JP4381898B2 - プロピレン系重合体、プロピレン系重合体の製造方法、及び塗装性材料 - Google Patents
プロピレン系重合体、プロピレン系重合体の製造方法、及び塗装性材料 Download PDFInfo
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- JP4381898B2 JP4381898B2 JP2004180947A JP2004180947A JP4381898B2 JP 4381898 B2 JP4381898 B2 JP 4381898B2 JP 2004180947 A JP2004180947 A JP 2004180947A JP 2004180947 A JP2004180947 A JP 2004180947A JP 4381898 B2 JP4381898 B2 JP 4381898B2
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- RXUVQQVBBHXRNR-UHFFFAOYSA-N 3-ethylhex-1-en-1-ol Chemical compound CCCC(CC)C=CO RXUVQQVBBHXRNR-UHFFFAOYSA-N 0.000 description 1
- OLGHJTHQWQKJQQ-UHFFFAOYSA-N 3-ethylhex-1-ene Chemical compound CCCC(CC)C=C OLGHJTHQWQKJQQ-UHFFFAOYSA-N 0.000 description 1
- YVQDJVQSDNSPFR-UHFFFAOYSA-N 4,8-dimethyldeca-1,4,8-triene Chemical compound CC=C(C)CCC=C(C)CC=C YVQDJVQSDNSPFR-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- HBPSHRBTXIZBDI-UHFFFAOYSA-N 4-ethylidene-8-methylnona-1,7-diene Chemical compound C=CCC(=CC)CCC=C(C)C HBPSHRBTXIZBDI-UHFFFAOYSA-N 0.000 description 1
- RMDKEBZUCHXUER-UHFFFAOYSA-N 4-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1(C)C2 RMDKEBZUCHXUER-UHFFFAOYSA-N 0.000 description 1
- TXQHJLUVWZNSLH-UHFFFAOYSA-N 5-ethenyl-2,5-dimethylcyclohexa-1,3-diene Chemical compound CC1(C=C)CC=C(C=C1)C TXQHJLUVWZNSLH-UHFFFAOYSA-N 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- PCBPVYHMZBWMAZ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C)CC1C=C2 PCBPVYHMZBWMAZ-UHFFFAOYSA-N 0.000 description 1
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 1
- OZYYQTRHHXLTKX-UHFFFAOYSA-N 7-octenoic acid Chemical class OC(=O)CCCCCC=C OZYYQTRHHXLTKX-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- AWQOXJOAQMCOED-UHFFFAOYSA-N 8-Nonenoic acid Chemical class OC(=O)CCCCCCC=C AWQOXJOAQMCOED-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WQCUULHFAPJBIS-UHFFFAOYSA-N CCCCCCCCCCC=C.CCCCCCCCCCCCC=C Chemical compound CCCCCCCCCCC=C.CCCCCCCCCCCCC=C WQCUULHFAPJBIS-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- LDABFTUDTQCWKA-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].C(C)(C)[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C LDABFTUDTQCWKA-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000005382 boronyl group Chemical group 0.000 description 1
- SIIVGPQREKVCOP-UHFFFAOYSA-N but-1-en-1-ol Chemical compound CCC=CO SIIVGPQREKVCOP-UHFFFAOYSA-N 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical group 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- HYPABJGVBDSCIT-UPHRSURJSA-N cyclododecene Chemical compound C1CCCCC\C=C/CCCC1 HYPABJGVBDSCIT-UPHRSURJSA-N 0.000 description 1
