JP6310387B2 - 選択的に金属化されたプラスチック部品および対応する製造プロセス - Google Patents
選択的に金属化されたプラスチック部品および対応する製造プロセス Download PDFInfo
- Publication number
- JP6310387B2 JP6310387B2 JP2014517727A JP2014517727A JP6310387B2 JP 6310387 B2 JP6310387 B2 JP 6310387B2 JP 2014517727 A JP2014517727 A JP 2014517727A JP 2014517727 A JP2014517727 A JP 2014517727A JP 6310387 B2 JP6310387 B2 JP 6310387B2
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- JP
- Japan
- Prior art keywords
- plastic
- metallized
- plastic part
- semi
- aromatic polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004033 plastic Substances 0.000 title claims description 57
- 229920003023 plastic Polymers 0.000 title claims description 57
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims description 23
- 229920000515 polycarbonate Polymers 0.000 claims description 20
- 239000004417 polycarbonate Substances 0.000 claims description 20
- 239000004952 Polyamide Substances 0.000 claims description 17
- 229920002647 polyamide Polymers 0.000 claims description 17
- 238000001465 metallisation Methods 0.000 claims description 16
- 229920000728 polyester Polymers 0.000 claims description 14
- 238000009713 electroplating Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- -1 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
- C25D5/56—Electroplating of non-metallic surfaces of plastics
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemically Coating (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Description
− ポリカーボネートと混合され、あるいは混合されない半芳香族ポリエステルから形成される少なくとも1つの第1の部分と、ポリアミドから形成される少なくとも1つの第2の部分とを備えるプラスチック部品を用意する段階と、
− 第2の部分の選択的な金属化を得るためにプラスチック部品を電気めっきする段階と、
を含むプロセスにも関連する。
− ポリカーボネートと混合され、あるいは混合されない半芳香族ポリエステルから形成される少なくとも1つの第1の部分7と、ポリアミドから形成される少なくとも1つの第2の部分9とを備えるプラスチック部品1を用意する段階と、
− 1または複数の第2の部分9の選択的な金属化を得るためにプラスチック部品1を電気めっきする段階と、
を含むプロセスにも関連する。
Claims (7)
- 選択的に金属化されたプラスチック部品(1)であって、
電気めっきによって金属化され得ない第1のプラスチック材料から形成される少なくとも1つの第1の非金属化部分(7)と、
金属化可能な第2のプラスチック材料から形成される少なくとも1つの第2の金属化部分(9)と、
を備え、
前記第1のプラスチック材料は、ポリカーボネート(polycarbonate)と半芳香族ポリエステル(semiaromatic polyester)との混合物であり、前記第2のプラスチック材料はポリアミド(polyamide)であり、
前記第1のプラスチック材料は、ガラスビードタイプのフィラーの付加によって補強されることを特徴とするプラスチック部品(1)。 - 前記半芳香族ポリエステルは、ポリエチレンテレフタレート(polyethylene terephthalate)およびポリブチレンテレフタレート(polybutylene terephthalate)から選択されることを特徴とする請求項1に記載のプラスチック部品(1)。
- 当該プラスチック部品の金属化のために使用される金属化金属はクロム(chromium)であることを特徴とする請求項1又は2のいずれか一項に記載のプラスチック部品(1)。
- 前記プラスチック部品は、自動車のキーのシェルであることを特徴とする請求項1から3のいずれか一項に記載のプラスチック部品(1)。
- 選択的に金属化されたプラスチック部品(1)の製造のためのプロセスであって、以下の段階、すなわち、
ポリカーボネート(polycarbonate)と半芳香族ポリエステル(semiaromatic polyester)との混合物から形成される少なくとも1つの第1の部分(7)と、ポリアミド(polyamide)から形成される少なくとも1つの第2の部分(9)とを備えるプラスチック部品(1)を用意する段階と、
前記第2の部分(9)の選択的な金属化を得るために前記プラスチック部品を電気めっきする段階と、
を含み、
前記ポリカーボネートと前記半芳香族ポリエステルとの前記混合物は、ガラスビードタイプのフィラーの付加によって補強される製造プロセス。 - 前記半芳香族ポリエステルは、ポリエチレンテレフタレート(polyethylene terephthalate)およびポリブチレンテレフタレート(polybutylene terephthalate)から選択されることを特徴とする請求項5に記載の製造プロセス。
- 金属化中に堆積される金属はクロム(chromium)であることを特徴とする請求項5から6のいずれか一項に記載の製造プロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR11/02021 | 2011-06-29 | ||
FR1102021A FR2977254B1 (fr) | 2011-06-29 | 2011-06-29 | Piece plastique a metallisation selective et procede de fabrication correspondant |
PCT/EP2012/062670 WO2013001053A1 (fr) | 2011-06-29 | 2012-06-29 | Piece plastique a metallisation selective et procede de fabrication correspondant |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014524977A JP2014524977A (ja) | 2014-09-25 |
