JP6993503B2 - 洗濯ケア組成物中の青味剤としてのロイコ着色剤 - Google Patents
洗濯ケア組成物中の青味剤としてのロイコ着色剤 Download PDFInfo
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- JP6993503B2 JP6993503B2 JP2020517509A JP2020517509A JP6993503B2 JP 6993503 B2 JP6993503 B2 JP 6993503B2 JP 2020517509 A JP2020517509 A JP 2020517509A JP 2020517509 A JP2020517509 A JP 2020517509A JP 6993503 B2 JP6993503 B2 JP 6993503B2
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- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 229940061610 sulfonated phenol Drugs 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000001003 triarylmethane dye Substances 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 229940030186 xpect Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/18—Preparation of azo dyes from other azo compounds by acylation of hydroxyl group or of mercapto group
- C09B43/26—Preparation of azo dyes from other azo compounds by acylation of hydroxyl group or of mercapto group with polyfunctional acylating agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B68/00—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology
- C09B68/40—Organic pigments surface-modified by grafting, e.g. by establishing covalent or complex bonds, in order to improve the pigment properties, e.g. dispersibility or rheology characterised by the chemical nature of the attached groups
- C09B68/44—Non-ionic groups, e.g. halogen, OH or SH
- C09B68/444—Polyether
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Description
本明細書で使用するとき、用語「アルコキシ」は、C1~C8アルコキシ、及びブチレンオキシド、グリシドールオキシド、エチレンオキシド、又はプロピレンオキシドなどの繰り返し単位を有するポリオールのアルコキシ誘導体を含むことを意図する。
洗濯ケア組成物は、いくつかの態様では、全体的に又は部分的に組み込まれ得る他の好適な補助剤を含んでもよい。補助剤は、選択ケア組成物の意図する機能に従って選択され得る。第1の組成物は添加剤を含み得る。いくつかの態様では、複数区画の単位用量物品の場合、添加剤は、第1の組成物とは別の区画に封入される、非第1(例えば第2、第3、第4等)の組成物の一部であってよい。非第1の組成物は、任意の好適な組成物であってよい。非第1の組成物は、固体、液体、分散体、ゲル、ペースト又はこれらの混合物の形態であってよい。単位用量が複数の区画を含む場合、ロイコ着色剤は、1つ、2つ、又は更には全ての区画に添加されてもよく、又は存在してもよい。一実施形態では、ロイコ着色剤をより大きな区画に添加して、より低濃度にし、それによって、潜在的な接触染色に関与するあらゆる問題を最小限に抑えることができる。他方、より小さな体積の区画内において抗酸化剤をロイコ着色剤で濃縮することにより、抗酸化剤の局所濃度を高くすることができ、それによって強化された安定性を提供することができる。したがって、当業者には理解されるように、配合者は、単位用量の所望の特性に従ってロイコ着色剤の位置及び量を選択することができる。
