JP6681654B2 - 多層粘着シート - Google Patents
多層粘着シート Download PDFInfo
- Publication number
- JP6681654B2 JP6681654B2 JP2014008556A JP2014008556A JP6681654B2 JP 6681654 B2 JP6681654 B2 JP 6681654B2 JP 2014008556 A JP2014008556 A JP 2014008556A JP 2014008556 A JP2014008556 A JP 2014008556A JP 6681654 B2 JP6681654 B2 JP 6681654B2
- Authority
- JP
- Japan
- Prior art keywords
- meth
- adhesive sheet
- acrylate
- sensitive adhesive
- protective layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000000853 adhesive Substances 0.000 title claims description 30
- 230000001070 adhesive effect Effects 0.000 title claims description 30
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 84
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 81
- 229920000642 polymer Polymers 0.000 claims description 74
- 239000010410 layer Substances 0.000 claims description 69
- 239000011241 protective layer Substances 0.000 claims description 66
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 60
- 239000000463 material Substances 0.000 claims description 44
- 239000002904 solvent Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 20
- 239000003431 cross linking reagent Substances 0.000 claims description 20
- 229920005862 polyol Polymers 0.000 claims description 12
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 65
- 239000000178 monomer Substances 0.000 description 62
- -1 adipate ester Chemical class 0.000 description 53
- 239000003999 initiator Substances 0.000 description 28
- 230000003068 static effect Effects 0.000 description 24
- 239000011248 coating agent Substances 0.000 description 21
- 238000000576 coating method Methods 0.000 description 21
- 239000002131 composite material Substances 0.000 description 20
- 238000011156 evaluation Methods 0.000 description 19
- 150000002009 diols Chemical class 0.000 description 18
- 239000007788 liquid Substances 0.000 description 16
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 125000005442 diisocyanate group Chemical group 0.000 description 12
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000004611 light stabiliser Substances 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 8
- 229920000058 polyacrylate Polymers 0.000 description 8
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 8
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 7
- 239000011737 fluorine Substances 0.000 description 7
- 229910052731 fluorine Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 5
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 4
- BYPFICORERPGJY-UHFFFAOYSA-N 3,4-diisocyanatobicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(N=C=O)C(N=C=O)=CC1C2 BYPFICORERPGJY-UHFFFAOYSA-N 0.000 description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000001678 irradiating effect Effects 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000006188 syrup Substances 0.000 description 4
