JP5861548B2 - 感熱記録体 - Google Patents
感熱記録体 Download PDFInfo
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- JP5861548B2 JP5861548B2 JP2012085275A JP2012085275A JP5861548B2 JP 5861548 B2 JP5861548 B2 JP 5861548B2 JP 2012085275 A JP2012085275 A JP 2012085275A JP 2012085275 A JP2012085275 A JP 2012085275A JP 5861548 B2 JP5861548 B2 JP 5861548B2
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- 238000004873 anchoring Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- BPLKDVGMXNZCQO-UHFFFAOYSA-N benzyl 4-phenylmethoxybenzoate Chemical compound C=1C=C(OCC=2C=CC=CC=2)C=CC=1C(=O)OCC1=CC=CC=C1 BPLKDVGMXNZCQO-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- ZUOTXZHOGPQFIU-UHFFFAOYSA-N butan-2-yl 4-hydroxybenzoate Chemical compound CCC(C)OC(=O)C1=CC=C(O)C=C1 ZUOTXZHOGPQFIU-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- OYQYHJRSHHYEIG-UHFFFAOYSA-N ethyl carbamate;urea Chemical class NC(N)=O.CCOC(N)=O OYQYHJRSHHYEIG-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LZXGBBYVBJFKEL-UHFFFAOYSA-N heptatriacontanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O LZXGBBYVBJFKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- ZSYJMXLJNPEAGP-UHFFFAOYSA-N methyl n-cyanocarbamate Chemical compound COC(=O)NC#N ZSYJMXLJNPEAGP-UHFFFAOYSA-N 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- RQAQWBFHPMSXKR-UHFFFAOYSA-N n-(4-chlorophenyl)-3-(phosphonooxy)naphthalene-2-carboxamide Chemical compound OP(O)(=O)OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=C(Cl)C=C1 RQAQWBFHPMSXKR-UHFFFAOYSA-N 0.000 description 1
- MJGLMEMIYDUEHA-UHFFFAOYSA-N n-(4-methylphenyl)-3-oxobutanamide Chemical compound CC(=O)CC(=O)NC1=CC=C(C)C=C1 MJGLMEMIYDUEHA-UHFFFAOYSA-N 0.000 description 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- 125000002004 n-butylamino group Chemical group [H]N(*)C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DVVFBRPYROBXHJ-UHFFFAOYSA-N n-octadecanoylbenzamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC(=O)C1=CC=CC=C1 DVVFBRPYROBXHJ-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- WGOROJDSDNILMB-UHFFFAOYSA-N octatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O WGOROJDSDNILMB-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical group C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- QHDYIMWKSCJTIM-UHFFFAOYSA-N phenyl 1-hydroxynaphthalene-2-carboxylate Chemical compound C1=CC2=CC=CC=C2C(O)=C1C(=O)OC1=CC=CC=C1 QHDYIMWKSCJTIM-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940050271 potassium alum Drugs 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JVFFWGJAAQAIBS-UHFFFAOYSA-K trisodium 2,2-dioctyl-3-sulfonatobutanedioate Chemical compound [Na+].C(CCCCCCC)C(C(C(=O)[O-])S(=O)(=O)[O-])(C(=O)[O-])CCCCCCCC.[Na+].[Na+] JVFFWGJAAQAIBS-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229920003170 water-soluble synthetic polymer Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Description
・ロイコ染料分散液(A液)の調製
3−ジ(n−ブチル)アミノ−6−メチル−7−アニリノフルオラン100部、鹸化度60モル%、重合度200のポリビニルアルコールの20%水溶液50部、及び水100部からなる組成物を、サンドミルによりレーザ回折式粒度分布測定装置SALD2200(島津製作所社製)によるメジアン径が0.5μmとなるように処理してロイコ染料分散液を得た。得られたロイコ染料分散液を、以下、A液ともいう。
N−p−トルエンスルホニル−N’−3−(p−トルエンスルホニルオキシ)フェニルウレア100部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、日本合成化学社製)の20%水溶液50部、及び水100部からなる組成物を、サンドミルによりレーザ回折式粒度分布測定装置SALD2200(島津製作所社製)によるメジアン径が1.0μmとなるように処理して顕色剤分散液を得た。得られた顕色剤分散液を、以下、B液ともいう。
1,2−ジ(3−メチルフェノキシ)エタン100部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、前出)の20%水溶液50部、及び水100部からなる組成物を、サンドミルによりレーザ回折式粒度分布測定装置SALD2200(島津製作所社製)によるメジアン径が1.0μmとなるように処理して増感剤分散液を得た。得られた増感剤分散液を、以下、C液ともいう。
A液30部、B液80部、C液40部、微粒子無定形シリカ(商品名:Nipsil E−743、東ソー・シリカ社製)4.5部、スチレン−ブタジエン系ラテックス(商品名:スマーテックスPA−9281、固形分濃度48%、日本A&L社製)40部、オレフィン−アクリル酸系共重合体塩(商品名:ハイテックS−3121、エチレン−アクリル酸共重合体アンモニア塩の水性ディスパージョン、固形分濃度25%、東邦化学工業株式会社製)25部、ジオクチルスルホコハク酸ナトリウム塩の10%水溶液0.5部、アジピン酸ジヒドラジド0.5部、及び水100部からなる組成物を混合して感熱記録層用塗液を得た。
カオリン〔商品名:UW−90(登録商標)、BASF社製〕50部、微粒子無定形シリカ(商品名:ミズカシールP−527、水澤化学工業社製)4部、ポリアクリル酸ナトリウムの40%水溶液(商品名:アロンT−50、東亞合成社製)0.4部、及び水80部からなる組成物を混合し、カオリン分散液を得た。得られたカオリン分散液を、以下、D液ともいう。
D液135部、アセトアセチル変性ポリビニルアルコール(商品名:ゴーセファイマーZ−200、重合度1000、日本合成化学工業社製)の10%水溶液250部、ステアリン酸亜鉛水分散液(商品名:ハイドリンZ−8−36、固形分濃度36%、中京油脂社製)20部、アイオノマー型ウレタン系樹脂ラテックス〔商品名:ハイドラン(登録商標)AP−30F、DIC社製、固形分濃度20%〕45部、ジオクチルスルホコハク酸ナトリウム塩の10%水溶液0.5部からなる組成物を混合して保護層用塗液を得た。
ポリオレフィン系樹脂と炭酸カルシウムを加熱混練して、ダイから押し出し、縦方向に延伸したものの両面にポリオレフィン系樹脂と炭酸カルシウムからなるフィルムを積層し、横方向に延伸して不透明化して製造される合成紙(商品名:ユポFPG95、紙厚95μm、ユポコーポレーション社製)の一方の面に、感熱記録層用塗液を乾燥後の重量が5.0g/m2となるように塗布及び乾燥して感熱記録層を形成し、その上に保護層用塗液を乾燥後の重量が2.5g/m2となるように塗布及び乾燥して保護層を形成した後、スーパーキャレンダーを施し、感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、オレフィン−アクリル酸系共重合体塩の量を25部に代えて14部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、スチレン−ブタジエン系ラテックスの量を40部に代えて24部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、スチレン−ブタジエン系ラテックスの量を40部に代えて100部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、オレフィン−アクリル酸系共重合体塩の量を25部に代えて100部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、オレフィン−アクリル酸系共重合体塩の量を25部に代えて5部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、スチレン−ブタジエン系ラテックスの量を40部に代えて30部とし、オレフィン−アクリル酸系共重合体塩の量を25部に代えて50部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の保護層用塗液の調製において、アセトアセチル変性ポリビニルアルコールの10%水溶液の代わりに、完全鹸化ポリビニルアルコール(商品名:PVA−110、重合度1000、クラレ社製)の10%水溶液を用いた以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、スチレン−ブタジエン系ラテックスの量を40部に代えて70部とし、オレフィン−アクリル酸系共重合体塩の量を25部に代えて80部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗料の調製において、オレフィン−アクリル酸系共重合体塩を使用しなかった以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗料の調製において、オレフィン−アクリル酸系共重合体塩の量を25部に代えて80部とし、スチレン−ブタジエン系ラテックスを使用しなかった以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、オレフィン−アクリル酸系共重合体塩の代わりに、スチレン−アクリル系樹脂エマルジョン(商品名:ジョンクリル537J、酸価:40、Tg:49℃、固形分濃度46%、BASFジャパン株式会社製)13部を用いた以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録層用塗液の調製において、スチレン−ブタジエン系ラテックスの代わりに、スチレン−アクリル系樹脂エマルジョン(商品名:ジョンクリル537J、酸価:40、Tg:49℃、固形分濃度46%、BASFジャパン株式会社製)42部を用いた以外は、実施例1と同様にして感熱記録体を得た。
感熱記録評価機(商品名:TH−PMD、大倉電機社製)を用いて、印加エネルギー0.34mJ/ドットにて各感熱記録体を印字し、記録部の光学濃度(記録濃度)をマクベス濃度計(商品名:RD−914型、マクベス社)のビジュアルモードで測定した。数値が大きい程、印字の濃度が濃く、発色性に優れていることを示しており、記録濃度1.20以上であれば問題のないレベルであり、1.30以上であれば極めて優れたレベルである。
10cm×5cmの感熱記録体の保護層面上に水を一滴(約30μl)垂らし、その上に指で保護層面を擦り、擦った回数と目視により下記の基準で評価した。
◎:30回でも感熱記録層が全く溶け出さない。
○:30回で僅かに感熱記録層が溶け出すが、実用上の問題はない。
×:20回で感熱記録層が溶け出し、実用上、問題である。
感熱記録体の保護層面上に水を一滴(約30μl)垂らし、その上に別の一枚の感熱記録体の保護層面を重ねて置き、更に直径5cmの円柱の真鍮製錘(9.8N)を載せ、3日後に錘を外し、保護層面同士を剥離させて、下記の基準で評価した。
◎:殆ど抵抗無く剥離する。
○:やや抵抗があるものの感熱記録層の剥離はなく、実用上の問題はない。
×:一部の感熱記録層が剥離し、実用上、問題である。
保護層上に粘着セロハンテープを100g/cm2の圧力で貼り付け、30m/分の速度で剥がし、感熱記録層の支持体からの剥がれの程度を目視により下記の基準で評価した。
◎:感熱記録層が剥がれない。
○:感熱記録層が少し剥がれる。
△:感熱記録層が大部分剥がれる。
×:感熱記録層が完全に剥がれる。
Claims (5)
- 合成紙または合成樹脂フィルムからなる支持体上に、ロイコ染料、顕色剤及び接着剤を含有する感熱記録層を備えた感熱記録体において、感熱記録層が接着剤としてオレフィン−アクリル酸系共重合体塩及びスチレン−ブタジエン系ラテックスを含有し、前記感熱記録層の全固形量中、前記オレフィン−アクリル酸系共重合体塩の含有割合が4.0〜25質量%であり、前記スチレン−ブタジエン系ラテックスの含有割合が15.0〜40質量%であることを特徴とする感熱記録体。
- 前記オレフィン−アクリル酸系共重合体塩の含有量が前記スチレン−ブタジエン系ラテックス100質量部に対して10〜150質量部である、請求項1に記載の感熱記録体。
- 前記オレフィン−アクリル酸系共重合体塩及びスチレン−ブタジエン系ラテックスの含有割合の合計が感熱記録層の全固形量中25〜50質量%である、請求項1または2のいずれか1項に記載の感熱記録体。
- 前記合成紙または合成樹脂フィルムからなる支持体がポリオレフィン系樹脂を含む支持体である、請求項1〜3のいずれか1項に記載の感熱記録体。
- 前記感熱記録層上に接着剤としてアセトアセチル変性ポリビニルアルコールを含有する保護層を備えた、請求項1〜4のいずれか1項に記載の感熱記録体。
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