JP6446175B2 - 溶射被覆した強化ポリマー複合材料 - Google Patents
溶射被覆した強化ポリマー複合材料 Download PDFInfo
- Publication number
- JP6446175B2 JP6446175B2 JP2013225975A JP2013225975A JP6446175B2 JP 6446175 B2 JP6446175 B2 JP 6446175B2 JP 2013225975 A JP2013225975 A JP 2013225975A JP 2013225975 A JP2013225975 A JP 2013225975A JP 6446175 B2 JP6446175 B2 JP 6446175B2
- Authority
- JP
- Japan
- Prior art keywords
- intermediate layer
- substrate
- fiber reinforced
- composite
- reinforced polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002131 composite material Substances 0.000 title claims description 103
- 239000007921 spray Substances 0.000 title claims description 17
- 229920000642 polymer Polymers 0.000 title description 7
- 239000010410 layer Substances 0.000 claims description 157
- 239000000758 substrate Substances 0.000 claims description 97
- 238000000576 coating method Methods 0.000 claims description 80
- 238000000034 method Methods 0.000 claims description 64
- 239000011248 coating agent Substances 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 37
- 229910052760 oxygen Inorganic materials 0.000 claims description 37
- 239000001301 oxygen Substances 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 31
- 238000000151 deposition Methods 0.000 claims description 30
- 229910052729 chemical element Inorganic materials 0.000 claims description 27
- 229910010272 inorganic material Inorganic materials 0.000 claims description 25
- 239000011147 inorganic material Substances 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 24
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 229910052710 silicon Inorganic materials 0.000 claims description 24
- 239000010703 silicon Substances 0.000 claims description 24
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims description 23
- 239000000919 ceramic Substances 0.000 claims description 21
- 239000004918 carbon fiber reinforced polymer Substances 0.000 claims description 20
- 239000011159 matrix material Substances 0.000 claims description 19
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
- 239000011229 interlayer Substances 0.000 claims description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 18
- 239000011151 fibre-reinforced plastic Substances 0.000 claims description 17
- 229920000620 organic polymer Polymers 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 239000010931 gold Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000010936 titanium Substances 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910009043 WC-Co Inorganic materials 0.000 claims description 8
- 229920000271 Kevlar® Polymers 0.000 claims description 7
- 229910000943 NiAl Inorganic materials 0.000 claims description 7
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 7
- 239000003365 glass fiber Substances 0.000 claims description 7
- 239000004761 kevlar Substances 0.000 claims description 7
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 7