- 235000020357 syrup Nutrition 0.000 description 4
- 238000009864 tensile test Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 244000028419 Styrax benzoin Species 0.000 description 3
- 235000000126 Styrax benzoin Nutrition 0.000 description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229960002130 benzoin Drugs 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 235000019382 gum benzoic Nutrition 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002075 main ingredient Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 230000013011 mating Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 2
- QGLRLXLDMZCFBP-UHFFFAOYSA-N 1,6-diisocyanato-2,4,4-trimethylhexane Chemical compound O=C=NCC(C)CC(C)(C)CCN=C=O QGLRLXLDMZCFBP-UHFFFAOYSA-N 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- OTCWVYFQGYOYJO-UHFFFAOYSA-N 1-o-methyl 10-o-(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound COC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 OTCWVYFQGYOYJO-UHFFFAOYSA-N 0.000 description 2
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 2
- UZUNCLSDTUBVCN-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-(2-phenylpropan-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound C=1C(C(C)(C)CC(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C(O)C=1C(C)(C)C1=CC=CC=C1 UZUNCLSDTUBVCN-UHFFFAOYSA-N 0.000 description 2
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- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 description 2
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 2
- CUXGDKOCSSIRKK-UHFFFAOYSA-N 7-methyloctyl prop-2-enoate Chemical compound CC(C)CCCCCCOC(=O)C=C CUXGDKOCSSIRKK-UHFFFAOYSA-N 0.000 description 2
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- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
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- 238000004040 coloring Methods 0.000 description 2
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- 238000010586 diagram Methods 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
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- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- RQXWJINLDMJNJQ-UHFFFAOYSA-N butane cyanic acid Chemical compound OC#N.OC#N.CCCC RQXWJINLDMJNJQ-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- OMLMPYVQBRBLBA-UHFFFAOYSA-N cyclododeca-1,3,5-triene;prop-2-enoic acid Chemical class OC(=O)C=C.C1CCCC=CC=CC=CCC1 OMLMPYVQBRBLBA-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- XBGSYTUNSOYWEF-UHFFFAOYSA-N dibutyltin;dodecanoic acid Chemical compound CCCC[Sn]CCCC.CCCCCCCCCCCC(O)=O XBGSYTUNSOYWEF-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
