JP6935745B2 - Color conversion layer and image display device - Google Patents
Color conversion layer and image display device Download PDFInfo
- Publication number
- JP6935745B2 JP6935745B2 JP2017248279A JP2017248279A JP6935745B2 JP 6935745 B2 JP6935745 B2 JP 6935745B2 JP 2017248279 A JP2017248279 A JP 2017248279A JP 2017248279 A JP2017248279 A JP 2017248279A JP 6935745 B2 JP6935745 B2 JP 6935745B2
- Authority
- JP
- Japan
- Prior art keywords
- color conversion
- conversion layer
- parts
- light
- organic dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 158
- 239000010410 layer Substances 0.000 claims description 105
- 239000002096 quantum dot Substances 0.000 claims description 65
- 239000000049 pigment Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 14
- 238000005192 partition Methods 0.000 claims description 5
- 239000002356 single layer Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 description 42
- 239000011347 resin Substances 0.000 description 42
- 239000000243 solution Substances 0.000 description 40
- 239000000976 ink Substances 0.000 description 38
- 239000000975 dye Substances 0.000 description 34
- 238000000034 method Methods 0.000 description 30
- -1 polyoxyethylene Polymers 0.000 description 30
- 239000006185 dispersion Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 22
- 239000004065 semiconductor Substances 0.000 description 22
- 239000000758 substrate Substances 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 20
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 20
- 239000011521 glass Substances 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 238000001035 drying Methods 0.000 description 16
- 239000002270 dispersing agent Substances 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 14
- 239000002904 solvent Substances 0.000 description 13
- 239000003446 ligand Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000007639 printing Methods 0.000 description 11
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 10
- 239000001052 yellow pigment Substances 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 239000010419 fine particle Substances 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000003513 alkali Substances 0.000 description 8
- 239000011324 bead Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 6
- 125000003709 fluoroalkyl group Chemical group 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- CDBORKXXLPAUKJ-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanethiol Chemical compound COCCOCCS CDBORKXXLPAUKJ-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000012860 organic pigment Substances 0.000 description 5
- 238000000206 photolithography Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical class 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000011258 core-shell material Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 239000001043 yellow dye Substances 0.000 description 4
- LIPRQQHINVWJCH-UHFFFAOYSA-N 1-ethoxypropan-2-yl acetate Chemical compound CCOCC(C)OC(C)=O LIPRQQHINVWJCH-UHFFFAOYSA-N 0.000 description 3
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 3
- MPAGVACEWQNVQO-UHFFFAOYSA-N 3-acetyloxybutyl acetate Chemical compound CC(=O)OC(C)CCOC(C)=O MPAGVACEWQNVQO-UHFFFAOYSA-N 0.000 description 3
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- QQOAQYATBPRSTN-UHFFFAOYSA-N OP(C1=C(CCC(C(C(C(F)(F)F)(F)F)(F)F)(F)F)C=CC=C1)(O)=O Chemical compound OP(C1=C(CCC(C(C(C(F)(F)F)(F)F)(F)F)(F)F)C=CC=C1)(O)=O QQOAQYATBPRSTN-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 3
- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 description 3
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000001053 orange pigment Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229940035024 thioglycerol Drugs 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 2
- CFXQEHVMCRXUSD-UHFFFAOYSA-N 1,2,3-Trichloropropane Chemical compound ClCC(Cl)CCl CFXQEHVMCRXUSD-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- AFZZYIJIWUTJFO-UHFFFAOYSA-N 1,3-diethylbenzene Chemical compound CCC1=CC=CC(CC)=C1 AFZZYIJIWUTJFO-UHFFFAOYSA-N 0.000 description 2
- DSNHSQKRULAAEI-UHFFFAOYSA-N 1,4-Diethylbenzene Chemical compound CCC1=CC=C(CC)C=C1 DSNHSQKRULAAEI-UHFFFAOYSA-N 0.000 description 2
- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 description 2
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 2
- POSWICCRDBKBMH-UHFFFAOYSA-N 3,3,5-trimethylcyclohexan-1-one Chemical compound CC1CC(=O)CC(C)(C)C1 POSWICCRDBKBMH-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229940116423 propylene glycol diacetate Drugs 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000001226 reprecipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 238000004528 spin coating Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- UTVGJHKGLOQOQM-UHFFFAOYSA-N (2,6-dinitrophenyl)methyl n-cyclohexylcarbamate Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1COC(=O)NC1CCCCC1 UTVGJHKGLOQOQM-UHFFFAOYSA-N 0.000 description 1
- NJMCHQONLVUNAM-UHFFFAOYSA-N (2-nitrophenyl)methyl n-cyclohexylcarbamate Chemical compound [O-][N+](=O)C1=CC=CC=C1COC(=O)NC1CCCCC1 NJMCHQONLVUNAM-UHFFFAOYSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FDKXTQMXEQVLRF-ZHACJKMWSA-N (E)-dacarbazine Chemical compound CN(C)\N=N\c1[nH]cnc1C(N)=O FDKXTQMXEQVLRF-ZHACJKMWSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- FWSHWHRUHWQULU-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,19-nonatriacontafluorononadecan-9-yl 2-methylprop-2-enoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(OC(=O)C(=C)C)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F FWSHWHRUHWQULU-UHFFFAOYSA-N 0.000 description 1
- QSNVPAFOIAPKDL-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heptacosafluorotridecan-5-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)F QSNVPAFOIAPKDL-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- IBSQPLPBRSHTTG-UHFFFAOYSA-N 1-chloro-2-methylbenzene Chemical compound CC1=CC=CC=C1Cl IBSQPLPBRSHTTG-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- HRWADRITRNUCIY-UHFFFAOYSA-N 2-(2-propan-2-yloxyethoxy)ethanol Chemical compound CC(C)OCCOCCO HRWADRITRNUCIY-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- XOSCOJBBKOVIOM-UHFFFAOYSA-N 2-aminoethanol;octadecanoic acid Chemical compound NCCO.CCCCCCCCCCCCCCCCCC(O)=O XOSCOJBBKOVIOM-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- HCGFUIQPSOCUHI-UHFFFAOYSA-N 2-propan-2-yloxyethanol Chemical compound CC(C)OCCO HCGFUIQPSOCUHI-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- TYNRPOFACABVSI-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC(F)(F)C(F)(F)C(F)(F)C(F)(F)F TYNRPOFACABVSI-UHFFFAOYSA-N 0.000 description 1
- FQHLOOOXLDQLPF-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F FQHLOOOXLDQLPF-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- QMYGFTJCQFEDST-UHFFFAOYSA-N 3-methoxybutyl acetate Chemical compound COC(C)CCOC(C)=O QMYGFTJCQFEDST-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 1
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 1
- MPYMXFPVZWGKBD-UHFFFAOYSA-N 4,4,4-trifluoro-2,3-bis(trifluoromethyl)but-2-enoic acid Chemical compound FC(F)(F)C(=C(C(=O)O)C(F)(F)F)C(F)(F)F MPYMXFPVZWGKBD-UHFFFAOYSA-N 0.000 description 1
- NPDACUSDTOMAMK-UHFFFAOYSA-N 4-Chlorotoluene Chemical compound CC1=CC=C(Cl)C=C1 NPDACUSDTOMAMK-UHFFFAOYSA-N 0.000 description 1
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 1
- ZMFWEWMHABZQNB-UHFFFAOYSA-N 6-acetyloxyhexyl acetate Chemical compound CC(=O)OCCCCCCOC(C)=O ZMFWEWMHABZQNB-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical class CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- NFWDNXZCLUSYFA-UHFFFAOYSA-N C(C(=C)C)(=O)OC(C(C(F)(F)F)(F)F)(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)F Chemical compound C(C(=C)C)(=O)OC(C(C(F)(F)F)(F)F)(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)F NFWDNXZCLUSYFA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- FKMGXBQOWDJPNA-UHFFFAOYSA-N OC(C(C(F)(F)F)=C(C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O Chemical compound OC(C(C(F)(F)F)=C(C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O FKMGXBQOWDJPNA-UHFFFAOYSA-N 0.000 description 1
- DIWVKZQDGASCQU-UHFFFAOYSA-N OC(C(C(F)(F)F)=C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O Chemical compound OC(C(C(F)(F)F)=C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O DIWVKZQDGASCQU-UHFFFAOYSA-N 0.000 description 1
- JILGIKJHVOKYRY-UHFFFAOYSA-N OC(C(C(F)(F)F)=C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O Chemical compound OC(C(C(F)(F)F)=C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)C(F)(F)F)=O JILGIKJHVOKYRY-UHFFFAOYSA-N 0.000 description 1
- VOJFQOFAKWWZIM-UHFFFAOYSA-N OC(C(C(F)(F)F)=C(C(C(F)(F)F)(F)F)C(F)(F)F)=O Chemical compound OC(C(C(F)(F)F)=C(C(C(F)(F)F)(F)F)C(F)(F)F)=O VOJFQOFAKWWZIM-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 1
- BEPURUHCIIKABU-UHFFFAOYSA-M [Na+].OCCN(CCO)CCO.CCCCCCCCCCCCOS([O-])(=O)=O Chemical compound [Na+].OCCN(CCO)CCO.CCCCCCCCCCCCOS([O-])(=O)=O BEPURUHCIIKABU-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- VZVHUBYZGAUXLX-UHFFFAOYSA-N azane;azanide;cobalt(3+) Chemical compound N.N.N.[NH2-].[NH2-].[NH2-].[Co+3] VZVHUBYZGAUXLX-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229910052795 boron group element Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 125000000609 carbazolyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052800 carbon group element Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000739 chaotic effect Effects 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- OVTCUIZCVUGJHS-UHFFFAOYSA-N dipyrrin Chemical compound C=1C=CNC=1C=C1C=CC=N1 OVTCUIZCVUGJHS-UHFFFAOYSA-N 0.000 description 1
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 1
- SVMUEEINWGBIPD-UHFFFAOYSA-N dodecylphosphonic acid Chemical compound CCCCCCCCCCCCP(O)(O)=O SVMUEEINWGBIPD-UHFFFAOYSA-N 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 1
- 229910001849 group 12 element Inorganic materials 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229960001330 hydroxycarbamide Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- XVTQAXXMUNXFMU-UHFFFAOYSA-N methyl 2-(3-oxo-2-pyridin-2-yl-1h-pyrazol-5-yl)acetate Chemical compound N1C(CC(=O)OC)=CC(=O)N1C1=CC=CC=N1 XVTQAXXMUNXFMU-UHFFFAOYSA-N 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229940069822 monoethanolamine lauryl sulfate Drugs 0.000 description 1
- HMCXUWOCJBEBES-UHFFFAOYSA-N n-ethyl-n-phosphanylethanamine Chemical compound CCN(P)CC HMCXUWOCJBEBES-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000001048 orange dye Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- LGUZHRODIJCVOC-UHFFFAOYSA-N perfluoroheptane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LGUZHRODIJCVOC-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000001443 photoexcitation Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052696 pnictogen Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 230000005610 quantum mechanics Effects 0.000 description 1
- 238000006862 quantum yield reaction Methods 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- ZJMWRROPUADPEA-UHFFFAOYSA-N sec-butylbenzene Chemical compound CCC(C)C1=CC=CC=C1 ZJMWRROPUADPEA-UHFFFAOYSA-N 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical class C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- LZTRCELOJRDYMQ-UHFFFAOYSA-N triphenylmethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C1=CC=CC=C1 LZTRCELOJRDYMQ-UHFFFAOYSA-N 0.000 description 1
- JODJRDDQVZMRIY-UHFFFAOYSA-N trityloxyboronic acid Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(OB(O)O)C1=CC=CC=C1 JODJRDDQVZMRIY-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Images
Description
本発明は、色変換層、量子ドットを含有する色変換層、およびこれらを用いた画像表示装置に関する。 The present invention relates to a color conversion layer, a color conversion layer containing quantum dots, and an image display device using these.
量子ドットは、量子力学に従う独特な光学特性を発現させるために、電子を微小な空間に閉じ込めるために形成された極小さな粒（ドット）である。１粒の量子ドットの大きさは、直径１ナノメートルから数１０ナノメートルであり、約１万個以下の原子で構成されている。発する蛍光の波長が、粒の大きさで連続的に制御できること、蛍光強度の波長分布が対称性の高いシャープな発光が得られることから近年注目を集めている。 Quantum dots are tiny particles (dots) formed to confine electrons in a minute space in order to express unique optical properties that follow quantum mechanics. The size of one quantum dot is from 1 nanometer to several tens of nanometers in diameter, and is composed of about 10,000 or less atoms. In recent years, attention has been focused on the fact that the wavelength of the emitted fluorescence can be continuously controlled by the grain size and that sharp emission with high symmetry in the wavelength distribution of the fluorescence intensity can be obtained.
量子ドットは、人体を透過しやすい波長に蛍光を調整でき、体内のあらゆる場所に送達できることより発光材料として生体イメージング用途（非特許文献１）、褪色の恐れがない波長変換材料として太陽電池用途（特許文献１）、鮮明な発光材料、波長変換材料としてエレクトロニクス・フォトニクス用途（特許文献２，３）への展開検討が行われている。 Quantum dots can adjust fluorescence to a wavelength that easily penetrates the human body and can be delivered to any location in the body, so they are used for bioimaging as a light emitting material (Non-Patent Document 1), and as a wavelength conversion material that does not fade (Non-Patent Document 1). Patent Document 1), a clear light emitting material, and a wavelength conversion material are being studied for development in electronics and photonics applications (Patent Documents 2 and 3).
波長変換材料として展開する際には、励起に用いる光を透過させずに、目的とする波長の光に変化する必要があるが、量子ドットは無機ナノ粒子であり、有機染顔料と比較して、励起光の吸収効率が低い。このため、量子ドットを含む層で励起光を吸収しきれずに励起光がもれてしまうことが問題となっている。この対策として、特許文献４には、量子ドット含有する層と散乱粒子を含有させ、実質的な光路長を長くする提案がされているが、改善効果としては不十分であった。 When developing as a wavelength conversion material, it is necessary to change to light of the target wavelength without transmitting the light used for excitation, but quantum dots are inorganic nanoparticles and are compared with organic dyes and pigments. , The absorption efficiency of excitation light is low. Therefore, there is a problem that the excitation light cannot be completely absorbed by the layer containing the quantum dots and the excitation light leaks. As a countermeasure against this, Patent Document 4 proposes to include a layer containing quantum dots and scattered particles to lengthen the actual optical path length, but the improvement effect is insufficient.
照射した紫外可視光を波長５００〜８００ｎｍに効率よく変換して透過させる色変換性に優れた色変換層を提供することである。 It is an object of the present invention to provide a color conversion layer having excellent color conversion property, which efficiently converts irradiated ultraviolet-visible light to a wavelength of 500 to 800 nm and transmits it.
