JP6278361B2 - 両面型偏光板及びこれを含む光学装置 - Google Patents
両面型偏光板及びこれを含む光学装置 Download PDFInfo
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- JP6278361B2 JP6278361B2 JP2015201402A JP2015201402A JP6278361B2 JP 6278361 B2 JP6278361 B2 JP 6278361B2 JP 2015201402 A JP2015201402 A JP 2015201402A JP 2015201402 A JP2015201402 A JP 2015201402A JP 6278361 B2 JP6278361 B2 JP 6278361B2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
- G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
-
- G02B1/105—
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
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Description
Si(R1)n(R2)4−n
ポリ(N−シクロヘキシルマレイミド−co−メチルメタクリレート)、スチレン−無水マレイン酸共重合体樹脂及びフェノキシ系樹脂を100:2.5:5の重量比で均一に混合した樹脂組成物を、原料ホッパー(hopper)から押出機までを窒素置換した24Φ押出機に供給し、250℃で溶融して原料ペレット(pellet)を製造した。
上記のような過程により製造されたアクリルフィルムをコロナ処理した後、上記アクリルフィルムの一面に、CK−PUD−F(Chokwang、ウレタン分散液)を純水で希釈して製造された固形分含量10重量%のプライマー組成物にカルボジイミド系架橋剤(日清紡社製、カルボジライトSV−02)10重量部を添加したプライマー組成物を、#7バーでコートした後、TD方向に130℃でテンターを用いて190%延伸し、プライマー層の厚さが400nmであるアクリルフィルム(A)を製造した。
製造例1の(1)により製造されたアクリルフィルムをコロナ処理した後、CK−PUD−F(Chokwang、ウレタン分散液)を純水で希釈して製造された固形分含量10重量%のプライマー組成物にカルボジイミド系架橋剤(日清紡社製、カルボジライトSV−02)20重量部を添加したプライマー組成物を、その上に#7バーでコートした後、TD方向に130℃でテンターを用いて190%延伸し、プライマー層の厚さが400nmであるアクリルフィルム(B)を製造した。
(1)接着剤組成物A
3,4−エポキシシクロへキシルメチル−3,4'−エポキシシクロへキサンカルボン酸25重量%(Dicel社のCelloxide 2021P)、1,4−シクロヘキサンジメタノールジグリシジルエーテル25重量%、3−エチル−3−[(3−エチルオキセタン−3−イル)メトキシメチル]オキセタン(東亞合成株式会社のアロンオキセタンDOX221)35重量%及び3−エチル−3−ヒドロキシメチルオキセタン(東亞合成株式会社のアロンオキセタンOXA)15重量を入れて製造した樹脂組成物100重量部に、カチオン開始剤であるCPI 100P(Sanapro社)5重量部を添加して偏光板用接着剤組成物Aを製造した。
3,4−エポキシシクロへキシルメチル−3,4'−エポキシシクロへキサンカルボン酸25重量%(Dicel社のCelloxide 2021P)、1,4−シクロヘキサンジメタノールジグリシジルエーテル25重量%、3−エチル−3−[(3−エチルオキセタン−3−イル)メトキシメチル]オキセタン(東亞合成株式会社のアロンオキセタンDOX221)50重量を入れて製造した樹脂組成物100重量部に、カチオン開始剤であるCPI 100P(Sanapro社)5重量部、ビニルトリエチルシラン5重量部を添加して偏光板用接着剤組成物Bを製造した。
3,4−エポキシシクロへキシルメチル−3,4'−エポキシシクロへキサンカルボン酸25重量%(Dicel社のCelloxide 2021P)、1,4−シクロヘキサンジメタノールジグリシジルエーテル25重量%、3−エチル−3−[(3−エチルオキセタン−3−イル)メトキシメチル]オキセタン(東亞合成株式会社のアロンオキセタンDOX221)50重量を入れて製造した樹脂組成物100重量部に、カチオン開始剤であるCPI 100P(Sanapro社)5重量部、ビニルアセテート5重量部を添加して偏光板用接着剤組成物Cを製造した。