洗濯ケア組成物は、界面活性剤系を含み得る。洗濯ケア組成物は、洗濯ケア組成物の約1重量%~約80重量%、又は1重量%~約60重量%、好ましくは約5重量%~約50重量%、より好ましくは約8重量%~約40重量%の界面活性剤系を含み得る。
(R)(R1)(R2)(R3)N+X-
(式中、Rは直鎖又は分岐鎖、置換又は非置換C6~18アルキル又はアルケニル部分であり、R1及びR2は、独立して、メチル又はエチル部分から選択され、R3はヒドロキシ、ヒドロキシメチル、又はヒドロキシエチル部分であり、Xは電荷の中性を提供するアニオンであり、好ましいアニオンとしては、ハライド、好ましくはクロリド、サルフェート、及びスルホネートが挙げられる)。
ロイコ着色剤組成物中の成分の別の分類は、希釈剤及び/又は溶媒であり得る。希釈剤及び/又は溶媒の目的は、多くの場合、流動性を改善する、及び/又はロイコ着色剤の粘度を低下させることであるが、これらに限定されない。多くの場合、その低コスト及び非毒性を考慮して、水が好ましい希釈剤及び/又は溶媒であるが、他の溶媒も同様に使用され得る。好ましい溶媒は、コストが低くかつ危険性が低いものである。好適な溶媒の例としては、エチレングリコール、プロピレングリコール、グリセリン、ポリエチレングリコール、ポリプロピレングリコールなどのアルコキシル化ポリマー、エチレンオキシドとプロピレンオキシドとのコポリマー、Tween20(登録商標)、Tween40(登録商標)、Tween80(登録商標)など、及びこれらの組み合わせが挙げられるが、これらに限定されない。ポリマーの中でも、エチレンオキシドとプロピレンオキシドとのコポリマーが好ましい場合がある。これらポリマーは、多くの場合、水による曇点を特徴とし、これは、生成物を水から分離して、望ましくない水溶性不純物を除去するのに役立ち得る。エチレンオキシドとプロピレンオキシドとのコポリマーの例としては、BASFによるPLURONICシリーズのポリマー及びDowによるTERGITOL(商標)シリーズのポリマーが挙げられるが、これらに限定されない。ロイコ着色剤組成物が洗濯ケア組成物に組み込まれたとき、これらポリマーは、非イオン性界面活性剤としても作用し得る。
当該組成物は、追加の布地シェーディング剤を含み得る。好適な布地シェーディング剤としては、染料、染料-粘土複合体、及び顔料が挙げられる。好適な染料としては、小分子染料及びポリマー染料が挙げられる。好適な小分子染料としては、ダイレクトブルー、ダイレクトレッド、ダイレクトバイオレット、アシッドブルー、アッシドレッド、アッシドバイオレット、ベーシックブルー、ベーシックバイオレット及びベーシックレッド、又はこれらの混合物のカラーインデックス(Colour Index、C.I.)分類に区分される染料からなる群から選択される小分子染料が挙げられる。好ましい染料としては、アルコキシル化アゾチオフェン、ソルベントバイオレット13、アシッドバイオレット50及びダイレクトバイオレット9が挙げられる。
本開示の洗浄組成物は、悪臭低減材料を含み得る。このような材料は、1種類以上の悪臭の知覚を減らすか、又は更には知覚しなくすることができる。これら材料は、計算された悪臭低減値(「MORV」)によって特徴付けることができ、MORVは国際公開第2016/049389号に示されている試験方法に従って計算される。
本開示の洗浄組成物は、タンニンを含み得る。タンニンは高等植物のポリフェノール二次代謝産物であり、タンニンはガロイル部分又はこれらの誘導体が種々のポリオール-、カテキン-及びトリテルペノイド核に結合している(ガロタンニン、エラジタンニン及び複合タンニン)ガロイルエステル並びにそれらの誘導体のいずれかであり、又はタンニンはフラバニル間結合及び置換パターン(縮合タンニン)を備え得るオリゴマーのプロアントシアニジン及びポリマーのプロアントシアニジンである。本開示の洗浄組成物は、ガロタンニン、エラジタンニン、複合タンニン、縮合タンニン、及びこれらの組み合わせからなる群から選択されるタンニンを含み得る。
(VI) -[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(VII) -[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(VIII) -[(OCHR5-CHR6)c-OR7]f
(式中、
a、b及びcは、1~200であり、
d、e及びfは、1~50であり、
Arは、1,4-置換フェニレンであり、
