JPH01101364A - Polybutylene terephthalate composition - Google Patents
Polybutylene terephthalate compositionInfo
- Publication number
- JPH01101364A JPH01101364A JP25921487A JP25921487A JPH01101364A JP H01101364 A JPH01101364 A JP H01101364A JP 25921487 A JP25921487 A JP 25921487A JP 25921487 A JP25921487 A JP 25921487A JP H01101364 A JPH01101364 A JP H01101364A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- pbt
- montan wax
- polybutylene terephthalate
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001707 polybutylene terephthalate Polymers 0.000 title claims abstract description 38
- -1 Polybutylene terephthalate Polymers 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 title abstract description 8
- 239000012170 montan wax Substances 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 235000019386 wax ester Nutrition 0.000 claims abstract description 6
- 239000011342 resin composition Substances 0.000 claims description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000011156 evaluation Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- YOILXOMTHPUMRG-JSGCOSHPSA-N (4as,10bs)-4-propyl-3,4a,5,10b-tetrahydro-2h-chromeno[4,3-b][1,4]oxazin-9-ol Chemical compound C1=C(O)C=C2[C@@H]3OCCN(CCC)[C@H]3COC2=C1 YOILXOMTHPUMRG-JSGCOSHPSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は成形性、耐熱安定性に優れ、特にコネクター、
リレー、スイッチ等の精密成形品に好適なポリブチレン
テレフタレート樹脂組成物に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention has excellent moldability and heat resistance stability, and is particularly suitable for connectors,
The present invention relates to a polybutylene terephthalate resin composition suitable for precision molded products such as relays and switches.
ポリブチレンテレフタレート（以下ＰＢＴと略ス）はそ
の優れた耐熱変形性、耐薬品性、耐衝撃性、寸法安定性
等の特長によシ自動車、家電製品の電気・電子機器回路
のコネクター、リレー、スイッチ等の部品として使用さ
れているが、これらに要求される機能が増すとともに形
状は複雑化しつつあり、さらにはコストダウン、軽量化
を目的に部品の薄肉化が必要とされている。かかる要求
に対応するためには、ＰＢＴ樹脂の高流動化、易離型化
、射出成形時の耐熱安定化が必要であるが、これらの条
件をすべて満足するＰＢＴ樹脂を得ることは、従来技術
では困難であった。Polybutylene terephthalate (hereinafter abbreviated as PBT) has excellent properties such as heat deformation resistance, chemical resistance, impact resistance, and dimensional stability, and is used in connectors, relays, and electrical/electronic circuits for automobiles and home appliances. They are used as components in switches and other devices, but as the functions required of these devices increase, their shapes are becoming more complex, and there is also a need to make parts thinner to reduce costs and weight. In order to meet these demands, it is necessary for PBT resin to have high fluidity, easy mold release, and stable heat resistance during injection molding, but it is difficult to obtain PBT resin that satisfies all of these conditions using conventional technology. It was difficult.
即ち、従来はＰＢＴ樹脂の流動性を増すために低分子′
！ｋＰＢＴを使用するのが一般的であるが、この場合射
出成形機シリンダー内で生ずるＰＢＴの熱劣化により、
得られる成形品の耐衝撃性、強度等の物性の低下が著し
く、熱劣化の一傾向は金型からの成形品の離型性を改良
するための核剤の添加によシ増長される傾向にある。That is, conventionally, in order to increase the fluidity of PBT resin, low molecular weight
! It is common to use kPBT, but in this case, due to the thermal deterioration of PBT that occurs in the injection molding machine cylinder,
Physical properties such as impact resistance and strength of the resulting molded product are significantly reduced, and the tendency for thermal deterioration tends to be exacerbated by the addition of a nucleating agent to improve the releasability of the molded product from the mold. It is in.
本発明者等は前記の問題点を解決するために鋭意検討の
結果、特定の極限粘度数のＰＢＴを組合せ、特定の添加
剤を用Ａることによう本発明を完成するに到った。In order to solve the above-mentioned problems, the inventors of the present invention conducted intensive studies and completed the present invention by combining PBT having a specific intrinsic viscosity and using specific additives.