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- ICQJNCNVUCTBHZ-UHFFFAOYSA-N dec-1-en-1-ol Chemical compound CCCCCCCCC=CO ICQJNCNVUCTBHZ-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- XUDOZULIAWNMIU-UHFFFAOYSA-N delta-hexenoic acid Chemical class OC(=O)CCCC=C XUDOZULIAWNMIU-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical group C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- CQKHFONAFZDDKV-UHFFFAOYSA-N dodec-1-en-1-ol Chemical compound CCCCCCCCCCC=CO CQKHFONAFZDDKV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- PDSKWUZFFRWRCD-UHFFFAOYSA-N hept-6-en-1-amine Chemical compound NCCCCCC=C PDSKWUZFFRWRCD-UHFFFAOYSA-N 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- JHEPBQHNVNUAFL-UHFFFAOYSA-N hex-1-en-1-ol Chemical compound CCCCC=CO JHEPBQHNVNUAFL-UHFFFAOYSA-N 0.000 description 1
- FICBXRYQMBKLJJ-UHFFFAOYSA-N hex-5-en-1-amine Chemical compound NCCCCC=C FICBXRYQMBKLJJ-UHFFFAOYSA-N 0.000 description 1
- GWSURTDMLUFMJH-UHFFFAOYSA-N hexadec-1-en-1-ol Chemical compound CCCCCCCCCCCCCCC=CO GWSURTDMLUFMJH-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- ACJQRYKUUGFHPV-UHFFFAOYSA-N icos-1-en-1-ol Chemical compound CCCCCCCCCCCCCCCCCCC=CO ACJQRYKUUGFHPV-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
- MDVPRIBCAFEROC-UHFFFAOYSA-N oct-1-en-1-ol Chemical compound CCCCCCC=CO MDVPRIBCAFEROC-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- LHTVMBMETNGEAN-UHFFFAOYSA-N pent-1-en-1-ol Chemical compound CCCC=CO LHTVMBMETNGEAN-UHFFFAOYSA-N 0.000 description 1
- LQAVWYMTUMSFBE-UHFFFAOYSA-N pent-4-en-1-ol Chemical compound OCCCC=C LQAVWYMTUMSFBE-UHFFFAOYSA-N 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical class OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical class O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UEIKOIYORDKQGZ-UHFFFAOYSA-N tetradec-1-en-1-ol Chemical compound CCCCCCCCCCCCC=CO UEIKOIYORDKQGZ-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
本発明に係るプロピレン系重合体は、プロピレンと水酸基含有オレフィンとの共重合によって得られるプロピレン系重合体である。
(A)上記一般式[3]で表されるメタロセン化合物と、
(B)(B-1) 有機金属化合物、
(B-2) 有機アルミニウムオキシ化合物、および
(B-3) メタロセン化合物(A)と反応してイオン対を形成する化合物
から選ばれる少なくとも1種の化合物、
さらに必要に応じて、
(C)微粒子状担体
から構成される、一般に公知の方法で重合触媒として用いることが出来、例えばWO01/27124記載の方法を採用することが出来る。
本発明に係るプロピレン系重合体は、水酸基を含有するポリオレフィン材料として、塗装性、接着性、印刷性等に優れた材料として用いられる。例えば、自動車外装材、樹脂フィルムとの張り合わせ、表面印刷用樹脂等に用いられる。またアルミニウム等の金属蒸着用フィルム樹脂として、高バリア性を付与した樹脂としても用いられる。さらに、他樹脂とのポリマーアロイ用相溶化剤としても好適に用いられる。その他、カレンダー成形、押出成形、射出成形、ブロー成形、プレス成形、スタンピング成形などの各種成型よって加工することができ、射出成型品、中空容器、フィルムシート、繊維など以外にも、その用途としては制限無く用いることができる。
