JP5284085B2 - 低ホルムアルデヒド放出量の熱成形性メラミン/ホルムアルデヒドフォーム材 - Google Patents
低ホルムアルデヒド放出量の熱成形性メラミン/ホルムアルデヒドフォーム材 Download PDFInfo
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- JP5284085B2 JP5284085B2 JP2008516292A JP2008516292A JP5284085B2 JP 5284085 B2 JP5284085 B2 JP 5284085B2 JP 2008516292 A JP2008516292 A JP 2008516292A JP 2008516292 A JP2008516292 A JP 2008516292A JP 5284085 B2 JP5284085 B2 JP 5284085B2
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- formaldehyde
- melamine
- foam material
- precondensate
- weight
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0028—Use of organic additives containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/21—Urea; Derivatives thereof, e.g. biuret
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08J2361/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Description
さらなる利用分野として断熱壁の被覆加工、及び機材の絶縁及び衝撃吸収梱包としての用途がある。架橋メラミン樹脂の高い硬度のため、フォーム材は研磨クリーニング、研磨及び磨き様スポンジ用としても利用できる。スポンジは特別なクリーニング作業のために疎水及び疎油処理を施すこともできる。今まで、市場に提供されたメラミン/ホルムアルデヒドフォーム材と比較して、特に低いホルムアルデヒド放出量のため、本発明によるフォーム材は衛生部門、例えば薄い不織布の形態で外傷用包帯、おしめ及び失禁用製品の一部として利用することもできる。
110℃での加熱の後、フォーム材はDIN55666による測定で、0.08ppmのホルムアルデヒドを放出する。フォーム材は熱成形性であり、ホルムアルデヒド放出量は禁止化学物質の規制制限値を下回る。
実施例1を、尿素を加えないで、繰り返した。110℃での加熱の後、フォーム材はDIN55666による測定で0.42ppmのホルムアルデヒドを放出する。フォーム材は熱成形性であるが、ホルムアルデヒド放出量は禁止化学物質の規制制限値を上回る。
Claims (6)
- メラミン/ホルムアルデヒド(MF)予備縮合物、硬化剤および発泡剤を含む混合物の発泡及び架橋とともに加熱することによるフォーム材の製造方法であって、加熱前にホルムアルデヒド捕捉剤として尿素をメラミン/ホルムアルデヒド(MF)予備縮合物を基準として2〜10質量%で添加し、当該フォーム材のホルムアルデヒド放出量が、DIN55666による測定で、0.1ppm以下であることを特徴とする製造方法。
- 混合物を、55〜85質量%のメラミン/ホルムアルデヒド(MF)予備縮合物を含む水溶液又は分散液の形態で使用することを特徴とする請求項1に記載の方法。
- 予備縮合物のメラミン/ホルムアルデヒドのモル比が1:1.3〜1:4であることを特徴とする請求項1または2に記載の方法。
- 硬化剤をメラミン/ホルムアルデヒド(MF)予備縮合物を基準として0.01〜20質量%で使用することを特徴とする請求項1〜3のいずれか1項に記載の方法。
- 0〜80℃の沸点を有する物理的発泡剤をメラミン/ホルムアルデヒド(MF)予備縮合物を基準として1〜40質量%で使用することを特徴とする請求項1〜4のいずれか1項に記載の方法。
- 発泡及び架橋の後、フォーム材を100〜160℃の範囲の温度で加熱することを特徴とする請求項1〜5のいずれか1項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005027552A DE102005027552A1 (de) | 2005-06-14 | 2005-06-14 | Thermoformbare Melamin/Formaldehyd-Schaumstoffe mit geringer Formaldehydemission |
DE102005027552.4 | 2005-06-14 | ||
PCT/EP2006/063082 WO2006134083A1 (de) | 2005-06-14 | 2006-06-12 | Thermoformbare melamin/formaldehyd-schaumstoffe mit geringer formaldehydemission |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008544005A JP2008544005A (ja) | 2008-12-04 |
JP5284085B2 true JP5284085B2 (ja) | 2013-09-11 |
Family
ID=36911354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008516292A Active JP5284085B2 (ja) | 2005-06-14 | 2006-06-12 | 低ホルムアルデヒド放出量の熱成形性メラミン/ホルムアルデヒドフォーム材 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20080197524A1 (ja) |
EP (1) | EP1893674B1 (ja) |
JP (1) | JP5284085B2 (ja) |
KR (1) | KR101328822B1 (ja) |