本発明者は、前記課題を解決するために、鋭意検討した結果、紫外可視光を吸収して蛍光を発する量子ドットと紫外可視光の透過を防止する有機色素を含有する膜中において、紫外可視光を照射する面の量子ドット濃度が反対側の面の濃度より高い濃度勾配を付けて、量子ドット濃度が高い第１の面から紫外可視光を照射した場合に第２の面から観測される発光強度の最大値（Ｐ１）と第２の面から紫外可視光を照射した場合に第１の面から観測される発光強度の最大値（Ｐ２）の間で、Ｐ２に対するＰ１の比が特定の値以上の色変換層とすると、色変換性に優れた色変換層となることを見出して、この知見に基づいて本発明をなしたものである。 As a result of diligent studies to solve the above problems, the present inventor has made ultraviolet visible light in a film containing quantum dots that absorb ultraviolet visible light and emit fluorescence and an organic dye that prevents transmission of ultraviolet visible light. It is observed from the second surface when ultraviolet visible light is irradiated from the first surface with a high quantum dot concentration with a density gradient higher than the concentration of the opposite surface with the quantum dot density of the surface to be irradiated with light. The ratio of P1 to P2 is specific between the maximum value of emission intensity (P1) and the maximum value of emission intensity observed from the first surface when ultraviolet visible light is irradiated from the second surface (P2). It has been found that a color conversion layer having a value equal to or higher than the value is a color conversion layer having excellent color conversion properties, and the present invention has been made based on this finding.
すなわち、本発明は、画像表示装置に用いられる色変換層であって、
該色変換層が、量子ドットおよび有機色素を含有し、
該色変換層の第１の面へ紫外可視光を照射した場合に第２の面から観測される波長５００〜８００ｎｍの発光強度の最大値（Ｐ１）と、第２の面へ紫外可視光を照射した場合に第１の面から観測される波長５００〜８００ｎｍの発光強度の最大値（Ｐ２）が下記式（１）を充足することを特徴とする色変換層に関する。
式（１）
Ｐ１/Ｐ２≧１．５
That is, the present invention is a color conversion layer used in an image display device.
The color conversion layer contains quantum dots and an organic dye, and the color conversion layer contains quantum dots and an organic dye.
When the first surface of the color conversion layer is irradiated with ultraviolet-visible light, the maximum value (P1) of the emission intensity at a wavelength of 500 to 800 nm observed from the second surface and the ultraviolet-visible light are applied to the second surface. The present invention relates to a color conversion layer characterized in that the maximum value (P2) of the emission intensity at a wavelength of 500 to 800 nm observed from the first surface when irradiated satisfies the following formula (1).
Equation (1)
P1 / P2 ≧ 1.5
また、本発明は、有機色素が、黄色有機色素であることを特徴とする前記の色変換層に関する。 The present invention also relates to the above-mentioned color conversion layer, wherein the organic dye is a yellow organic dye.
また、本発明は、黄色有機色素が、顔料であることを特徴とする前記の色変換層に関する。 The present invention also relates to the above-mentioned color conversion layer, wherein the yellow organic dye is a pigment.
また、本発明は、色変換層が、量子ドットおよび有機色素から構成される単層であることを特徴とする前記の色変換層に関する。 The present invention also relates to the above-mentioned color conversion layer, wherein the color conversion layer is a single layer composed of quantum dots and an organic dye.
また、本発明は透明基材と、前記の色変換層とを有することを特徴とする色変換フィルタに関する。 The present invention also relates to a color conversion filter characterized by having a transparent base material and the color conversion layer described above.
また、本発明は、色変換層が、パターンニングされていることを特徴とする前記の色変換フィルタに関する。 The present invention also relates to the color conversion filter, wherein the color conversion layer is patterned.
また、本発明は、パターンニングされた色変換層が、遮光性の隔壁で区切られていることを特徴とする前記の色変換フィルタに関する。 The present invention also relates to the above-mentioned color conversion filter, wherein the patterned color conversion layer is separated by a light-shielding partition wall.
さらに、本発明は、前記の色変換フィルタと、バックライト光源とを具備する画像表示装置であって、バックライト光源側に前記色変換層の第１の面が配置され、画像表示側に前記色変換層の第２の面が配置されていることを特徴とする画像表示装置に関する。 Further, the present invention is an image display device including the color conversion filter and a backlight light source, in which the first surface of the color conversion layer is arranged on the backlight light source side and the image display side. The present invention relates to an image display device characterized in that a second surface of a color conversion layer is arranged.
本発明の第１態様によれば、変換効率が良い色変換層が提供される。
また、本発明の第２〜６の態様によれば量子ドットを含み、変換効率が良い色変換層が提供される。
According to the first aspect of the present invention, a color conversion layer having good conversion efficiency is provided.
Further, according to the second to sixth aspects of the present invention, a color conversion layer containing quantum dots and having good conversion efficiency is provided.
以下、本発明を詳細に説明する。
本発明の色変換膜は、第１の面から紫外可視光を照射した場合に第２の面から観測される波長５００〜８００ｎｍの間の発光強度の最大値（Ｐ１）と第２の面から紫外可視光を照射した場合に第２の面から観測される波長５００〜８００ｎｍの間の発光強度の最大値（Ｐ２）が下記式（１）を充足する色変換層である。
式（１）
Ｐ１／Ｐ２≧１．５
Hereinafter, the present invention will be described in detail.
In the color conversion film of the present invention, when ultraviolet-visible light is irradiated from the first surface, the maximum value (P1) of the emission intensity between the wavelengths of 500 to 800 nm observed from the second surface and the second surface A color conversion layer in which the maximum value (P2) of the emission intensity between the wavelengths of 500 and 800 nm observed from the second surface when irradiated with ultraviolet-visible light satisfies the following formula (1).
Equation (1)
P1 / P2 ≧ 1.5
本発明の画像表示装置とは、予め記憶された、及び放送または通信により与えられる図形、文字、数字、もしくは画像を表示する装置をいう。 The image display device of the present invention refers to a device that displays figures, characters, numbers, or images stored in advance and given by broadcasting or communication.
本発明で色変換に用いることができる紫外可視光とは、波長２８０ｎｍ〜７００ｎｍの紫外可視光である。２８０ｎｍ以下の光は樹脂に吸収されて減衰したり、部材の劣化を促進する恐れがある。７００ｎｍ以上の光では、可視光を発光させるためにはエネルギー不足である。 The ultraviolet-visible light that can be used for color conversion in the present invention is ultraviolet-visible light having a wavelength of 280 nm to 700 nm. Light of 280 nm or less may be absorbed by the resin and attenuated, or may accelerate the deterioration of the member. Light of 700 nm or more has insufficient energy to emit visible light.
色変換層に紫外可視光を照射した場合に観測される波長５００〜８００ｎｍの間の発光強度の最大値は、色変換層に含まれる量子ドットが紫外可視光を吸収し、５００〜８００ｎｍの間に発した蛍光の最大値である。 The maximum value of the emission intensity between the wavelengths of 500 and 800 nm observed when the color conversion layer is irradiated with ultraviolet visible light is between 500 and 800 nm when the quantum dots contained in the color conversion layer absorb the ultraviolet visible light. It is the maximum value of the fluorescence emitted in.
照射した可視紫外光の色変換層透過防止のため有機色素を含有する。色変換層中で量子ドットと有機色素が膜厚方向に濃度分布を生じることで、照射する面を変更した際の波長５００〜８００ｎｍの間の発光強度の最大値Ｐ１とＰ２の間に差異が生じる。第１の面側の量子ドット濃度が高く、第２の面側に有機色素濃度が高くなると、色変換された光のみが効率的に透過し色変換効率が良くなり、この状態の場合にＰ１が大きく、Ｐ２が小さくなるので、Ｐ１／Ｐ２が大きくなる。 Contains an organic dye to prevent transmission of the irradiated visible ultraviolet light through the color conversion layer. Due to the density distribution of the quantum dots and the organic dye in the color conversion layer in the film thickness direction, there is a difference between the maximum value P1 and P2 of the emission intensity between the wavelengths of 500 to 800 nm when the surface to be irradiated is changed. Occurs. When the quantum dot density on the first surface side is high and the organic dye concentration is high on the second surface side, only the color-converted light is efficiently transmitted and the color conversion efficiency is improved. In this state, P1 Is large and P2 is small, so that P1 / P2 is large.
Ｐ１／Ｐ２は１．５以上が好ましい。1.5未満では十分な効果が得られない。より好ましくは１．８以上、さらに好ましくは１０以上である。 P1 / P2 is preferably 1.5 or more. If it is less than 1.5, a sufficient effect cannot be obtained. It is more preferably 1.8 or more, still more preferably 10 or more.
＜量子ドット＞
本発明の量子ドットは、半導体微粒子に必要に応じて、有機物からなるリガンドで処理されている。
<Quantum dot>
The quantum dots of the present invention are treated with a ligand made of an organic substance, if necessary, on the semiconductor fine particles.
本発明の半導体微粒子は、無機物を成分とする半導体であり、単一組成でも、コアシェル型でも、３層以上の複数層になっていてもよい。 The semiconductor fine particles of the present invention are semiconductors containing an inorganic substance as a component, and may have a single composition, a core-shell type, or a plurality of layers having three or more layers.
本発明の半導体は、２族元素、１０属元素、１１族元素、１２族元素、１３族元素、１４族元素、１５族元素および１６族元素で示される元素の群から選ばれる少なくとも２種以上の元素を含む化合物からなる半導体である。
The semiconductor of the present invention is at least two kinds selected from the group of elements represented by group 2 element,
さらに好ましくは化合物半導体である。化合物半導体は、Ｚｎ、Ｃｄ、Ｂ、Ａｌ、Ｇａ、Ｉｎ、Ｃ、Ｓｉ、Ｇｅ、Ｓｎ、Ｎ、Ｐ、Ａｓ、Ｓｂ、Ｐｂ、Ｓ，Ｓｅ，Ｔｅで示される元素群から選ばれる少なくとも２種の元素を含む化合物からなる半導体である。 More preferably, it is a compound semiconductor. The compound semiconductor is at least two kinds selected from the element group represented by Zn, Cd, B, Al, Ga, In, C, Si, Ge, Sn, N, P, As, Sb, Pb, S, Se and Te. It is a semiconductor composed of a compound containing the above elements.
さらに好ましくは、人に対する安全性が懸念される元素を除いた、Ｚｎ、Ｂ、Ａｌ、Ｇａ、Ｉｎ、Ｃ、Ｓｉ、Ｇｅ、Ｓｎ、Ｎ、Ｐ、Ｓ，Ｔｅで示される元素群から選ばれる少なくとも２種の元素を含む化合物からなる半導体である。 More preferably, it is selected from the group of elements represented by Zn, B, Al, Ga, In, C, Si, Ge, Sn, N, P, S and Te, excluding the elements that are concerned about human safety. It is a semiconductor composed of a compound containing at least two kinds of elements.
可視光を発光する用途では、バンドギャップの狭さからＩｎを構成元素として含む半導体が、さらに好ましい。 For applications that emit visible light, semiconductors containing In as a constituent element are more preferable because of the narrow bandgap.
コアシェル型の半導体微粒子はコアを形成する半導体と異なる成分からなる半導体でコア構造を被覆された構造となる。外部がバントギャップの大きい半導体をすることで、光励起によって生成された励起子（電子−正孔対）はコア内に閉じ込められる。その結果、半導体微粒子表面での無輻射遷移の確率が減少し、発光の量子収率および半導体量子ドットの蛍光特性の安定性が向上する。 The core-shell type semiconductor fine particles have a structure in which the core structure is coated with a semiconductor having a component different from that of the semiconductor forming the core. By making a semiconductor with a large bunt gap on the outside, excitons (electron-hole pairs) generated by photoexcitation are confined in the core. As a result, the probability of non-radiation transition on the surface of the semiconductor fine particles is reduced, and the quantum yield of light emission and the stability of the fluorescence characteristics of the semiconductor quantum dots are improved.
本発明の半導体微粒子の平均粒径は０．５ｎｍ〜１００ｎｍであることが好ましく、所望の発色が得られる粒径を選択することができる。コアシェル型の場合、一つの半導体微粒子の中に複数のシェル微粒子を含有してもよい。単一半導体組成である場合の半導体微粒子の平均粒径および、コアシェル型のコアの平均粒径は０．５ｎｍ〜１０ｎｍであることが好ましい。平均粒径が０．５ｎｍ未満となる合成は困難であり、また、１０ｎｍを超えると量子閉じ込め効果が得られず、求める蛍光が得られない。 The average particle size of the semiconductor fine particles of the present invention is preferably 0.5 nm to 100 nm, and a particle size capable of obtaining a desired color can be selected. In the case of the core-shell type, a plurality of shell fine particles may be contained in one semiconductor fine particle. In the case of a single semiconductor composition, the average particle size of the semiconductor fine particles and the average particle size of the core-shell type core are preferably 0.5 nm to 10 nm. Synthesis with an average particle size of less than 0.5 nm is difficult, and if it exceeds 10 nm, the quantum confinement effect cannot be obtained and the desired fluorescence cannot be obtained.
本発明の量子ドットは、平均粒径が２ｎｍ〜１μｍであることが好ましい。
量子ドットの形状は、球状に限らず、棒状、円盤状、そのほかの形状であっても良い。
The quantum dots of the present invention preferably have an average particle size of 2 nm to 1 μm.
The shape of the quantum dot is not limited to a spherical shape, and may be a rod shape, a disk shape, or another shape.
本発明の量子ドットは、分散安定化の目的に、半導体微粒子の表面をリガンドで処理することができる。リガンドには界面活性剤などいろいろな有機物を用いることができる。チオール基、カルボキシル基、リン酸基、ホスホン酸、アミノ基等を部分構造として有するリガンドを、コア剤、シェル剤の種類に合わせて選択して用いることができる。 The quantum dots of the present invention can treat the surface of semiconductor fine particles with a ligand for the purpose of stabilizing dispersion. Various organic substances such as surfactants can be used as the ligand. A ligand having a thiol group, a carboxyl group, a phosphoric acid group, a phosphonic acid, an amino group or the like as a partial structure can be selected and used according to the type of the core agent and the shell agent.
リガンドには、炭素数６以上のアルキル基が部分構造を有するリガンドが分散安定化に寄与が大きく好適である。 As the ligand, a ligand having a partial structure of an alkyl group having 6 or more carbon atoms is suitable because it greatly contributes to dispersion stabilization.
リガンドの例として、ドデカンチオール、ヘキシルチオール、オレイン酸、ステアリン酸、リン酸モノオクチル、ドデカンホスホン酸、オレイルアミン、ヘキシルアミン等をあげることができる。 Examples of the ligand include dodecanethiol, hexylthiol, oleic acid, stearic acid, monooctyl phosphate, dodecanephosphonic acid, oleylamine, hexylamine and the like.
リガンドにフルオロアルキル基やシロキサン基を有するリガンドを用いると、色変換層形成時に、ＱＤが表面に偏在してＰ１／Ｐ２を増大させるので、第１面を色変換膜形成面にする際には好適である。 When a ligand having a fluoroalkyl group or a siloxane group is used as the ligand, QD is unevenly distributed on the surface to increase P1 / P2 when the color conversion layer is formed. Therefore, when the first surface is used as the color conversion film forming surface, Suitable.
