JP5053591B2 - 水性多彩模様塗料 - Google Patents
水性多彩模様塗料Info
- Publication number
- JP5053591B2 JP5053591B2 JP2006217756A JP2006217756A JP5053591B2 JP 5053591 B2 JP5053591 B2 JP 5053591B2 JP 2006217756 A JP2006217756 A JP 2006217756A JP 2006217756 A JP2006217756 A JP 2006217756A JP 5053591 B2 JP5053591 B2 JP 5053591B2
- Authority
- JP
- Japan
- Prior art keywords
- aqueous
- aqueous resin
- water
- coating film
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003973 paint Substances 0.000 title claims description 95
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 59
- 238000000576 coating method Methods 0.000 claims description 116
- 239000011248 coating agent Substances 0.000 claims description 109
- 229920005989 resin Polymers 0.000 claims description 89
- 239000011347 resin Substances 0.000 claims description 89
- 239000002245 particle Substances 0.000 claims description 67
- 239000000203 mixture Substances 0.000 claims description 30
- 239000008199 coating composition Substances 0.000 claims description 23
- 239000012736 aqueous medium Substances 0.000 claims description 15
- 239000003086 colorant Substances 0.000 claims description 15
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 13
- 229920001282 polysaccharide Polymers 0.000 claims description 13
- 239000005017 polysaccharide Substances 0.000 claims description 13
- 125000000524 functional group Chemical group 0.000 claims description 12
- 229910021645 metal ion Inorganic materials 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 150000002429 hydrazines Chemical class 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 125000005587 carbonate group Chemical group 0.000 claims description 3
- 150000004676 glycans Chemical class 0.000 claims 2
- -1 2-ethylhexyl Chemical group 0.000 description 68
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 50
- 238000004519 manufacturing process Methods 0.000 description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 23
- 239000000178 monomer Substances 0.000 description 20
- 239000000975 dye Substances 0.000 description 19
- 239000000839 emulsion Substances 0.000 description 19
- 239000000049 pigment Substances 0.000 description 14
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- 150000004804 polysaccharides Chemical class 0.000 description 11
- 229920000178 Acrylic resin Polymers 0.000 description 10
- 239000004925 Acrylic resin Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229920005862 polyol Polymers 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 150000002736 metal compounds Chemical class 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 238000013461 design Methods 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 6
- 229920001228 polyisocyanate Polymers 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000000987 azo dye Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 5
- 125000003700 epoxy group Chemical group 0.000 description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide group Chemical group NNC(=O)N DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 239000012463 white pigment Substances 0.000 description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 3
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000001055 blue pigment Substances 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 125000003367 polycyclic group Chemical group 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920005749 polyurethane resin Polymers 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- RHUYHJGZWVXEHW-UHFFFAOYSA-N 1,1-Dimethyhydrazine Chemical compound CN(C)N RHUYHJGZWVXEHW-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LGNQGTFARHLQFB-UHFFFAOYSA-N 1-dodecyl-2-phenoxybenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1 LGNQGTFARHLQFB-UHFFFAOYSA-N 0.000 description 2
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 description 2
- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
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- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Chemical class 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
1.
少なくとも2色の着色塗料粒子(A)並びに塗膜形成成分(B)を含んでなる水性多彩模様塗料組成物であって、着色塗料粒子(A)が、水性樹脂(a1)、着色剤(a2)及び水溶性多糖類を含む水性塗料組成物を、水溶性多糖類と水不溶性もしくは難溶性の塩を形成し得る一価又は多価の金属イオンを含有する水性媒体と接触させることにより得られるものであり、塗膜形成成分(B)が、低屈折率である水性樹脂(b1)及び高屈折率である水性樹脂(b2)を含んでなり、
水性樹脂(b2)に含まれる芳香族環、脂環式環、チッソ含有複素環及びカーボネート鎖の含有量が水性樹脂(b1)よりも多いものであって、
水性樹脂(b1)により形成される塗膜の屈折率と水性樹脂(b2)により形成される塗膜の屈折率との差が0.03以上であることを特徴とする水性多彩模様塗料組成物、
2.
着色塗料粒子(A)が、反応性官能基(x)を含有してなり、且つ塗膜形成成分(B)が、反応性官能基(x)と反応し得る反応性官能基(y)を含有する1項に記載の水性多彩模様塗料組成物、
3.
