JPH0212632B2 - - Google Patents
Info
- Publication number
- JPH0212632B2 JPH0212632B2 JP8413081A JP8413081A JPH0212632B2 JP H0212632 B2 JPH0212632 B2 JP H0212632B2 JP 8413081 A JP8413081 A JP 8413081A JP 8413081 A JP8413081 A JP 8413081A JP H0212632 B2 JPH0212632 B2 JP H0212632B2
- Authority
- JP
- Japan
- Prior art keywords
- film
- sheet
- unevenness
- forming
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 40
- 239000002904 solvent Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 230000008961 swelling Effects 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 description 27
- 239000004033 plastic Substances 0.000 description 27
- 238000001723 curing Methods 0.000 description 26
- 238000000576 coating method Methods 0.000 description 17
- -1 and if necessary Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000004568 cement Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000008602 contraction Effects 0.000 description 6
- 239000003981 vehicle Substances 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000000025 natural resin Substances 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 239000002985 plastic film Substances 0.000 description 4
- 229920006255 plastic film Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920005749 polyurethane resin Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- HXBPYFMVGFDZFT-UHFFFAOYSA-N allyl isocyanate Chemical compound C=CCN=C=O HXBPYFMVGFDZFT-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- WARQUFORVQESFF-UHFFFAOYSA-N isocyanatoethene Chemical compound C=CN=C=O WARQUFORVQESFF-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/04—Modelling plastic materials, e.g. clay
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/141—Hydrophilic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
【発明の詳細な説明】
本発明は模様状凹凸を付与する方法に関し、更
に詳しくは凹凸形成用フイルム又はシートを用い
た模様状凹凸を硬化前において可塑性を有する材
料（以下本明細書中ではしばしば可塑性材料と称
す）の表面に付与する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for imparting pattern-like unevenness, and more specifically, to a method of imparting pattern-like unevenness using a film or sheet for forming unevenness, which is formed using a material having plasticity (hereinafter referred to as often referred to in the present specification) before curing. The present invention relates to a method of applying the material to the surface of a plastic material (referred to as a plastic material).
従来、硬化前において可塑性材料の表面に模様
状凹凸を設ける方法としては型板や型ロール等の
型を使用する方法や可塑性材料の中に発抱剤を混
入しておき、発抱の程度を変える等の方法がある
が、前者の型を使用する方法においては型に忠実
な模様状凹凸を付与することができるが、使用す
る型は高価で作業性が悪く、又、複雑な付帯装置
と作業を要する場合が多く、又、後者の発泡剤を
用いる方法では対象となる材料が限定されるとい
ういずれも欠点を有するものである。 Conventionally, methods for creating pattern-like irregularities on the surface of plastic materials before curing include using molds such as templates or mold rolls, or mixing a binder into the plastic material to control the degree of entrainment. There are methods such as changing the mold, but the former method can give a pattern-like unevenness that is faithful to the mold, but the mold used is expensive, has poor workability, and requires complicated accessory equipment. Both methods have the disadvantage that they often require a lot of work, and the latter method using a blowing agent limits the materials that can be used.
一方、本発明と同一の出願人は以前に、未処理
前の化粧層の上に、該化粧層を構成する成分によ
つて伸縮変形を受ける区域と伸縮変化を受けない
区域及び／又は伸縮変形を受ける程度に差異を有
する区域を設けたシートを重ね合わせ、次いで上
記の化粧層を構成する成分に適した後処理を施し
て、上記の各区域に対応して上記の化粧層上に凹
凸を形成させることを特徴とする化粧材の製造法
（特開昭52−91061号公報記載）を提案している
が、この方法においては前記したような金型や発
泡剤を使用する際の欠点は一応解消しているもの
の、伸縮変形は化粧層を構成する成分によつてい
るため、化粧層の成分の配合比の不均一や経時的
変化等による成分の配合比の変化により伸縮変形
が均一に発生せず不安定であり、従つて形成する
凹凸が均一にならず外観意匠上好ましくないもの
である。 On the other hand, the same applicant as the present invention has previously proposed that on an untreated makeup layer, an area that undergoes expansion/contraction deformation by the components constituting the makeup layer, an area that does not undergo expansion/contraction change, and/or an area that undergoes expansion/contraction deformation. The sheets having areas with different degrees of reception are superimposed, and then a post-treatment suitable for the ingredients constituting the above-mentioned decorative layer is applied to create irregularities on the above-mentioned decorative layer corresponding to each of the above-mentioned areas. proposed a manufacturing method for decorative materials (described in JP-A No. 52-91061) characterized by the formation of Although the expansion and contraction deformation has been resolved for the time being, the expansion and contraction deformation depends on the components that make up the makeup layer, so the expansion and contraction deformation becomes uniform due to unevenness in the composition ratio of the components of the makeup layer and changes in the composition ratio of the components due to changes over time. It is unstable because it does not occur, and therefore the unevenness formed is not uniform, which is undesirable in terms of appearance and design.