即ち、本発明は、極限粘度数０．７０〜０．９２ｄｌｌ
ＩのＰＢＴ ５〜９４．９９を置部、極限粘度数０．９
３〜１．４０ ｄｌＡｌのＰＢＴ ５〜９４．９９重量
部、モンタンワックス塩及び／又は、モンタンワックス
エステル塩０．０１〜２重量部からなるＰＢＴ樹脂組成
物に関するものである。That is, the present invention has an intrinsic viscosity of 0.70 to 0.92 dll.
PBT of I: 5 to 94.99, intrinsic viscosity number: 0.9
The present invention relates to a PBT resin composition comprising 5 to 94.99 parts by weight of PBT of 3 to 1.40 dlAl, and 0.01 to 2 parts by weight of montan wax salt and/or montan wax ester salt.
本発明の組成物では従来技術では困難であった、高流動
化、易離型化、射出成形時の耐熱安定化を同時に達成す
ることが可能である。With the composition of the present invention, it is possible to simultaneously achieve high fluidity, easy mold release, and stabilization of heat resistance during injection molding, which were difficult to achieve with conventional techniques.
本発明でのＰＢＴは、例えば１．４−ブタンジオールと
ジメチルテレフタレートから製造されるものが用いられ
るが、代りに製造の際に必要に応じてエチレングリコー
ル、１．３−ｆロノ９ンジオール等のジオールや、テレ
フタル酸以外のジカル？ン酸などの少量の第三成分を共
縮合させたものを用いてもよい。本発明で用いられる２
種類のＰＢＴの配合割合は、極限粘度〔・η〕（テトラ
クロルエタン／フェノールの４０／６０（重量比）混合
溶媒中、３０℃で測定した相対粘度に基いて算出。）の
値が０．７０〜０．９２ ｄｌ／ｉのＰＢＴ ５〜９４
．９９重量部、好ましくは１０〜９０重量部、〔η〕の
値が０．９３〜１．４０ ｄｉ／ｇのＰＢＴ ５〜９４
．９９重量部、好ましくは１０〜９０３［部であシ、前
者のＰＢＴＯ量が５１址部未満では射出成形時の流動性
が悪く、又、９４゜９９重量部を越えると成形品の機械
的強度が低下する。The PBT used in the present invention is, for example, one produced from 1,4-butanediol and dimethyl terephthalate, but instead, ethylene glycol, 1,3-f lono-9ane diol, etc. may be used as needed during production. Diols and radicals other than terephthalic acid? A product obtained by co-condensing a small amount of a third component such as phosphoric acid may also be used. 2 used in the present invention
The blending ratio of the types of PBT is such that the value of the intrinsic viscosity [·η] (calculated based on the relative viscosity measured at 30°C in a 40/60 (weight ratio) mixed solvent of tetrachloroethane/phenol) is 0. 70-0.92 dl/i PBT 5-94
．． 99 parts by weight, preferably 10 to 90 parts by weight, PBT with a [η] value of 0.93 to 1.40 di/g 5 to 94
．． If the PBTO content is less than 51 parts by weight, the fluidity during injection molding will be poor, and if it exceeds 94.99 parts by weight, the mechanical strength of the molded product will deteriorate. decreases.
モンタンワックス塩は、モンタン酸と０．１〜１当量の
金属の酸化物又は水酸化物との反応によって製造される
塩で、金属としては周期律表の第１〜第３主属の金属、
例えばナトリウム、カリウム、ベリリウム、マダネ７ウ
ム、カルシウム、リチウムならびにアルミニウム等が挙
げられる。ここで言うモンタン酸とは２６〜３２個の炭
素原子を有する脂肪族モノカルボン酸を主成分とする酸
混合物である。Montan wax salt is a salt produced by the reaction of montanic acid and 0.1 to 1 equivalent of a metal oxide or hydroxide, and the metals include metals from the first to third main groups of the periodic table;
Examples include sodium, potassium, beryllium, heptadium, calcium, lithium, and aluminum. Montanic acid as used herein is an acid mixture whose main component is an aliphatic monocarboxylic acid having 26 to 32 carbon atoms.
