JP6309018B2 - アミン含有ホモポリマまたはコポリマによるアルケニルコハク酸無水物の乳化 - Google Patents
アミン含有ホモポリマまたはコポリマによるアルケニルコハク酸無水物の乳化 Download PDFInfo
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- JP6309018B2 JP6309018B2 JP2015543087A JP2015543087A JP6309018B2 JP 6309018 B2 JP6309018 B2 JP 6309018B2 JP 2015543087 A JP2015543087 A JP 2015543087A JP 2015543087 A JP2015543087 A JP 2015543087A JP 6309018 B2 JP6309018 B2 JP 6309018B2
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- 229940073608 benzyl chloride Drugs 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- ZTGUNQDGUVVFHL-UHFFFAOYSA-N carboxymethyl-methyl-(2-prop-2-enoyloxyethyl)sulfanium;chloride Chemical compound [Cl-].OC(=O)C[S+](C)CCOC(=O)C=C ZTGUNQDGUVVFHL-UHFFFAOYSA-N 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- ZTUMLBMROBHIIH-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical group ClCC1=CC=CC=C1.CN(C)CCOC(=O)C(C)=C ZTUMLBMROBHIIH-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- IOMDIVZAGXCCAC-UHFFFAOYSA-M diethyl-bis(prop-2-enyl)azanium;chloride Chemical group [Cl-].C=CC[N+](CC)(CC)CC=C IOMDIVZAGXCCAC-UHFFFAOYSA-M 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- JCRDPEHHTDKTGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound Cl.CN(C)CCOC(=O)C(C)=C JCRDPEHHTDKTGB-UHFFFAOYSA-N 0.000 description 1
- CTQCRZPAPNYGJT-UHFFFAOYSA-N dimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical group Cl.CN(C)CCCNC(=O)C(C)=C CTQCRZPAPNYGJT-UHFFFAOYSA-N 0.000 description 1
- LZPKOWNQYHIGGH-UHFFFAOYSA-N dimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;hydrogen sulfate Chemical group OS(O)(=O)=O.CN(C)CCCNC(=O)C(C)=C LZPKOWNQYHIGGH-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PHIAIMNBQOYUSA-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-2-methylprop-2-enamide;methyl hydrogen sulfate Chemical compound COS(O)(=O)=O.CN(C)CCCNC(=O)C(C)=C PHIAIMNBQOYUSA-UHFFFAOYSA-N 0.000 description 1
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical group Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- RZKYDQNMAUSEDZ-UHFFFAOYSA-N prop-2-enylphosphonic acid Chemical compound OP(O)(=O)CC=C RZKYDQNMAUSEDZ-UHFFFAOYSA-N 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
- D21H17/15—Polycarboxylic acids, e.g. maleic acid
- D21H17/16—Addition products thereof with hydrocarbons
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/56—Polyamines; Polyimines; Polyester-imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
- C08J2333/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2339/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
Description
1.DAA/AcAmコポリマによるASA乳化により、典型的な乳化剤に比べて明確に異なる粒子サイズ分布が得られるか?
2.サイジング応答は、DAA/AcAmコポリマによるASA乳化で、典型的な乳化剤に比べて増加するか?
3.DAA/AcAm:ASA比はサイジング応答に影響するか?