本発明は凹凸形成を一層安定させ、均一さを向
上させるためのものであつて、凹凸形成用フイル
ム又はシートの膨潤による伸びはすべて化粧層の
成分によるのではなく、別に用意した溶媒を塗布
することにより実質的に行なわしめることにより
なり、より詳しくは、硬化前において可塑性を有
する材料の硬化前の表面に、溶媒により膨潤して
伸びる区域と伸びない区域および／又は前記の膨
潤して伸びる区域の伸びとは伸びの程度が異なる
区域とを設けてなる凹凸形成用フイルム又はシー
トを密着させ、次いで前記凹凸形成用フイルム又
はシートの側から一面に前記凹凸形成用フイルム
又はシートを膨潤させる溶媒を塗装して前記凹凸
形成用フイルム又はシートに変形を生じさせ該変
形に対応せる模様状凹凸を前記の硬化前において
可塑性を有する材料の表面に生じさせた後、前記
の硬化前において可塑性を有する材料を硬化さ
せ、しかる後前記凹凸形成用フイルム又はシート
を剥離することを特徴とするものである。 The present invention is intended to further stabilize the unevenness formation and improve its uniformity, and the elongation of the unevenness forming film or sheet due to swelling is not caused entirely by the components of the decorative layer, but by applying a separately prepared solvent. More specifically, on the surface of the material having plasticity before curing, a region that swells and stretches with the solvent, a region that does not stretch, and/or a region that swells and stretches by the solvent. A film or sheet for forming unevenness is brought into close contact with a region having a different degree of elongation from the elongation, and then a solvent for swelling the film or sheet for forming unevenness is applied to one side of the film or sheet for forming unevenness. After coating the film or sheet for forming irregularities to cause deformation and producing pattern-like irregularities corresponding to the deformation on the surface of the material that has plasticity before curing, the material that has plasticity before curing. The method is characterized in that the film or sheet for forming irregularities is peeled off.
以下、本発明について詳しく説明する。 The present invention will be explained in detail below.
（可塑性材料）
本発明において使用する可塑性材料としては、
結合材を主成分とし必要に応じて、充填剤、骨
材、顔料或いは染料等の着色剤、架橋剤、可塑
剤、安定剤、硬化剤、乾燥剤、水和剤、活性剤、
乳化剤、増粘剤、発泡剤、水、有機溶剤、希釈
剤、無機酸、無機塩類、有機酸等の成分、或いは
添加剤を任意に添加し、硬化型、溶剤型、乳化
型、分散型、ゾル型としてなるものが使用され
る。(Plastic material) As the plastic material used in the present invention,
The main component is a binder, and if necessary, fillers, aggregates, colorants such as pigments or dyes, crosslinking agents, plasticizers, stabilizers, curing agents, desiccants, hydrating agents, activators,
Components such as emulsifiers, thickeners, blowing agents, water, organic solvents, diluents, inorganic acids, inorganic salts, organic acids, etc., or additives are optionally added to form hardening type, solvent type, emulsification type, dispersion type, A sol type is used.
結合剤としては、種々の物を使用することがで
き、例えば天然ないし合成樹脂類、無機質系バイ
ンダー、半水石膏、セメント等の水硬性物質等を
単独ないし混合して使用される。 Various materials can be used as the binder, such as natural or synthetic resins, inorganic binders, hydraulic substances such as gypsum hemihydrate, and cement, etc., used alone or in combination.
樹脂としては、公知のもの、例えば、塩化ビニ
ル、塩化ビニリデン等のハロゲン化ビニル単量
体、スチレン並びにその誘導体、酢酸ビニル等の
ビニルエステル単量体、アリルアルコールおよび
アリルエステル類、アクリル酸、メタクリル酸、
イタコン酸、クロトン酸、マレイン酸又はフマル
酸等の不飽和カルボン酸類、上記の不飽和カルボ
ン酸類のエステル誘導体、同ニトリル誘導体又は
同酸アミド誘導体、上記の不飽和カルボン酸類の
酸アミド誘導体のＮ−メチロール誘導体及び同Ｎ
−アルキルメチロールエーテル誘導体、グリシジ
ルアクリレート、グリシジルメタクリレート、ア
リルグリシジルエーテル、ビニルイソシアネー
ト、アリルイソシアネート、２−ヒドロキシエチ
ルアクリレート又はメタクリレート、２−ヒドロ
キシプロピルアクリレート又はメタクリレート、
エチレングリコールモノアクリレート又はメタク
リレート、エチレングリコールジアクリレート又
はメタクリレート、無水マレイン酸、無水イタコ
ン酸、メチルビニルケトン、ブタジエン、エチレ
ン、プロピレン、ジメチルアミノエチルメタクリ
レート、ビニルピリジン、tert−ブチルアミノエ
チルメタクリレート、多価アルコールのモノアリ
ルエーテル等の如き単量体の単独ないし共重合体
類等の熱可塑性樹脂、ポリアミド系樹脂、ポリエ
ステル系樹脂、フエノール系樹脂、メラミン系樹
脂、尿素樹脂、エポキシ系樹脂、フタル酸ジアリ
ル系樹脂、ケイ素樹脂、ポリウレタン系樹脂等の
如き熱硬化性樹脂又はそれらの変性樹脂若しくは
初期縮含物等、その他、天然樹脂、ロジン及びそ
の誘導体、セルロース誘導体、天然又は合成ゴ
ム、石油樹脂等を使用することができる。 Examples of the resin include known ones, such as vinyl halide monomers such as vinyl chloride and vinylidene chloride, styrene and its derivatives, vinyl ester monomers such as vinyl acetate, allyl alcohol and allyl esters, acrylic acid, and methacrylate. acid,
N- of unsaturated carboxylic acids such as itaconic acid, crotonic acid, maleic acid or fumaric acid, ester derivatives, nitrile derivatives or acid amide derivatives of the above unsaturated carboxylic acids, and acid amide derivatives of the above unsaturated carboxylic acids. Methylol derivatives and N
- alkyl methylol ether derivatives, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether, vinyl isocyanate, allyl isocyanate, 2-hydroxyethyl acrylate or methacrylate, 2-hydroxypropyl acrylate or methacrylate,
Ethylene glycol monoacrylate or methacrylate, ethylene glycol diacrylate or methacrylate, maleic anhydride, itaconic anhydride, methyl vinyl ketone, butadiene, ethylene, propylene, dimethylaminoethyl methacrylate, vinylpyridine, tert-butylaminoethyl methacrylate, polyhydric alcohol Thermoplastic resins such as mono- or copolymers of monomers such as monoallyl ether, polyamide resins, polyester resins, phenolic resins, melamine resins, urea resins, epoxy resins, diallyl phthalates Thermosetting resins such as resins, silicone resins, polyurethane resins, modified resins or initial condensates, etc., as well as natural resins, rosins and their derivatives, cellulose derivatives, natural or synthetic rubbers, petroleum resins, etc. are used. can do.