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- PODOEQVNFJSWIK-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethoxyphenyl)methanone Chemical compound COC1=CC(OC)=CC(OC)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 PODOEQVNFJSWIK-UHFFFAOYSA-N 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
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- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
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- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
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- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FDAKZQLBIFPGSV-UHFFFAOYSA-N n-butyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCCCNC1CC(C)(C)NC(C)(C)C1 FDAKZQLBIFPGSV-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- OPECTNGATDYLSS-UHFFFAOYSA-N naphthalene-2-sulfonyl chloride Chemical compound C1=CC=CC2=CC(S(=O)(=O)Cl)=CC=C21 OPECTNGATDYLSS-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- TWCBCCIODCKPGX-UHFFFAOYSA-N octyl 2-[4-[4,6-bis(4-phenylphenyl)-1,3,5-triazin-2-yl]-3-hydroxyphenoxy]propanoate Chemical compound OC1=CC(OC(C)C(=O)OCCCCCCCC)=CC=C1C1=NC(C=2C=CC(=CC=2)C=2C=CC=CC=2)=NC(C=2C=CC(=CC=2)C=2C=CC=CC=2)=N1 TWCBCCIODCKPGX-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002601 oligoester Polymers 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
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- 230000037303 wrinkles Effects 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
- C09J2433/006—Presence of (meth)acrylic polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
- C09J2475/006—Presence of polyurethane in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
本発明の多層粘着シートは、少なくとも粘着剤層と基材層と表面保護層とを有する積層シートである。但し、表面保護層は、N,N−ジメチルホルムアミド(DMF)不溶分を含有する。なお、表面保護層は多層粘着シートの最表面に配置されていることが好ましい。
例えば、オキサゾリン系架橋剤としては、商品名「(登録商標)エポクロス WS−700」(オキサゾリン基含有水溶性ポリマー、日本触媒株式会社製)、商品名「(登録商標)エポクロス WS−500」(オキサゾリン基含有水溶性ポリマー、日本触媒株式会社製)などが商業的に入手可能なものとして挙げられ、カルボジイミド系架橋剤としては、商品名「(登録商標)カルボジライトE−02」(カルボジイミド基含有水溶性ポリマー、日清紡績株式会社製)、商品名「(登録商標)カルボジライトE−01」(カルボジイミド基含有水溶性ポリマー、日清紡績株式会社製)などが商業的に入手可能なものとして挙げられ、また、エポキシ系架橋剤としては、商品名「(登録商標)GL−PEP」(エポキシ基含有水溶性ポリマー、四日市合成株式会社製)、商品名「(登録商標)デナコールEX−313」(エポキシ基含有水溶性ポリマー、ナガセケムテックス株式会社製)などが商業的に入手可能なものとして挙げられる。
本発明において「主成分として含む」という場合には、50重量%以上含有することを意味し、好ましくは90重量%以上含有することであり、また、100%含有する場合も該当する。
本発明においては、Tgが0℃未満の単官能(メタ)アクリル系モノマーとして、アクリル酸n−ブチルを用いることが特に好ましい。
μ=Fs/Fp
(μ:静摩擦係数、Fs:静摩擦力(N)、Fp:法線力)
(1)最大応力値の測定
多層粘着シートを、幅10mm×長さ160mmに切断し、引張速度200mm/min、チャック間距離100mm、23℃で引張試験を実施し、応力−歪み曲線を求めた。多層粘着シートの0%〜10%伸長時における単位面積当たりの応力の最大値(最大応力値)を求めた。
多層粘着シートを、幅80mm×長さ100mmのサイズに切断し、この多層粘着シートを標準試験板(JISG3141:日本テストパネル株式会社製)の上に貼着し、この粘着シートの上に滑り片を載せ、JISK7125に準じて最表面層(ex. 表面保護層)の静摩擦係数を測定した。なお、滑り片の接触面積は63mm×63mm、滑り片の全質量を200g(1.96N)とし、滑り片の粘着シート表面との接触面にはスキージークロスを貼り付け、滑り速度100mm/minの条件で滑り片を引っ張って測定を行った。静摩擦係数は、JISK7125に準ずる下記算出式を用いて求めた。