Claims (32)
- 製紙プロセスにより製造された紙をサイジングする方法であって、
水中油エマルジョンを前記製紙プロセスに添加する工程を含み、
前記水中油エマルジョンは、少なくとも1つの一級または二級アミンを含有するビニルモノマまたはアリルモノマを含むコポリマにより乳化されたアルケニルコハク酸無水物を含み、
前記コポリマはジアリルアミン−アクリルアミドコポリマであり、前記ジアリルアミン−アクリルアミドコポリマ中のジアリルアミンの含有量は10から40パーセントのモルパーセントである方法。 - 前記少なくとも1つの一級または二級アミンはジアリルアミンを含む二級アミンである、請求項1に記載の方法。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は0.01重量パーセントから40重量パーセントである、請求項1に記載の方法。
- 前記水中油エマルジョン中の前記コポリマは0.001重量パーセントから20重量パーセントである、請求項1に記載の方法。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は8−12重量パーセントであり、前記水中油エマルジョン中の前記コポリマの含有量は1−5重量パーセントである、請求項1に記載の方法。
- 前記添加は、前記製紙プロセスにおいて、ウエットエンド、ヘッドボックス前、ヘッドボックス時、紙に直接、サイズプレス時、およびそれらの任意の組み合わせからなる群より選択される時点で実施される、請求項1に記載の方法。
- 前記添加は、0.01lbから100lbの前記水中油エマルジョン/1トンの乾燥繊維の投与量速度で実施される、請求項1に記載の方法。
- 少なくとも1つの一級または二級アミンを含有するビニルモノマまたはアリルモノマを含むコポリマにより乳化されたアルケニルコハク酸無水物を含む水中油エマルジョンであって、
前記コポリマはジアリルアミン−アクリルアミドコポリマであり、前記ジアリルアミン−アクリルアミドコポリマ中のジアリルアミンの含有量は10から40パーセントのモルパーセントである水中油エマルジョン。 - 前記一級または二級アミンはジアリルアミンを含む、請求項8に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は0.01重量パーセントから40重量パーセントである、請求項8に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記ジアリルアミン−アクリルアミドコポリマの含有量は0.001重量パーセントから20重量パーセントである、請求項8に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は8−12重量パーセントであり、前記水中油エマルジョン中の前記ジアリルアミン−アクリルアミドコポリマの含有量は1−5重量パーセントである、請求項8に記載の水中油エマルジョン。
- 製紙プロセスを処理する方法であって、
水中油エマルジョンを前記製紙プロセスに添加する工程を含み、
前記水中油エマルジョンはジアリルアミン−アクリルアミドコポリマにより乳化されたアルケニルコハク酸無水物を含み、
前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は0.01重量パーセントから40重量パーセントであり、前記水中油エマルジョン中の前記ジアリルアミン−アクリルアミドコポリマの含有量は0.001重量パーセントから20重量パーセントであり、
前記ジアリルアミン−アクリルアミドコポリマ中のジアリルアミンの含有量は10から40パーセントのモルパーセントである方法。 - 製紙プロセスにより製造された紙をサイジングする方法であって、
水中油エマルジョンを前記製紙プロセスに添加する工程を含み、
前記水中油エマルジョンは少なくとも1つのアミンを含有するビニルモノマまたはアリルモノマを含むポリマであって当該ポリマの残りがアクリルアミド、メタクリルアミド、N,N−ジメチルアクリルアミド、N,N−ジエチルアクリルアミド、N−イソプロピルアクリルアミド、N−ビニルホルムアミド、N−ビニルメチルアセトアミド、N−ビニルピロリドン、ヒドロキシエチルメタクリレート、ヒドロキシエチルアクリレート、ヒドロキシプロピルアクリレート、ヒドロキシプロピルメタクリレート、N−t−ブチルアクリルアミド、N−メチロールアクリルアミド、酢酸ビニル、ビニルアルコール、およびそれらの組み合わせからなる群より選択される非イオン性モノマを含むポリマにより乳化されたアルケニルコハク酸無水物を含み、
