JP5102295B2 - コポリエステルエーテル組成物層を備える再帰反射物品、及びその作製方法 - Google Patents
コポリエステルエーテル組成物層を備える再帰反射物品、及びその作製方法 Download PDFInfo
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- JP5102295B2 JP5102295B2 JP2009521887A JP2009521887A JP5102295B2 JP 5102295 B2 JP5102295 B2 JP 5102295B2 JP 2009521887 A JP2009521887 A JP 2009521887A JP 2009521887 A JP2009521887 A JP 2009521887A JP 5102295 B2 JP5102295 B2 JP 5102295B2
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- copolyester ether
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- 239000000203 mixture Substances 0.000 title claims description 116
- 229920001634 Copolyester Polymers 0.000 title claims description 103
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- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 91
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 9
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- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
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- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
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- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- 229920012753 Ethylene Ionomers Polymers 0.000 description 1
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- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/285—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
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- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B2305/54—Filled microcapsules
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/24612—Composite web or sheet
Landscapes
- Physics & Mathematics (AREA)
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- Optics & Photonics (AREA)
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- Laminated Bodies (AREA)
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- Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Description
127マイクロメートル(5ミル)のコポリエステルエーテル組成物層又はフィルム、並びに、約90重量%のコポリエステルエーテルを有する構成成分、及び約10重量%のコポリエステルを有する構成成分を含む組成物を有する152マイクロメートル(6ミル)のブレンドフィルムの固有の機械的特性を試験した。この双方とも、テネシー州キングスポート(Kingsport)のイーストマンケミカル社(Eastman Chemical Company)製であり、そのうちコポリエステルエーテル組成物は、FN006ネオスター(NEOSTAR)(登録商標)という名称で販売されている。双方とも、ワシントン州エバレット(Everett)のアキレスUSA社(Achilles USA, Inc.)製の184マイクロメートル(7.25ミル)の可塑化PVCフィルム、並びに、ミシガン州オーバーンヒルズ(Auburn Hills)のハンツマン社(Huntzman LLC)製の102マイクロメートル(4ミル)及び254マイクロメートル(10ミル)のポリウレタンフィルムとの比較を行った。「受け取った状態のままの」フィルムのそれぞれを切断して、2.54cm(1インチ)×10.16cm(4インチ)の方形切片にした。ただし、254マイクロメートル(10ミル)のポリウレタンは、幅1.5cm(0.6インチ)〜1.9cm(0.75インチ)×長さ10cm(4インチ)に切断した。
2 PVC=可塑化ポリ塩化ビニルフィルム
3.ネオスター(Neostar)(登録商標)ブレンド=コポリエステルエーテル90重量%/コポリエステル10重量%のフィルム
4.ネオスター(Neostar)(登録商標)=コポリエステルエーテルフィルム
2 PVC=可塑化ポリ塩化ビニルフィルム
3.ネオスター(Neostar)(登録商標)ブレンド=コポリエステルエーテル90重量%/コポリエステル10重量%のフィルム
4.ネオスター(Neostar)(登録商標)=コポリエステルエーテルフィルム
5.貯蔵弾性率
6.ガラス転移温度
127ミクロン(5ミル)のフィルム、及び203ミクロン(8ミル)のコポリエステルエーテル組成物フィルム(双方とも、テネシー州キングスポート(Kingsport)のイーストマンケミカル社(Eastman Chemical Company)によってネオスター(NEOSTAR)(登録商標)という商標名で製造されている)を、178ミクロン(7.0ミル)のニッケル製初期間隔取り工具(primary spacing nickel tooling)を用いて、キャスト・硬化複製によって、ジョージア州スマーナ(Smyrna)にあるサイテックサーフェススペシャルティーズ(Cytec Surface Specialties)によって製造されているC2001というアクリレート樹脂で処理した。メリーランド州ゲイサーズバーグ(Gaithersburg)のフュージョンUVシステムズ社(Fusion UV Systems, Inc.)製のUV Dランプを、ニッケル製パターン化工具上でアクリレート樹脂をフィルムに硬化及び付着させるための設定である、最大出力の約60%という設定で使用した。試験中、フィルムは、毎分約6メートル(20フィート)のライン速度で動かした。
Claims (3)
- コポリエステルエーテル組成物から構成される第1の層及び、少なくとも部分的に上を覆う関係で前記第1の層に並置された再帰反射構造体から構成される第2の層を備える、再帰反射物品。
- 再帰反射物品を形成する方法であって、
コポリエステルエーテル組成物を含有する第1の層をもたらす工程と、
再帰反射構造体を、並置されるとともに少なくとも部分的に上を覆う位置に、前記組成物層に対して配置する工程と、を含む、方法。 - 再帰反射物品を形成する方法であって、
コポリエステルエーテル組成物を含有する第1の層を準備する工程と、
前記第1の層の少なくとも一部に、硬化可能な樹脂性組成物を結合させて、前記硬化可能な樹脂性組成物が、硬化されると、再帰反射構造体を形成させるようにする工程と、及び
前記第1の層の上で前記硬化可能な樹脂性組成物を硬化させて、再帰反射構造体を形成させ、前記再帰反射構造体を前記第1の層に結合させる工程と、を含む、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/460,749 US7842374B2 (en) | 2006-07-28 | 2006-07-28 | Retroreflective article comprising a copolyester ether composition layer and method of making same |
US11/460,749 | 2006-07-28 | ||
PCT/US2007/073196 WO2008014115A1 (en) | 2006-07-28 | 2007-07-11 | Retroreflective article comprising a copolyester ether composition layer and method of making same |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009545009A JP2009545009A (ja) | 2009-12-17 |
JP2009545009A5 JP2009545009A5 (ja) | 2010-08-12 |
JP5102295B2 true JP5102295B2 (ja) | 2012-12-19 |
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Application Number | Title | Priority Date | Filing Date |
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JP2009521887A Expired - Fee Related JP5102295B2 (ja) | 2006-07-28 | 2007-07-11 | コポリエステルエーテル組成物層を備える再帰反射物品、及びその作製方法 |
Country Status (7)
Country | Link |
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US (1) | US7842374B2 (ja) |
EP (1) | EP2046576B1 (ja) |
JP (1) | JP5102295B2 (ja) |
KR (1) | KR101401716B1 (ja) |
CN (1) | CN101495309B (ja) |
TW (1) | TW200815797A (ja) |
WO (1) | WO2008014115A1 (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101471964B (zh) * | 2007-12-27 | 2011-11-02 | 华为技术有限公司 | 一种网络地址的分配方法、网络***及网络节点 |
JP5223123B2 (ja) * | 2010-03-10 | 2013-06-26 | 豊田合成株式会社 | 表示装置 |
JP6074128B2 (ja) * | 2010-04-15 | 2017-02-01 | デクセリアルズ株式会社 | 光学体およびその製造方法、日射遮蔽部材、窓材、内装部材ならびに建具 |
KR101281153B1 (ko) * | 2011-05-24 | 2013-07-02 | (주)에스시아이 | 도로표지용 반사체 및 이의 제조방법 |
CN103971610A (zh) * | 2013-01-30 | 2014-08-06 | 宁波大红鹰学院 | 一种卡通荧光交通安全贴 |
EP3036097B1 (en) * | 2013-08-19 | 2020-09-23 | 3M Innovative Properties Company | Retroreflective sheeting including a substantially amorphous polymeric layer |
EP3036570A4 (en) * | 2013-08-19 | 2017-04-19 | 3M Innovative Properties Company | Retroreflective sheeting including a low elastic modulus layer |
JP6510318B2 (ja) * | 2015-05-14 | 2019-05-08 | スリーエム イノベイティブ プロパティズ カンパニー | ライセンスプレート用のグラフィックフィルム、並びにグラフィックフィルムを含むライセンスプレート及びその製造方法 |
US20180337460A1 (en) * | 2017-05-18 | 2018-11-22 | Srg Global Inc. | Vehicle body components comprising retroreflectors and their methods of manufacture |
US10723299B2 (en) * | 2017-05-18 | 2020-07-28 | Srg Global Inc. | Vehicle body components comprising retroreflectors and their methods of manufacture |
CN115508931A (zh) * | 2022-09-27 | 2022-12-23 | 青岛理工大学 | 一种热致变色回归反射复合材料及其应用 |
Family Cites Families (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2171986A1 (ja) | 1972-02-18 | 1973-09-28 | Coat Jean | |
JPS5225898A (en) * | 1975-08-22 | 1977-02-26 | Toray Ind Inc | Process for producing copolyesters |
US4025159A (en) * | 1976-02-17 | 1977-05-24 | Minnesota Mining And Manufacturing Company | Cellular retroreflective sheeting |
JPS6042813B2 (ja) * | 1978-06-05 | 1985-09-25 | 東レ株式会社 | ポリエステルエラストマの製造法 |
DE2949307C2 (de) * | 1979-12-07 | 1983-12-15 | Bosch und Pierburg System oHG, 4040 Neuss | Verfahren und Vorrichtung zur Veränderung des Abstands von von einem Zündimpulsgeber abgegebenen Zündsteuerimpulsen |
US4533592A (en) * | 1984-08-02 | 1985-08-06 | Minnesota Mining And Manufacturing Company | Thermally stable flame retardant reflective and retroreflective trim |
US4664966A (en) * | 1985-11-18 | 1987-05-12 | Minnesota Mining And Manufacturing Company | Enclosed-lens retroreflective sheeting having tough, weather-resistant, transparent cover film |
US5064272A (en) * | 1985-11-18 | 1991-11-12 | Minnesota Mining And Manufacturing Company | Encapsulated-lens retroreflective sheeting and method of making |
US4983436A (en) * | 1987-04-15 | 1991-01-08 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting with backing film |
US5066098A (en) * | 1987-05-15 | 1991-11-19 | Minnesota Mining And Manufacturing Company | Cellular encapsulated-lens high whiteness retroreflective sheeting with flexible cover sheet |
US5262225A (en) * | 1988-09-02 | 1993-11-16 | Minnesota Mining And Manufacturing Company | Embossable sign construction |
US5055347A (en) * | 1988-12-09 | 1991-10-08 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting adapted to be bonded to vulcanizable or curable substrate |
US5175030A (en) * | 1989-02-10 | 1992-12-29 | Minnesota Mining And Manufacturing Company | Microstructure-bearing composite plastic articles and method of making |
US5069964A (en) * | 1989-05-23 | 1991-12-03 | Minnesota Mining And Manufacturing Company | Flexible, substrate-insular retroreflective sheeting |
US5138488A (en) * | 1990-09-10 | 1992-08-11 | Minnesota Mining And Manufacturing Company | Retroreflective material with improved angularity |
ZA918849B (en) * | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
US5186597A (en) * | 1991-08-23 | 1993-02-16 | Sematech, Inc. | Apparatus for servicing of semiconductor manufacturing equipment |
US5238733A (en) * | 1991-09-30 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Stretchable nonwoven webs based on multi-layer blown microfibers |
JPH05131589A (ja) * | 1991-11-13 | 1993-05-28 | Minnesota Mining & Mfg Co <3M> | 耐可塑剤性を有する再帰反射性シート |
US5648145A (en) * | 1993-09-10 | 1997-07-15 | Reflexite Corporation | Fire-resistant, retroreflective structure |
US5450235A (en) * | 1993-10-20 | 1995-09-12 | Minnesota Mining And Manufacturing Company | Flexible cube-corner retroreflective sheeting |
US5691846A (en) * | 1993-10-20 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture |
US5614286A (en) * | 1993-10-20 | 1997-03-25 | Minnesota Mining And Manufacturing Company | Conformable cube corner retroreflective sheeting |
KR100431164B1 (ko) * | 1994-11-28 | 2004-09-16 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 착색내구성및/또는형광내구성이우수한제품 |
US5812317A (en) * | 1995-10-26 | 1998-09-22 | Minnesota Mining And Manufacturing Company | Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers |
AU7724196A (en) * | 1995-11-02 | 1997-05-22 | Minnesota Mining And Manufacturing Company | Microstructured articles with backing and methods of manufacture |
US5805338A (en) * | 1996-04-10 | 1998-09-08 | Minnesota Minning And Manufacturing Company | Pillowed flexible cube-corner sheeting and methods of manufacture |
US6531230B1 (en) | 1998-01-13 | 2003-03-11 | 3M Innovative Properties Company | Color shifting film |
KR100554582B1 (ko) * | 1998-01-13 | 2006-03-03 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 변형된 코폴리에스테르 및 개선된 다층 반사성 필름 |
US6157486A (en) * | 1998-01-13 | 2000-12-05 | 3M Innovative Properties Company | Retroreflective dichroic reflector |
US6024455A (en) * | 1998-01-13 | 2000-02-15 | 3M Innovative Properties Company | Reflective article with concealed retroreflective pattern |
US6800378B2 (en) * | 1998-02-19 | 2004-10-05 | 3M Innovative Properties Company | Antireflection films for use with displays |
US6096247A (en) * | 1998-07-31 | 2000-08-01 | 3M Innovative Properties Company | Embossed optical polymer films |
CA2375420A1 (en) * | 1999-06-17 | 2000-12-28 | 3M Innovative Properties Company | Retroreflective article having a colored layer containing reflective flakes and a dye covalently bonded to a polymer |
US6361850B1 (en) * | 1999-06-17 | 2002-03-26 | 3M Innovative Properties Company | Retroreflective article having a colored layer containing a dye covalently bonded to a polymer |
US6677028B1 (en) | 1999-09-10 | 2004-01-13 | 3M Innovative Properties Company | Retroreflective articles having multilayer films and methods of manufacturing same |
US6325515B1 (en) * | 2000-03-21 | 2001-12-04 | 3M Innovative Properties Company | Cube corner retroreflective article with enhanced pigmentation |
WO2002023232A2 (en) | 2000-09-13 | 2002-03-21 | Reflexite Corporation | Retroreflective film product |
US6972147B1 (en) * | 2000-11-09 | 2005-12-06 | Avery Dennison Corporation | Fluorescent polymeric articles fabricated from U.V. light absorbing polymer |
DE60133221T2 (de) * | 2000-11-09 | 2009-03-26 | Avery Dennison Corp., Pasadena | Aus uv-licht absorbierendem polymer hergestellte fluoreszente polymergegenstände |
CN100370279C (zh) | 2000-11-09 | 2008-02-20 | 瑞弗莱克塞特公司 | 弹性光学结构 |
US20020102389A1 (en) * | 2000-12-01 | 2002-08-01 | Nielsen Steven M. | Retroreflective laminate comprising a tear resistant film |
US6592967B2 (en) * | 2001-02-14 | 2003-07-15 | Avery Dennison Corporation | Microprism reflective sheeting with improved retention of reflectivity |
US6531214B2 (en) * | 2001-02-14 | 2003-03-11 | 3M Innovative Properties Company | Replacement for plasticized polyvinyl chloride |
JP2002341103A (ja) * | 2001-05-18 | 2002-11-27 | Lintec Corp | 光学用フィルム |
JP2002350621A (ja) * | 2001-05-25 | 2002-12-04 | Toppan Printing Co Ltd | レンズシート反射板およびそれを用いた反射型液晶表示装置 |
US6599994B2 (en) * | 2001-07-18 | 2003-07-29 | Eastman Chemical Company | Polyester blends and heat shrinkable films made therefrom |
US6723768B2 (en) | 2002-03-27 | 2004-04-20 | Eastman Chemical Company | Polyester/polycarbonate blends with reduced yellowness |
JP2003301425A (ja) * | 2002-04-12 | 2003-10-24 | Toyo Tire & Rubber Co Ltd | 視線誘導標識柱と反射体部材 |
US7618709B2 (en) * | 2002-04-30 | 2009-11-17 | Avery Dennison Corporation | Fluorescent articles having multiple film layers |
US6818293B1 (en) | 2003-04-24 | 2004-11-16 | Eastman Chemical Company | Stabilized polyester fibers and films |
US20040234724A1 (en) | 2003-05-22 | 2004-11-25 | Eastman Kodak Company | Immisible polymer filled optical elements |
US20050137359A1 (en) * | 2003-12-18 | 2005-06-23 | General Electric Company | Polyester molding composition |
US7059936B2 (en) * | 2004-03-23 | 2006-06-13 | Cabot Microelectronics Corporation | Low surface energy CMP pad |
WO2005111157A1 (en) | 2004-05-07 | 2005-11-24 | 3M Innovative Properties Company | Stain repellent optical hard coating |
-
2006
- 2006-07-28 US US11/460,749 patent/US7842374B2/en not_active Expired - Fee Related
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2007
- 2007-07-11 WO PCT/US2007/073196 patent/WO2008014115A1/en active Application Filing
- 2007-07-11 CN CN2007800277031A patent/CN101495309B/zh not_active Expired - Fee Related
- 2007-07-11 EP EP07799471.3A patent/EP2046576B1/en not_active Not-in-force
- 2007-07-11 KR KR1020097001581A patent/KR101401716B1/ko active IP Right Grant
- 2007-07-11 JP JP2009521887A patent/JP5102295B2/ja not_active Expired - Fee Related
- 2007-07-27 TW TW096127600A patent/TW200815797A/zh unknown
Also Published As
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EP2046576B1 (en) | 2013-05-01 |
EP2046576A1 (en) | 2009-04-15 |
US20080026184A1 (en) | 2008-01-31 |
CN101495309A (zh) | 2009-07-29 |
US7842374B2 (en) | 2010-11-30 |
TW200815797A (en) | 2008-04-01 |
KR101401716B1 (ko) | 2014-06-19 |
WO2008014115A1 (en) | 2008-01-31 |
JP2009545009A (ja) | 2009-12-17 |
EP2046576A4 (en) | 2012-04-18 |
CN101495309B (zh) | 2012-08-29 |
KR20090033455A (ko) | 2009-04-03 |
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