JP5539517B2 - メタノール製造のための複合改質プロセス - Google Patents
メタノール製造のための複合改質プロセス Download PDFInfo
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- JP5539517B2 JP5539517B2 JP2012524152A JP2012524152A JP5539517B2 JP 5539517 B2 JP5539517 B2 JP 5539517B2 JP 2012524152 A JP2012524152 A JP 2012524152A JP 2012524152 A JP2012524152 A JP 2012524152A JP 5539517 B2 JP5539517 B2 JP 5539517B2
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
SN=([H2]−[CO2])/([CO]+[CO2])
と定義される、いわゆる化学量論数(SN)により一般に表され、ここで、各成分の濃度は体積%またはモル%で表される。
・ SMRユニット:約1150GJ/hの最大熱負荷;
・ GHRユニット:420GJ/hの最大エネルギー入力;
・ POXユニット:約5200キロモル/hの酸素の最大ASU容量により制限される
を考慮して、Pro−IIなどの標準的なシミュレーションパッケージを使用して、フロースキームによるプロセスでメタンの豊富なガスからのメタノールの製造をシミュレーションする。表2には、ここで、新たに比較実験Aと命名された、特許文献1により実施例3および表3に提供されるような、流量、組成データ、温度および圧力に基づく10000mtpdのメタノール生産能力に関する合成ガス製造のシミュレーション結果が示されている。この実験において供給原料として使用された天然ガスの組成が、表1に与えられている。
Claims (9)
- 脱硫されたガス状炭化水素供給原料から合成ガス混合物を製造するための複合改質プロセスであって、前記供給原料が第1と第2の供給原料流に分割され、該第1の供給原料流が、水蒸気と混合され、直列に運転されているガス加熱改質装置(GHR)および水蒸気メタン改質装置(SMR)に供給され、前記第2の供給原料流が、SMRから来る改質されたガスと混合され、酸素と共に、非触媒部分酸化改質装置(POX)に供給されることを特徴とするプロセス。
- 前記炭化水素供給原料は、少なくとも80モル%のメタンを含有する、メタンの豊富な供給原料であることを特徴とする請求項1記載のプロセス。
- 前記第1の供給原料流が、前記供給原料の45〜50体積%を構成し、2.3〜2.7の水蒸気/炭素比で水蒸気と混合されることを特徴とする請求項1または2記載のプロセス。
- 水蒸気と混合された前記第1の供給原料流が、500〜550℃に加熱され、次いで、GHRに供給されることを特徴とする請求項1から3いずれか1項記載のプロセス。
- GHRから来るある程度改質されたガスが、625〜675℃の温度を有し、その後、SMRに供給されることを特徴とする請求項1から4いずれか1項記載のプロセス。
- SMRからの全ての改質されたガスが、前記第2の供給原料流と混合されることを特徴とする請求項1から5いずれか1項記載のプロセス。
- 1つのGHR、1つのSMRおよび1つのPOXを備えることを特徴とする請求項1から6いずれか1項記載のプロセス。
- 得られた前記合成ガス混合物が、2.0〜2.2の化学量論数を有することを特徴とする請求項1から7いずれか1項記載のプロセス。
- 請求項1から8いずれか1項記載の複合改質プロセスを含む、炭化水素供給原料からメタノールを製造するためのプロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09075363.3 | 2009-08-14 | ||
EP09075363 | 2009-08-14 | ||
PCT/EP2010/004972 WO2011018233A1 (en) | 2009-08-14 | 2010-08-10 | Combined reforming process for methanol production |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013501700A JP2013501700A (ja) | 2013-01-17 |
JP5539517B2 true JP5539517B2 (ja) | 2014-07-02 |
Family
ID=41435369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012524152A Expired - Fee Related JP5539517B2 (ja) | 2009-08-14 | 2010-08-10 | メタノール製造のための複合改質プロセス |
Country Status (8)
Country | Link |
---|---|
US (1) | US9079770B2 (ja) |
EP (1) | EP2464598B1 (ja) |
JP (1) | JP5539517B2 (ja) |
KR (1) | KR20120054632A (ja) |
CN (2) | CN106431834A (ja) |
DK (1) | DK2464598T3 (ja) |
ES (1) | ES2433231T3 (ja) |
WO (1) | WO2011018233A1 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013062415A1 (en) * | 2011-10-26 | 2013-05-02 | Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center | Method for producing synthesis gas for methanol production |
US9067847B2 (en) | 2012-06-21 | 2015-06-30 | Saudi Basic Industries Corporation | Process for producing a synthesis gas mixture |
KR101587476B1 (ko) | 2014-05-19 | 2016-02-03 | 대우조선해양 주식회사 | Smr을 이용한 fpso 상의 ft gtl 장치 및 방법 |
DE102014016704A1 (de) | 2014-11-12 | 2016-05-12 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung eines oder mehrerer Reaktionsprodukte |
JP6728751B2 (ja) | 2016-02-23 | 2020-07-22 | 株式会社Ihi | 反応装置及び反応システム |
CN109310971B (zh) * | 2016-06-14 | 2022-06-03 | 乔治洛德方法研究和开发液化空气有限公司 | 通过蒸汽重整产生合成气的反应器 |
WO2020150249A1 (en) * | 2019-01-15 | 2020-07-23 | Sabic Global Technologies, B.V. | Use of intermittent energy in the production of chemicals |
EP4105170A1 (en) | 2021-06-18 | 2022-12-21 | Technip Energies France | Process and plant for flexible production of syngas from hydrocarbons |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
Family Cites Families (25)
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GB440258A (en) | 1934-04-23 | 1935-12-23 | Cleveland Graphite Bronze Co | Improvements relating to the production of bi-metallic strip |
