JPH0143780B2 - - Google Patents
Info
- Publication number
- JPH0143780B2 JPH0143780B2 JP7186481A JP7186481A JPH0143780B2 JP H0143780 B2 JPH0143780 B2 JP H0143780B2 JP 7186481 A JP7186481 A JP 7186481A JP 7186481 A JP7186481 A JP 7186481A JP H0143780 B2 JPH0143780 B2 JP H0143780B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- monomer
- parts
- polymerizable
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 claims description 68
- 239000000839 emulsion Substances 0.000 claims description 56
- 229920005989 resin Polymers 0.000 claims description 44
- 239000011347 resin Substances 0.000 claims description 44
- -1 unsaturated alcohol ester Chemical class 0.000 claims description 27
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000008199 coating composition Substances 0.000 claims description 13
- 125000001424 substituent group Chemical group 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 10
- 239000003505 polymerization initiator Substances 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 150000001491 aromatic compounds Chemical class 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 150000005846 sugar alcohols Polymers 0.000 claims description 7
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
- 150000002825 nitriles Chemical class 0.000 claims description 6
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 229920003180 amino resin Polymers 0.000 claims description 5
- 239000010419 fine particle Substances 0.000 claims description 5
- 150000007519 polyprotic acids Polymers 0.000 claims description 5
- 239000003125 aqueous solvent Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000002612 dispersion medium Substances 0.000 claims description 3
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 48
- 238000003756 stirring Methods 0.000 description 33
- 239000008367 deionised water Substances 0.000 description 28
- 229910021641 deionized water Inorganic materials 0.000 description 28
- 239000002253 acid Substances 0.000 description 26
- 238000000576 coating method Methods 0.000 description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 21
- 239000003822 epoxy resin Substances 0.000 description 20
- 229920000647 polyepoxide Polymers 0.000 description 20
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 19
- 239000011248 coating agent Substances 0.000 description 19
- 229960002887 deanol Drugs 0.000 description 19
- 239000000203 mixture Substances 0.000 description 18
- 239000012972 dimethylethanolamine Substances 0.000 description 17
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 15
- 229920001225 polyester resin Polymers 0.000 description 14
- 239000004645 polyester resin Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 11
- 239000003973 paint Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000004090 dissolution Methods 0.000 description 9
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 8
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 8
- 239000004925 Acrylic resin Substances 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 8
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 8
- 239000011259 mixed solution Substances 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 7
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 5
- 229920000180 alkyd Polymers 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229960003080 taurine Drugs 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 239000004711 α-olefin Chemical class 0.000 description 3
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 2
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- 229920003270 Cymel® Polymers 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- RFFFKMOABOFIDF-UHFFFAOYSA-N Pentanenitrile Chemical compound CCCCC#N RFFFKMOABOFIDF-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- LGPAKRMZNPYPMG-UHFFFAOYSA-N (3-hydroxy-2-prop-2-enoyloxypropyl) prop-2-enoate Chemical compound C=CC(=O)OC(CO)COC(=O)C=C LGPAKRMZNPYPMG-UHFFFAOYSA-N 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- JEJIWKKGUFJLAF-UHFFFAOYSA-N 2-(hydroxymethyl)-2-methylpropane-1,3-diol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.OCC(C)(CO)CO JEJIWKKGUFJLAF-UHFFFAOYSA-N 0.000 description 1
- XZWQPQHCWPXUMF-UHFFFAOYSA-N 2-(hydroxymethyl)-2-methylpropane-1,3-diol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.OCC(C)(CO)CO XZWQPQHCWPXUMF-UHFFFAOYSA-N 0.000 description 1
- KANYKVYWMZPGSL-UHFFFAOYSA-N 2-(hydroxymethyl)-2-methylpropane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(C)(CO)CO KANYKVYWMZPGSL-UHFFFAOYSA-N 0.000 description 1
- RGADKZXRWFOTFV-UHFFFAOYSA-N 2-(hydroxymethyl)-2-methylpropane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OCC(C)(CO)CO RGADKZXRWFOTFV-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- CLDPKFWKBZAVLP-UHFFFAOYSA-N 2-[methyl(1-phenylprop-2-enyl)amino]ethanesulfonic acid Chemical compound OS(=O)(=O)CCN(C)C(C=C)C1=CC=CC=C1 CLDPKFWKBZAVLP-UHFFFAOYSA-N 0.000 description 1
- CVUYSVSDCCHRNV-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO CVUYSVSDCCHRNV-UHFFFAOYSA-N 0.000 description 1
- JMWGZSWSTCGVLX-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO JMWGZSWSTCGVLX-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- XNFIEYMGNIUQIF-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO XNFIEYMGNIUQIF-UHFFFAOYSA-N 0.000 description 1
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical compound OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 description 1
- XGJZQNMUVTZITK-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexamethoxy-1,3,5-triazine-2,4,6-triamine Chemical compound CON(OC)C1=NC(N(OC)OC)=NC(N(OC)OC)=N1 XGJZQNMUVTZITK-UHFFFAOYSA-N 0.000 description 1
- CKSURTJJJBWBOU-UHFFFAOYSA-N 3-[(3-amino-3-imino-2-methylpropyl)diazenyl]-2-methylpropanimidamide;hydrochloride Chemical compound Cl.NC(=N)C(C)CN=NCC(C)C(N)=N CKSURTJJJBWBOU-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- OYNZJZVQLMGGLB-UHFFFAOYSA-N C[N+](C)(CC([O-])=O)C(C=C)C1=CC=CC=C1 Chemical compound C[N+](C)(CC([O-])=O)C(C=C)C1=CC=CC=C1 OYNZJZVQLMGGLB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical class CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- ONTAEZSXZGCILH-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)-methoxyamino]methanol Chemical compound CON(CO)C1=NC(N)=NC(N)=N1 ONTAEZSXZGCILH-UHFFFAOYSA-N 0.000 description 1
- GQPVFBDWIUVLHG-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)COC(=O)C(C)=C GQPVFBDWIUVLHG-UHFFFAOYSA-N 0.000 description 1
- CQHKDHVZYZUZMJ-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-prop-2-enoyloxypropyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(CO)COC(=O)C=C CQHKDHVZYZUZMJ-UHFFFAOYSA-N 0.000 description 1
- JUDXBRVLWDGRBC-UHFFFAOYSA-N [2-(hydroxymethyl)-3-(2-methylprop-2-enoyloxy)-2-(2-methylprop-2-enoyloxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(COC(=O)C(C)=C)COC(=O)C(C)=C JUDXBRVLWDGRBC-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- ZDNFTNPFYCKVTB-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,4-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C=C1 ZDNFTNPFYCKVTB-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000003811 finger Anatomy 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000003944 halohydrins Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Description
æ¬çºæã¯æ°èŠãªãšãã«ãžãšã³æš¹èããã®è£œé æ³
ããã³è©²ãšãã«ãžãšã³æš¹èãããŒã¹ãšããå¡æçµ
æç©ã«é¢ããã éåæ§ã¢ãããŒãåç¬ãŸãã¯äºçš®é¡ä»¥äžçµã¿å
ãããŠæ°Žäžã§ä¹³åéåããŠåŸãããé«ååãšãã«
ãžãšã³ã¯ãåæã©ããã¯ã¹ãšãåŒã°ãããšãã«ãž
ãšã³ã®åœ¢ã§æ°Žæ§å¡æãæ¥çå€ãšããŠåºã䜿çšãã
ãŠããããšãã«ãžãšã³ã®å®å®æ§ã¯ä¹³åå€ããã³ä¿
è·ã³ãã€ãã®äœ¿çšéã«ãäŸåãããã®äœ¿çšéã«æ£
æ¯äŸããŠå®å®æ§ãå¢ããäžè¬ã«äœ¿çšãããä¹³åå€
ã¯ãé°ã€ãªã³ãéœã€ãªã³ãŸãã¯éã€ãªã³æ§ã®çé¢
掻æ§å€ã§ãããä¿è·ã³ãã€ãã¯CMCãPVAãã
ãããã·ãšãã«ã»ã«ããŒã¹çã®æ°Žæº¶æ§ããªããŒã§
ãããåŸã€ãŠãããä¹³åå€ããã³ä¿è·ã³ãã€ãã®
ååšã¯ãåæã©ããã¯ã¹å¡æã«ãšã€ãŠå¿ é ã§ã¯ã
ããã也ç¥ããå¡èã«ãšã€ãŠã¯äžçŽç©ã§ãããã
ã®å€éã®ååšã¯å¡èã®æ§èœãç¹ã«èæ°Žæ§ãèåæ§
ã«æªåœ±é¿ãåãŒãããšã¯èªæã§ããã è¿å¹Žå ¬å®³é²æ¢ãäœæ¥ç°å¢ä¿å šãçè³æºãªã©ã®ç€Ÿ
äŒçèŠè«ã«ããææ©æº¶å€ã䜿çšããªãæ°Žç³»å¡æã
çç®ãããããã«ãªã€ããåŸã€ãŠä¹³åéåã®éã«
ä¹³åå€ãŸãã¯ä¿è·ã³ãã€ããšããŠãšãã«ãžãšã³ã®
å®å®åã«åœ¹ç«ã€äžæ¹ãä»æ¹å¡èã«æ®åããŠããã®
æ§èœãäœäžãããããšã®ãªãä¹³åå€ãŸãã¯ä¿è·ã³
ãã€ãã®éçºãæãŸããã æ¬çºæã«ãããŠäžè¬ã«äœ¿çšãããŠããä¹³åå€ãŸ
ãã¯ä¿è·ã³ãã€ãã®ä»£ãã«äœ¿çšããååäžã«åŒ
ããã³è©²ãšãã«ãžãšã³æš¹èãããŒã¹ãšããå¡æçµ
æç©ã«é¢ããã éåæ§ã¢ãããŒãåç¬ãŸãã¯äºçš®é¡ä»¥äžçµã¿å
ãããŠæ°Žäžã§ä¹³åéåããŠåŸãããé«ååãšãã«
ãžãšã³ã¯ãåæã©ããã¯ã¹ãšãåŒã°ãããšãã«ãž
ãšã³ã®åœ¢ã§æ°Žæ§å¡æãæ¥çå€ãšããŠåºã䜿çšãã
ãŠããããšãã«ãžãšã³ã®å®å®æ§ã¯ä¹³åå€ããã³ä¿
è·ã³ãã€ãã®äœ¿çšéã«ãäŸåãããã®äœ¿çšéã«æ£
æ¯äŸããŠå®å®æ§ãå¢ããäžè¬ã«äœ¿çšãããä¹³åå€
ã¯ãé°ã€ãªã³ãéœã€ãªã³ãŸãã¯éã€ãªã³æ§ã®çé¢
掻æ§å€ã§ãããä¿è·ã³ãã€ãã¯CMCãPVAãã
ãããã·ãšãã«ã»ã«ããŒã¹çã®æ°Žæº¶æ§ããªããŒã§
ãããåŸã€ãŠãããä¹³åå€ããã³ä¿è·ã³ãã€ãã®
ååšã¯ãåæã©ããã¯ã¹å¡æã«ãšã€ãŠå¿ é ã§ã¯ã
ããã也ç¥ããå¡èã«ãšã€ãŠã¯äžçŽç©ã§ãããã
ã®å€éã®ååšã¯å¡èã®æ§èœãç¹ã«èæ°Žæ§ãèåæ§
ã«æªåœ±é¿ãåãŒãããšã¯èªæã§ããã è¿å¹Žå ¬å®³é²æ¢ãäœæ¥ç°å¢ä¿å šãçè³æºãªã©ã®ç€Ÿ
äŒçèŠè«ã«ããææ©æº¶å€ã䜿çšããªãæ°Žç³»å¡æã
çç®ãããããã«ãªã€ããåŸã€ãŠä¹³åéåã®éã«
ä¹³åå€ãŸãã¯ä¿è·ã³ãã€ããšããŠãšãã«ãžãšã³ã®
å®å®åã«åœ¹ç«ã€äžæ¹ãä»æ¹å¡èã«æ®åããŠããã®
æ§èœãäœäžãããããšã®ãªãä¹³åå€ãŸãã¯ä¿è·ã³
ãã€ãã®éçºãæãŸããã æ¬çºæã«ãããŠäžè¬ã«äœ¿çšãããŠããä¹³åå€ãŸ
ãã¯ä¿è·ã³ãã€ãã®ä»£ãã«äœ¿çšããååäžã«åŒ
ãåŒãåºãŸãã¯
ãåŒãåº
ïŒåŒäžïŒ²ã¯çœ®æåºãæããããšãããC1ãC6ã®ã¢
ã«ãã¬ã³åºãŸãã¯ããšãã¬ã³åºã§ãããïŒãæã
ã氎溶æ§æš¹èã¯åèšèŠè«ãæºããã°ããã§ãªãã
ããã䜿çšããŠåŸããããšãã«ãžãšã³æš¹èãå¡æ
ãšããŠäœ¿çšããå Žåãå Žåã«ãã€ãŠã¯å¡èã®æ§èœ
ãäžå±€åäžãããã ããã«æ¬çºæã«ããã°ãéåžžã®åå®èœæ§åé
äœãããªãã¡éåãåŸããšãã¬ã³æ§äžé£œåçµåã
ïŒåã ãæããåéäœãä¹³åéåãããŠåŸããã
ãšãã«ãžãšã³æš¹èã«æ¯ããåèšåå®èœæ§åéäœãš
ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšãã¬ã³
æ§äžé£œååºãæããåéäœãšãå ±éåãããããš
ã«ãããåŸãããå¡èã®èæ°Žæ§ãè溶å€æ§ããã³