このリガンドの例として、HS-(CH2)11-O-(CH2)2-(CF2)5-CF3、HS-(CH2)11-O-CH2-C6F5ペルフルオロヘプタン酸、2-（ノナフルオロブチル）エチルフェニルフォスホン酸、メガファックＦ−５１０（ＤＩＣ製、パーフルオロアルキル基、リン酸基含有リン酸エステル）、メルカプト変性シリコーンＫＦ−２００１，２００４（信越シリコーン製）などをあげることができる。 Examples of this ligand are HS- (CH 2 ) 11 -O- (CH 2 ) 2- (CF 2 ) 5- CF 3 , HS- (CH 2 ) 11 -O-CH 2- C 6 F 5 perfluoroheptane. Acid, 2- (nonafluorobutyl) ethylphenylphosphonic acid, Megafuck F-510 (manufactured by DIC, perfluoroalkyl group, phosphoric acid group-containing phosphoric acid ester), mercapto-modified silicone KF-2001,2004 (manufactured by Shinetsu Silicone) ) Etc. can be given.
＜有機色素＞
本発明の有機色素には、有機染料と有機顔料を用いることができる、色素の低マイグレーション性から、有機顔料が好適用いることができる。
<Organic pigment>
As the organic dye of the present invention, an organic dye and an organic pigment can be used, and the organic pigment can be preferably used because of the low migration property of the dye.
本発明の黄色色素としては、黄色、橙色の色素を用いることができる。 As the yellow pigment of the present invention, yellow and orange pigments can be used.
黄色、橙色染料としては、本発明の効果を損なわない限り特に制限はなく、公知の染料を用いることが可能であり、例えば、アゾ系染料、キノフタロン系染料、シアニン系染料、アントラキノン系染料、メチン系染料及びジピロメテン系染料などが挙げられる。 The yellow and orange dyes are not particularly limited as long as the effects of the present invention are not impaired, and known dyes can be used. For example, azo dyes, quinophthalone dyes, cyanine dyes, anthraquinone dyes, and methines can be used. Examples thereof include dyes and dipyrromethene dyes.
黄色、橙色の有機顔料としては、例えば、Ｃ．Ｉ．ピグメントイエローとＣ．Ｉ．ピグメントオレンジの顔料等が挙げられる。 Examples of yellow and orange organic pigments include C.I. I. Pigment Yellow and C.I. I. Pigment orange pigments and the like.
黄色顔料としては、１、２、３、４、５、６、９、１０、１２、１３、１４、１５、１６、１７、１８、２４、３１、３２、３４、３５、３５：１、３６、３６：１、３７、３７：１、４０、４２、４３、５３、５５、６０、６１、６２、６３、６５、７３、７４、７７、８１、８３、８７、９３、９４、９５、９７、９８、１００、１０１、１０４、１０６、１０８、１０９、１１０、１１３、１１４、１１５、１１６、１１７、１１８、１１９、１２０、１２３、１２６、１２７、１２８、１２９、１３２、１３８、１３９、１４７、１５０、１５１、１５２、１５３、１５４、１５５、１５６、１６１、１６２、１６４、１６６、１６７、１６８、１７０、１７１、１７２、１７３、１７４、１７５、１７６、１７７、１７９、１８０、１８１、１８２、１８３、１８５、１８７、１８８、１９１、１９３、１９４、１９８、１９９、２０３，２１４等を好適に用いることができる。 Yellow pigments include 1, 2, 3, 4, 5, 6, 9, 10, 12, 13, 14, 15, 16, 17, 18, 24, 31, 32, 34, 35, 35: 1, 36. , 36: 1, 37, 37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 87, 93, 94, 95, 97 , 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 126, 127, 128, 129, 132, 138, 139, 147. , 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182. , 183, 185, 187, 188, 191 and 193, 194, 198, 199, 203, 214 and the like can be preferably used.
オレンジ色顔料としては、例えばＣ．Ｉ．ピグメントオレンジ３６、３８、４３、５１、５５、５９、６１、７１、７３、８０等を好適に用いることができる。 Examples of the orange pigment include C.I. I. Pigment Orange 36, 38, 43, 51, 55, 59, 61, 71, 73, 80 and the like can be preferably used.
染料は溶剤に溶解して用いることができる。 The dye can be used by dissolving it in a solvent.
顔料は溶剤に分散して用いることができる。顔料を分散する際には、適宜、界面活性剤、樹脂型顔料分散剤、色素誘導体等の分散剤が使用できる。分散剤は、顔料の分散に優れ、分散後の顔料の再凝集を防止する効果が大きいので、分散剤を用いて顔料をバインダー樹脂および有機溶剤中に分散すると、均一の液体として取り扱うことができる。分散剤は、着色組成物中の顔料１００重量部に対して、０．１〜２００重量部、好ましくは０．１〜１５０重量部の量で用いることができる。 The pigment can be used dispersed in a solvent. When dispersing the pigment, a dispersant such as a surfactant, a resin-type pigment dispersant, or a pigment derivative can be appropriately used. Since the dispersant is excellent in dispersing the pigment and has a great effect of preventing the pigment from reaggregating after dispersion, when the pigment is dispersed in the binder resin and the organic solvent by using the dispersant, it can be treated as a uniform liquid. .. The dispersant can be used in an amount of 0.1 to 200 parts by weight, preferably 0.1 to 150 parts by weight, based on 100 parts by weight of the pigment in the coloring composition.
界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル硫酸塩、ドデシルベンゼンスルホン酸ナトリウム、スチレン−アクリル酸共重合体のアルカリ塩、アルキルナフタリンスルホン酸ナトリウム、アルキルジフェニルエーテルジスルホン酸ナトリウム、ラウリル硫酸モノエタノールアミン、ラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ステアリン酸モノエタノールアミン、ステアリン酸ナトリウム、ラウリル硫酸ナトリウム、スチレン−アクリル酸共重合体のモノエタノールアミン、ポリオキシエチレンアルキルエーテルリン酸エステルなどのアニオン性界面活性剤；ポリオキシエチレンオレイルエーテル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレンアルキルエーテルリン酸エステル、ポリオキシエチレンソルビタンモノステアレート、ポリエチレングリコールモノラウレートなどのノニオン性界面活性剤；アルキル４級アンモニウム塩やそれらのエチレンオキサイド付加物などのカオチン性界面活性剤；アルキルジメチルアミノ酢酸ベタインなどのアルキルベタイン、アルキルイミダゾリンなどの両性界面活性剤、また、フッ素系やシリコーン系の界面活性剤が挙げられる。 Examples of the surfactant include polyoxyethylene alkyl ether sulfate, sodium dodecylbenzene sulfonate, alkali salt of styrene-acrylic acid copolymer, sodium alkylnaphthalin sulfonate, sodium alkyldiphenyl ether disulfonate, and monoethanolamine lauryl sulfate. , Sodium lauryl sulfate triethanolamine, ammonium lauryl sulfate, monoethanolamine stearate, sodium stearate, sodium lauryl sulfate, monoethanolamine of styrene-acrylic acid copolymer, anionic surfactant such as polyoxyethylene alkyl ether phosphate Agents: Nonionic surfactants such as polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene alkyl ether phosphate, polyoxyethylene sorbitan monostearate, and polyethylene glycol monolaurate. Chaotic surfactants such as alkyl quaternary ammonium salts and their ethylene oxide adducts; Alkyl betaines such as alkyldimethylaminoacetic acid betaine, amphoteric surfactants such as alkyl imidazoline, and fluorine-based and silicone-based surfactants. Agents can be mentioned.
樹脂型顔料分散剤は、顔料に吸着する性質を有する顔料親和性部位と、透明樹脂と相溶性のある部位とを有する樹脂であり、顔料に吸着して顔料の透明樹脂への分散を安定化する働きをするものである。樹脂型顔料分散剤として具体的には、ポリウレタン、ポリアクリレートなどのポリカルボン酸エステル、不飽和ポリアミド、ポリカルボン酸、ポリカルボン酸（部分）アミン塩、ポリカルボン酸アンモニウム塩、ポリカルボン酸アルキルアミン塩、ポリシロキサン、長鎖ポリアミノアマイドリン酸塩、水酸基含有ポリカルボン酸エステルや、これらの変性物、ポリ（低級アルキレンイミン）と遊離のカルボキシル基を有するポリエステルとの反応により形成されたアミドやその塩などの油性分散剤、（メタ）アクリル酸−スチレン共重合体、（メタ）アクリル酸−（メタ）アクリル酸エステル共重合体、スチレン−マレイン酸共重合体、ポリビニルアルコール、ポリビニルピロリドンなどの水溶性樹脂や水溶性高分子化合物、ポリエステル系、変性ポリアクリレート系、エチレンオキサイド／プロピレンオキサイド付加化合物、燐酸エステル系等が用いられ、これらは単独でまたは２種以上を混合して用いることができる。 The resin-type pigment dispersant is a resin having a pigment-affinitive portion having a property of adsorbing to a pigment and a portion compatible with a transparent resin, and is adsorbed on the pigment to stabilize the dispersion of the pigment in the transparent resin. It works to do. Specific examples of the resin-type pigment dispersant include polycarboxylic acid esters such as polyurethane and polyacrylate, unsaturated polyamides, polycarboxylic acids, polycarboxylic acid (partial) amine salts, polycarboxylic acid ammonium salts, and polycarboxylic acid alkylamines. Salts, polysiloxanes, long-chain polyaminoamide phosphates, hydroxyl group-containing polycarboxylic acid esters, modified products of these, amides formed by the reaction of poly (lower alkyleneimine) with polyesters having free carboxyl groups, and their amides. Oil-based dispersants such as salts, (meth) acrylic acid-styrene copolymer, (meth) acrylic acid- (meth) acrylic acid ester copolymer, styrene-maleic acid copolymer, polyvinyl alcohol, polyvinylpyrrolidone and other water-soluble Sexual resins, water-soluble polymer compounds, polyester-based, modified polyacrylate-based, ethylene oxide / propylene oxide-added compounds, phosphoric acid ester-based, and the like are used, and these can be used alone or in admixture of two or more.
色素誘導体は、有機色素に置換基を導入した化合物である。このような有機色素には、一般に色素とは呼ばれていないナフタレン系、アントラキノン系等の淡黄色の芳香族多環化合物も含まれる。色素誘導体としては、特開昭６３−３０５１７３号公報、特公昭５７−１５６２０号公報、特公昭５９−４０１７２号公報、特公昭６３−１７１０２号公報、特公平５−９４６９号公報等に記載されているものを使用でき、これらは単独でまたは２種類以上を混合して用いることができる。 A dye derivative is a compound in which a substituent is introduced into an organic dye. Such organic dyes also include pale yellow aromatic polycyclic compounds such as naphthalene and anthraquinone, which are not generally called dyes. Examples of the dye derivative are described in JP-A-63-305173, Japanese Patent Publication No. 57-15620, Japanese Patent Publication No. 59-40172, Japanese Patent Application Laid-Open No. 63-17102, Japanese Patent Publication No. 5-1469, and the like. These can be used alone or in admixture of two or more.
分散剤にフルオロアルキル基またはシロキサン基を有する分散剤を用いると、色変換層形成時に、有機顔料が表面に偏在してＰ１／Ｐ２を増大させるので、第１面を基板面にする際には好適である。 When a dispersant having a fluoroalkyl group or a siloxane group is used as the dispersant, the organic pigment is unevenly distributed on the surface to increase P1 / P2 when the color conversion layer is formed. Suitable.
この分散剤の例として、パーフルオロアルキル基とリン酸基含有リン酸エステルである、メガファックＦ−５１０（ＤＩＣ製）、炭素不飽和二重結合を有するパーフルオロアルキル基を有する単量体、エチレン性不飽和二重結合とポリオルガノシロキサン鎖を有する単量体を0.01〜10％共重合させた樹脂型分散体等を挙げることができる。0.01％以下では、偏在させることが不十分となる場合があり、 10％以上では塗工性が低下する場合がある。 Examples of this dispersant include Megafuck F-510 (manufactured by DIC), which is a phosphoric acid ester containing a perfluoroalkyl group and a phosphoric acid group, and a monomer having a perfluoroalkyl group having a carbon unsaturated double bond. Examples thereof include a resin-type dispersion in which a monomer having an ethylenically unsaturated double bond and a polyorganosiloxane chain is copolymerized by 0.01 to 10%. If it is 0.01% or less, uneven distribution may be insufficient, and if it is 10% or more, the coatability may be deteriorated.
炭素不飽和二重結合を有するパーフルオロアルキル基を有する単量体の例として2-(パーフルオロイソノニル)エチルメタクリレート、2-(パーフルオロノニル)エチルメタクリレート、2-(パーフルオロデシル)エチルメタクリレート、2-(パーフルオロブチル)エチルメタクリレート、パーフルオロメチル-メチルメタクリレート、パーフルオロエチル-メチルメタクリレート、パーフルオロブチル-メチルメタクリレート、パーフルオロオクチル-メチルメタクリレート、パーフルオロデシル-メチルメタクリレート、パーフルオロプロピル-プロピルメタクリレート、パーフルオロオクチル-プロピルメタクリレート、パーフルオロオクチル-アミルメタクリレート、パーフルオロオクチル-ウンデシルメタクリレート等の炭素数1〜20のパーフルオロ基を有するパーフルオロアルキル-アルキルメタクリレート及び上記メタクリレートをアクリレートに変えたパーフルオロアルキル-アルキルアクリレート類；パーフルオロブチルエチレン、パーフルオロヘキシルエチレン、パーフルオロオクチルエチレン、パーフルオロデシルエチレン等が挙げられる。要求性能に応じてこれらの内から１種類、あるいは２種類以上を混合して使用できる。 2- (Perfluoroisononyl) ethyl methacrylate, 2- (perfluorononyl) ethyl methacrylate, 2- (perfluorodecyl) ethyl methacrylate are examples of monomers having a perfluoroalkyl group having a carbon unsaturated double bond. , 2- (Perfluorobutyl) ethyl methacrylate, perfluoromethyl-methylmethacrylate, perfluoroethyl-methylmethacrylate, perfluorobutyl-methylmethacrylate, perfluorooctyl-methylmethacrylate, perfluorodecyl-methylmethacrylate, perfluoropropyl- Perfluoroalkyl-alkyl methacrylate having a perfluoro group having 1 to 20 carbon atoms such as propyl methacrylate, perfluorooctyl-propyl methacrylate, perfluorooctyl-amyl methacrylate, perfluorooctyl-undecyl methacrylate, and the above methacrylate are converted to acrylate. Perfluoroalkyl-alkyl acrylates; examples include perfluorobutylethylene, perfluorohexylethylene, perfluorooctylethylene, perfluorodecylethylene and the like. Depending on the required performance, one type or a mixture of two or more types can be used.
エチレン性不飽和二重結合とポリオルガノシロキサン鎖を有する単量体として、具体的には、東芝シリコーン（株）製のＴＳＬ９７０５などの片末端ビニル基含有ポリオルガノシロキサン化合物、チッソ（株）製のサイラプレーンＦＭ−０７１１、ＦＭ−０７２１、ＦＭ−０７２５などの片末端（メタ）アクリロキシ基含有ポリオルガノシロキサン化合物等が挙げられ、要求性能に応じてこれらの内から１種類、あるいは２種類以上を混合して使用できる。 Specific examples of the monomer having an ethylenically unsaturated double bond and a polyorganosiloxane chain include a one-terminal vinyl group-containing polyorganosiloxane compound such as TSL9705 manufactured by Toshiba Silicone Co., Ltd. and Chisso Co., Ltd. Examples include one-terminal (meth) acryloxy group-containing polyorganosiloxane compounds such as silaplane FM-0711, FM-0721, and FM-0725, and one or two or more of these are mixed depending on the required performance. Can be used.