（凹凸形成用フイルム又はシート）
本発明において用いる、溶媒により膨潤して伸
びる区域と伸びない区域および／又は前記の膨潤
して伸びる区域の伸びとは伸びの程度が異なる区
域とを設けてなる凹凸形成用フイルム又はシート
を構成するフイルム又はシートについて述べる
と、かかるフイルム又はシートとしては、各種の
紙類、各種の織布ないし不織布類、セロハン等の
繊維素類、各種の合成紙類、ポリエチレンフイル
ム、ポリプロピレンフイルム、ポリスチレンフイ
ルム、ポリ塩化ビニルフイルム、ポリ塩化ビニリ
デンフイルム、ポリビニルアルコールフイルム、
ふつ素樹脂フイルム、ポリカーボネートフイル
ム、アセテートフイルム、ポリエステルフイル
ム、ポリアミドフイルム、塩酸ゴムフイルム、イ
オノマーフイルム、ポリイミドフイルム、ポリウ
レタンフイルム、ポリメタアクソレート等の各種
のプラスチツクフイルム、各種のポリマーブレン
ド或いは共重合物のプラスチツクフイルム、各種
の架橋結合プラスチツクフイルム、各種の収縮性
プラスチツクフイルム、及びこれらフイルムを２
種以上貼合せた複合フイルム等が使用される。こ
れらフイルム状物は必要に応じて撥水剤、離型
剤、充填剤、柔軟剤、可塑剤、安定剤、帯電防止
剤、紫外線劣化防止剤等の添加剤が加えられる。
又、場合によつては各種の表面処理を施こすこと
もできる。(Film or sheet for forming unevenness) Used in the present invention, the unevenness is formed by providing a region that swells and stretches with a solvent, a region that does not stretch, and/or a region that has a different degree of elongation from the region that swells and stretches. Regarding the films or sheets constituting the forming film or sheet, such films or sheets include various papers, various woven or non-woven fabrics, cellulose such as cellophane, various synthetic papers, and polyethylene films. , polypropylene film, polystyrene film, polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film,
Various plastic films such as fluorine resin film, polycarbonate film, acetate film, polyester film, polyamide film, hydrochloric acid rubber film, ionomer film, polyimide film, polyurethane film, polymethacrylate, various polymer blends or copolymers. Plastic films, various cross-linked plastic films, various shrinkable plastic films, and 2 types of these films.
A composite film made by laminating more than one type of material is used. Additives such as a water repellent, a mold release agent, a filler, a softener, a plasticizer, a stabilizer, an antistatic agent, and an anti-ultraviolet deterioration agent are added to these film-like materials as necessary.
In addition, various surface treatments can be applied depending on the case.
次に上記のフイルム又はシートに溶媒により膨
潤して伸びる区域と伸びない区域および／又は前
記の膨潤して伸びる区域の伸びとは伸びの程度が
異なる区域とを設ける方法について述べると各種
の方法があるが、標準的な方法としては先ずフイ
ルム又はシートに伸びの程度に差異を生じさせる
インキ、塗料等を部分的に付与する方法である。
該方法としては公知の方法例えば、凹版印刷方
式、平版印刷方式、凸版印刷方式、スクリーン印
刷方式等の如き印刷方法、はけ塗り、へら塗り、
吹付け塗り等の如き塗布方法、その他、手、筆等
による描画方法等で行うことができ、かかる方法
で行えば、文字、図形、記号、絵柄等の任意の区
域を設けることができ、前記した凹凸形成用フイ
ルム又はシートを構成するフイルム又はシートの
表裏いずれの面に設けてもよく、又、両面に設け
てもよい。 Next, we will discuss how to provide the above-mentioned film or sheet with a region that swells and stretches with a solvent, a region that does not stretch, and/or a region that has a different degree of elongation from the region that swells and stretches. However, the standard method is to first partially apply ink, paint, etc. that causes differences in the degree of elongation to the film or sheet.
The method includes known methods such as intaglio printing, planographic printing, letterpress printing, screen printing, etc., brush coating, spatula coating,
This can be done by a coating method such as spray painting, or by a drawing method by hand, brush, etc. If carried out by such a method, arbitrary areas such as letters, figures, symbols, patterns, etc. can be provided, and the above-mentioned It may be provided on either the front or back surface of the film or sheet constituting the film or sheet for forming unevenness, or may be provided on both surfaces.
上記方法において、インキ、塗料組成物として
は公知のもの、例えば通常のインキないし塗料組
成物用のビヒクルを主成分とし、これらに必要な
場合に例えば可塑剤、安定剤、硬化剤、乾燥剤、
界面活性剤、離型剤、撥水剤、湿潤剤、防湿剤、
柔軟剤、染料、顔料等の着色剤、充填剤、その他
の種々の添加剤の１種又はそれ以上を添加し、硬
化型組成物、溶液型組成物、エマルジヨン型組成
物又はゾル型組成物として使用される。上記のビ
ヒクルとしては、前記の硬化前において可塑性を
有する材料を構成する際に使用した天然ないし合
成樹脂等を使用することができる。 In the above method, the main component of the ink or coating composition is a known one, such as a vehicle for ordinary ink or coating compositions, and if necessary, for example, plasticizers, stabilizers, curing agents, drying agents, etc.
surfactant, mold release agent, water repellent, wetting agent, moisture proofing agent,
One or more of colorants such as softeners, dyes, and pigments, fillers, and other various additives are added to form curable compositions, solution-type compositions, emulsion-type compositions, or sol-type compositions. used. As the vehicle, natural or synthetic resins used in forming the plastic material before curing can be used.