sArは、5位がSO3Meで置換されている1,3-置換フェニレンであり、
Meは、Li、K、Mg/2、Ca/2、Al/3、アンモニウム、モノ-、ジ-、トリ-、若しくはテトラ-アルキルアンモニウム(アルキル基は、C1~C18アルキル又はC2~C10ヒドロキシアルキルである)、又はこれらの混合物であり、
R1、R2、R3、R4、R5及びR6は、独立して、H、又はC1~C18n-若しくはイソ-アルキルから選択され、
R7は、直鎖若しくは分枝鎖C1~C18アルキル、又は直鎖若しくは分枝鎖C2~C30アルケニル、又は5個~9個の炭素原子を有するシクロアルキル基、又はC8~C30アリール基、又はC6~C30アリールアルキル基である)。
(I) -[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(II) -[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(III) -[(OCHR5-CHR6)c-OR7]f
(式中、
a、b及びcは、1~200であり、
d、e及びfは、1~50であり、
Arは、1,4-置換フェニレンであり、
sArは、5位がSO3Meで置換されている1,3-置換フェニレンであり、
Meは、Li、K、Mg/2、Ca/2、Al/3、アンモニウム、モノ-、ジ-、トリ-、若しくはテトラ-アルキルアンモニウム(アルキル基は、C1~C18アルキル又はC2~C10ヒドロキシアルキルである)、又はこれらの混合物であり、
R1、R2、R3、R4、R5及びR6は、独立して、H、又はC1~C18n-若しくはイソ-アルキルから選択され、
R7は、直鎖若しくは分枝鎖C1~C18アルキル、又は直鎖若しくは分枝鎖C2~C30アルケニル、又は5個~9個の炭素原子を有するシクロアルキル基、又はC8~C30アリール基、又はC6~C30アリールアルキル基である)。
(a)米国特許第6,312,936(B1)号、同第5,679,630号、同第4,760,025号、同第7,262,042号、及び国際公開第09/021867号に記載されている、バチルス・レンタス(Bacillus lentus)、バチルス・アルカロフィラス(B.alkalophilus)、バチルス・ズブチルス(B.subtilis)、バチルス・アミロリケファシエンス(B.amyloliquefaciens)、バチルス・プミルス(Bacillus pumilus)及びバチルス・ギブソニイ(Bacillus gibsonii)などのバチルス属由来のものを含むサブチリシン(EC 3.4.21.62)。
(b)国際公開第89/06270号に記載されているフサリウム属プロテアーゼ、並びに同第05/052161号及び同第05/052146号に記載されているセルロモナス属に由来するキモトリプシンプロテアーゼを含む、トリプシン(例えば、ブタ又はウシ起源)などのトリプシン型又はキモトリプシン型のプロテアーゼ。
(c)国際公開第07/044993(A2)号に記載されているバチルス・アミロリケファシエンスに由来するものを含むメタロプロテアーゼ。
(a)国際公開第94/02597号、同第94/18314号、同第96/23874号及び同第97/43424号に記載されている変異体、特に国際公開第96/23874号に配列番号2として列挙されている酵素に対して、以下の位置:15、23、105、106、124、128、133、154、156、181、188、190、197、202、208、209、243、264、304、305、391、408及び444のうちの1つ以上が置換されている変異体。
(b)米国特許第5,856,164号、並びに国際公開第99/23211号、同第96/23873号、同第00/60060号及び同第06/002643号に記載されている変異体、特に国際公開第06/002643号に配列番号12として列挙されているAA560酵素に対して、以下の位置:
26、30、33、82、37、106、118、128、133、149、150、160、178、182、186、193、203、214、231、256、257、258、269、270、272、283、295、296、298、299、303、304、305、311、314、315、318、319、339、345、361、378、383、419、421、437、441、444、445、446、447、450、461、471、482、484のうちの1つ以上が置換されている変異体、好ましくはD183*及びG184*の欠失も含有する変異体。
(c)国際公開第06/002643号における配列番号4、バチルス属SP722由来の野生型酵素と少なくとも90%の同一性を示す変異体、特に183及び184位に欠失を有する変異体、並びに参照により本明細書に組み込まれる国際公開第00/60060号に記載されている変異体。
