JP5571382B2 - カプセル化小滴形状の粒子、及び当該粒子の製造方法 - Google Patents
カプセル化小滴形状の粒子、及び当該粒子の製造方法 Download PDFInfo
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- JP5571382B2 JP5571382B2 JP2009522141A JP2009522141A JP5571382B2 JP 5571382 B2 JP5571382 B2 JP 5571382B2 JP 2009522141 A JP2009522141 A JP 2009522141A JP 2009522141 A JP2009522141 A JP 2009522141A JP 5571382 B2 JP5571382 B2 JP 5571382B2
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- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 150000001629 stilbenes Chemical class 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
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- C08F8/00—Chemical modification by after-treatment
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
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- D—TEXTILES; PAPER
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
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- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description
<測定方法>
(粒径)
光子相関分光法(PCS)を用いて、イミド化(imidsation)後の分散液の粒子の平均流体力学的半径を求めた。Vertriebsgesellschaft mbH(Langen, Germany)のALVレーザーを用いて測定を行った。
赤外線乾燥/重量計タイプMettler LP16/PM600を用いて、固形分を求めた。
Knick752Cl(番号051489)pH測定器を用いて各サンプルのpH値を測定した。pH測定器を負荷電極(loas electrode)(3M KCl)に取付け、Merck製の、それぞれ4.00(クエン酸/HCl緩衝液)、7.00及び9.00のpHを有する緩衝液を用いて20℃で較正した。サンプルのpHを20℃で測定した。
接触角を接触角計タイプDigidrop(GBX(Roman, France))で測定した。接触角を250画像/秒でフィルムに基づき測定した。
アンカー翼攪拌機を有する1リットル容の二重壁油加熱オートクレーブに、225gのスチレン無水マレイン酸コポリマー(以下、「SMA」という。)及び334.4gの水を添加した。SMAは、26モル%の無水マレイン酸含量及び80.000g/モルの分子量を有していた。この反応混合物に、150gのパーム油(Cargill(USA)製)及び40.6gの25%NH3溶液を添加し、無水マレイン酸(MA):NH3比を約1:1とした。
375gのSMA及び344.56gの水を用いた以外は、実施例1の記載と同様に本実験を実施した。MA:NH3比が1:1となるように25%NH3溶液を添加した。160℃における反応中、最大トルクを上げてゲル化構造とし、この反応を中断させた。
150gのSMA、348gの水及び225gのパーム油を用いた以外は、実施例1の記載と同様に本実験を実施した。MA:NH3比が1:1となるように25%NH3溶液を添加した。
112.5gのSMA、354.7gの水及び262.5gのパーム油を用いた以外は、実施例1の記載と同様に本実験を実施した。MA:NH3比が1:1となるように25%NH3溶液を添加した。
実験1〜実験3に記載の分散液を、95gのサイズ調整していない上質紙に平均乾燥層厚み7g/m2で適用した。
225gのSMA及び334.4gの水を用いた以外は、実施例1の記載と同様に本実施例を実施する。この反応混合物に、150gのパラフィン油及び40.6gの25%NH3溶液を添加した。
パラフィン油の代わりに150gのヒマシ油を用いること以外、本実施例は実施例4と同じである。
実施例1を参照のこと。175gのSMA、318.4gの水及び157.5gのパーム油を用いた。この油に、17.5gのチオフェンジイルベンゾオキサゾール(Ciba SC製)を添加した。この反応混合物に、31.6gの25%NH3溶液を添加した。温度を160℃に上げた後、300rpmの回転速度で、圧力は6バールに上がり、15の最大トルクが観測された。4時間の反応時間後、反応混合物を室温で冷ました。約50重量%の固形分を有するポリマー分散液が得られ、この粒径は30〜120nmであった。
製剤A:
CaCO3(78%水分散液) 89部
カオリン(77%水分散液) 39部
SBRラテックス(50%水分散液) 20部
実施例6に記載のナノ粒子 20部
ナノ粒子の代わりに、
ポリビニルアルコール(20%水溶液) 20部
Tinopal OB(Ciba SC(Switzerland)製) 1部
を用いる以外は、製剤Aと同様
13g/m2コーティング重量を有する100g/m2プレコーティングされた上質原紙100gについてのELRHEPHO試験(輝度測定装置)
製剤A=96
製剤B=95
製剤A=99.9
製剤B=99.2
製剤A=51
製剤B=47
実施例1を参照のこと。180gのSMA、420gの水、及び75gのパーム油と15gのFat Yellow 3G(Clariant(Switzerland)製)との混合物を用いた。この反応混合物に、MA:NH3比が1:1となるように25%NH3溶液を添加した。