モンタンワックスエステル酸は、モンタン酸ヲアルキレ
ン基中に２〜４個の炭素を有する２価のアルコール０．
１〜０６ｇ当量で部分的にエステル化し、ついで上記し
た金属の酸化物又は水酸化物で中和することＫよりて得
られる。特に好適なジオールは、例えばエチレングリコ
ール、ｌ・２又はｌ・３プロパンジオール、１・３又は
１・４２タンジオールである。Montan wax ester acid is a dihydric alcohol having 2 to 4 carbons in the alkylene group.
It is obtained by partial esterification in an amount of 1 to 0.6 g equivalent, followed by neutralization with the above-mentioned metal oxides or hydroxides. Particularly suitable diols are, for example, ethylene glycol, 1.2 or 1.3 propanediol, 1.3 or 1.42 tanediol.
モンタンワックス塩及び／又はモンタンワックスエステ
ル塩の使用量は０．０１〜２重量部、好ましくは０．１
〜ｌｌｉ量部で、０．０１重量部未満では射出成形時の
離型性が低下し、゛２！量部を越えると成形品表面への
印刷、接着等の２次加工が困難となったシ、ワックス成
分の表面への移行（ツリード現象）を生じたシする。The amount of montan wax salt and/or montan wax ester salt used is 0.01 to 2 parts by weight, preferably 0.1
If the amount is less than 0.01 part by weight, the mold releasability during injection molding will decrease, and ゛2! If the amount is exceeded, secondary processing such as printing and adhesion on the surface of the molded product becomes difficult, and migration of the wax component to the surface (treeing phenomenon) occurs.
本発明においては、無機及び／又は有機の充填剤は必須
でないが、必要に応じて下記充填剤を使用するととＫよ
って剛性等の向上をはかることができる。好適な充填剤
としては、ガラス繊維、炭素繊維、金属繊維、アラミツ
ド繊維、チタン酸カリウム、アスベスト、炭化ケイ素、
セラミック繊維、窒化ケイ素などの繊維状強化剤、硫酸
バリウム、硫酸カル７ウム、カオリン、クレー、／フィ
ロフィライト、ベントナイト、セリサイト、ゼオライト
、マイカ、雲母、ネフェリンミナイト、メルク、アタル
ノＩルノヤイト、ウオラストナイト、ＰＭＦ、フェライ
ト、硅酸カル／ラム、炭酸カルシウム、炭酸マグネ７ウ
ム、ドロマイト、三酸化アンモン、酸化亜鉛、酸化チタ
ン、酸化マグネシウム、酸化鉄、二硫化モリブデン、黒
鉛、石こう、Ｗ５スビーズ、ガラスパウダー、ガラスバ
ルーン、石英、石英ガラスなどの強化充填剤を挙げるこ
とができる。他に核剤、離型剤、カップリング剤、着色
剤、滑剤、耐熱安定剤、耐候性安定剤、発泡剤、難燃剤
、三酸化アンチモン等の難燃助剤２・エチルヘキクルー
Ｐ−ヒドロキシペン：、’−Ｃ−）、ベンゼンスルホン
酸ブナルアミド等の可塑剤等ヲ添加してもよい。In the present invention, inorganic and/or organic fillers are not essential, but if necessary, the following fillers can be used to improve rigidity and the like. Suitable fillers include glass fiber, carbon fiber, metal fiber, aramid fiber, potassium titanate, asbestos, silicon carbide,
Ceramic fibers, fibrous reinforcing agents such as silicon nitride, barium sulfate, calcium sulfate, kaolin, clay, /phyllophyllite, bentonite, sericite, zeolite, mica, mica, nephelinminite, Merck, atarno I lunoyite, Wollastonite, PMF, ferrite, cal/rum silicate, calcium carbonate, magnesium carbonate, dolomite, ammonium trioxide, zinc oxide, titanium oxide, magnesium oxide, iron oxide, molybdenum disulfide, graphite, gypsum, W5 beads , glass powder, glass balloon, quartz, quartz glass, and other reinforcing fillers. In addition, flame retardant aids such as nucleating agents, mold release agents, coupling agents, coloring agents, lubricants, heat-resistant stabilizers, weather-resistant stabilizers, foaming agents, flame retardants, and antimony trioxide 2-ethylhexyl-p-hydroxy Plasticizers such as pen:, '-C-), benzenesulfonic acid bunalamide, etc. may be added.