JP6310387B2 true JP6310387B2 (ja) | 2018-04-11 |
Family
ID=46506334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014517727A Active JP6310387B2 (ja) | 2011-06-29 | 2012-06-29 | 選択的に金属化されたプラスチック部品および対応する製造プロセス |
Country Status (5)
Country | Link |
---|---|
US (2) | US20140224659A1 (ja) |
EP (1) | EP2726542B1 (ja) |
JP (1) | JP6310387B2 (ja) |
FR (1) | FR2977254B1 (ja) |
WO (1) | WO2013001053A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3028710B1 (fr) * | 2014-11-13 | 2019-05-31 | Valeo Comfort And Driving Assistance | Procede de realisation de pictogramme et boitier de commande comprenant des pictogrammes |
US10737530B2 (en) * | 2015-05-14 | 2020-08-11 | Lacks Enterprises, Inc. | Two-shot molding for selectively metalizing parts |
DE102021117567A1 (de) | 2021-07-07 | 2023-01-12 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Verfahren zur selektiven Beschichtung von Mehrkomponenten-Kunststoffverbunden und Bauteile aus selektiv beschichteten Mehrkomponenten-Kunststoffverbunden |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4552626A (en) * | 1984-11-19 | 1985-11-12 | Michael Landney, Jr. | Metal plating of polyamide thermoplastics |
JPS6287326U (ja) * | 1985-11-21 | 1987-06-04 | ||
JP2574707B2 (ja) * | 1990-08-09 | 1997-01-22 | ワイケイケイ株式会社 | 金属薄膜を表面に有するフアスナ− |
FI973391A (fi) * | 1997-08-19 | 1999-02-20 | Silitek Corp | Metallivärinen kaksoisväritetty ekstrudoitu muovinäppäin |
JP3958952B2 (ja) * | 2001-11-12 | 2007-08-15 | 三菱レイヨン株式会社 | 電気めっき部品 |
JP4010355B2 (ja) * | 2001-07-16 | 2007-11-21 | ポリマテック株式会社 | 押釦スイッチ用キートップ及びその製造方法 |
JP2004042595A (ja) * | 2002-05-22 | 2004-02-12 | Teijin Chem Ltd | 金属層または金属酸化物層を有する樹脂成形品 |
DE10327453A1 (de) * | 2003-06-18 | 2005-01-27 | Bayer Materialscience Ag | Verbundsysteme zur Herstellung von dekorierten Kunststoffformteilen und ein Verfahren zur Herstellung der Verbundsysteme |
WO2008004315A1 (fr) * | 2006-07-05 | 2008-01-10 | Kakihara Kogyo Co., Ltd. | procédé de production d'objets plaqués de manière décorative en communiquant une électroconductivité à la résine par pulvérisation cathodique |
JP2008098014A (ja) * | 2006-10-12 | 2008-04-24 | Polymatech Co Ltd | 金属調加飾樹脂成形体付きシートの製造方法及び金属調加飾樹脂成形体付きシート |
JP4896703B2 (ja) * | 2006-12-26 | 2012-03-14 | 東海ゴム工業株式会社 | ニッケル電気めっき膜およびその製法 |
JP4160623B2 (ja) * | 2007-02-01 | 2008-10-01 | 日立マクセル株式会社 | ポリマー部材の製造方法及び製造装置 |
WO2009003901A1 (de) * | 2007-07-03 | 2009-01-08 | Basf Se | Verfahren zur metallisierung von polyamidblends |
JP5572287B2 (ja) * | 2007-12-27 | 2014-08-13 | ユーエムジー・エービーエス株式会社 | めっき基材用強化樹脂組成物および成形品、ならびに電気めっき部品 |
-
2011
- 2011-06-29 FR FR1102021A patent/FR2977254B1/fr active Active
-
2012
- 2012-06-29 US US14/126,045 patent/US20140224659A1/en not_active Abandoned
- 2012-06-29 EP EP12733644.4A patent/EP2726542B1/fr active Active
- 2012-06-29 JP JP2014517727A patent/JP6310387B2/ja active Active
- 2012-06-29 WO PCT/EP2012/062670 patent/WO2013001053A1/fr active Application Filing
-
2018
- 2018-03-21 US US15/927,571 patent/US10648098B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2014524977A (ja) | 2014-09-25 |
US10648098B2 (en) | 2020-05-12 |
FR2977254B1 (fr) | 2013-08-30 |
US20140224659A1 (en) | 2014-08-14 |
FR2977254A1 (fr) | 2013-01-04 |
WO2013001053A1 (fr) | 2013-01-03 |
EP2726542A1 (fr) | 2014-05-07 |
EP2726542B1 (fr) | 2015-06-24 |
US20180274117A1 (en) | 2018-09-27 |
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