JP3748108B2 - Electrode connection structure of connection member using conductive particles - Google Patents
Electrode connection structure of connection member using conductive particles Download PDFInfo
- Publication number
- JP3748108B2 JP3748108B2 JP2003047434A JP2003047434A JP3748108B2 JP 3748108 B2 JP3748108 B2 JP 3748108B2 JP 2003047434 A JP2003047434 A JP 2003047434A JP 2003047434 A JP2003047434 A JP 2003047434A JP 3748108 B2 JP3748108 B2 JP 3748108B2
- Authority
- JP
- Japan
- Prior art keywords
- connection
- layer
- conductive particles
- conductive
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Landscapes
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Combinations Of Printed Boards (AREA)
- Wire Bonding (AREA)
- Conductive Materials (AREA)
- Non-Insulated Conductors (AREA)
Description
【0001】
【発明の属する技術分野】
本発明は例えば電極の接続などに好適な、変形度の制御が可能な導電性粒子を用いた接続部材の電極接続構造に関する。
【0002】
【従来の技術】
回路素子と回路基板、回路基板同士を、エポキシ樹脂などの接着成分中に導電性粒子を分散した接続部材で接着し、回路素子と回路基板、回路基板同士を加圧方向にのみ電気的に接続する異方導電性接続部材がある。
この接続部材において、接着成分中に分散させる導電性粒子として、高分子重合体を核体(高分子核体)とし、その表面を金属薄層で被覆してなる導電性粒子が知られている。この粒子は、比重が小さいため、接着成分が液状であるとき、沈降しにくい。またこのような接続部材を用いて、例えば電子部品の微小電極などを接続するときに、接続時の温度や圧力で高分子核体が変形、導電性粒子と電極との接触面積を大きくすることができるなどの特徴がある。この場合、上記導電性粒子が変形しすぎないようにするため、硬質のスペーサ粒子を混合することも提案されている。
【0003】
【発明が解決しようとする課題】
高分子核体の表面を金属薄層で被覆してなる導電性粒子は、接続時の温度や圧力が高くなると、高分子核体の変形が大きくなり、金属薄層が高分子核体から剥離したり、部分的に破壊したりして離散し、離散した金属片が接続電極と接触して隣接電極間の絶縁性を損なうことがあった。このため、接続条件を厳密にコントロールする必要があり、条件の変動を考慮し接続後の検査工程が必須な状況であった。
【0004】
また、硬質のスペーサ粒子を混合する場合、これら混合粒子を均一に分散させる必要があるが、比重の差や表面電荷の相違により微小部分における均一分散性が困難である。特に最近では、この種の接着剤の適用分野が、IC、LSIなどの集積回路類や液晶やEL、プラズマなどの表示素子類と電子回路類との接続といった、微細な電極や回路の接続用途に接続部材として多用され、そのため、広い接続条件で安定した接続信頼性が得られることや、大量生産における接続後の検査工程を不要にしたいといった要望が強く、一層使いやすい接続部材が求められるようになっている。
【0005】
【課題を解決するための手段】
本発明は、接着成分中に導電性粒子を分散した接続部材を介してガラス回路とプラスチック回路を接続する異方導電性接続部材の導電性粒子が、高分子からなる硬質核の表面に架橋高分子からなる軟質層を、その外側に導電層を形成され、前記高分子からなる硬質核の粒径と略等しい間隔を隔てて回路電極が接続されていることを特徴とする導電性粒子を用いた接続部材の電極接続構造である。
【0006】
本発明を以下図面を用いて説明する。
図1(a)は、本発明で用いる導電性粒子の一実施例を示す断面模式図である。
硬質核1の材料は、金属でも高分子類でもよい。ここで、硬質の意味は、導電性粒子の使用環境下例えば電極や回路の接続用途の場合の接続条件下で、軟質層2と比べての相対的な硬さの関係を意味する。一定温度における弾性率や硬度などの一般的な硬さの指標や、例えば融点やガラス転移温度及び軟化点などの熱的変態点の差を目安とすることができる。
【0007】
硬質核1の粒径は、平均して、0.1〜20μm、好ましくは0.3〜10μm、より好ましくは0.5〜6μmとすることが、接続後の電極間距離を狭めて接続信頼性を向上する点から好ましい。硬質核1の粒径は均一とすることが好ましい。また硬質核1の粒形は略球状が好ましいが、(b)に示すように、表面に多数の凹凸があるなどの任意の形でよい。硬質核1は導電性でも非導電性でもよい。
【0008】
軟質層2はポリスチレンやナイロン、各種ゴム類などの高分子類が好ましく、これらは架橋体であると耐溶剤性が向上するので、接着成分中に溶剤が含まれている場合、溶出がなく、特性に影響が少ないことからより好ましい。
また軟質層2を高分子とすると変形性を得やすく、導電層や核体との接着性もよい。そのため接続部材とした時、低抵抗で信頼性に優れた接続が得られる。また、接続電極や基板の耐熱性や硬さに応じて、適宜組み合わせを設定可能である。
【0009】
軟質層2の厚みは、0.1〜10μm程度が好適である。0.1μm未満では変形量が十分に得られず信頼性が不足し、10μmを超えると変形量が過剰となり金属薄層の被覆が剥離し易くなる。このような理由から、0.3〜5μmが好ましく0.5〜3μmがより好ましい。