(d)バチルス属707の野生型酵素(米国特許第6,093,562号の配列番号7)と少なくとも95%の同一性を示す変異体、特に、以下の変異M202、M208、S255、R172、及び/又はM261のうちの1つ以上を含むもの。好ましくは、当該アミラーゼは、M202L、M202V、M202S、M202T、M202I、M202Q、M202W、S255N及び/又はR172Qのうちの1つ以上を含む。特に好ましいのは、M202L又はM202T変異を含むものである。
(e)国際公開第09/149130号に記載されている変異体、好ましくは国際公開第09/149130号において配列番号1又は配列番号2と少なくとも90%の同一性を示すもの、ゲオバチルス・ステアロフェルモフィルス(Geobacillus Stearophermophiluss)に由来する野生型酵素又はその切断バージョン。
(1)光漂白剤、例えば、スルホン化亜鉛フタロシアニン、スルホン化アルミニウムフタロシアニン、キサンテン染料、チオキサントン、及びこれらの混合物。
(2)予形成過酸:好適な予形成過酸としては、予形成ペルオキシ酸又はその塩、典型的には過カルボン酸及び塩、過炭酸及び塩、過イミド酸及び塩、ペルオキシ一硫酸及び塩、例えばOxone(登録商標)、並びにこれらの混合物からなる群から選択される化合物が挙げられるが、これらに限らない。
(3)過酸化水素源、例えば、過ホウ酸塩(通常、一水和物又は四水和物)、過炭酸塩、過硫酸塩、過リン酸塩、過ケイ酸塩及びこれらの混合物のナトリウム塩などのアルカリ金属塩を含む、無機過水和物の塩。無機過水和物の塩は、使用する場合、典型的には、布地ケア及びホームケア製品全体の0.05~40重量%又は1~30重量%の量で存在し、典型的には、コーティングされ得る結晶性固体としてこのような布地ケア及びホームケア製品に組み込まれる。好適なコーティングとしては、無機塩、例えば、アルカリ金属ケイ酸塩、炭酸塩若しくはホウ酸塩又はこれらの混合物、又は有機物質、例えば、水溶性若しくは分散性ポリマー、ワックス、油又は脂肪石鹸などが挙げられる。
(4)R-(C=O)-L(式中、Rはアルキル基であり、任意に分岐しており、漂白活性剤が疎水性である場合、6個~14個の炭素原子、又は8個~12個の炭素原子を有し、漂白活性剤が親水性である場合、6つ未満の炭素原子又は更には4つ未満の炭素原子を有し、Lは脱離基である)を有する漂白活性剤。好適な脱離基の例は、安息香酸及びその誘導体、特にベンゼンスルホネートである。好適な漂白活性剤としては、ドデカノイルオキシベンゼンスルホネート、デカノイルオキシベンゼンスルホネート、デカノイルオキシ安息香酸又はその塩、3,5,5-トリメチルヘキサノイルオキシベンゼンスルホネート、テトラアセチルエチレンジアミン(TAED)及びノナノイルオキシベンゼンスルホネート(NOBS)が挙げられる。
(5)漂白触媒。本発明の組成物は、ペルオキシ酸及び/又はその塩から酸素原子を受け取って、その酸素原子を酸化可能な基質に転移させることができる1つ以上の漂白触媒を含んでいてもよい。好適な漂白触媒としては、イミニウムカチオン及びポリイオン、イミニウム双性イオン、変性アミン、変性アミンオキシド、N-スルホニルイミン、N-ホスホニルイミン、N-アシルイミン、チアジアゾールジオキシド、ペルフルオロイミン、環状糖ケトン及びαアミノ-ケトン並びにこれらの混合物が挙げられるが、これらに限定されない。特に好ましい一触媒は、4-(2-(2-((2-ヒドロキシフェニルメチル)メチレン)-ヒドラジニル)-2-オキソエチル)-4-メチルクロリドなどのアシルヒドラゾン型である。
(6)当該組成物は、好ましくは、触媒金属錯体を含み得る。金属含有漂白触媒の好ましい一種は、銅、鉄、チタン、ルテニウム、タングステン、モリブデン、又はマンガンのカチオンなどの、規定の漂白触媒活性の遷移金属カチオンを含む触媒系である。
当該組成物は、任意に、有機溶媒を含み得る。好適な有機溶媒としては、C4~14エーテル及びジエーテル、グリコール、アルコキシル化グリコール、C6~C16グリコールエーテル、アルコキシル化芳香族アルコール、芳香族アルコール、脂肪族分岐鎖アルコール、アルコキシル化脂肪族分岐鎖アルコール、アルコキシル化直鎖C1~C5アルコール、直鎖C1~C5アルコール、アミン、C8~C14アルキル及びシクロアルキル炭化水素及びハロ炭化水素、並びにこれらの混合物が挙げられる。好適な有機溶媒としては、1,2-プロパンジオール、2,3ブタンジオール、エタノール、グリセロール、エトキシル化グリセロール、ジプロピレングリコール、メチルプロパンジオール及びこれらの混合物が挙げられる。また、他の低級アルコール、C1~C4アルカノールアミン、例えば、モノエタノールアミン及びトリエタノールアミンなどを使用してもよい。溶媒系は、例えば本発明の無水固形物実施形態には存在しなくてもよいが、より典型的には、液体洗剤組成物の約0.1重量%~約98重量%の範囲、好ましくは少なくとも約1重量%~約50重量%、より通常は約5重量%~約25重量%、あるいは約1重量%~約10重量%の当該有機溶媒の濃度で存在する。これら有機溶媒は、水と共に使用されてもよく、又は水なしで使用されてもよい。