有機色素は所望の外観色相、照射紫外可視光の遮蔽性に対応して、量子ドット１重量部に対して、０．０１〜１０重量部含有させることが好ましい。０．０１重量部以下では、照射紫外可視光の遮蔽が不十分となる場合があり、１０重量部以上では、量子ドットが励起できず蛍光が発せられない場合がある。 The organic dye is preferably contained in an amount of 0.01 to 10 parts by weight with respect to 1 part by weight of the quantum dots, corresponding to the desired appearance hue and the shielding property of the irradiated ultraviolet visible light. If it is 0.01 part by weight or less, the shielding of the irradiated ultraviolet visible light may be insufficient, and if it is 10 parts by weight or more, the quantum dots may not be excited and fluorescence may not be emitted.
＜インキ＞
本発明に用いるインキには、着色剤を十分に樹脂中に分散させ、ガラス基板等の基板上に本発明の着色組成物を乾燥膜厚が所望の膜厚になるように塗布することを容易にするために溶剤を含んでいてもよい。粘度を３〜５０ｍＰａ・ｓに調製して、インクジェットインキとすることもできる。
<Ink>
In the ink used in the present invention, it is easy to sufficiently disperse the colorant in the resin and apply the coloring composition of the present invention on a substrate such as a glass substrate so that the dry film thickness becomes a desired film thickness. It may contain a solvent to make it. The viscosity can be adjusted to 3 to 50 mPa · s to obtain an inkjet ink.
インキには印刷物への要求物性により、樹脂、架橋剤、重合性単量体、光感応性物質、熱感応性物質を添加することができる。 A resin, a cross-linking agent, a polymerizable monomer, a light-sensitive substance, and a heat-sensitive substance can be added to the ink depending on the required physical characteristics of the printed matter.
樹脂、架橋剤、重合性単量体、光感応性物質、熱感応性物質の添加物質の添加量としては、所望の量子ドット濃度により、量子ドット１重量部に対し、添加物質を０〜１００重量部添加することができる。１００を超えると量子ドット含有率が低くなる場合があり、十分な蛍光強度が得られない場合がある。 The amount of the additive to be added to the resin, the cross-linking agent, the polymerizable monomer, the light-sensitive substance, and the heat-sensitive substance is 0 to 100 per 1 part by weight of the quantum dot, depending on the desired quantum dot concentration. It can be added by weight. If it exceeds 100, the quantum dot content may be low, and sufficient fluorescence intensity may not be obtained.
本発明の量子ドットを含むインキを用いて、塗布し、紫外線照射により、フォトリソグラフィー法によりパターニングする際には、光感応性物質、重合性単量体を添加して、ポジ型レジスト、または、ネガ型レジストとすることができる。これらを単独で、または２種以上混合して用いることができる。 When the ink containing the quantum dots of the present invention is used for coating and patterning by the photolithography method by irradiation with ultraviolet rays, a photosensitive substance and a polymerizable monomer are added to form a positive resist or a positive resist. It can be a negative resist. These can be used alone or in combination of two or more.
溶剤としては、トルエン、１,２,３−トリクロロプロパン、１,３-ブチレングリコール、１,３-ブチレングリコールジアセテート、１,４−ジオキサン、２−ヘプタノン、２−メチル−１,３−プロパンジオール、３,５,５-トリメチル-２-シクロヘキセン-１-オン、３,３,５−トリメチルシクロヘキサノン、３−エトキシプロピオン酸エチル、３−メチル−１,３−ブタンジオール、３−メトキシ−３−メチル−１−ブタノール、３−メトキシ−３−メチルブチルアセテート、３-メトキシブタノール、３−メトキシブチルアセテート、４−ヘプタノン、ｍ−キシレン、ｍ−ジエチルベンゼン、ｍ−ジクロロベンゼン、Ｎ，Ｎ−ジメチルアセトアミド、Ｎ，Ｎ−ジメチルホルムアミド、ｎ−ブチルアルコール、ｎ−ブチルベンゼン、ｎ−プロピルアセテート、Ｎ−メチルピロリドン、o−キシレン、o−クロロトルエン、ｏ−ジエチルベンゼン、ｏ−ジクロロベンゼン、ｐ−クロロトルエン、ｐ−ジエチルベンゼン、ｓｅｃ−ブチルベンゼン、ｔｅｒｔ−ブチルベンゼン、トリメチルベンゼン、γ―ブチロラクトン、水、メタノール、エタノール、イソプロピルアルコール、ターシャルターシャルブタノール、イソブチルアルコール、イソホロン、エチレングリコールジエチルエーテル、エチレングリコールジブチルエーテル、エチレングリコールモノイソプロピルエーテル、エチレングリコールモノエチルエーテル、エチレングリコールモノエチルエーテルアセテート、エチレングリコールモノターシャリーブチルエーテル、エチレングリコールモノブチルエーテル、エチレングリコールモノブチルエーテルアセテート、エチレングリコールモノプロピルエーテル、エチレングリコールモノヘキシルエーテル、エチレングリコールモノメチルエーテル、エチレングリコールモノメチルエーテルアセテート、ジイソブチルケトン、ジエチレングリコールジエチルエーテル、ジエチレングリコールジメチルエーテル、ジエチレングリコールモノイソプロピルエーテル、ジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテル、ジエチレングリコールモノブチルエーテルアセテート、ジエチレングリコールモノメチルエーテル、シクロヘキサノール、シクロヘキサノールアセテート、シクロヘキサノン、ジプロピレングリコールジメチルエーテル、ジプロピレングリコールメチルエーテルアセテート、ジプロピレングリコールモノエチルエーテル、ジプロピレングリコールモノブチルエーテル、ジプロピレングリコールモノプロピルエーテル、ジプロピレングリコールモノメチルエーテル、ダイアセトンアルコール、トリアセチン、トリプロピレングリコールモノブチルエーテル、トリプロピレングリコールモノメチルエーテル、プロピレングリコールジアセテート、プロピレングリコールフェニルエーテル、プロピレングリコールモノエチルエーテル、プロピレングリコールモノエチルエーテルアセテート、プロピレングリコールモノブチルエーテル、プロピレングリコールモノプロピルエーテル、プロピレングリコールモノメチルエーテル、プロピレングリコールモノメチルエーテルアセテート、プロピレングリコールモノメチルエーテルプロピオネート、ベンジルアルコール、メチルイソブチルケトン、メチルシクロヘキサノール、酢酸ｎ−アミル、酢酸ｎ−ブチル、酢酸イソアミル、酢酸イソブチル、酢酸プロピル、及び二塩基酸エステル等が挙げられる。 As the solvent, toluene, 1,2,3-trichloropropane, 1,3-butylene glycol, 1,3-butylene glycol diacetate, 1,4-dioxane, 2-heptanone, 2-methyl-1,3-propane. Diol, 3,5,5-trimethyl-2-cyclohexene-1-one, 3,3,5-trimethylcyclohexanone, ethyl 3-ethoxypropionate, 3-methyl-1,3-butanediol, 3-methoxy-3 -Methyl-1-butanol, 3-methoxy-3-methylbutyl acetate, 3-methoxybutanol, 3-methoxybutyl acetate, 4-heptanone, m-xylene, m-diethylbenzene, m-dichlorobenzene, N, N-dimethyl Acetamide, N, N-dimethylformamide, n-butyl alcohol, n-butylbenzene, n-propyl acetate, N-methylpyrrolidone, o-xylene, o-chlorotoluene, o-diethylbenzene, o-dichlorobenzene, p-chloro Toluene, p-diethylbenzene, sec-butylbenzene, tert-butylbenzene, trimethylbenzene, γ-butyrolactone, water, methanol, ethanol, isopropyl alcohol, tershal tarshalbutanol, isobutyl alcohol, isophorone, ethylene glycol diethyl ether, ethylene glycol di Butyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monoethyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monotersial butyl ether, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol monopropyl ether, ethylene glycol monohexyl ether , Ethylene glycol monomethyl ether, ethylene glycol monomethyl ether acetate, diisobutyl ketone, diethylene glycol diethyl ether, diethylene glycol dimethyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, diethylene glycol monobutyl ether acetate, diethylene glycol monomethyl ether, cyclohexanol, cyclo Hexanol acetate, cyclohexanone, dipropylene glycol dimethyl ether, dipropylene glyco Lumethyl ether acetate, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monomethyl ether, diacetone alcohol, triacetin, tripropylene glycol monobutyl ether, tripropylene glycol monomethyl ether, Propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol monoethyl ether, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether pro Examples thereof include propyleneate, benzyl alcohol, methylisobutylketone, methylcyclohexanol, n-amyl acetate, n-butyl acetate, isoamyl acetate, isobutyl acetate, propyl acetate, and dibasic acid ester.
これらの溶剤は、１種を単独で、または必要に応じて任意の比率で２種以上混合して用いることができる。 These solvents may be used alone or in admixture of two or more at any ratio as required.
インクジェットインキとする場合には、樹脂に対する溶解性、装置部材に対する膨潤作用、粘度、及びノズルにおけるインキの乾燥性の点から選択され、一般式（１）：Ｒ1−（Ｏ−Ｃ2Ｈ4）m−Ｏ−Ｃ（＝Ｏ）−ＣＨ3［ただし、Ｒ1は炭素原子数１〜８のアルキル基であり、Ｃ2Ｈ4は直鎖若しくは分岐エチレン鎖であり、１≦ｍ≦３である。］で表される溶剤（Ａ−１）、及び一般式（２）：Ｒ2−（Ｏ−Ｃ3Ｈ6）p−Ｏ−Ｃ（＝Ｏ）−ＣＨ3［ただし、Ｒ2は炭素原子数１〜８のアルキル基であり、Ｃ3Ｈ6は直鎖若しくは分岐プロピレン鎖であり、１≦ｎ≦３である。］で表される溶剤（Ａ−２）、及びアセテート構造を２つ以上持つ溶剤（Ａ−３）からなる群から選ばれる７６０ｍｍＨｇでの沸点が１３５℃以上の１種類以上の溶剤を含むことが好ましい。 In the case of inkjet ink, it is selected from the viewpoints of solubility in resin, swelling action on device members, viscosity, and dryness of ink in nozzles, and general formula (1): R1- (OC 2 H 4 ). m-OC (= O) -CH 3 [However, R1 is an alkyl group having 1 to 8 carbon atoms, C 2 H 4 is a linear or branched ethylene chain, and 1 ≦ m ≦ 3. .. ], And the general formula (2): R2- (OC 3 H 6 ) p-OC (= O) -CH 3 [However, R2 has 1 carbon atom. It is an alkyl group of ~ 8, and C 3 H 6 is a linear or branched propylene chain, and 1 ≦ n ≦ 3. ], And one or more solvents having a boiling point of 135 ° C. or higher at 760 mmHg selected from the group consisting of the solvent (A-2) having two or more acetate structures. preferable.
さらに好ましくは、前記７６０ｍｍＨｇでの沸点が１３５℃以上の溶剤が全溶剤中６０重量％以上含むことが吐出安定性やノズルにおけるインキの乾燥性の点から好ましい。
前記溶剤の具体例としては、例えばジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテルアセテート、ジプロピレングリコールメチルエーテルアセテート、プロピレングリコールジアセテート、１，３−ブチレングリコールジアセテート、１，６−ヘキサンジオールジアセテート、トリアセチン等を挙げることができるが、必ずしもこれに限定されるものではない。中でも、好ましくはジエチレングリコールモノエチルエーテルアセテート、ジプロピレングリコールメチルエーテルアセテート、プロピレングリコールメチルエーテルアセテート、１，３−ブチレングリコールジアセテートが、吐出安定性の点から好ましい。
More preferably, the solvent having a boiling point of 135 ° C. or higher at 760 mmHg is contained in an amount of 60% by weight or more based on the total solvent from the viewpoint of ejection stability and ink drying property at the nozzle.
Specific examples of the solvent include, for example, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, dipropylene glycol methyl ether acetate, propylene glycol diacetate, 1,3-butylene glycol diacetate, 1,6-hexanediol diacetate, and the like. Triacetin and the like can be mentioned, but are not necessarily limited to this. Of these, diethylene glycol monoethyl ether acetate, dipropylene glycol methyl ether acetate, propylene glycol methyl ether acetate, and 1,3-butylene glycol diacetate are preferable from the viewpoint of discharge stability.
樹脂としては、石油系樹脂、マレイン酸樹脂、ニトロセルロース、セルロースアセテートブチレート、環化ゴム、塩化ゴム、アルキド樹脂、アクリル樹脂、ポリエステル樹脂、アミノ樹脂、ビニル樹脂、又はブチラール樹脂等があげられ、基材により適時選択することができる。 Examples of the resin include petroleum-based resin, maleic acid resin, nitrocellulose, cellulose acetate butyrate, cyclized rubber, rubber chloride, alkyd resin, acrylic resin, polyester resin, amino resin, vinyl resin, butyral resin and the like. It can be selected in a timely manner depending on the base material.
架橋剤としては、架橋剤はメラミン化合物、ベンゾグアナミン化合物、アクリレート系モノマー、カルボジイミド化合物、エポキシ化合物、オキセタン化合物、フェノール化合物、ベンゾオキサジン化合物、ブロック化カルン酸化合物、ブロック化イソシアネート化合物、及びシランカップリング剤からなる群から選ばれる化合物１種若しくは２種以上であることが耐熱耐性を持つ熱架橋性の架橋剤である点から好ましい。 As the cross-linking agent, the cross-linking agent is a melamine compound, a benzoguanamine compound, an acrylate-based monomer, a carbodiimide compound, an epoxy compound, an oxetane compound, a phenol compound, a benzoxazine compound, a blocked caric acid compound, a blocked isocyanate compound, and a silane coupling agent. It is preferable that one or more of the compounds selected from the group consisting of two or more are heat-resistant, because they are thermally crosslinkable cross-linking agents.
本発明に用いる重合性単量体には、紫外線や熱などにより硬化して樹脂を生成するモノマーもしくはオリゴマーが含まれ、これらを単独で、または２種以上混合して用いることができる。 The polymerizable monomer used in the present invention contains a monomer or an oligomer that is cured by ultraviolet rays, heat, or the like to form a resin, and these can be used alone or in combination of two or more.
本発明の組成物が含んでもよい熱感応性物質としては、熱重合開始剤としては、有機過酸化物系開始剤、アゾ系開始剤等を挙げることができる。 Examples of the heat-sensitive substance that the composition of the present invention may contain include an organic peroxide-based initiator, an azo-based initiator, and the like as the thermal polymerization initiator.
本発明の組成物が含んでもよい光感応性物質としては、光重合開始剤、光酸発生剤、光塩基発生剤があげられる。光感応性物質は、１種を単独で、または必要に応じて任意の比率で２種以上混合して用いることができる。 Examples of the photosensitive substance that the composition of the present invention may contain include a photopolymerization initiator, a photoacid generator, and a photobase generator. As the photosensitive substance, one kind may be used alone, or two or more kinds may be mixed at an arbitrary ratio as required.