攪拌器を備え、十分に窒素置換した内容積1000mlのガラス製重合器に、トルエン(800ml)を導入し、プロピレンガス(100NL/h)を供給しながら温度を40℃に保った。トリイソブチルアルミニウム(22mmol)と1−ウンデセノール(20mmol)を加え10分間攪拌した後、メチルアルモキサン(MAO、アルベマール社製、10%トルエン溶液)3mmol[Al]で活性化されたジメチルシリルビス(2−メチル−4−フェニルインデニル)ジルコニウムジクロライド(0.003mmol)を重合器内に加え、温度を40℃に保ちながら15分間重合を行った。メタノールを重合器内に導入して重合を終了し、重合液を2Lの塩酸含有のメタノール中に注ぎ込み、濾過によりポリマーを回収した。減圧下80℃で10時間乾燥し、得られたポリマーは17.9gであった。ポリマーはTm=132.7℃、GPCで測定したMw=456,000、Mn=155,000であり、Mw/Mn=2.9であった。1H−NMR測定から得られたポリマー中のOH基含量は、1.94mol%であった。
トリイソブチルアルミニウムを11mmol、1−ウンデセノールを10mmol用い、水素を5NL/hで供給した以外は実施例1と同様に重合を行い、25.2gのポリマーが得られた。ポリマーはTm=150.3℃、GPCで測定したMw=95,000、Mn=37,000であり、Mw/Mn=2.6であった。1H−NMR測定から得られたポリマー中のOH基含量は、0.66mol%であった。
イソプロピル(3−t−ブチル−5−メチルシクロペンタジエニル)(フルオレニル)ジルコニウムジクロリド(5.1mg)の代わりに、エチレンビス(インデニル)ジルコニウムジクロリド(4.2mg)を用いた以外は、実施例1と同様に重合を行ない、40.4gのポリマーが得られた。ポリマーはTm=115.4℃、GPCで測定したMw=55,000、Mn=21,000であり、Mw/Mn=2.6であった。1H−NMR測定から得られたポリマー中のOH基含量は、2.30mol%であった。
Claims (4)
- プロピレンと、水酸基含有オレフィンからなるプロピレン系重合体であって、(i) 該重合体中の水酸基含有オレフィン量が10mol%以下であり、(ii) 該重合体のゲルパーミエーションクロマトグラフィ(GPC)測定によって得られた重量平均分子量(Mw)が5000以上であり、(iii) 重量平均分子量(Mw)と数平均分子量(Mn)の比の値(Mw/Mn)が、1.0〜3.5の範囲にあり、(iv) 該重合体のDSCで測定した融点([Tm];℃)と核磁気共鳴(NMR)で測定した水酸基含有オレフィン量([−OH];mol%)とが、0<[−OH]≦3、かつ下記関係式(Eq-1)を満たすことを特徴とするプロピレン系重合体。
- 下記一般式[3]の構造のメタロセン化合物を含んだ触媒成分から製造されることを特徴とする請求項1に記載のプロピレン系重合体。
(式中、Mは周期表第4族の遷移金属原子を示し、R1は、互いに同一でも異なっていてもよく、炭素原子数1〜6の炭化水素基を示し、R2、R4、R5およびR6は、互いに同一でも異なっていてもよく、水素原子、ハロゲン原子またはR1と同様の炭素原子数1〜6の炭化水素基を示し、R3は互いに同一でも異なっていてもよく、炭素原子数6〜16のアリール基を示す。X1およびX2はハロゲン、炭化水素基、アニオン配位子または孤立電子対で配位可能な中性配位子から同一または異なる組合せで選んでもよく、Yは炭素原子数1〜20の2価の炭化水素基、炭素原子数1〜20の2価のハロゲン化炭化水素基、2価のケイ素含有基、2価のゲルマニウム含有基、2価のスズ含有基、−O−、−CO−、−S−、−SO−、−SO2−、−Ge−、−Sn−、−NR7−、−PR7−、−P(O)R7−、−BR7−、−AlR7−(但し、R7は互いに同一でも異なっていてもよく、炭素原子数1〜20の2価の炭化水素基、炭素原子数1〜20の2価のハロゲン化炭化水素基、水素原子、ハロゲン原子または窒素原子に炭素原子数1〜20の2価の炭化水素基が1個または2個結合した窒素化合物残基である)を示す。) - (I) プロピレンに、
(II) 水酸基含有オレフィンと、
(III) 下記(A)及び(B)を含む触媒成分と、
を順次、又は同時に添加し共重合反応させ、
下記(i)〜(iv)を満たすプロピレン系重合体を製造する方法。
(A)下記一般式[3]で表されるメタロセン化合物。
(式中、Mは周期表第4族の遷移金属原子を示し、R 1 は、互いに同一でも異なっていてもよく、炭素原子数1〜6の炭化水素基を示し、R 2 、R 4 、R 5 およびR 6 は、互いに同一でも異なっていてもよく、水素原子、ハロゲン原子またはR 1 と同様の炭素原子数1〜6の炭化水素基を示し、R 3 は互いに同一でも異なっていてもよく、炭素原子数6〜16のアリール基を示す。X 1 およびX 2 はハロゲン、炭化水素基、アニオン配位子または孤立電子対で配位可能な中性配位子から同一または異なる組合せで選んでもよく、Yは炭素原子数1〜20の2価の炭化水素基、炭素原子数1〜20の2価のハロゲン化炭化水素基、2価のケイ素含有基、2価のゲルマニウム含有基、2価のスズ含有基、−O−、−CO−、−S−、−SO−、−SO 2 −、−Ge−、−Sn−、−NR 7 −、−PR 7 −、−P(O)R 7 −、−BR 7 −、−AlR 7 −(但し、R 7 は互いに同一でも異なっていてもよく、炭素原子数1〜20の2価の炭化水素基、炭素原子数1〜20の2価のハロゲン化炭化水素基、水素原子、ハロゲン原子または窒素原子に炭素原子数1〜20の2価の炭化水素基が1個または2個結合した窒素化合物残基である)を示す。)
(B)(B-1) 有機金属化合物、
(B-2) 有機アルミニウムオキシ化合物、および
(B-3) メタロセン化合物(A)と反応してイオン対を形成する化合物、
から選ばれる少なくとも1種の化合物。
(i) 該重合体中の水酸基含有オレフィン量が10mol%以下であり、
(ii) 該重合体のゲルパーミエーションクロマトグラフィ(GPC)測定によって得られた重量平均分子量(Mw)が5000以上であり、
(iii) 重量平均分子量(Mw)と数平均分子量(Mn)の比の値(Mw/Mn)が、1.0〜3.5の範囲にあり、
(iv) 該重合体のDSCで測定した融点([Tm];℃)と核磁気共鳴(NMR)で測定した水酸基含有オレフィン量([−OH];mol%)とが、0<[−OH]≦3、かつ下記関係式(Eq-1)を満たす。
- 請求項1又は請求項2に記載のプロピレン系重合体を含む塗装性材料。
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