å æ²¢ãäžå±€é«ããããšãã§ããã æ¬çºæã«ããã°ãåæ£çžã (a) ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšã
ã¬ã³æ§äžé£œååºãæããåéäœã®å°ãªããšãïŒ
çš® (b) åèš(a)以å€ã®éåæ§åéäœã®å°ãªããšãïŒçš®
ãšã®å ±éåäœã®åŸ®ç²åãããªãã åæ£åªãæ°Žæ§æº¶åªãããªãã ç³»å ã«ãååäžã«åŒ
ã«ãã¬ã³åºãŸãã¯ããšãã¬ã³åºã§ãããïŒãæã
ã氎溶æ§æš¹èã¯åèšèŠè«ãæºããã°ããã§ãªãã
ããã䜿çšããŠåŸããããšãã«ãžãšã³æš¹èãå¡æ
ãšããŠäœ¿çšããå Žåãå Žåã«ãã€ãŠã¯å¡èã®æ§èœ
ãäžå±€åäžãããã ããã«æ¬çºæã«ããã°ãéåžžã®åå®èœæ§åé
äœãããªãã¡éåãåŸããšãã¬ã³æ§äžé£œåçµåã
ïŒåã ãæããåéäœãä¹³åéåãããŠåŸããã
ãšãã«ãžãšã³æš¹èã«æ¯ããåèšåå®èœæ§åéäœãš
ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšãã¬ã³
æ§äžé£œååºãæããåéäœãšãå ±éåãããããš
ã«ãããåŸãããå¡èã®èæ°Žæ§ãè溶å€æ§ããã³
å æ²¢ãäžå±€é«ããããšãã§ããã æ¬çºæã«ããã°ãåæ£çžã (a) ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšã
ã¬ã³æ§äžé£œååºãæããåéäœã®å°ãªããšãïŒ
çš® (b) åèš(a)以å€ã®éåæ§åéäœã®å°ãªããšãïŒçš®
ãšã®å ±éåäœã®åŸ®ç²åãããªãã åæ£åªãæ°Žæ§æº¶åªãããªãã ç³»å ã«ãååäžã«åŒ
ãåŒãåºïŒåŒäžïŒ²
ã¯çœ®æåºãæããããšãããC1ãC6ã®ã¢ã«ã
ã¬ã³åºãŸãã¯ããšãã¬ã³åºãã¯âCOOHãŸ
ãã¯âSO3Hã§ãããïŒãæãã氎溶æ§æš¹èã
å«æãããšãã«ãžãšã³æš¹èãæäŸãããã æ¬çºæã®å¥ã®å±é¢ã«ããã°ãåèšã®ãšãã«ãžãš
ã³æš¹èã¯ãéåéå§å€ã®ååšäžãååäžã«åŒ
ã¬ã³åºãŸãã¯ããšãã¬ã³åºãã¯âCOOHãŸ
ãã¯âSO3Hã§ãããïŒãæãã氎溶æ§æš¹èã
å«æãããšãã«ãžãšã³æš¹èãæäŸãããã æ¬çºæã®å¥ã®å±é¢ã«ããã°ãåèšã®ãšãã«ãžãš
ã³æš¹èã¯ãéåéå§å€ã®ååšäžãååäžã«åŒ
ãåŒãåºãŸãã¯
ãåŒãåº
ïŒåŒäžç¬Šå·ã¯åèšã«åããïŒãæãã氎溶æ§æš¹èã
å«ãæ°Žæ§åªäœäžãåèš(a)ããã³(b)ã®åéäœãä¹³å
éåããäž¡è ã®å ±éåäœã®åŸ®ç²åãåæ£çžãšãã
åæ£ç³»ãåŸãããšãããªããšãã«ãžãšã³æš¹èã®è£œ
é æ³ãæäŸãããã ããã«æ¬çºæã«ããã°ãåèšãšãã«ãžãšã³æš¹è
ãããŒã¹ãšããå¡æçµæç©ãæäŸãããã ååäžã«åŒ
å«ãæ°Žæ§åªäœäžãåèš(a)ããã³(b)ã®åéäœãä¹³å
éåããäž¡è ã®å ±éåäœã®åŸ®ç²åãåæ£çžãšãã
åæ£ç³»ãåŸãããšãããªããšãã«ãžãšã³æš¹èã®è£œ
é æ³ãæäŸãããã ããã«æ¬çºæã«ããã°ãåèšãšãã«ãžãšã³æš¹è
ãããŒã¹ãšããå¡æçµæç©ãæäŸãããã ååäžã«åŒ
ãåŒãåºãŸãã¯
ãåŒãåºïŒç¬Šå·ã«åèšã«åããïŒãæ
ãã氎溶æ§æš¹èã®äŸã«ã¯ããããåºãæããã¢ã«
ããæš¹èãããªãšã¹ãã«æš¹èãå€æ§ãšããã·æš¹
èãã¢ã¯ãªã«æš¹èãã¡ã©ãã³æš¹èãããªãšãŒãã«
æš¹èãªã©ãããã äžèšåŒ
ããæš¹èãããªãšã¹ãã«æš¹èãå€æ§ãšããã·æš¹
èãã¢ã¯ãªã«æš¹èãã¡ã©ãã³æš¹èãããªãšãŒãã«
æš¹èãªã©ãããã äžèšåŒ
ãåŒãåºãŸãã¯
ãåŒãåºã¯äž¡æ§ã€ãªã³æ§åºã§ãã€ãŠã
ãã®ãããªäž¡ã€ãªã³æ§åºãæã€æš¹èã¯åå¿æ§ãç
é¢æŽ»æ§ãé»æ°ååŠçæ§è³ªçã«ãããŠç¹ç°ãªæåã
瀺ãã ãã®ãããªäž¡ã€ãªã³æ§åºãååå ã«æããã¢ã«
ããæš¹èããã³ãªã€ã«ããªãŒããªãšã¹ãã«æš¹èã«
ã€ããŠã¯ãæ¬çºæãã®ç¹é¡æ54â110865å·ããã³
ç¹é¡æ55â56048å·ã«èšèŒãããŠãããã¢ã«ãã
æš¹èããã³ããªãšã¹ãã«æš¹èã¯ãå¿ é ã®æåãšã
ãŠå€å¡©åºé žãšå€äŸ¡ã¢ã«ã³ãŒã«ã䜿çšããŠé£ç¶ãã
ãšã¹ãã«é£éãçæãããããšãç¹åŸŽãšãããã
å€äŸ¡ã¢ã«ã³ãŒã«æåã®äžéšããåŒ ïŒåŒäžR1ã¯å°ãªããšãïŒåã®ããããã·ã«åºã
æããã¢ã«ãã«åºãR2ããã³R3ã¯åäžãŸãã¯ç°
ãªã€ãŠãæ°ŽçŽ ãããŸãã¯çœ®æåºãæããããšãã
ãã¢ã«ãã«åºãã¯çœ®æåºãæããããšããã
C1ãC6ã®ã¢ã«ãã¬ã³åºãããã¯ããšãã¬ã³åºã§
ãããïŒã§çœ®ãæããããšã«ããåèšã®äž¡ã€ãªã³
æ§åºãæããã¢ã«ããæš¹èãŸãã¯ããªãšã¹ãã«æš¹
èã補é ããããšãã§ããã詳现ã«ã€ããŠã¯ååº
ã®æ¬çºæè ãã®ç¹é¡æ54â110865ãåæ55â
11865åç §ã æ¬çºæã§ã¯ãããäž¡ã€ãªã³æ§åºãæããã¢ã«ã
ããŸãã¯ããªãšã¹ãã«æš¹èã®ãã¡ãé žäŸ¡ã30ã
150ãç¹ã«40ã150ãæ°å¹³åååéã500ã5000ã
ç¹ã«700ã3000ã§ãããã®ã䜿çšããã®ã奜ãŸã
ãã åŒ
é¢æŽ»æ§ãé»æ°ååŠçæ§è³ªçã«ãããŠç¹ç°ãªæåã
瀺ãã ãã®ãããªäž¡ã€ãªã³æ§åºãååå ã«æããã¢ã«
ããæš¹èããã³ãªã€ã«ããªãŒããªãšã¹ãã«æš¹èã«
ã€ããŠã¯ãæ¬çºæãã®ç¹é¡æ54â110865å·ããã³
ç¹é¡æ55â56048å·ã«èšèŒãããŠãããã¢ã«ãã
æš¹èããã³ããªãšã¹ãã«æš¹èã¯ãå¿ é ã®æåãšã
ãŠå€å¡©åºé žãšå€äŸ¡ã¢ã«ã³ãŒã«ã䜿çšããŠé£ç¶ãã
ãšã¹ãã«é£éãçæãããããšãç¹åŸŽãšãããã
å€äŸ¡ã¢ã«ã³ãŒã«æåã®äžéšããåŒ ïŒåŒäžR1ã¯å°ãªããšãïŒåã®ããããã·ã«åºã
æããã¢ã«ãã«åºãR2ããã³R3ã¯åäžãŸãã¯ç°
ãªã€ãŠãæ°ŽçŽ ãããŸãã¯çœ®æåºãæããããšãã
ãã¢ã«ãã«åºãã¯çœ®æåºãæããããšããã
C1ãC6ã®ã¢ã«ãã¬ã³åºãããã¯ããšãã¬ã³åºã§
ãããïŒã§çœ®ãæããããšã«ããåèšã®äž¡ã€ãªã³
æ§åºãæããã¢ã«ããæš¹èãŸãã¯ããªãšã¹ãã«æš¹
èã補é ããããšãã§ããã詳现ã«ã€ããŠã¯ååº
ã®æ¬çºæè ãã®ç¹é¡æ54â110865ãåæ55â
11865åç §ã æ¬çºæã§ã¯ãããäž¡ã€ãªã³æ§åºãæããã¢ã«ã
ããŸãã¯ããªãšã¹ãã«æš¹èã®ãã¡ãé žäŸ¡ã30ã
150ãç¹ã«40ã150ãæ°å¹³åååéã500ã5000ã
ç¹ã«700ã3000ã§ãããã®ã䜿çšããã®ã奜ãŸã
ãã åŒ
ãåŒãåºãŸãã¯
ãåŒã
åºïŒç¬Šå·ã¯åèšã«åããïŒãååäžã«æããå€æ§
ãšããã·æš¹èã¯ãæ¬çºæè ãã®ç¹é¡æ55â116293
å·ã«èšèŒãããŠãããäžè¬ã«ãšããã·æš¹èã¯ãæ«
端ã«åŒ ïŒR4ãR5ã¯æ°ŽçŽ ãã¡ãã«åºïŒãæããã®ãç¹åŸŽ
ã§ãããã該æ«ç«¯åºã«åŒ R6âNHââSO3M ïŒïŒ ïŒåŒäžR4ã¯ãšããã·åºãšåå¿ããªã眮æåºãæ
ããããšãããã¢ã«ãã«åºãïŒã¯ã¢ã«ã«ãªéå±ãŸ
ãã¯ã¢ã³ã¢ããŠã åºãã¯åèšã«åããïŒã®åå
ç©ãåå¿ãããããšã«ãã€ãŠãªãã·ã©ã³ç°ãéè£
ããã該ãšããã·æš¹èã®æ«ç«¯åºã®äžéšãåŒ ïŒåŒäžç¬Šå·ã¯åèšã«åããïŒãšãªã€ãå€æ§ãšãã
ã·æš¹èãåŸãããããšããã·æš¹èã®åèšåŒïŒïŒ
ã®äž¡ã€ãªã³æ§åºã®çœ®æåºã«æ¯äŸããŠãå€æ§ãšãã
ã·æš¹èã®èŠªæ°Žæ§ãé«ãŸãã詳现ã«ã€ããŠã¯ååºã®
ç¹é¡æ55â116293å·ãåç §ã åŒ
ãšããã·æš¹èã¯ãæ¬çºæè ãã®ç¹é¡æ55â116293
å·ã«èšèŒãããŠãããäžè¬ã«ãšããã·æš¹èã¯ãæ«
端ã«åŒ ïŒR4ãR5ã¯æ°ŽçŽ ãã¡ãã«åºïŒãæããã®ãç¹åŸŽ
ã§ãããã該æ«ç«¯åºã«åŒ R6âNHââSO3M ïŒïŒ ïŒåŒäžR4ã¯ãšããã·åºãšåå¿ããªã眮æåºãæ
ããããšãããã¢ã«ãã«åºãïŒã¯ã¢ã«ã«ãªéå±ãŸ
ãã¯ã¢ã³ã¢ããŠã åºãã¯åèšã«åããïŒã®åå
ç©ãåå¿ãããããšã«ãã€ãŠãªãã·ã©ã³ç°ãéè£
ããã該ãšããã·æš¹èã®æ«ç«¯åºã®äžéšãåŒ ïŒåŒäžç¬Šå·ã¯åèšã«åããïŒãšãªã€ãå€æ§ãšãã
ã·æš¹èãåŸãããããšããã·æš¹èã®åèšåŒïŒïŒ
ã®äž¡ã€ãªã³æ§åºã®çœ®æåºã«æ¯äŸããŠãå€æ§ãšãã
ã·æš¹èã®èŠªæ°Žæ§ãé«ãŸãã詳现ã«ã€ããŠã¯ååºã®
ç¹é¡æ55â116293å·ãåç §ã åŒ
ãåŒãåºãŸãã¯
ãåŒã
åºïŒç¬Šå·ã¯åèšã«åããïŒãååäžã«æããã¢ã¯
ãªã«æš¹èã«ã€ããŠã¯ãæ¬çºæè ãã®ç¹é¡æ53â
123899å·ãç¹é¡æ53â125996å·ãç¹é¡æ55â
47651å·ããã³ç¹é¡æ55â47652å·ã«èšèŒãããŠã
ãåŒã ãåŒäžãR7ã»R8ã»R9ã»R10ã¯ããããã»CH3ã»
C2H5ã®ããããã§ãããR11ã¯ïŒšãããŸãã¯éäž
ã«âSOâåºãâCOOâåºãââåºã®ããããã
å«ãã§ããããšãããC1ãC20ã®ã¢ã«ãã«åºã§ã
ããR12ã¯âOHåºãâSHåºãâSR13åºïŒR13ã¯C1
ãC4ã®ã¢ã«ãã«åºïŒã®ããããã§çœ®æãããŠã
ãããšããããããŠïŒåãããã¯è€æ°åã®C1ã
C4ã®ã¢ã«ãã«åºã§çœ®æãããŠããããšãããC1
ãC12ã®ã¢ã«ãã¬ã³åºã§ãããã¯COOHåºãŸã
ã¯SO3Håºã§ãããã ãŸãã¯åŒã ãåŒäžãR14ã»R15ã»R16ã¯ãããããŸãã¯C1ã
C6ã®ã¢ã«ãã«åºã§ãããR17ã¯ïŒšããéäžã«âSO
âåºãâCOOâåºãââåºã®ãããããå«ãã§
ããããšãããC1ãC20ã®ã¢ã«ãã«åºãããŸãã¯
ãªã«æš¹èã«ã€ããŠã¯ãæ¬çºæè ãã®ç¹é¡æ53â
123899å·ãç¹é¡æ53â125996å·ãç¹é¡æ55â
47651å·ããã³ç¹é¡æ55â47652å·ã«èšèŒãããŠã
ãåŒã ãåŒäžãR7ã»R8ã»R9ã»R10ã¯ããããã»CH3ã»
C2H5ã®ããããã§ãããR11ã¯ïŒšãããŸãã¯éäž
ã«âSOâåºãâCOOâåºãââåºã®ããããã
å«ãã§ããããšãããC1ãC20ã®ã¢ã«ãã«åºã§ã
ããR12ã¯âOHåºãâSHåºãâSR13åºïŒR13ã¯C1
ãC4ã®ã¢ã«ãã«åºïŒã®ããããã§çœ®æãããŠã
ãããšããããããŠïŒåãããã¯è€æ°åã®C1ã
C4ã®ã¢ã«ãã«åºã§çœ®æãããŠããããšãããC1
ãC12ã®ã¢ã«ãã¬ã³åºã§ãããã¯COOHåºãŸã
ã¯SO3Håºã§ãããã ãŸãã¯åŒã ãåŒäžãR14ã»R15ã»R16ã¯ãããããŸãã¯C1ã
C6ã®ã¢ã«ãã«åºã§ãããR17ã¯ïŒšããéäžã«âSO
âåºãâCOOâåºãââåºã®ãããããå«ãã§
ããããšãããC1ãC20ã®ã¢ã«ãã«åºãããŸãã¯
ãåŒãåºã§ãããR18ã¯ïŒåã
ããã¯è€æ°åã®C1ãC6ã®ã¢ã«ãã«åºã§çœ®æãã
ãŠããããšãããC2ãC12ã®ã¢ã«ãã¬ã³åºã§ã
ããã ãŸãã¯åŒã ãåŒäžãR19ã»R20ã»R21ã¯ããããåäžãããã¯
ç°ãªã€ãŠïŒšãŸãã¯CH3ãR22ã¯å°ãªããšãïŒåã®
ããããã·ã«åºãæãã¢ã«ãã«éªšæ Œäžã«ââã
ããã¯âCOOâãå«ãããšãããççŽ æ°ïŒã20
ã®ã¢ã«ãã«åºãR23ã¯å°ãªããšãïŒåã®ãããã
ã·ã«åºãæãã¢ã«ãã«éªšæ Œäžã«ââãããã¯â
COOâãå«ãããšãããççŽ æ°ïŒã20ã®ã¢ã«ã
ã«åºãŸãã¯ïŒšãããã¯ççŽ æ°ïŒã20ã®ã¢ã«ãã«
åºãR24ã¯åºæ¬çã«ã¯ïŒCH2ïŒoïŒïœã¯ïŒãïŒïŒã§
è¡šããã眮æãããŠããããšãããã¢ã«ãã¬ã³
åºãããã³ïŒ¡ã¯CO2ãŸãã¯SO3ã§ãããã ãŸãã¯åŒã ãåŒäžãR25ã»R26ã»R27ã¯ããããåäžãããã¯
ç°ãªã€ãŠïŒšãŸãã¯CH3ãR28ã»R29ã¯ããããåäž
ãããã¯ç°ãªã€ãŠççŽ æ°ïŒã20ã®ââãããã¯
âCOOâãå«ãããšãããã¢ã«ãã«åºãããã¯
ã·ã¯ãã¢ã«ãã«åºãŸãã¯R28ãšR29ãçµåããŠïŒ®
ååãå«ããããç°ã圢æãããã®ãR30ã¯åºæ¬
çã«ã¯ïŒCH2ïŒïœïŒïœã¯ïŒãïŒïŒã§è¡šããã眮æ
ãããŠããããšãããã¢ã«ãã¬ã³åºãããã³ïŒ¡ã¯
CO2ãŸãã¯SO3ã§ãããã ã®éåæ§ã¢ããé žååç©ã®çŸ€ããéžã°ããå°ãªã
ãšãïŒçš®ãšã èŠããã°ãããããã·ã«åºå«æåéäœãã«ã«ã
ãã·ã«åºå«æåéäœãã°ãªã·ãžã«åºå«æåéäœã
ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒãã
å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒããéåæ§ã¢ãããéåæ§ãããªã«ãéåæ§è³
éŠæååç©ãαâãªã¬ãã€ã³ååç©ãããã«åå
ç©ããã³ãžãšã³ååç©ããæ§æãããéåæ§åé
äœã®çŸ€ããéžã°ããå°ãªããšãïŒçš®ãšãéåžžã®ã©
ãžã«ã«éåæ³ã«åŸã€ãŠææ©æº¶åªäžã§æº¶æ¶²éåãã
ããšã«ãã€ãŠè£œé ãããã äžèšã®éåæ§ã¢ããé žååç©ã®è©³çŽ°ã«ã€ããŠ
ã¯ãååºã®æ¬çºæè ãã®ç¹é¡æ53â123899ãåæ
53â125996ãåæ55â47651ãåæ55â47652å
ç §ã äž¡ã€ãªã³æ§åºãæããã¢ã¯ãªã«æš¹èã®è£œé ã«çš
ããããšã®ã§ããäžèšä»ã®éåæ§åéäœãšããŠ
ã¯ããšãã¬ã³æ§äºéçµåãæããéåžžã®ãã®ã§ã
ã€ãŠãããå ·äœçã«ã¯ä»¥äžã®ãã®ãæããããã ããããã·ã«åºå«æåéäœãå ·äœäŸãšããŠ
ã¯ãïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒãããã
ããã·ãããã«ã¢ã¯ãªã¬ãŒããïŒâããããã·
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããããããã·ãããã«ã¡
ã¿ã¯ãªã¬ãŒããããããã·ããã«ã¢ã¯ãªã¬ãŒ
ããããããã·ããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«
ã¢ã«ã³ãŒã«ãã¡ã¿ã¢ãªã«ã¢ã«ã³ãŒã«çãå å«ã
ããã ã«ã«ããã·ã«åºå«æåéäœãå ·äœäŸãšããŠ
ã¯ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žã
ã€ã¿ã³ã³é žããã¬ã€ã³é žãããã«é žããããã®
èªå°äœçãå å«ãããã ã°ãªã·ãžã«åºå«æåéäœãå ·äœäŸãšããŠã¯ã
ã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãª
ã¬ãŒãçãå å«ãããã ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒ
ããå ·äœäŸãšããŠã¯ãã¡ãã«ã¢ã¯ãªã¬ãŒããã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœ
âããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬
ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒãçãå
å«ãããã å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯
ãªã¬ãŒããå ·äœäŸãšããŠã¯ãïŒïŒ®âãžã¡ãã«
ã¢ãããšãã«ã¢ã¯ãªããŒããïŒïŒ®âãžã¡ãã«
ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãçãå å«ãããã éåæ§ã¢ãããå ·äœäŸãšããŠã¯ãã¢ã¯ãªã«é ž
ã¢ãããã¡ã¿ã¯ãªã«é žã¢ãããïœâãããã·ã¡
ãã«ã¢ã¯ãªã«ã¢ããçãå å«ãããã éåæ§ãããªã«ãå ·äœäŸãšããŠã¯ãã¢ã¯ãªã
ãããªã«ãã¡ã¿ã¯ãªããããªã«çãå å«ãã
ãã éåæ§è³éŠæååç©ãå ·äœäŸãšããŠã¯ãã¹ã
ã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãããã«ãã«ãšã³ã
ïœâããã«ã¹ãã¬ã³çãå å«ãããã αâãªã¬ãã€ã³ååç©ãå ·äœäŸãšããŠã¯ããš
ãã¬ã³ããããã¬ã³çãå å«ãããã ããã«ååç©ãå ·äœäŸãšããŠã¯ãé ¢é žãã
ã«ãããããªã³é žããã«çãå å«ãããã ãžãšã³ååç©ãå ·äœäŸãšããŠã¯ããã¿ãžãš
ã³ãã€ãœãã¬ã³çãå å«ãããã ãããã®ä»ã®éåæ§åéäœïŒãïŒã®ïŒçš®ã
ããã¯ïŒçš®ä»¥äžã®æ··åç©ã§å¿ èŠã«å¿ããŠäœ¿çšã«äŸ
ããã ä»ã®éåæ§åéäœã䜿çšããå Žåã®äžèšéåæ§
ã¢ããé žååç©ã®äœ¿çšå²åã¯ãåœè©²æº¶æ¶²åéåæš¹
èã®ç¹æ§ã«å¿ããŠé©å®å€åãããŠããéåžžå šåé
äœäž0.1ã50ïŒ ïŒééïŒ ã以äžåæ§ïŒå¥œãŸããã¯
0.2ã30ïŒ ã®ç¯å²ã§éžå®ãããŠããã0.1ïŒ æªæºã§
ãããšéåæ§ã¢ããé žååç©ã®è«žç¹æ§ãçºæ®ãã
ãããŸã50ïŒ ãè¶ãããšå¡èã®èæ°Žæ§ãäœäžãã
åŸåã«ããã äžèšæº¶æ¶²éåã«äœ¿çšããéåéå§å€ãšããŠã¯ã
éåžžã®ãã®ã䜿çšãããŠãããäŸãã°éé žåãã³
ãŸã€ã«ããžâïœâããã«ãã«ãªãã·ããã¯ã¡ã³ã
ã€ãããã«ãªãã·ããªã©ã®éé žåç©ãã¢ãŸãã¹ã€
ãœããããããªã«ãïŒïŒ2â²âã¢ãŸãã¹âïŒïŒïŒïŒ
âãžã¡ãã«ïŒãã¬ããããªã«ãïŒïŒ4â²âã¢ãŸãã¹
âïŒâã·ã¢ããã¬ãªãã¯é žãªã©ã®ã¢ãŸååç©çã
æãããããããã®ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··å
ç©ã§äœ¿çšã«äŸããã䜿çšéã¯ãéåžžå šåéäœã«å¯Ÿ
ããŠ0.05ãïŒïŒ ã奜ãŸããã¯0.1ãïŒïŒ ã®ç¯å²ã§