さらに必要に応じて、ポリエチレンテレフタレート、ポ
リアミド、ウレタン化ＦＡＴ 、ポリエチレン、ポリグ
ロピレン、ｊ１！リステレン、ポリアクリレ−）、ＡＢ
Ｓ、Ａｓ、ポリ塩化ビニル、ポリアセタール、ポリカー
ざネート、Ｉリサルホン、ポリエ−チルサルホン、ポリ
フェニレンオキシド、ポリフェニレンサルファイド等の
ゲラステック類や、ポリエステル系、ポリアミド系、ポ
リウレタン系、アクリル系、オレフイン基、塩ビ系、ス
チレン系、Ａｇ３系等の熱可塑性エラストマー類を添加
することも可能である。Furthermore, if necessary, polyethylene terephthalate, polyamide, urethanized FAT, polyethylene, polyglopylene, j1! Listerene, polyacrylate), AB
S, As, polyvinyl chloride, polyacetal, polycarbonate, I resulfone, polyethyl sulfone, polyphenylene oxide, polyphenylene sulfide, etc., gelastec, polyester type, polyamide type, polyurethane type, acrylic type, olefin group, PVC type, It is also possible to add thermoplastic elastomers such as styrene type and Ag3 type.
本発明において前記発明の組成物の調製は糧々の公知の
方法で可能である。例えば、原料を予めタンブラ−又は
ヘン７エルミキサーのような混合機で均一に混合した後
、−軸又は二軸の押出機等に供給して溶融混練した後、
Ｋレットとして調製する方法がある。In the present invention, the composition of the invention can be prepared by a variety of known methods. For example, after the raw materials are mixed uniformly in advance using a mixer such as a tumbler or Hen-7er mixer, the raw materials are fed to a -screw or twin-screw extruder, etc., and then melted and kneaded.
There is a method of preparing it as K-let.
以下に、本発明を実施例により具体的に説明するが、本
発明はこれらの実施例のみに限定されるものではない。EXAMPLES The present invention will be specifically explained below with reference to Examples, but the present invention is not limited to these Examples.
尚、例中の部は重量部を意味する。In addition, parts in the examples mean parts by weight.
実施例１
極限粘度数〔η〕が０．８５ ｄｌＡ！のＰＢＴ ５０
部、〔η〕が１．００ ｄｌｌＩ！のＰＢＴ ４９．４
部、モノタンワックスナトリウム塩０．３部、イルガノ
ックス（Ｅ）１０１０（テパガイギー製耐熱安定剤）０
．３部を均一混合した後、４０Ｍ１φの１軸押出機を用
いて２４０℃の７リンダ一温度で溶融混線、ペレット化
した。Example 1 Intrinsic viscosity number [η] is 0.85 dlA! PBT of 50
part, [η] is 1.00 dllI! PBT of 49.4
part, monothane wax sodium salt 0.3 part, Irganox (E) 1010 (heat resistant stabilizer manufactured by Tepa Geigy) 0
．． After uniformly mixing three parts, the mixture was melted and mixed at a temperature of 7 cylinders at 240° C. using a 40M 1φ single-screw extruder to form pellets.