- 239000004919 Carbon nanotube reinforced polymer Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 229910001120 nichrome Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 238000004544 sputter deposition Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052727 yttrium Inorganic materials 0.000 claims description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 claims description 5
- 238000005299 abrasion Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 238000007740 vapor deposition Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 14
- 230000036961 partial effect Effects 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 230000008021 deposition Effects 0.000 description 11
- 239000010408 film Substances 0.000 description 11
- 238000005507 spraying Methods 0.000 description 9
- 238000007751 thermal spraying Methods 0.000 description 8
- -1 region Substances 0.000 description 7
- 239000010409 thin film Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 238000005137 deposition process Methods 0.000 description 6
- 239000011651 chromium Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 238000001755 magnetron sputter deposition Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- 239000004713 Cyclic olefin copolymer Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010891 electric arc Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 2
- 238000007750 plasma spraying Methods 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000001552 radio frequency sputter deposition Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 2
- YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000684 Cobalt-chrome Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical class [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000010952 cobalt-chrome Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000012720 thermal barrier coating Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
- C23C14/0036—Reactive sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
- C23C14/0036—Reactive sputtering
- C23C14/0084—Producing gradient compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0635—Carbides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/324—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal matrix material layer comprising a mixture of at least two metals or metal phases or a metal-matrix material with hard embedded particles, e.g. WC-Me
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/36—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating By Spraying Or Casting (AREA)
- Physical Vapour Deposition (AREA)
Description
一実施形態では、繊維強化ポリマー複合材料は、基材として使用する。このようなポリマー複合材料としては、有機および/または無機の強化繊維と組み合わせたエンジニアリング樹脂を挙げることができる。強化繊維と組み合わせたエンジニアリング樹脂のクラスの一例は、炭素繊維強化ポリマー(CFRP)であり、これを使用することができる。他の強化ポリマーを使用してもよい。例えば、エンジニアリングプラスチックとしては、例えば、超高分子量ポリエチレン、ナイロン6、ナイロン66、ポリテトラフルオロエチレン、アクリロニトリルブタジエンスチレン、ポリカルボナート、ポリアミド、ポリブチレンテレフタラート、ポリエチレンテレフタレート、ポリフェニレンオキシド、ポリスルホン、ポリエーテルケトン、ポリエーテルエーテルケトン、ポリアミド、ポリフェニレンスルフィド、ポリオキシメチレン、環状オレフィンコポリマー(COC)、およびそれらのブレンドを挙げることができる。他のエンジニアリングポリマー、樹脂、熱硬化性樹脂(thermal set)、プラスチック、およびそれらのブレンドを、本明細書に開示および記載の方法に従って使用することができる。例示的な複合材料としては、カーボンナノチューブ、ガラス繊維、ケブラー繊維(例えば、ポリ−パラフェニレンテレフタルアミド)、セラミック繊維、炭素繊維、またはそれらの組合せと組み合わせた上記のエンジニアリング樹脂が挙げられる。本開示は、高温/高速度の被膜、特に、金属、金属合金、および/またはセラミックなどの無機被膜を用いて被覆したときの、従来の複合材料被覆工程およびその工程から作製される被覆済み複合材料の多数の欠陥に対処するものである。