光重合開始剤としては、アセトフェノン系化合物、ベンゾイン系化合物、ベンゾフェノン系化合物、チオキサントン系化合物、トリアジン系化合物、オキシムエステル系化合物、ホスフィン系化合物、キノン系化合物、ボレート系化合物； カルバゾール系化合物；イミダゾール系化合物；あるいは、チタノセン系化合物等が用いられる。 Photopolymerization initiators include acetphenone compounds, benzoin compounds, benzophenone compounds, thioxanthone compounds, triazine compounds, oxime ester compounds, phosphine compounds, quinone compounds, borate compounds; carbazole compounds; imidazole compounds. Compound; Alternatively, a titanosen-based compound or the like is used.
光酸発生剤としては、スルホニウム塩、テトラヒドロチオフェニウム塩、 Ｎ−スルホニルオキシイミド化合物などが挙げられる。 Examples of the photoacid generator include a sulfonium salt, a tetrahydrothiophenium salt, an N-sulfonyloxyimide compound and the like.
光重合開始剤および／または光酸発生剤は光硬化性接着剤に含まれる樹脂成分（本発明の飽和脂環式エポキシエステル化合物、および、必要に応じて含まれる他の活性エネルギー重合性化合物から構成される樹脂成分）１００部に対して、０．０１部〜２０部であることが好ましい。０．０１部未満であると硬化が不十分であり、２０部より多い場合、光酸発生剤由来の着色や他の諸物性の低下を招く。 The photopolymerization initiator and / or photoacid generator is derived from the resin component (saturated alicyclic epoxy ester compound of the present invention and other active energy polymerizable compounds contained as necessary) contained in the photocurable adhesive. It is preferably 0.01 to 20 parts with respect to 100 parts of the constituent resin component). If it is less than 0.01 part, the curing is insufficient, and if it is more than 20 parts, coloring derived from the photoacid generator and deterioration of other physical properties are caused.
光塩基発生剤としては、複素環基含有光塩基発生剤、２−ニトロベンジルシクロヘキシルカルバメート、［［（２，６−ジニトロベンジル）オキシ］カルボニル］シクロヘキシルアミン、ビス［［（２−ニトロベンジル）オキシ］カルボニル］ヘキサン−１，６−ジアミン、トリフェニルメタノール、ｏ−カルバモイルヒドロキシルアミド、ｏ−カルバモイルオキシム、ヘキサアンミンコバルト（ＩＩＩ）トリス（トリフェニルメチルボレート）などが挙げられる。 Examples of the photobase generator include a heterocyclic group-containing photobase generator, 2-nitrobenzylcyclohexylcarbamate, [[(2,6-dinitrobenzyl) oxy] carbonyl] cyclohexylamine, and bis [[(2-nitrobenzyl) oxy. ] Carbonyl] Hexan-1,6-diamine, triphenylmethanol, o-carbamoylhydroxylamide, o-carbamoyloxime, hexaammine cobalt (III) tris (triphenylmethylborate) and the like.
さらに、本発明の組成物には、増感剤を含有させることができる。１種を単独で、または必要に応じて任意の比率で２種以上混合して用いることができる。 Further, the composition of the present invention may contain a sensitizer. One type can be used alone, or two or more types can be mixed at any ratio as required.
＜色変換層＞
本発明の色変換層は、画像表示装置に用いられ、第１の面から紫外可視光を照射した場合に第２面から観測される波長５００〜８００ｎｍの間の発光強度の最大値（Ｐ１）と第２の面から紫外可視光を照射した場合に第１の面から観測される波長５００〜８００ｎｍの間の発光強度の最大値（Ｐ２）が下記式（１）を充足することを特徴とする色変換層である。
式（１）
Ｐ１/Ｐ２≧１．５
なお、色変換層の２面のうち、第１の面と第２面とは、Ｐ１とＰ２がＰ１＞Ｐ２の関係を満たすように定める。
<Color conversion layer>
The color conversion layer of the present invention is used in an image display device, and is the maximum value of emission intensity between the wavelengths of 500 to 800 nm observed from the second surface when ultraviolet-visible light is irradiated from the first surface (P1). When ultraviolet-visible light is irradiated from the second surface, the maximum value (P2) of the emission intensity between the wavelengths of 500 to 800 nm observed from the first surface satisfies the following equation (1). It is a color conversion layer.
Equation (1)
P1 / P2 ≧ 1.5
Of the two surfaces of the color conversion layer, the first surface and the second surface are defined so that P1 and P2 satisfy the relationship of P1> P2.
本発明における色変換は照射した紫外可視光を透過させずに、量子ドットが発した蛍光を透過させることである。効率の良い色変換とは、同一の紫外可視光を用いた時に、変換された光の強度が高いことを示す。
たとえば、４３０nm〜４９０nmの紫外可視光を照射して、５２０〜５６０nm蛍光を透過させれば、青色光を緑色光に変換することができる。また、３６０nm〜４００nmの紫外可視光を照射して、５９０〜７００nmの蛍光を透過させれば、紫外光を赤色光に変換することが可能となる。
The color conversion in the present invention is to transmit the fluorescence emitted by the quantum dots without transmitting the irradiated ultraviolet-visible light. Efficient color conversion means that the intensity of the converted light is high when the same ultraviolet-visible light is used.
For example, blue light can be converted to green light by irradiating ultraviolet-visible light of 430 nm to 490 nm and transmitting fluorescence of 520 to 560 nm. Further, by irradiating ultraviolet visible light of 360 nm to 400 nm and transmitting fluorescence of 590 to 700 nm, it is possible to convert ultraviolet light into red light.
本発明の色変換層の作成は、図２の第１の色変換層（Ａ１）と第２の色変換層（Ａ２）に例示するように、量子ドットと有機色素が異なる比率で含有されている塗料やインキを積層し、図２の（Ａ）に例示する色変換層を形成する方法や、１液の量子ドットと有機色素を含む塗料やインキを塗布乾燥する工程中に、膜厚方向に量子ドットと有機色素の濃度勾配を生じた単層を作成し、図１の（Ａ）に例示する色変換層を形成する方法などを用いることができる。
単層を作成する場合に、層内での量子ドットと有機色素の濃度勾配を生じさせる方法としては、上述のように、量子ドットのリガントにフルオロアルキル基やシロキサン基を用いることで、量子ドットを表面に偏在させる方法や、有機色素の分散剤にフルオロアルキル基やシロキサン基を用いることで有機色素を表面に偏在させる方法が挙げられる。
なお、色変換層が複数の層を有する場合には、積層した色変換層の２つの最外面のうち、一方を第１の面、もう一方を第２の面とする。第１の面と、第２の面との決め方は、上述のとおりである。
In the production of the color conversion layer of the present invention, as illustrated in the first color conversion layer (A1) and the second color conversion layer (A2) of FIG. 2, quantum dots and organic dyes are contained in different ratios. During the method of laminating the existing paints and inks to form the color conversion layer illustrated in (A) of FIG. 2 and the process of applying and drying the paint or ink containing one liquid quantum dot and an organic dye, the film thickness direction. A method of forming a single layer having a density gradient of quantum dots and an organic dye and forming a color conversion layer illustrated in FIG. 1 (A) can be used.
When creating a single layer, as a method of generating a concentration gradient of quantum dots and organic dyes in the layer, as described above, a fluoroalkyl group or a siloxane group is used for the liganto of the quantum dots, so that the quantum dots are formed. Examples include a method of unevenly distributing the organic dye on the surface and a method of unevenly distributing the organic dye on the surface by using a fluoroalkyl group or a siloxane group as a dispersant for the organic dye.
When the color conversion layer has a plurality of layers, one of the two outermost surfaces of the laminated color conversion layers is the first surface and the other is the second surface. The method of determining the first surface and the second surface is as described above.
＜色変換フィルム＞
本発明の色変換フィルムは、透明基材と、上述の色変換層とを有することを特徴とする。
透明基板としては、ソーダ石灰ガラス、低アルカリ硼珪酸ガラス、無アルカリアルミノ硼珪酸ガラスなどのガラス板や、ポリカーボネート、ポリメタクリル酸メチル、ポリエチレンテレフタレートなどの樹脂板が用いられる。
<Color conversion film>
The color conversion film of the present invention is characterized by having a transparent base material and the above-mentioned color conversion layer.
As the transparent substrate, a glass plate such as soda-lime glass, low-alkali borosilicate glass, or non-alkali aluminum borosilicate glass, or a resin plate such as polycarbonate, polymethylmethacrylate, or polyethylene terephthalate is used.
また、適宜、色変換層をパターニングすることでき、パターニングの方法としては、印刷法又はフォトリソグラフィー法により、製造することができる。 Further, the color conversion layer can be patterned as appropriate, and the patterning method can be produced by a printing method or a photolithography method.
印刷法による色変換層の形成は、印刷と乾燥を繰り返すだけでパターン化ができるため、低コストであり、かつ量産性に優れている。さらに、印刷技術の発展により高い寸法精度及び平滑度を有する微細パターンの印刷を行うことができる。印刷を行うためには、印刷の版上、インクジェットヘッド、あるいはブランケット上にてインキが乾燥、固化しないようなインキとすることが好ましい。また、印刷機上やインキジェットヘッドでのインキの流動性制御も重要であり、分散剤や溶剤によってインキ粘度の調整も行うことができる。
フォトリソグラフィー法によりフィルタセグメントを形成する場合は、上記溶剤現像型あるいはアルカリ現像型着色レジスト材として調製し、透明基板上に、スプレーコートやスピンコート、スリットコート、ロールコート等の塗布方法により、乾燥膜厚が０．２〜５μｍとなるように塗布する。必要により乾燥された膜には、この膜と接触あるいは非接触状態で設けられた所定のパターンを有するマスクを通して紫外線露光を行う。その後、溶剤又はアルカリ現像液に浸漬するか若しくはスプレーなどにより現像液を噴霧して未硬化部を除去して所望のパターンを製造することができる。さらに、レジスト材の重合を促進するため、必要に応じて加熱を施すこともできる。フォトリソグラフィー法によれば、上記印刷法より精度の高い色変換層が製造できる。
The formation of the color conversion layer by the printing method is low in cost and excellent in mass productivity because it can be patterned only by repeating printing and drying. Further, with the development of printing technology, it is possible to print a fine pattern having high dimensional accuracy and smoothness. In order to perform printing, it is preferable to use ink that does not dry or solidify on the printing plate, inkjet head, or blanket. It is also important to control the fluidity of the ink on the printing machine or on the ink jet head, and the ink viscosity can be adjusted with a dispersant or a solvent.
When the filter segment is formed by the photolithography method, it is prepared as the above-mentioned solvent-developed or alkali-developed colored resist material, and dried on a transparent substrate by a coating method such as spray coating, spin coating, slit coating, or roll coating. Apply so that the film thickness is 0.2 to 5 μm. If necessary, the dried film is exposed to ultraviolet rays through a mask having a predetermined pattern provided in contact with or without contact with the film. After that, a desired pattern can be produced by immersing in a solvent or an alkaline developer or spraying the developer with a spray or the like to remove the uncured portion. Further, in order to promote the polymerization of the resist material, heating can be applied as needed. According to the photolithography method, a color conversion layer having higher accuracy than the above printing method can be manufactured.
現像に際しては、アルカリ現像液として炭酸ナトリウム、水酸化ナトリウム等の水溶液が使用され、ジメチルベンジルアミン、トリエタノールアミン等の有機アルカリを用いることもできる。また、現像液には、消泡剤や界面活性剤を添加することもできる。なお、紫外線露光感度を上げるために、上記着色レジスト材を塗布乾燥後、水溶性あるいはアルカリ水溶性樹脂、例えばポリビニルアルコールや水溶性アクリル樹脂等を塗布乾燥し酸素による重合阻害を防止する膜を形成した後、紫外線露光を行うこともできる。 At the time of development, an aqueous solution of sodium carbonate, sodium hydroxide or the like is used as the alkaline developer, and an organic alkali such as dimethylbenzylamine or triethanolamine can also be used. Further, an antifoaming agent or a surfactant can be added to the developing solution. In order to increase the UV exposure sensitivity, the colored resist material is applied and dried, and then a water-soluble or alkaline water-soluble resin such as polyvinyl alcohol or a water-soluble acrylic resin is applied and dried to form a film that prevents polymerization inhibition by oxygen. After that, ultraviolet exposure can be performed.
本発明の色変換層は、上記方法の他に電着法、転写法などにより製造することができる。なお、電着法は、基板上に形成した透明導電膜を利用して、コロイド粒子の電気泳動により各色フィルタセグメントを透明導電膜の上に電着形成することで色変換層を製造する方法である。また、転写法は剥離性の転写ベースシートの表面に、あらかじめ色変換層を形成しておき、このフィルタセグメントを所望の基板に転写させる方法である。 The color conversion layer of the present invention can be produced by an electrodeposition method, a transfer method, or the like in addition to the above method. The electrodeposition method is a method of producing a color conversion layer by electrodepositing each color filter segment on the transparent conductive film by electrophoresis of colloidal particles using the transparent conductive film formed on the substrate. be. Further, the transfer method is a method in which a color conversion layer is formed in advance on the surface of a peelable transfer base sheet, and this filter segment is transferred to a desired substrate.
＜遮蔽性の隔壁＞
本発明の色変換フィルムは、パターンニングされた色変換層が、遮光性の隔壁で区切られていること態様も可能である。
<Shielding partition>
The color conversion film of the present invention can also have an embodiment in which the patterned color conversion layer is separated by a light-shielding partition wall.
本発明における遮光性とは、紫外可視光における厚み１μｍあたり光学密度ＯＤ値が２以上の遮蔽性である。２以上であれば、十分な遮蔽性が得ることができる。 The light-shielding property in the present invention is a light-shielding property having an optical density OD value of 2 or more per 1 μm of thickness in ultraviolet-visible light. If it is 2 or more, sufficient shielding property can be obtained.
本発明における遮蔽性の隔壁には、ブラックマトリックスを用いることができる。ブラックマトリックスは、例えば、クロムやクロム／酸化クロムの多層膜、窒化チタニウムなどの無機膜や、遮光剤を分散した樹脂膜が用いられるが、これらに限定されない。 A black matrix can be used for the shielding partition wall in the present invention. As the black matrix, for example, a multilayer film of chromium or chromium / chromium oxide, an inorganic film such as titanium nitride, or a resin film in which a light-shielding agent is dispersed is used, but the black matrix is not limited thereto.
ラジカル重合型のブラックレジストを塗布し、露光、そして現像してパターニングするフォトリソグラフィー法、黒色インクを印刷する印刷法、又は無機膜を用いるエッチング法等により基板上に形成することができる。 It can be formed on a substrate by a photolithography method in which a radical polymerization type black resist is applied, exposed, developed and patterned, a printing method in which black ink is printed, an etching method using an inorganic film, or the like.
＜画像表示装置＞
本発明の画像表示装置は、本発明の色変換フィルタと、バックライト光源とを具備し、
バックライト光源側に前記色変換層の第１の面が配置され、画像表示側に前記色変換層の第２の面が配置されていることを特徴とする。
<Image display device>
The image display device of the present invention includes the color conversion filter of the present invention and a backlight light source.