又、上記した方法以外にも例えば模様状にフイ
ルム又はシートを部分的に架橋させる方法等も行
なえ、これら以外の方法であつても、溶媒により
膨潤して伸びる区域と伸びない区域および／又は
前記の膨潤して伸びる区域の伸びとは伸びの程度
が異なる区域を設ける方法であれば差支えない。 In addition to the methods described above, a method of partially crosslinking a film or sheet in a pattern may also be used. Any method is acceptable as long as it provides a region with a different degree of elongation from the region that swells and elongates.
次に凹凸形成用フイルム又はシートには全面に
微細な貫通孔を設けておくと、硬化前において可
塑性を有する材料の硬化前の表面に気泡を抱き込
むことなく密着させることができ好ましい。かか
る貫通孔を凹凸形成用フイルム又はシートに設け
る方法としては公知の方法が使用でき、ロールの
全面に針を植えてなる針ロールを使用し針ロール
と対接するゴムロールとの間を通す方法、平板の
表面に均一に針を植えた型を用い型の上下動とフ
イルム又はシートの間欠送りにより行なう方法、
或いは上記の針ロール、針を植えた型の針を加熱
しておきフイルム又はシートを部分的に溶融する
方法、フイルム又はシートを溶かしうる溶剤を点
状に設けた後フイルム又はシートを加温し点状に
溶解する方法等を用いることができるが、これら
以外の方法でもよい。又、上記した貫通孔を設け
る方法は、前記したフイルム又はシートに溶媒に
より膨潤して伸びる区域と伸びない区域および／
又は前記の膨潤して伸びる区域の伸びとは伸びの
程度が異なる区域とを設ける方法の先に行なつて
もよいが、例えば針ロールや針を植えた型を用い
る場合には貫通孔を先に設けると貫通孔の周囲の
平滑性が低下しインキや塗料による均一な印刷や
塗布等は困難になるので、かかる場合には貫通孔
を設ける方法を印刷や塗布等の後に行なうことが
好ましい。 Next, it is preferable to provide the film or sheet for forming irregularities with fine through-holes over the entire surface so that the film or sheet can be brought into close contact with the surface of the plastic material before curing without trapping air bubbles. Known methods can be used to provide such through holes in the film or sheet for forming unevenness, such as a method using a needle roll with needles planted on the entire surface of the roll and passing the holes between the needle roll and an opposing rubber roll, and a flat plate. A method using a mold with needles evenly planted on the surface of the mold, by moving the mold up and down and intermittent feeding of the film or sheet.
Alternatively, the above-mentioned needle roll or needle type with needles is heated to partially melt the film or sheet, or the film or sheet is heated after providing dots of a solvent that can dissolve the film or sheet. A method of dissolving in dots can be used, but methods other than these may also be used. In addition, the method for providing the above-mentioned through-holes is such that the above-mentioned film or sheet has areas that swell and expand with a solvent, areas that do not expand, and/or
Alternatively, this method may be performed prior to the method of providing a region whose degree of elongation is different from that of the region that swells and elongates. If the through-holes are provided, the smoothness around the through-holes will deteriorate and it will be difficult to print or apply uniformly with ink or paint, so in such cases it is preferable to provide the through-holes after printing or coating.
なお、可塑性材料が水を成分として含むもので
あり、凹凸形成用フイルム又はシートが水により
膨潤して伸びる区域と伸びない区域および／又は
前記の膨潤して伸びる区域の伸びとは伸びの程度
が異なる区域とを設けてなるときには、凹凸形成
用フイルム又はシートの、可塑性材料と接する側
の全面に実質的不透水層を設けておき、水を凹凸
形成用フイルム又はシートの側から一面に塗装す
る前に可塑性材料が含む水による影響を少なく
し、水の塗装によりはじめて実質的な変形を生じ
させると均一な模様状凹凸が得られ好ましい。か
かる目的で設ける不透水層としては種々のものが
使用できるが、全面に設けるため、変形を阻害す
るようなものであつてはならず、変形には容易に
追随し、しかも実質的に不透水性であるものが望
まれる。以上の条件に合致する不透水層として
は、例えば通常のインキないし塗料組成物用のビ
ヒクルを主成分とし、これらに必要な場合に例え
ば、安定剤、硬化剤、離型剤、撥水剤、その他の
添加剤を１種又はそれ以上を添加し、硬化型組成
物、溶剤型組成物として使用することができ、か
かるビヒクルとしては、前記の硬化前において可
塑性を有する材料を構成する際に使用した天然な
いし合成樹脂等を使用することができる。 In addition, the plastic material contains water as a component, and the degree of elongation differs between the area where the film or sheet for forming unevenness swells and stretches with water, the area where it does not stretch, and/or the area where it swells and stretches. When different areas are provided, a substantially water-impermeable layer is provided on the entire surface of the film or sheet for forming unevenness on the side in contact with the plastic material, and water is applied over the entire surface of the film or sheet for forming unevenness from the side. It is preferable to first reduce the influence of water contained in the plastic material, and then allow substantial deformation to occur only by applying water, since uniform pattern-like irregularities can be obtained. Various types of impermeable layers can be used as the impermeable layer provided for this purpose, but since it is provided over the entire surface, it must not inhibit deformation, easily follow deformation, and be substantially impermeable. Something that is sexual is desired. The water-impermeable layer that meets the above conditions may have, for example, a vehicle for ordinary ink or coating compositions as its main component, and if necessary, stabilizers, curing agents, mold release agents, water repellents, etc. One or more other additives can be added and used as a curable composition or a solvent-based composition, and such a vehicle can be used when forming the above-mentioned plastic material before curing. Natural or synthetic resins can be used.
