JPH0150324B2 - - Google Patents

Info

Publication number: JPH0150324B2
Authority: JP; Japan
Prior art keywords: titanium; acid esters; compound; polymerization; catalyst component
Prior art date: 1982-06-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP9468282A

Other languages

English (en)

Japanese (ja)

Other versions

JPS58213005A (ja

Inventor

Tadashi Asanuma

Shinryu Uchikawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsui Toatsu Chemicals Inc

Original Assignee

Mitsui Toatsu Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-06-04

Filing date

1982-06-04

Publication date

1989-10-30

1982-06-04 Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc

1982-06-04 Priority to JP9468282A priority Critical patent/JPS58213005A/ja

1983-12-10 Publication of JPS58213005A publication Critical patent/JPS58213005A/ja

1989-10-30 Publication of JPH0150324B2 publication Critical patent/JPH0150324B2/ja

Status Granted legal-status Critical Current

Links

-1 alkoxy silicon compounds Chemical class 0.000 claims description 31
239000010936 titanium Substances 0.000 claims description 30
239000003054 catalyst Substances 0.000 claims description 24
229910052719 titanium Inorganic materials 0.000 claims description 23
238000006116 polymerization reaction Methods 0.000 claims description 18
238000000034 method Methods 0.000 claims description 15
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 14
239000007788 liquid Substances 0.000 claims description 10
150000002148 esters Chemical class 0.000 claims description 9
239000004711 α-olefin Substances 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 7
150000001733 carboxylic acid esters Chemical class 0.000 claims description 6
239000007787 solid Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
239000011777 magnesium Substances 0.000 claims description 5
150000002170 ethers Chemical class 0.000 claims description 4
230000000379 polymerizing effect Effects 0.000 claims description 4
150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
150000008301 phosphite esters Chemical class 0.000 claims description 2
150000003609 titanium compounds Chemical class 0.000 claims description 2
150000001336 alkenes Chemical class 0.000 claims 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 23
230000000694 effects Effects 0.000 description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
229910052723 transition metal Inorganic materials 0.000 description 8
150000003624 transition metals Chemical class 0.000 description 8
230000005484 gravity Effects 0.000 description 6
238000010298 pulverizing process Methods 0.000 description 6
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
239000004743 Polypropylene Substances 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
229920001155 polypropylene Polymers 0.000 description 5
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
239000002002 slurry Substances 0.000 description 4
238000010908 decantation Methods 0.000 description 3
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
238000005406 washing Methods 0.000 description 3
NDQXKKFRNOPRDW-UHFFFAOYSA-N 1,1,1-triethoxyethane Chemical compound CCOC(C)(OCC)OCC NDQXKKFRNOPRDW-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
150000002896 organic halogen compounds Chemical class 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 1
ZMAPKOCENOWQRE-UHFFFAOYSA-N diethoxy(diethyl)silane Chemical compound CCO[Si](CC)(CC)OCC ZMAPKOCENOWQRE-UHFFFAOYSA-N 0.000 description 1
JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002899 organoaluminium compounds Chemical class 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
229920013639 polyalphaolefin Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
BQFPCTXLBRVFJL-UHFFFAOYSA-N triethoxymethylbenzene Chemical compound CCOC(OCC)(OCC)C1=CC=CC=C1 BQFPCTXLBRVFJL-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

JP9468282A 1982-06-04 1982-06-04 アルフア−オレフインの重合方法 Granted JPS58213005A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP9468282A JPS58213005A (ja)	1982-06-04	1982-06-04	アルフア−オレフインの重合方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP9468282A JPS58213005A (ja)	1982-06-04	1982-06-04	アルフア−オレフインの重合方法

Publications (2)

Publication Number	Publication Date
JPS58213005A JPS58213005A (ja)	1983-12-10
JPH0150324B2 true JPH0150324B2 (pl)	1989-10-30

Family

ID=14116976

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP9468282A Granted JPS58213005A (ja)	1982-06-04	1982-06-04	アルフア−オレフインの重合方法

Country Status (1)

Country	Link
JP (1)	JPS58213005A (pl)

1982
- 1982-06-04 JP JP9468282A patent/JPS58213005A/ja active Granted

Also Published As

Publication number	Publication date
JPS58213005A (ja)	1983-12-10

Publication	Publication Date	Title
EP0282929B1 (en)	1993-06-16	Method for producing a propylene-alpha-olefin block copolymer
JPS64404B2 (pl)	1989-01-06
JPH07651B2 (ja)	1995-01-11	オレフイン重合体の製造法
JPH072790B2 (ja)	1995-01-18	α−オレフイン重合体製造方法
JPH0150324B2 (pl)	1989-10-30
JPS64403B2 (pl)	1989-01-06
JPS623163B2 (pl)	1987-01-23
JPS5812889B2 (ja)	1983-03-10	ポリエチレンノセイゾウホウホウ
JPS60152511A (ja)	1985-08-10	α−オレフインの重合法
JPH0149287B2 (pl)	1989-10-24
JPS5835522B2 (ja)	1983-08-03	α↓−オレフィンの立体規則性重合方法
JPH0532404B2 (pl)	1993-05-17
JPS5812886B2 (ja)	1983-03-10	ポリオレフインノセイゾウホウホウ
JPH0145484B2 (pl)	1989-10-03
JPH0830088B2 (ja)	1996-03-27	オレフイン類重合用触媒
JPH0347644B2 (pl)	1991-07-22
JPH0532407B2 (pl)	1993-05-17
EP0366204A2 (en)	1990-05-02	Alkene polymerization process and catalyst compositions therefor
JPH0149163B2 (pl)	1989-10-23
JPS5825083B2 (ja)	1983-05-25	ポリオレフインの製造方法
JP3436319B2 (ja)	2003-08-11	オレフィン類重合用固体触媒成分および触媒
JPH0134446B2 (pl)	1989-07-19
JPH05155922A (ja)	1993-06-22	オレフィン重合体の製造方法
JPS64964B2 (pl)	1989-01-10
JPH0830087B2 (ja)	1996-03-27	オレフイン類重合用触媒