JPH0118929B2 - - Google Patents

Info

Publication number: JPH0118929B2
Authority: JP; Japan
Prior art keywords: olefins; olefin; polymerization; isomerization; trimethylaluminum
Prior art date: 1981-07-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP10762181A

Other languages

English (en)

Japanese (ja)

Other versions

JPS588708A (ja

Inventor

Takayuki Ootsu

Kyoji Endo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Petrochemical Co Ltd

Original Assignee

Mitsubishi Petrochemical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-07-10

Filing date

1981-07-10

Publication date

1989-04-07

1981-07-10 Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd

1981-07-10 Priority to JP10762181A priority Critical patent/JPS588708A/ja

1983-01-18 Publication of JPS588708A publication Critical patent/JPS588708A/ja

1989-04-07 Publication of JPH0118929B2 publication Critical patent/JPH0118929B2/ja

Status Granted legal-status Critical Current

Links

150000001336 alkenes Chemical class 0.000 claims description 39
239000004711 α-olefin Substances 0.000 claims description 36
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 25
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 23
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 18
238000000034 method Methods 0.000 claims description 17
229910052799 carbon Inorganic materials 0.000 claims description 12
239000003054 catalyst Substances 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 6
230000000379 polymerizing effect Effects 0.000 claims description 6
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
238000006116 polymerization reaction Methods 0.000 description 27
229920000642 polymer Polymers 0.000 description 24
238000006317 isomerization reaction Methods 0.000 description 20
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 13
GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 11
150000001721 carbon Chemical group 0.000 description 11
239000000178 monomer Substances 0.000 description 11
230000000052 comparative effect Effects 0.000 description 10
JTXUVHFRSRTSAT-UHFFFAOYSA-N 3,5,5-trimethylhex-1-ene Chemical compound C=CC(C)CC(C)(C)C JTXUVHFRSRTSAT-UHFFFAOYSA-N 0.000 description 7
238000007334 copolymerization reaction Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
-1 aluminum compound Chemical class 0.000 description 6
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000002994 raw material Substances 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 4
238000004817 gas chromatography Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
125000002370 organoaluminium group Chemical group 0.000 description 3
239000010936 titanium Substances 0.000 description 3
DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000007423 decrease Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
229920001580 isotactic polymer Polymers 0.000 description 2
239000000203 mixture Substances 0.000 description 2
SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 2
150000002899 organoaluminium compounds Chemical class 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
MXAFMRHRWMAVRM-SOFGYWHQSA-N (e)-3,5,5-trimethylhex-2-ene Chemical compound C\C=C(/C)CC(C)(C)C MXAFMRHRWMAVRM-SOFGYWHQSA-N 0.000 description 1
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
DPFRBPJIKDMNCN-UHFFFAOYSA-N 2,2,4-trimethylhex-3-ene Chemical compound CCC(C)=CC(C)(C)C DPFRBPJIKDMNCN-UHFFFAOYSA-N 0.000 description 1
VIURXUSJLMYXAD-UHFFFAOYSA-N 2,2-dimethyl-4-methylidenehexane Chemical compound CCC(=C)CC(C)(C)C VIURXUSJLMYXAD-UHFFFAOYSA-N 0.000 description 1
MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
ILPBINAXDRFYPL-UHFFFAOYSA-N 2-octene Chemical compound CCCCCC=CC ILPBINAXDRFYPL-UHFFFAOYSA-N 0.000 description 1
JUQRLACJJQXBDE-UHFFFAOYSA-N 6,6-dimethylhept-1-ene Chemical compound CC(C)(C)CCCC=C JUQRLACJJQXBDE-UHFFFAOYSA-N 0.000 description 1
DFGKGUXTPFWHIX-UHFFFAOYSA-N 6-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]acetyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)C1=CC2=C(NC(O2)=O)C=C1 DFGKGUXTPFWHIX-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000032683 aging Effects 0.000 description 1
238000012661 block copolymerization Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
BPBOWYWUOUJKLO-UHFFFAOYSA-N ethylidenecyclohexane Chemical compound CC=C1CCCCC1 BPBOWYWUOUJKLO-UHFFFAOYSA-N 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 1
230000037048 polymerization activity Effects 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