(μ:静摩擦係数、Fs:静摩擦力(N)、Fp:滑り片の質量によって生じる法線力(=9.8N/kg×0.2kg))
得られた多層粘着シート(幅30mm、長さ50mm)を、黒パネル(KINO−1210TW:関西ペイント株式会社製)に貼り付け、エタノールを含浸させたウエスで多層粘着シート表面を20往復擦り、その後、多層粘着シートを二段階で評価した。なお、評価は、下記に示す評価基準に基づいて行った。
(評価基準)
○ 多層粘着シートの白濁(溶解)が確認されない。
× 多層粘着シートの白濁(溶解)が確認される。
得られた表面保護層(幅100mm、長さ100mm)を#100 SUSメッシュで包み、DMFに3日間浸漬した。その後、表面保護層を包んだSUSメッシュを130℃で1時間乾燥させ、SUSメッシュの重量を測定した。表面保護層のゲル分率を下記式に基づいて算出した。
(算出式)
ゲル分率(%)={(浸漬・乾燥後の表面保護層の重量)/(浸漬・乾燥前の表面保護層の重量)}×100
三次元曲面部位(大きさ:縦300mm×横210mm、曲率:最大凸部曲率(R=43.3)、最大凹部曲率(R=34.6)からなる断面曲線(図2参照)を含む曲面を有する部位)に対し、多層粘着シートを貼り付けるという貼付作業を行って貼付作業性の評価を行った。すなわち、「表面滑り性」および「曲面追従性」のそれぞれについて、点数(1〜4点)で評価し、両者の合計点数を求めた。但し、試験に参加した貼付作業者は3名である。また、「表面滑り性」および「曲面追従性」の点数付けの基準は、非常に良いレベルを4点、問題ないレベルを3点、少し改善が必要なレベルを2点、改善が必要なレベルを1点とし、作業者3名の平均値で示した。
(評価基準):
「優」 貼付作業性の合計点数が5点以上
「良」 貼付作業性の合計点数が4.5点より大きく、5点未満
「劣」 貼付作業性の合計点数が4.5点以下
《表面保護層用塗布液の作製》
表面保護層用塗布液として、水系ウレタンポリマー(第一工業薬品株式会社製のカーボネート系ポリウレタンエマルジョン(主剤)、商品名「F−2954D−5」)を55.88部、水系ウレタンポリマー(第一工業薬品株式会社製のカーボネート系ポリウレタンエマルジョン(主剤)、商品名「スーパーフレックス460」)を44.12部、オキサゾリン系架橋剤として商品名「エポクロスWS−700」(日本触媒株式会社製)を5.81部、レベリング剤として、ポリエーテル系変性シロキサン(商品名「BYK−349」、ビックケミー−ジャパン株式会社製)を0.1部とパーフルオロアルケニルオキシベンゼンスルホン酸ナトリウム(商品名「フタージェント100」(1%希釈溶媒)、株式会社ネオス製)を1.00部、増粘剤として商品名「レオレート216」(エレメンティスジャパン株式会社製)を1.00部、水分散型光安定剤として商品名「UC−606」(株式会社ADEKA製)を0.80部、および、水分散型ベンゾトリアゾール系紫外線吸収剤として商品名「UC−3140」(株式会社ADEKA製)を0.20部の割合で混合した。次いで、ディスパーを用いて回転速度2000rpmで10分間攪拌した後、脱泡装置(2000rpm、10min)を用いて脱泡し、表面保護層用塗布液を作製した。なお、この塗布液を用いてなる表面保護層の0%〜100%伸長状態までにおける最大応力値は6.45MPa(計算値)であり、表1に記載した。
基材層として、厚み140μmのアジペート・エステル系熱可塑性ポリウレタンフィルム(日本マタイ株式会社製、硬度86A)を使用した。このアジペート系熱可塑性ポリウレタンフィルム(アジペート系TPUフィルム」の上に、作製した表面保護層用塗布液を硬化後の厚みが10μmとなるように塗布し、温度140℃で3分間、乾燥および硬化させて、基材層の一方の面に表面保護層を形成した。
モノマー成分として、2−エチルヘキシルアクリレート94部およびアクリル酸6部を混合した混合物に、光重合開始剤として、商品名「イルガキュア 651」(チバ・スペシャリティ・ケミカルズ社製)を0.07部と、商品名「イルガキュア 184」(チバ・スペシャリティ・ケミカルズ社製)を0.07部とを配合した後、粘度が約15Pa・s(BH粘度計No.5ローター、10rpm、測定温度30℃)になるまで紫外線を照射して、一部が重合したアクリル組成物(UVシロップ)を作製した。
セパレータを除去し、得られた多層シートの表面保護層側の面とは反対側の面(すなわち基材層面)に、ハンドローラーを用いて粘着剤層が重なるように貼り合わせて厚みが200μmの多層粘着シート(表面保護層/基材層/粘着剤層)を作製した。なお、この多層粘着シートには、粘着剤層の上に剥離ライナーが設けられている。
得られた多層粘着シートについて、上記に示す評価方法に従い、0%を越えて10%伸長状態までにおける最大応力値を求め、また、耐溶剤性の評価を行い、貼付作業性の評価を行った。さらにまた、得られた表面保護層について静摩擦係数およびゲル分率を測定した。その結果を表2に示す。
表面保護層用塗布液の配合量を表1に示すように、商品名「F−2954D−5」を45.78部、商品名「スーパーフレックス460」を54.22部、商品名「エポクロスWS−700」を5.81部、商品名「BKY−349」を0.1部、商品名「フタージェント100(1%希釈溶媒)」を1.00部、商品名「レオレート216」を1.00部、商品名「UC−606」を0.80部、商品名「UC−3140」を0.20部の混合割合に変更した以外は実施例1と同様にして、基材層の一方の面に表面保護層を有し、他方の面に粘着剤層を有する、多層粘着シートを作製した。得られた多層粘着シートおよび表面保護層について、実施例1と同様にして、上記に示す評価方法に従い、静摩擦係数の測定、最大応力値の測定、ゲル分率の測定、耐溶剤性の評価、貼付作業性の評価を行った。その結果を表2に示す。