éžå®ãããŠããã䜿çšã«éããŠã¯ããã®å šéšãå
éäœäžã«æ··åšãããŠãããããŸããã®äžéšããã
ã¯å šéšãææ©æº¶åªäžã«æ··åšãããŠããããæŽã«ã
éåžžã®é£é移åå€ïŒäŸãã°ã©ãŠãªã«ã¡ã«ã«ãã¿
ã³ãããã·ã«ã¡ã«ã«ãã¿ã³ãªã©ã®ã¡ã«ã«ãã¿ã³
é¡ïŒãé©é䜿çšãããŠããã äžèšææ©æº¶åªãšããŠã¯ãéåžžã®ãã®ã䜿çšãã
ãŠãããäŸãã°C1ãC6ã®ã¢ã«ã³ãŒã«é¡ããšãã«
ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒã«ãªã©ã®ãžãªãŒã«
é¡ãã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡ãã«ã€ãœ
ããã«ã±ãã³ãªã©ã®ã±ãã³é¡ããšãã¬ã³ã°ãªã³ãŒ
ã«ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ãšãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«
ãšãŒãã«ãïŒâã¡ãã«âïŒâã¡ããã·ãã¿ããŒã«
ãªã©ã®ãšãŒãã«ã¢ã«ã³ãŒã«é¡ããã®ä»äžè¬ã®å¡æ
çšæº¶åªãšããŠãã·ã¬ã³ããã«ãšã³çãæãããã
ãããã®ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ã§äœ¿çšã«
äŸããã äžèšæº¶æ¶²éåã¯ãéåžžã®ã©ãžã«ã«éåæ³ã«åŸã€
ãŠå®æœãããŠãããäŸãã°äžèšéåéå§å€ã®ååš
äžãææ©æº¶åªäžã«æå®ã®éå枩床ïŒéåžž40ã250
âïŒã«ãŠå šåéäœãäžæ¬æ··åããŠåå¿ããããã
ãŸãã¯äºãäžèšéå枩床ã«èšå®ããææ©æº¶åªäžã«
å šåéäœã滎äžãã€ã€åå¿ããã次ãã§èŠããã°
çæããã°ãããéåæéã¯ãéåžž0.5ã20æé
ãæ¡çšããã ãã®ããã«ããŠåŸããã溶液åéåæš¹èã¯ãšã
ãã¬ãŒã¿ãŒãçšããŠè±æº¶åªãã䜿çšã«äŸãããã æ¬çºæã§ã¯ããããäž¡ã€ãªã³æ§åºãæããã¢ã¯
ãªã«æš¹èã®ãã¡ãé žäŸ¡ã30ã180ãç¹ã«40ã160ã
æ°å¹³åååéã500ã10000ãç¹ã«700ã6000ã§ã
ããã®ã䜿çšããã®ã奜ãŸããã åŒ
ãŠããããšãããC2ãC12ã®ã¢ã«ãã¬ã³åºã§ã
ããã ãŸãã¯åŒã ãåŒäžãR19ã»R20ã»R21ã¯ããããåäžãããã¯
ç°ãªã€ãŠïŒšãŸãã¯CH3ãR22ã¯å°ãªããšãïŒåã®
ããããã·ã«åºãæãã¢ã«ãã«éªšæ Œäžã«ââã
ããã¯âCOOâãå«ãããšãããççŽ æ°ïŒã20
ã®ã¢ã«ãã«åºãR23ã¯å°ãªããšãïŒåã®ãããã
ã·ã«åºãæãã¢ã«ãã«éªšæ Œäžã«ââãããã¯â
COOâãå«ãããšãããççŽ æ°ïŒã20ã®ã¢ã«ã
ã«åºãŸãã¯ïŒšãããã¯ççŽ æ°ïŒã20ã®ã¢ã«ãã«
åºãR24ã¯åºæ¬çã«ã¯ïŒCH2ïŒoïŒïœã¯ïŒãïŒïŒã§
è¡šããã眮æãããŠããããšãããã¢ã«ãã¬ã³
åºãããã³ïŒ¡ã¯CO2ãŸãã¯SO3ã§ãããã ãŸãã¯åŒã ãåŒäžãR25ã»R26ã»R27ã¯ããããåäžãããã¯
ç°ãªã€ãŠïŒšãŸãã¯CH3ãR28ã»R29ã¯ããããåäž
ãããã¯ç°ãªã€ãŠççŽ æ°ïŒã20ã®ââãããã¯
âCOOâãå«ãããšãããã¢ã«ãã«åºãããã¯
ã·ã¯ãã¢ã«ãã«åºãŸãã¯R28ãšR29ãçµåããŠïŒ®
ååãå«ããããç°ã圢æãããã®ãR30ã¯åºæ¬
çã«ã¯ïŒCH2ïŒïœïŒïœã¯ïŒãïŒïŒã§è¡šããã眮æ
ãããŠããããšãããã¢ã«ãã¬ã³åºãããã³ïŒ¡ã¯
CO2ãŸãã¯SO3ã§ãããã ã®éåæ§ã¢ããé žååç©ã®çŸ€ããéžã°ããå°ãªã
ãšãïŒçš®ãšã èŠããã°ãããããã·ã«åºå«æåéäœãã«ã«ã
ãã·ã«åºå«æåéäœãã°ãªã·ãžã«åºå«æåéäœã
ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒãã
å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒããéåæ§ã¢ãããéåæ§ãããªã«ãéåæ§è³
éŠæååç©ãαâãªã¬ãã€ã³ååç©ãããã«åå
ç©ããã³ãžãšã³ååç©ããæ§æãããéåæ§åé
äœã®çŸ€ããéžã°ããå°ãªããšãïŒçš®ãšãéåžžã®ã©
ãžã«ã«éåæ³ã«åŸã€ãŠææ©æº¶åªäžã§æº¶æ¶²éåãã
ããšã«ãã€ãŠè£œé ãããã äžèšã®éåæ§ã¢ããé žååç©ã®è©³çŽ°ã«ã€ããŠ
ã¯ãååºã®æ¬çºæè ãã®ç¹é¡æ53â123899ãåæ
53â125996ãåæ55â47651ãåæ55â47652å
ç §ã äž¡ã€ãªã³æ§åºãæããã¢ã¯ãªã«æš¹èã®è£œé ã«çš
ããããšã®ã§ããäžèšä»ã®éåæ§åéäœãšããŠ
ã¯ããšãã¬ã³æ§äºéçµåãæããéåžžã®ãã®ã§ã
ã€ãŠãããå ·äœçã«ã¯ä»¥äžã®ãã®ãæããããã ããããã·ã«åºå«æåéäœãå ·äœäŸãšããŠ
ã¯ãïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒãããã
ããã·ãããã«ã¢ã¯ãªã¬ãŒããïŒâããããã·
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããããããã·ãããã«ã¡
ã¿ã¯ãªã¬ãŒããããããã·ããã«ã¢ã¯ãªã¬ãŒ
ããããããã·ããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«
ã¢ã«ã³ãŒã«ãã¡ã¿ã¢ãªã«ã¢ã«ã³ãŒã«çãå å«ã
ããã ã«ã«ããã·ã«åºå«æåéäœãå ·äœäŸãšããŠ
ã¯ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žã
ã€ã¿ã³ã³é žããã¬ã€ã³é žãããã«é žããããã®
èªå°äœçãå å«ãããã ã°ãªã·ãžã«åºå«æåéäœãå ·äœäŸãšããŠã¯ã
ã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãª
ã¬ãŒãçãå å«ãããã ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒ
ããå ·äœäŸãšããŠã¯ãã¡ãã«ã¢ã¯ãªã¬ãŒããã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœ
âããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬
ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒãçãå
å«ãããã å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯
ãªã¬ãŒããå ·äœäŸãšããŠã¯ãïŒïŒ®âãžã¡ãã«
ã¢ãããšãã«ã¢ã¯ãªããŒããïŒïŒ®âãžã¡ãã«
ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãçãå å«ãããã éåæ§ã¢ãããå ·äœäŸãšããŠã¯ãã¢ã¯ãªã«é ž
ã¢ãããã¡ã¿ã¯ãªã«é žã¢ãããïœâãããã·ã¡
ãã«ã¢ã¯ãªã«ã¢ããçãå å«ãããã éåæ§ãããªã«ãå ·äœäŸãšããŠã¯ãã¢ã¯ãªã
ãããªã«ãã¡ã¿ã¯ãªããããªã«çãå å«ãã
ãã éåæ§è³éŠæååç©ãå ·äœäŸãšããŠã¯ãã¹ã
ã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãããã«ãã«ãšã³ã
ïœâããã«ã¹ãã¬ã³çãå å«ãããã αâãªã¬ãã€ã³ååç©ãå ·äœäŸãšããŠã¯ããš
ãã¬ã³ããããã¬ã³çãå å«ãããã ããã«ååç©ãå ·äœäŸãšããŠã¯ãé ¢é žãã
ã«ãããããªã³é žããã«çãå å«ãããã ãžãšã³ååç©ãå ·äœäŸãšããŠã¯ããã¿ãžãš
ã³ãã€ãœãã¬ã³çãå å«ãããã ãããã®ä»ã®éåæ§åéäœïŒãïŒã®ïŒçš®ã
ããã¯ïŒçš®ä»¥äžã®æ··åç©ã§å¿ èŠã«å¿ããŠäœ¿çšã«äŸ
ããã ä»ã®éåæ§åéäœã䜿çšããå Žåã®äžèšéåæ§
ã¢ããé žååç©ã®äœ¿çšå²åã¯ãåœè©²æº¶æ¶²åéåæš¹
èã®ç¹æ§ã«å¿ããŠé©å®å€åãããŠããéåžžå šåé
äœäž0.1ã50ïŒ ïŒééïŒ ã以äžåæ§ïŒå¥œãŸããã¯
0.2ã30ïŒ ã®ç¯å²ã§éžå®ãããŠããã0.1ïŒ æªæºã§
ãããšéåæ§ã¢ããé žååç©ã®è«žç¹æ§ãçºæ®ãã
ãããŸã50ïŒ ãè¶ãããšå¡èã®èæ°Žæ§ãäœäžãã
åŸåã«ããã äžèšæº¶æ¶²éåã«äœ¿çšããéåéå§å€ãšããŠã¯ã
éåžžã®ãã®ã䜿çšãããŠãããäŸãã°éé žåãã³
ãŸã€ã«ããžâïœâããã«ãã«ãªãã·ããã¯ã¡ã³ã
ã€ãããã«ãªãã·ããªã©ã®éé žåç©ãã¢ãŸãã¹ã€
ãœããããããªã«ãïŒïŒ2â²âã¢ãŸãã¹âïŒïŒïŒïŒ
âãžã¡ãã«ïŒãã¬ããããªã«ãïŒïŒ4â²âã¢ãŸãã¹
âïŒâã·ã¢ããã¬ãªãã¯é žãªã©ã®ã¢ãŸååç©çã
æãããããããã®ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··å
ç©ã§äœ¿çšã«äŸããã䜿çšéã¯ãéåžžå šåéäœã«å¯Ÿ
ããŠ0.05ãïŒïŒ ã奜ãŸããã¯0.1ãïŒïŒ ã®ç¯å²ã§
éžå®ãããŠããã䜿çšã«éããŠã¯ããã®å šéšãå
éäœäžã«æ··åšãããŠãããããŸããã®äžéšããã
ã¯å šéšãææ©æº¶åªäžã«æ··åšãããŠããããæŽã«ã
éåžžã®é£é移åå€ïŒäŸãã°ã©ãŠãªã«ã¡ã«ã«ãã¿
ã³ãããã·ã«ã¡ã«ã«ãã¿ã³ãªã©ã®ã¡ã«ã«ãã¿ã³
é¡ïŒãé©é䜿çšãããŠããã äžèšææ©æº¶åªãšããŠã¯ãéåžžã®ãã®ã䜿çšãã
ãŠãããäŸãã°C1ãC6ã®ã¢ã«ã³ãŒã«é¡ããšãã«
ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒã«ãªã©ã®ãžãªãŒã«
é¡ãã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡ãã«ã€ãœ
ããã«ã±ãã³ãªã©ã®ã±ãã³é¡ããšãã¬ã³ã°ãªã³ãŒ
ã«ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ãšãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«
ãšãŒãã«ãïŒâã¡ãã«âïŒâã¡ããã·ãã¿ããŒã«
ãªã©ã®ãšãŒãã«ã¢ã«ã³ãŒã«é¡ããã®ä»äžè¬ã®å¡æ
çšæº¶åªãšããŠãã·ã¬ã³ããã«ãšã³çãæãããã
ãããã®ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ã§äœ¿çšã«
äŸããã äžèšæº¶æ¶²éåã¯ãéåžžã®ã©ãžã«ã«éåæ³ã«åŸã€
ãŠå®æœãããŠãããäŸãã°äžèšéåéå§å€ã®ååš
äžãææ©æº¶åªäžã«æå®ã®éå枩床ïŒéåžž40ã250
âïŒã«ãŠå šåéäœãäžæ¬æ··åããŠåå¿ããããã
ãŸãã¯äºãäžèšéå枩床ã«èšå®ããææ©æº¶åªäžã«
å šåéäœã滎äžãã€ã€åå¿ããã次ãã§èŠããã°
çæããã°ãããéåæéã¯ãéåžž0.5ã20æé
ãæ¡çšããã ãã®ããã«ããŠåŸããã溶液åéåæš¹èã¯ãšã
ãã¬ãŒã¿ãŒãçšããŠè±æº¶åªãã䜿çšã«äŸãããã æ¬çºæã§ã¯ããããäž¡ã€ãªã³æ§åºãæããã¢ã¯
ãªã«æš¹èã®ãã¡ãé žäŸ¡ã30ã180ãç¹ã«40ã160ã
æ°å¹³åååéã500ã10000ãç¹ã«700ã6000ã§ã
ããã®ã䜿çšããã®ã奜ãŸããã åŒ
ãåŒãåºãŸãã¯
ãåŒã
åºïŒç¬Šå·ã¯åèšã«åããïŒãååäžã«æããã¡ã©
ãã³æš¹èã«ã€ããŠã¯ãåå¿æåäžã®ã¢ã«ã³ãŒã«æ
åãšããŠã åŒ ãŸã㯠ãŸã㯠ãåŒäžãR34ã¯ã¢ã«ãã«éªšæ Œäžã«ââãããã¯
âCOOâãå«ãããšãããC1ãC20ã®ããããã·
ã«åºãR35ã¯ã¢ã«ãã«éªšæ Œäžã«ââãããã¯â
COOâãå«ãããšãããC1ãC20ã®ããããã·ã¢
ã«ãã«åºãŸãã¯äœçŽã¢ã«ãã«åºãR36ã¯æ°ŽçŽ åå
ãŸãã¯ã¡ãã«åºãããã³ïŒã¯ã¢ã«ã«ãªéå±ãè¡šã
ããã ã§ç€ºãããããããã·ã«åºå«æã¢ããã¹ã«ãã³é ž
åäž¡æ§ã€ãªã³ååç©ã®çŸ€ããéžã°ããå°ãªããšã
ïŒçš®ãšãã¡ã©ãã³ããã³ãã«ããªã³ã®ïŒæåãæ··
åãéåžžã®ã¡ã©ãã³æš¹èã®è£œé ã«ãããåå¿æ¡
件ã»æ¹åŒã«åŸã€ãŠè£œé ããããšã«ãã€ãŠåŸãã
ãããããéåžžã®åå¿æ¡ä»¶ã»æ¹åŒãšããŠã¯ãäŸã
ã°å岡åäžèãå¡æçšåææš¹èå ¥éãïŒ1974幎ïŒ
æ25æ¥é«åååè¡äŒçºè¡ã134ã139é ïŒã®èšèŒå
容ã«æºããŠå®æœããã äžèšããããã·ã«åºå«æã¢ããã¹ã«ãã³é žåäž¡
æ§ã€ãªã³ååç©ã®è©³çŽ°ã«ã€ããŠã¯ãæ¬çºæè ãã®
ç¹é¡æ54â107624åç §ã åŒ
ãã³æš¹èã«ã€ããŠã¯ãåå¿æåäžã®ã¢ã«ã³ãŒã«æ
åãšããŠã åŒ ãŸã㯠ãŸã㯠ãåŒäžãR34ã¯ã¢ã«ãã«éªšæ Œäžã«ââãããã¯
âCOOâãå«ãããšãããC1ãC20ã®ããããã·
ã«åºãR35ã¯ã¢ã«ãã«éªšæ Œäžã«ââãããã¯â
COOâãå«ãããšãããC1ãC20ã®ããããã·ã¢
ã«ãã«åºãŸãã¯äœçŽã¢ã«ãã«åºãR36ã¯æ°ŽçŽ åå
ãŸãã¯ã¡ãã«åºãããã³ïŒã¯ã¢ã«ã«ãªéå±ãè¡šã
ããã ã§ç€ºãããããããã·ã«åºå«æã¢ããã¹ã«ãã³é ž
åäž¡æ§ã€ãªã³ååç©ã®çŸ€ããéžã°ããå°ãªããšã
ïŒçš®ãšãã¡ã©ãã³ããã³ãã«ããªã³ã®ïŒæåãæ··
åãéåžžã®ã¡ã©ãã³æš¹èã®è£œé ã«ãããåå¿æ¡
件ã»æ¹åŒã«åŸã€ãŠè£œé ããããšã«ãã€ãŠåŸãã
ãããããéåžžã®åå¿æ¡ä»¶ã»æ¹åŒãšããŠã¯ãäŸã
ã°å岡åäžèãå¡æçšåææš¹èå ¥éãïŒ1974幎ïŒ
æ25æ¥é«åååè¡äŒçºè¡ã134ã139é ïŒã®èšèŒå
容ã«æºããŠå®æœããã äžèšããããã·ã«åºå«æã¢ããã¹ã«ãã³é žåäž¡
æ§ã€ãªã³ååç©ã®è©³çŽ°ã«ã€ããŠã¯ãæ¬çºæè ãã®
ç¹é¡æ54â107624åç §ã åŒ
ãåŒãåºãŸãã¯
ãåŒã
åºïŒç¬Šå·ã¯åèšã«åããïŒãååäžã«æããããª
ãšãŒãã«æš¹èã«ã€ããŠã¯ãæ¬çºæè ãã®ç¹é¡æ55
â116293å·ã«èšèŒãããŠããããã«æ«ç«¯ã«åŒ ïŒR31ãR32ã¯æ°ŽçŽ ãã¡ãã«åºïŒãæããããªãš
ãŒãã«åãšããã·æš¹èã«ãåŒR33âNHââ
SO3MïŒåŒäžR33ã¯ãšããã·åºãšåå¿ããªã眮æåº
ãæããããšããã眮æåºãïŒã¯ã¢ã«ã«ãªéå±ãŸ
ãã¯ã¢ã³ã¢ããŠã åºãã¯åèšã«åããïŒ ã®ååç©ãåå¿ãããããšã«ãã€ãŠããªãã·ã©ã³
ç°ãéè£ããã該ããªãšãŒãã«åãšããã·æš¹èã®
æ«ç«¯åºã®äžéšã åŒ ïŒåŒäžç¬Šå·ã¯åèšã«åããïŒãšãªã€ãå€æ§ããªãš
ãŒãã«åãšããã·æš¹èãåŸããããããªãšãŒãã«
åãšããã·æš¹èã¯å ¬ç¥ã§ãããçš®ã ã®ãã®ãåžè²©
ãããŠãããããã¹ããšããŒã«ïŒ¡ä»¥å€ã®å€äŸ¡ããš
ããŒã«ãå€äŸ¡ã¢ã«ã³ãŒã«ããããããªã³ãšåå¿ã
ããããšã«ããåŸãã 詳现ã«ã€ããŠã¯ååºã®ç¹é¡æ55â116293å·ãå
ç §ã æ¬çºæã«ãããŠã(a)æåã®äžèšååå ã«ïŒå以
äžã®ã©ãžã«ã«éåå¯èœãªãšãã¬ã³æ§äžé£œååºãæ
ããåéäœïŒä»¥äžãå€å®èœæ§åéäœãšç¥ãïŒãšã
ãŠã¯ãå€äŸ¡ã¢ã«ã³ãŒã«ã®éåæ§äžé£œåã¢ãã«ã«ã
ã³é žãšã¹ãã«ãå€å¡©åºé žã®éåæ§äžé£œåã¢ã«ã³ãŒ
ã«ãšã¹ãã«ãããã³ïŒå以äžã®ããã«åºã§çœ®æã
ããè³éŠæååç©ãªã©ãããã ãããã®å€å®èœæ§åéäœã®äŸãšããŠã¯ä»¥äžã®ã
ããªååç©ãããã ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããšãã¬ã³
ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°ãªã³
ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâããã¬ã³ã°ã¯ã³
ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³
ããªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããª
ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãã¿ã³ãžãªãŒã«ãžã¢ã¯
ãªã¬ãŒããããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ãã³ã¿ãšãªã¹ãªããŒã«ãžã¢ã¯ãªã¬ãŒãããã³ã¿ãš
ãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãª
ããŒã«ããã©ã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒ
ã«ãžã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããª
ã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¡
ã¿ã¯ãªã¬ãŒããã°ãªã»ããŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»ããŒã«ã¢ã¯
ããã·ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ã
ãããã·ã¡ãã«ãšã¿ã³ãžã¢ã¯ãªã¬ãŒããïŒïŒïŒïŒ
ïŒâããªã¹ããããã·ã¡ãã«ãšã¿ã³ããªã¢ã¯ãªã¬
ãŒããïŒïŒïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãšã¿
ã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ããã
ãã·ã¡ãã«ãšã¿ã³ããªã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒ
ïŒâããªã¹ããããã·ã¡ãã«ãããã³ãžã¢ã¯ãªã¬
ãŒããïŒïŒïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãã
ãã³ããªã¢ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ãã
ããã·ã¡ãã«ãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒ
ïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãããã³ããªã¡
ã¿ã¯ãªã¬ãŒããããªã¢ãªã«ã·ã¢ãã¬ãŒããããªã¢
ãªã«ã€ãœã·ã¢ãã¬ãŒããããªã¢ãªã«ããªã¡ãªããŒ
ãããžã¢ãªã«ãã¬ãã¿ã¬ãŒãããžã¢ãªã«ãã¿ã¬ãŒ
ãããã³ãžããã«ãã³ãŒã³ã æ¬çºæã«ãããŠãåèš(a)以å€ã®éåæ§åéäœ(b)
ãšã¯ãååå ã«éåå¯èœãªåºïŒåãæããåå®èœ
åéäœãæãã以äžã®ã°ã«ãŒãã«åããããã () ã«ã«ããã·ã«åºå«æåéäœãäŸãã°ãã¢ã¯
ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žãã€ã¿ã³ã³
é žããã¬ã€ã³é žãããã«é žãªã©ã () ããããã·ã«åºå«æåéäœãäŸãã°ïŒâã
ãããã·ãšãã«ã¢ã¯ãªã¬ãŒããããããã·ãã
ãã«ã¢ã¯ãªã¬ãŒããïŒâããããã·ãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããããã·ãããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããããã·ããã«ã¢ã¯ãªã¬ãŒãããããã
ã·ããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«ã¢ã«ã³ãŒã«ã
ã¡ã¿ã¢ãªã«ã¢ã«ã³ãŒã«ãªã©ã () å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿
ã¯ãªã¬ãŒããäŸãã°ãžã¡ãã«ã¢ãããšãã«ã¢ã¯
ãªã¬ãŒãããžã¡ãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããªã©ã () éåæ§ã¢ãããäŸãã°ã¢ã¯ãªã«é žã¢ããã
ã¡ã¿ã¯ãªã«é žã¢ãããªã©ã () éåæ§ãããªã«ãäŸãã°ã¢ã¯ãªããããª
ã«ãã¡ã¿ã¯ãªããããªã«ãªã©ã () ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒããäŸãã°ã¡ãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâããã«
ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒããïŒ
âãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããªã©ã () éåæ§è³éŠæååç©ãäŸãã°ã¹ãã¬ã³ãα
âã¡ãã«ã¹ãã¬ã³ãããã«ãã«ãšã³ãïœâãã
ã«ã¹ãã¬ã³ãªã©ã () αâãªã¬ãã€ã³ãäŸãã°ããšãã¬ã³ããã
ãã¬ã³ãªã©ã () ããã«ååç©ãäŸãã°é ¢é žããã«ãããã
ãªã³é žããã«ãªã©ã () ãžãšã³ååç©ãäŸãã°ãã¿ãžãšã³ãã€ãœã
ã¬ã³ãªã©ã ãããã®åéäœ(b)ã¯åç¬ãŸãã¯äœµçšããŠäœ¿çšã
ããã å ±éåäœãæ§æããåèš(a)åéäœãš(b)åéäœã®
å²åã¯ãåŸãããæš¹èãšãã«ãžãšã³ã®å®å®æ§ãã
ã³å¡èæ§èœã«é¢ä¿ãããäžè¬ã«(a)åéäœã¯ãåé
äœå šéšã®åèšééãåºæºãšããŠå°ãªããšã0.01
ïŒ ã奜ãŸããã¯0.1ïŒ ä»¥äžååšãã¹ãã§ããããŸ
ã20ïŒ ã奜ãŸããã¯10ïŒ ãè¶ããŠã¯ãªããªãã(a)
åéäœã®éãå°ãªéãããšææã®å¡èç©æ§ãåŸã
ããªãããå€éãããšãšãã«ãžãšã³ã®åæ£å®å®æ§
ããã³å¡ææ§èœã«æªåœ±é¿ãåãŒãã(a)åéäœã®æ®
äœã¯(b)åéäœã§ããããã®ãã¡åè¿°ã®ïŒïŒã
ïŒïŒã®(b)åéäœã¯èŠªæ°Žæ§ã§ãããããããåé
äœå šéšã®åèšééã®å€§ããªå²åãå ãããšç®èã®
èæ°Žæ§ãå£åãããã®ã§ã奜ãŸããã¯40ïŒ ãè¶ã
ãŠã¯ãªããªãã éåã¯éåéå§å€ã®ååšäžãåèšã®æ°Žæº¶æ§æš¹è
ãå«ãæ°Žæ§åªäœäžã«æå®å²åã®åéäœæ··åç©ã滎
äžããŠè¡ãã®ã奜ãŸããã åèšã®æ°Žæº¶æ§æš¹èã¯ãåéäœæ··åç©ã®åèšéé
ã«å¯ŸããŠ0.3ïŒ ãªããïŒïŒ ã奜ãŸããã¯0.5ãªãã
ïŒïŒ 䜿çšããããšã§å åã§ããã æ°Žã¯åŸããããšãã«ãžãšã³æš¹èã®äžæ®çºåãïŒ
ãªãã65ïŒ ã奜ãŸããã¯20ãªãã60ïŒ ãšãªããã
ãªéã§çšããã®ã奜ãŸãããããã«åèšæ°Žæº¶æ§æš¹
èã®æº¶è§£ãå©ããããããã®é žäŸ¡ã«å¯Ÿå¿ããéã®
å¡©åºãå«ãã®ããããå¡©åºãšããŠã¯æ°Žé žåã¢ã«ã«
ãªãã¢ã³ã¢ãã¢ãææ©ã¢ãã³ã䜿çšãåŸãããæ®
æ£ããŠå¡èã«ç¡æ©ã€ãªã³ãæ®åããªãã¢ã³ã¢ãã¢
ãŸãã¯ææ©ã¢ãã³ã奜ãŸãããæ°Žæ§æº¶åªã¯æ°Žãšæ··
åãåŸãææ©æº¶åªãå«ãã§ããŠãããã äžèšéåéå§å€ãšããŠã¯ãéåžžã®ãã®ã䜿çšã§
ããäŸãã°ãéé žåãã³ãŸã€ã«ãïœâããã«ãã«
ãªãã·ããã¯ã¡ã³ãã€ãããã«ãªãã·ããªã©ã®æ
æ©éé žåç©ãã¢ãŸãã¹ã·ã¢ãåèé žãã¢ãŸãã¹ã€
ãœããããããªã«ãã¢ãŸãã¹âïŒïŒïŒïŒâãžã¡ã
ã«ïŒãã¬ããããªã«ãã¢ãŸãã¹âïŒïŒâã¢ããžã
ãããã³ïŒãã€ããã¯ãã©ã€ããªã©ã®ææ©ã¢ãŸå
åç©ãéç¡«é žã«ãªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãé
ç¡«é žãããªãŠã ãéé žåæ°ŽçŽ ãªã©ã®ç¡æ©æ°Žæº¶æ§ã©
ãžã«ã«éå§å€ãããã³ãããã®ç¡æ©æ°Žæº¶æ§ã©ãžã«
ã«éå§å€ãšããäºç¡«é žãããªãŠã ãäºç¡«é žæ°ŽçŽ ã
ããªãŠã ãïŒäŸ¡ã®éã€ãªã³ãªã©ãšã®çµåããã§åŸ
ãããã¬ããã¯ã¹ç³»éå§å€ãæãããããããã®
ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ã§äœ¿çšã«äŸããã ãããéåéå§å€ã¯äºããåå¿åªäœäžã«å ¥ããŠ
ãããŠãããããŸãæ§æã¢ãããŒãšåæã«æ»Žäžã
ãŠãããããããã®éåéå§å€ã®äœ¿çšéã¯ãéåžž
å šåéäœã«å¯ŸããŠ0.05ãïŒïŒ ã奜ãŸããã¯0.1ã
ïŒïŒ ã®ç¯å²ã§éžå®ãããŠãããããã«å¿ èŠã«å¿ã
ãŠéåžžã®é£é移åå€ïŒäŸãã°ã©ãŠãªã«ã¡ã«ã«ãã¿
ã³ãããã·ã«ã¡ã«ã«ãã¿ã³ãªã©ã®ã¡ã«ã«ãã¿ã³
é¡ïŒãé©é䜵çšããŠãããã 以äžãå ·äœçã«ãã®éåã®æäœäŸã瀺ãã å ããäžæŽ»æ§ã¬ã¹ãµãå²æ°äžã§åžžå§ãŸãã¯å å§
äžã§æ°Žæº¶æ§æš¹èããã³éåéå§å€ãå«æããåå¿
åªäœã§ããæ°ŽïŒèŠããã°èŠªæ°Žæ§ææ©æº¶å€ãæ·»å ã
ãŠãããïŒãéå枩床ïŒéåžžïŒã100âïŒã«èšå®
ããããã«äžè¿°ã®åéäœæ··åç©ã10ã300åéã
èŠããŠæ»Žäžãããã滎äžåŸå枩床ã§ïŒåã10æé
çæããã°ããã ãã®ããã«ããŠå®å®ã«æ°Žåæ£ããç²åºŠïŒ25âïŒ
10ã50000cpsãäžæ®çºåïŒã65ïŒ ã®ãã«ã¯ç¶ä¹è³
ã¯ãªãŒã ç¶ã®ãšãã«ãžãšã³æš¹èãåŸãããã æ¬çºæã«ä¿ãå¡æçµæç©ã¯ãåœè©²å ±éåäœã®ãš
ãã«ãžãšã³æš¹èãäž»æåãšãããã®ã§ãããå ·äœ
çã«ã¯ãããäž»æååç¬ãŸãã¯ããã«ãå¿ èŠã«å¿
ããŠéåžžã®æš¹èããã¯ã«ãäŸãã°ã¡ã©ãã³æš¹èã
å°¿çŽ æš¹èãã°ã¢ããã³æš¹èãªã©ã®ã¢ãããã©ã¹ã
æš¹èãããšããã©ã¹ãæš¹èããšããã·æš¹èãªã©ã
ææ©ç³»ããã³ç¡æ©ç³»ã®çè²é¡æãäœè³ªé¡æãé²é
é¡æããã®ä»æ·»å å€ïŒå å¡«å€ãå¢éå€ãå¢ç²å€ã
èçå€ãªã©ïŒãããã«çé¢æŽ»æ§å€ãPH調æŽå€ãæ°Žã
溶å€çãé©éæ··å ¥ããåžžæž©ã§åæ£æ··åããŠèª¿è£œã
ããã ããã«åœè©²ãšãã«ãžãšã³æš¹èã«ããããã·ã«åº
ãå°å ¥ïŒå ·äœçã«ã¯ãäžèš(b)æåãšããŠïŒã®å
éäœã䜿çšïŒããããã«äžèšã¢ãããã©ã¹ãæš¹è
ãçµåãããããšã«ãããããåªããäœæž©ç¡¬åç¹
æ§ãçºçŸããããšãã§ãããŸããèæ°Žæ§è¯å¥œãªç¡¬
åå¡èã圢æããããšãã§ããã 以äžã®åŠãããŠèª¿è£œãããå¡æçµæç©ãé©åœãª
被èç©ïŒéå±æ¿ãæšæãçŽç³»åºæããã©ã¹ããã¯
ç³»åºæãªã©ïŒã«éåžžã®æ¹æ³ã§èåïŒã500ÎŒã«ãŠ
å¡è£ ãã60ã2400â枩床ã§20ç§ã60å也ç¥ããã
ãšã«ããè¯å¥œãªç¡¬åå¡èã圢æãããã 次ã«åèäŸãå®æœäŸããã³æ¯èŒäŸãæããŠæ¬çº
æãå ·äœçã«èª¬æããããªããäŸæäžãéšããšã
ãã®ã¯ãéééšããæå³ããã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ããã
ããã·ãšãã«ã¿ãŠãªã³191éšããšãã¬ã³ã°ãªã³ãŒ
ã«140éšãããªãšãã¬ã³ã°ãªã³ãŒã«170éšãã¢ãžã
ã³é ž331éšãç¡æ°Žãã¿ã«é ž168éšããã³ãã·ã¬ã³40
éšãä»èŸŒã¿ãææž©ãããåå¿ã«ããçæããæ°Žã
ãã·ã¬ã³ãšå ±æ²žéæµããé€å»ãããéæµéå§ãã
çŽïŒæéãããŠæž©åºŠã190âã«ããã«ã«ãã³é žçž
åœã®é žäŸ¡ã10以äžã«ãªããŸã§æ¹æãšè±æ°Žãç¶ç¶ã
ãŠåå¿ãçµäºãããåŸãããããªãšã¹ãã«æš¹è
ã¯ãé žäŸ¡79ãæ°Žé žåºäŸ¡79ãïŒ708ã§ãã€ãã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ããã¹
ããããã·ãšãã«ã¿ãŠãªã³134éšãããªãã³ãã«
ã°ãªã³ãŒã«130éšãã¢ãŒã©ã€ã³é ž236éšãç¡æ°Žãã¿
ã«é ž186éšããã³ãã·ã¬ã³27éšãä»èŸŒã¿ãææž©ã
ããåå¿ã«ããçæããæ°Žããã·ã¬ã³ãšå ±æ²žéæµ
ããé€å»ãããéæµéå§ããçŽïŒæéãããŠæž©åºŠ
ã190âã«ããã«ã«ãã³é žçžåœã®é žäŸ¡ã145ã«ãªã
ãŸã§æ¹æãšè±æ°Žãç¶ç¶ãã140âãŸã§å·åŽããã 次ãã§ãåå¿æ¶²æž©åºŠã140âã«ä¿æãããã«ãŒãž
ãŠã©E10ãïŒã·ãšã«ç€Ÿè£œã®ããŒãµãã€ãã¯é žã°ãª
ã·ãžã«ãšã¹ãã«ïŒ314éšã30åã§æ»Žäžãããã®åŸ
ïŒæéæ¹æãç¶ç¶ãåå¿ãçµäºãããåŸãããã
ãªãšã¹ãã«æš¹èã¯ãé žäŸ¡59ãæ°Žé žåºäŸ¡90ãïŒ
1054ã§ãã€ãã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ãè±æ°Ž
ããã·æ²¹85éšãšã€ã·æ²¹63éšãšããªã¡ãããŒã«ãã
ãã³53éšãä»èŸŒã¿ãçªçŽ é°å²æ°äžã§æž©åºŠã240â
ã«äžããŠ30åéæ¹æãããšãããã¡ã¿ããŒã«ãã¬
ã©ã³ã¹ãç¡é倧ãšãªã€ããå 容ç©ã®æž©åºŠã150â
ã«äžããæ¹æããšããŠç¡æ°Žãã¿ã«é ž725éšãšãžãš
ãã¬ã³ã°ãªã³ãŒã«343éšãšããªã¡ãããŒã«ããã
ã³43éšãšïŒ®ïŒïŒ®âãã¹âïŒïŒâããããã·ãšãã«ïŒ
ã¢ãããšã¿ã³ã¹ã«ãã³é ž375éšãšãã·ã¬ã³45éšã
ä»èŸŒãã ãåã³æ¹æãéå§ãã枩床ãåŸã ã«äžã
ãªããçæããæ°Žããã·ã¬ã³ãšå ±æ²žéæµãããŠé€
å»ãããçŽïŒæéãããŠæž©åºŠã240âã«ãããã
ã«åäžæž©åºŠã§ã«ã«ãã³é žçžåœã®é žäŸ¡ãïŒã«ãªããŸ
ã§æ¹æãšè±æ°Žãç¶ç¶ããŠãåå¿ãçµäºãããåŸã
ããããªãšã¹ãã«æš¹èã¯æ²¹é·10ãé žäŸ¡66ãæ°Žé žåº
䟡100ãïŒ800ã§ãã€ãã åèäŸ ïŒ ããã¯ãåšãå·åŽç®¡ããã³æž©åºŠå¶åŸ¡è£ 眮ãåã
ãïŒã®ãã©ã¹ã³ãžãã¿ãŠãªã³25éšãæ°Žé žåãã
ãªãŠã ïŒéšãè±ã€ãªã³æ°Ž100éšããšãã¬ã³ã°ãªã³
ãŒã«ã¢ããšãã«ãšãŒãã«400éšãä»èŸŒã¿ããããŸ
ããªãã枩床ã100âãžããããå 容ç©ãåäžãª
溶解ç¶æ ã«ãªã€ãåŸããšãã³ãŒã828ïŒã·ãšã«ã±ã
ã«ã«ç€Ÿè£œããã¹ããšããŒã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒ
ãã«åãšããã·æš¹èããšããã·åœé190ïŒ190éšãš
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«200éšã
ããªã溶液ãïŒæéã§æ»Žäžããã滎äžåŸïŒæéã
ãã¯ããå ç±ãç¶ç¶ããŠåå¿ãçµäºãããåå¿æ¶²
ãå¡©é žã æ§ãšããåŸãããæ²æ®¿ãæ¡åããŠãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ãšæ°Žã«ããåæ²
殿æ³ã«ãã粟補ããæžå§äžã«ä¹Ÿç¥ããå€æ§ãšãã
ã·æš¹è205éšãåŸãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯48.6ã§ãè¢
å ç·åæã«ããã€ãªãŠå«éã¯ïŒïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšããã¿ãŠãªã³ã®ãã
ãªãŠã å¡©73.5éšããšãã¬ã³ã°ãªã³ãŒã«100éšããš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«200éšãä»
蟌ã¿ããããŸããªããå ç±ããŠæž©åºŠã120âã«äž
ãããå 容ç©ãåäžãªæº¶è§£ç¶æ ã«éããåŸããšã
ã³ãŒã1001ïŒã·ãšã«ã±ãã«ã«ç€Ÿè£œããã¹ããšããŒ
ã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒãã«åãšããã·æš¹èããš
ããã·åœé470ïŒ470éšãšãšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ã¡ãã«ãšãŒãã«400éšãããªã溶液ãïŒæéã§æ»Ž
äžããã滎äžåŸ20æéããã¯ããšå ç±ãç¶ç¶ããŠ
åå¿ãçµäºãããåå¿ç©ãåèäŸïŒãšåæ§ã«ç²Ÿ
補ã也ç¥ããŠãå€æ§ãšããã·æš¹è518éšãåŸãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯49.4ã§ãè¢
å ç·åæã«ããã€ãªãŠã®å«éã¯2.8ïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšããâã¡ãã«ã¿ãŠ
ãªã³ã®ãããªãŠã å¡©121éšããšãã¬ã³ã°ãªã³ãŒã«
100éšããšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«
200éšãä»èŸŒã¿ããããŸããªããå ç±ããŠæž©åºŠã
120âã«ããããå 容ç©ãåäžãªæº¶è§£ç¶æ ã«éã
ãåŸããšãã³ãŒã1004ïŒã·ãšã«ã±ãã«ã«ç€Ÿè£œãã
ã¹ããšããŒã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒãã«åãšãã
ã·æš¹èããšããã·åœé950ïŒ475éšãšãšãã¬ã³ã°ãª
ã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«400éšãã溶液ãïŒæ
éã§æ»Žäžããã滎äžåŸ20æéããã¯ããšå ç±ãç¶
ç¶ããŠåå¿ãçµäºãããåå¿ç©ãåèäŸïŒãšåæ§
ã«ç²Ÿè£œã也ç¥ããŠãå€æ§ãšããã·æš¹è540éšãåŸ
ãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯50ã§ãè¢å
ç·åæã«ããã€ãªãŠã®å«éã¯2.9ïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšãããšãã¬ã³ã°ãªã³
ãŒã«ã¢ãã¡ãã«ãšãŒãã«100éšãä»èŸŒã¿ã100âã«
ææž©ãä¿æããã滎äžããŒããäºæ¬çšæããäžæ¹
ã«100éšã®ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒã
ã«ãå ¥ããã®äžã«ïŒ®âã¡ãã«ââïŒããã«ãã³
ãžã«ïŒã¿ãŠãªã³ã75éšæº¶ããããã®éã溶解è£å©
å€ãšããŠå°éã®ãžã¡ãã«ãšã¿ããŒã«ã¢ãã³ãå ã
ãã ããã«äžæ¹ã®æ»ŽäžããŒããšïŒâããããã·ãšã
ã«ã¢ã¯ãªã¬ãŒã50éšãã¢ã¯ãªã«é ž10éšãã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒã110éšãã¹ãã¬ã³110éšãïœâããã«
ã¢ã¯ãªã¬ãŒã145éšããã³ã©ãŠãªã«ã¡ã«ã«ãã¿ã³
10éšãæ··åããã¢ãŸãã¹ã€ãœããããããªã«10éš
ã溶解ããã äºæ¬ã®æ»ŽäžããŒãå 容ç©ã120åéã§æ»Žäžãã
ã®åŸæž©åºŠã100âã«ä¿æããŠ60åéæ¹æãç¶ç¶ã
ãã次ãã§ããã®æš¹è溶液ã®æº¶åªãããŒã¿ãªãŒãš
ããã¬ãŒã¿ãŒã§é€å»ããæš¹èåºåå96ïŒ ã§ïœã
4500ã®ã¢ã¯ãªã«æš¹èãåŸãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªåå¿æ§åŒãçšã㊠ïŒïŒ®âãžã¡ãã«ââïŒããã«ãã³ãžã«ïŒã¢ã³
ã¢ããªé ¢é žãã¿ã€ã³ 100éš ïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒã âŠâŠ50éš ã¢ã¯ãªã«é ž âŠâŠ25éš ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã âŠâŠ80éš ã¹ãã¬ã³ âŠâŠ80éš ïœâããã«ã¢ã¯ãªã¬ãŒã âŠâŠ165éš ã©ãŠãªã«ã¡ã«ã«ãã¿ã³ âŠâŠ15éš ã¢ãŸãã¹ã€ãœããããããªã« âŠâŠ10éš ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«
âŠâŠ200éš ãããªãæš¹è溶液ãåŸãããã®æš¹è溶液ã®æº¶åªã
ããŒã¿ãªãŒãšããã¬ãŒã¿ãŒã§é€å»ããæš¹èåºåå
97ïŒ ã§ïœã3900ã®ã¢ã¯ãªã«æš¹èãåŸãã å®æœäŸ ïŒ æ¹æåšãå·åŽåšã枩床å¶åŸ¡è£ 眮ãå ·åããïŒ
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
