JP4454319B2 - 重合体組成物及びその製法 - Google Patents
重合体組成物及びその製法 Download PDFInfo
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- JP4454319B2 JP4454319B2 JP2004003628A JP2004003628A JP4454319B2 JP 4454319 B2 JP4454319 B2 JP 4454319B2 JP 2004003628 A JP2004003628 A JP 2004003628A JP 2004003628 A JP2004003628 A JP 2004003628A JP 4454319 B2 JP4454319 B2 JP 4454319B2
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Description
オレフィン系重合体(A)は、フィルム、シート、ファイバーなどに成形可能な程度の分子量を有するものであれば、樹脂状のものでもエラストマー状のものであってもよい。より具体的にはエチレンの単独重合体又はエチレンと炭素数3〜12のα−オレフィンとの共重合体、例えば高圧法ポリエチレン、中・高密度ポリエチレン、直鎖状低密度ポリエチレン、超低密度ポリエチレンなどの各種ポリエチレン、ポリプロピレン、ポリ−1−ブテン、ポリ−4−メチル−1−ペンテンなどのポリオレフィン樹脂、エチレンと極性モノマーとの共重合体、例えばエチレン・酢酸ビニル共重合体、エチレンと不飽和カルボン酸、例えばアクリル酸、メタクリル酸、マレイン酸モノエチル、無水マレイン酸などとの共重合体、エチレンと1種又は2種以上の不飽和カルボン酸エステル、例えばアクリル酸メチル、アクリル酸エチル、アクリル酸イソブチル、アクリル酸nブチル、アクリル酸−2−エチルヘキシル、メタクリル酸メチル、マレイン酸ジメチルなどとの共重合体、エチレンと上記のような不飽和カルボン酸と不飽和カルボン酸エステルの共重合体、ポリオレフィン系エラストマーの如きオレフィン系重合体あるいはこれら2種以上の混合物などを例示することができる。これらの中では、とりわけ各種有機添加剤の大量配合が困難なポリオレフィン樹脂に適用するのが最も好ましい。
オレフィン系重合体(A)としてエチレン・酢酸ビニル共重合体(エバフレックスP1405、三井・デュポンポリケミカル(株)製:EVAと略して記す)、配合剤(B)としてフェノトリン(殺虫剤:住友化学工業(株)製、商品名スミスリン)、昇華性物質(C)としてトリイソプロピル−S−トリオキサン、無機充填材(D)としてシリカ(AZ−200、日本シリカ工業(株)製)をそれぞれ用いた。前記の物質を表1に記載した割合で、まずスーパーミキサーを用いてエチレン・酢酸ビニル共重合体、シリカおよび昇華性物質を混合し、次いでフェノトリンを加えてさらに撹拌を続けた。
実施例1〜2において、重合体組成物中に昇華性物質を配合しないこと以外は実施例1〜2と同様におこなった。樹脂組成およびブリードアウト量の測定結果を表1に併せて記した。
オレフィン系重合体(A)として実施例1で用いたと同じエチレン・酢酸ビニル共重合体(EVAと略す)、ポリ塩化ビニル(サン・アロー化成(株)製、PVCと略す)(参考例)、線状低密度ポリエチレン(ウルトゼックス 20100J、三井住友ポリオレフィン(株)製、LLDPEと略す)、プロピレン単独重合体(J105W、三井住友ポリオレフィン(株)製、PPと略す)、プロピレンランダム共重合体(J704WA、三井住友ポリオレフィン(株)製、r−PPと略す)及びプロピレンブロック共重合体(J226EA、三井住友ポリオレフィン(株)製、b−PPと略す)を用いた。また配合剤(B)として、帯電防止剤[エレクトロストリッパーEA(ラウリルジエタノールアミン)、花王(株)製]を用いた。昇華性物質およびシリカは実施例1で用いたものと同じ物質を用いた。
熱可塑性重合体(A):66質量%
帯電防止剤 :14質量%
昇華性物質 :10質量%
シリカ :10質量%
4:ブリードアウトが全く見られなかった。
3:表面に微量ブリードアウトが見られた。
2:ブリードアウトが少し見られた。
1:非常に多くのブリードアウトが見られた。
実施例3〜8において、昇華性物質を配合しなかった以外は実施例3〜8と同様に行なった。すなわち、各成分の混合割合は次に記す通りであった。
熱可塑性重合体(A):76質量%
帯電防止剤 :14質量%
昇華性物質 : 0質量%
シリカ :10質量%
実際例5又は比較例5において、帯電防止剤、昇華性物質(C)及びシリカ(D)の配合量を表4に示すように変更した以外は同様の評価を行なった。実施例5及び比較例5の結果を併せて表4に示す。
実施例8において、帯電防止剤、昇華性物質(C)及びシリカ(D)の配合量を表5に示すように変更した以外は同様の評価を行なった。実施例8及び比較例8の結果を併せて表5に示す。
Claims (10)
- オレフィン系重合体(A)、100質量部当たり、ピレスロイド系殺虫剤又はポリ(オキシエチレン)アルキルアミン(B)0.01〜350質量部及びトリイソプロピル−S−トリオキサン、トリ−t−ブチル−S−トリオキサン、パラジクロルベンゼン、ナフタリン、樟脳、硫黄及びトリシクロデカンから選ばれる昇華性物質(C)0.1〜100質量部からなる重合体組成物。
- 前記オレフィン系重合体(A)が、ポリオレフィン樹脂であることを特徴とする請求項1に記載の重合体組成物。
- 前記ピレスロイド系殺虫剤又はポリ(オキシエチレン)アルキルアミン(B)が、ラウリルジエタノールアミンであることを特徴とする請求項1または2に記載の重合体組成物。
- 前記ピレスロイド系殺虫剤又はポリ(オキシエチレン)アルキルアミン(B)が、フェノトリンであることを特徴とする請求項1または2に記載の重合体組成物。
- 前記昇華性物質(C)が、トリイソプロピル−S−トリオキサンである請求項1〜4のいずれかに記載の重合体組成物。
- 前記オレフィン系重合体(A)、前記ピレスロイド系殺虫剤又はポリ(オキシエチレン)アルキルアミン(B)及び昇華性物質(C)を、オレフィン系重合体(A)の溶融条件下に混合したものである請求項1〜5のいずれかに記載の重合体組成物。
- さらに無機充填剤(D)が、オレフィン系重合体(A)100質量部当たり、0.1〜100質量部配合されてなる請求項1〜6のいずれかに記載の重合体組成物。
- 無機充填剤(D)がシリカである請求項7に記載の重合体組成物。
- オレフィン系重合体(A)100質量部当り、ピレスロイド系殺虫剤又はポリ(オキシエチレン)アルキルアミン(B)を0.01〜350質量部及びトリイソプロピル−S−トリオキサン、トリ−t−ブチル−S−トリオキサン、パラジクロルベンゼン、ナフタリン、樟脳、硫黄及びトリシクロデカンから選ばれる昇華性物質(C)を0.1〜100質量部を、オレフィン系重合体(A)の溶融条件下に混合することを特徴とする重合体組成物の製造方法。
- 無機充填剤(D)の存在下に溶融混合することを特徴とする請求項9に記載の重合体組成物の製造方法。
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