JP7345501B2 - 多層シートおよび転写材 - Google Patents
多層シートおよび転写材 Download PDFInfo
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- JP7345501B2 JP7345501B2 JP2020559072A JP2020559072A JP7345501B2 JP 7345501 B2 JP7345501 B2 JP 7345501B2 JP 2020559072 A JP2020559072 A JP 2020559072A JP 2020559072 A JP2020559072 A JP 2020559072A JP 7345501 B2 JP7345501 B2 JP 7345501B2
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14754—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles being in movable or releasable engagement with the coating, e.g. bearing assemblies
- B29C2045/1477—Removable inserts, e.g. the insert being peeled off after moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2683/00—Use of polymers having silicon, with or without sulfur, nitrogen, oxygen or carbon only, in the main chain, for preformed parts, e.g. for inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2715/00—Condition, form or state of preformed parts, e.g. inserts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
<重量平均分子量、数平均分子量>
(メタ)アクリル樹脂からサンプルとして0.2mgを採取し、これをテトラヒドロフラン10mLに溶解させ、示差屈折率検出器(RID)を装備したゲルパーミエーションクロマトグラフ(GPC)によってサンプルの分子量分布を測定し、クロマトグラム(チャート)を得た。
示差屈折率検出器:製品名HLC-8220GPCに内蔵されたRI検出器
カラム:製品名TSKgel GMHXL(東ソー社製)3本
移動相:テトラヒドロフラン
カラム流量:0.5mL/min
注入量:20μL
測定温度:40℃
標準ポリスチレン分子量:1250、3250、9200、28500、68000、165000、475000、950000、1900000
<ガラス転移温度>
(メタ)アクリル樹脂のガラス転移温度は、フォックスの式により算出した。
<粘度>
JIS K5600-2-3(2014年)に準拠し、粘度を測定した。
<酸価>
JIS K5601-2-1(1999年)に準拠し、酸価を測定した。
<不揮発分濃度>
JIS K5601-1-2(2008年)に準拠し、不揮発分濃度を測定した。
<エポキシ当量>
JIS K7236(2001年)に準拠し、エポキシ当量を測定した。
<水酸基価>
(メタ)アクリル樹脂の水酸基価は、JIS K1557-1:2007(ISO14900:2001)「プラスチック-ポリウレタン原料ポリオール試験方法-第1部:水酸基価の求め方」の4.2B法に準拠して測定した。
<(メタ)アクリロイル当量>
(メタ)アクリル樹脂の(メタ)アクリロイル当量は、(メタ)アクリル樹脂の原料であるモノマー組成から、下記式(I)に従って算出した。
合成例1~14
反応容器中に、溶剤としてメチルイソブチルケトン(MIBK)400重量部を供給して90℃まで加熱して、温度を維持した。
実施例1~15および比較例1~2
・多層シート
表5~表9に記載の(メタ)アクリル樹脂を、バーコーターを用いて、基材シート(王子エフテックス社製、50μm厚のオレフィンフィルム)の一方面に塗布し、60℃で1分加熱し、溶剤を除去した。
実施例15では、さらに、基材シートにおいて、層が形成される一方側に対する他方側の面に、金型付着防止層を形成した。
上側金型および下側金型のセットからなる注型用金型を用意し、その下側金型に多層シートを保護層が金型内側を向くようにセットした。なお、金型から成形される表層付モールド樹脂に対し、JIS K 5600-5-6(1999)に基づいて密着性を正確に評価できるよう、下側金型として、平らで滑らかな表面の金型を用いた。
表8に記載の(メタ)アクリル樹脂を、バーコーターを用いて、基材シート(王子エフテックス社製、50μm厚のオレフィンフィルム)の一方面に塗布し、60℃で1分加熱し、溶剤を除去した。
モールド樹脂の物性を評価するため、基材シートにモールド樹脂を積層した。
・多層シート
表9に記載の(メタ)アクリル樹脂を、バーコーターを用いて、基材シート(王子エフテックス社製、50μm厚のオレフィンフィルム)の一方面に塗布し、60℃で1分加熱し、溶剤を除去した。
上側金型および下側金型のセットからなる注型用金型を用意し、その下部金型に多層シートを保護層が金型内側を向くようにセットした。なお、金型から成形される表層付モールド樹脂に対し、JIS K 5600-5-6(1999)に基づいて密着性を正確に評価できるよう、下側金型として、平らで滑らかな表面の金型を用いた。
多層シートに代えて、基材シート(王子エフテックス社製、50μm厚のオレフィンフィルム)を用いた以外は、実施例1と同じ方法で、モールド樹脂を得た。
(1)引張伸度
多層シートの引張伸度を、プラスチック-引張特性の試験方法(JIS K7127(1999)))に準拠して、測定した。なお、比較例5では、多層シートに代えて、基材シートの引張伸度を測定した。
B:引張伸度5%以上10%未満
C:引張伸度5%未満
(2)鉛筆硬度
表層(熱硬化層)の鉛筆硬度を、JIS K5600-5-4(1999)「引っ掻き硬度(鉛筆法)」の試験法に準拠して、評価した。なお、比較例4では、表層(熱硬化層)に代えて、モールド樹脂層(熱硬化したエポキシ樹脂層)の鉛筆硬度を評価した。また、比較例5では、表層(熱硬化層)に代えて、表層を有しないモールド樹脂の表面の鉛筆硬度を評価した。
(3)密着性(接着性)
表層(熱硬化層)とモールド樹脂との密着性を、JIS K5600-5-6(1999)の「クロスカット法」の試験法に準拠して、評価した。
表層付モールド樹脂の代替として、表層(熱硬化層)付の試験板を準備した。すなわち、試験板(アクリル板)の表面に、各実施例および比較例1~3の条件で、(メタ)アクリル樹脂を塗布し、光硬化させ、その後、モールド樹脂の成形条件と同じ条件で、熱硬化させた。これにより、試験板(アクリル板)の表面に、表層(熱硬化層)を得た。