ããªãšã¹ãã«æš¹è30éšããã³ãžã¡ãã«ãšã¿ããŒã«
ã¢ãã³ïŒéšãä»èŸŒã¿ãæ¹æäžæž©åºŠã80âã«ä¿æã
ãªãã溶解ããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž4.5
éšãè±ã€ãªã³æ°Ž45éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³
4.3éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒã70.7éšãïœâããã«ã¢ã¯ãªã¬ãŒ
ã94.2éšãã¹ãã¬ã³70.7éšãïŒâããããã·ãšã
ã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒã«ãž
ã¡ã¿ã¯ãªã¬ãŒã4.5éšãããªãæ··å溶液ã60åé
èŠããŠæ»Žäžããã滎äžåŸãæŽã«ã¢ãŸãã¹ã·ã¢ãå
èé ž1.5éšãè±ã€ãªã³æ°Ž15éšãšãžã¡ãã«ãšã¿ããŒ
ã«ã¢ãã³1.4éšã«æº¶è§£ãããã®ãæ·»å ããŠ80âã§
60åéæ¹æãç¶ãããšãããäžæ®çºå45ïŒ ãPH
7.4ãç²åºŠ78cpsïŒ25âïŒãç²ååŸ0.138ÎŒïŒå æ£ä¹±æ³
ã«ãããé»åé¡åŸ®é¡ã«ããç²ååŸã¯0.052ÎŒã§ã
ãã以äžåŸè ã®å€ãåè ã®å€ã®çŽåŸã«ã«ãã³å ã«
䜵èšãããïŒã®ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.3ïŒ ïŒå¯Ÿçæãš
ãã«ãžãšã³æ¯ïŒã§ãããåéç©ã®çæã¯æ¥µããŠåŸ®
éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§ããã
宀枩ã§ïŒã±ææŸçœ®ããŠãåéç©ãæ²ã§ããçãã
ããšããªãå®å®ã§ãã€ãã ãªãäžèšç²åºŠã¯ïŒ¢åç²åºŠèšãç²ååŸã¯å æ£ä¹±æ³
ã§æž¬å®ããæ©æ¢°çå®å®æ§ã¯ãšãã«ãžãšã³ã®ïŒæ»Žã
芪æãšäººå·®ãæã®éã§ïŒåãããåããããšãè
çãããããªããã®ãè¯å¥œãšããã 以äžã®å®æœäŸã«ãããŠãåæ§ã§ããã å®æœäŸ ïŒ å®æœäŸïŒã®è£œé æ¹æ³ã«ãããŠãåèäŸïŒã§åŸã
ããªãšã¹ãã«æš¹è30éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ã
ã³ïŒéšã®ãããã«åèäŸïŒã§åŸãããªãšã¹ãã«æš¹
è10éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³0.75éšã䜿çš
ãã以å€ã¯ãåæ§ãªææ³ããã³æ¡ä»¶ã«åŸã€ãŠäžæ®
çºå45ïŒ ãPH7.2ãç²åºŠ92cpsïŒ25âïŒãç²ååŸ
0.156ÎŒïŒ0.102ÎŒïŒã®ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.2ïŒ ã§ããã極
ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§
ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒãšåãåå¿å®¹åšã«è±ã€ãªã³æ°Ž306éšã
åèäŸïŒã§åŸãããªãšã¹ãã«æš¹è20éšããã³ããª
ãšãã«ã¢ãã1.8éšãä»èŸŒã¿ãæ¹æäžæž©åºŠã75â
ã«ä¿æããªãã溶解ããããã«ã¢ãŸãã¹ã·ã¢ãå
èé ž4.5éšãè±ã€ãªã³æ°Ž45éšãšããªãšãã«ã¢ãã³
4.9éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒã150éšãïœâããã«ã¢ã¯ãªã¬ãŒ
ã127éšããžããã«ãã³ãŒã³ïŒéšãããªãæ··å溶
液ã90åéãèŠããŠæ»Žäžããã滎äžåŸãæŽã«ã¢ãŸ
ãã¹ã·ã¢ãåèé ž1.5éšãè±ã€ãªã³æ°Ž15éšãšããª
ãšãã«ã¢ãã³1.6éšã«æº¶è§£ãããã®ãæ·»å ããŠ80
âã§60åéæ¹æãç¶ãããšãããäžæ®çºå45ïŒ ã
PH7.2ãç²åºŠ84cpsïŒ25âïŒãç²åŸ0.158ÎŒïŒ0.070ÎŒïŒã®
ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.2ïŒ ã§ããã極
ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§
ãã€ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã®ãšãã«ãžãšã³è£œé æ¹æ³ã«ãããŠã第
ïŒè¡šã«ç€ºãå²åïŒéšïŒã§ããªãšã¹ãã«æš¹èãè±ã€
ãªã³æ°Žããžã¡ãã«ãšã¿ããŒã«ã¢ãããšæ··å溶液ãš
ãããããçšããæå®ã®æ»Žäžæéã§æ»Žäžãã以å€
ã¯åæ§ãªææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ã®ãšãã«ãž
ãšã³ïŒNo.ïŒãïŒïŒãåŸããããããšãã«ãžãšã³ã®
æ§ç¶ããã³400ã¡ãã·ãŠã®é網ã§éããéã®äž
ééåã第ïŒè¡šã«ç€ºãã
ãšãŒãã«æš¹èã«ã€ããŠã¯ãæ¬çºæè ãã®ç¹é¡æ55
â116293å·ã«èšèŒãããŠããããã«æ«ç«¯ã«åŒ ïŒR31ãR32ã¯æ°ŽçŽ ãã¡ãã«åºïŒãæããããªãš
ãŒãã«åãšããã·æš¹èã«ãåŒR33âNHââ
SO3MïŒåŒäžR33ã¯ãšããã·åºãšåå¿ããªã眮æåº
ãæããããšããã眮æåºãïŒã¯ã¢ã«ã«ãªéå±ãŸ
ãã¯ã¢ã³ã¢ããŠã åºãã¯åèšã«åããïŒ ã®ååç©ãåå¿ãããããšã«ãã€ãŠããªãã·ã©ã³
ç°ãéè£ããã該ããªãšãŒãã«åãšããã·æš¹èã®
æ«ç«¯åºã®äžéšã åŒ ïŒåŒäžç¬Šå·ã¯åèšã«åããïŒãšãªã€ãå€æ§ããªãš
ãŒãã«åãšããã·æš¹èãåŸããããããªãšãŒãã«
åãšããã·æš¹èã¯å ¬ç¥ã§ãããçš®ã ã®ãã®ãåžè²©
ãããŠãããããã¹ããšããŒã«ïŒ¡ä»¥å€ã®å€äŸ¡ããš
ããŒã«ãå€äŸ¡ã¢ã«ã³ãŒã«ããããããªã³ãšåå¿ã
ããããšã«ããåŸãã 詳现ã«ã€ããŠã¯ååºã®ç¹é¡æ55â116293å·ãå
ç §ã æ¬çºæã«ãããŠã(a)æåã®äžèšååå ã«ïŒå以
äžã®ã©ãžã«ã«éåå¯èœãªãšãã¬ã³æ§äžé£œååºãæ
ããåéäœïŒä»¥äžãå€å®èœæ§åéäœãšç¥ãïŒãšã
ãŠã¯ãå€äŸ¡ã¢ã«ã³ãŒã«ã®éåæ§äžé£œåã¢ãã«ã«ã
ã³é žãšã¹ãã«ãå€å¡©åºé žã®éåæ§äžé£œåã¢ã«ã³ãŒ
ã«ãšã¹ãã«ãããã³ïŒå以äžã®ããã«åºã§çœ®æã
ããè³éŠæååç©ãªã©ãããã ãããã®å€å®èœæ§åéäœã®äŸãšããŠã¯ä»¥äžã®ã
ããªååç©ãããã ãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããšãã¬ã³
ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°ãªã³
ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâããã¬ã³ã°ã¯ã³
ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³
ããªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããª
ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãã¿ã³ãžãªãŒã«ãžã¢ã¯
ãªã¬ãŒããããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ãã³ã¿ãšãªã¹ãªããŒã«ãžã¢ã¯ãªã¬ãŒãããã³ã¿ãš
ãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãª
ããŒã«ããã©ã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒ
ã«ãžã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããª
ã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¡
ã¿ã¯ãªã¬ãŒããã°ãªã»ããŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»ããŒã«ã¢ã¯
ããã·ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ã
ãããã·ã¡ãã«ãšã¿ã³ãžã¢ã¯ãªã¬ãŒããïŒïŒïŒïŒ
ïŒâããªã¹ããããã·ã¡ãã«ãšã¿ã³ããªã¢ã¯ãªã¬
ãŒããïŒïŒïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãšã¿
ã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ããã
ãã·ã¡ãã«ãšã¿ã³ããªã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒïŒ
ïŒâããªã¹ããããã·ã¡ãã«ãããã³ãžã¢ã¯ãªã¬
ãŒããïŒïŒïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãã
ãã³ããªã¢ã¯ãªã¬ãŒããïŒïŒïŒïŒïŒâããªã¹ãã
ããã·ã¡ãã«ãããã³ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒ
ïŒïŒïŒâããªã¹ããããã·ã¡ãã«ãããã³ããªã¡
ã¿ã¯ãªã¬ãŒããããªã¢ãªã«ã·ã¢ãã¬ãŒããããªã¢
ãªã«ã€ãœã·ã¢ãã¬ãŒããããªã¢ãªã«ããªã¡ãªããŒ
ãããžã¢ãªã«ãã¬ãã¿ã¬ãŒãããžã¢ãªã«ãã¿ã¬ãŒ
ãããã³ãžããã«ãã³ãŒã³ã æ¬çºæã«ãããŠãåèš(a)以å€ã®éåæ§åéäœ(b)
ãšã¯ãååå ã«éåå¯èœãªåºïŒåãæããåå®èœ
åéäœãæãã以äžã®ã°ã«ãŒãã«åããããã () ã«ã«ããã·ã«åºå«æåéäœãäŸãã°ãã¢ã¯
ãªã«é žãã¡ã¿ã¯ãªã«é žãã¯ããã³é žãã€ã¿ã³ã³
é žããã¬ã€ã³é žãããã«é žãªã©ã () ããããã·ã«åºå«æåéäœãäŸãã°ïŒâã
ãããã·ãšãã«ã¢ã¯ãªã¬ãŒããããããã·ãã
ãã«ã¢ã¯ãªã¬ãŒããïŒâããããã·ãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããããã·ãããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããããã·ããã«ã¢ã¯ãªã¬ãŒãããããã
ã·ããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«ã¢ã«ã³ãŒã«ã
ã¡ã¿ã¢ãªã«ã¢ã«ã³ãŒã«ãªã©ã () å«çªçŽ ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿
ã¯ãªã¬ãŒããäŸãã°ãžã¡ãã«ã¢ãããšãã«ã¢ã¯
ãªã¬ãŒãããžã¡ãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããªã©ã () éåæ§ã¢ãããäŸãã°ã¢ã¯ãªã«é žã¢ããã
ã¡ã¿ã¯ãªã«é žã¢ãããªã©ã () éåæ§ãããªã«ãäŸãã°ã¢ã¯ãªããããª
ã«ãã¡ã¿ã¯ãªããããªã«ãªã©ã () ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬
ãŒããäŸãã°ã¡ãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâããã«
ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒããïŒ
âãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããªã©ã () éåæ§è³éŠæååç©ãäŸãã°ã¹ãã¬ã³ãα
âã¡ãã«ã¹ãã¬ã³ãããã«ãã«ãšã³ãïœâãã
ã«ã¹ãã¬ã³ãªã©ã () αâãªã¬ãã€ã³ãäŸãã°ããšãã¬ã³ããã
ãã¬ã³ãªã©ã () ããã«ååç©ãäŸãã°é ¢é žããã«ãããã
ãªã³é žããã«ãªã©ã () ãžãšã³ååç©ãäŸãã°ãã¿ãžãšã³ãã€ãœã
ã¬ã³ãªã©ã ãããã®åéäœ(b)ã¯åç¬ãŸãã¯äœµçšããŠäœ¿çšã
ããã å ±éåäœãæ§æããåèš(a)åéäœãš(b)åéäœã®
å²åã¯ãåŸãããæš¹èãšãã«ãžãšã³ã®å®å®æ§ãã
ã³å¡èæ§èœã«é¢ä¿ãããäžè¬ã«(a)åéäœã¯ãåé
äœå šéšã®åèšééãåºæºãšããŠå°ãªããšã0.01
ïŒ ã奜ãŸããã¯0.1ïŒ ä»¥äžååšãã¹ãã§ããããŸ
ã20ïŒ ã奜ãŸããã¯10ïŒ ãè¶ããŠã¯ãªããªãã(a)
åéäœã®éãå°ãªéãããšææã®å¡èç©æ§ãåŸã
ããªãããå€éãããšãšãã«ãžãšã³ã®åæ£å®å®æ§
ããã³å¡ææ§èœã«æªåœ±é¿ãåãŒãã(a)åéäœã®æ®
äœã¯(b)åéäœã§ããããã®ãã¡åè¿°ã®ïŒïŒã
ïŒïŒã®(b)åéäœã¯èŠªæ°Žæ§ã§ãããããããåé
äœå šéšã®åèšééã®å€§ããªå²åãå ãããšç®èã®
èæ°Žæ§ãå£åãããã®ã§ã奜ãŸããã¯40ïŒ ãè¶ã
ãŠã¯ãªããªãã éåã¯éåéå§å€ã®ååšäžãåèšã®æ°Žæº¶æ§æš¹è
ãå«ãæ°Žæ§åªäœäžã«æå®å²åã®åéäœæ··åç©ã滎
äžããŠè¡ãã®ã奜ãŸããã åèšã®æ°Žæº¶æ§æš¹èã¯ãåéäœæ··åç©ã®åèšéé
ã«å¯ŸããŠ0.3ïŒ ãªããïŒïŒ ã奜ãŸããã¯0.5ãªãã
ïŒïŒ 䜿çšããããšã§å åã§ããã æ°Žã¯åŸããããšãã«ãžãšã³æš¹èã®äžæ®çºåãïŒ
ãªãã65ïŒ ã奜ãŸããã¯20ãªãã60ïŒ ãšãªããã
ãªéã§çšããã®ã奜ãŸãããããã«åèšæ°Žæº¶æ§æš¹
èã®æº¶è§£ãå©ããããããã®é žäŸ¡ã«å¯Ÿå¿ããéã®
å¡©åºãå«ãã®ããããå¡©åºãšããŠã¯æ°Žé žåã¢ã«ã«
ãªãã¢ã³ã¢ãã¢ãææ©ã¢ãã³ã䜿çšãåŸãããæ®
æ£ããŠå¡èã«ç¡æ©ã€ãªã³ãæ®åããªãã¢ã³ã¢ãã¢
ãŸãã¯ææ©ã¢ãã³ã奜ãŸãããæ°Žæ§æº¶åªã¯æ°Žãšæ··
åãåŸãææ©æº¶åªãå«ãã§ããŠãããã äžèšéåéå§å€ãšããŠã¯ãéåžžã®ãã®ã䜿çšã§
ããäŸãã°ãéé žåãã³ãŸã€ã«ãïœâããã«ãã«
ãªãã·ããã¯ã¡ã³ãã€ãããã«ãªãã·ããªã©ã®æ
æ©éé žåç©ãã¢ãŸãã¹ã·ã¢ãåèé žãã¢ãŸãã¹ã€
ãœããããããªã«ãã¢ãŸãã¹âïŒïŒïŒïŒâãžã¡ã
ã«ïŒãã¬ããããªã«ãã¢ãŸãã¹âïŒïŒâã¢ããžã
ãããã³ïŒãã€ããã¯ãã©ã€ããªã©ã®ææ©ã¢ãŸå
åç©ãéç¡«é žã«ãªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãé
ç¡«é žãããªãŠã ãéé žåæ°ŽçŽ ãªã©ã®ç¡æ©æ°Žæº¶æ§ã©
ãžã«ã«éå§å€ãããã³ãããã®ç¡æ©æ°Žæº¶æ§ã©ãžã«
ã«éå§å€ãšããäºç¡«é žãããªãŠã ãäºç¡«é žæ°ŽçŽ ã
ããªãŠã ãïŒäŸ¡ã®éã€ãªã³ãªã©ãšã®çµåããã§åŸ
ãããã¬ããã¯ã¹ç³»éå§å€ãæãããããããã®
ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ã§äœ¿çšã«äŸããã ãããéåéå§å€ã¯äºããåå¿åªäœäžã«å ¥ããŠ
ãããŠãããããŸãæ§æã¢ãããŒãšåæã«æ»Žäžã
ãŠãããããããã®éåéå§å€ã®äœ¿çšéã¯ãéåžž
å šåéäœã«å¯ŸããŠ0.05ãïŒïŒ ã奜ãŸããã¯0.1ã
ïŒïŒ ã®ç¯å²ã§éžå®ãããŠãããããã«å¿ èŠã«å¿ã
ãŠéåžžã®é£é移åå€ïŒäŸãã°ã©ãŠãªã«ã¡ã«ã«ãã¿
ã³ãããã·ã«ã¡ã«ã«ãã¿ã³ãªã©ã®ã¡ã«ã«ãã¿ã³
é¡ïŒãé©é䜵çšããŠãããã 以äžãå ·äœçã«ãã®éåã®æäœäŸã瀺ãã å ããäžæŽ»æ§ã¬ã¹ãµãå²æ°äžã§åžžå§ãŸãã¯å å§
äžã§æ°Žæº¶æ§æš¹èããã³éåéå§å€ãå«æããåå¿
åªäœã§ããæ°ŽïŒèŠããã°èŠªæ°Žæ§ææ©æº¶å€ãæ·»å ã
ãŠãããïŒãéå枩床ïŒéåžžïŒã100âïŒã«èšå®
ããããã«äžè¿°ã®åéäœæ··åç©ã10ã300åéã
èŠããŠæ»Žäžãããã滎äžåŸå枩床ã§ïŒåã10æé
çæããã°ããã ãã®ããã«ããŠå®å®ã«æ°Žåæ£ããç²åºŠïŒ25âïŒ
10ã50000cpsãäžæ®çºåïŒã65ïŒ ã®ãã«ã¯ç¶ä¹è³
ã¯ãªãŒã ç¶ã®ãšãã«ãžãšã³æš¹èãåŸãããã æ¬çºæã«ä¿ãå¡æçµæç©ã¯ãåœè©²å ±éåäœã®ãš
ãã«ãžãšã³æš¹èãäž»æåãšãããã®ã§ãããå ·äœ
çã«ã¯ãããäž»æååç¬ãŸãã¯ããã«ãå¿ èŠã«å¿
ããŠéåžžã®æš¹èããã¯ã«ãäŸãã°ã¡ã©ãã³æš¹èã
å°¿çŽ æš¹èãã°ã¢ããã³æš¹èãªã©ã®ã¢ãããã©ã¹ã
æš¹èãããšããã©ã¹ãæš¹èããšããã·æš¹èãªã©ã
ææ©ç³»ããã³ç¡æ©ç³»ã®çè²é¡æãäœè³ªé¡æãé²é
é¡æããã®ä»æ·»å å€ïŒå å¡«å€ãå¢éå€ãå¢ç²å€ã
èçå€ãªã©ïŒãããã«çé¢æŽ»æ§å€ãPH調æŽå€ãæ°Žã
溶å€çãé©éæ··å ¥ããåžžæž©ã§åæ£æ··åããŠèª¿è£œã
ããã ããã«åœè©²ãšãã«ãžãšã³æš¹èã«ããããã·ã«åº
ãå°å ¥ïŒå ·äœçã«ã¯ãäžèš(b)æåãšããŠïŒã®å
éäœã䜿çšïŒããããã«äžèšã¢ãããã©ã¹ãæš¹è
ãçµåãããããšã«ãããããåªããäœæž©ç¡¬åç¹
æ§ãçºçŸããããšãã§ãããŸããèæ°Žæ§è¯å¥œãªç¡¬
åå¡èã圢æããããšãã§ããã 以äžã®åŠãããŠèª¿è£œãããå¡æçµæç©ãé©åœãª
被èç©ïŒéå±æ¿ãæšæãçŽç³»åºæããã©ã¹ããã¯
ç³»åºæãªã©ïŒã«éåžžã®æ¹æ³ã§èåïŒã500ÎŒã«ãŠ
å¡è£ ãã60ã2400â枩床ã§20ç§ã60å也ç¥ããã
ãšã«ããè¯å¥œãªç¡¬åå¡èã圢æãããã 次ã«åèäŸãå®æœäŸããã³æ¯èŒäŸãæããŠæ¬çº
æãå ·äœçã«èª¬æããããªããäŸæäžãéšããšã
ãã®ã¯ãéééšããæå³ããã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ããã
ããã·ãšãã«ã¿ãŠãªã³191éšããšãã¬ã³ã°ãªã³ãŒ
ã«140éšãããªãšãã¬ã³ã°ãªã³ãŒã«170éšãã¢ãžã
ã³é ž331éšãç¡æ°Žãã¿ã«é ž168éšããã³ãã·ã¬ã³40
éšãä»èŸŒã¿ãææž©ãããåå¿ã«ããçæããæ°Žã
ãã·ã¬ã³ãšå ±æ²žéæµããé€å»ãããéæµéå§ãã
çŽïŒæéãããŠæž©åºŠã190âã«ããã«ã«ãã³é žçž