なお上記の例のように可塑性材料に含まれる溶
媒が凹凸形成用フイルム又はシートを膨潤させる
溶媒と同一の場合には、溶媒を透さない層を設け
るとよく、同一でない場合には不要である。 Note that if the solvent contained in the plastic material is the same as the solvent that swells the film or sheet for forming unevenness, as in the example above, it is better to provide a layer that is impermeable to the solvent, and if it is not the same, it is not necessary. .
（溶媒）
本発明において溶媒により膨潤して伸びる区域
と伸びない区域および／又は前記の膨潤して伸び
る区域の伸びとは伸びの程度が異なる区域とを設
けてなる凹凸形成用フイルム又はシートを膨潤さ
せる溶媒としては、公知のもの例えば、ペンタ
ン、ヘキサン、ヘプタン、オクタン等、或いはこ
れらの混合液であるガソリン、石油、ベンジン、
ミネラルスピリツト、石油ナフサ等の脂肪族炭化
水素類、ベンゼン、トルエン、キシレン、シクロ
ヘキサン、エチルベンゼン等の芳香族炭化水素
類、トリクロルエチレン、パークロルエチレン、
クロロホルム、四塩化炭素等のハロゲン化炭化水
素類、水、メチルアルコール、エチルアルコー
ル、プロピルアルコール、ブチルアルコール、ア
ミルアルコール、ベンジルアルコール等の一価ア
ルコール類、エチレングリコール、プロピレング
リコール、グリセリン等の多価アルコール類、ア
セトン、メチルエチルケトン、メチルイソブチル
ケトン、シクロヘキサノン、イソホロン等のケト
ン類、エチルエーテル、イソプロピルエーテル、
エチレングリコールモノメチルエーテル、エチレ
ングリコールモノエチルエーテル、ジエチレング
リコールモノメチルエーテル、ジエチレングリコ
ールモノエチルエーテル、等のエーテル類、酢酸
エステル類、酪酸エステル類、等のエステル類、
ニトロ炭化水素類、ニトリル類、アミン類、その
他アセタール類、酸類、フラン類等の単独或いは
混合溶剤として使用され、前記した凹凸形成用フ
イルム又はシートを構成するフイルム又はシート
の材質、希望する膨潤の速度等を考慮し選択し使
用するが、一例として可塑性材料として水を含む
ものを用い、凹凸形成用フイルム又はシートを構
成するフイルム又はシートとしてポリビニルアル
コール系のものを用いるときは水を主体とするも
のを使用する。(Solvent) In the present invention, a film or sheet for forming unevenness is swollen with a solvent and has a region that swells and stretches, a region that does not stretch, and/or a region that has a different degree of elongation from the region that swells and stretches. Examples of the solvent include known solvents such as pentane, hexane, heptane, octane, etc., or mixtures thereof such as gasoline, petroleum, benzine,
Mineral spirits, aliphatic hydrocarbons such as petroleum naphtha, aromatic hydrocarbons such as benzene, toluene, xylene, cyclohexane, ethylbenzene, trichlorethylene, perchloroethylene,
Halogenated hydrocarbons such as chloroform and carbon tetrachloride, water, monohydric alcohols such as methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol, amyl alcohol, and benzyl alcohol, and polyhydric alcohols such as ethylene glycol, propylene glycol, and glycerin. Alcohols, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, isophorone, ethyl ether, isopropyl ether,
Ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, esters such as acetate esters, butyrate esters,
Nitrohydrocarbons, nitriles, amines, other acetals, acids, furans, etc. are used alone or as a mixed solvent, and the material of the film or sheet constituting the above-mentioned unevenness forming film or sheet, the desired swelling They are selected and used in consideration of speed, etc., but for example, if a plastic material containing water is used, and if a polyvinyl alcohol-based film or sheet is used as the film or sheet constituting the film or sheet for forming unevenness, water is used as the main component. use something
（基材）
次に上述した硬化前において可塑性を有する材
料、凹凸形成用フイルム又はシート、溶媒を用い
て模様状凹凸を付与する方法について述べると、
まず、適当な基材に前記した硬化前において可塑
性を有する材料を塗工する。(Substrate) Next, a method for imparting patterned unevenness using a plastic material, a film or sheet for forming unevenness, and a solvent before curing will be described.
First, the above-described plastic material is applied to a suitable base material before curing.
基材としては、種々のものが使え、例えば、木
材、合板、パーテイクルボード等の木質板、薄手
ないし厚手の紙、化粧紙、段ボール等の各種の紙
類、各種の織布ないし不織布類、鋼板、ステンレ
ス鋼板、アルミニウム板、銅板等の各種の金属
板、各種のプラスチツク板ないしフイルム、ハー
ドボード等の各種繊維質板、石膏ボード類、パル
プセメント板、ロツクウール板、木毛セメント
板、木片セメント板等の各種の有機高分子化合物
と無機物質との複合体基材、石綿スレート板、ケ
イ酸カルシウム板、GRC板、その他各種の無機
質板、コンクリートによる建築物のコンクリート
面等を使用することができる。これらは必要な場
合、前処理、接着剤等が施される。 Various materials can be used as the base material, such as wood, plywood, wooden boards such as particle board, various papers such as thin or thick paper, decorative paper, and cardboard, various woven or non-woven fabrics, Various metal plates such as steel plates, stainless steel plates, aluminum plates, and copper plates, various plastic plates or films, various fibrous plates such as hardboard, gypsum boards, pulp cement plates, rock wool plates, wood wool cement plates, and wood chip cement. Composite base materials of various organic polymer compounds and inorganic substances such as boards, asbestos slate boards, calcium silicate boards, GRC boards, various other inorganic boards, concrete surfaces of buildings made of concrete, etc. can be used. can. These are subjected to pretreatment, adhesive, etc., if necessary.