前記ポリマ中の少なくとも1つのアミンを含有するビニルモノマまたはアリルモノマの含有量は10モルパーセントから60モルパーセントであり、
前記水中油エマルジョンは0.01μmから10μmの範囲のエマルジョン粒子サイズを有し、
前記少なくとも1つのアミンを含有するビニルモノマまたはアリルモノマが塩の形態であり、以下からなる群より選択される構造を有し、
- 前記ポリマが加水分解されている、請求項14に記載の方法。
- 前記ポリマおよび前記アルケニルコハク酸無水物はアルケニルコハク酸無水物10部当たりポリマ1部から5部の範囲の重量比で前記水中油エマルジョン中に存在する、請求項14に記載の方法。
- 前記ポリマおよび前記アルケニルコハク酸無水物はアルケニルコハク酸無水物100部当たりポリマ28部から32部の範囲のポリマ対アルケニルコハク酸無水物比で前記水中油エマルジョン中に存在する、請求項14に記載の方法。
- 前記水中油エマルジョンは乾燥繊維1トン当たり水中油エマルジョン0.01ポンドから100ポンドの範囲の速度で前記製紙プロセスに投与される、請求項14に記載の方法。
- カチオン剤を前記製紙プロセスに添加する工程をさらに含む、請求項14に記載の方法。
- 前記カチオン剤はミョウバン、塩化アルミニウム、ポリ塩化アルミニウム、長鎖脂肪族アミン、アルミン酸ナトリウム、置換ポリアクリルアミド、硫酸第二クロム、動物性にかわ、カチオン性熱硬化性樹脂、ポリアミドポリマ、アミンを含有するデンプン誘導体、およびそれらの組み合わせからなる群より選択される、請求項20に記載の方法。
- 前記水中油エマルジョンは混合チャンバを介して前記製紙プロセスに添加される、請求項14に記載の方法。
- 前記水中油エマルジョンは乾燥繊維1トン当たり水中油エマルジョン0.25ポンドから20ポンドの範囲の速度で前記製紙プロセスに投与される、請求項14に記載の方法。
- 前記水中油エマルジョンは乾燥繊維1トン当たり水中油エマルジョン1ポンドから4ポンドの範囲の速度で前記製紙プロセスに投与される、請求項14に記載の方法。
- ジアリルアミンと、アクリルアミド、メタクリルアミド、N,N−ジメチルアクリルアミド、N,N−ジエチルアクリルアミド、N−イソプロピルアクリルアミド、N−ビニルホルムアミド、N−ビニルメチルアセトアミド、N−ビニルピロリドン、ヒドロキシエチルメタクリレート、ヒドロキシエチルアクリレート、ヒドロキシプロピルアクリレート、ヒドロキシプロピルメタクリレート、N−t−ブチルアクリルアミド、N−メチロールアクリルアミド、酢酸ビニル、ビニルアルコール、およびそれらの組み合わせからなる群より選択される非イオン性モノマと、からなるポリマにより乳化されたアルケニルコハク酸無水物を含む水中油エマルジョンであって、
前記ポリマ中のジアリルアミンの含有量は10モルパーセントから60モルパーセントであり、
0.01μmから10μmの範囲のエマルジョン粒子サイズを有し、
前記ポリマ中のジアリルアミンの含有量は10から40パーセントのモルパーセントである水中油エマルジョン。 - 前記アルケニルコハク酸無水物10重量部当たり1重量部から5重量部の前記ポリマが前記水中油エマルジョン中に存在する、請求項25に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は8重量パーセントから12重量パーセントである、請求項25に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記ポリマの含有量は1重量パーセントから5重量パーセントである、請求項25に記載の水中油エマルジョン。
- 前記水中油エマルジョン中の前記アルケニルコハク酸無水物の含有量は8重量パーセントから12重量パーセントであり、前記水中油エマルジョン中の前記ポリマの含有量は1重量パーセントから5重量パーセントである、請求項25に記載の水中油エマルジョン。
- 製紙プロセスにより製造された紙をサイジングする方法であって、
請求項25に記載の水中油エマルジョンを前記製紙プロセスに添加する工程を含む、方法。 - 前記製紙プロセスは飲料容器として用いるのに適した製品を製造する、請求項30に記載の方法。
- 前記水中油エマルジョンは混合チャンバを介して前記製紙プロセスに添加される、請求項30に記載の方法。
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