JP6279610B2 - 熱膨張性耐火樹脂組成物 - Google Patents
熱膨張性耐火樹脂組成物 Download PDFInfo
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- JP6279610B2 JP6279610B2 JP2015548521A JP2015548521A JP6279610B2 JP 6279610 B2 JP6279610 B2 JP 6279610B2 JP 2015548521 A JP2015548521 A JP 2015548521A JP 2015548521 A JP2015548521 A JP 2015548521A JP 6279610 B2 JP6279610 B2 JP 6279610B2
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Images
Classifications
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Description
本願は、2014年8月27日に出願した特願2014-173016号明細書の優先権の利益を主張するものであり、当該明細書はその全体が参照により本明細書中に援用される。
(技術分野)
本発明は、熱膨張性耐火樹脂組成物に関する。
項1.樹脂成分100重量部、熱膨張性黒鉛10〜300重量部、及び無機充填剤2〜200重量部を含有し、熱膨張性黒鉛の平均アスペクト比が20以上であり、熱膨張性黒鉛の平均粒径が100〜1000μmの範囲にあり、かつ平均厚さが50μm以下であり、樹脂成分がポリ塩化ビニル及び/又は塩素化塩化ビニルを含む、ことを特徴とする熱膨張性耐火樹脂組成物。
項2.リン化合物(燐酸エステル可塑剤を除く。)を含有しないことを特徴とする項1に記載の熱膨張性耐火樹脂組成物
項3.項1又は2に記載の熱膨張性耐火樹脂組成物を備えた耐火部材。
項4.項3に記載の耐火部材を備えた建具。
トリフェニルホスフェート、トリクレジルホスフェート、トリキシレニルホスフェート、クレジルジフェニルホスフェート、キシレニルジフェニルホスフェート等の各種リン酸エステル、
リン酸ナトリウム、リン酸カリウム、リン酸マグネシウム等のリン酸金属塩、
ポリリン酸アンモニウム類、
下記化学式(1)で表される化合物等が挙げられる。
R2は、水酸基、炭素数1〜16の直鎖状若しくは分岐状のアルキル基、炭素数1〜16の直鎖状若しくは分岐状のアルコキシル基、炭素数6〜16のアリール基、又は、炭素数6〜16のアリールオキシ基を表す。
アスペクト比
熱膨張性黒鉛として、ADT社製「ADT501」を実施例1、日本黒鉛工業社製「EXP50T」を実施例2、東ソ一社製「GREP−EG」(膨張開始温度220℃)を比較例1とし、各熱膨張性黒鉛のアスペクト比と、各熱膨張性黒鉛を表1に示した組成で配合した。
(成形性)
実施例1,2及び比較例1のいずれとも、表面が美麗な長尺異型成形体を2時間押出成形でき、2時間押出成形した後のスクリュー及び金型への配合物の付着もなく、成形性は良好であった。
(膨張倍率)
得られた成形体から作製した試験片(長さ100mm、幅100mm、厚さ2.0mm)を電気炉に供給し、600℃で30分間加熱した後、試験片の厚さを測定し、(加熱後の試験片の厚さ)/(加熱前の試験片の厚さ)を膨張倍率として算出した。
(残渣硬さ)
膨張倍率を測定した加熱後の試験片を圧縮試験機(カトーテック社製、「フィンガーフイリングテスター」)に供給し、0.25cm2の圧子で0.1cm/秒の速度で圧縮し、破断点応力を測定した。
(残渣の形状保持性)
上記残渣硬さは膨張後の残渣の硬さの指標になるが、測定が残渣の表面部分に限られるため、残渣全体の硬さの指標にならないことがあるので、残渣全体の硬さの指標として形状保持性を測定した。残渣の形状保持性は、膨張倍率を測定した試験片の両端部を手で持って持ち上げて、その際の残渣の崩れやすさを目視して測定した、試験片が崩れることなく持ち上げられた場合をPASSと評価し、試験片が崩壊して持ち上げられない場合をFAILと評価した。
表2に示した配合の成分を含有する配合物を、実施例1〜2および比較例1に関して上記に記載したのと同様に一軸押出機に供給し、150℃で断面形状がE字状の長尺異型成形体を1m/hrの速度で2時間押出成形した。
(成形性)
実施例3〜22のいずれとも、表面が美麗な長尺異型成形体を2時間押出成形でき、2時間押出成形した後のスクリュー及び金型への配合物の付着もなく、成形性は良好であった。
(膨張倍率)
得られた成形体から作製した試験片(長さ100mm、幅100mm、厚さ2.0mm)を電気炉に供給し、600℃で30分間加熱した後、試験片の厚さを測定し、(加熱後の試験片の厚さ)/(加熱前の試験片の厚さ)を膨張倍率として算出した。
(残渣硬さ)
膨張倍率を測定した加熱後の試験片を圧縮試験機(カトーテック社製、「フィンガーフイリングテスター」)に供給し、0.25cm2の圧子で0.1cm/秒の速度で圧縮し、破断点応力を測定した。
(残渣の形状保持性)
上記残渣硬さは膨張後の残渣の硬さの指標になるが、測定が残渣の表面部分に限られるため、残渣全体の硬さの指標にならないことがあるので、残渣全体の硬さの指標として形状保持性を測定した。残渣の形状保持性は、膨張倍率を測定した試験片の両端部を手で持って持ち上げて、その際の残渣の崩れやすさを目視して測定した、試験片が崩れることなく持ち上げられた場合をPASSと評価し、試験片が崩壊して持ち上げられない場合をFAILと評価した。
Claims (4)
- 樹脂成分100重量部、熱膨張性黒鉛10〜300重量部、及び無機充填剤2〜200重量部を含有し、熱膨張性黒鉛の平均アスペクト比が20以上であり、
熱膨張性黒鉛の平均粒径が100〜1000μmの範囲にあり、かつ平均厚さが50μm以下であり、
樹脂成分がポリ塩化ビニル及び/又は塩素化塩化ビニルを含む、
ことを特徴とする熱膨張性耐火樹脂組成物。 - リン化合物(燐酸エステル可塑剤を除く。)を含有しないことを特徴とする請求項1に記載の熱膨張性耐火樹脂組成物。
- 請求項1又は2に記載の熱膨張性耐火樹脂組成物を備えた耐火部材。
- 請求項3に記載の耐火部材を備えた建具。
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