【0010】
また、軟質層2の厚みは、硬質核1の粒径以下、より好ましくは1/2以下とすると、導電粒子の変形量が制御しやすく回路の接続部材料として好ましい。軟質層2は、図1(c)に示すように粒子状で存在してもよく、単層又は複層以上の構成とすることもできる。複層以上の構成の場合、強度保持性、耐溶剤性、接着性、柔軟性、耐熱性、耐めっき液性などの機能を分担することも可能なため好適である。軟質層2は、例えば噴霧法、高速撹拌法、スプレードライヤーなど任意の方法で形成できる。
【0011】
導電層3は導電性を有する各種の金属や合金、酸化物などである。導電性と耐腐食性を加味して好ましく用いられる材料としては、Ni、Cu、Al、Sn、Zn、Au、Pd、Ag、Co、Pb、などであり、これらは単層もしくは複層以上の構成とすることもできる。
【0012】
導電層3の形成手段としては、蒸着法、スパッタリング法、イオンプレーティング法、溶射法、めっき法、などの一般的な方法でよいが、無電解めっき法が均一厚みの被覆層の得られることから好ましい。
【0013】
図1(d)に示すように、必要に応じて導電層3の表面に接続条件で溶融可能な樹脂層4を形成してもよい。この場合、前記した微細電極の接続用とした場合、加熱加圧下において電極との接触面においては樹脂層が溶融し接続が可能となるが、隣接電極方向は熱量が不十分なため樹脂層が溶融し難いので絶縁性の低下が少なく、より高密度の実装が可能となる。
【0014】
上記した各層間には必要に応じて、密着性向上のためのカップリング剤などの補助層を形成できる。
【0015】
本発明の導電性粒子を微細電極の接続用とするためには、その粒径を隣接配線パターン間距離の最小幅よりも小さくすることが、隣接配線パターンとのショートを防止し配線の細線化に対応する上で必要である。
【0016】
この場合の接着成分としては、熱可塑性材料でもよいが、熱、光、電子線などのエネルギーによる硬化性材料が耐熱性や耐湿性に優れることから好ましく適用できる。形態は液状、ペースト状、フィルム状などの何れでもよい、それぞれの特徴を生かして使いわける。例えばフィルム状であると一定の厚みが得やすく塗布作業も不要であり、また液状やペースト状の場合、微小面積の必要部のみに形成できるなどの特徴がある。
【0017】
接続部材中に占める導電性粒子の割合は、用途により任意に設定できる。厚み方向のみに導電性の必要な微細電極用の接続部材の場合、0.1〜15体積%、好ましくは0.2〜10体積%、より好ましくは0.5〜6体積%である。配合量が少ないと、接続すべき電極上の導電性粒子数が減少するため信頼性が低下し、過多であると隣接電極の絶縁性が低下し微細電極の接続が困難となる。
【0018】
面方向にも導電性が必要な塗料用の場合10〜35体積%が用いられる。
【0019】
本発明になる導電性粒子を用いた接続部材の電極接続構造を、図2に示す。
基板12、12に設けられた電極13、13間で、接続時の加熱加圧により導電性粒子11は、核の粒径で制御させて接続部材14で接続される。この時硬質核1上の軟質層2は変形性を有するので、導電層3の剥離がない。電極の横方向は、導電性粒子の添加量や粒径の制御により絶縁性を保てる。
【0020】
本発明で用いる導電性粒子は、導電層3が、軟質層2の上に形成されており、この軟質層2が接続時に変形追随する。そして、その最大変形量は、核1の粒径で制御されるので、過度の変形を生じない。このため、接続作業時に、導電層3が剥離しない。
【0021】
核1は、電極接続時の加熱加圧の際に軟質な層に比べ硬質としたことにより変形がほとんど無いか、あっても僅かとすることができる。そのため、加熱加圧による接続後の電極間距離を硬質核の粒径に制御可能なので、接続条件の考慮が少なくても安定した接続が得られる。よく知られているように、電極間距離の制御が接続信頼性向上に大きく影響する。
【0022】
【実施例】
以下実施例でさらに詳細に説明するが、本発明はこれに限定されない。
実施例1
平均粒径3μmの硬化エポキシ粒子(ガラス転移点190℃)の表面に、被覆層としてポリスチレン/ジビニルベンゼン=100/0.5(ガラス転移点115℃)よりなる平均粒径1μmの粒子を、アルコールを分散剤としてスプレイドライヤで被覆し、125℃に加熱し、固定化した。
【0023】
この粒子を水中に分散し、塩化パラジウム系の活性化処理の後、無電解Niめっき液を用いてNiめっきを90℃で行った後、Auめっき液を用い置換めっきを70℃で行った。Ni/Auの厚さは0.2/0.02μmであった。
【0024】
高分子量エポキシを主成分とする接着成分に、前記導電性粒子を2体積%添加し、厚み50μmのポリテトラフルオロエチレンフィルム上に、厚み20μmとなるように塗布して接続部材を得た。得られた接続部材を、100℃の純水で、10時間抽出した後の抽出水のナトリウムイオン及び塩素イオンは、それぞれ10ppm以下であった。
【0025】
厚み75μmのポリイミド基板上に、厚み15μmの接着剤層を介し厚み18μmで回路上にSn薄層を有するのCu回路電極と、厚み1.1mmのガラス上に形成した酸化インジウム(ITO、表面抵抗20Ω/□)の薄層電極との間に、前記接続部材を1.5mm幅で載置し両電極を位置合わせ後、接続した。
【0026】
なお、回路ピッチ100μm、電極幅50μmの平行回路の電極で、試験片1枚で300本の電極接続部を有する。接続部の温度を、150℃、170℃、190℃、また、圧力を、0.5MPa、2MPa、10MPaと広く変動させた。このように広範囲の接続条件下で、電極間距離は、核体の平均粒径である3μmに制御され、良好な接続信頼性を示した。また接続条件の異なる接続部の導電性粒子を走査型電子顕微鏡で観察したところ、いずれも電極との接触部に微小なクラックが見られ菊の花状となっているものの、金属層の剥離がみられなかった。
【0027】
比較例1
平均粒径5μmの硬化エポキシ粒子の表面に、直接Ni/Au層(厚さは0.2/0.02μm)を形成した導電性粒子を用い以下実施例1と同様にして接続部材を得、同様に評価した。