本開示は、ひとつには、有機ポリマー複合材料の基材表面の少なくとも一部分上に十分な付着性の薄膜(以下、「中間層」とも呼ぶ)を堆積させる方法を提供する。開示する堆積技術および中間層構造設計によって、基材への被膜の付着を向上させ、複合材料にさらなる表面機能を付与し、後続の被覆、例えば、動的および/または高温被覆技術、ならびにその技術から製造される被膜を受けることが可能になる。複合材料の性能および機能性のこれらの向上ならびにこのような高エネルギー/高温噴霧被覆との使用は、中間層材料の厚み(例えば、基材表面から垂直な厚み)による中間層材料の化学的性質(例えば、組成)および/または元素濃度を制御および/または調節することによって実現される。中間層構造は、「下端」層(複合材料基材表面に隣接)を有し、その化学組成は、複合材料表面と適合するように構成されている。中間層を記述するために、中間層は、基材表面における中間層の界面と界面の最外面とにそれぞれ対応する「基材近接層」と「表面近接層」とを有するものと称することができる。中間層は、単独でまたは後続被膜と組み合わせて、複合材料の化学的、電気的、および機械的状態を変質させることができ、それによって、用途範囲をより広くすることが可能になる。本開示の工程は、金属またはプラスチック基材において、ならびに他の薄膜材料および薄膜被覆方法と組み合わせて、使用することができる。一態様では、中間層は、動的/高温被覆中、基材を保護するのに使用することができ、したがって、基材の少なくとも一部分を、複合材料への変化が低減または除去されている状態で、動的または高温被膜で被覆することが可能になる。
本明細書に開示の方法では、高温および/または動的な被膜を、上に中間層が堆積している基材に施す。一態様では、高温および/または動的な被膜は、1種または複数の無機材料を含み、中間層を有する基材上に被膜を形成する。無機材料としては、例えば、1種または複数の金属、金属合金、セラミック、および/または耐火性酸化物が挙げられる。高温/動的被覆工程で使用する無機材料は、基材に射出された(またはそこに向けて射出されている)溶融、半溶融、または固体の材料、ならびに無機材料の他の形態、またはその前駆物、例えば、ワイヤ、粉末、液体、金属、金属合金、セラミック、および/もしくは耐火性酸化物を包含する。
中間層バリアを、炭化ケイ素ターゲットおよびRFマグネトロンスパッタリング源を用いて堆積させる。第1層は、5W/cm2のパワー/ターゲット範囲を使用して、酸素分圧が0〜低い状態で、大気(10−3トール真空)中において製造する。この層は、高炭素含有量を有して、CFRPとより適合する。出発濃度は、基材の性質に依存する。例えば、炭素の相対濃度が高い基材では、適合性を増大させるのに、堆積中の酸素分圧が0であることが望ましい。ステップバイステップ法または連続法では、酸素濃度を、堆積中、徐々に、すなわち、0〜10%に増加させる。堆積中に分圧を増加させると、膜中の酸素の相対含有量が増加する。上層は、酸素濃度が10%超存在する状態で堆積させることができる。これにより、ガラス状で、硬質で、かつより引っ掻き耐性のある膜または被膜をもたらすことができる。複合材料を保護するために多層の勾配被膜を堆積させた後、溶射に基づく技術または代替の高温/高速度技術を使用して、表面の電気的、機械的、および/または熱的性質を変質させることができる。
20 第1化学組成
30 第2化学組成
40 第3化学組成
60 RFスパッタリングユニット
75 第1矢印
85 矢印
100 中間層
200 勾配中間層
300 中間層
520 反応ガス
530 反応ガス
540 反応ガス
700 火炎噴霧器
705 ワイヤ
707 粉末供給原料
709 無機原料
710 供給装置
715 キャリアガス、燃料
717 燃料
719 圧縮ガス供給原料
720 火炎
725 無機材料、溶融/半溶融粒子
730 無機被覆物
740 中間層
750 複合材料基材
800 噴霧ユニット
Claims (12)
- 強化有機ポリマーマトリックスを含む基材(10)であって、基材表面を有する基材と、
前記基材表面上にある少なくとも1層の中間層(100)であって、前記基材(10)から垂直に延在する厚み部分、および垂直に延在する前記厚み部分の少なくとも一部分内における少なくとも1種の化学元素の線状の組成勾配を有し、オキシ炭化ケイ素を含む、中間層と、
前記中間層の少なくとも一部分上に堆積した少なくとも1種の溶射またはコールドスプレーされた無機被膜と
を含む複合材料。 - 前記強化有機ポリマーマトリックスが、炭素繊維強化ポリマー、ガラス繊維強化ポリマー、カーボンナノチューブ強化ポリマー、ケブラー(ポリ−パラフェニレンテレフタルアミド)繊維強化ポリマー、またはセラミック繊維強化ポリマーから選択される繊維強化ポリマーである、請求項1に記載の複合材料。
- 前記中間層が、ケイ素、酸素、および炭素を含む、請求項1に記載の複合材料。
- 前記少なくとも1種の化学元素が、酸素、炭素、窒素、硫黄、またはハロゲンである、請求項1に記載の複合材料。
- 前記組成勾配が、前記厚み部分内において前記少なくとも1種の元素の様々な濃度を含む、請求項1に記載の複合材料。
- 前記様々な濃度が、前記基材の近傍に炭素豊富な中間層部分を、および前記無機被膜の近傍に酸素豊富な、または窒素豊富な、または窒化物豊富な中間層部分を構成する、請求項5に記載の複合材料。
- 前記無機被膜が、金属、金属合金、セラミック、またはそれらの組合せである、請求項1に記載の複合材料。
- 前記金属が、銅(Cu)、銀(Ag)、白金(Pt)、パラジウム(Pd)、金(Au)、アルミニウム(Al)、チタン(Ti)、およびそれらの合金であり、前記金属合金が、合金鉄、WC−Co、WC−Co−Cr、NiAl、CrC−NiCr、二硫化モリブデン(MoS2)、もしくはMCrAlY(但し、Mは、Co、Ni、もしくはCo/Ni)であり、または前記セラミックが、ジルコニア、アルミナ、およびイットリウム安定化ジルコニウム(YSZ)の群から選択される1種もしくは複数の耐火性酸化物である、請求項7に記載の複合材料。
- 被覆したポリマー性複合材料基材を提供する方法であって、
