JP5466149B2 - 光学異方性化合物及びこれを含む樹脂組成物 - Google Patents
光学異方性化合物及びこれを含む樹脂組成物 Download PDFInfo
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- JP5466149B2 JP5466149B2 JP2010510233A JP2010510233A JP5466149B2 JP 5466149 B2 JP5466149 B2 JP 5466149B2 JP 2010510233 A JP2010510233 A JP 2010510233A JP 2010510233 A JP2010510233 A JP 2010510233A JP 5466149 B2 JP5466149 B2 JP 5466149B2
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- 238000004381 surface treatment Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Q1乃至Q12は、それぞれ独立に、−H、−F、−Cl、−Br、−I、−CN、−CF3、−OCF3、−R6、−OR6、−NHR6、−NR6R6または−C(=O)R6を示し、
Zは、CまたはNを示し(ZがNの場合、対応するQ1乃至Q12との結合は存在しない)、
l、m及びnは、それぞれ独立に、0〜2の整数を示し(l+m+nは、1以上の整数である)、
Y、G1及びG2は、それぞれ独立に、−(CH2)rSiW1W2(CH2)s−、−O−、−NR6−、−S−、−SO−、−SO2−、−(CH2)q−、−CH=CH−、−C≡C−、−C(=O)O(CH2)q−、−OC(=O)(CH2)q−、−(CH2)qC(=O)O−、−(CH2)qOC(=O)−、−C(=O)(CH2)q−、−(CH2)qC(=O)−、−C(=O)NR6−、−NR6C(=O)−、−C(=O)S−または−SC(=O)−を示し(qは、0〜5の整数、r及びsは、それぞれ独立に0〜2の整数である)、
Eは、−H、−F、−Cl、−Br、−I、−CN、−NCO、−NCS、−SiW1W2R6、−R6、−N(R6)2、−OR6、−CF3または−OCF3を示し、
X1乃至X5は、それぞれ独立に、−SiW1W2−、−O−、−NR6−、−S−、−SO−、−SO2−、−(CH2)p−、−C(=O)NR6−、−NR6C(=O)−、−NR6C(=O)NR6−、−C(=O)O−、−OC(=O)−または−OC(=O)O−を示し(pは、0〜2の整数である)、
W1は、−R7、−OR7、−NHR7または−N(R7)2を示し、
W2は、−R8、−OR8、−NHR8または−N(R8)2を示し、
R1乃至R8は、それぞれ独立に、−H、C1〜C20のアルキル、C1〜C20のフルオロアルキル、C2〜C20のアルケニル、C2〜C20のフルオロアルケニル、C2〜C20のアルキニル、C2〜C20のフルオロアルキニル、−(CH2CH2O)tCH3、−(CH2CHCH3O)tCH3または−(CHCH3CH2O)tCH3を示し(tは、1〜5の整数である)、
前記Y、G1、G2、E及びX1乃至X5の少なくとも1つは、Si含有置換基を示す(前記Si含有置換基は、Y、G1及びG2の場合は、−(CH2)rSiW1W2(CH2)s−、Eの場合は、−SiW1W2R6、X1乃至X5の場合は、−SiW1W2−である))
1HNMR (400MHz, CDCl3): δ 0.30 (s, 6H), 0.69-0.81 (m, 2H), 0.85-0.93 (m, 3H), 1.20-1.39 (m, 8H), 7.62 (d, 2H), 7.35 (d, 2H), 7.67 (d, 2H), 7.70 (d, 2H), 7.74 (d, 2H), 8.17 (d, 2H).
1HNMR (400MHz, CDCl3): δ 0.31 (s, 12H), 0.69-0.80 (m, 4H), 0.86-0.92 (m, 6H), 1.62-1.71 (m, 4H), 7.45-7.54 (m, 8H).
Claims (12)
- 下記の化学式1で表されるシリコン含有化合物。
(式中、
Q1乃至Q12は、それぞれ独立に、−H、−CN、−CF3、−OCF3、−R6、−OR6、−NHR6、−NR6R6または−C(=O)R6を示し、
Zは、Cを示し、
l、m及びnは、それぞれ独立に、0〜2の整数を示し(l+m+nは、2以上の整数である)、
Yは、−(CH2)rSiW1W2(CH2)s−、−NR6−、−SO−、−SO2−、−(CH2)q−、−CH=CH−、−C≡C−、−C(=O)O(CH2)q−、−OC(=O)(CH2)q−、−(CH2)qC(=O)O−、−(CH2)qOC(=O)−、−C(=O)NR6−、−NR6C(=O)−、−C(=O)S−または−SC(=O)−を示し、
G1及びG2はそれぞれ独立に、−(CH2)rSiW1W2(CH2)s−、−NR6−、−SO−、−SO2−、−(CH2)q−、−CH=CH−、−C≡C−、−C(=O)NR6−、−NR6C(=O)−、−C(=O)S−または−SC(=O)−を示し(qは、0〜5の整数、r及びsは、それぞれ独立に0〜2の整数である)、
Eは、−CNを示し、
X1 、X 2 、X 4 、及びX5 は−(CH2)p−を示し(pは、整数0である)、
X 3 は−SiW 1 W 2 −を表し、
W1は、−R7、−OR7、−NHR7または−N(R7)2を示し、
W2は、−R8、−OR8、−NHR8または−N(R8)2を示し、
R 1 、R 2 、R 4 、及びR 5 は、−Hを示し、
R 3 はC 1 〜C 20 アルキルを示し、
R 6 〜R 8 はそれぞれ独立に、−HまたはC 1 〜C 20 アルキルを示す。 - 前記l+m+nは、2〜3の整数であることを特徴とする請求項1に記載のシリコン含有化合物。
- 高分子樹脂と請求項1乃至9のいずれか一項に記載のシリコン含有化合物を含む樹脂組成物。
- 前記高分子樹脂:化学式1で表されるシリコン含有化合物の重量比は、50:50〜99:1であることを特徴とする請求項10に記載の樹脂組成物。
- 請求項10に記載の樹脂組成物を含む光学部材。
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