（可塑性材料の塗工）
上記の基材に硬化前において可塑性材料を塗工
する方法としては公知の方法である、ロールコー
ト法、グラビアロールコート法、エアーナイフコ
ート法、スピンナーコート法、かけ流しコート
法、デイツプコート法、スプレーコート法等の
他、こて塗り等の方法を用いて行なうことができ
る。(Coating of plastic material) There are known methods for coating the above-mentioned base material with plastic material before curing, such as roll coating method, gravure roll coating method, air knife coating method, spinner coating method, continuous coating method, etc. In addition to coating methods, dip coating methods, spray coating methods, etc., methods such as troweling can be used.
（凹凸形成）
上記のようにして基材に硬化前において可塑性
を有する材料を塗工後、塗工面に前記した凹凸形
成用フイルム又はシートを密着するようにして重
ねる。凹凸形成用フイルム又はシートとして全面
に貫通孔を設けてなるものを使用すると凹凸形成
用フイルム又はシートを硬化前に可塑性を有する
材料の塗工面に重ねる際に生じる気泡の抱き込み
は貫通孔を経由して容易に除去出来、望ましい
が、かかる場合においてさえ気泡の抱き込みは出
来るだけ少ない方が望ましく、凹凸フイルム又は
シートの一方から順次密着させて行くよう留意
し、適当な補助具として鏝、ローラー、刷毛など
を用いるとよい。(Formation of unevenness) After coating the base material with a material that has plasticity before curing as described above, the film or sheet for forming unevenness described above is stacked on the coated surface so as to be in close contact with it. If a film or sheet for forming unevenness is used that has through-holes on the entire surface, air bubbles that occur when the film or sheet for forming unevenness is laid on the coated surface of a plastic material before curing will be trapped through the through-holes. However, even in such a case, it is desirable to minimize the amount of air bubbles trapped in the film or sheet. Care should be taken to ensure that the film or sheet is brought into close contact with the uneven film or sheet from one side. Use a trowel or roller as an appropriate auxiliary tool , a brush, etc. may be used.
次に、基材に硬化前において可塑性を有する材
料を塗工後、塗工面に前記した凹凸形成用フイル
ム又はシートを密着するようにして重ねた後、該
凹凸形成用フイルム又はシートの側から前記した
凹凸形成用フイルム又はシートを膨潤させる前記
した溶媒を塗装するが、塗装の方法としては、公
知の方法として、基材に硬化前において可塑性を
有する材料を塗工する方法として挙げた方法のう
ちから適宜選択して用いることができるが、可塑
性を有する材料の表面にフイルム又はシートを重
ねてある比較的軟らかい材料に対して行なうこと
となるため非接触で行なえるスプレーコート法が
望ましいが、この限りではない。 Next, after coating the base material with a material that has plasticity before curing, the above-described unevenness forming film or sheet is stacked on the coated surface so as to be in close contact with the above-mentioned unevenness forming film or sheet. The above-mentioned solvent that swells the unevenness forming film or sheet is coated with the above-described solvent, and the coating method is one of the known methods listed as a method of coating a base material with a plastic material before curing. However, since the coating is applied to a relatively soft material in which a film or sheet is layered on the surface of a plastic material, a spray coating method that can be applied without contact is preferable. Not as long.
上記のようにして溶媒を塗装することにより、
凹凸形成用フイルム又はシートの溶媒による膨潤
して伸びる区域および／又は前記の膨潤して伸び
る区域とは伸びの程度が異なる区域は膨潤して伸
び、しかも伸びた部分におけるフイルム又はシー
トと硬化前において可塑性を有する材料は表面張
力により密着しているため該部分においてフイル
ム又はシートおよび硬化前において可塑性を有す
る材料は共にしわを生じ、結果として凹凸形成用
フイルム又はシートの変形に対応する模様状凹凸
が前記の硬化前において可塑性を有する材料の表
面に生じる。 By applying the solvent as described above,
The area of the unevenness forming film or sheet that swells and stretches with the solvent and/or the area that has a different degree of elongation from the area that swells and stretches, and the film or sheet in the stretched area and before curing. Since the plastic material is in close contact with each other due to surface tension, both the film or sheet and the plastic material before curing will wrinkle, resulting in patterned unevenness corresponding to the deformation of the film or sheet for forming the unevenness. This occurs on the surface of the plastic material before it is cured.
（硬化）
上記のごとく模様状凹凸を生じさせた後、硬化
前において可塑性を有する材料を硬化させる。硬
化の方法としては、前記した硬化前において可塑
性を有する材料を構成する成分によつて異なる
が、各々の成分に適した方法をとり、例えば無機
質系バインダー、半水石膏、セメント等を用いる
場合は水和反応により硬化するため、自然放置す
るか、或いは発熱反応であれば熱を逃げやすくす
る等の手段を構じ、多くの熱可塑性樹脂にあつて
は加熱乾燥によつて溶剤や分散剤を蒸発せしめ、
熱硬化性樹脂にあつては、加熱や紫外線・電子線
により重合硬化させる等の方法によつて硬化さ
せ、硬化後、凹凸形成用フイルム又はシートを剥
離して模様状凹凸を形成するものである。(Curing) After creating the patterned irregularities as described above, the plastic material is hardened before hardening. The curing method differs depending on the components that make up the material that has plasticity before curing, but a method suitable for each component is used. For example, when using an inorganic binder, gypsum hemihydrate, cement, etc. Since it hardens through a hydration reaction, it must be left to stand naturally, or if it is an exothermic reaction, measures must be taken to make it easier for heat to escape.For many thermoplastic resins, solvents and dispersants are removed by heating and drying. evaporate,
In the case of a thermosetting resin, it is cured by a method such as polymerization and curing by heating or ultraviolet rays or electron beams, and after curing, the unevenness forming film or sheet is peeled off to form patterned unevenness. .
