding two or more types.
Preferably it is 0.4-2g/. For example, when polyester and silicone oil are added in combination, the addition rate is halved compared to when they are added alone, which is economical. If the carrier floats up for some reason during the treatment, an appropriate amount of carrier wettability improver may be added. [Examples] Example 1 Experiments of the present invention, Comparative Example 1, and Comparative Example 2 were conducted using aeration tanks (3 series) each having a diameter of 400 mm and a height of 2850 mm, using underground water as raw water. Table 1 shows the treatment conditions at the start of each treatment. The carrier wettability improver in the present invention contains oleic acid ethyl ester, which is mainly composed of a fatty acid ester, and organopolysiloxane, which is mainly composed of silicone oil, in a ratio of 2:8. I used a mixture.

〔発明の効果〕〔Effect of the invention〕

以上述べたように本発明によれば、次に列記す
るような極めて顕著な効果を得ることができる。 微生物を付着させた担体の流動状態を理想的
にし、もし何らかの原因で担体が浮上した場合
でも、速やかに良好な流動状態に戻すことがで
き、処理能力の低下,悪臭発生などの二次公害
の恐れがない。 処理開始時等の馴致期間においては、従来の
種汚泥添加率を低減でき、かつ短期間で定常運
転に導くことができる。
As described above, according to the present invention, extremely remarkable effects as listed below can be obtained. The fluidity of the carrier with microorganisms attached to it is ideal, and even if the carrier floats for some reason, it can be quickly returned to a good fluidity, which prevents secondary pollution such as a decrease in processing capacity and the generation of bad odors. There is no fear. During the acclimatization period such as at the start of treatment, the conventional seed sludge addition rate can be reduced and steady operation can be achieved in a short period of time.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明と比較例における流動する担
体への生物付着量と経過日数との関係を示す線図
である。
FIG. 1 is a diagram showing the relationship between the amount of biofouling on a flowing carrier and the number of days elapsed in the present invention and a comparative example.

Claims (1)

【特許請求の範囲】[Claims] 1 微生物を付着させた担体を流動状態にして汚
水を処理する方法において、高級アルコール,脂
肪酸エステル又はシリコン油を主成分とする担体
ぬれ性改良剤の1種もしくは2種以上を添加する
ことを特徴とする汚水処理方法。
1. A method for treating wastewater by making a carrier attached with microorganisms into a fluidized state, characterized by the addition of one or more carrier wettability improvers whose main components are higher alcohols, fatty acid esters, or silicone oil. wastewater treatment method.
JP1028592A 1989-02-09 1989-02-09 Sewage treatment Granted JPH02207893A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1028592A JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1028592A JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Publications (2)

Publication Number Publication Date
JPH02207893A JPH02207893A (en) 1990-08-17
JPH0455757B2 true JPH0455757B2 (en) 1992-09-04

Family

ID=12252866

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1028592A Granted JPH02207893A (en) 1989-02-09 1989-02-09 Sewage treatment

Country Status (1)

Country Link
JP (1) JPH02207893A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4914855B2 (en) * 2008-03-18 2012-04-11 株式会社イノアックコーポレーション Water treatment carrier
JP5284057B2 (en) * 2008-11-21 2013-09-11 株式会社イノアックコーポレーション Method for producing microbial carrier for water treatment
CN102627373A (en) * 2011-06-29 2012-08-08 兰州理工大学 Micro-polluted water resource pollution treatment method

Also Published As

Publication number Publication date
JPH02207893A (en) 1990-08-17

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