着色塗料粒子(A)が、水性樹脂(a1)としてカルボニル基含有水性樹脂を含み、塗膜形成成分(B)が、水性樹脂(b1)及び/又は水性樹脂(b2)としてカルボニル基含有水性樹脂を含んでなり、着色塗料粒子(A)及び/又は塗膜形成成分(B)が、ヒドラジン誘導体を含有する1項又は2項に記載の水性多彩模様塗料組成物、
4.
被塗面に、下塗り塗料を介してまたは介さずに1項ないし3項のいずれか1項に記載の水性多彩模様塗料組成物を塗装することを特徴とする塗装方法、
に関する。
上記着色塗料粒子(A)としては、材料、製造方法など特に制限されるものではなく従来公知のものを使用できるが、例えば、水性樹脂(a1)並びに着色剤(a2)を含んでなる水性塗料組成物を多糖類金属塩ゲル中に内包してなるものであると、好適である。
本発明の水性多彩模様塗料は、多彩模様塗膜の耐水性等の塗膜物性を確保し、且つ塗装作業性を向上させるために着色塗料粒子(A)に加えて塗膜形成成分(B)を含有する。塗膜形成成分(B)は、それ自体成膜性を有するものであり、非架橋型及び架橋型のいずれであってもよい。
被塗面としては、例えば、石膏ボード、コンクリート壁、モルタル壁、スレート板、PC板、ALC板、セメント珪酸カルシウム板、木材、石材、プラスチック成形物、金属加工材等の基材の表面、これら基材上に設けられたアクリル樹脂系、アクリルウレタン樹脂系、ポリウレタン樹脂系、フッ素樹脂系、シリコンアクリル樹脂系、酢酸ビニル樹脂系、エポキシ樹脂系等の塗膜面、ポリ塩化ビニル、ポリオレフィン、紙、布等の材質からなる壁紙面などを挙げることができる。
ここで用いられる下塗り塗料としては、基材表面の種類や状態などに応じて適宜選択することができ、例えば、シーラー、下地調整材等の下塗り塗料を使用することができる。また、通常の上塗り塗料を本発明の塗料組成物の下地形成用塗料として塗装することも可能である。
製造例1
容量2リットルの4つ口フラスコに脱イオン水285部、「Newcol707SF」(注1)1部を加え、窒素置換後、85℃に保った。この中に下記組成をエマルション化してなるプレエマルションの3%分及び3部の過硫酸アンモニウムを120重量部の脱イオン水に溶解させた溶液123部のうち41部を添加し、添加20分後から残りのプレエマルション及び残りの過硫酸アンモニウム水溶液を4時間かけて滴下した。
脱イオン水 368部
スチレン 600部
n−ブチルアクリレート 370部
ダイアセトンアクリルアミド 20部
メタクリル酸 10部
「Newcol707SF」(注1) 66部
滴下終了後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いでアンモニア水でpH8〜9に調整し、固形分55%のエマルション(a1)を得た。エマルション(a1)の粒子径は165nm、pHは8.4であり、このエマルション(a1)から形成される塗膜の屈折率は1.54であった。
(注1)「ニューコール707SF」:商品名、日本乳化剤社製、ポリオキシエチレン鎖を有するアニオン性界面活性剤、不揮発分30%。
容量2リットルの4つ口フラスコに脱イオン水285部、「Newcol707SF」(注1)1部を加え、窒素置換後、85℃に保った。この中に下記組成をエマルション化してなるプレエマルションの3%分及び1.5部の過硫酸アンモニウムを120部の脱イオン水に溶解させた溶液123部のうち41部を添加し、添加20分後から残りのプレエマルション及び残りの過硫酸アンモニウム水溶液を4時間かけて滴下した。
脱イオン水 368部
メチルメタクリレート 600部
n−ブチルアクリレート 370部
ダイアセトンアクリルアミド 20部
メタクリル酸 10部
「Newcol707SF」(注1) 66部
滴下終了後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いでアンモニア水でpH8〜9に調整し、固形分55%のエマルション(a2)を得た。エマルション(a2)の粒子径は170nm、pHは8.2であり、この
エマルション(a2)から形成される塗膜の屈折率は1.48であった。
容量2リットルの4つ口フラスコに脱イオン水285部、「Newcol707SF」(注1)1部を加え、窒素置換後、85℃に保った。この中に下記組成をエマルション化してなるプレエマルションの3%分及び3部の過硫酸アンモニウムを120部を脱イオン水に溶解させた溶液123部のうち41部を添加し、添加20分後から残りのプレエマルション及び残りの過硫酸アンモニウム水溶液を4時間かけて滴下した。
脱イオン水 368部
メチルメタクリレート 600部