表面保護層用塗布液の配合量を表1に示すように、商品名「F−2954D−5」を55.88部、商品名「スーパーフレックス460」を44.12部、商品名「BKY−349」を0.1部、商品名「フタージェント100(1%希釈溶媒)」を1.00部、商品名「レオレート216」を1.00部、商品名「UC−606」を0.80部、商品名「UC−3140」を0.20部の混合割合に変更した以外は実施例1と同様にして、基材層の一方の面に表面保護層を有し、他方の面に粘着剤層を有する、多層粘着シートを作製した。得られた多層粘着シートおよび表面保護層について、実施例1と同様にして、上記に示す評価方法に従い、静摩擦係数の測定、最大応力値の測定、ゲル分率の測定、耐溶剤性の評価、貼付作業性の評価を行った。その結果を表2に示す。
表面保護層用塗布液の配合量を表1に示すように、商品名「F−2954D−5」を45.78部、商品名「スーパーフレックス460」を54.22部、商品名「BKY−349」を0.1部、商品名「フタージェント100(1%希釈溶媒)」を1.00部、商品名「レオレート216」を1.00部、商品名「UC−606」を0.80部、商品名「UC−3140」を0.20部の混合割合に変更した以外は実施例1と同様にして、基材層の一方の面に表面保護層を有し、他方の面に粘着剤層を有する、多層粘着シートを作製した。得られた多層粘着シートおよび表面保護層について、実施例1と同様にして、上記に示す評価方法に従い、静摩擦係数の測定、最大応力値の測定、ゲル分率の測定、耐溶剤性の評価、貼付作業性の評価を行った。その結果を表2に示す。
表面保護層用塗布液の種類を表2に示すようにフッ素系塗布液に変更した以外は実施例1と同様にして、多層粘着シートを作製した。すなわち、フルオロエチレンビニルエーテルのキシレンおよびトルエンによる50%濃度溶解液(旭硝子株式会社製の商品名「ルミフロンLF600」を100.00部と、イソシアネート系架橋剤(日本ポリウレタン工業株式会社製の商品名「コロネートHX」)を9.49部と、触媒としてジブチル錫ラウリン酸(東京ファインケミカル株式会社製の商品名「OL1」)のキシレン希釈液(固形分濃度が0.1%)を0.35部と、希釈溶媒としてトルエン76.41部の割合で混合してフッ素系塗布液を作製した。このフッ素系塗布液を使用して、実施例1と同様にして基材層の一方の面にフッ素系表面保護層を形成し、他方の面に粘着剤層を形成して、多層粘着シートを作製した。得られた多層粘着シートおよび表面保護層について、実施例1と同様にして、上記に示す評価方法に従い、静摩擦係数の測定、最大応力値の測定、ゲル分率の測定、耐溶剤性の評価、貼付作業性の評価を行った。その結果を表2に示す。
表面保護層を設けなかった以外は実施例1と同様にして、基材層の一方の面に粘着剤層を有する粘着シートを作製した。得られた多層粘着シートについて、実施例1と同様にして、上記に示す評価方法に従い、静摩擦係数の測定、最大応力値の測定、耐溶剤性の評価、貼付作業性の評価を行った。その結果を表2に示す。
基材層をカプロラクトン系ポリウレタン(日本マタイ株式会社製)に変更し、また表面保護層を設けなかった以外は実施例1と同様にして粘着シートを作製し、また、実施例1と同様の測定および評価を行った。その結果を表2に示す。
F−2954D−5: カーボネート系ポリウレタンエマルジョン(主剤)(第一工業製薬株式会社製)
スーパーフレックス460: カーボネート系ポリウレタンエマルジョン(主剤)(第一工業製薬株式会社製)
エポクロスWS−700: オキサゾリン系架橋剤(株式会社日本触媒製)
BYK−349: レベリング剤、ポリエーテル系変性シロキサン(ビックケミー−ジャパン株式会社製)
フタージェント100: レベリング剤、パーフルオロアルケニルオキシベンゼンスルホン酸ナトリウム(ネオス株式会社製)
レオレート216: 増粘剤(エレメンティスジャパン株式会社製)
UC−606: 水分散型光安定剤(株式会社ADEKA製)
UC−3140: 水分散型光安定剤(株式会社ADEKA製)
LF600: フルオロエチレンビニルエーテル交互共重合体(旭硝子株式会社製)
「コロネートHX」: イソシアネート系架橋剤(日本ポリウレタン工業株式会社製)
したがって、本発明により、柔軟性、滑り性、耐溶剤性の全てにおいて優れた多層粘着シートを実現することができた。
Claims (5)
- 少なくとも、ウレタン系ポリマーを主成分とする表面保護層と、1種類のポリオールと1種類のポリイソシアネートを反応させて得られるポリウレタン成分のみからなる重合体を含有する基材層と粘着剤層とを有する多層粘着シートであって、該粘着剤層は該基材層の一方の面に設けられており、該表面保護層は該基材層の他方の面に設けられており、前記表面保護層はN,N−ジメチルホルムアミド(DMF)不溶分を50重量%以上含有し、かつ、前記多層粘着シートの0%を越えて10%伸張状態における最大応力値が0.5MPa以上、4.0MPa以下の範囲内であることを特徴とする多層粘着シート。
- 前記表面保護層が、エステル系のウレタンポリマー、エーテル系のウレタンポリマー、およびエステル/アクリル系のウレタンポリマーからなる群から選ばれる少なくとも1種類のウレタン系ポリマーを主成分とすることを特徴とする請求項1に記載の多層粘着シート。
- 前記表面保護層を構成する前記ウレタン系ポリマーが、水系ウレタンポリマーまたは溶剤系ウレタンポリマーであることを特徴とする請求項1または2に記載の多層粘着シート。
- 前記表面保護層は、前記ウレタン系ポリマー100重量部に対し、架橋剤を5重量部以上、12重量部以下含有することを特徴とする請求項1から3のいずれか1項に記載の多層粘着シート。
- 前記多層粘着シートが、被着体の表面を保護するための保護シートとして使用されることを特徴とする請求項1から4のいずれか1項に記載の多層粘着シート。
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JP5568428B2 (ja) * | 2009-10-15 | 2014-08-06 | アキレス株式会社 | 半導体製造工程用テープの基材フィルム |
JP5791945B2 (ja) * | 2011-04-15 | 2015-10-07 | 日東電工株式会社 | 粘着シート |
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2014
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JP7055227B2 (ja) | 2022-04-15 |
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