当該組成物が有機真珠光沢剤を含むとき、当該組成物の0.05重量%~2.0重量%、好ましくは0.1重量%~1.0重量%活性濃度で、100%活性有機真珠光沢剤が含まれる。好適な有機真珠光沢剤としては、エチレングリコールジステアレートなどのアルキレングリコールのモノエステル及び/又はジエステルが挙げられる。
別の実施形態では、当該組成物は無機真珠光沢剤を含んでもよい。当該組成物が無機真珠光沢剤を含むとき、当該組成物の0.005重量%~1.0重量%、好ましくは0.01重量%~0.2重量%活性濃度で、100%活性無機真珠光沢剤が含まれる。
一実施形態では、当該組成物は、約0.01重量%~約5重量%、あるいは約0.05重量%~約4重量%、あるいは約0.1重量%~約3重量%の濃度で複数の懸濁粒子を更に含む。好適な懸濁粒子の例は、米国特許第7,169,741号及び米国特許公開第2005/0203213号に記載されており、それらの開示は参照により本明細書に組み込まれる。これら懸濁粒子は、液体コア又は固体コアを含み得る。これら液体コア粒子及び固体コア粒子の詳細な説明、並びに好ましい粒径、粒子形状、粒子密度、及び粒子破裂強度の説明は、米国特許出願第12/370,714号に記載されており、その開示は参照により本明細書に組み込まれる。
一実施形態では、当該組成物は、乳白剤を含んでもよい。
本明細書の試験方法で使用される布地スワッチは、Testfabrics,Inc.(West Pittston,PA)から入手され、100%綿のスタイル403(2”×2”に切断)及び/又はスタイル464(4”×6”に切断)、並びに増白されていない多繊維布地、具体的にはスタイル41(5cm×10cm)である。
使用前に綿スワッチ(スタイル464)を細片化し、49℃の増白剤無配合強力液体洗濯洗剤(水溶液中1.55g/L)により2回洗浄することによって使用する。試験を行う各ロイコ組成物の濃縮原液を、エタノール、又は50:50のエタノール:水、好ましくはエタノールから選択される溶媒で調製する。
乾燥後、布地は、測定時点の間、室温で暗所に保管される。綿布のL*、a*、b*、及び白色度指数(WI CIE)値は、2時間の乾燥期間の終了後の時間t=0、6、24及び48時間の時点で測定する。各ロイコ着色剤について生成された12のスワッチ(それぞれ4つのスワッチを有する3つのフラスコ)の値を平均して、各時点tにおけるL*、a*、b*及びWI CIEのサンプル値を得る。
LCEt=DE*=((L* c-L* s)2+(a* c-a* s)2+(b* c-b* s)2)1/2
式中、下付き文字c及びsは、それぞれ、対照、すなわち、増白剤無配合AATCC強力液体洗濯洗剤で洗浄された布地、及びサンプル、すなわち、ロイコ着色剤を含有する洗濯ケア配合物で洗浄された布地を指し、LCEtを計算するために使用される値は、対応する時点t(0、6、24又は48時間)における値である。
ΔWI=WI CIE(洗浄後)-WI CIE(洗浄前)
δΔWI=ΔWIサンプル-ΔWI対照
乾燥後の特定の綿布を、15分、30分、45分、60分、75分、90分、120分、及び240分間にわたって模擬太陽光に曝露する。綿布のL*、a*、b*、及び白色度指数(WI CIE)値を、各曝露期間後にスワッチ上で測定する。各曝露時点におけるLCE及びΔWI値の計算は、上記の方法I.A.に記載されているとおりであり、サンプル及び対照洗濯ケア配合物のLCE値及びΔWI値は、列挙される曝露時間のセットから得られる最大値に設定される。
上記の方法Iに従って処理された綿布にロイコ着色剤によってもたらされる相対色相角は、以下のように求められる。
a)各溶液からの12のスワッチのa*値及びb*値を平均し、以下の式を使用してΔa*及びΔb*を求める。
Δa*=a* s-a* c及びΔb*=b* s-b* c
式中、下付き文字c及びsは、それぞれ、増白剤無配合AATCC強力液体洗濯洗剤(対照)で洗浄された布地、及びロイコ着色剤を含有する洗濯ケア配合物(サンプル)で洗浄された布地を指す。
b)Δa*及びΔb*の両方の絶対値が<0.25である場合、相対色相角(Relative Hue Angle、RHA)は計算されない。Δa*又はΔb*のいずれかの絶対値が≧0.25である場合、RHAは以下の式の1つを用いて求められる。