得られた４レツトから３．５オンスのスクリーー盤射出
成形機を用いてシリンダー温度２６０℃、金型温度４５
℃、射出圧１４００〜５００ ｋ！ＩＡ肩 、射出速度
中速、成形サイクル射出／冷却＝７／３０秒の成形条件
で物性試験用のテストピース、及び自動車ワイヤーハー
ネス用コネクターを成形した。Using a 3.5 oz screen plate injection molding machine, the cylinder temperature was 260°C and the mold temperature was 45°C.
℃, injection pressure 1400-500k! Test pieces for physical property tests and connectors for automobile wire harnesses were molded under the following molding conditions: IA shoulder, medium injection speed, molding cycle injection/cooling = 7/30 seconds.
テストピースについては、通常の成形法に加え、シリン
ダー内に樹脂を５分滞溜させて成形した場合の物性も評
価した。In addition to the usual molding method, the test pieces were also evaluated for their physical properties when molded by allowing the resin to stay in the cylinder for 5 minutes.
実施例２
〔η〕が０．８５ ｄｌ／ｌｌのＰＢＴを５０部に代え
て７０部、１． ＯＯｄｌ／１／のＰＢＴを４９．４部
に代えて２９．４部用いたことを除いて実施例１と全く
同様の評価を行なった。 ・
実施例３
〔η〕が０．８５ ｄｉ／ｇのＰＢＴを５０部に代えて
８０部、１．００ ｄｌ／ＩのＰＢＴ ４９．４部に代
えて１．１５ ｄｌ／ＩのＰＢＴ １９．４部を用いた
ことを除いて実施例１と全く同様の評価を行なった。Example 2 PBT with [η] of 0.85 dl/ll was replaced with 50 parts and 70 parts, 1. Evaluation was performed in exactly the same manner as in Example 1, except that 29.4 parts of PBT at OOdl/1/ was used instead of 49.4 parts. - Example 3 PBT with [η] of 0.85 di/g was replaced with 50 parts and 80 parts, PBT with 1.00 dl/I was replaced with 49.4 parts with PBT with 1.15 dl/I 19. Evaluation was carried out in exactly the same manner as in Example 1 except that 4 parts were used.
実施例４
〔η〕が０．８５ ｄｉ／ｇのＰＢＴを５０部に代えて
４９．７部、モンタンワックスナトリウム塩を０．３部
１ｃ代えて０．６部用いたことを除いて実施例１と全く
同様の評価を行なった。Example 4 Example except that 49.7 parts of PBT with [η] of 0.85 di/g was used instead of 50 parts, and 0.6 parts of montan wax sodium salt was used instead of 0.3 parts of 1c. Evaluation was conducted in exactly the same manner as in 1.
実施例５
モンタンワックスナトリウム塩０．３部に代えてモンタ
ンワックスエステルカルシウム塩０．３ 部ｔ−用いた
ことを除いて実施例１と全く同様の評価を行なった。Example 5 The same evaluation as in Example 1 was carried out except that 0.3 part of montan wax ester calcium salt was used in place of 0.3 part of montan wax sodium salt.
比較例１
〔η〕が０．８５ ｄＶＩｌのＰＢＴ ５０部及び１．
ＯＯｄ＆／ｇのＰＢＴ ４９．４部に代えて、０．８
５ ｄｌｌ＆のＰＢＴ ９９．４部を用いたことを除い
て実施例１と全く同様の評価を行なった。Comparative Example 1 50 parts of PBT with [η] of 0.85 dVIl and 1.
0.8 parts instead of 49.4 parts of PBT in OOd&/g
Evaluation was conducted in exactly the same manner as in Example 1 except that 99.4 parts of PBT of 5 dll& was used.
比較例２
〔η〕が０．８５元々のＰＢＴ ９９．４部に代えて、
０、９２ ｄＶＩ！のＰＢＴ ９９．４部を用いたこと
を除いて比較例１と全く同様の評価を行なった。Comparative Example 2 [η] was 0.85 instead of 99.4 parts of the original PBT,
0.92 dVI! Evaluation was carried out in exactly the same manner as in Comparative Example 1 except that 99.4 parts of PBT was used.