エチルアクリレート 370部
ダイアセトンアクリルアミド 20部
メタクリル酸 10部
「Newcol707SF」(注1) 66部
滴下終了後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いでアンモニア水でpH8〜9に調整し、固形分55%のエマルション(a3)を得た。エマルション(a3)の粒子径は170nm、pHは8.1であり,エマルション(a3)から形成される塗膜の屈折率は1.48であった。
製造例4
還流冷却器、温度計および攪拌器を備えた反応器に、ポリテトラメチレンカーボネートジオール(分子量2000)410部、イソホロンジイソシアネート133部、トリエチルアミン中和ジメチロールプロピオン酸46.8部、メチルエチルケトン1480部を入れ、50℃にて窒素雰囲気下2時間ウレタン化反応を行い、NCO末端のプレポリマー溶液を得た。30℃に調節した該プレポリマー溶液に、1370部の脱イオン水を、攪拌しながら25部/分の速度で滴下し、プレポリマー溶液のエマルションを作製した。その後、鎖延長剤としてイソホロンジアミン(IPDA)の20%水溶液136部を30分かけて添加した後、温度を40℃に昇温し、30分反応させた。減圧下に3時間かけて80℃まで昇温しながら、脱溶剤し、固形分40%のポリウレタンディスパージョン(a4)を得た。ポリウレタンディスパージョン(a4)から形成される塗膜の屈折率は1.56であった。
製造例5
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより白顔料ペーストを得た。
水 45部
「スラオフ72N」(注2) 3部
「DISPER BYK−190」(注3) 6部
「TITANIX JR−605」(注4) 100部
(注2)「スラオフ72N」:商品名、日本エンバイロケミカルズ社製、防腐剤、
(注3)「DISPER BYK−190」:商品名、BYKケミー社製、分散剤、
(注4)「TITANIX JR−605」:商品名、テイカ社製、チタン白。
製造例6
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより青顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注2) 1部
「DISPER BYK−190」(注3) 6部
「SNデフォーマー380」(注5) 2部
フタロシアニンブルー 25部
(注5)「SNデフォーマー380」:商品名、サンノプコ社製、消泡剤。
製造例7
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより赤錆顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注2) 1部
「DISPER BYK−190」(注3) 6部
「SNデフォーマー380」(注5) 2部
酸化鉄 30部
黒顔料ペーストの製造
製造例8
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより黒顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注2) 1部
「DISPER BYK−190」(注3) 6部
「SNデフォーマー380」(注5) 2部
カーボンブラック 25部
着色塗料粒子用の水性液状組成物の製造
製造例9
容器に下記の成分を順次配合し、均一となるように攪拌混合して、着色塗料粒子用の水性液状組成物(A−1)を得た。
55%エマルション(a2) 364部
「TEXANOL」(注6) 10部
白顔料ペースト 200部
「SNデフォーマー380」(注5) 4部
「アデカノールUH438」(注7) 4部
2%アルギン酸ナトリウム 360部
(注6)「TEXANOL」:商品名、イーストマンケミカル社製、2,2,4−トリメチル−1,3−ペンタンジオールモノイソブチレート、造膜助剤、
(注7)「アデカノールUH438」:商品名、アデカ社製、ポリエーテルウレタン変性物。
上記製造例9において、配合組成を下記表1に示す配合組成に変える以外は製造例9と同様にして、水性液状組成物(A−2)〜(A−4)を製造した。
製造例13
4リットルステンレス容器に、0.15%水酸化カルシウム(注8)水溶液を1,300部仕込み、75mmの径を有する攪拌羽根を用いて回転速度2,500rpmで攪拌しながら、上記で得られた水性液状組成物(A−1)650部を徐々に容器内に滴下し、着色塗料粒子を生成させた。次いで容器内液を同回転速度でさらに15分攪拌した後、200メッシュの金網を用いて濾別し、着色塗料粒子(I−1)を得た。得られた着色塗料粒子(I−1)は、固形分が20%であった。