JP10762181A 1981-07-10 1981-07-10 オレフインの重合方法 Granted JPS588708A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP10762181A JPS588708A (ja)	1981-07-10	1981-07-10	オレフインの重合方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10762181A JPS588708A (ja)	1981-07-10	1981-07-10	オレフインの重合方法

Publications (2)

Publication Number	Publication Date
JPS588708A JPS588708A (ja)	1983-01-18
JPH0118929B2 true JPH0118929B2 (th)	1989-04-07

Family

ID=14463817

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10762181A Granted JPS588708A (ja)	1981-07-10	1981-07-10	オレフインの重合方法

Country Status (1)

Country	Link
JP (1)	JPS588708A (th)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0674343B2 (ja) *	1984-04-02	1994-09-21	三菱化成株式会社	耐熱耐薬品性高分子多孔体
JPS617349A (ja) *	1984-06-22	1986-01-14	Mitsubishi Chem Ind Ltd	３−メチルブテン−１重合体組成物およびその製法
JPS6169452A (ja) *	1984-09-14	1986-04-10	三菱化学株式会社	積層体
JPH0699514B2 (ja) *	1985-05-28	1994-12-07	三菱化成株式会社	３−メチルブテン−１重合体の製造方法
US20060100474A1 (en) *	2004-11-10	2006-05-11	Bercen Incorporated	Method of making mixtures of internal olefins

1981
- 1981-07-10 JP JP10762181A patent/JPS588708A/ja active Granted

Also Published As

Publication number	Publication date
JPS588708A (ja)	1983-01-18

Publication	Publication Date	Title
CA2107634C (en)	1998-07-28	Titanium catalyst component for ethylene polymerization, ethylene polymerization catalyst, and process for ethylene polymerization using the same
JP2625126B2 (ja)	1997-07-02	アルフアーオレフインの立体特異性重合に使用できる固形触媒
US10053523B2 (en)	2018-08-21	Supported polymetal olefin polymerization catalyst, preparation method and use thereof
US4247669A (en)	1981-01-27	Process for the polymerization of olefins
JPH0118929B2 (th)	1989-04-07
US5109084A (en)	1992-04-28	Polymerization catalyst, preparation, and use
JPH0725820B2 (ja)	1995-03-22	プロピレンの重合方法
KR0181729B1 (ko)	1999-05-15	지이글러-나타형 촉매계
JPS6072903A (ja)	1985-04-25	α−オレフィンの重合法
JPH0118933B2 (th)	1989-04-07
JPH0680101B2 (ja)	1994-10-12	プロピレンのブロツク共重合体の製造方法
EP0055446B1 (en)	1986-02-26	Method for production of polyolefins which form articles having fewer gel discontinuities
US4851378A (en)	1989-07-25	Olefin polymerization of copolymerization catalyst components
US3047551A (en)	1962-07-31	Continuous polymerization of olefins using a fixed bed, supported transition metal-organometallic catalyst
JP2553246B2 (ja)	1996-11-13	プロピレンエチレン共重合体の製造方法
JP2731479B2 (ja)	1998-03-25	３−エチル−１−ヘキセンの重合体及びその製造法
JPH0580496B2 (th)	1993-11-09
US5095080A (en)	1992-03-10	Olefin polymerization catalyst and method for production and use
JP3308062B2 (ja)	2002-07-29	オレフィン重合用触媒及びポリオレフィンの製造方法
JP2981262B2 (ja)	1999-11-22	ポリプロピレンの架橋方法
KR840000917B1 (ko)	1984-06-28	α-올레핀의 중합방법과 그 촉매
EP0878485B1 (en)	2006-04-26	A process for polymerization of olefins
JPH0816140B2 (ja)	1996-02-21	プロピレンのブロツク共重合体の製造方法
JPH0618839B2 (ja)	1994-03-16	プロピレンのブロツク共重合体の製造方法
JPH0580495B2 (th)	1993-11-09