なお本発明において前記したごとく硬化前にお
いて可塑性を有する材料に着色しておいてもよ
く、又、模様状凹凸を付与した後に着色してもよ
く、又、谷汚しと呼ばれる凹部に着色する方法
や、凸部を着色する方法をとつてもよく、又、以
上のような方法を適宜組み合わせてもよい。 In addition, in the present invention, as described above, the plastic material may be colored before curing, or it may be colored after giving the patterned unevenness, or there may be a method called trough staining in which the concave portions are colored. , a method of coloring the convex portions may be used, or the above methods may be combined as appropriate.
本発明によれば模様状凹凸を均一に安定的に付
与することが出来、しかも各工程は公知の手段を
使用しうるので複雑な付帯装置や作業は必要とせ
ず、又、発泡剤を使用する際のように材料が限定
されることもないものである。 According to the present invention, it is possible to uniformly and stably provide a patterned unevenness, and since each step can use known means, there is no need for complicated incidental equipment or operations, and there is no need to use a foaming agent. The materials are not limited as in the case of the present invention.
而して本発明によつて得られる製品は極めてユ
ニークで立体感の豊富なものであり、壁、天井等
の内装材および外装材等の建材、各種化粧板、看
板、包装関係等種々の分野に適用でき用途も極め
て広いものである。 The products obtained by the present invention are extremely unique and have a rich three-dimensional effect, and can be used in various fields such as interior materials such as walls and ceilings, building materials such as exterior materials, various decorative boards, signboards, packaging, etc. It can be applied to a wide range of applications.
次に実施例をあげて更に具体的に本発明を説明
する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例 １
厚み30μｍのポリビニールアルコール系フイル
ム（日本合成化学工業(株)製、ハイセロンＤ−103）
の片面にポリウレタン系樹脂をビヒクルとするグ
ラビアインキ（諸星インキ(株)製、ARインキ）を
用い、古代エジプトのレリーフ調壁画模様を模し
て、模様部の版深が50μｍとなるように作成した
グラビア版を用いグラビア印刷にて印刷し、次に
印刷を施した面とは反対側の面に不透水性層とし
て塩化ビニル系樹脂およびポリウレタン系樹脂を
ビヒクルとするインキ（諸星インキ(株)製、ARプ
ライマー）を用いて全面にベタ印刷した。Example 1 Polyvinyl alcohol film with a thickness of 30 μm (manufactured by Nippon Gosei Kagaku Kogyo Co., Ltd., Hi-Selon D-103)
Using gravure ink (manufactured by Moroboshi Ink Co., Ltd., AR ink) with a polyurethane resin vehicle on one side, it was created to imitate the relief-like mural pattern of ancient Egypt, with a printing depth of 50 μm in the patterned area. Gravure printing is performed using a gravure plate, and then an impermeable layer is applied to the opposite side of the printed surface using an ink containing a vinyl chloride resin and a polyurethane resin as a vehicle (Moroboshi Ink Co., Ltd.) The entire surface was printed solidly using AR Primer (manufactured by Manufacturer Co., Ltd., AR Primer).
次に上記のようにして得た印刷フイルムにピツ
チ約５mm、先端径0.2mmの針を一面に植えた針ロ
ールを用い、全面に貫通孔を形成した。 Next, through holes were formed all over the printed film obtained as described above using a needle roll having needles with a pitch of about 5 mm and a tip diameter of 0.2 mm all over the surface.
建築物のコンクリート躯体の外壁垂直面にアク
リル系エマルジヨンをプライマーとしてスポンジ
ロールにて塗布し30分間放置して乾燥した後、下
記組成からなる材料を鏝塗りにて厚みが３mmにな
るよう塗工し、
ポルトランドセメント 100重量部
シリカ 30 〃
水 50 〃
塗工面に前記の貫通孔形成済フイルムを不透水
層と塗工面が接するように重ねた。塗工面の水に
よる凹凸が多少生じるがその程度はごく小さかつ
た。更にフイルム面側から霧吹きを用いて水を全
面に吹きつけた。吹きつけの程度は全面に隅なく
水が塗られ、しかも水が流れ落ちない程度とし
た。水の吹きつけにより印刷模様のない部分のフ
イルムが膨潤してしわを形成し印刷模様のある部
分は平坦なままであり、レリーフ調の模様が形成
された。この後、自然放置してセメントを硬化さ
せ、フイルムを剥離した。 Apply acrylic emulsion as a primer to the vertical surface of the exterior wall of the concrete frame of the building using a sponge roll, leave it to dry for 30 minutes, and then apply the material with the following composition to a thickness of 3 mm using a trowel. , Portland cement 100 parts by weight Silica 30 〃 Water 50 〃 The above-mentioned film with through-holes formed was placed on the coated surface so that the impermeable layer and the coated surface were in contact. Although some unevenness occurred on the coated surface due to water, the extent was very small. Furthermore, water was sprayed onto the entire surface of the film using a sprayer. The degree of spraying was such that the entire surface was coated with water without any corners, and the water did not run off. When sprayed with water, the portions of the film without the printed pattern swelled and wrinkled, while the portions with the printed pattern remained flat, forming a relief-like pattern. Thereafter, the cement was left to harden naturally, and the film was peeled off.
実施例 ２
ポルトランドセメント、シリカ、水のかわりに
石膏、石灰、水からなる石膏系プラスターを用い
て、その他は実施例１と同様にして行ない、実施
例１と同様なレリーフ調の効果を有し、且つ白色
の化粧面を得た。Example 2 A gypsum-based plaster consisting of gypsum, lime, and water was used instead of Portland cement, silica, and water, and the rest was carried out in the same manner as in Example 1, and the same relief-like effect as in Example 1 was obtained. , and a white decorative surface was obtained.