Δb*≧0の場合、RHA=ATAN2(Δa*,Δb*)
Δb*<0の場合、RHA=360+ATAN2(Δa*,Δb*)
試験される物質は、本発明によるロイコ着色剤、又はロイコ着色剤の第2の着色状態を表す染料(例えば、トリアリールメタン染料)のいずれかである。試験される物質の合計250~255mgを、4oz.のガラス瓶に秤量し、50.0mLの脱イオン水(Barnstesb Pure System、約17.27オーム)を磁気撹拌棒と共に添加する。瓶に蓋をし、磁気撹拌プレート上に置き、混合物を22.0℃で1時間撹拌する。その後、撹拌を停止し、混合物を1時間静置したままにしておく。その時間の終わりに、10.0mLの溶液を注射器内に引いて、次いでガラスファイバーAcrodisc(登録商標)フィルタを取り付け、アリコートを20mLシンチレーションバイアルに濾過する。VWR LabMaxピペッタを使用してピペット分けし、45.0マイクロリットルの濾過溶液を96ウェルプレートの8つの別個のウェルの各々に供給する。溶液を、Kibron Delta 8 Tensiometerにより約22.0℃で試験し、8つの測定された複製の平均値は表面張力値としてmN/m単位で報告される。
ΔWI=WI CIE(洗浄後)-WI CIE(洗浄前)
δΔWICIE=ΔWI(洗剤B)-ΔWI(洗剤A)
以下は、本開示に係る洗浄組成物の例示の実施例であり、限定を意図するものではない。
これら実施例は、単位用量洗濯洗剤用の様々な配合物を提供する。組成物8~12は、1つの単位容量区画を含む。組成物を封入するために使用されるフィルムは、ポリビニルアルコール系フィルムである。
Claims (6)
- 消費者起源の着古した綿布に対して改善された白色度をもたらす方法であって、
(i)(a)少なくとも1つの洗濯ケア成分と、(b)少なくとも1つのロイコ化合物を含むロイコ組成物を含む、洗濯ケア組成物を提供する工程であって、前記ロイコ化合物は、ロイコ部分と、前記ロイコ部分に共有結合したアルキレンオキシ部分とを含み、前記アルキレンオキシ部分が、少なくとも1つのエチレンオキシド基及び少なくとも1つのプロピレンオキシド基を含み、
前記ロイコ化合物は、下記式(CVII)の構造を有する化合物を含む、前記工程、
(ii)前記洗濯ケア組成物を液体媒体に添加する工程と、
(iii)織物物品を前記液体媒体中に配置する工程と、
(iv)任意に、前記織物をすすぐ工程と、
(v)前記織物物品を乾燥させる工程と、を含む、方法。 - 前記ロイコ組成物が、水、エチレングリコール、プロピレングリコール、グリセリン、ポリ(エチレングリコール)、ポリ(プロピレングリコール)、エチレンオキシドとプロピレンオキシドとのコポリマー、及びこれらの混合物からなる群から選択される溶媒を更に含む、請求項1に記載の方法。
- 前記ロイコ組成物が、抗酸化化合物を更に含む、請求項1又は2に記載の方法。
- 前記抗酸化化合物が、ヒンダードフェノール、ジアリールアミン、ベンゾフラノン、及びこれらの混合物からなる群から選択される、請求項3に記載の方法。
- 前記洗濯ケア成分が、界面活性剤、ビルダー、キレート剤、移染防止剤、分散剤、酵素、酵素安定剤、触媒物質、漂白活性剤、ポリマー分散剤、泥汚れ除去剤、再付着防止剤、増白剤、抑泡剤、染料、香料、香料送達系、構造化剤、布地柔軟剤、キャリア、ヒドロトロープ、加工助剤、顔料、抗酸化剤、及びこれらの混合物からなる群から選択される、請求項1~4のいずれか一項に記載の方法。
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- 2018-10-11 JP JP2020517509A patent/JP6993503B2/ja active Active
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JP2020535276A (ja) | 2020-12-03 |
CA3074938A1 (en) | 2019-04-18 |
US20190112558A1 (en) | 2019-04-18 |
US10717950B2 (en) | 2020-07-21 |
CN111201309A (zh) | 2020-05-26 |
MX2020003103A (es) | 2020-07-28 |
EP3694972A1 (en) | 2020-08-19 |
WO2019075146A1 (en) | 2019-04-18 |
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