アンカー翼攪拌機を有する1リットル容の二重壁油加熱オートクレーブに、175gのSMA及び318.4gの水を添加した。SMAは、26モル%の無水マレイン酸含量及び80.000g/モルの分子量を有していた。この反応混合物に、157.5gのパーム油(Cargill(USA)製)と、直径3nm及び長さ約5マイクロメートルを有する16.6gのカーボンナノチューブ(Nanocyl(Belgium)製)との配合物を添加した。その後、31.6gの25%NH3溶液を添加した。温度を160℃に上げた後、300rpmの回転速度で、圧力は7バールに上がり、15の最大トルクが観測された。4時間の反応時間後、反応混合物を室温で冷ました。約50重量%の固形分を有するポリマー分散液が得られた。
33gのTiO2を197gのパーム油に分散させた。この分散液を、アンカー翼攪拌機を有する1リットル容の二重壁油加熱オートクレーブに添加した。これに、133gのSMA、309gの水及び24gの25%NH3水溶液を添加した。SMAは、26モル%の無水マレイン酸含量及び80.000g/モルの分子量を有していた。この反応混合物を攪拌し、155℃で3時間加熱した。その後、反応混合物を冷まし、非常に安定な分散液を得た。室温における3ヶ月間の放置後でも水相からの油分離は観測することができなかった。
33gのTiO2の代わりに50gのカーボンブラックを用いたこと以外は、実施例9に記載の実施例を繰り返した。反応時間は4時間とした。非常に安定な分散液が得られた。室温における3ヶ月間の放置後でも水相からの油分離は観測することができなかった。
33gのTiO2の代わりに33gのアルミニウム粉末を用いたこと以外は、実施例9に記載の実施例を繰り返した。さらに、150gのパーム油及び150gのSMAを用いた。固形分は50%であり、アンモニアと環状酸無水物基とのモルの比が1:1となるようにアンモニアを添加した。反応時間は4時間とし、反応の圧力は22バールに達した。非常に安定な分散液が得られた。室温における3ヶ月間の放置後でも水相からの油分離は観測することができなかった。
以下の数量:パーム油184g、SMA133g、水290g及びCaCO3粉末116gを用いて実施例9に記載の実施例を繰り返した。MA:NH3比は1:1であった。反応時間は1時間とし、分散液のpHは7.5であった。非常に安定な分散液が得られた。室温における1ヶ月間の放置後でも水相からの油分離は観測することができなかった。油を用いずとも同様の反応が起こり、凝固した。
以下の数量:パーム油184g、SMA133g、水290g及び滑石60gを用いて実施例9に記載の実施例を繰り返した。MA:NH3比は1:1であった。反応時間は2時間とし、分散液のpHは7.2であった。非常に安定な分散液が得られた。室温における1ヶ月間の放置後でも水相からの油分離は観測することができなかった。滑石が分散される場合にはよくある時間の肥大(thickening of time)は観測されない。油を用いずとも同様の反応が起こり、凝固した。
33gのTiO2を25gのD&C Red No30に代えたこと以外は実施例9に記載のサンプルを繰り返した。反応を4時間行った。冷ました後に、安定な分散液が得られた。
Claims (22)
- 不活性であり且つ水溶性でないコア材料と、前記コア材料を取り囲むシェル材料とを含むカプセル化小滴形状の粒子であって、前記シェル材料がスチレン誘導体と無水マレイン酸誘導体とのコポリマーを含有し、前記無水マレイン酸誘導体の75モル%より多くがマレイミドであり、平均粒径が300nm未満であることを特徴とする、カプセル化小滴形状の粒子。
- 前記シェル材料は、スチレン誘導体と無水マレイン酸誘導体とのコポリマーを含有し、前記無水マレイン酸誘導体の90モル%より多くがマレイミドであることを特徴とする、請求項1に記載の粒子。
- 前記シェル材料のTgは、120℃を超えることを特徴とする、請求項1又は2に記載の粒子。
- 前記コア材料は、活性成分を含有することを特徴とする、請求項1〜3のいずれか一項に記載の粒子。
- 前記コア材料は、油、アルカン、テルペン、ポリオレフィン及びワックスからなる群から選択される水不溶性材料であることを特徴とする、請求項1〜4のいずれか一項に記載の粒子。
- 前記コア材料は、植物油、エポキシ化油、ワセリン油、シリコーン油及びパラフィン油からなる群から選択される水不溶性材料であることを特徴とする、請求項1〜4のいずれか一項に記載の粒子。
- 前記コア材料は、パーム油、ダイズ油、ナタネ油、シリコーン油及び全種類のパラフィン油からなる群から選択される水不溶性材料であることを特徴とする、請求項1〜4のいずれか一項に記載の粒子。
- コア:シェルの重量比は、90:10〜1:40であることを特徴とする、請求項1〜7のいずれか一項に記載の粒子。
- コア:シェルの重量比は、85:15〜1:10であることを特徴とする、請求項1〜7のいずれか一項に記載の粒子。
- 前記粒子は、前記溶媒から分離されることを特徴とする、請求項1〜9のいずれか一項に記載の粒子。
- 前記粒子は、前記コア材料の存在下で無水マレイン酸含有ポリマーのアンモニウム塩を80℃〜195℃に加熱することによって得られることを特徴とする、請求項1〜9のいずれか一項に記載の粒子の製造方法。
- 前記粒子は、前記コア材料の存在下で無水マレイン酸含有ポリマーのアンモニウム塩を120℃〜190℃に加熱することによって得られることを特徴とする、請求項1〜9のいずれか一項に記載の粒子の製造方法。
- 反応が水中で行われることを特徴とする、請求項11又は12に記載の方法。
- 前記粒子は、酸無水物官能性ポリマーのアンモニウム塩による液体の乳化を介して形成されることを特徴とする、請求項11〜13のいずれか一項に記載の方法。
- 活性成分は、前記コア材料中に組み込まれることを特徴とする、請求項11〜14のいずれか一項に記載の方法。
- 活性成分は、コア−シェル材料の形成中に添加されることを特徴とする、請求項11〜15のいずれか一項に記載の方法。
- 前記粒子の形成は、無機材料若しくは有機材料、又は金属の存在下で実施されることを特徴とする、請求項11〜16のいずれか一項に記載の方法。