B:ΔEが1以上3未満
C:ΔEが3以上10未満
(5)金型汚染
表層付モールド樹脂の成形時において、上側金型に対して接触する接触層が、上側金型に転写(付着)される量を観察し、評価した。
表層付きモールド樹脂から、基材シートを剥離させる際の応力(剥離力)を測定した。
B:剥離力 0.1N/25mm以上0.3N/25mm未満
C:剥離力 0.3N/25mm以上
AA:アクリル酸
2-HEA:2-ヒドロキシエチルアクリレート
FM-0721:商品名、JNC製、3-メタクリロキシプロピルジメチルポリシロキサン
MMA:メチルメタクリレート
BA:ブチルアクリレート
ABN-E:ラジカル重合開始剤、アゾビス-2-メチルブチロニトリル
MIBK:メチルイソブチルケトン
カレンズAOI:商品名、昭和電工製、イソシアナトメチルアクリレート
イルガキュア127:商品名、BASF製、重合開始剤、2-ヒドロキシ-1-{4-[4-(2-ヒドロキシ-2-メチルプロピオニル)-ベンジル]フェニル}-2-メチル-プロパン-1-オン
なお、上記発明は、本発明の例示の実施形態として提供したが、これは単なる例示に過ぎず、限定的に解釈してはならない。当該技術分野の当業者によって明らかな本発明の変形例は、後記特許請求の範囲に含まれる。
2 基材シート
3 未熱硬化層
Claims (9)
- 基材シートと、前記基材シートの一方面に配置され、モールド樹脂の表面の少なくとも一部に、接着層を介さずに配置可能な層とを備え、接着層を備えていない多層シートであって、
前記層は、
前記多層シートの最表層であり、
熱硬化によりハードコート層を形成する未熱硬化層であり、
活性エネルギー線硬化性樹脂の活性エネルギー線による硬化物または半硬化物を含み、
さらに、前記層が、前記モールド樹脂の原料成分と熱硬化反応できる熱反応性基と、ポリシロキサン鎖とを有する
ことを特徴とする、多層シート。 - 前記熱反応性基が、水酸基、エポキシ基、カルボキシ基および(メタ)アクリロイル基からなる群から選択される少なくとも1種である
ことを特徴とする、請求項1に記載の多層シート。 - 前記活性エネルギー線硬化性樹脂が、前記熱反応性基とポリシロキサン側鎖と活性エネルギー線硬化基とを有する(メタ)アクリル樹脂を含有する
ことを特徴とする、請求項1に記載の多層シート。 - 前記活性エネルギー線硬化性樹脂のエポキシ当量が、1000g/eq以上10000g/eq以下である
ことを特徴とする、請求項1に記載の多層シート。 - 前記活性エネルギー線硬化性樹脂は、
ポリシロキサン含有化合物および熱反応性基含有化合物を含む中間原料成分を反応させて得られる中間体ポリマーと、活性エネルギー線硬化基含有化合物との反応生成物であり、
前記中間体ポリマーのガラス転移温度が、0℃以上70℃以下であることを特徴とする、請求項1に記載の多層シート。 - 前記活性エネルギー線硬化性樹脂の重量平均分子量が、5000以上100000以下であることを特徴とする、請求項1に記載の多層シート。
- 前記活性エネルギー線硬化性樹脂の原料成分が、ポリシロキサン含有化合物を含み、
前記活性エネルギー線硬化性樹脂の原料成分の総量に対して、前記ポリシロキサン含有化合物の割合が、0.10質量%以上10.0質量%以下である
ことを特徴とする、請求項1に記載の多層シート。 - 請求項1に記載の多層シートを備えることを特徴とする、転写材。
- さらに、前記多層シートの前記層の一方面に配置される剥離層を備えることを特徴とする、請求項8に記載の転写材。
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PCT/JP2019/046107 WO2020116231A1 (ja) | 2018-12-04 | 2019-11-26 | 多層シートおよび転写材 |
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JP (1) | JP7345501B2 (ja) |
KR (1) | KR20210098980A (ja) |
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WO2001025362A1 (fr) | 1999-10-01 | 2001-04-12 | Nippon Soda Co., Ltd. | Feuille de transfert de photocatalyseur |
WO2009008224A1 (ja) | 2007-07-10 | 2009-01-15 | Aica Kogyo Co., Ltd. | 組成物、転写シート、メラミン化粧板、及びメラミン化粧板の製造方法 |
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- 2019-11-26 KR KR1020217016187A patent/KR20210098980A/ko not_active Application Discontinuation
- 2019-11-26 WO PCT/JP2019/046107 patent/WO2020116231A1/ja active Application Filing
- 2019-11-26 CN CN201980080519.6A patent/CN113165356B/zh active Active
- 2019-11-26 US US17/296,741 patent/US20210387386A1/en active Pending
- 2019-11-26 JP JP2020559072A patent/JP7345501B2/ja active Active
- 2019-12-03 TW TW108144135A patent/TW202103955A/zh unknown
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WO2001025362A1 (fr) | 1999-10-01 | 2001-04-12 | Nippon Soda Co., Ltd. | Feuille de transfert de photocatalyseur |
WO2009008224A1 (ja) | 2007-07-10 | 2009-01-15 | Aica Kogyo Co., Ltd. | 組成物、転写シート、メラミン化粧板、及びメラミン化粧板の製造方法 |
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CN113165356A (zh) | 2021-07-23 |
KR20210098980A (ko) | 2021-08-11 |
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US20210387386A1 (en) | 2021-12-16 |
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