接続条件の変動により電極間距離は4〜15μmと変動し接続抵抗のばらつき幅が大きく、実用化のためにはごく狭い温度圧力の範囲内で接続条件の厳密なコントロールが必要であった。
【0028】
実施例2
核として平均粒径3μmのカルボニル法で得た導電性のNi粒子(融点1455℃)を使用し、実施例1と同様にして、図1(b)の構成の導電性粒子を得、実施例1と同様にして接続部材を得、同様な評価を行った。ただし、電極の表面を、SnからSn/Pb=10/90のはんだ薄層に変更した。
【0029】
実施例1と同様に広範囲の接続条件下で良好な接続信頼性を得、電極間距離は核体の平均粒径である3μmに制御されていた。本例においては、硬質核を融点の高い金属粒子としたことで、電極の表面がはんだのような酸化物質であっても酸化層に食い込む形で良好な接続が得られた。
【0030】
実施例3
実施例1で得られた導電性粒子をナイロン(ガラス転移点110℃)のアルコールの溶液で処理後、60℃で乾燥し表面に厚み1〜2μmのナイロン層を有する図1(d)に示す構造の導電性粒子を得た。この導電性粒子を実施例1と同様の接着成分中に、6体積%配合分散させ、以下同様な評価を行った。
【0031】
この場合も広範囲の接続条件下で良好な接続信頼性を得、電極間距離は核体の平均粒径である3μmに制御されていた。本例においては導電性粒子の配合量を6体積%と増加したにもかかわらず、隣接方向の絶縁性は良好であった。
【0032】
実施例4及び比較例2
実施例1及び比較例1の接続部材を用いて、基板並びに接続条件を変更した。すなわち一方の回路基板を厚み1.1mmのガラスに代えて、厚み0.2mmのポリエチレンテレフタレートのフィルム基板とした。ガラスに比べフィルム基板では耐熱性が大きく異なるので、接続条件を130℃、1MPa、30秒として同様に接続評価した。
【0033】
実施例4(実施例1の接続部材)の場合、電極間距離が核体の平均粒径である3μmに制御され、良好な接続信頼性を示した。一方比較例2(比較例1の接続部材)の場合、フィルム基板上のITO回路にクラックが発生した。
【0034】
両者の比較から実施例4の場合、ポリスチレン系軟質層が接続時に衝撃緩衝材として作用し、加えて最大変形量が硬質核の粒径で制御されたことから、ITO回路にクラックの発生が無かったのに対し、比較例2では接続温度と粒子のガラス転移点との差が大きく、硬質核が軟質フィルム上のITO回路に食い込む形でクラックが発生したものと考えられる。
【0035】
従って、本発明の導電性粒子を用いた接続部材を用いることで、例えばポリエチレンフタレートやポリカーボネート、ポリエーテルサルホン、ポリアリレートなどの、いわゆる軟質・軽量で耐熱性のないプラスチック基板類の場合にも、良好な接続を得ることが可能となった。
【0036】
【発明の効果】
以上詳述したように、本発明によれば広い接続条件下で安定した接続信頼性が得られ、一層使いやすい導電性粒子を用いた接続部材の電極接続構造を得ることが可能となる。
【図面の簡単な説明】
【図1】本発明で用いる導電性粒子の断面図である。
【図2】本発明の一実施例を示す電極接続構造の断面図である。
【符号の説明】
1 硬質核
2 軟質層
3 導電層
4 樹脂層
11 導電性粒子
12 基板
13 電極
14 接続部材[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an electrode connection structure of a connection member using conductive particles suitable for connection of electrodes, for example, and capable of controlling the degree of deformation.
[0002]
[Prior art]
The circuit element and the circuit board, and the circuit boards are bonded to each other with a connecting member in which conductive particles are dispersed in an adhesive component such as an epoxy resin, and the circuit elements, the circuit board, and the circuit boards are electrically connected only in the pressing direction. There is an anisotropic conductive connecting member.
In this connection member, as the conductive particles dispersed in the adhesive component, there are known conductive particles in which a high molecular polymer is used as a core (polymer core) and the surface thereof is covered with a thin metal layer. . Since these particles have a small specific gravity, they are difficult to settle when the adhesive component is liquid. In addition, using such a connection member, for example, when connecting a microelectrode of an electronic component, the polymer core is deformed by the temperature and pressure at the time of connection, and the contact area between the conductive particles and the electrode is increased. There are features such as being able to. In this case, in order to prevent the conductive particles from being deformed excessively, it has also been proposed to mix hard spacer particles.
[0003]
[Problems to be solved by the invention]
Conductive particles made by coating the surface of the polymer core with a thin metal layer will cause large deformation of the polymer core when the temperature and pressure at the time of connection increase, and the thin metal layer will peel from the polymer core. In some cases, the metal pieces are separated by being broken or partially broken, and the discrete metal pieces come into contact with the connection electrodes to impair the insulation between the adjacent electrodes. For this reason, it is necessary to strictly control the connection conditions, and the inspection process after the connection is indispensable in consideration of variation in conditions.
[0004]
In addition, when mixing hard spacer particles, it is necessary to uniformly disperse these mixed particles, but it is difficult to uniformly disperse in a minute portion due to a difference in specific gravity and a difference in surface charge. In particular, this type of adhesive has recently been applied to the connection of fine electrodes and circuits, such as the connection of integrated circuits such as IC and LSI, and display elements such as liquid crystal, EL, and plasma with electronic circuits. Therefore, there is a strong demand for stable connection reliability over a wide range of connection conditions and for eliminating the need for post-connection inspection processes in mass production. It has become.
[0005]
[Means for Solving the Problems]
In the present invention, conductive particles of an anisotropic conductive connecting member for connecting a glass circuit and a plastic circuit through a connecting member in which conductive particles are dispersed in an adhesive component are crosslinked on the surface of a hard core made of a polymer. Conductive particles characterized in that a soft layer made of molecules, a conductive layer formed on the outer side thereof, and circuit electrodes are connected at an interval substantially equal to the particle size of the hard core made of the polymer are used. This is an electrode connection structure of a connecting member.
[0006]
The present invention will be described below with reference to the drawings.
Fig.1 (a) is a cross-sectional schematic diagram which shows one Example of the electroconductive particle used by this invention.