åœã®é žäŸ¡ã10以äžã«ãªããŸã§æ¹æãšè±æ°Žãç¶ç¶ã
ãŠåå¿ãçµäºãããåŸãããããªãšã¹ãã«æš¹è
ã¯ãé žäŸ¡79ãæ°Žé žåºäŸ¡79ãïŒ708ã§ãã€ãã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ããã¹
ããããã·ãšãã«ã¿ãŠãªã³134éšãããªãã³ãã«
ã°ãªã³ãŒã«130éšãã¢ãŒã©ã€ã³é ž236éšãç¡æ°Žãã¿
ã«é ž186éšããã³ãã·ã¬ã³27éšãä»èŸŒã¿ãææž©ã
ããåå¿ã«ããçæããæ°Žããã·ã¬ã³ãšå ±æ²žéæµ
ããé€å»ãããéæµéå§ããçŽïŒæéãããŠæž©åºŠ
ã190âã«ããã«ã«ãã³é žçžåœã®é žäŸ¡ã145ã«ãªã
ãŸã§æ¹æãšè±æ°Žãç¶ç¶ãã140âãŸã§å·åŽããã 次ãã§ãåå¿æ¶²æž©åºŠã140âã«ä¿æãããã«ãŒãž
ãŠã©E10ãïŒã·ãšã«ç€Ÿè£œã®ããŒãµãã€ãã¯é žã°ãª
ã·ãžã«ãšã¹ãã«ïŒ314éšã30åã§æ»Žäžãããã®åŸ
ïŒæéæ¹æãç¶ç¶ãåå¿ãçµäºãããåŸãããã
ãªãšã¹ãã«æš¹èã¯ãé žäŸ¡59ãæ°Žé žåºäŸ¡90ãïŒ
1054ã§ãã€ãã åèäŸ ïŒ æ¹æåšãçªçŽ å°å ¥ç®¡ã枩床å¶åŸ¡è£ 眮ãã³ã³ãã³
ãµãŒããã«ã³ã¿ãŒãåããïŒã³ã«ãã³ã«ãè±æ°Ž
ããã·æ²¹85éšãšã€ã·æ²¹63éšãšããªã¡ãããŒã«ãã
ãã³53éšãä»èŸŒã¿ãçªçŽ é°å²æ°äžã§æž©åºŠã240â
ã«äžããŠ30åéæ¹æãããšãããã¡ã¿ããŒã«ãã¬
ã©ã³ã¹ãç¡é倧ãšãªã€ããå 容ç©ã®æž©åºŠã150â
ã«äžããæ¹æããšããŠç¡æ°Žãã¿ã«é ž725éšãšãžãš
ãã¬ã³ã°ãªã³ãŒã«343éšãšããªã¡ãããŒã«ããã
ã³43éšãšïŒ®ïŒïŒ®âãã¹âïŒïŒâããããã·ãšãã«ïŒ
ã¢ãããšã¿ã³ã¹ã«ãã³é ž375éšãšãã·ã¬ã³45éšã
ä»èŸŒãã ãåã³æ¹æãéå§ãã枩床ãåŸã ã«äžã
ãªããçæããæ°Žããã·ã¬ã³ãšå ±æ²žéæµãããŠé€
å»ãããçŽïŒæéãããŠæž©åºŠã240âã«ãããã
ã«åäžæž©åºŠã§ã«ã«ãã³é žçžåœã®é žäŸ¡ãïŒã«ãªããŸ
ã§æ¹æãšè±æ°Žãç¶ç¶ããŠãåå¿ãçµäºãããåŸã
ããããªãšã¹ãã«æš¹èã¯æ²¹é·10ãé žäŸ¡66ãæ°Žé žåº
䟡100ãïŒ800ã§ãã€ãã åèäŸ ïŒ ããã¯ãåšãå·åŽç®¡ããã³æž©åºŠå¶åŸ¡è£ 眮ãåã
ãïŒã®ãã©ã¹ã³ãžãã¿ãŠãªã³25éšãæ°Žé žåãã
ãªãŠã ïŒéšãè±ã€ãªã³æ°Ž100éšããšãã¬ã³ã°ãªã³
ãŒã«ã¢ããšãã«ãšãŒãã«400éšãä»èŸŒã¿ããããŸ
ããªãã枩床ã100âãžããããå 容ç©ãåäžãª
溶解ç¶æ ã«ãªã€ãåŸããšãã³ãŒã828ïŒã·ãšã«ã±ã
ã«ã«ç€Ÿè£œããã¹ããšããŒã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒ
ãã«åãšããã·æš¹èããšããã·åœé190ïŒ190éšãš
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«200éšã
ããªã溶液ãïŒæéã§æ»Žäžããã滎äžåŸïŒæéã
ãã¯ããå ç±ãç¶ç¶ããŠåå¿ãçµäºãããåå¿æ¶²
ãå¡©é žã æ§ãšããåŸãããæ²æ®¿ãæ¡åããŠãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ãšæ°Žã«ããåæ²
殿æ³ã«ãã粟補ããæžå§äžã«ä¹Ÿç¥ããå€æ§ãšãã
ã·æš¹è205éšãåŸãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯48.6ã§ãè¢
å ç·åæã«ããã€ãªãŠå«éã¯ïŒïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšããã¿ãŠãªã³ã®ãã
ãªãŠã å¡©73.5éšããšãã¬ã³ã°ãªã³ãŒã«100éšããš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«200éšãä»
蟌ã¿ããããŸããªããå ç±ããŠæž©åºŠã120âã«äž
ãããå 容ç©ãåäžãªæº¶è§£ç¶æ ã«éããåŸããšã
ã³ãŒã1001ïŒã·ãšã«ã±ãã«ã«ç€Ÿè£œããã¹ããšããŒ
ã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒãã«åãšããã·æš¹èããš
ããã·åœé470ïŒ470éšãšãšãã¬ã³ã°ãªã³ãŒã«ã¢ã
ã¡ãã«ãšãŒãã«400éšãããªã溶液ãïŒæéã§æ»Ž
äžããã滎äžåŸ20æéããã¯ããšå ç±ãç¶ç¶ããŠ
åå¿ãçµäºãããåå¿ç©ãåèäŸïŒãšåæ§ã«ç²Ÿ
補ã也ç¥ããŠãå€æ§ãšããã·æš¹è518éšãåŸãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯49.4ã§ãè¢
å ç·åæã«ããã€ãªãŠã®å«éã¯2.8ïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšããâã¡ãã«ã¿ãŠ
ãªã³ã®ãããªãŠã å¡©121éšããšãã¬ã³ã°ãªã³ãŒã«
100éšããšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«
200éšãä»èŸŒã¿ããããŸããªããå ç±ããŠæž©åºŠã
120âã«ããããå 容ç©ãåäžãªæº¶è§£ç¶æ ã«éã
ãåŸããšãã³ãŒã1004ïŒã·ãšã«ã±ãã«ã«ç€Ÿè£œãã
ã¹ããšããŒã«ïŒ¡ã®ãžã°ãªã·ãžã«ãšãŒãã«åãšãã
ã·æš¹èããšããã·åœé950ïŒ475éšãšãšãã¬ã³ã°ãª
ã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«400éšãã溶液ãïŒæ
éã§æ»Žäžããã滎äžåŸ20æéããã¯ããšå ç±ãç¶
ç¶ããŠåå¿ãçµäºãããåå¿ç©ãåèäŸïŒãšåæ§
ã«ç²Ÿè£œã也ç¥ããŠãå€æ§ãšããã·æš¹è540éšãåŸ
ãã ãã®æš¹èã®KOH滎å®ã«ããé žäŸ¡ã¯50ã§ãè¢å
ç·åæã«ããã€ãªãŠã®å«éã¯2.9ïŒ ã§ãã€ãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªè£ 眮ãçšãããšãã¬ã³ã°ãªã³
ãŒã«ã¢ãã¡ãã«ãšãŒãã«100éšãä»èŸŒã¿ã100âã«
ææž©ãä¿æããã滎äžããŒããäºæ¬çšæããäžæ¹
ã«100éšã®ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒã
ã«ãå ¥ããã®äžã«ïŒ®âã¡ãã«ââïŒããã«ãã³
ãžã«ïŒã¿ãŠãªã³ã75éšæº¶ããããã®éã溶解è£å©
å€ãšããŠå°éã®ãžã¡ãã«ãšã¿ããŒã«ã¢ãã³ãå ã
ãã ããã«äžæ¹ã®æ»ŽäžããŒããšïŒâããããã·ãšã
ã«ã¢ã¯ãªã¬ãŒã50éšãã¢ã¯ãªã«é ž10éšãã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒã110éšãã¹ãã¬ã³110éšãïœâããã«
ã¢ã¯ãªã¬ãŒã145éšããã³ã©ãŠãªã«ã¡ã«ã«ãã¿ã³
10éšãæ··åããã¢ãŸãã¹ã€ãœããããããªã«10éš
ã溶解ããã äºæ¬ã®æ»ŽäžããŒãå 容ç©ã120åéã§æ»Žäžãã
ã®åŸæž©åºŠã100âã«ä¿æããŠ60åéæ¹æãç¶ç¶ã
ãã次ãã§ããã®æš¹è溶液ã®æº¶åªãããŒã¿ãªãŒãš
ããã¬ãŒã¿ãŒã§é€å»ããæš¹èåºåå96ïŒ ã§ïœã
4500ã®ã¢ã¯ãªã«æš¹èãåŸãã åèäŸ ïŒ åèäŸïŒãšåæ§ãªåå¿æ§åŒãçšã㊠ïŒïŒ®âãžã¡ãã«ââïŒããã«ãã³ãžã«ïŒã¢ã³
ã¢ããªé ¢é žãã¿ã€ã³ 100éš ïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒã âŠâŠ50éš ã¢ã¯ãªã«é ž âŠâŠ25éš ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã âŠâŠ80éš ã¹ãã¬ã³ âŠâŠ80éš ïœâããã«ã¢ã¯ãªã¬ãŒã âŠâŠ165éš ã©ãŠãªã«ã¡ã«ã«ãã¿ã³ âŠâŠ15éš ã¢ãŸãã¹ã€ãœããããããªã« âŠâŠ10éš ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«
âŠâŠ200éš ãããªãæš¹è溶液ãåŸãããã®æš¹è溶液ã®æº¶åªã
ããŒã¿ãªãŒãšããã¬ãŒã¿ãŒã§é€å»ããæš¹èåºåå
97ïŒ ã§ïœã3900ã®ã¢ã¯ãªã«æš¹èãåŸãã å®æœäŸ ïŒ æ¹æåšãå·åŽåšã枩床å¶åŸ¡è£ 眮ãå ·åããïŒ
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
ããªãšã¹ãã«æš¹è30éšããã³ãžã¡ãã«ãšã¿ããŒã«
ã¢ãã³ïŒéšãä»èŸŒã¿ãæ¹æäžæž©åºŠã80âã«ä¿æã
ãªãã溶解ããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž4.5
éšãè±ã€ãªã³æ°Ž45éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³
4.3éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒã70.7éšãïœâããã«ã¢ã¯ãªã¬ãŒ
ã94.2éšãã¹ãã¬ã³70.7éšãïŒâããããã·ãšã
ã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒã«ãž
ã¡ã¿ã¯ãªã¬ãŒã4.5éšãããªãæ··å溶液ã60åé
èŠããŠæ»Žäžããã滎äžåŸãæŽã«ã¢ãŸãã¹ã·ã¢ãå
èé ž1.5éšãè±ã€ãªã³æ°Ž15éšãšãžã¡ãã«ãšã¿ããŒ
ã«ã¢ãã³1.4éšã«æº¶è§£ãããã®ãæ·»å ããŠ80âã§
60åéæ¹æãç¶ãããšãããäžæ®çºå45ïŒ ãPH
7.4ãç²åºŠ78cpsïŒ25âïŒãç²ååŸ0.138ÎŒïŒå æ£ä¹±æ³
ã«ãããé»åé¡åŸ®é¡ã«ããç²ååŸã¯0.052ÎŒã§ã
ãã以äžåŸè ã®å€ãåè ã®å€ã®çŽåŸã«ã«ãã³å ã«
䜵èšãããïŒã®ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.3ïŒ ïŒå¯Ÿçæãš
ãã«ãžãšã³æ¯ïŒã§ãããåéç©ã®çæã¯æ¥µããŠåŸ®
éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§ããã
宀枩ã§ïŒã±ææŸçœ®ããŠãåéç©ãæ²ã§ããçãã
ããšããªãå®å®ã§ãã€ãã ãªãäžèšç²åºŠã¯ïŒ¢åç²åºŠèšãç²ååŸã¯å æ£ä¹±æ³
ã§æž¬å®ããæ©æ¢°çå®å®æ§ã¯ãšãã«ãžãšã³ã®ïŒæ»Žã
芪æãšäººå·®ãæã®éã§ïŒåãããåããããšãè
çãããããªããã®ãè¯å¥œãšããã 以äžã®å®æœäŸã«ãããŠãåæ§ã§ããã å®æœäŸ ïŒ å®æœäŸïŒã®è£œé æ¹æ³ã«ãããŠãåèäŸïŒã§åŸã
ããªãšã¹ãã«æš¹è30éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ã
ã³ïŒéšã®ãããã«åèäŸïŒã§åŸãããªãšã¹ãã«æš¹
è10éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³0.75éšã䜿çš
ãã以å€ã¯ãåæ§ãªææ³ããã³æ¡ä»¶ã«åŸã€ãŠäžæ®
çºå45ïŒ ãPH7.2ãç²åºŠ92cpsïŒ25âïŒãç²ååŸ
0.156ÎŒïŒ0.102ÎŒïŒã®ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.2ïŒ ã§ããã極
ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§
ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒãšåãåå¿å®¹åšã«è±ã€ãªã³æ°Ž306éšã
åèäŸïŒã§åŸãããªãšã¹ãã«æš¹è20éšããã³ããª
ãšãã«ã¢ãã1.8éšãä»èŸŒã¿ãæ¹æäžæž©åºŠã75â
ã«ä¿æããªãã溶解ããããã«ã¢ãŸãã¹ã·ã¢ãå
èé ž4.5éšãè±ã€ãªã³æ°Ž45éšãšããªãšãã«ã¢ãã³
4.9éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒã150éšãïœâããã«ã¢ã¯ãªã¬ãŒ
ã127éšããžããã«ãã³ãŒã³ïŒéšãããªãæ··å溶
液ã90åéãèŠããŠæ»Žäžããã滎äžåŸãæŽã«ã¢ãŸ
ãã¹ã·ã¢ãåèé ž1.5éšãè±ã€ãªã³æ°Ž15éšãšããª
ãšãã«ã¢ãã³1.6éšã«æº¶è§£ãããã®ãæ·»å ããŠ80
âã§60åéæ¹æãç¶ãããšãããäžæ®çºå45ïŒ ã
PH7.2ãç²åºŠ84cpsïŒ25âïŒãç²åŸ0.158ÎŒïŒ0.070ÎŒïŒã®
ãšãã«ãžãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.2ïŒ ã§ããã極
ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§ãè¯å¥œã§
ãã€ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã®ãšãã«ãžãšã³è£œé æ¹æ³ã«ãããŠã第
ïŒè¡šã«ç€ºãå²åïŒéšïŒã§ããªãšã¹ãã«æš¹èãè±ã€
ãªã³æ°Žããžã¡ãã«ãšã¿ããŒã«ã¢ãããšæ··å溶液ãš
ãããããçšããæå®ã®æ»Žäžæéã§æ»Žäžãã以å€
ã¯åæ§ãªææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ã®ãšãã«ãž
ãšã³ïŒNo.ïŒãïŒïŒãåŸããããããšãã«ãžãšã³ã®
æ§ç¶ããã³400ã¡ãã·ãŠã®é網ã§éããéã®äž
ééåã第ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
ã«ã¢ã¯ãªã¬ãŒããïŒïŒïŒ¡ã¯ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒ
ããã¯ã¹ãã¬ã³ãïœâã¯ïœâããã«ã¢
ã¯ãªã¬ãŒããïŒã¯ããã·ã«ã¡ã«ã«ãã¿ã³ã
ïŒã¯ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ã¯ãžããã«ãã³ãŒã³ã瀺ãã
泚ïŒå®æœäŸïŒãšïŒã®æ··å溶液ã®çµæïŒéšïŒã¯ã以äž
ã®ãšããã§ããã
ããã¯ã¹ãã¬ã³ãïœâã¯ïœâããã«ã¢
ã¯ãªã¬ãŒããïŒã¯ããã·ã«ã¡ã«ã«ãã¿ã³ã
ïŒã¯ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãã
ã¯ãžããã«ãã³ãŒã³ã瀺ãã
泚ïŒå®æœäŸïŒãšïŒã®æ··å溶液ã®çµæïŒéšïŒã¯ã以äž
ã®ãšããã§ããã
ãè¡šã
å®æœäŸ 10
å®æœäŸïŒãšåãåå¿å®¹åšã«ãè±ã€ãªã³æ°Ž408éšã
ãžã¡ãã«ãšã¿ããŒã«ã¢ããïŒéšãä»èŸŒã¿ãæ¹æäž
枩床ã80âã«ä¿æããªããã¢ãŸãã¹ã·ã¢ãåèé ž
6.4éšãè±ã€ãªã³æ°Ž64éšãšãžã¡ãã«ãšã¿ããŒã«ã¢
ãã6.1éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ã
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã94.8éšãïœâããã«ã¢ã¯ãª
ã¬ãŒã126.4éšãã¹ãã¬ã³94.8éšãïŒâãããã
ã·ã¢ã¯ãªã¬ãŒã40éšããã³ãšãã¬ã³ã°ãªã³ãŒã«ãž
ã¡ã¿ã¯ãªã¬ãŒãïŒéšã«åèäŸïŒã®ããªãšã¹ãã«æš¹
è40éšã溶解ããæ··å液ã60åéãèŠããŠæ»Žäžã
ãã滎äžåŸãæŽã«ã¢ãŸãã¹ã·ã¢ãåèé ž1.6éšã
è±ã€ãªã³æ°Ž16éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³1.5
éšã«æº¶è§£ãã溶液ãæ·»å ããŠã80âã§60åéæ¹æ
ãç¶ãããšãããäžæ®çºå45ïŒ ãPH7.2ãç²åºŠ
96cpsïŒ25âïŒãç²ååŸ0.168ÎŒïŒ0.055ÎŒïŒã®ãšãã«ãž
ãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.1ïŒ ã§ãããå
éç©ã®çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°ç
å®å®æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 11 æ¹æåšãå·åŽåšã枩床å¶åŸ¡è£ 眮ãåããïŒã®
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
å€æ§ãšããã·æš¹è7.5éšããžã¡ãã«ãšã¿ããŒã«ã¢
ãã³1.0éšãä»èŸŒã¿ããããŸããªãã80âãŸã§æ
æž©ããããå 容ç©ã溶解ããåŸããããŸããªãã
枩床ã80âã«ä¿æããããã«ã¢ãŸãã¹ã·ã¢ãåè
é ž4.8éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³4.56éšãã
ã³è±ã€ãªã³æ°Ž48éšãããªã氎溶液ãä»èŸŒã¿ãã€ã
ã§ã¹ãã¬ã³80éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã80éšãïœ
âããã«ã¢ã¯ãªã¬ãŒã107éšãïŒâããããã·ãš
ãã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒã«
ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å液ã60åéã
èŠããŠæ»Žäžããã滎äžåŸãããã«å枩床ã§ã¢ãŸã
ã¹ã·ã¢ãåèé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢ã
ã³1.14éšããã³è±ã€ãªã³æ°Ž12éšãããªãæ··å氎溶
液ãæ·»å ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå
47ïŒ ãPH7.2ãç²åºŠ76cpsïŒ25âïŒãç²ååŸ0.112ÎŒ
ïŒ0.041ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯0.2ïŒ ã§ããåéç©
ã®çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®
æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 12 ã¹ãã³ã¬ã¹å®¹åšã«è±ã€ãªã³æ°Ž200éšãããªãšã
ã«ã¢ãã³0.2éšãå ãããã€ã¹ããŒã§ãããŸããª
ããåèäŸïŒã§åŸãå€æ§ãšããã·æš¹èïŒéšãå