比較例３
〔η〕が０．８５ ｄｌ／ＩのＰＢＴ ９９．４部に代
えて、１、１５ ｄＶＩのＰＢＴ ９９．４部を用いた
ことを除いて比較例１と全く同様の評価を行なった。Comparative Example 3 The same evaluation as in Comparative Example 1 was performed except that 99.4 parts of PBT with 1.15 dVI was used instead of 99.4 parts of PBT with [η] of 0.85 dl/I. Ta.
比較例４
〔η〕が１．００ ｄｌ／ｇのＰＢＴを４９．４部に４
９．７部に代え、同時にモンタンワックスナトリウＡｊ
Ｊｌ用いなかったことを除いて実施例１と全く同様の評
価を行なった。Comparative Example 4 PBT with [η] of 1.00 dl/g was added to 49.4 parts.
9.In place of 7 parts, at the same time use Montan Wax Natriu Aj
Evaluation was conducted in exactly the same manner as in Example 1 except that Jl was not used.
比較例５
モンタンワックスナトリウム塩０．３部に代えてタルク
０．３部を用いたことを除いて実施例１と全く同様の評
価を行なった。Comparative Example 5 Evaluation was conducted in exactly the same manner as in Example 1 except that 0.3 part of talc was used in place of 0.3 part of montan wax sodium salt.
各側めテストピースの物性、コネクターの外観評価の結
果を表１に示す。曲げ強度はＡＳＴＭ Ｄ−７９０、ア
イゾツト衝撃ｉ度（ノツチ付）はＡＳＴＭ Ｄ−２５６
に準拠して測定した。Table 1 shows the physical properties of each side test piece and the results of the connector appearance evaluation. Bending strength is ASTM D-790, Izo impact degree (notched) is ASTM D-256
Measured according to.
ＭＦＲ（メルトフローレイト）は東洋精機製作所製メル
トインデクターを使用し、温度２５０℃、荷重３２５Ｉ
で測定した。MFR (melt flow rate) uses a melt indexer made by Toyo Seiki Seisakusho, temperature 250℃, load 325I.
It was measured with
本発明の組成物は、高流動性、易離型性、優れた射出成
形時の耐熱安定性を有するものである。The composition of the present invention has high fluidity, easy mold releasability, and excellent heat resistance stability during injection molding.
代理人 弁理士 高 橋 勝 利Agent: Patent Attorney Katsutoshi Takahashi
Claims (1)
テレフタレート５〜９４．９９重量部、極限粘度数０．
９３〜１．４０ｄｌ／ｇのポリブチレンテレフタレート
５〜９４．９９重量部、モンタンワックス塩及び／又は
、モンタンワックスエステル塩０．０１〜２重量部から
なるポリブチレンテレフタレート樹脂組成物。5 to 94.99 parts by weight of polybutylene terephthalate with an intrinsic viscosity of 0.70 to 0.92 dl/g, an intrinsic viscosity of 0.