The first surface of the color conversion layer is arranged on the backlight light source side, and the second surface of the color conversion layer is arranged on the image display side.
本発明のバックライト光源は、図形、文字、数字、もしくは画像を表示する入力信号をサブピクセルごとの光強度に変換し、変換された強度の光を得られるようにサブピクセル毎に光強度を調整されていてもよい。サブピクセル毎の光強度の調整には、液晶パネルを用いる方法、有機ＥＬやマイクロＬＥＤなど自発光と呼ばれるサブピクセルやピクセル毎に光強度を指定できるデバイスと組み合わせる方法を用いることができる。また、バックライトは一様に光を発し、本発明の色変換層で色変換した光を液晶パネル等でサブピクセル毎の光強度に調節するように表示装置に組み込み使用することもできる。 The backlight source of the present invention converts an input signal for displaying a figure, a character, a number, or an image into a light intensity for each subpixel, and converts the light intensity for each subpixel so that light of the converted intensity can be obtained. It may be adjusted. To adjust the light intensity for each sub-pixel, a method using a liquid crystal panel or a method of combining with a device such as an organic EL or a micro LED that can specify the light intensity for each sub-pixel or pixel, which is called self-luminous, can be used. Further, the backlight emits light uniformly, and the light color-converted by the color conversion layer of the present invention can be incorporated into a display device and used so as to adjust the light intensity for each sub-pixel with a liquid crystal panel or the like.
バックライト光源側に前記色変換層の第１の面が配置され、画像表示側に前記色変換層の第２の面が配置されていることで、バックライトの光が所望の色相の光に効率よく変換できるため色再現性が良く、エネルギー効率が良い画像表示装置の提供が可能となる。 By arranging the first surface of the color conversion layer on the backlight light source side and arranging the second surface of the color conversion layer on the image display side, the light of the backlight becomes light of a desired hue. Since it can be converted efficiently, it is possible to provide an image display device having good color reproducibility and energy efficiency.
以下に、本発明を実施例に基づいて説明するが、本発明はこれによって限定されるものではない。なお、特にことわりがない限り、「部」とは「質量部」を意味する。 Hereinafter, the present invention will be described based on examples, but the present invention is not limited thereto. Unless otherwise specified, "part" means "part by mass".
＜バインダー樹脂溶液１の調製＞
ノルボルネン２００部、シクロペンテン５０部、１−ヘキセン１８０部およびトルエン７５０部を、窒素置換した反応容器に仕込み、６０℃に加熱した。これに、トリエチルアルミニウム（１．５モル／ｌ）のトルエン溶液０．６２部、ｔｅｒｔ−Ｃ４Ｈ５ＯＨ／ＣＨ３ＯＨで変性（ｔｅｒｔ−Ｃ４Ｈ９ＯＨ／ＣＨ３ＯＨ／Ｗ＝０．３５／０．３／１；モル比）したＷＣｌ６溶液（濃度０．０５モル／ｌ）３．７部を加え、８０℃で３時間加熱攪拌して、開環重合反応、水素添加反応を行い、次いでトリメチルベンゼンを用いてNVを2０％に調製してバインダー樹脂溶液１を得た。
<Preparation of binder resin solution 1>
200 parts of norbornene, 50 parts of cyclopentene, 180 parts of 1-hexene and 750 parts of toluene were placed in a nitrogen-substituted reaction vessel and heated to 60 ° C. This was modified with 0.62 parts of a toluene solution of triethylaluminum (1.5 mol / l) and tert-C 4 H 5 OH / CH 3 OH (tert-C 4 H 9 OH / CH 3 OH / W = 0). Add 3.7 parts of WCl 6 solution (concentration: 0.05 mol / l) (.35 / 0.3 / 1; molar ratio), heat and stir at 80 ° C. for 3 hours, and perform ring-opening polymerization reaction and hydrogenation reaction. Then, NV was adjusted to 20% using trimethylbenzene to obtain a binder resin solution 1.
＜バインダー樹脂溶液２の調製＞
セパラブル４口フラスコに温度計、冷却管、窒素ガス導入管、撹拌装置を取り付けた反応容器にトリメチルベンゼン７０．０部を仕込み、８０℃に昇温し、反応容器内を窒素置換した後、滴下管よりｎ−ブチルメタクリレート１４．０部、メタクリル酸メチル１０．０部、スチレン６．０部、２，２’−アゾビスイソブチロニトリル０．４部の混合物を２時間かけて滴下した。滴下終了後、更に３時間反応を継続し、重量平均分子量（Ｍｗ）２６０００のアクリル樹脂の溶液を得た。室温まで冷却した後、樹脂溶液約２ｇをサンプリングして１８０℃、２０分加熱乾燥して不揮発分を測定し、先に合成した樹脂溶液に不揮発分が２０重量％になるようにトリメチルベンゼンを添加してバインダー樹脂溶液２を調製した。
<Preparation of binder resin solution 2>
70.0 parts of trimethylbenzene was placed in a reaction vessel equipped with a thermometer, a cooling pipe, a nitrogen gas introduction pipe, and a stirrer in a separable 4-neck flask, the temperature was raised to 80 ° C., the inside of the reaction vessel was replaced with nitrogen, and then dropped. A mixture of 14.0 parts of n-butyl methacrylate, 10.0 parts of methyl methacrylate, 6.0 parts of styrene, and 0.4 parts of 2,2′-azobisisobutyronitrile was added dropwise from the tube over 2 hours. After completion of the dropping, the reaction was continued for another 3 hours to obtain a solution of an acrylic resin having a weight average molecular weight (Mw) of 26000. After cooling to room temperature, about 2 g of the resin solution was sampled and dried by heating at 180 ° C. for 20 minutes to measure the non-volatile content, and trimethylbenzene was added to the previously synthesized resin solution so that the non-volatile content was 20% by weight. The binder resin solution 2 was prepared.
＜ブラックマトリックス基板の作成＞
（カーボンブラック分散体の作製）
下記の混合物を均一になるように攪拌混合した後、直径１ｍｍのジルコニアビーズを用いて、アイガーミル（アイガージャパン社製「ミニモデルＭ−２５０ ＭＫＩＩ」）で５時間分散した。その後プロピレングリコールモノメチルエーテルアセテートを３０．０部加えた後、５μｍのフィルタで濾過し、カーボンブラック分散体を得た。
カーボンブラック ：１２．６部
ＣＡＢＯＴ社製「Ｒｅｇａｌ２５０Ｒ」
色素誘導体（下記の式（２）で表される化合物） ： １．４部
樹脂溶液１ ：３０．０部
プロピレングリコールモノメチルエーテルアセテート ：２６．０部
<Creation of black matrix substrate>
(Preparation of carbon black dispersion)
The following mixture was stirred and mixed so as to be uniform, and then dispersed with an Eiger mill (“Mini Model M-250 MKII” manufactured by Eiger Japan Co., Ltd.) for 5 hours using zirconia beads having a diameter of 1 mm. Then, 30.0 parts of propylene glycol monomethyl ether acetate was added, and the mixture was filtered through a 5 μm filter to obtain a carbon black dispersion.
Carbon black: 12.6 copies "Regal250R" manufactured by CABOT
Dye derivative (compound represented by the following formula (2)): 1.4 parts Resin solution 1: 30.0 parts Propylene glycol monomethyl ether acetate: 26.0 parts
式（２）
（カーボンブラックレジストの調整）
カーボンブラック分散体を６０部、トリメチロールプロパントリアクリレート(新中村化学社製「NKエステルATMPT」)４．３部、光重合開始剤２−ベンジル−２−ジメチルアミノ−１−（４−モルフォリノフェニル）−ブタノン−１(チバガイギー社製「イルガキュア369」)２部、増感剤(保土ヶ谷化学社製「EAB-F」)０．４部、及びシクロヘキサノン２１．６部、撥液剤である含フッ素オリゴマー（ダイキン化学工業製商品名：オプツールDAC）０．９部の混合物を均一に攪拌混合した後、１μｍのフィルターで濾過して感光性黒色組成物を調製した。
(Adjustment of carbon black resist)
60 parts of carbon black dispersion, 4.3 parts of trimethylol propantriacrylate (“NK ester ATMPT” manufactured by Shin-Nakamura Chemical Co., Ltd.), photopolymerization initiator 2-benzyl-2-dimethylamino-1- (4-morpholino) Phenyl) -butanon-1 ("Irgacure 369" manufactured by Ciba Geigy), 0.4 parts of sensitizer ("EAB-F" manufactured by Hodogaya Chemical Co., Ltd.), 21.6 parts of cyclohexanone, and fluorine-containing liquid repellent. A mixture of 0.9 parts of an oligomer (trade name: Optool DAC manufactured by Daikin Chemical Industry Co., Ltd.) was uniformly stirred and mixed, and then filtered through a 1 μm filter to prepare a photosensitive black composition.
（ブラックマトリックス基板作成）
感光性黒色組成物をスピンコート法により１０ｃｍ×１０ｃｍのガラス基板に塗工した後、７０℃で１５分の乾燥により乾燥膜厚３．３μｍの塗膜を作成した。その後、超高圧水銀ランプを用い、フォトマスクを介して紫外線を２００ｍＪ／ｃｍ２露光した。次いで、炭酸ナトリウム水溶液を用いて未露光部をスプレー現像した後、イオン交換水で洗浄し未露光部を取り除き、２３０℃、３０分のポストベークを行い作成した。得られたブラックマトリックス基板はおよそ縦１００μｍ、横３００μｍの開口部を有していた。ブラックマトリックスの厚みはおよそ２μｍであった。
(Making a black matrix board)
The photosensitive black composition was applied to a glass substrate of 10 cm × 10 cm by a spin coating method, and then dried at 70 ° C. for 15 minutes to prepare a coating film having a dry film thickness of 3.3 μm. Then, using an ultra-high pressure mercury lamp, ultraviolet rays were exposed to 200 mJ / cm2 through a photomask. Next, the unexposed portion was spray-developed with an aqueous sodium carbonate solution, washed with ion-exchanged water to remove the unexposed portion, and post-baked at 230 ° C. for 30 minutes to prepare the product. The obtained black matrix substrate had an opening of about 100 μm in length and 300 μm in width. The thickness of the black matrix was about 2 μm.
＜分散樹脂溶液１の調製＞
ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器に、メチルメタクリレート５００部、チオグリセロール２２部と、プロピレングリコールモノメチルエーテルアセテート５１１部を仕込み、窒素ガスで置換した。反応容器内を９０℃に加熱して、ＡＩＢＮ ０．５０部を添加した後７時間反応した。不揮発分測定により９５％が反応したことを確認後、室温まで冷却して、重量平均分子量５２００の、片末端領域に２つの遊離ヒドロキシル基を有するビニル重合体の不揮発分５０％溶液を得た。ついでイソホロンジイソシアネート ９０．４部と、プロピレングリコールモノメチルエーテルアセテート４５．１部と、触媒としてジブチル錫ジラウレート０．１１部を仕込み、窒素ガスで置換した。反応容器内を１００℃に加熱して、３時間反応した後、４０℃まで冷却し、イソシアネート基を有するプレポリマー溶液を得た。ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器２にメチルイミノビスプロピルアミン２２．２部、ジブチルアミン １３．２部、プロピレングリコールモノメチルエーテルアセテート３０４．６部を仕込み１００℃に加熱した。そこへ前記プレポリマー溶液を３０分かけて滴下し、さらに１時間反応した後、室温まで冷却して反応を終了した。ここへプロピレングリコールモノメチルエーテルアセテートを追加して不揮発分を２０％に調整し、櫛型の分散樹脂溶液１を得た。
<Preparation of dispersion resin solution 1>
A reaction vessel equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer was charged with 500 parts of methyl methacrylate, 22 parts of thioglycerol, and 511 parts of propylene glycol monomethyl ether acetate, and replaced with nitrogen gas. The inside of the reaction vessel was heated to 90 ° C., 0.50 part of AIBN was added, and then the reaction was carried out for 7 hours. After confirming that 95% had reacted by measuring the non-volatile content, the mixture was cooled to room temperature to obtain a 50% non-volatile content solution of a vinyl polymer having a weight average molecular weight of 5200 and having two free hydroxyl groups in one terminal region. Then, 90.4 parts of isophorone diisocyanate, 45.1 parts of propylene glycol monomethyl ether acetate, and 0.11 part of dibutyltin dilaurate as a catalyst were charged and replaced with nitrogen gas. The inside of the reaction vessel was heated to 100 ° C., reacted for 3 hours, and then cooled to 40 ° C. to obtain a prepolymer solution having an isocyanate group. 22.2 parts of methyliminobispropylamine, 13.2 parts of dibutylamine, and 304.6 parts of propylene glycol monomethyl ether acetate were charged in a reaction vessel 2 equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, and heated to 100 ° C. .. The prepolymer solution was added dropwise thereto over 30 minutes, and the reaction was further carried out for 1 hour, and then cooled to room temperature to complete the reaction. Propylene glycol monomethyl ether acetate was added thereto to adjust the non-volatile content to 20%, and a comb-shaped dispersed resin solution 1 was obtained.
＜分散樹脂溶液２の調製＞
ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器に、メチルメタクリレート４５０部、メタクリル酸 1H,1H,2H,2H-ノナフルオロヘキシル５０部、チオグリセロール２２部と、プロピレングリコールモノメチルエーテルアセテート５１１部を仕込み、窒素ガスで置換した。反応容器内を９０℃に加熱して、ＡＩＢＮ ０．５０部を添加した後７時間反応した。不揮発分測定により９５％が反応したことを確認後、室温まで冷却して、重量平均分子量５２００の、片末端領域に２つの遊離ヒドロキシル基を有するビニル重合体の不揮発分５０％溶液を得た。ついでイソホロンジイソシアネート ９０．４部と、プロピレングリコールモノメチルエーテルアセテート４５．１部と、触媒としてジブチル錫ジラウレート０．１１部を仕込み、窒素ガスで置換した。反応容器内を１００℃に加熱して、３時間反応した後、４０℃まで冷却し、イソシアネート基を有するプレポリマー溶液を得た。ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器２にメチルイミノビスプロピルアミン２２．２部、ジブチルアミン １３．２部、プロピレングリコールモノメチルエーテルアセテート３０４．６部を仕込み１００℃に加熱した。そこへ前記プレポリマー溶液を３０分かけて滴下し、さらに１時間反応した後、室温まで冷却して反応を終了した。ここへプロピレングリコールモノメチルエーテルアセテートを追加して不揮発分を２０％に調整し、櫛型の分散樹脂溶液２を得た。
<Preparation of dispersion resin solution 2>
In a reaction vessel equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, 450 parts of methyl methacrylate, 50 parts of 1H, 1H, 2H, 2H-nonafluorohexyl methacrylic acid, 22 parts of thioglycerol, and 511 parts of propylene glycol monomethyl ether acetate. The part was charged and replaced with nitrogen gas. The inside of the reaction vessel was heated to 90 ° C., 0.50 part of AIBN was added, and then the reaction was carried out for 7 hours. After confirming that 95% had reacted by measuring the non-volatile content, the mixture was cooled to room temperature to obtain a 50% non-volatile content solution of a vinyl polymer having a weight average molecular weight of 5200 and having two free hydroxyl groups in one terminal region. Then, 90.4 parts of isophorone diisocyanate, 45.1 parts of propylene glycol monomethyl ether acetate, and 0.11 part of dibutyltin dilaurate as a catalyst were charged and replaced with nitrogen gas. The inside of the reaction vessel was heated to 100 ° C., reacted for 3 hours, and then cooled to 40 ° C. to obtain a prepolymer solution having an isocyanate group. 22.2 parts of methyliminobispropylamine, 13.2 parts of dibutylamine, and 304.6 parts of propylene glycol monomethyl ether acetate were charged in a reaction vessel 2 equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, and heated to 100 ° C. .. The prepolymer solution was added dropwise thereto over 30 minutes, and the reaction was further carried out for 1 hour, and then cooled to room temperature to complete the reaction. Propylene glycol monomethyl ether acetate was added thereto to adjust the non-volatile content to 20%, and a comb-shaped dispersed resin solution 2 was obtained.