CN (1) | CN101198646B (ja) |
DE (1) | DE102005027552A1 (ja) |
ES (1) | ES2426344T3 (ja) |
PL (1) | PL1893674T3 (ja) |
WO (1) | WO2006134083A1 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9347004B2 (en) * | 2009-06-16 | 2016-05-24 | The Boeing Company | Flame propagation resistant foam and method |
EP2371891A3 (en) | 2010-03-09 | 2012-04-25 | Borealis Agrolinz Melamine GmbH | Use of modified inorganic particles as aldehyde scavenger and curing agent, in particular in wood based panels |
WO2012035457A1 (de) * | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur herstellung von melamin/formaldehyd-schaumstoffen |
WO2012052375A1 (en) | 2010-10-19 | 2012-04-26 | Borealis Agrolinz Melamine Gmbh | Colloidal aminotriazine-aldehyde condensates and their use as aldehyde scavenger |
DE102011009397A1 (de) | 2011-01-25 | 2012-07-26 | Basf Se | Verbundschaumstoff zur Schalldämmung |
DE102012015128B4 (de) | 2012-07-30 | 2014-11-20 | Püschner GmbH + Co. KG | Verfahren und Vorrichtung zur Herstellung von harzbasierten Schaumstoffen |
EP2703074A1 (de) * | 2012-09-04 | 2014-03-05 | Basf Se | Verfahren zur Herstellung von Melamin/Formaldehyd-Schaumstoffen |
CN102898778B (zh) * | 2012-09-07 | 2014-07-30 | 南通紫鑫实业有限公司 | 一种三聚氰胺甲醛树脂闭孔泡沫的制备方法 |
EP2735584A1 (de) | 2012-11-26 | 2014-05-28 | Basf Se | Thermoverformbarer Melaminharzschaumstoff mit partikelförmigem Füllmaterial |
DE102013217654B4 (de) | 2013-09-04 | 2017-02-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Formaldehydfreie Amino- oder Amidharze basierend auf einer reaktiven Schutzgruppe und einem Di- oder Trialdehyd als Netzwerkbildner |
EP3080178B1 (de) | 2013-12-12 | 2018-11-21 | Fraunhofer Gesellschaft zur Förderung der Angewand | Formaldehyd-freie harze basierend auf hydroxyaldehyden |
EP3080179A1 (de) | 2013-12-12 | 2016-10-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Formaldehyd-freie harze basierend auf glyoxylsäureestern |
DE102015000393A1 (de) | 2014-01-21 | 2015-07-23 | Frank Becher | Verfahren zur Herstellung von geschlossen-porigen Erzeugnissen mit hohlen Zellen, mittels dessen der Druck in den Zellen kontrolliert während des Aufschäumens erhöht oder reduziert werden kann, sowie Erzeugnisse, die nach diesem Verfahren hergestellt werden |
DE102014105093B4 (de) | 2014-04-10 | 2016-01-28 | Püschner Gmbh & Co. Kg | Verfahren und Mehrkammeranlage zur Herstellung von Keramikschäumen auf Basis von wässrigen Keramiksuspensionen und von harzbasierten Schaumstoffen |
KR102176171B1 (ko) * | 2018-08-22 | 2020-11-09 | 주식회사 동성화학 | 내열성이 우수한 열성형성 멜라민 발포체 및 이의 제조방법 |
CN113710736A (zh) | 2019-05-02 | 2021-11-26 | 巴斯夫欧洲公司 | 具有降低的甲醛释放的三聚氰胺甲醛泡沫 |
KR102295346B1 (ko) * | 2019-07-17 | 2021-08-31 | 주식회사 동성케미컬 | 열성형성 멜라민 발포체 및 이의 제조 방법 |