A polybutylene terephthalate resin composition comprising 5 to 94.99 parts by weight of polybutylene terephthalate of 93 to 1.40 dl/g and 0.01 to 2 parts by weight of montan wax salt and/or montan wax ester salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62259214A JPH0651829B2 (en) | 1987-10-14 | 1987-10-14 | Polybutylene terephthalate resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62259214A JPH0651829B2 (en) | 1987-10-14 | 1987-10-14 | Polybutylene terephthalate resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01101364A true JPH01101364A (en) | 1989-04-19 |
| JPH0651829B2 JPH0651829B2 (en) | 1994-07-06 |
Family
ID=17330981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62259214A Expired - Fee Related JPH0651829B2 (en) | 1987-10-14 | 1987-10-14 | Polybutylene terephthalate resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0651829B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0287487A (en) * | 1988-09-26 | 1990-03-28 | Sumitomo Wiring Syst Ltd | Connector |
| JPH02102231A (en) * | 1988-10-07 | 1990-04-13 | Sumitomo Wiring Syst Ltd | Molding of resin and molded item |
| JPH06279664A (en) * | 1992-12-22 | 1994-10-04 | General Electric Co <Ge> | Method for stabilizing low-molecular-weight polybutylene terephthalate/polyester composition with phosphorus compound, and thermoplastic resin composition obtained thereby |
| JP2001316577A (en) * | 2000-05-11 | 2001-11-16 | Toyobo Co Ltd | Thermoplastic polyester resin composition |
| JP2003026786A (en) * | 2001-07-16 | 2003-01-29 | Sumitomo Electric Ind Ltd | Polybutylene terephtalate and its molded article |
| KR100524162B1 (en) * | 1998-03-06 | 2005-12-21 | 에스케이케미칼주식회사 | Polybutylene Terephthalate Resin Composition |
| JP2022510101A (en) * | 2019-10-24 | 2022-01-26 | エルジー・ケム・リミテッド | Polyester resin composition and its molded product |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5285293A (en) * | 1976-01-09 | 1977-07-15 | Toray Ind Inc | Preparation of polytetramethylene terephthalate of high polymerization degree |
| JPS5552340A (en) * | 1978-10-11 | 1980-04-16 | Teijin Ltd | Polyester resin composition |
| JPS5560552A (en) * | 1978-10-30 | 1980-05-07 | Teijin Ltd | Polyester resin composition |
| JPS5562957A (en) * | 1978-11-06 | 1980-05-12 | Teijin Ltd | Preparation of polyester resin composition |
| JPS58157827A (en) * | 1982-03-16 | 1983-09-20 | Toray Ind Inc | Preparation of polyester molded article having metallized surface |
-
1987
- 1987-10-14 JP JP62259214A patent/JPH0651829B2/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5285293A (en) * | 1976-01-09 | 1977-07-15 | Toray Ind Inc | Preparation of polytetramethylene terephthalate of high polymerization degree |
| JPS5552340A (en) * | 1978-10-11 | 1980-04-16 | Teijin Ltd | Polyester resin composition |
| JPS5560552A (en) * | 1978-10-30 | 1980-05-07 | Teijin Ltd | Polyester resin composition |
| JPS5562957A (en) * | 1978-11-06 | 1980-05-12 | Teijin Ltd | Preparation of polyester resin composition |
| JPS58157827A (en) * | 1982-03-16 | 1983-09-20 | Toray Ind Inc | Preparation of polyester molded article having metallized surface |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0287487A (en) * | 1988-09-26 | 1990-03-28 | Sumitomo Wiring Syst Ltd | Connector |
| JPH041477B2 (en) * | 1988-09-26 | 1992-01-13 | Sumitomo Wiring Systems | |
| JPH02102231A (en) * | 1988-10-07 | 1990-04-13 | Sumitomo Wiring Syst Ltd | Molding of resin and molded item |
| US5039727A (en) * | 1988-10-07 | 1991-08-13 | Sumitomo Wiring Systems, Ltd. | Polybutylene terephthalate moulding compositions with an improved flowability |
| JPH0660246B2 (en) * | 1988-10-07 | 1994-08-10 | 住友電装株式会社 | Resin molding method and molded body |
| JPH06279664A (en) * | 1992-12-22 | 1994-10-04 | General Electric Co <Ge> | Method for stabilizing low-molecular-weight polybutylene terephthalate/polyester composition with phosphorus compound, and thermoplastic resin composition obtained thereby |
| KR100524162B1 (en) * | 1998-03-06 | 2005-12-21 | 에스케이케미칼주식회사 | Polybutylene Terephthalate Resin Composition |
| JP2001316577A (en) * | 2000-05-11 | 2001-11-16 | Toyobo Co Ltd | Thermoplastic polyester resin composition |
| JP2003026786A (en) * | 2001-07-16 | 2003-01-29 | Sumitomo Electric Ind Ltd | Polybutylene terephtalate and its molded article |
| JP2022510101A (en) * | 2019-10-24 | 2022-01-26 | エルジー・ケム・リミテッド | Polyester resin composition and its molded product |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0651829B2 (en) | 1994-07-06 |
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