＜分散樹脂溶液３の調製＞
ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器に、メチルメタクリレート４９０部、化合物（１）１０部、チオグリセロール２２部と、プロピレングリコールモノメチルエーテルアセテート５１１部を仕込み、窒素ガスで置換した。反応容器内を９０℃に加熱して、ＡＩＢＮ ０．５０部を添加した後７時間反応した。不揮発分測定により９５％が反応したことを確認後、室温まで冷却して、重量平均分子量５２００の、片末端領域に２つの遊離ヒドロキシル基を有するビニル重合体の不揮発分５０％溶液を得た。ついでイソホロンジイソシアネート ９０．４部と、プロピレングリコールモノメチルエーテルアセテート４５．１部と、触媒としてジブチル錫ジラウレート０．１１部を仕込み、窒素ガスで置換した。反応容器内を１００℃に加熱して、３時間反応した後、４０℃まで冷却し、イソシアネート基を有するプレポリマー溶液を得た。ガス導入管、温度計、コンデンサー、攪拌機を備えた反応容器２にメチルイミノビスプロピルアミン２２．２部、ジブチルアミン １３．２部、プロピレングリコールモノメチルエーテルアセテート３０４．６部を仕込み１００℃に加熱した。そこへ前記プレポリマー溶液を３０分かけて滴下し、さらに１時間反応した後、室温まで冷却して反応を終了した。ここへプロピレングリコールモノメチルエーテルアセテートを追加して不揮発分を２０％に調整し、櫛型の分散樹脂溶液３を得た。
<Preparation of dispersion resin solution 3>
In a reaction vessel equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, 490 parts of methyl methacrylate, 10 parts of compound (1), 22 parts of thioglycerol, and 511 parts of propylene glycol monomethyl ether acetate were charged and replaced with nitrogen gas. .. The inside of the reaction vessel was heated to 90 ° C., 0.50 part of AIBN was added, and then the reaction was carried out for 7 hours. After confirming that 95% had reacted by measuring the non-volatile content, the mixture was cooled to room temperature to obtain a 50% non-volatile content solution of a vinyl polymer having a weight average molecular weight of 5200 and having two free hydroxyl groups in one terminal region. Then, 90.4 parts of isophorone diisocyanate, 45.1 parts of propylene glycol monomethyl ether acetate, and 0.11 part of dibutyltin dilaurate as a catalyst were charged and replaced with nitrogen gas. The inside of the reaction vessel was heated to 100 ° C., reacted for 3 hours, and then cooled to 40 ° C. to obtain a prepolymer solution having an isocyanate group. 22.2 parts of methyliminobispropylamine, 13.2 parts of dibutylamine, and 304.6 parts of propylene glycol monomethyl ether acetate were charged in a reaction vessel 2 equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, and heated to 100 ° C. .. The prepolymer solution was added dropwise thereto over 30 minutes, and the reaction was further carried out for 1 hour, and then cooled to room temperature to complete the reaction. Propylene glycol monomethyl ether acetate was added thereto to adjust the non-volatile content to 20%, and a comb-shaped dispersed resin solution 3 was obtained.
化合物（１）
＜黄色色素分散体１の調製＞
イルガフォア・イエロー2R−CF（Irgaphor Yellow 2R-CF） １０部
分散樹脂溶液１ ５０部
バインダー樹脂溶液１ ２００部
プロピレングリコールモノメチルエーテルアセテート ２０部
を均一に撹拌混合し、直径１ｍｍのガラスビーズを用いて、サンドミルで８時間分散した後、１μｍのフィルタで濾過し、黄色色素分散体１を調製した。
<Preparation of yellow pigment dispersion 1>
Irgaphor Yellow 2R-CF (Irgaphor Yellow 2R-CF) 10 parts dispersion resin solution 1 50 parts binder resin solution 1 200 parts propylene glycol monomethyl ether acetate 20 parts are uniformly stirred and mixed, and glass beads having a diameter of 1 mm are used. After dispersing for 8 hours in a sand mill, the mixture was filtered through a 1 μm filter to prepare a yellow dye dispersion 1.
＜黄色顔料分散体２の調製＞
イルガフォア・イエロー2R−CF（Irgaphor Yellow 2R-CF） １０部
分散樹脂溶液２ ５０部
バインダー樹脂溶液１ ２５０部
プロピレングリコールモノメチルエーテルアセテート ２０部
を均一に撹拌混合し、直径１ｍｍのガラスビーズを用いて、サンドミルで８時間分散した後、１μｍのフィルタで濾過し、黄色色素分散体２を調製した。
<Preparation of yellow pigment dispersion 2>
Irgaphor Yellow 2R-CF (Irgaphor Yellow 2R-CF) 10 parts Dispersed resin solution 2 50 parts Binder resin solution 1 250 parts propylene glycol monomethyl ether acetate 20 parts are uniformly stirred and mixed, and glass beads having a diameter of 1 mm are used. After dispersing for 8 hours in a sand mill, the mixture was filtered through a 1 μm filter to prepare a yellow dye dispersion 2.
＜黄色顔料分散体３の調製＞
イルガフォア・イエロー2R−CF（Irgaphor Yellow 2R-CF） １０部
分散樹脂溶液３ ５０部
バインダー樹脂溶液１ ２５０部
プロピレングリコールモノメチルエーテルアセテート ２０部
を均一に撹拌混合し、直径１ｍｍのガラスビーズを用いて、サンドミルで８時間分散した後、１μｍのフィルタで濾過し、黄色色素分散体３を調製した。
<Preparation of yellow pigment dispersion 3>
Irgaphor Yellow 2R-CF (Irgaphor Yellow 2R-CF) 10 parts Dispersed resin solution 3 50 parts Binder resin solution 1 250 parts propylene glycol monomethyl ether acetate 20 parts are uniformly stirred and mixed, and glass beads having a diameter of 1 mm are used. After dispersing for 8 hours in a sand mill, the mixture was filtered through a 1 μm filter to prepare a yellow dye dispersion 3.
＜散乱ビーズ分散体の調製＞
シリカビーズ ＫＥ-Ｐ Ｐ２５０（日本触媒社製） １０部
分散樹脂溶液１ ５０部
バインダー樹脂溶液１ ２５０部
プロピレングリコールモノメチルエーテルアセテート ２０部
を均一に撹拌混合し、直径１ｍｍのガラスビーズを用いて、サンドミルで８時間分散した後、１μｍのフィルタで濾過し、散乱ビーズ分散体を調製した。
<Preparation of scattered bead dispersion>
Silica beads KE-P P250 (manufactured by Nippon Katsura Co., Ltd.) 10 parts Dispersed resin solution 1 50 parts Binder resin solution 1 250 parts propylene glycol monomethyl ether acetate 20 parts are uniformly stirred and mixed, and a sand mill is used using glass beads having a diameter of 1 mm. After dispersion for 8 hours, the mixture was filtered through a 1 μm filter to prepare a scattered bead dispersion.
＜量子ドット ＱＤ−Ｇ１の合成＞
無水酢酸亜鉛０．５５部、ドデカンチオール７．０部、オレイルアミン５．０部を加熱溶解し添加液を作成した。
<Synthesis of quantum dot QD-G1>
0.55 parts of acetic anhydride, 7.0 parts of dodecanethiol, and 5.0 parts of oleylamine were dissolved by heating to prepare an additive solution.
塩化インジウム０．２２部、オクチルアミン８．２５部を反応容器に入れ、窒素バブリングを行いながら、１６５℃に加熱した。塩化インジウムが溶解した後、ジエチルアミノホスフィン０．８６部を短時間で注入し、２０分間１７０℃に制御した。その後、急冷し、４０℃に冷却した。上記添加液を注入し、２４０℃２時間加熱した後に、室温まで放冷した。放冷後、ヘキサンとエタノールを用いて再沈殿法で精製を行った。トリメチルベンゼンを用いて、固形分濃度２．９％に調製し、量子ドットＱＤ−Ｇ１の分散液を得た。 0.22 parts of indium chloride and 8.25 parts of octylamine were placed in a reaction vessel and heated to 165 ° C. while performing nitrogen bubbling. After the indium chloride was dissolved, 0.86 part of diethylaminophosphine was injected in a short time and controlled at 170 ° C. for 20 minutes. Then, it was rapidly cooled and cooled to 40 ° C. The above additive solution was injected, heated at 240 ° C. for 2 hours, and then allowed to cool to room temperature. After allowing to cool, purification was carried out by a reprecipitation method using hexane and ethanol. Using trimethylbenzene, the solid content concentration was adjusted to 2.9% to obtain a dispersion of quantum dots QD-G1.
＜量子ドット ＱＤ−Ｒ１の合成＞
量子ドット ＱＤ−Ｇ１の合成において、１７０℃を２２０℃に変更したことを除き同様に処理して、量子ドットＱＤ−Ｒ１の分散液を得た。
<Synthesis of quantum dot QD-R1>
In the synthesis of the quantum dot QD-G1, the same treatment was carried out except that 170 ° C. was changed to 220 ° C. to obtain a dispersion liquid of the quantum dot QD-R1.
＜量子ドット ＱＤ−Ｇ２の合成＞
量子ドットＱＤ-Ｇ１を、トルエンを用いて固形分濃度１％に希釈した。２−（２−メトキシエトキシ）エタンチオールの５％トルエン溶液を添加し、１２時間撹拌した。トルエンとエタノールを用いて再沈殿法で精製を行った。プロピレングリコールモノエチルエーテルアセテートを用いて、固形分濃度２．９％に調製し、２−（２−メトキシエトキシ）エタンチオールで表面処理された量子ドットＱＤ−Ｇ２の分散液を得た。
<Synthesis of quantum dot QD-G2>
Quantum dot QD-G1 was diluted with toluene to a solid content concentration of 1%. A 5% toluene solution of 2- (2-methoxyethoxy) ethanethiol was added and stirred for 12 hours. Purification was carried out by the reprecipitation method using toluene and ethanol. A dispersion of quantum dots QD-G2 prepared to a solid content concentration of 2.9% using propylene glycol monoethyl ether acetate and surface-treated with 2- (2-methoxyethoxy) ethanethiol was obtained.
＜量子ドット ＱＤ−Ｒ２の合成＞
量子ドットＱＤ-Ｇ２の調製において、量子ドットＱＤ-Ｇ１を量子ドットＱＤ−Ｒ１に変更した以外は同様に調整し、２−（２−メトキシエトキシ）エタンチオールで表面処理された量子ドットＱＤ−Ｒ２の分散液を得た。
<Synthesis of quantum dot QD-R2>
In the preparation of the quantum dot QD-G2, the quantum dot QD-G1 was adjusted in the same manner except that the quantum dot QD-G1 was changed to the quantum dot QD-R1, and the quantum dot QD-R2 was surface-treated with 2- (2-methoxyethoxy) ethanethiol. The dispersion liquid of was obtained.
＜量子ドット ＱＤ−Ｇ３の合成＞
ＱＤ−Ｇ２の合成において、２−（２−メトキシエトキシ）エタンチオールの代わりに、2-（ノナフルオロブチル）エチルフェニルフォスホン酸を用いたこと以外はＱＤ-Ｇ２と同様に調製し、量子ドットＱＤ−Ｇ３の分散液を得た。
<Synthesis of quantum dot QD-G3>
In the synthesis of QD-G2, prepared in the same manner as QD-G2 except that 2- (nonafluorobutyl) ethylphenylphosphonic acid was used instead of 2- (2-methoxyethoxy) ethanethiol, and the quantum dots were prepared. A dispersion of QD-G3 was obtained.
＜量子ドット ＱＤ−Ｒ３の合成＞
ＱＤ−Ｒ２の合成において、２−（２−メトキシエトキシ）エタンチオールの代わりに、2-（ノナフルオロブチル）エチルフェニルフォスホン酸を用いたこと以外はＱＤ-Ｒ２と同様に調製し、量子ドットＱＤ−Ｒ３の分散液を得た。
<Synthesis of quantum dot QD-R3>
In the synthesis of QD-R2, prepared in the same manner as QD-R2 except that 2- (nonafluorobutyl) ethylphenylphosphonic acid was used instead of 2- (2-methoxyethoxy) ethanethiol, and the quantum dots were prepared. A dispersion of QD-R3 was obtained.
＜インキの調製＞
表１に示したインキ組成にて、密閉できる容器に、量子ドット溶液、樹脂溶液、溶剤の順番で計量し、その後、密閉して、３分間、振とうしてインクジェットインキを作成した。
<Ink preparation>
With the ink composition shown in Table 1, the quantum dot solution, the resin solution, and the solvent were weighed in this order in a container that could be sealed, and then the ink was sealed and shaken for 3 minutes to prepare an inkjet ink.
表中 PGMAｃ：プロピレングリコールモノエチルエーテルアセテート
In the table PGMAc: Propylene glycol monoethyl ether acetate
＜色変換層の作成方法１＞
［実施例１］色変換層ＣＲ１の作成
黄色顔料の比率が高くＱＤ濃度が低いインキＩＲ３を、無アルカリガラスにスピンコーターを用いて、乾燥後膜厚が１μｍになるように塗布、乾燥した。次いで、インキＩＲ３を塗布した上に、黄色顔料の比率が低くＱＤ濃度が高いインキＩＲ２を乾燥後の合計膜厚が２μｍになるように、スピンコーターを用いて塗布、乾燥して、ガラス基板上に、色変換層ＣＲ１を形成した。この色変換層はガラス基板側のＱＤ濃度が低く、２番目のインキの乾燥面側のQD濃度が高い。乾燥は６０℃５分の間、熱風乾燥機に入れて行った。
<How to create a color conversion layer 1>
[Example 1] Preparation of color conversion layer CR1 Ink IR3 having a high proportion of yellow pigment and a low QD concentration was applied to non-alkali glass using a spin coater so that the film thickness would be 1 μm after drying, and dried. Next, the ink IR3 is applied, and then the ink IR2 having a low yellow pigment ratio and a high QD concentration is applied and dried using a spin coater so that the total film thickness after drying is 2 μm, and then the ink IR2 is applied onto a glass substrate. The color conversion layer CR1 was formed on the surface. This color conversion layer has a low QD density on the glass substrate side and a high QD density on the dry surface side of the second ink. Drying was carried out in a hot air dryer for 5 minutes at 60 ° C.