- 基材処理用水性コーティング組成物であって、前記コーティング組成物が、請求項1〜9のいずれか一項に記載の粒子、又は請求項11〜17のいずれか一項に記載の方法によって得られる粒子を含有することを特徴とする、基材処理用水性コーティング組成物。
- 結合剤、顔料、及び任意の添加剤をさらに含有する、請求項18に記載の水性コーティング組成物。
- 基材をコーティングするための、請求項1〜9のいずれか一項に記載の粒子を含むポリマー分散液、又は請求項11〜17のいずれか一項に記載の方法によって得られる粒子を含むポリマー分散液の使用。
- 前記基材が、紙、厚紙、織物、ガラス、皮革、木材若しくは木製基材、金属、プラスチック、皮膚、毛髪、爪又は石であることを特徴とする、請求項20に記載の使用。
- 請求項1〜10のいずれか一項に記載の粒子を含むポリマー分散液で基材をコーティングした後に乾燥して得られる乾燥コーティングを有する基材であって、前記基材が、紙、厚紙、ガラス、皮革、木材若しくは木製基材、金属、プラスチック、又は石である、基材。
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PCT/EP2007/006518 WO2008014903A1 (en) | 2006-07-31 | 2007-07-23 | Particle in the shape of an encapsulated droplet and process for making such a particle |
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JP5229488B2 (ja) * | 2008-03-24 | 2013-07-03 | 株式会社豊田中央研究所 | カーボンナノ複合体、それを含む分散液および樹脂組成物、ならびにカーボンナノ複合体の製造方法 |
DE102008040728A1 (de) * | 2008-07-25 | 2010-01-28 | Voith Patent Gmbh | Endlosband zur Bearbeitung flächig ausgebildeter Materialbahnen |
KR20110042173A (ko) * | 2008-08-13 | 2011-04-25 | 아사히 가라스 가부시키가이샤 | 도료 조성물 및 도포막이 형성된 물품 |
CN102652195B (zh) * | 2009-12-09 | 2014-07-23 | 帝人芳纶有限公司 | 核-壳粒子用于纱线或织物的抗芯吸应用的用途 |
WO2011110498A1 (en) | 2010-03-09 | 2011-09-15 | Topchim Nv | A heat sealable substrate and a process for making the same |
JP5789746B2 (ja) * | 2010-08-25 | 2015-10-07 | パナソニックIpマネジメント株式会社 | 低誘虫性基材および低誘虫性基材を用いた照明器具 |
CN103314021B (zh) * | 2011-01-21 | 2017-05-17 | 斯泰伦博斯大学 | 改性的聚(苯乙烯‑共‑马来酸酐)及其用途 |
US10092485B2 (en) | 2013-10-04 | 2018-10-09 | Encapsys, Llc | Benefit agent delivery particle |
CN105705697B (zh) | 2013-11-07 | 2022-02-08 | 帝人芳纶有限公司 | 包含多根纤维的漂浮线性拉伸构件 |
DE102014119572B4 (de) | 2014-12-23 | 2017-07-06 | Delfortgroup Ag | Umweltfreundliches Verpackungspapier für Lebensmittel |
RU2606350C1 (ru) * | 2015-05-19 | 2017-01-10 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ) | Защитное покрытие на основе полимерного композиционного радиоматериала |
CN104974303B (zh) * | 2015-07-02 | 2017-01-25 | 江南大学 | 一种含胸腺嘧啶的光敏性双亲共聚物及其自组装胶束 |
BE1023525B9 (nl) * | 2015-10-30 | 2017-09-27 | Ctf 2000 Nv | Ingekapselde additieven |
CN109804118A (zh) | 2016-07-28 | 2019-05-24 | 托普希姆股份有限公司 | 具有防水和部分热封性能的纸 |
WO2019101749A1 (en) * | 2017-11-21 | 2019-05-31 | Akzo Nobel Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
CN108912930B (zh) * | 2018-05-23 | 2020-08-28 | 风骊建材(上海)有限公司 | 一种环保水性漆及其制备方法 |
DE102019101671A1 (de) | 2019-01-23 | 2020-07-23 | Mitsubishi Hitec Paper Europe Gmbh | Barrierepapier umfassend Grasfasern |
DE102019101670A1 (de) | 2019-01-23 | 2020-07-23 | Mitsubishi Hitec Paper Europe Gmbh | Barrierepapier mit hohem Zellstofffaseranteil |