ポリマー性複合材料基材(10)表面上に、オキシ炭化ケイ素を含む中間層(100)の厚み部分の少なくとも一部分内において少なくとも1種の化学元素の線状の濃度勾配を有するある厚みの前記中間層を堆積させることであって、気相堆積技術、スパッタリング技術、もしくはプラズマ堆積技術、またはそれらの組合せによって堆積させることと、
コールドスプレー技術によって前記中間層の少なくとも一部分に、金属、金属合金、セラミック、またはそれらの組合せである無機材料を堆積させることと、
前記中間層および複合材料基材表面上の少なくとも一部分上に前記無機材料の被膜を形成させることと
を含む方法。 - 高温材料および/または動的な無機材料による前記複合材料基材の少なくとも一部分への化学的変化または物理的変化を除去または低減することをさらに含む、請求項9に記載の方法。
- 前記ポリマー性複合材料が、炭素繊維強化ポリマー、ガラス繊維強化ポリマー、カーボンナノチューブ強化ポリマー、ケブラー(ポリ−パラフェニレンテレフタルアミド)繊維強化ポリマー、またはセラミック繊維強化ポリマーから選択される繊維強化有機ポリマーマトリックスである、請求項9に記載の方法。
- 請求項1に記載の複合材料を含む物品であって、前記基材が繊維強化有機ポリマー複合材料基材を含み、前記中間層が、本質的にオキシ炭化ケイ素からなり、前記オキシ炭化ケイ素が、前記オキシ炭化ケイ素中間層の厚み部分の少なくとも一部分において炭素と酸素の濃度が反比例関係を有しており、前記無機被膜が、前記複合材料基材に耐摩耗性、耐摩滅性、耐食性、回復性、電気伝導性および/または熱伝導性、ならびに減摩性の1つまたは複数を付与する物品。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/679,399 | 2012-11-16 | ||
US13/679,399 US10060019B2 (en) | 2012-11-16 | 2012-11-16 | Thermal spray coated reinforced polymer composites |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014111364A JP2014111364A (ja) | 2014-06-19 |
JP6446175B2 true JP6446175B2 (ja) | 2018-12-26 |
Family
ID=49165632
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013225975A Active JP6446175B2 (ja) | 2012-11-16 | 2013-10-30 | 溶射被覆した強化ポリマー複合材料 |
Country Status (5)
Country | Link |
---|---|
US (1) | US10060019B2 (ja) |
EP (3) | EP3388544B1 (ja) |
JP (1) | JP6446175B2 (ja) |
CN (1) | CN103819705B (ja) |
CA (2) | CA2824830C (ja) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11479652B2 (en) | 2012-10-19 | 2022-10-25 | Rutgers, The State University Of New Jersey | Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom |
CN104884243B (zh) | 2012-10-19 | 2017-07-18 | 新泽西鲁特格斯州立大学 | 制备石墨烯补强的聚合物基质复合材料的原位剥离法 |
MX2015014631A (es) | 2013-04-18 | 2016-09-29 | Univ Rutgers | Metodo de exfoliacion in situ para fabricar un compuesto de la matriz reforzados con grafeno. |
CN116804117A (zh) | 2014-07-30 | 2023-09-26 | 新泽西鲁特格斯州立大学 | 石墨烯增强的聚合物基质复合材料 |
US20160153080A1 (en) * | 2014-12-01 | 2016-06-02 | Inometa Gmbh & Co. Kg | Method for producing a coated component and a coated component |
EP3266607B1 (en) * | 2015-03-04 | 2020-10-07 | Tocalo Co., Ltd. | Fiber-reinforced resin structure and method for producing fiber-reinforced resin structure |
CN104757863B (zh) * | 2015-03-17 | 2016-08-17 | 浙江三禾厨具有限公司 | 等离子不粘锅及其制造方法 |
CN104878357A (zh) * | 2015-06-11 | 2015-09-02 | 桂林理工大学 | 一种碳纤维表面射频磁控溅射制备SiC涂层的方法 |
US10118195B2 (en) | 2016-03-16 | 2018-11-06 | The Boeing Company | Methods for depositing a transparent thin film onto substrates using an atmospheric plasma generating device |
KR102379827B1 (ko) | 2016-07-22 | 2022-03-29 | 럿거스, 더 스테이트 유니버시티 오브 뉴 저지 | 탄소 섬유 및 나노튜브의 폴리머에 원위치(in situ) 결합 |
US11702518B2 (en) | 2016-07-22 | 2023-07-18 | Rutgers, The State University Of New Jersey | In situ bonding of carbon fibers and nanotubes to polymer matrices |
WO2018200053A1 (en) * | 2017-04-26 | 2018-11-01 | Fisher-Barton Inc. | Method of thermal spray coating fiber-reinforced composite materials |