CN111234291B (zh) * | 2020-03-06 | 2022-09-20 | 郑州峰泰纳米材料有限公司 | 一种三聚氰胺甲醛树脂阻燃泡沫的制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5580441A (en) * | 1978-12-14 | 1980-06-17 | Mitsui Toatsu Chem Inc | Production of urea resin foam |
JPS5826370B2 (ja) * | 1979-04-03 | 1983-06-02 | 三井東圧化学株式会社 | 尿素−ホルムアルデヒド樹脂発泡体の製造方法 |
JPS56166237A (en) * | 1980-05-23 | 1981-12-21 | Mitsui Toatsu Chem Inc | Foam of urea formaldehyde resin |
JPS5840330A (ja) * | 1981-09-04 | 1983-03-09 | Mitsui Toatsu Chem Inc | 尿素樹脂発泡体の製造方法 |
US4935149A (en) * | 1989-01-12 | 1990-06-19 | Calgon Corporation | Low free formaldehyde melamine-formaldehyde detackifier and method of using |
DE4123050A1 (de) * | 1991-07-12 | 1993-01-14 | Basf Ag | Modifizierte melamin-formaldehyd-harze |
US5914365A (en) * | 1997-02-06 | 1999-06-22 | Georgia-Pacific Resins, Inc. | Modified urea-formaldehyde binder for making fiber mats |
DE19735809A1 (de) * | 1997-08-18 | 1999-02-25 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von Amino- und/oder Phenoplasten |
US6497959B1 (en) * | 2000-03-30 | 2002-12-24 | General Electric Company | Use of dendrimers as a processing aid and surface modifier for thermoplastic resins |
DE10047717A1 (de) * | 2000-09-27 | 2002-04-18 | Basf Ag | Hydrophile, offenzellige, elastische Schaumstoffe auf Basis von Melamin/Formaldehyd-Harzen, ihre Herstellung und ihre Verwendung in Hygieneartikeln |
CN1216679C (zh) * | 2003-04-10 | 2005-08-31 | 上海化工研究院 | 微胶囊包覆聚磷酸铵的制备方法 |
DE10335957A1 (de) * | 2003-08-04 | 2005-02-24 | Basf Ag | Formteile aus Melamin/Formaldehyd-Schaumstoffen mit geringer Formaldehyd-Emission |
-
2005
- 2005-06-14 DE DE102005027552A patent/DE102005027552A1/de not_active Withdrawn
-
2006
- 2006-06-12 CN CN2006800211171A patent/CN101198646B/zh active Active
- 2006-06-12 ES ES06763637T patent/ES2426344T3/es active Active
- 2006-06-12 EP EP06763637.3A patent/EP1893674B1/de active Active
- 2006-06-12 US US11/917,481 patent/US20080197524A1/en not_active Abandoned
- 2006-06-12 WO PCT/EP2006/063082 patent/WO2006134083A1/de active Application Filing
- 2006-06-12 KR KR1020087000863A patent/KR101328822B1/ko active IP Right Grant
- 2006-06-12 JP JP2008516292A patent/JP5284085B2/ja active Active
- 2006-06-12 PL PL06763637T patent/PL1893674T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
PL1893674T3 (pl) | 2014-01-31 |
EP1893674A1 (de) | 2008-03-05 |
KR20080026605A (ko) | 2008-03-25 |
DE102005027552A1 (de) | 2006-12-21 |
ES2426344T3 (es) | 2013-10-22 |
EP1893674B1 (de) | 2013-08-14 |
US20080197524A1 (en) | 2008-08-21 |
CN101198646A (zh) | 2008-06-11 |
WO2006134083A1 (de) | 2006-12-21 |
KR101328822B1 (ko) | 2013-11-13 |
CN101198646B (zh) | 2011-03-02 |
JP2008544005A (ja) | 2008-12-04 |
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