［実施例２］色変換層ＣＧ１の作成
黄色顔料の比率が高くＱＤ濃度が低いインキＩＧ３を、無アルカリガラスにスピンコーターを用いて、乾燥後膜厚が１μｍになるように塗布、乾燥した。次いで、インキＩＧ３を塗布した上に、黄色顔料の比率が低くＱＤ濃度が高いインキＩＲ２を乾燥後の合計膜厚が２μｍになるように、スピンコーターを用いて塗布、乾燥して、ガラス基板上に、色変換層ＣＧ１を形成した。この色変換層はガラス基板側のＱＤ濃度が低く、２番目のインキの乾燥面側のQD濃度が高い。乾燥は６０℃５分の間、熱風乾燥機に入れて行った。
[Example 2] Preparation of color conversion layer CG1 Ink IG3, which has a high proportion of yellow pigment and a low QD concentration, was applied to non-alkali glass using a spin coater so that the film thickness would be 1 μm after drying, and dried. Next, on the ink IG3, the ink IR2 having a low yellow pigment ratio and a high QD concentration is applied and dried using a spin coater so that the total film thickness after drying is 2 μm, and then the ink IR2 is applied onto a glass substrate. The color conversion layer CG1 was formed on the surface. This color conversion layer has a low QD density on the glass substrate side and a high QD density on the dry surface side of the second ink. Drying was carried out in a hot air dryer for 5 minutes at 60 ° C.
［比較例１］
インキＩＧ１を、無アルカリガラスにスピンコーターを用いて、乾燥後膜厚が２μｍになるように塗布、乾燥し、濃度勾配のない色変換層ＣＲ５をガラス基板上に作成した。乾燥は６０℃５分の間、熱風乾燥機に入れて行った。
[Comparative Example 1]
Ink IG1 was applied to non-alkali glass using a spin coater so that the film thickness would be 2 μm after drying, and dried to prepare a color conversion layer CR5 having no density gradient on a glass substrate. Drying was carried out in a hot air dryer for 5 minutes at 60 ° C.
［比較例２］
インキＩＧ１を、無アルカリガラスにスピンコーターを用いて、乾燥後膜厚が２μｍになるように塗布、乾燥し、濃度勾配のない色変換層、色変換層ＣＧ８をガラス基板上に作成した。乾燥は６０℃５分の間、熱風乾燥機に入れて行った。
[Comparative Example 2]
Ink IG1 was applied to non-alkali glass using a spin coater so that the film thickness would be 2 μm after drying, and dried to prepare a color conversion layer and a color conversion layer CG8 having no density gradient on a glass substrate. Drying was carried out in a hot air dryer for 5 minutes at 60 ° C.
［比較例３］
インキＩＲ７を、無アルカリガラスにスピンコーターを用いて、乾燥後膜厚が２μｍになるように塗布、乾燥し、濃度勾配のない色変換層、色変換層ＣＲ６をガラス基板上に作成した。乾燥は６０℃５分の間、熱風乾燥機に入れて行った。
[Comparative Example 3]
Ink IR7 was applied to non-alkali glass using a spin coater so that the film thickness would be 2 μm after drying, and dried to prepare a color conversion layer and a color conversion layer CR6 having no density gradient on a glass substrate. Drying was carried out in a hot air dryer for 5 minutes at 60 ° C.
＜色変換層の作成方法２＞
［実施例３〜１１］
インキＩＲ４〜６およびインキＩＧ４〜９を用いて、ブラックマトリックス基板に、下記のインクジェット吐出条件で、インクジェット印刷を行い、パターニングされ、画素間に遮光性のブラックマトリックスがある色変換層ＣＲ２〜ＣＲ４およびＣＧ２〜ＣＧ７を作成した。
<How to create a color conversion layer 2>
[Examples 3 to 11]
Inkjet IR4 to 6 and inks IG4 to 9 are used to perform inkjet printing on a black matrix substrate under the following inkjet ejection conditions, and the color conversion layers CR2 to CR4 and the color conversion layers CR2 to CR4 which are patterned and have a light-shielding black matrix between pixels. CG2 to CG7 were created.
［比較例４、５］
同様に、インキＩＲ１、インキＩＧ１を用いて、同様に色変換層ＣＲ７、色変換層ＣＧ９を作成した。
・インクジェット吐出試験条件
印刷機ＤｉｍａｔｉｘＭａｔｅｒｉａｌｓＰｒｉｎｔｅｒ
カートリッジ１０ＤｉｍａｔｉｘＭａｔｅｒｉａｌｓＣａｒｔｒｉｇｅｓ、１０ｐＬ
基板温度３０℃
印刷後乾燥４０℃２０分
乾燥後膜厚２μｍ
[Comparative Examples 4 and 5]
Similarly, using the ink IR1 and the ink IG1, the color conversion layer CR7 and the color conversion layer CG9 were similarly prepared.
・ Inkjet ejection test conditions Printing machine DimatixMaterialsPrinter
Cartridge 10DimatixMaterialsCartriges, 10pL
Substrate temperature 30 ° C
Dry after printing 40 ° C for 20 minutes After drying, film thickness 2 μm
＜量子ドット分布観察＞
色変換層の表面と色変換層の表面から０．１μｍの膜厚を残して研磨した面について、X線光電子分光分析にて、量子ドットにのみ含まれるＩｎ元素の分布観察を行った。色変換層ＣＲ２、ＣＲ３、ＣＧ２、ＣＧ３では研磨面に、色変換層ＣＲ４とＣＧ４〜ＣＧ７では表面にＩｎが多く分布し、色変換層ＣＲ７とＣＧ９においては、表面と研磨面で分布の違いは見られなかった。
<Observation of quantum dot distribution>
The distribution of the In element contained only in the quantum dots was observed by X-ray photoelectron spectroscopy on the surface of the color conversion layer and the surface polished leaving a film thickness of 0.1 μm from the surface of the color conversion layer. In the color conversion layers CR2, CR3, CG2, and CG3, a large amount of In is distributed on the polished surface, and in the color conversion layers CR4 and CG4 to CG7, a large amount of In is distributed on the surface. I couldn't see it.
これは、色変換層ＣＲ２、ＣＲ３、ＣＧ２、ＣＧ３では、顔料分散剤にフルオロアルキル基またはシロキサン基を有する分散剤を用いたため、顔料が乾燥面に偏在して、表面の量子ドット濃度が下がり、相対的に基板側にあたる研磨面の量子ドット濃度が高くなった結果である。また、色変換層ＣＲ４とＣＧ４〜ＣＧ７ではリガンドにフルオロアルキル基またはシロキサン基を有するリガンドを用いたため、量子ドットが乾燥面に偏在して、表面の量子ドット濃度が高くなった結果である。 This is because in the color conversion layers CR2, CR3, CG2, and CG3, a dispersant having a fluoroalkyl group or a siloxane group was used as the pigment dispersant, so that the pigment was unevenly distributed on the dry surface and the quantum dot concentration on the surface decreased. This is a result of the relatively high quantum dot density on the polished surface, which is on the substrate side. Further, since the color conversion layers CR4 and CG4 to CG7 used ligands having a fluoroalkyl group or a siloxane group as the ligands, the quantum dots were unevenly distributed on the dry surface, resulting in an increase in the quantum dot concentration on the surface.
（透過光測定）
青色ＬＥＤ（ピーク波長450nm）の発光した光を第１の面から照射し、第２の面に透過させて、日立社製分光蛍光光度計Ｆ−２５００を用いて、４００〜８００ｎｍの光強度を１ｎｍ間隔で測定した。５００〜８００ｎｍのピーク強度（Ｐ１）を求めた。
(Measurement of transmitted light)
The light emitted by the blue LED (peak wavelength 450 nm) is irradiated from the first surface, transmitted through the second surface, and the light intensity is 400 to 800 nm using the Hitachi spectrofluorescence meter F-2500. It was measured at 1 nm intervals. The peak intensity (P1) of 500 to 800 nm was determined.
第１の面の裏側の第２の面から色変換膜側から青色ＬＥＤの光を照射させて、同様に、Ｐ２を求めた。 P2 was obtained in the same manner by irradiating the light of the blue LED from the color conversion film side from the second surface on the back side of the first surface.
色変換層、使用インキ、第１の面、第２の面、Ｐ１、Ｐ２、Ｐ１／Ｐ２を表２にまとめた。 Table 2 summarizes the color conversion layer, the ink used, the first surface, the second surface, P1, P2, and P1 / P2.
表中 基板側 色変換層の面のうち、色変換層用インキを塗布した基材と接する側
膜形成側 色変換層の面のうち、色変換層用インキを塗布した基板と対向する側
In the table, the side of the color conversion layer on the substrate side that is in contact with the base material coated with the color conversion layer ink. The side of the color conversion layer facing the substrate on which the color conversion layer ink is applied.
Ｐ１／Ｐ２が１．５以上の場合に、Ｐ１の光強度が高くなり、効率よく色変換できることが示された。 It was shown that when P1 / P2 is 1.5 or more, the light intensity of P1 becomes high and color conversion can be performed efficiently.
１０ 色変換フィルム
（Ａ） 色変換層
（Ａ１） 第１の色変換層
（Ａ２） 第２の色変換層
（ a１ ） 色変換層の第１の面
（ a２） 色変換層の第２の面
（Ｂ） 透明基材
10 Color conversion film (A) Color conversion layer (A1) First color conversion layer (A2) Second color conversion layer (a1) First surface of color conversion layer (a2) Second surface of color conversion layer (B) Transparent base material
Claims (8)
該色変換層が、量子ドットおよび有機色素を含有し、
該色変換層の第１の面へ紫外可視光を照射した場合に第２の面から観測される波長５００〜８００ｎｍの発光強度の最大値（Ｐ１）と、第２の面へ前記紫外可視光を照射した場合に第１の面から観測される波長５００〜８００ｎｍの発光強度の最大値（Ｐ２）が下記式（１）を充足することを特徴とする色変換層。
式（１）
Ｐ１/Ｐ２≧１．５
A color conversion layer used in an image display device.
The color conversion layer contains quantum dots and an organic dye, and the color conversion layer contains quantum dots and an organic dye.
When the first surface of the color conversion layer is irradiated with ultraviolet visible light, the maximum value (P1) of the emission intensity at a wavelength of 500 to 800 nm observed from the second surface and the ultraviolet visible light on the second surface. A color conversion layer characterized in that the maximum value (P2) of the emission intensity at a wavelength of 500 to 800 nm observed from the first surface when irradiated with is satisfied by the following formula (1).
Equation (1)
P1 / P2 ≧ 1.5
バックライト光源側に前記色変換層の第１の面が配置され、画像表示側に前記色変換層の第２の面が配置されていることを特徴とする画像表示装置。 An image display device including the color conversion filter according to any one of claims 5 to 7 and a backlight light source.
An image display device characterized in that a first surface of the color conversion layer is arranged on the backlight light source side and a second surface of the color conversion layer is arranged on the image display side.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017248279A JP6935745B2 (en) | 2017-12-25 | 2017-12-25 | Color conversion layer and image display device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017248279A JP6935745B2 (en) | 2017-12-25 | 2017-12-25 | Color conversion layer and image display device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019113765A JP2019113765A (en) | 2019-07-11 |
| JP6935745B2 true JP6935745B2 (en) | 2021-09-15 |
Family
ID=67223205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017248279A Active JP6935745B2 (en) | 2017-12-25 | 2017-12-25 | Color conversion layer and image display device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6935745B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020193249A (en) | 2019-05-27 | 2020-12-03 | 信越化学工業株式会社 | Quantum dot, quantum dot composition, wavelength conversion material, wavelength conversion film, backlight unit and image display device |
| KR20220000021A (en) | 2020-06-24 | 2022-01-03 | 삼성디스플레이 주식회사 | Display apparatus including light control member and manufacturing method of including light control member |
| WO2024040511A1 (en) * | 2022-08-25 | 2024-02-29 | 京东方科技集团股份有限公司 | Display panel and display apparatus |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110162711A1 (en) * | 2008-06-06 | 2011-07-07 | Sumitomo Bakelite Co., Ltd. | Wavelength-converting composition and photovoltaic device comprising layer composed of wavelength-converting composition |
| KR102381463B1 (en) * | 2010-11-10 | 2022-04-01 | 나노시스, 인크. | Quantum dot films, lighting devices, and lighting methods |
| JP2013045948A (en) * | 2011-08-25 | 2013-03-04 | Fujifilm Corp | Wavelength conversion film and photoelectric conversion device |
| CN111500281A (en) * | 2012-10-25 | 2020-08-07 | 亮锐控股有限公司 | PDMS-based ligands for quantum dots in silicones |
-
2017
- 2017-12-25 JP JP2017248279A patent/JP6935745B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019113765A (en) | 2019-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5847993B2 (en) | Resin composition for color filter containing cardo resin | |
| JP6935745B2 (en) | Color conversion layer and image display device | |
| JP5817099B2 (en) | Green pigment colored resin composition, color filter, liquid crystal display device, and organic EL display device | |
| CN102576190A (en) | Colored photosensitive resin composition, color filter, and liquid crystal display device | |
| WO2018074539A1 (en) | Method for forming cured film, radiation-sensitive resin composition, and display element and sensor provided with cured film | |
| JPWO2012067026A1 (en) | Color filter manufacturing method, display element, and color filter | |
| JP2013228727A (en) | Color filter coloring resin composition, color filter, liquid crystal display device, and organic el display device | |
| JP2005010604A (en) | Photosensitive black composition, black matrix substrate obtained by using the same and color filter | |
| JP2006337952A (en) | Manufacturing method of color filter | |
| CN104914669B (en) | Blue photosensitive resin composition, blue filter and display device having the same | |
| JP2001164142A (en) | Pigment dispersion composition | |
| JP2007094307A (en) | Color filter and its manufacturing method | |
| JP2020012115A (en) | Green pigment colored resin composition, color filter, liquid crystal display device, and organic el display device | |
| KR102241498B1 (en) | Colored photosensitive resin composition for red or green pixel | |
| JP2014134721A (en) | Colored resin composition for color filter, color filter, liquid crystal display device, and organic el display device | |
| KR20190093915A (en) | Colored photo sensitive resin composition, a color filter comprising the same, and a display devide comprising the color filter | |
| JP7449642B2 (en) | Colored resin composition, color filter, and image display device | |
| KR20190058126A (en) | Colored Photosensitive Resin Composition, Color Filter and Display Device | |
| KR20190082588A (en) | Colored Photosensitive Resin Composition, Color Filter and Display Device | |
| JP2013041156A (en) | Colored resin composition, color filter, liquid crystal display device, and organic el display device | |
| JP2012197369A (en) | Colored resin composition, color filter, liquid crystal display device, and organic el display device | |
| JP5664127B2 (en) | Green pigment colored resin composition, color filter, liquid crystal display device, and organic EL display device | |
| JP6597717B2 (en) | Green pigment colored resin composition, color filter, liquid crystal display device, and organic EL display device | |
| JP2013079315A (en) | Coloring resin composition, color filter, liquid crystal display, organic el display, and dye for liquid crystal display member | |
| JP2004250535A (en) | Colored resin composition, color filter and liquid crystal display device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200804 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210727 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210809 |
|
| R151 | Written notification of patent or utility model registration |
Ref document number: 6935745 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |