JP5199131B2 - 装飾面を有する物品の形成方法 - Google Patents
装飾面を有する物品の形成方法 Download PDFInfo
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- JP5199131B2 JP5199131B2 JP2008556448A JP2008556448A JP5199131B2 JP 5199131 B2 JP5199131 B2 JP 5199131B2 JP 2008556448 A JP2008556448 A JP 2008556448A JP 2008556448 A JP2008556448 A JP 2008556448A JP 5199131 B2 JP5199131 B2 JP 5199131B2
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- ink
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- Prior art date
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- 238000010438 heat treatment Methods 0.000 claims description 5
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- IYBOGQYZTIIPNI-UHFFFAOYSA-N 2-methylhexano-6-lactone Chemical compound CC1CCCCOC1=O IYBOGQYZTIIPNI-UHFFFAOYSA-N 0.000 description 1
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- GZYXPXGNODDCBD-UHFFFAOYSA-N 3,3,6,6-tetramethyl-1,4-dioxane-2,5-dione Chemical compound CC1(C)OC(=O)C(C)(C)OC1=O GZYXPXGNODDCBD-UHFFFAOYSA-N 0.000 description 1
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- OSKVFHONCZMKCM-UHFFFAOYSA-N 4,6,6-trimethyloxepan-2-one Chemical compound CC1CC(=O)OCC(C)(C)C1 OSKVFHONCZMKCM-UHFFFAOYSA-N 0.000 description 1
- HEXADYGOPKQMSD-UHFFFAOYSA-N 5-(hydroxymethyl)oxepan-2-one Chemical compound OCC1CCOC(=O)CC1 HEXADYGOPKQMSD-UHFFFAOYSA-N 0.000 description 1
- FBGOPBALJSIXQZ-UHFFFAOYSA-N 5-nonyloxepan-2-one Chemical compound CCCCCCCCCC1CCOC(=O)CC1 FBGOPBALJSIXQZ-UHFFFAOYSA-N 0.000 description 1
- GZGQVPASOBQUKB-UHFFFAOYSA-N 6-methyloxepan-2-one Chemical compound CC1CCCC(=O)OC1 GZGQVPASOBQUKB-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
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- 239000004793 Polystyrene Substances 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
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- XKRFYHLGVUSROY-UHFFFAOYSA-N argon Substances [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 1
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- 238000010420 art technique Methods 0.000 description 1
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 1
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- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F15/00—Screen printers
- B41F15/08—Machines
- B41F15/12—Machines with auxiliary equipment, e.g. for drying printed articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/02—Combined thermoforming and manufacture of the preform
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C2793/00—Shaping techniques involving a cutting or machining operation
- B29C2793/009—Shaping techniques involving a cutting or machining operation after shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
- B29C51/082—Deep drawing or matched-mould forming, i.e. using mechanical means only by shaping between complementary mould parts
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- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2055/00—Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
- B29K2055/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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Description
a)熱成形可能なポリマーシートの少なくとも1つの主要面上に、硬化性組成物を含むインク組成物をスクリーン印刷する;
b)前記硬化性組成物を硬化し、少なくとも1つの主要面上に硬化された組成物を含むインクを有する印刷されたシートを得る;及び
c)印刷されたシートを熱成形し、装飾物品を得る;
ここで、前記硬化性組成物は、ポリイソシアネートとイソシアネート反応基を含む成分とを含み、前記インク組成物は、その中に前記硬化性組成物が可溶性又は混和性である溶媒又は溶媒ブレンドを含有する。
D7900:3M社から市販される、望ましい色のインクを調製するためのクリアーベースインク。クリアーベースインクは、PVC樹脂及びアクリル樹脂に基づき、シクロヘキサノン、芳香族溶媒及びエチレングリコールブチルエーテルアセテートの溶媒混合物を含有する。
a)50重量部のD7900;
b)40重量部の顔料分散物P1;
c)0.87重量部のジョンクリル(Joncryl)(商標)587;
d)0.43重量部のTONE(商標)200;
e)0.0002重量部のジラウリン酸ジブチルスズ;
f)1.8重量部のHMDI;
g)5.7重量部のCGS80。
D7900:3M社から市販される、望ましい色のインクを調製するためのクリアーベースインク。当該クリアーベースインクは、PVC樹脂及びアクリル樹脂に基づき、シクロヘキサノン、芳香族溶媒、及びエチレングリコールブチルエーテルアセテートの溶媒混合物を含有する。
h)30重量部のD7900クリアー樹脂;
i)60重量部の顔料分散物P1;
j)0.83重量部のジョンクリル(Joncryl)(商標)587;
k)0.41重量部のTONE(商標)200;
l)0.0002重量部のジラウリン酸ジブチルスズ;
m)0.4重量部のHMDI;
n)0.46重量部のデスモフェン(Desmophen)A450M PA/X
o)0.00035重量部のナフテン酸亜鉛(Zinc napthenate)
p)0.000029重量部のジメチルポリシロキサン
q)5.7重量部のCGS80。
1.スクリーン印刷工程
厚さ200μmの透明のポリカーボネートマクロフォール(Makrofol)(商標)(バイエルAG(Bayer AG)、(ドイツ)から入手可能)のシートに、市販の平床スクリーン印刷機を使用してスクリーン印刷した。実施例1及び2のインク組成物を使用した2工程におけるスクリーン印刷により、所望のデザインを得た。
上記で得られる印刷されたシートを、印刷された領域が雄型の型に面するような手段で、キャノン(Cannon)真空熱成形機モデル番号フォーマ(Forma)(商標)1200(コルソノバラ(Corso Novara)179−27029ヴィジェーヴァノ(Vigevano)(PV)−イタリア)に適用した。当該雄型の型は、熱成形装置の下側部分であった。当該シートが可撓性になったとき、真空により、雄型の型の外側周辺をシートで包んだ。当該ポリカーボネートの熱成形プロセスの温度は、145℃付近であった(以下のISO360方法B50)。
当該得られる多色のポリカーボネート部分について、印刷されたインク層における亀裂を視覚により検査した。当該印刷された画像に亀裂は見つからなかった。
別の方法によって硬化された代わりのインクを使用した以外は、実施例Aを繰り返した。このインクは、セリコール(SERICOL)(富士フィルム・セリコール英国(FujifilmSericol UK Limited)、ブロードスタイル(Broadstairs)、ケント(Kent)CT102LE)から市販されているUV硬化性インクディラソル(Dirasol)(商標)916/917であった。当該製造業社によって推奨されるように、インクを上記のように適用し、UVランプを使用して硬化した。
1903:3M(商標)スクリーン印刷インク1903ホワイト、3M社(米国、ミネソタ州、セントポール(St. Paul))から入手可能。
DBTDL:イソシアネート反応により重合するためのジラウリン酸ジブチルスズ触媒、ポリサイエンス社(PolySciences, Inc.)(米国、ペンシルベニア州、ウォリントン(Warrington))から入手可能。
Claims (10)
- 装飾面を有する物品の形成方法であって、下記の工程:
a)熱成形可能なポリマーシートの少なくとも1つの主要面上に、硬化性組成物を含むインク組成物をスクリーン印刷する工程;
b)硬化された組成物を含むインクを少なくとも1つの主要面上に有する、印刷されたシートを得るために、前記硬化性組成物を硬化する工程;及び
c)装飾物品を得るために、前記印刷されたシートを熱成形する工程;を含み、
前記硬化性組成物が、ポリイソシアネート、及びイソシアネート反応基を含む成分を含み、前記インク組成物が、カプロラクトン又はポリカプロラクトン化合物を更に含み、そして前記インク組成物が、前記硬化性組成物が可溶な溶媒又は溶媒ブレンドを含有する、物品の形成方法。 - 反応基を有する前記成分が、ヒドロキシル基を有するアクリルポリマーを含む、請求項1に記載の方法。
- 前記ポリイソシアネートが、ジイソシアネート又はトリイソシアネートを含む、請求項1又は2に記載の方法。
- 前記溶媒が、ケトン、エステル、アミド、又はこれらの混合物から選択される、請求項1〜3のいずれか1項に記載の方法。
- 前記溶媒が、シクロヘキサノン、イソホロン、ジアセトンアルコール、N−メチルピロリドン、メトキシプロピルアセテート、イソプロポキシエチルアセテート、エトキシエチルプロピオネート、エチルラクテート、及びこれらの混合物から選択される、請求項1〜4のいずれか1項に記載の方法。
- 前記熱成形可能なポリマーシートが、ポリカーボネート、ポリエチレンテレフタレートグリコール(PETG)、アクリロニトリルブタジエンスチレン(ABS)、熱可塑性ポリオレフィン(TPO)、ポリプロピレン、アクリル化合物、及びこれらの混合物を含む群から選択される1材料から製造される、請求項1〜5のいずれか1項に記載の方法。
- 前記熱成形可能なポリマーシートがポリカーボネートである、請求項1〜5のいずれか1項に記載の方法。
- 前記硬化工程b)が、前記印刷されたシートの加熱を含む、請求項1〜7のいずれか1項に記載の方法。
- 前記方法が、当該インク組成物を当該熱成形可能なポリマーシートに部分的に浸透させる工程を包含する、請求項1〜8のいずれか1項に記載の方法。
- 請求項1〜9のいずれか1項に記載の方法で得られる装飾面を有する物品。
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GB0603596A GB2435472A (en) | 2006-02-23 | 2006-02-23 | Method for forming an article having a decorative surface |
GB0603596.8 | 2006-02-23 | ||
PCT/US2007/004763 WO2007100681A1 (en) | 2006-02-23 | 2007-02-23 | Method for forming an article having a decorative surface |
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EP2613923A2 (en) * | 2010-09-08 | 2013-07-17 | Avery Dennison Corporation | Thermoform labeling |
EP2511352A1 (de) * | 2011-04-13 | 2012-10-17 | Bayer Materialscience AG | Siebdruckverfahren mit zu einem Polyurethanpolymer reagierender Drucktinte |
JP6068162B2 (ja) * | 2012-04-18 | 2017-01-25 | 理想科学工業株式会社 | 非水系顔料インク及び顔料複合体の製造方法 |
US20130288018A1 (en) * | 2012-04-30 | 2013-10-31 | Patrick W. Moller | System and method for printing on plastic and forming the printed plastic |
JP6238790B2 (ja) * | 2014-02-28 | 2017-11-29 | 日本カーバイド工業株式会社 | インキおよびそのインキ層を有する樹脂フィルム |
EP3124239B1 (en) * | 2014-03-26 | 2023-07-12 | Dainippon Printing Co., Ltd. | Transfer film for three-dimensional molding |
CN107077909B (zh) | 2014-10-14 | 2019-08-23 | 太阳化学公司 | 可热成型的导电油墨和涂料以及用于制造热成型设备的方法 |
JP6576166B2 (ja) * | 2015-08-31 | 2019-09-18 | 日本カーバイド工業株式会社 | インキ及び積層体 |
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CN109228426A (zh) * | 2017-07-11 | 2019-01-18 | 义乌市巨丰塑胶有限公司 | 一种花盆套的制造工艺 |
JP6909675B2 (ja) * | 2017-08-17 | 2021-07-28 | 日本カーバイド工業株式会社 | インキ及び積層体 |
JP6909676B2 (ja) * | 2017-08-17 | 2021-07-28 | 日本カーバイド工業株式会社 | インキ及び積層体 |
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- 2007-02-23 CA CA002643010A patent/CA2643010A1/en not_active Abandoned
- 2007-02-23 DE DE602007009802T patent/DE602007009802D1/de active Active
- 2007-02-23 US US12/280,071 patent/US9290031B2/en not_active Expired - Fee Related
- 2007-02-23 EP EP07751518A patent/EP1987076B1/en not_active Not-in-force
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Also Published As
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JP2009527392A (ja) | 2009-07-30 |
KR101388873B1 (ko) | 2014-04-23 |
EP1987076B1 (en) | 2010-10-13 |
DE602007009802D1 (de) | 2010-11-25 |
BRPI0708205A2 (pt) | 2011-05-17 |
WO2007100681A1 (en) | 2007-09-07 |
GB2435472A (en) | 2007-08-29 |
EP1987076A1 (en) | 2008-11-05 |
KR20080099853A (ko) | 2008-11-13 |
US9688063B2 (en) | 2017-06-27 |
CN101389680A (zh) | 2009-03-18 |
US20160193826A1 (en) | 2016-07-07 |
CA2643010A1 (en) | 2007-09-07 |
CN101389680B (zh) | 2012-01-18 |
US9290031B2 (en) | 2016-03-22 |
GB0603596D0 (en) | 2006-04-05 |
ATE484536T1 (de) | 2010-10-15 |
US20100215918A1 (en) | 2010-08-26 |
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