EP3401419B1 (en) * | 2017-05-11 | 2019-07-31 | AIRBUS HELICOPTERS DEUTSCHLAND GmbH | A method of manufacturing a structural arrangement with a fiber reinforced polymer component and a cold gas sprayed electrically conductive layer |
US11306384B2 (en) | 2017-07-10 | 2022-04-19 | ResOps, LLC | Strengthening mechanism for thermally sprayed deposits |
KR102148508B1 (ko) * | 2017-07-26 | 2020-08-26 | 주식회사 엘지화학 | 리튬 전극 및 이의 제조방법 |
CN107761803A (zh) * | 2017-09-21 | 2018-03-06 | 镇江市胜得机械制造有限责任公司 | 用于挖掘机的液压油缸的内衬层 |
US11479653B2 (en) | 2018-01-16 | 2022-10-25 | Rutgers, The State University Of New Jersey | Use of graphene-polymer composites to improve barrier resistance of polymers to liquid and gas permeants |
US11492708B2 (en) * | 2018-01-29 | 2022-11-08 | The Boeing Company | Cold spray metallic coating and methods |
US20190283340A1 (en) * | 2018-03-16 | 2019-09-19 | Hamilton Sundstrand Corporation | Oxygen barrier for composites |
CN110542351B (zh) * | 2018-05-28 | 2022-03-08 | 中国科学院宁波材料技术与工程研究所 | 一种防弹头盔及其制备方法 |
CN110542350B (zh) * | 2018-05-28 | 2022-03-08 | 中国科学院宁波材料技术与工程研究所 | 一种防弹衣甲片及其制备方法 |
US20200040214A1 (en) | 2018-08-01 | 2020-02-06 | The Boeing Company | Thermoplastic Coating Formulations For High-Velocity Sprayer Application and Methods For Applying Same |
US11767436B2 (en) | 2018-08-01 | 2023-09-26 | The Boeing Company | Thermal and cold spray plastic coating covering vehicle fasteners inside fuel tank for lightning strike and other electromagnetic protection |
US11136480B2 (en) * | 2018-08-01 | 2021-10-05 | The Boeing Company | Thermal spray plastic coating for edge sealing and fillet sealing |
RU2702881C1 (ru) * | 2018-09-28 | 2019-10-11 | Общество с ограниченной ответственностью "Научно-производственное объединение "Защитные покрытия", ООО "НПО "Защитные покрытия" | Градиентное металлополимерное покрытие |
DE202018106258U1 (de) | 2018-10-15 | 2020-01-20 | Rutgers, The State University Of New Jersey | Nano-Graphitische Schwämme |
US11591103B2 (en) | 2019-03-28 | 2023-02-28 | The Boeing Company | Multi-layer thermoplastic spray coating system for high performance sealing on airplanes |
US11807757B2 (en) | 2019-05-07 | 2023-11-07 | Rutgers, The State University Of New Jersey | Economical multi-scale reinforced composites |
CN110144599A (zh) * | 2019-05-21 | 2019-08-20 | 华南理工大学 | 一种高效氧析出薄膜电极及其制备方法和应用 |
US11634820B2 (en) | 2019-06-18 | 2023-04-25 | The Boeing Company | Molding composite part with metal layer |
CN111218638B (zh) * | 2020-01-14 | 2020-12-11 | 兰州理工大学 | 一种球阀硬密封面耐磨蚀复合防护涂层及其制备方法 |
CN111455316A (zh) * | 2020-06-03 | 2020-07-28 | 中国科学院兰州化学物理研究所 | 利用磁控溅射技术制备Mo-S-C-N自组装纳米多层薄膜的方法 |
CN111719128B (zh) * | 2020-08-04 | 2021-06-01 | 中国科学院兰州化学物理研究所 | 一种硫代钼酸铵复合多孔非晶碳超滑薄膜的制备方法 |
CN114381683B (zh) * | 2020-10-20 | 2024-04-12 | 中国兵器工业第五九研究所 | 基体防护涂层的制备方法 |
CN113088957B (zh) * | 2021-02-20 | 2022-09-02 | 景德镇明兴航空锻压有限公司 | 一种激光熔覆制备钛合金表面耐磨耐高温涂层的方法 |
CN113002022B (zh) * | 2021-03-25 | 2022-03-08 | 南京工程学院 | 一种纤维增强树脂基复合材料修复方法 |
