JP5495154B2 - 流動性、剛性および衝撃強さに優れたエチレン−プロピレンブロック共重合体系ポリプロピレン樹脂組成物 - Google Patents

流動性、剛性および衝撃強さに優れたエチレン−プロピレンブロック共重合体系ポリプロピレン樹脂組成物 Download PDF

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Publication number: JP5495154B2
Authority: JP; Japan
Prior art keywords: ethylene; propylene; polypropylene resin; resin composition; copolymer
Prior art date: 2007-07-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

JP2008182659A

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English (en)

Japanese (ja)

Other versions

JP2009019208A (ja

Inventor

ショックチェ，ション

イェルハン，シュン

キュンリ，テ

イックキム，ション

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

SK Geo Centric Co Ltd

Original Assignee

SK Global Chemical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-07-13

Filing date

2008-07-14

Publication date

2014-05-21

2008-07-14 Application filed by SK Global Chemical Co Ltd filed Critical SK Global Chemical Co Ltd

2009-01-29 Publication of JP2009019208A publication Critical patent/JP2009019208A/ja

2014-05-21 Application granted granted Critical

2014-05-21 Publication of JP5495154B2 publication Critical patent/JP5495154B2/ja

Status Active legal-status Critical Current

2028-07-14 Anticipated expiration legal-status Critical

Links

-1 polypropylene Polymers 0.000 title claims description 49
239000004743 Polypropylene Substances 0.000 title claims description 47
229920001155 polypropylene Polymers 0.000 title claims description 47
239000011342 resin composition Substances 0.000 title claims description 26
229920005676 ethylene-propylene block copolymer Polymers 0.000 title claims description 25
229920001577 copolymer Polymers 0.000 claims description 61
229920005989 resin Polymers 0.000 claims description 26
239000011347 resin Substances 0.000 claims description 26
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 24
239000005977 Ethylene Substances 0.000 claims description 24
229920005629 polypropylene homopolymer Polymers 0.000 claims description 23
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
239000001257 hydrogen Substances 0.000 claims description 14
229910052739 hydrogen Inorganic materials 0.000 claims description 14
239000000155 melt Substances 0.000 claims description 14
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 13
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
239000000203 mixture Substances 0.000 claims description 11
239000002667 nucleating agent Substances 0.000 claims description 11
239000011159 matrix material Substances 0.000 claims description 3
FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 claims description 2
DFXFBQFUSURGOJ-CRWXNKLISA-N (3R,4S,5S,6S)-7-methyl-1-phenyloct-1-ene-2,3,4,5,6,7-hexol Chemical compound CC([C@H]([C@H]([C@@H]([C@H](C(O)=CC1=CC=CC=C1)O)O)O)O)(O)C DFXFBQFUSURGOJ-CRWXNKLISA-N 0.000 claims description 2
CTPBWPYKMGMLGS-CIAFKFPVSA-N (3s,4s,5s,6r)-1,8-bis(4-methylphenyl)octa-1,7-diene-2,3,4,5,6,7-hexol Chemical compound C1=CC(C)=CC=C1C=C(O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=CC1=CC=C(C)C=C1 CTPBWPYKMGMLGS-CIAFKFPVSA-N 0.000 claims description 2
238000007334 copolymerization reaction Methods 0.000 claims description 2
229940087101 dibenzylidene sorbitol Drugs 0.000 claims description 2
229910052751 metal Inorganic materials 0.000 claims description 2
239000002184 metal Substances 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims 1
230000000052 comparative effect Effects 0.000 description 12
238000000034 method Methods 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 7
150000001451 organic peroxides Chemical class 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 7
238000009826 distribution Methods 0.000 description 6
239000007924 injection Substances 0.000 description 6
238000002347 injection Methods 0.000 description 6
239000006185 dispersion Substances 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
239000007789 gas Substances 0.000 description 4
239000008096 xylene Substances 0.000 description 4
239000002253 acid Substances 0.000 description 3
239000003963 antioxidant agent Substances 0.000 description 3
230000003078 antioxidant effect Effects 0.000 description 3
238000000635 electron micrograph Methods 0.000 description 3
229920001038 ethylene copolymer Polymers 0.000 description 3
238000005259 measurement Methods 0.000 description 3
238000012805 post-processing Methods 0.000 description 3
239000010409 thin film Substances 0.000 description 3
WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
230000006866 deterioration Effects 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000000465 moulding Methods 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
238000004806 packaging method and process Methods 0.000 description 2
239000008188 pellet Substances 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
230000035939 shock Effects 0.000 description 2
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
229920005674 ethylene-propylene random copolymer Polymers 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
239000012778 molding material Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000005457 optimization Methods 0.000 description 1
229920006280 packaging film Polymers 0.000 description 1
239000012785 packaging film Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000012899 standard injection Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP2008182659A 2007-07-13 2008-07-14 流動性、剛性および衝撃強さに優れたエチレン−プロピレンブロック共重合体系ポリプロピレン樹脂組成物 Active JP5495154B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
KR1020070070638A KR101133359B1 (ko)	2007-07-13	2007-07-13	유동성, 강성 및 충격강도가 우수한 에틸렌-프로필렌블록공중합체계 폴리프로필렌 수지 조성물
KR10-2007-0070638		2007-07-13