マイクログラビアコーターを用いて上記製造例1により製造されたアクリルフィルム(A)2枚のプライマー層上に接着剤組成物Aを最終接着剤層の厚さが1μmになるよう夫々塗布した。その後、接着剤組成物が塗布された2枚のアクリルフィルム(A)をPVA素子の両面にラミネートし、UV照射装置(Metal halide lamp)を用いて、PVA素子の片面の方向から500mJ/cm2の紫外線を照射して偏光板を製造した。
接着剤組成物としてBを用いたことを除き、実施例1と同様の方法で偏光板を製造した。
接着剤組成物としてCを用いたことを除き、実施例1と同様の方法で偏光板を製造した。
接着剤層の厚さを3μmにコーティングすることを除き、実施例1と同様の方法で偏光板を製造した。
接着剤層の厚さを3μmにコーティングすることを除き、実施例2と同様の方法で偏光板を製造した。
接着剤層の厚さを3μmにコーティングすることを除き、実施例3と同様の方法で偏光板を製造した。
上記製造例1により製造されたアクリルフィルム(A)のプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが1μmになるようコーティングした(以下、アクリルフィルム(A−1)とする)。また、上記製造例1により製造されたアクリルフィルム(A)のプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが3μmになるようコーティングした(以下、アクリルフィルム(A−2)とする)。上記アクリルフィルム(A−1)とアクリルフィルム(A−2)をPVA素子の両面にラミネートし、UV照射装置(Metal halide lamp)を用いて、アクリルフィルム(A−2)が積層された面に500mJ/cm2の紫外線を照射して偏光板を製造した。
上記製造例1により製造されたアクリルフィルム(A)のプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが3μmになるようコーティングした(以下、アクリルフィルム(A−3)とする)。また、上記製造例1により製造されたアクリルフィルム(A)のプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが10μmになるようコーティングした(以下、アクリルフィルム(A−4)とする)。上記アクリルフィルム(A−3)とアクリルフィルム(A−4)をPVA素子の両面にラミネートし、UV照射装置(Metal halide lamp)を用いて、アクリルフィルム(A−4)が積層された面に500mJ/cm2の紫外線を照射して偏光板を製造した。
上記製造例1により製造されたアクリルフィルム(B)のプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが1μmになるようコーティングした(以下、アクリルフィルム(B−1)とする)。また、上記製造例1により製造されたアクリルフィルムのプライマー層上にマイクログラビアコーターを用いて接着剤組成物Aを最終接着剤層の厚さが3μmになるようコーティングした(以下、アクリルフィルム(B−2)とする)。上記アクリルフィルム(B−1)とアクリルフィルム(B−2)をPVA素子の両面にラミネートし、UV照射装置(Metal halide lamp)を用いて、アクリルフィルム(B−2)が積層された面に500mJ/cm2の紫外線を照射して偏光板を製造した。
接着剤層の厚さを5μmにコーティングすることを除き、実施例1と同様の方法で偏光板を製造した。
接着剤層の厚さを5μmにコーティングすることを除き、実施例2と同様の方法で偏光板を製造した。
接着剤層の厚さを5μmにコーティングすることを除き、実施例3と同様の方法で偏光板を製造した。
実施例1〜9及び比較例1〜3により製造された偏光板に対し、第1接着剤層の剥離力を測定した。剥離力は幅20mm、長さ100mmの偏光板を用いて、PVA素子と紫外線非照射面のアクリルフィルムを速度300mm/min、90度で剥離した時の剥離力で測定した。その結果を下表1に示した。剥離力が2N/cmを超える場合をOK、2N/cm以下の場合をNGと表示した。
上記実施例1〜9及び比較例1〜3の偏光板をガラス基板にラミネーション(glass lamination)した後、60℃の恒温槽に浸漬させた。8時間経過後、偏光板の端部の脱色有無で耐水性を判断し、変更のない場合をOK、脱色が生じた場合をNGと表示した。
実施例1〜9及び比較例1〜3により製造された偏光板をガラス基板にラミネーション(glass lamination)し、これを−40℃で30分間放置した後、再び80℃で30分間放置することを100回繰り返して行った。それから、偏光板の外観の変形有無を目視で評価した。偏光板の外観の変形がない場合をOK、クラックが発生した場合をNGと表示した。その結果は下表2に示した。
Claims (4)
- 偏光子、前記偏光子の一面に形成される第1接着剤層、前記偏光子の他面に形成される第2接着剤層、前記第1接着剤層上に形成される第1透明フィルム、及び、前記第2接着剤層上に形成される第2透明フィルムを含む両面型偏光板であって、
前記第1接着剤層及び前記第2接着剤層は活性エネルギー線硬化型接着剤により形成され、
前記第1接着剤層の厚さが0.1〜3μmであり
前記第2接着剤層の厚さが0.1〜10μmであり、
活性エネルギー線硬化型接着剤は、(1)分子内に少なくとも2つのエポキシ基を有するエポキシ化合物5〜90重量部;(2)分子内に少なくとも1つのオキセタニル基を有するオキセタン化合物5〜90重量部;及び(3)光カチオン性重合開始剤0.5〜20重量部を含むカチオン性接着剤であり、
前記エポキシ化合物は、エポキシ化脂肪族環基を1つ以上含む第1エポキシ化合物及びグリシジルエーテル基を1つ以上含む第2エポキシ化合物の組み合わせであり、
前記第1エポキシ化合物と前記第2エポキシ化合物は、1:1〜3:1の重量比で混合され、
前記活性エネルギー線硬化型接着剤は、15〜50cPの範囲の粘度を有するか、または、前記活性エネルギー線硬化型接着剤は、硬化後において90℃以上のガラス転移温度を有し、
前記両面型偏光板は、前記第1接着剤層と前記第1透明フィルムとの間、及び前記第2接着剤層と前記第2透明フィルムとの間のうち少なくとも1つにプライマー層をさらに含み、
前記プライマー層は、1〜50重量部のウレタン高分子、0.1〜10重量部の水分散性微粒子及び残部の水を含むプライマー組成物により形成され、
前記プライマー組成物は、0.1〜30重量部の架橋剤をさらに含み、
前記架橋剤は、オキサゾリン、ホウ酸、トリメチロールメラミン、カルボジイミド、イソシアネート、及び、アジリジン化合物からなる群から選択され、
前記第2エポキシ化合物は、1,4−シクロへキサンジメタノールジグリシジルエーテルであり、
前記カチオン性接着剤は、ビニル系化合物をさらに含む、
両面型偏光板。 - 前記プライマー層はその厚さが100nm〜1μmである、
請求項1に記載の両面型偏光板。 - 前記第1透明フィルム及び前記第2透明フィルムのうち少なくとも1つはアクリル系フィルムである、
請求項1又は請求項2に記載の両面型偏光板。 - 請求項1から請求項3までの何れか1項に記載の両面型偏光板を含む、
光学装置。
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US9523792B2 (en) * | 2011-10-14 | 2016-12-20 | Lg Chem, Ltd. | Polarizer having protection films in two sides and optical device comprising the same |
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KR101482406B1 (ko) * | 2012-05-30 | 2015-01-14 | 주식회사 엘지화학 | 수계 프라이머 조성물, 이를 포함하는 광학필름, 이를 이용한 편광판 및 액정표시장치 |
KR101462579B1 (ko) * | 2013-02-06 | 2014-11-18 | 동우 화인켐 주식회사 | 편광판 및 이를 포함하는 액정표시장치 |
KR101685252B1 (ko) * | 2013-06-18 | 2016-12-20 | 주식회사 엘지화학 | 편광판 및 이를 포함하는 화상표시장치 |
KR101503216B1 (ko) * | 2013-06-18 | 2015-03-17 | 주식회사 엘지화학 | 라디칼 경화형 접착제 조성물 및 이를 포함하는 편광판 |
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