CN114029216B (zh) * | 2021-10-08 | 2023-08-01 | 北京卫星制造厂有限公司 | 提高无机热控涂层在碳纤维复合材料表面结合强度的方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3136385B2 (ja) | 1993-12-08 | 2001-02-19 | 株式会社日立製作所 | 耐熱耐酸化性高強度部材及びその製造方法 |
FR2752235B3 (fr) * | 1996-08-07 | 1998-08-28 | Saint Gobain Vitrage | Substrat verrier muni d'une couche reflechissante |
JPH11124693A (ja) | 1997-10-20 | 1999-05-11 | Nippon Steel Corp | 精密機器用部材 |
US6221737B1 (en) | 1999-09-30 | 2001-04-24 | Philips Electronics North America Corporation | Method of making semiconductor devices with graded top oxide and graded drift region |
WO2001046324A2 (en) | 1999-10-25 | 2001-06-28 | Rolls-Royce Corporation | Erosion-resistant coatings for organic matrix composites |
FR2800731B1 (fr) * | 1999-11-05 | 2002-01-18 | Saint Gobain Vitrage | Substrat transparent muni d'une couche en derive de silicium |
US6982116B1 (en) | 2000-02-18 | 2006-01-03 | Praxair S.T. Technology, Inc. | Coatings on fiber reinforced composites |
FR2857030B1 (fr) * | 2003-07-01 | 2006-10-27 | Saint Gobain | Procede de depot d'oxyde de titane par source plasma |
US20050118502A1 (en) | 2003-11-27 | 2005-06-02 | Matsushita Electric Industrial Co., Ltd. | Energy device and method for producing the same |
US7700167B2 (en) | 2006-08-31 | 2010-04-20 | Honeywell International Inc. | Erosion-protective coatings on polymer-matrix composites and components incorporating such coated composites |
KR101408510B1 (ko) * | 2007-05-18 | 2014-06-17 | 삼성전자주식회사 | 표시소자용 연성기판 및 이를 이용한 디스플레이 소자 |
DE102008028540A1 (de) * | 2008-06-16 | 2009-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Abscheiden einer Gradientenschicht auf einem Kunststoffsubstrat sowie Kunststoffsubstrat mit einer Gradientenschicht |
US8465812B2 (en) * | 2009-03-23 | 2013-06-18 | The Boeing Company | Durable transparent intelligent coatings for polymeric transparencies |
US10309018B2 (en) * | 2011-05-31 | 2019-06-04 | United Technologies Corporation | Composite article having layer with co-continuous material regions |
-
2012
- 2012-11-16 US US13/679,399 patent/US10060019B2/en active Active
-
2013
- 2013-08-23 CA CA2824830A patent/CA2824830C/en active Active
- 2013-08-23 CA CA2967253A patent/CA2967253C/en active Active
- 2013-09-16 EP EP18173710.7A patent/EP3388544B1/en active Active
- 2013-09-16 EP EP13184586.9A patent/EP2733231B1/en active Active
- 2013-09-16 EP EP18173709.9A patent/EP3388543A1/en active Pending
- 2013-10-30 JP JP2013225975A patent/JP6446175B2/ja active Active
- 2013-11-18 CN CN201310576618.8A patent/CN103819705B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CA2967253A1 (en) | 2014-05-16 |
CN103819705B (zh) | 2018-09-04 |
EP2733231A1 (en) | 2014-05-21 |
CA2824830A1 (en) | 2014-05-16 |
US10060019B2 (en) | 2018-08-28 |
CN103819705A (zh) | 2014-05-28 |
JP2014111364A (ja) | 2014-06-19 |
EP3388544B1 (en) | 2019-12-04 |
EP3388543A1 (en) | 2018-10-17 |
US20140141257A1 (en) | 2014-05-22 |
CA2967253C (en) | 2019-12-03 |
EP3388544A1 (en) | 2018-10-17 |
CA2824830C (en) | 2018-12-04 |