ããæ··åç©ã®æž©åºŠã70âã«äžãã10åéãããŸã
ããšãããããã«çœæ¿ãã氎溶液ãåŸãããã次
ã«ãã®æ°Žæº¶æ¶²ãå®æœäŸïŒã§çšããã®ãšåæ§ã®åå¿
容åšã«ä»èŸŒã¿ãè±ã€ãªã³æ°Ž106éšãå ããããŸã
ãªãã枩床ã80âã«ä¿æãããããã«ã¢ãŸãã¹ã·
ã¢ãåèé ž4.5éšãããªãšãã«ã¢ãã³4.9éšããã³
è±ã€ãªã³æ°Ž45éšãããªãæ··å氎溶液ãå ãã枩床
ã80âã«ä¿æããªããã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã150
éšãïœâããã«ã¢ã¯ãªã¬ãŒã142éšããšãã¬ã³ã°
ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å溶液
ã120åãèŠããŠæ»Žäžããã滎äžåŸãããã«åæž©
床ã§ã¢ãŸãã¹ã·ã¢ãåèé ž1.5éšããªãšãã«ã¢ã
ã³1.6éšããã³è±ã€ãªã³æ°Ž15éšãããªãæ··å氎溶
液ãæ·»å ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå
45ïŒ ãPH7.2ãç²åºŠ69cpsïŒ25âïŒãç²ååŸ0.172ÎŒ
ïŒ0.050ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãšã®é網ã§é
ããéã®äžééã®åéç©ã¯0.1ïŒ ã§ããåéç©ã®
çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§
ãè¯å¥œã§ãã€ãã å®æœäŸ 13 å®æœäŸïŒãšåãåå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšã
åèäŸïŒã§åŸãå€æ§ãšããã·æš¹è45éšããã³ãžã¡
ãã«ãšã¿ããŒã«ã¢ãã³3.6éšãä»èŸŒã¿ããããŸã
ãªãã80âãŸã§ææž©ããå 容ç©ã溶解ãããåå
溶解ããåŸãããã¯ãäžæž©åºŠã80âã«ä¿æããªã
ããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž4.8éšããžã¡ã
ã«ãšã¿ããŒã«ã¢ãã³4.56éšããã³è±ã€ãªã³æ°Ž48éš
ãããªãæ··å氎溶液ãå ãã次ãã§ãã¹ãã¬ã³67
éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã67éšãïœâããã«ã¢ã¯
ãªã¬ãŒã89.5éšãïŒâããããã·ãšãã«ã¢ã¯ãªã¬
ãŒã30éšããã³ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãª
ã¬ãŒã1.5éšãããªãæ··å溶液ã150åãèŠããŠæ»Ž
äžããã滎äžåŸããã«å枩床ã§ã¢ãŸãã¹ã·ã¢ãå
èé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³1.14éšã
ãã³è±ã€ãªã³æ°Ž12éšãããªãæ··å氎溶液ãæ·»å
ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå45ïŒ ãPH
7.2ãç²åºŠ72cpsïŒ25âïŒãç²ååŸ0.120ÎŒïŒ0.032ÎŒïŒã®
ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§é
ããéã®äžééã®åéç©ã¯0.1ïŒ ã§ããåéç©ã®
çæã¯ã極ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®
æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 14ã21 å®æœäŸ11ã«ãããŠã第ïŒè¡šã«ç€ºãå²åïŒéšïŒã§
å€æ§ãšããã·æš¹èãè±ã€ãªã³æ°Žããžã¡ãã«ãšã¿ã
ãŒã«ã¢ãã³ãšæ··å溶液ãšãããããçšãã以å€
ã¯ãåæ§ã®ææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ãšãã«ãž
ãšã³ïŒNo.14ã21ïŒã補é ãããããããšãã«ãžãš
ã³ã®æ§ç¶ããã³400ã¡ãã·ãŠé網ã§éããéã®
äžééåã第ïŒè¡šã«ç€ºãã
ãžã¡ãã«ãšã¿ããŒã«ã¢ããïŒéšãä»èŸŒã¿ãæ¹æäž
枩床ã80âã«ä¿æããªããã¢ãŸãã¹ã·ã¢ãåèé ž
6.4éšãè±ã€ãªã³æ°Ž64éšãšãžã¡ãã«ãšã¿ããŒã«ã¢
ãã6.1éšã«æº¶è§£ãããã®ãæ·»å ããã次ãã§ã
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã94.8éšãïœâããã«ã¢ã¯ãª
ã¬ãŒã126.4éšãã¹ãã¬ã³94.8éšãïŒâãããã
ã·ã¢ã¯ãªã¬ãŒã40éšããã³ãšãã¬ã³ã°ãªã³ãŒã«ãž
ã¡ã¿ã¯ãªã¬ãŒãïŒéšã«åèäŸïŒã®ããªãšã¹ãã«æš¹
è40éšã溶解ããæ··å液ã60åéãèŠããŠæ»Žäžã
ãã滎äžåŸãæŽã«ã¢ãŸãã¹ã·ã¢ãåèé ž1.6éšã
è±ã€ãªã³æ°Ž16éšãšãžã¡ãã«ãšã¿ããŒã«ã¢ãã³1.5
éšã«æº¶è§£ãã溶液ãæ·»å ããŠã80âã§60åéæ¹æ
ãç¶ãããšãããäžæ®çºå45ïŒ ãPH7.2ãç²åºŠ
96cpsïŒ25âïŒãç²ååŸ0.168ÎŒïŒ0.055ÎŒïŒã®ãšãã«ãž
ãšã³ãåŸãããã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯ã0.1ïŒ ã§ãããå
éç©ã®çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°ç
å®å®æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 11 æ¹æåšãå·åŽåšã枩床å¶åŸ¡è£ 眮ãåããïŒã®
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
å€æ§ãšããã·æš¹è7.5éšããžã¡ãã«ãšã¿ããŒã«ã¢
ãã³1.0éšãä»èŸŒã¿ããããŸããªãã80âãŸã§æ
æž©ããããå 容ç©ã溶解ããåŸããããŸããªãã
枩床ã80âã«ä¿æããããã«ã¢ãŸãã¹ã·ã¢ãåè
é ž4.8éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³4.56éšãã
ã³è±ã€ãªã³æ°Ž48éšãããªã氎溶液ãä»èŸŒã¿ãã€ã
ã§ã¹ãã¬ã³80éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã80éšãïœ
âããã«ã¢ã¯ãªã¬ãŒã107éšãïŒâããããã·ãš
ãã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒã«
ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å液ã60åéã
èŠããŠæ»Žäžããã滎äžåŸãããã«å枩床ã§ã¢ãŸã
ã¹ã·ã¢ãåèé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢ã
ã³1.14éšããã³è±ã€ãªã³æ°Ž12éšãããªãæ··å氎溶
液ãæ·»å ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå
47ïŒ ãPH7.2ãç²åºŠ76cpsïŒ25âïŒãç²ååŸ0.112ÎŒ
ïŒ0.041ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ããããšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§
éããéã®äžééã®åéç©ã¯0.2ïŒ ã§ããåéç©
ã®çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®
æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 12 ã¹ãã³ã¬ã¹å®¹åšã«è±ã€ãªã³æ°Ž200éšãããªãšã
ã«ã¢ãã³0.2éšãå ãããã€ã¹ããŒã§ãããŸããª
ããåèäŸïŒã§åŸãå€æ§ãšããã·æš¹èïŒéšãå
ããæ··åç©ã®æž©åºŠã70âã«äžãã10åéãããŸã
ããšãããããã«çœæ¿ãã氎溶液ãåŸãããã次
ã«ãã®æ°Žæº¶æ¶²ãå®æœäŸïŒã§çšããã®ãšåæ§ã®åå¿
容åšã«ä»èŸŒã¿ãè±ã€ãªã³æ°Ž106éšãå ããããŸã
ãªãã枩床ã80âã«ä¿æãããããã«ã¢ãŸãã¹ã·
ã¢ãåèé ž4.5éšãããªãšãã«ã¢ãã³4.9éšããã³
è±ã€ãªã³æ°Ž45éšãããªãæ··å氎溶液ãå ãã枩床
ã80âã«ä¿æããªããã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã150
éšãïœâããã«ã¢ã¯ãªã¬ãŒã142éšããšãã¬ã³ã°
ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å溶液
ã120åãèŠããŠæ»Žäžããã滎äžåŸãããã«åæž©
床ã§ã¢ãŸãã¹ã·ã¢ãåèé ž1.5éšããªãšãã«ã¢ã
ã³1.6éšããã³è±ã€ãªã³æ°Ž15éšãããªãæ··å氎溶
液ãæ·»å ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå
45ïŒ ãPH7.2ãç²åºŠ69cpsïŒ25âïŒãç²ååŸ0.172ÎŒ
ïŒ0.050ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãšã®é網ã§é
ããéã®äžééã®åéç©ã¯0.1ïŒ ã§ããåéç©ã®
çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§
ãè¯å¥œã§ãã€ãã å®æœäŸ 13 å®æœäŸïŒãšåãåå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšã
åèäŸïŒã§åŸãå€æ§ãšããã·æš¹è45éšããã³ãžã¡
ãã«ãšã¿ããŒã«ã¢ãã³3.6éšãä»èŸŒã¿ããããŸã
ãªãã80âãŸã§ææž©ããå 容ç©ã溶解ãããåå
溶解ããåŸãããã¯ãäžæž©åºŠã80âã«ä¿æããªã
ããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž4.8éšããžã¡ã
ã«ãšã¿ããŒã«ã¢ãã³4.56éšããã³è±ã€ãªã³æ°Ž48éš
ãããªãæ··å氎溶液ãå ãã次ãã§ãã¹ãã¬ã³67
éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã67éšãïœâããã«ã¢ã¯
ãªã¬ãŒã89.5éšãïŒâããããã·ãšãã«ã¢ã¯ãªã¬
ãŒã30éšããã³ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãª
ã¬ãŒã1.5éšãããªãæ··å溶液ã150åãèŠããŠæ»Ž
äžããã滎äžåŸããã«å枩床ã§ã¢ãŸãã¹ã·ã¢ãå
èé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³1.14éšã
ãã³è±ã€ãªã³æ°Ž12éšãããªãæ··å氎溶液ãæ·»å
ãã60åéããã¯ããç¶ç¶ããŠäžæ®çºå45ïŒ ãPH
7.2ãç²åºŠ72cpsïŒ25âïŒãç²ååŸ0.120ÎŒïŒ0.032ÎŒïŒã®
ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãŠã®é網ã§é
ããéã®äžééã®åéç©ã¯0.1ïŒ ã§ããåéç©ã®
çæã¯ã極ããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®
æ§ãè¯å¥œã§ãã€ãã å®æœäŸ 14ã21 å®æœäŸ11ã«ãããŠã第ïŒè¡šã«ç€ºãå²åïŒéšïŒã§
å€æ§ãšããã·æš¹èãè±ã€ãªã³æ°Žããžã¡ãã«ãšã¿ã
ãŒã«ã¢ãã³ãšæ··å溶液ãšãããããçšãã以å€
ã¯ãåæ§ã®ææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ãšãã«ãž
ãšã³ïŒNo.14ã21ïŒã補é ãããããããšãã«ãžãš
ã³ã®æ§ç¶ããã³400ã¡ãã·ãŠé網ã§éããéã®
äžééåã第ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
ãè¡šã
å®æœäŸ 22
æ¹æåšãå·åŽç®¡ã枩床å¶åŸ¡è£
眮ãåããïŒã®
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
ã¢ã¯ãªã«æš¹è18éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³
2.6éšãä»èŸŒã¿ããããŸããªãã80âãŸã§ææž©ã
ãããå 容ç©ã溶解ããåŸããããŸããªãã枩床
ã80âã«ä¿æããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž
4.8éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³4.56éšããã³
è±ã€ãªã³æ°Ž48éšãããªã氎溶液ãä»èŸŒã¿ã次ãã§
ã¹ãã¬ã³74.7éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã74.7éšã
ïœâããã«ã¢ã¯ãªã¬ãŒã99.6éšãïŒâããããã·
ãšãã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒ
ã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å液ã60åé
ãèŠããŠæ»Žäžããã滎äžåŸãããã«å枩床ã§ã¢ãŸ
ãã¹ã·ã¢ãåèé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢
ãã1.14éšããã³è±ã€ãªã³æ°Ž12éšãããªãæ··åæ°Ž
溶液ãæ·»å ãã60åéæ¹æãç¶ç¶ããŠäžæ®çºå45
ïŒ ãPH7.4ãç²åºŠ92cpsïŒ25âïŒãç²ååŸ0.132ÎŒ
ïŒ0.090ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãšé網ã§éã
ãéã®äžééã®åéç©ã¯0.6ïŒ ã§ãããåéç©ã®
çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§
ãè¯å¥œã§ãã€ãã å®æœäŸ 23ã26 å®æœäŸ22ã«ãããŠã第ïŒè¡šã«ç€ºãå²åïŒéšïŒã§
ã¢ã¯ãªã«æš¹èãè±ã€ãªã³æ°Žããžã¡ãã«ãšã¿ããŒã«
ã¢ãã³ãšæ··å溶液ãšãããããçšãã以å€ã¯ãå
æ§ã®ææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ãšãã«ãžãšã³
ïŒNo.23ã26ïŒãåŸããããããšãã«ãžãšã³ã®æ§ç¶
ããã³400ã¡ãã·ãŠé網ã§éããéã®äžééå
ã第ïŒè¡šã«ç€ºãã
åå¿å®¹åšã«ãè±ã€ãªã³æ°Ž306éšãåèäŸïŒã§åŸã
ã¢ã¯ãªã«æš¹è18éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³
2.6éšãä»èŸŒã¿ããããŸããªãã80âãŸã§ææž©ã
ãããå 容ç©ã溶解ããåŸããããŸããªãã枩床
ã80âã«ä¿æããããã«ã¢ãŸãã¹ã·ã¢ãåèé ž
4.8éšããžã¡ãã«ãšã¿ããŒã«ã¢ãã³4.56éšããã³
è±ã€ãªã³æ°Ž48éšãããªã氎溶液ãä»èŸŒã¿ã次ãã§
ã¹ãã¬ã³74.7éšãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã74.7éšã
ïœâããã«ã¢ã¯ãªã¬ãŒã99.6éšãïŒâããããã·
ãšãã«ã¢ã¯ãªã¬ãŒã30éšããã³ãšãã¬ã³ã°ãªã³ãŒ
ã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒéšãããªãæ··å液ã60åé
ãèŠããŠæ»Žäžããã滎äžåŸãããã«å枩床ã§ã¢ãŸ
ãã¹ã·ã¢ãåèé ž1.2éšããžã¡ãã«ãšã¿ããŒã«ã¢
ãã1.14éšããã³è±ã€ãªã³æ°Ž12éšãããªãæ··åæ°Ž
溶液ãæ·»å ãã60åéæ¹æãç¶ç¶ããŠäžæ®çºå45
ïŒ ãPH7.4ãç²åºŠ92cpsïŒ25âïŒãç²ååŸ0.132ÎŒ
ïŒ0.090ÎŒïŒã®ãšãã«ãžãšã³ãåŸãã ãã®ãšãã«ãžãšã³ã400ã¡ãã·ãšé網ã§éã
ãéã®äžééã®åéç©ã¯0.6ïŒ ã§ãããåéç©ã®
çæã¯æ¥µããŠåŸ®éã§ãã€ãããŸããæ©æ¢°çå®å®æ§
ãè¯å¥œã§ãã€ãã å®æœäŸ 23ã26 å®æœäŸ22ã«ãããŠã第ïŒè¡šã«ç€ºãå²åïŒéšïŒã§
ã¢ã¯ãªã«æš¹èãè±ã€ãªã³æ°Žããžã¡ãã«ãšã¿ããŒã«
ã¢ãã³ãšæ··å溶液ãšãããããçšãã以å€ã¯ãå
æ§ã®ææ³ããã³æ¡ä»¶ã«åŸã€ãŠåçš®ãšãã«ãžãšã³
ïŒNo.23ã26ïŒãåŸããããããšãã«ãžãšã³ã®æ§ç¶
ããã³400ã¡ãã·ãŠé網ã§éããéã®äžééå
ã第ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
ïŒåç¬ãŸãã¯ã¢ãããã©ã¹ãæš¹èãšãã¬ã³ããã
ãšãã«ãžãšã³ã®æ°Žæ§å¡æçµæç©ïŒ å®æœäŸ 27 å®æœäŸïŒã§åŸããšãã«ãžãšã³ãã¬ã©ã¹æ¿ã«ããŒ
ã³ãŒã¿ãŒïŒ30ã§å¡è£ ãã宀枩ã§ä¹Ÿç¥ããããšã
ããéæã§åäžãªå¡èãåŸãããã ãŸãåæ§ã«æ¥æ¬ãã¹ãããã«ç€Ÿã®0.8mmã®ãã³
ã144åŠçéŒæ¿ã«ããŒã³ãŒã¿ãŒïŒ30ã§å¡è£ ãã
ç±é¢šä¹Ÿç¥æ©ã«ãã100âã§ïŒåé也ç¥ããããšã
ããéæã§åäžãªå¡èãåŸããããã®60ãã°ãã¹
ã¯75ã§ãã€ãã ããã«å®æœäŸïŒãªããïŒããã³11ãªãã16ãŸã§
ã§åŸããããšãã«ãžãšã³ã«ã€ããŠåæ§ã«ããŒã³ãŒ
ã¿ãŒã«ããå¡è£ ããé èããããšããããããã
éæã§åäžãªå¡èãåŸãããšãã§ããã å®æœäŸ 28 å®æœäŸïŒã§åŸããããšãã«ãžãšã³200éšã«ãã
ããµã¡ããã·ã¡ã©ãã³ïŒã¢ã¡ãªã«ã³ãµã€ã¢ããã
瀟補åååããµã€ã¡ã«303ãïŒ23éšããšãã¬ã³ã°ãª
ã³ãŒã«ã¢ãããã«ãšãŒãã«14éšãšè±ã€ãªã³æ°Ž14éš
ãšã«æº¶è§£ããã¢ãããã©ã¹ãæš¹è溶液ãã©ããã
ãµãŒã§ãããŸããªããåŸã ã«æ·»å ããããã«ãžã¡
ãã«ã¢ãããšã¿ããŒã«ã§PHã8.3ã«èª¿ç¯ããç±ç¡¬
åæ§å¡æçµæç©ã補é ããã äžèšçµæç©ãæ¥æ¬ãã¹ãããã«ç€Ÿã®0.8mmãã³
ã144åŠçéŒæ¿ã«ä¹Ÿç¥å¡èã20ÎŒãšãªãããã«
å¡è£ ãã10åéã»ããã€ã³ã°ããåŸã120âã140
âããã³160âã®æž©åºŠã§ãããã30åéç±ç¡¬åã
ãããšãããè¡šé¢ãå¹³æ»ã§éæãªå¡èãåŸãã
ãããããå¡èã100âã®æ²žãšãæ°Žã«ïŒæé浞挬
ãããšããã溶解çããã³èšæœ€çã¯ããããçŒä»
枩床ã¯120âã§ã¯6.8ïŒ ããã³30.2ïŒ ã140âã§ã¯
1.8ïŒ ããã³15.2ïŒ ã160âã§ã¯0.5ïŒ ããã³6.2ïŒ