実施例 ３
基材として木片セメント板を用い、以下実施例
１と同様にして行ない、レリーフ調の模様を有す
る化粧木片セメント板を得た。Example 3 Using a wood cement board as a base material, the same procedure as in Example 1 was carried out to obtain a decorative wood cement board having a relief-like pattern.
Claims (1)
の表面に、溶媒により膨潤して伸びる区域と伸び
ない区域および／又は前記の膨潤して伸びる区域
の伸びとは伸びの程度が異なる区域とを設けてな
る凹凸形成用フイルム又はシートを密着させ、次
いで前記凹凸形成用フイルム又はシートの側から
一面に前記凹凸形成用フイルム又はシートを膨潤
させる溶媒を塗装して前記凹凸形成用フイルム又
はシートに変形を生じさせ該変形に対応せる模様
状凹凸を前記の硬化前において可塑性を有する材
料の表面に生じさせた後、前記の硬化前において
可塑性を有する材料を硬化させ、しかる後前記凹
凸形成用フイルム又はシートを剥離することを特
徴とする、模様状凹凸を付与する方法。 ２ 硬化前に可塑性を有する材料は無機質水和硬
化性材料であり、凹凸形成用フイルム又はシート
はその無機質水和硬化性材料に密着する側の表面
の全面に実質的不透水層を設けてなり、溶媒で水
である事を特徴とする事を特徴とする特許請求の
範囲第１項記載の模様状凹凸を付与する方法。 ３ 凹凸形成用フイルム又はシートは全面に微細
な貫通孔を設けてあることを特徴とする特許請求
の範囲第１項又は第２項記載の模様状凹凸を付与
する方法。[Scope of Claims] 1. On the surface of a material that has plasticity before curing, there are regions that swell and stretch with a solvent and regions that do not stretch, and/or the degree of elongation of the region that swells and stretches. A film or sheet for forming unevenness, which has different areas, is brought into close contact with the film or sheet for forming unevenness, and then a solvent for swelling the film or sheet for forming unevenness is applied to one side of the film or sheet for forming unevenness, so that the film for forming unevenness is formed. Alternatively, after deforming the sheet and producing pattern-like unevenness corresponding to the deformation on the surface of the material that has plasticity before curing, hardening the material that has plasticity before curing, and then forming the unevenness. A method for imparting pattern-like unevenness, characterized by peeling off a forming film or sheet. 2. The material that has plasticity before curing is an inorganic hydration-curable material, and the film or sheet for forming irregularities is provided with a substantially water-impermeable layer on the entire surface of the side that is in close contact with the inorganic hydration-curable material. A method for imparting patterned irregularities according to claim 1, characterized in that the solvent is water. 3. The method for imparting patterned unevenness according to claim 1 or 2, wherein the film or sheet for forming unevenness has fine through holes provided over the entire surface.
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8413081A JPS57199618A (en) | 1981-05-30 | 1981-05-30 | Method of giving contoured pattern |
| US06/380,836 US4407881A (en) | 1981-05-30 | 1982-05-21 | Decorative sheets and processes for producing decorative articles by using the same |
| AU84203/82A AU545217B2 (en) | 1981-05-30 | 1982-05-26 | Hydrophilic decorative sheet |
| GB08215581A GB2104445B (en) | 1981-05-30 | 1982-05-27 | Decorative sheets and processes for producing decorative articles using the same |
| DE19823219992 DE3219992A1 (en) | 1981-05-30 | 1982-05-27 | DECORATION PATHS AND METHOD FOR PRODUCING DECORATION PRODUCTS USING THE DECORATION PATHS |
| SE8203317A SE8203317L (en) | 1981-05-30 | 1982-05-28 | DECORATIVE SHEET AND SET FOR MAKING DECORATIVE ARTICLES USING THE SHEET |
| BE2/59727A BE893334A (en) | 1981-05-30 | 1982-05-28 | DECORATIVE SHEETS AND METHODS OF MAKING DECORATIVE ARTICLES USING THE SHEETS |
| IT48527/82A IT1148313B (en) | 1981-05-30 | 1982-05-28 | DECORATIVE SHEETS AND PROCEDURE TO PRODUCE DECORATIVE OBJECTS WITH THEIR USE |
| ES512666A ES8401386A1 (en) | 1981-05-30 | 1982-05-28 | Decorative sheets and processes for producing decorative articles by using the same |
| CA000404010A CA1170122A (en) | 1981-05-30 | 1982-05-28 | Decorative sheets and processes for producing decorative articles by using the same |
| FR8209434A FR2506682B1 (en) | 1981-05-30 | 1982-05-28 | DECORATIVE SHEET AND METHOD FOR MANUFACTURING DECORATIVE OBJECTS USING SUCH SHEET |
| KR8202413A KR870000696B1 (en) | 1981-05-30 | 1982-05-29 | Decorative sheets and method of decorative article using them |
| PH27378A PH18826A (en) | 1981-05-30 | 1982-05-31 | Decorative sheets and processes for producing decorative articles by using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8413081A JPS57199618A (en) | 1981-05-30 | 1981-05-30 | Method of giving contoured pattern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57199618A JPS57199618A (en) | 1982-12-07 |
| JPH0212632B2 true JPH0212632B2 (en) | 1990-03-22 |
Family
ID=13821918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8413081A Granted JPS57199618A (en) | 1981-05-30 | 1981-05-30 | Method of giving contoured pattern |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS57199618A (en) |
| BE (1) | BE893334A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63317577A (en) * | 1987-06-19 | 1988-12-26 | Kanto Auto Works Ltd | Tape for design of coating film |
-
1981
- 1981-05-30 JP JP8413081A patent/JPS57199618A/en active Granted
-
1982
- 1982-05-28 BE BE2/59727A patent/BE893334A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE893334A (en) | 1982-09-16 |
| JPS57199618A (en) | 1982-12-07 |
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