FR2372116A1 (fr) * | 1977-03-22 | 1978-06-23 | Banquy David | Procede de production de gaz de synthese |
JPS5610129A (en) * | 1979-07-05 | 1981-02-02 | Mitsubishi Gas Chem Co Inc | Preparation of aromatic dialdehyde |
GB8414491D0 (en) | 1984-06-07 | 1984-07-11 | Humphreys & Glasgow Ltd | Ammonia plant re-vamp process |
JPH0669881B2 (ja) * | 1984-11-26 | 1994-09-07 | 日揮株式会社 | 炭化水素の水蒸気改質法 |
DK167864B1 (da) * | 1990-02-02 | 1993-12-27 | Topsoe Haldor As | Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling |
EP0522744B1 (en) | 1991-07-09 | 1997-08-13 | Imperial Chemical Industries Plc | Synthesis gas production |
CN1033267C (zh) * | 1991-07-09 | 1996-11-13 | 帝国化学工业公司 | 合成气的生产方法 |
GB9203375D0 (en) * | 1992-02-18 | 1992-04-01 | Davy Mckee London | Process |
JPH06256239A (ja) * | 1993-03-01 | 1994-09-13 | Mitsubishi Gas Chem Co Inc | メタノールの製造法 |
JPH07126201A (ja) | 1993-10-27 | 1995-05-16 | Mitsubishi Gas Chem Co Inc | メタノール製造方法 |
US5496859A (en) | 1995-01-28 | 1996-03-05 | Texaco Inc. | Gasification process combined with steam methane reforming to produce syngas suitable for methanol production |
WO1998014536A1 (fr) | 1996-10-03 | 1998-04-09 | Hajime Kato | .procede de reformage d'hydrocarbures a l'aide de vapeur |
JP4033988B2 (ja) | 1997-11-27 | 2008-01-16 | 東洋エンジニアリング株式会社 | メタノ−ルの製造方法 |
US6444712B1 (en) | 2000-09-28 | 2002-09-03 | Exxonmobil Chemical Patents, Inc. | Methanol, olefin, and hydrocarbon synthesis process |
US20020165417A1 (en) | 2001-03-14 | 2002-11-07 | Toyo Engineering Corporation | Process for producing synthesis gas |
DE10214003B4 (de) * | 2002-03-27 | 2005-12-22 | Lurgi Ag | Verfahren zur Erzeugung von Kohlenmonoxid und Methanol |
EP1403216B1 (en) | 2002-09-26 | 2011-03-23 | Haldor Topsoe A/S | Process for the preparation of synthesis gas |
EP1413547A1 (en) | 2002-09-26 | 2004-04-28 | Haldor Topsoe A/S | Process for the production of synthesis gas |
GB2407819A (en) | 2003-11-04 | 2005-05-11 | Alexander Have Quartey-Papafio | Production of syngas using parallel reforming steps |
EP1708982A1 (en) | 2004-01-22 | 2006-10-11 | Acetex (Cyprus) Limited | Integrated process for acetic acid and methanol |
WO2006117499A1 (en) | 2005-05-03 | 2006-11-09 | Quartey-Papafio Alexander H | Synthesis gas production process |
US7485767B2 (en) * | 2005-06-29 | 2009-02-03 | Exxonmobil Chemical Patents Inc. | Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids |
DE102006023248C5 (de) | 2006-05-18 | 2018-01-25 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas |
ES2357185T5 (es) * | 2007-04-04 | 2015-04-14 | Saudi Basic Industries Corporation | Proceso combinado de reformado para producción de metanol |
-
2010
- 2010-08-10 WO PCT/EP2010/004972 patent/WO2011018233A1/en active Application Filing
- 2010-08-10 CN CN201610816557.1A patent/CN106431834A/zh active Pending
- 2010-08-10 JP JP2012524152A patent/JP5539517B2/ja not_active Expired - Fee Related
- 2010-08-10 KR KR1020127006583A patent/KR20120054632A/ko active IP Right Grant
- 2010-08-10 US US13/390,474 patent/US9079770B2/en not_active Expired - Fee Related
- 2010-08-10 EP EP10742775.9A patent/EP2464598B1/en not_active Not-in-force
- 2010-08-10 CN CN2010800359527A patent/CN102498060A/zh active Pending
- 2010-08-10 DK DK10742775.9T patent/DK2464598T3/da active
- 2010-08-10 ES ES10742775T patent/ES2433231T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
EP2464598B1 (en) | 2013-07-31 |
DK2464598T3 (da) | 2013-10-28 |
US20120149788A1 (en) | 2012-06-14 |
JP2013501700A (ja) | 2013-01-17 |
KR20120054632A (ko) | 2012-05-30 |
ES2433231T3 (es) | 2013-12-10 |
EP2464598A1 (en) | 2012-06-20 |
CN102498060A (zh) | 2012-06-13 |
US9079770B2 (en) | 2015-07-14 |
CN106431834A (zh) | 2017-02-22 |
WO2011018233A1 (en) | 2011-02-17 |
WO2011018233A8 (en) | 2012-03-01 |
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