ã§ãã€ãããŸãæ±çšå¡æçšã·ã³ããŒã«ïŒæé浞挬
ããçµæã溶解çããã³èšæœ€çã¯ãããããçŒä»
枩床120âã§ã¯5.8ïŒ ããã³48.0ïŒ ã140âã§ã¯0.9
ïŒ ããã³26.2ïŒ ã160âã§ã¯0.5ïŒ ããã³8.2ïŒ ã§ã
ã€ãã ãªãäžèšæº¶è§£çããã³èšæœ€çã¯äžåŒã«åŸã€ãŠç®
åºããã 溶解çïŒïŒ¢âïŒïŒ¢âÃ100ïŒïŒ ïŒ èšæœ€çïŒïŒ£âïŒïŒ€âÃ100ïŒïŒ ïŒ åŒäžïŒ¡ã¯éŒæ¿ã®ééãã¯éŒæ¿ãšå¡èã®ç·é
éãã¯æµžæŒ¬çµäºçŽåŸã®éŒæ¿ãšå¡èã®ç·ééãã
ãã³ïŒ€ã¯æµžæŒ¬çµäºåŸ120âÃ20åã§ä¹Ÿç¥ãããšã
ã®éŒæ¿ãšå¡èã®ç·ééãæå³ããã å®æœäŸ 29 å®æœäŸïŒã§åŸããããšãã«ãžãšã³200éšã«ãã¡
ããã·ã¡ãããŒã«ã¡ã©ãã³ïŒã¢ã¡ãªã«ã³ãµã€ã¢ã
ãã瀟補åååããµã€ã¡ã«370ãïŒ25.6éšããšãã¬
ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«11.4éšãšè±ã€ãª
ã³æ°Ž14éšãšã«æº¶è§£ããã¢ãããã©ã¹ãæš¹è溶液ã
ã©ããããµãŒã§ãããŸããªããåŸã ã«æ·»å ããã
ãã«ãžã¡ãã«ã¢ãããšã¿ããŒã«ã§PH8.3ã«èª¿ç¯ã
ãŠç±ç¡¬åæ§å¡æçµæç©ãåŸãã次ã«å®æœäŸïŒãšå
æ§ã«ããŠçŒä»å¡èã圢æãã沞ãšã氎浞挬æã®æº¶
解çããã³èšæœ€çã枬å®ãããšãããããããçŒ
ä»æž©åºŠã¯120âã§ã¯3.0ïŒ ããã³30.2ïŒ ã140âã§
ã¯1.7ïŒ ããã³22.8ïŒ ã160âã§ã¯0.9ïŒ ããã³10.2
ïŒ ã§ãã€ãããŸãæ±çšå¡æçšã·ã³ããŒã«ïŒæé浞
挬ãããšãã®æº¶è§£çããã³èšæœ€çã¯ãããããçŒ
ä»æž©åºŠ120âã§ã¯0.8ïŒ ããã³20.2ïŒ ã140âã§ã¯
0.4ïŒ ããã³17.4ïŒ ã160âã§ã¯0.2ïŒ ããã³12.1ïŒ
ã§ãã€ãã å®æœäŸ 30 å®æœäŸ28ã«ãããŠããšãã«ãžãšã³ãšããŠå®æœäŸ
ïŒãïŒããã³ïŒãªãã26ã§åŸããããšãã«ãžãšã³
ãããããã¢ãããã©ã¹ãæš¹èãšã®åºåœ¢æ¯ãïŒå¯Ÿ
ïŒã«ãªãããã«äœ¿çšãã以å€ã¯ãå®æœäŸ28ãšåã
æäœãç¹°ãè¿ããç±ç¡¬åæ§å¡æçµæç©ãšãããçš
ãã硬åå¡èãåŸããå¡èã¯ããããå¹³æ»éæ
ã§ããããã®çŒä»æž©åºŠã§åŸãããå¡èã«ãããŠ
ããèæ°Žæ§ã¯è¯å¥œã§ãã€ãã
ãšãã«ãžãšã³ã®æ°Žæ§å¡æçµæç©ïŒ å®æœäŸ 27 å®æœäŸïŒã§åŸããšãã«ãžãšã³ãã¬ã©ã¹æ¿ã«ããŒ
ã³ãŒã¿ãŒïŒ30ã§å¡è£ ãã宀枩ã§ä¹Ÿç¥ããããšã
ããéæã§åäžãªå¡èãåŸãããã ãŸãåæ§ã«æ¥æ¬ãã¹ãããã«ç€Ÿã®0.8mmã®ãã³
ã144åŠçéŒæ¿ã«ããŒã³ãŒã¿ãŒïŒ30ã§å¡è£ ãã
ç±é¢šä¹Ÿç¥æ©ã«ãã100âã§ïŒåé也ç¥ããããšã
ããéæã§åäžãªå¡èãåŸããããã®60ãã°ãã¹
ã¯75ã§ãã€ãã ããã«å®æœäŸïŒãªããïŒããã³11ãªãã16ãŸã§
ã§åŸããããšãã«ãžãšã³ã«ã€ããŠåæ§ã«ããŒã³ãŒ
ã¿ãŒã«ããå¡è£ ããé èããããšããããããã
éæã§åäžãªå¡èãåŸãããšãã§ããã å®æœäŸ 28 å®æœäŸïŒã§åŸããããšãã«ãžãšã³200éšã«ãã
ããµã¡ããã·ã¡ã©ãã³ïŒã¢ã¡ãªã«ã³ãµã€ã¢ããã
瀟補åååããµã€ã¡ã«303ãïŒ23éšããšãã¬ã³ã°ãª
ã³ãŒã«ã¢ãããã«ãšãŒãã«14éšãšè±ã€ãªã³æ°Ž14éš
ãšã«æº¶è§£ããã¢ãããã©ã¹ãæš¹è溶液ãã©ããã
ãµãŒã§ãããŸããªããåŸã ã«æ·»å ããããã«ãžã¡
ãã«ã¢ãããšã¿ããŒã«ã§PHã8.3ã«èª¿ç¯ããç±ç¡¬
åæ§å¡æçµæç©ã補é ããã äžèšçµæç©ãæ¥æ¬ãã¹ãããã«ç€Ÿã®0.8mmãã³
ã144åŠçéŒæ¿ã«ä¹Ÿç¥å¡èã20ÎŒãšãªãããã«
å¡è£ ãã10åéã»ããã€ã³ã°ããåŸã120âã140
âããã³160âã®æž©åºŠã§ãããã30åéç±ç¡¬åã
ãããšãããè¡šé¢ãå¹³æ»ã§éæãªå¡èãåŸãã
ãããããå¡èã100âã®æ²žãšãæ°Žã«ïŒæé浞挬
ãããšããã溶解çããã³èšæœ€çã¯ããããçŒä»
枩床ã¯120âã§ã¯6.8ïŒ ããã³30.2ïŒ ã140âã§ã¯
1.8ïŒ ããã³15.2ïŒ ã160âã§ã¯0.5ïŒ ããã³6.2ïŒ
ã§ãã€ãããŸãæ±çšå¡æçšã·ã³ããŒã«ïŒæé浞挬
ããçµæã溶解çããã³èšæœ€çã¯ãããããçŒä»
枩床120âã§ã¯5.8ïŒ ããã³48.0ïŒ ã140âã§ã¯0.9
ïŒ ããã³26.2ïŒ ã160âã§ã¯0.5ïŒ ããã³8.2ïŒ ã§ã
ã€ãã ãªãäžèšæº¶è§£çããã³èšæœ€çã¯äžåŒã«åŸã€ãŠç®
åºããã 溶解çïŒïŒ¢âïŒïŒ¢âÃ100ïŒïŒ ïŒ èšæœ€çïŒïŒ£âïŒïŒ€âÃ100ïŒïŒ ïŒ åŒäžïŒ¡ã¯éŒæ¿ã®ééãã¯éŒæ¿ãšå¡èã®ç·é
éãã¯æµžæŒ¬çµäºçŽåŸã®éŒæ¿ãšå¡èã®ç·ééãã
ãã³ïŒ€ã¯æµžæŒ¬çµäºåŸ120âÃ20åã§ä¹Ÿç¥ãããšã
ã®éŒæ¿ãšå¡èã®ç·ééãæå³ããã å®æœäŸ 29 å®æœäŸïŒã§åŸããããšãã«ãžãšã³200éšã«ãã¡
ããã·ã¡ãããŒã«ã¡ã©ãã³ïŒã¢ã¡ãªã«ã³ãµã€ã¢ã
ãã瀟補åååããµã€ã¡ã«370ãïŒ25.6éšããšãã¬
ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«11.4éšãšè±ã€ãª
ã³æ°Ž14éšãšã«æº¶è§£ããã¢ãããã©ã¹ãæš¹è溶液ã
ã©ããããµãŒã§ãããŸããªããåŸã ã«æ·»å ããã
ãã«ãžã¡ãã«ã¢ãããšã¿ããŒã«ã§PH8.3ã«èª¿ç¯ã
ãŠç±ç¡¬åæ§å¡æçµæç©ãåŸãã次ã«å®æœäŸïŒãšå
æ§ã«ããŠçŒä»å¡èã圢æãã沞ãšã氎浞挬æã®æº¶
解çããã³èšæœ€çã枬å®ãããšãããããããçŒ
ä»æž©åºŠã¯120âã§ã¯3.0ïŒ ããã³30.2ïŒ ã140âã§
ã¯1.7ïŒ ããã³22.8ïŒ ã160âã§ã¯0.9ïŒ ããã³10.2
ïŒ ã§ãã€ãããŸãæ±çšå¡æçšã·ã³ããŒã«ïŒæé浞
挬ãããšãã®æº¶è§£çããã³èšæœ€çã¯ãããããçŒ
ä»æž©åºŠ120âã§ã¯0.8ïŒ ããã³20.2ïŒ ã140âã§ã¯
0.4ïŒ ããã³17.4ïŒ ã160âã§ã¯0.2ïŒ ããã³12.1ïŒ
ã§ãã€ãã å®æœäŸ 30 å®æœäŸ28ã«ãããŠããšãã«ãžãšã³ãšããŠå®æœäŸ
ïŒãïŒããã³ïŒãªãã26ã§åŸããããšãã«ãžãšã³
ãããããã¢ãããã©ã¹ãæš¹èãšã®åºåœ¢æ¯ãïŒå¯Ÿ
ïŒã«ãªãããã«äœ¿çšãã以å€ã¯ãå®æœäŸ28ãšåã
æäœãç¹°ãè¿ããç±ç¡¬åæ§å¡æçµæç©ãšãããçš
ãã硬åå¡èãåŸããå¡èã¯ããããå¹³æ»éæ
ã§ããããã®çŒä»æž©åºŠã§åŸãããå¡èã«ãããŠ
ããèæ°Žæ§ã¯è¯å¥œã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ åæ£çžã (a) ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšã
ã¬ã³æ§äžé£œååºãæããåéäœã®å°ãªããšãïŒ
çš® (b) åèš(a)以å€ã®éåæ§åéäœã®å°ãªããšãïŒçš®
ãšã®æ¶æ©å ±éåäœã®åŸ®ç²åãããªãã åæ£åªãæ°Žæ§æº¶åªãããªãã ç³»å ã«ãååäžã«åŒãåŒãåºãŸã ã¯ãåŒãåº ïŒåŒäžïŒ²ã¯çœ®æåºãæããããšãããC1ãC6
ã®ã¢ã«ãã¬ã³ãããã¯ããšãã¬ã³åºã§ãããïŒ
ãæãã氎溶æ§æš¹èãå«æãããšãã«ãžãšã³ã ïŒ åèš(a)ã®åéäœã¯ãå€äŸ¡ã¢ã«ã³ãŒã«ã®éåæ§
äžé£œåã¢ãã«ã«ãã³é žã®ãšã¹ãã«ããå€å¡©åºé žã®
éåæ§äžé£œåã¢ã«ã³ãŒã«ãšã¹ãã«ãããŸãã¯ïŒå
以äžã®ããã«åºã§çœ®æãããè³éŠæååç©ããéž
ã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã®ãšãã«ãžãšã³ã ïŒ åèš(b)ã®åéäœã¯ãã«ã«ããã·åºå«æåé
äœãããããã·åºå«æåéäœãå«çªçŽ ã¢ã«ãã«ã¢
ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§ã¢ã
ããéåæ§ãããªã«ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒããã
ãã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§è³éŠæååç©ãαâ
ãªã¬ãã€ã³ååç©ãããã«ååç©ããŸã¯ããžãšã³
ååç©ããéžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯
第ïŒé ã®ãšãã«ãžãšã³ã ïŒ åèš(b)ã®åéäœãšããŠããããã·åºå«æåé
äœãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé ã®ãš
ãã«ãžãšã³ã ïŒ éåéå§å€ã®ååšäžãååå ã«åŒ ãåŒãåºãŸãã¯ãåŒãåº ïŒåŒäžïŒ²ã¯çœ®æåºãæããããšãããC1ãC6ã®
ã¢ã«ãã¬ã³åºãããã¯ããšãã¬ã³åºã§ãããïŒã
æãã氎溶æ§æš¹èãå«æããæ°Žæ§åªäœäžã«ãã
ãŠã (a) ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšã
ã¬ã³æ§äžé£œååºãæããåéäœã®å°ãªããšãïŒ
çš® (b) åèš(a)以å€ã®éåæ§åéäœã®å°ãªããšãïŒçš®
ãšãä¹³åéåããäž¡è ã®æ¶æ©å ±éåäœã®åŸ®ç²å
ãåæ£çžãšããåæ£ç³»ãåŸãããšãããªããšã
ã«ãžãšã³ã®è£œé æ³ã ïŒ åèš(a)ã®åéäœã¯ãå€äŸ¡ã¢ã«ã³ãŒã«ã®éåæ§
äžé£œåã¢ãã«ã«ãã³é žã®ãšã¹ãã«ããå€å¡©åºé žã®
éåæ§äžé£œåã¢ã«ã³ãŒã«ãšã¹ãã«ãããŸãã¯ïŒå
以äžã®ããã«åºã§çœ®æãããè³éŠæååç©ããéž
ã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã®æ¹æ³ã ïŒ åèš(b)ã®åéäœã¯ãã«ã«ããã·åºå«æåé
äœãããããã·åºå«æåéäœãå«çªçŽ ã¢ã«ãã«ã¢
ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§ã¢ã
ããéåæ§ãããªã«ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒããã
ãã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§è³éŠæååç©ãαâ
ãªã¬ãã€ã³ååç©ãããã«ååç©ããŸãã¯ãžãšã³
ååç©ããéžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯
第ïŒé ã®æ¹æ³ã ïŒ åèš(b)ã®åéäœãšããŠããããã·åºå«æåé
äœãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé ã®æ¹
æ³ã ïŒ åæ£çžã (a) ååå ã«ïŒå以äžã®ã©ãžã«ã«éåå¯èœãªãšã
ã¬ã³æ§äžé£œååºãæããåéäœã®å°ãªããšãïŒ
çš® (b) åèš(a)以å€ã®éåæ§åéäœã®å°ãªããšãïŒçš®
ãšã®æ¶æ©å ±éåäœã®åŸ®ç²åãããªãã åæ£åªãæ°Žæ§æº¶åªãããªãã ç³»å ã«ãååäžã«åŒã ãåŒãåºãŸãã¯ãåŒãåº ïŒåŒäžïŒ²ã¯çœ®æåºãæããããšãããC1ãC6
ã®ã¢ã«ãã¬ã³åºãããã¯ããšãã¬ã³åºã§ãããïŒ
ãæãã氎溶æ§æš¹èãå«æãããšãã«ãžãšã³ã
å«ãå¡æçµæç©ã ïŒïŒ åèš(a)ã®åéäœã¯ãå€äŸ¡ã¢ã«ã³ãŒã«ã®éå
æ§äžé£œåã¢ãã«ã«ãã³é žã®ãšã¹ãã«ããå€å¡©åºé ž
ã®éåæ§äžé£œåã¢ã«ã³ãŒã«ãšã¹ãã«ãããŸãã¯ïŒ
å以äžã®ããã«åºã§çœ®æãããè³éŠæååç©ãã
éžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã®å¡æçµæç©ã ïŒïŒ åèš(b)ã®åéäœã¯ãã«ã«ããã·åºå«æåé
äœãããããã·åºå«æåéäœãå«çªçŽ ã¢ã«ãã«ã¢
ã¯ãªã¬ãŒããããã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§ã¢ã
ããéåæ§ãããªã«ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒããã
ãã¯ã¡ã¿ã¯ãªã¬ãŒããéåæ§è³éŠæååç©ãαâ
ãªã¬ãã€ã³ååç©ãããã«ååç©ããŸãã¯ãžãšã³
ååç©ããéžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯
第ïŒïŒé ã®å¡æçµæç©ã ïŒïŒ åèš(b)ã®åéäœãšããŠããããã·åºå«æå
éäœãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒïŒé
ã®å¡æçµæç©ã ïŒïŒ ã¢ãããã©ã¹ãæš¹èãããã«å«æããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒïŒé ã®å¡æçµæç©ã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7186481A JPS57187302A (en) | 1981-05-12 | 1981-05-12 | Emulsion resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7186481A JPS57187302A (en) | 1981-05-12 | 1981-05-12 | Emulsion resin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57187302A JPS57187302A (en) | 1982-11-18 |
JPH0143780B2 true JPH0143780B2 (ja) | 1989-09-22 |
Family
ID=13472804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7186481A Granted JPS57187302A (en) | 1981-05-12 | 1981-05-12 | Emulsion resin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57187302A (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61120869A (ja) * | 1984-11-16 | 1986-06-07 | Nippon Paint Co Ltd | ãã¿ãŒã³ããŒã«çšãšãã«ã·ã§ã³å¡æçµæç© |
JPH0635564B2 (ja) * | 1985-05-29 | 1994-05-11 | æ¥æ¬ãã€ã³ãæ ªåŒäŒç€Ÿ | æ°Žæ§å¡æçµæç© |
JPH0786122B2 (ja) * | 1986-05-30 | 1995-09-20 | æ¥æ¬ãã€ã³ãæ ªåŒäŒç€Ÿ | äžæ¬¡å æ¶æ©ããã埮å°æš¹èç²åããã³ãã®è£œé æ³ |
JPH0717735B2 (ja) * | 1987-12-25 | 1995-03-01 | æ¥æ¬ãã€ã³ãæ ªåŒäŒç€Ÿ | 埮å°æš¹èç²åã®è£œé æ³ |
JP3587267B2 (ja) * | 1994-10-07 | 2004-11-10 | æ±æŽçŽ¡çžŸæ ªåŒäŒç€Ÿ | èå¡©æ°Žæ§ã©ããã¯ã¹ |
WO2018079592A1 (ja) * | 2016-10-27 | 2018-05-03 | ãªã³ããã¯æ ªåŒäŒç€Ÿ | 芪氎æ§æš¹èçµæç©ãåã³ç©å±€ã·ãŒã |
-
1981
- 1981-05-12 JP JP7186481A patent/JPS57187302A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS57187302A (en) | 1982-11-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4205152A (en) | Thermosetting resin and its production | |
JPS62283162A (ja) | äžæ¬¡å æ¶æ©ããã埮å°æš¹èç²åããã³ãã®è£œé æ³ | |
WO1997020004A1 (fr) | Composition de resine solidifiable pour peintures a l'eau | |
US4530946A (en) | Resinous emulsion comprising microparticles for coating use and preparation thereof | |
JPH0699666B2 (ja) | è€åäžæ¬¡å åæš¹èç²åãªãã³ã«ãã®è£œæ³ | |
JPH0368074B2 (ja) | ||
JP3071998B2 (ja) | æ°Žæ§å¡æçµæç© | |
JPH07216241A (ja) | äžç²çæ§ãèåŒæ»æ§ã§äžã€èè¬åæ§ã®å¡æã®ããã®ãã€ã³ããŒãšããŠã®ããªããŒæ°Žæ§åæ£ç© | |
JPH0143780B2 (ja) | ||
JPH0135861B2 (ja) | ||
JP2002155229A (ja) | é¡æåæ£çšæ°Žæ§æš¹èçµæç©ã®è£œé æ¹æ³ | |
JPS62119271A (ja) | å¡©åºæ§è€åæš¹èç²åããã®è£œæ³ãªãã³ã«å¡æçšæš¹èçµæç© | |
JP3650994B2 (ja) | ããã«å€æ§ãšããã·æš¹èæ°Žæ§ç©ããã®è£œé æ¹æ³ããã³æ°Žæ§è¢«èŠå€ | |
JP4096345B2 (ja) | ããã«å€æ§ãšããã·ãšã¹ãã«ããã³æ°Žæ§è¢«èŠå€ | |
JPH0627124B2 (ja) | 埮å°æš¹èç²åããã³ãã®è£œæ³ | |
JPH0635564B2 (ja) | æ°Žæ§å¡æçµæç© | |
JPS63258913A (ja) | 硬åæ§æ°Žæ§æš¹èåæ£æ¶² | |
JP4273658B2 (ja) | æ°Žåæ£äœã®è£œé æ¹æ³ããã³ãã®æ°Žåæ£äœ | |
JPH0369923B2 (ja) | ||
JPH0617421B2 (ja) | ä¹³åéåçµæç© | |
JPH0211607B2 (ja) | ||
JPH0474386B2 (ja) | ||
JPS59149913A (ja) | é žåéååæ°Žæ§ãšãã«ã·ãšã³ãªãã³ã«ãã®è£œé æ³ | |
JPH07331224A (ja) | ææž©æ§ææ | |
JPH0453881B2 (ja) |