(注8) 水酸化カルシウム:25℃の水100gに対して0.15g溶解。
製造例13において、水性液状組成物(A−1)の代わりに下記表2に示す水性液状組成物を使用する以外は上記製造例13と同様にして、着色塗料粒子(I−2)〜(I−4)を得た。
製造例17
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間攪拌混合することにより、固形分50%の水性クリヤー塗料(C1)を得た。
55%エマルション(a1) 750部
「TEXANOL」(注6) 50部
水 279部
「タルク SS」(注9) 250部
「SNデフォーマー380」(注5) 10部
「アデカノールUH438」 (注7) 6部
(注9)「タルク SS」:商品名、日本タルク社製、タルク。
上記製造例17において、配合組成を下記表3に示す配合組成に変える以外は製造例17と同様にして、水性クリヤー塗料(C2)〜(C4)を製造した。
実施例1〜4及び比較例1〜2
500ミリリットルのステレンス容器に、下記表4に示す配合組成で、前記で得た着色塗料粒子などを順次攪拌しながら配合し、多彩模様塗料(1)〜(6)を製造した。
スレート板(150×70×3mm)上に、「EPシーラー透明」(関西ペイント社製、水系シーラー)を塗布量100g/m2になるようにローラー塗装し乾燥させた後、「ビニデラックス300」(関西ペイント社製、JIS K 5663 1種適合塗料)を塗布量100g/m2になるようにローラー塗装し、気温20℃、相対湿度60%の条件下で1日間乾燥させたものを被塗板とし、この上に上記実施例及び比較例で得た各多彩模様塗料を塗布量300g/m2になるようにスプレーで1回塗装した。その後、気温23℃、相対湿度60%の条件下で7日間乾燥して、各試験塗板を得た。得られた試験塗板を下記性能試験に供した。結果を表4に併せて示す。
(*1)塗膜の意匠性
○:模様が鮮やかで且つ模様の境界線が不明瞭であるので深みが感じられ、陶磁器のような独特の意匠性がある、△:模様の鮮やかさはあるが、模様の境界線が明瞭であるので深みが感じられず、陶磁器のような独特の意匠性が不十分、×:外観不良。
(*2)耐水性
◎:良好、○:わずかに艶引けが認められるが、実用レベル、△:艶引け、白化、フクレが認められる、×:著しくフクレが認められる、又は塗膜が軟化する
(*3)貯蔵安定性
各塗料を容量が1Lの内面コート缶に1kg入れ、40℃の恒温室で60日間貯蔵した。その後、室温に戻し、容器の中の状態を目視にて観察し、次の基準で評価した。
○:分離が認められず、着色粒子の合一や破壊も認められない、△:ソフトケーキングや分離が認められるが、攪拌により均一となる、×:ハードケーキングや分離が認められ、元に戻らない。
Claims (4)
- 少なくとも2色の着色塗料粒子(A)並びに塗膜形成成分(B)を含んでなる水性多彩模様塗料組成物であって、着色塗料粒子(A)が、水性樹脂(a1)、着色剤(a2)及び水溶性多糖類を含む水性塗料組成物を、水溶性多糖類と水不溶性もしくは難溶性の塩を形成し得る一価又は多価の金属イオンを含有する水性媒体と接触させることにより得られるものであり、塗膜形成成分(B)が、低屈折率である水性樹脂(b1)及び高屈折率である水性樹脂(b2)を含んでなり、
水性樹脂(b2)に含まれる芳香族環、脂環式環、チッソ含有複素環及びカーボネート鎖の含有量が水性樹脂(b1)よりも多いものであって、
水性樹脂(b1)により形成される塗膜の屈折率と水性樹脂(b2)により形成される塗膜の屈折率との差が0.03以上であることを特徴とする水性多彩模様塗料組成物。 - 着色塗料粒子(A)が、反応性官能基(x)を含有してなり、且つ塗膜形成成分(B)が、反応性官能基(x)と反応し得る反応性官能基(y)を含有する請求項1に記載の水性多彩模様塗料組成物。
- 着色塗料粒子(A)が、水性樹脂(a1)としてカルボニル基含有水性樹脂を含み、塗膜形成成分(B)が、水性樹脂(b1)及び/又は水性樹脂(b2)としてカルボニル基含有水性樹脂を含んでなり、着色塗料粒子(A)及び/又は塗膜形成成分(B)が、ヒドラジン誘導体を含有する請求項1又は2に記載の水性多彩模様塗料組成物。
- 被塗面に、下塗り塗料を介してまたは介さずに請求項1ないし3のいずれか1項に記載の水性多彩模様塗料組成物を塗装することを特徴とする塗装方法。
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