Publications (2)

Publication Number	Publication Date
JP2009019208A JP2009019208A (ja)	2009-01-29
JP5495154B2 true JP5495154B2 (ja)	2014-05-21

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JP (1)	JP5495154B2 (zh)
KR (1)	KR101133359B1 (zh)
CN (1)	CN101343393B (zh)

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KR100977665B1 (ko) *	2009-12-18	2010-08-24	에스케이에너지 주식회사	충격강도, 표면특성 및 유동성이 우수한 에틸렌-프로필렌 블록공중합체계 폴리프로필렌 수지 조성물
CN101812200B (zh) *	2009-12-28	2013-07-31	上海金发科技发展有限公司	热水器内胆用α晶型均聚聚丙烯组合物及其制备方法
KR101410231B1 (ko) *	2012-04-18	2014-06-27	대윤계기산업 주식회사	전기화학식 기체투과형 잔류염소센서
CN109423150A (zh) *	2017-08-25	2019-03-05	韩华道达尔有限公司	涂装性优异的聚丙烯树脂组合物
EP3722364B1 (en)	2019-04-12	2024-01-24	Thai Polyethylene Co., Ltd.	High flow and high stiffness impact copolymer polypropylene
CN114106454B (zh) *	2020-08-27	2023-06-09	中国石油化工股份有限公司	一种聚丙烯组合物及其制备方法
CN116157468A (zh) *	2020-08-27	2023-05-23	中国石油化工股份有限公司	聚丙烯组合物及其制备方法和由其制成的制品
CN114106453B (zh) *	2020-08-27	2023-07-21	中国石油化工股份有限公司	一种聚丙烯组合物和聚丙烯粒料及其制备方法

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JP3482732B2 (ja) *	1995-03-31	2004-01-06	チッソ株式会社	高剛性プロピレン・エチレンブロック共重合体の製造方法
US6300415B1 (en) *	1995-11-24	2001-10-09	Chisso Corporation	Propylene composition, process for preparing the same, polypropylene composition, and molded articles
JPH09194651A (ja) *	1996-01-22	1997-07-29	Tonen Chem Corp	ポリプロピレン樹脂組成物
KR100537923B1 (ko) *	1998-12-31	2006-02-28	삼성토탈 주식회사	용융 흐름성이 우수하고 내열성 및 저온충격강도가 우수한폴리프로필렌 수지 조성물
JP2001233923A (ja) *	1999-12-17	2001-08-28	Idemitsu Petrochem Co Ltd	プロピレン−エチレンブロック共重合体、樹脂組成物及びブロー成形体
KR100656829B1 (ko) *	2000-06-03	2006-12-15	삼성토탈 주식회사	용융 흐름성, 강성 및 저온충격강도가 우수한 고결정성폴리프로필렌 수지조성물
KR20020049854A (ko) *	2000-12-20	2002-06-26	유현식	고결정성 폴리프로필렌계 수지조성물
KR20040065079A (ko) *	2003-01-15	2004-07-21	삼성아토피나주식회사	내압특성과 내충격성이 우수한 자동차용 고투명성폴리프로필렌 수지조성물
JP4887785B2 (ja) *	2005-01-07	2012-02-29	住友化学株式会社	ポリプロピレン系樹脂組成物および成形体
JP4715238B2 (ja) *	2005-03-04	2011-07-06	住友化学株式会社	自動車用アンダーカバー
KR101183747B1 (ko) *	2005-05-10	2012-09-17	에스케이종합화학 주식회사	우수한 내충격성, 굴곡탄성율 및 투명성을 갖는폴리프로필렌 조성물 및 이의 제품

2007
- 2007-07-13 KR KR1020070070638A patent/KR101133359B1/ko active IP Right Grant
2008
- 2008-07-14 CN CN2008101316256A patent/CN101343393B/zh active Active
- 2008-07-14 JP JP2008182659A patent/JP5495154B2/ja active Active

Also Published As

Publication number	Publication date
CN101343393B (zh)	2013-05-08
KR20090007044A (ko)	2009-01-16
CN101343393A (zh)	2009-01-14
JP2009019208A (ja)	2009-01-29
KR101133359B1 (ko)	2012-04-06

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Publication	Publication Date	Title
JP5495154B2 (ja)	2014-05-21	流動性、剛性および衝撃強さに優れたエチレン−プロピレンブロック共重合体系ポリプロピレン樹脂組成物
EP2174980B1 (en)	2015-07-15	High flowable heterophasic polypropylene
AU2014368700B2 (en)	2017-02-02	Multimodal polypropylene with respect to comonomer content
EP1963424B1 (en)	2011-09-21	Polypropylene composition comprising a propylene homopolymer component
KR101183747B1 (ko)	2012-09-17	우수한 내충격성, 굴곡탄성율 및 투명성을 갖는폴리프로필렌 조성물 및 이의 제품
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