DE102019114197A1 (de) | 2019-05-27 | 2020-12-03 | Mitsubishi Hitec Paper Europe Gmbh | Aufzeichnungsmaterial umfassend eine bedruckbare Aufzeichnungsschicht, insbesondere eine bedruckbare Glanz- oder Hochglanzschicht, und eine Barriereschicht sowie Herstellungsverfahren und Verwendungen hierfür |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPH05142847A (ja) * | 1991-11-15 | 1993-06-11 | Fuji Xerox Co Ltd | マイクロカプセルおよびマイクロカプセルトナー並びにそ の製造法 |
JPH08262619A (ja) * | 1995-03-20 | 1996-10-11 | Ricoh Co Ltd | 熱現像型ジアゾ複写材料および該材料に用いるカップラーのカプセル化方法 |
NL1008469C2 (nl) * | 1998-03-04 | 1999-09-07 | Dsm Nv | Waterige dispersies van een polymeer. |
US6235800B1 (en) * | 1998-03-13 | 2001-05-22 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microcapsules and method of utilizing the same |
US6218339B1 (en) | 1999-03-18 | 2001-04-17 | Fmc Corporation | Microencapsulated clomazone in the presence of fat and resin |
CA2311194A1 (en) * | 2000-06-12 | 2001-12-12 | Anna Shulkin | Encapsulation process using anhydride moieties |
ATE479639T1 (de) * | 2001-05-18 | 2010-09-15 | Sun Chemical Corp | Verfahren zum färben von baumaterialien unter verwendung von kationischen pigmentdispersionen |
US6881484B2 (en) | 2001-05-30 | 2005-04-19 | Mitsubishi Kagaku Iatron, Inc. | Core-shell particle including signal-generating substance enclosed therein and process for producing the same |
WO2004031249A1 (en) | 2002-10-04 | 2004-04-15 | Ciba Specialty Chemicals Holding Inc. | Aqueous polymer dispersion, preparation and use thereof |
JP4432513B2 (ja) * | 2003-03-31 | 2010-03-17 | 東ソー株式会社 | 光学フィルム用樹脂組成物及び光学フィルム |
JP4530682B2 (ja) * | 2004-02-20 | 2010-08-25 | 三洋化成工業株式会社 | 熱膨張性マイクロカプセル |
US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
DE602005020342D1 (de) * | 2004-09-13 | 2010-05-12 | Kureha Corp | Thermal aufschäumende mikrokugel, deren herstellung, verwendung, sie enthaltende zusammensetzung sowie erzeugnis |
EP1910449B1 (en) | 2005-08-02 | 2013-12-18 | Topchim N.V. | Aqueous dispersion of hybrid particles consisting of organic or inorganic pigment particles and organic nano-particles and process for preparing the same |
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CN101511464A (zh) | 2009-08-19 |
EP2046492A1 (en) | 2009-04-15 |
CN101511464B (zh) | 2013-03-13 |
MY147967A (en) | 2013-02-28 |
CA2657261A1 (en) | 2008-02-07 |
BRPI0715534B1 (pt) | 2016-11-08 |
ZA200900113B (en) | 2009-11-25 |
EA017347B1 (ru) | 2012-11-30 |
AU2007280795A1 (en) | 2008-02-07 |
US20090253828A1 (en) | 2009-10-08 |
MX2009000761A (es) | 2009-05-28 |
AU2007280795B2 (en) | 2011-02-24 |
US8859641B2 (en) | 2014-10-14 |
CA2657261C (en) | 2014-10-07 |
WO2008014903A1 (en) | 2008-02-07 |
JP2009545428A (ja) | 2009-12-24 |
BRPI0715534A2 (pt) | 2013-06-25 |
EP2046492B1 (en) | 2012-06-06 |
EA200900250A1 (ru) | 2009-06-30 |
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