EP2733231B1 (en) | 2018-05-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6446175B2 (ja) | 溶射被覆した強化ポリマー複合材料 | |
Kobayashi et al. | Fe-based metallic glass coatings produced by smart plasma spraying process | |
CN107109626B (zh) | 用于在部件的表面上形成涂层的装置 | |
US20120183790A1 (en) | Thermal spray composite coatings for semiconductor applications | |
Kobayashi et al. | Mechanical property of Fe-base metallic glass coating formed by gas tunnel type plasma spraying | |
JP2012082519A (ja) | 熱遮蔽被覆構造体を製造する方法 | |
EP2591136B1 (en) | Thermally sprayed completely amorphic oxide coating | |
CN106567045A (zh) | 管状旋转高纯硅溅射靶材的制备方法 | |
Wang et al. | Effect of spraying power on oxidation resistance and mechanical properties of plasma sprayed La-Mo-Si coating | |
Shishkovsky et al. | Chemical and physical vapor deposition methods for nanocoatings | |
Kim et al. | Thick tungsten layer coating on ferritic-martensitic steel without interlayer using a DC vacuum plasma spray and a RF low pressure plasma spray method | |
Sharma et al. | Microstructure, mechanical and erosion wear analysis of post heat treated iron alloy based coating with varying chromium | |
CN106011729B (zh) | 一种热喷涂法制备多层涂层的方法 | |
Khandanjou et al. | The investigation of the microstructure behavior of the spray distances and argon gas flow rates effects on the aluminum coating using self-generated atmospheric plasma spray system | |
CN104271793B (zh) | 高表面积涂层 | |
JP4458911B2 (ja) | プラスチックス複合材料およびその製造方法 | |
US20090258214A1 (en) | Vapor-deposited coating and thermally stressable component having such a coating, and also a process and apparatus for producing such a coating | |
JP4975583B2 (ja) | 繊維強化複合材料の製造方法 | |
Xie | Thermal Spray Methods and Splat Formation | |
Kobayashi et al. | Effect of Zr on microstructure of metallic glass coatings prepared by gas tunnel type plasma spraying | |
Kang et al. | Processing and microstructures of tungsten/copper composites produced by plasma spray and cold spray | |
Kobayashi et al. | Properties of fe-base metal glass coatings produced by gas tunnel type plasma spraying | |
Kobayashi et al. | Fe-based Metal Glass Coating Produced by Gas Tunnel Type Plasma Spraying | |
Grigoryev | Surface coating of tungsten carbide by electric exploding of contact | |
Gevelber et al. | Feedback enhanced plasma spray tool |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20161020 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20170801 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170829 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20171129 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20171130 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180403 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180612 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20181127 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20181203 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6446175 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |