JP5675356B2 - 車両用透明物 - Google Patents
車両用透明物 Download PDFInfo
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- JP5675356B2 JP5675356B2 JP2010522011A JP2010522011A JP5675356B2 JP 5675356 B2 JP5675356 B2 JP 5675356B2 JP 2010522011 A JP2010522011 A JP 2010522011A JP 2010522011 A JP2010522011 A JP 2010522011A JP 5675356 B2 JP5675356 B2 JP 5675356B2
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 99
- 238000000576 coating method Methods 0.000 claims description 79
- 239000011248 coating agent Substances 0.000 claims description 72
- 239000011521 glass Substances 0.000 claims description 51
- 239000011787 zinc oxide Substances 0.000 claims description 49
- 229910052751 metal Inorganic materials 0.000 claims description 46
- 239000002184 metal Substances 0.000 claims description 46
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 43
- 239000000463 material Substances 0.000 claims description 39
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 37
- 229910052709 silver Inorganic materials 0.000 claims description 37
- 239000004332 silver Substances 0.000 claims description 37
- 238000002834 transmittance Methods 0.000 claims description 29
- 239000006117 anti-reflective coating Substances 0.000 claims description 11
- 239000012780 transparent material Substances 0.000 claims description 4
- 239000005347 annealed glass Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 214
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 81
- 239000010409 thin film Substances 0.000 description 45
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 42
- 239000000377 silicon dioxide Substances 0.000 description 40
- 239000011701 zinc Substances 0.000 description 27
- 150000004706 metal oxides Chemical class 0.000 description 26
- 239000000203 mixture Substances 0.000 description 26
- 229910044991 metal oxide Inorganic materials 0.000 description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 21
- 239000010936 titanium Substances 0.000 description 21
- 229910052719 titanium Inorganic materials 0.000 description 21
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 19
- 239000010408 film Substances 0.000 description 19
- 230000003287 optical effect Effects 0.000 description 19
- 239000011253 protective coating Substances 0.000 description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 16
- 229910001092 metal group alloy Inorganic materials 0.000 description 15
- 229910052725 zinc Inorganic materials 0.000 description 15
- 239000000853 adhesive Substances 0.000 description 14
- 230000001070 adhesive effect Effects 0.000 description 14
- 230000005540 biological transmission Effects 0.000 description 14
- 239000000758 substrate Substances 0.000 description 12
- 230000005855 radiation Effects 0.000 description 10
- 239000011247 coating layer Substances 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- -1 oligomers Polymers 0.000 description 6
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
- 229910001887 tin oxide Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910001128 Sn alloy Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000005329 float glass Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 229910001297 Zn alloy Inorganic materials 0.000 description 3
- 229910002064 alloy oxide Inorganic materials 0.000 description 3
- 230000003667 anti-reflective effect Effects 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910052755 nonmetal Inorganic materials 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000006124 Pilkington process Methods 0.000 description 2
- 238000003848 UV Light-Curing Methods 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- INFDPOAKFNIJBF-UHFFFAOYSA-N paraquat Chemical compound C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 INFDPOAKFNIJBF-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- DUCFBDUJLLKKPR-UHFFFAOYSA-N [O--].[Zn++].[Ag+] Chemical compound [O--].[Zn++].[Ag+] DUCFBDUJLLKKPR-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000005566 electron beam evaporation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 238000005118 spray pyrolysis Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
- Optical Elements Other Than Lenses (AREA)
- Joining Of Glass To Other Materials (AREA)
Description
積層物品を調製した。物品は下記の構造を有していた。
クリアガラス 2.0mm
PVB 0.75mm
保護用上塗り 1000Å (85/15重量%、シリカ/アルミナ)
スズ酸亜鉛 302.6Å
酸化亜鉛 101Å
チタン 20Å
銀 118.6Å
酸化亜鉛 93.4Å
スズ酸亜鉛 560.0Å
酸化亜鉛 93.4Å
チタン 20Å
銀 126.4Å
酸化亜鉛 103Å
スズ酸亜鉛 618.4Å
酸化亜鉛 103Å
チタン 20Å
銀 131.2Å
酸化亜鉛 100.8Å
スズ酸亜鉛 302.3Å
Starphire(登録商標)ガラス 2.3mm
実施例2は、PVB層を従来の光学接着剤に取り替えた以外は、上記の実施例1と同じであった。光学接着剤は、Norland Optical Adhesive(No.61、UV硬化)を使用した。中間層を、液体の光学接着剤(0.5cm3未満)をコーティング上に配置し、次に外側ガラスプライを接着剤上に配置して、接着剤の取扱説明書に従って接着剤を硬化することにより形成した。硬化した光学接着剤の厚さは、測定しなかった。
コンピューターで作製した積層物品を、FTG Software Associates(Princeton,New Jersey)から市販されているWINFILMソフトウエアを使用してデザインした。モデル化した物品は下記の構造を有していた。
クリアガラス 2.1mm
PVB 0.76mm
保護用上塗り 40Å (チタニア)
スズ酸亜鉛 246.3Å
酸化亜鉛 80Å
チタン 20Å
銀 80.3Å
酸化亜鉛 80Å
スズ酸亜鉛 548.2Å
酸化亜鉛 80Å
チタン 20Å
銀 105.7Å
酸化亜鉛 80Å
スズ酸亜鉛 585.8Å
酸化亜鉛 80Å
チタン 20Å
銀 97.2Å
酸化亜鉛 80Å
スズ酸亜鉛 307.2Å
Starphire(登録商標)ガラス 2.1mm
積層物品を調製した。物品は、下記の構造を有していた。
GL−20(登録商標)ガラス 2.0mm
光学接着剤 Norland Optical Adhesive (No.61)
保護用上塗り 1000Å (85/15重量%、シリカ/アルミナ)
スズ酸亜鉛 213.3Å
酸化亜鉛 80Å
チタン 13Å
銀 117.8Å
酸化亜鉛 80Å
スズ酸亜鉛 537.1Å
酸化亜鉛 80Å
チタン 13Å
銀 139Å
酸化亜鉛 80Å
スズ酸亜鉛 669.9Å
酸化亜鉛 80Å
チタン 13Å
銀 203.2Å
酸化亜鉛 80Å
スズ酸亜鉛 251.7Å
Starphire(登録商標)ガラス 2.3mm
Claims (8)
- 第1可視光透過率を有する、ガラスを含む第1プライであって、550nmの基準波長で少なくとも87%の可視光透過率を有する第1プライと、
第1可視光透過率が第2可視光透過率よりも高い、第2可視光透過率を有する、ガラスを含む第2プライと、
第1プライ及び第2プライの間に配置される太陽光制御コーティングとを含み、
太陽光制御コーティングが、第1赤外反射金属層、第2赤外反射金属層及び第3赤外反射金属層を有し、かつ、これらの赤外反射金属層が金属の銀を含み、
第1赤外反射金属層が第2赤外反射金属層よりも厚く、第2赤外反射金属層が第3赤外反射金属層よりも厚く、
第1プライは車両外部側にあり、第2プライは車両内部側にあり、
第1赤外反射金属層、第2赤外反射金属層及び第3赤外反射金属層はこの順で車両外部側から車両内部側にある車両用透明物。 - 第2プライの少なくとも一部の上に反射防止コーティングをさらに含む、請求項1に記載の車両用透明物。
- 第1及び第2のプライが焼き鈍し済ガラスを含む、請求項1に記載の車両用透明物。
- 第1銀層が90Åから205Åの範囲の厚さを有し、第2銀層が100Åから140Åの範囲の厚さを有し、第3銀層が80Åから120Åの範囲の厚さを有する、請求項1に記載の車両用透明物。
- 第1プライが1番表面及び2番表面を有し、第2プライが3番表面及び4番表面を有し、2番表面が3番表面に面し、太陽光制御コーティングが2番表面の少なくとも一部の上に形成される、請求項1に記載の車両用透明物。
- 反射防止コーティングが、1.75以下の屈折率を有する材料を含む少なくとも1層と、1.75を超える屈折率を有する材料を含む少なくとも1層とを含む多層コーティングである、請求項2に記載の車両用透明物。
- 第2プライの4番表面の少なくとも一部の上に提供される反射防止コーティングを更に含む、請求項5に記載の車両用透明物。
- 太陽光制御コーティングが
250Åから310Åの範囲の厚さを有するスズ酸亜鉛層と、
80Åから105Åの範囲の厚さを有する酸化亜鉛層と、
90Åから205Åの範囲の厚さを有する第1銀層と、
80Åから110Åの範囲の厚さを有する酸化亜鉛層と、
585Åから680Åの範囲の厚さを有するスズ酸亜鉛層と、
80Åから110Åの範囲の厚さを有する酸化亜鉛層と、
100Åから140Åの範囲の厚さを有する第2銀層と、
80Åから100Åの範囲の厚さを有する酸化亜鉛層と、
530Åから565Åの範囲の厚さを有するスズ酸亜鉛層と、
80Åから105Åの範囲の厚さを有する酸化亜鉛層と、
80Åから120Åの範囲の厚さを有する第3銀層と、
80Åから105Åの範囲の厚さを有する酸化亜鉛層と、
210Åから305Åの範囲の厚さを有するスズ酸亜鉛層とを含み、
第1銀層が第2銀層よりも厚く、第2銀層が第3銀層よりも厚い、請求項1に記載の車両用透明物。
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US95779607P | 2007-08-24 | 2007-08-24 | |
US60/957,796 | 2007-08-24 | ||
PCT/US2008/073803 WO2009029466A1 (en) | 2007-08-24 | 2008-08-21 | Vehicle transparency |
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JP (1) | JP5675356B2 (ja) |
CN (1) | CN101808821B (ja) |
CA (1) | CA2697488C (ja) |
ES (1) | ES2666496T3 (ja) |
MX (1) | MX337302B (ja) |
PL (1) | PL2183102T3 (ja) |
WO (1) | WO2009029466A1 (ja) |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1019346A3 (fr) * | 2010-05-25 | 2012-06-05 | Agc Glass Europe | Vitrage de controle solaire. |
BE1019345A3 (fr) * | 2010-05-25 | 2012-06-05 | Agc Glass Europe | Vitrage de controle solaire a faible facteur solaire. |
GB201017855D0 (en) | 2010-10-22 | 2010-12-01 | Pilkington Group Ltd | Coating glass |
BE1020331A4 (fr) | 2011-11-29 | 2013-08-06 | Agc Glass Europe | Vitrage de contrôle solaire. |
JP5847334B2 (ja) | 2012-01-10 | 2016-01-20 | サン−ゴバン グラス フランスSaint−Gobain Glass France | 導電性コーティングを有する透明ガラスペイン |
BR112014012695B1 (pt) * | 2012-01-10 | 2021-01-19 | Saint-Gobain Glass France | painel transparente, e, método para produzir o painel transparente |
WO2013109582A1 (en) * | 2012-01-17 | 2013-07-25 | Cardinal Cg Company | Low solar transmittance coatings |
EP2882588B1 (de) | 2012-08-09 | 2019-12-11 | Saint-Gobain Glass France | Elektrisch schaltbare verbundscheibenanordnung |
BE1020862A3 (fr) * | 2012-08-21 | 2014-06-03 | Agc Glass Europe | Vitrage automobile. |
US10082716B2 (en) | 2012-08-21 | 2018-09-25 | Saint-Gobain Glass France | Composite panel with electrically switchable optical properties |
JP5859476B2 (ja) * | 2013-04-11 | 2016-02-10 | 日東電工株式会社 | 赤外線反射フィルム |
CN104267499B (zh) | 2014-10-14 | 2016-08-17 | 福耀玻璃工业集团股份有限公司 | 一种抬头显示*** |
WO2016081896A1 (en) * | 2014-11-21 | 2016-05-26 | Saint-Gobain Performance Plastics Corporation | Infra-red control optical film |
CN106116174B (zh) * | 2016-06-20 | 2018-07-27 | 东莞市银建玻璃工程有限公司 | 一种高透型三银low-e玻璃 |
EP3514583B1 (en) | 2016-09-15 | 2020-12-09 | Central Glass Company, Limited | Sunlight shielding member |
US10618252B2 (en) * | 2017-04-12 | 2020-04-14 | Vitro Flat Glass Llc | Solar control coating for laminated glazing |
WO2018207555A1 (ja) | 2017-05-12 | 2018-11-15 | セントラル硝子株式会社 | 日射遮蔽部材 |
US10788667B2 (en) | 2017-08-31 | 2020-09-29 | Vitro Flat Glass Llc | Heads-up display and coating therefor |
MX2020005856A (es) * | 2017-12-05 | 2020-09-09 | Saint Gobain | Cristal compuesto que tiene recubrimiento de proteccion solar y recubrimiento que refleja radiacion termica. |
CN112074405A (zh) * | 2018-03-27 | 2020-12-11 | 皮尔金顿集团有限公司 | 层叠玻璃件 |
JP2021519258A (ja) * | 2018-03-27 | 2021-08-10 | ピルキントン グループ リミテッド | 積層グレイジング |
FR3114315B1 (fr) * | 2020-09-21 | 2023-03-24 | Saint Gobain | Materiau comprenant un substrat muni d’un empilement de couches minces a proprietes thermiques |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4799745A (en) * | 1986-06-30 | 1989-01-24 | Southwall Technologies, Inc. | Heat reflecting composite films and glazing products containing the same |
FR2710333B1 (fr) * | 1993-09-23 | 1995-11-10 | Saint Gobain Vitrage Int | Substrat transparent muni d'un empilement de couches minces agissant sur le rayonnement solaire et/ou infra-rouge. |
FR2748743B1 (fr) * | 1996-05-14 | 1998-06-19 | Saint Gobain Vitrage | Vitrage a revetement antireflet |
US6899953B1 (en) * | 1998-05-08 | 2005-05-31 | Ppg Industries Ohio, Inc. | Shippable heat-treatable sputter coated article and zinc cathode sputtering target containing low amounts of tin |
FR2787440B1 (fr) * | 1998-12-21 | 2001-12-07 | Saint Gobain Vitrage | Substrat transparent comportant un revetement antireflet |
US20020136905A1 (en) * | 1999-11-24 | 2002-09-26 | Medwick Paul A. | Low shading coefficient and low emissivity coatings and coated articles |
AU2003231310B2 (en) * | 2002-05-03 | 2007-03-29 | Vitro Flat Glass Llc | Substrate having thermal management coating for an insulating glass unit |
US7588829B2 (en) * | 2002-05-31 | 2009-09-15 | Ppg Industries Ohio, Inc. | Article having an aesthetic coating |
FR2859721B1 (fr) * | 2003-09-17 | 2006-08-25 | Saint Gobain | Substrat transparent muni d'un empilement de couches minces pour un blindage electromagnetique |
FR2862961B1 (fr) * | 2003-11-28 | 2006-02-17 | Saint Gobain | Substrat transparent utilisable alternativement ou cumulativement pour le controle thermique, le blindage electromagnetique et le vitrage chauffant. |
US7335421B2 (en) * | 2005-07-20 | 2008-02-26 | Ppg Industries Ohio, Inc. | Heatable windshield |
US7339728B2 (en) * | 2005-10-11 | 2008-03-04 | Cardinal Cg Company | Low-emissivity coatings having high visible transmission and low solar heat gain coefficient |
US20070264479A1 (en) * | 2006-05-09 | 2007-11-15 | Thiel James P | Aesthetic transparency |
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PL2183102T3 (pl) | 2018-08-31 |
EP2183102A1 (en) | 2010-05-12 |
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ES2666496T3 (es) | 2018-05-04 |
CA2697488C (en) | 2013-08-13 |
WO2009029466A1 (en) | 2009-03-05 |
MX2010001937A (es) | 2010-03-11 |
CA2697488A1 (en) | 2009-03-05 |
JP2010536707A (ja) | 2010-12-02 |
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MX337302B (es) | 2016-02-24 |
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