The material of the
[0007]
The average particle size of the
[0008]
The
Moreover, when the
[0009]
The thickness of the
[0010]
If the thickness of the
[0011]
The
[0012]
The
[0013]
As shown in FIG. 1D, a resin layer 4 that can be melted under connection conditions may be formed on the surface of the
[0014]
An auxiliary layer such as a coupling agent for improving adhesion can be formed between the above-described layers as necessary.
[0015]
In order to use the conductive particles of the present invention for connecting fine electrodes, it is possible to make the particle size smaller than the minimum width of the distance between adjacent wiring patterns to prevent a short circuit between adjacent wiring patterns and to reduce the thickness of the wiring. It is necessary to cope with.
[0016]
The adhesive component in this case may be a thermoplastic material, but is preferably applied because a curable material using energy such as heat, light, and electron beam is excellent in heat resistance and moisture resistance. The form may be any of liquid, paste, film, etc., and can be used by taking advantage of each feature. For example, when it is in the form of a film, it is easy to obtain a certain thickness, and an application operation is not necessary. In the case of a liquid or paste, it can be formed only in a necessary portion of a small area.
[0017]
The ratio of the conductive particles in the connecting member can be arbitrarily set depending on the application. In the case of a connecting member for a fine electrode that requires electrical conductivity only in the thickness direction, it is 0.1 to 15% by volume, preferably 0.2 to 10% by volume, more preferably 0.5 to 6% by volume. When the blending amount is small, the number of conductive particles on the electrode to be connected is reduced, so that the reliability is lowered. When the blending amount is excessive, the insulating property of the adjacent electrode is lowered and the connection of the fine electrode becomes difficult.
[0018]
In the case of a coating material that requires conductivity also in the surface direction, 10 to 35% by volume is used.
[0019]
The electrode connection structure of the connection member using the electroconductive particle which becomes this invention is shown in FIG.
Between the electrodes 13 and 13 provided on the substrates 12 and 12, the conductive particles 11 are connected by the connection member 14 while being controlled by the particle diameter of the nucleus by heat and pressure at the time of connection. At this time, since the
[0020]
In the conductive particles used in the present invention, the
[0021]
Since the
[0022]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
Example 1
On the surface of cured epoxy particles having an average particle diameter of 3 μm (glass transition point 190 ° C.), particles having an average particle diameter of 1 μm made of polystyrene / divinylbenzene = 100 / 0.5 (glass transition point 115 ° C.) as a coating layer Was coated with a spray dryer as a dispersant, heated to 125 ° C. and fixed.
[0023]
The particles were dispersed in water, and after palladium chloride activation treatment, Ni plating was performed at 90 ° C. using an electroless Ni plating solution, and substitution plating was then performed at 70 ° C. using an Au plating solution . The thickness of Ni / Au was 0.2 / 0.02 μm.
[0024]
2% by volume of the conductive particles were added to an adhesive component having a high molecular weight epoxy as a main component, and applied on a polytetrafluoroethylene film having a thickness of 50 μm to a thickness of 20 μm to obtain a connecting member. The sodium ion and the chlorine ion of the extracted water after extracting the obtained connection member for 10 hours with 100 degreeC pure water were 10 ppm or less, respectively.
[0025]
A Cu circuit electrode having a Sn thin layer on a circuit having a thickness of 18 μm on a polyimide substrate having a thickness of 75 μm via an adhesive layer having a thickness of 15 μm, and indium oxide (ITO, surface resistance) formed on a glass having a thickness of 1.1 mm The connecting member was placed with a width of 1.5 mm between 20 Ω / □) thin layer electrodes, and both electrodes were aligned and then connected.
[0026]
In addition, it is an electrode of a parallel circuit with a circuit pitch of 100 μm and an electrode width of 50 μm, and one test piece has 300 electrode connection portions. The temperature of the connection part was widely varied as 150 ° C., 170 ° C., 190 ° C., and the pressure was widely changed to 0.5 MPa, 2 MPa, and 10 MPa. Thus, under a wide range of connection conditions, the distance between the electrodes was controlled to 3 μm, which is the average particle diameter of the nuclei, and good connection reliability was exhibited. In addition, when the conductive particles at the connection part with different connection conditions were observed with a scanning electron microscope, all of the contact parts with the electrode had minute cracks and became chrysanthemums, but the metal layer was peeled off. It was not seen.
[0027]
Comparative Example 1
Using conductive particles in which a Ni / Au layer (thickness: 0.2 / 0.02 μm) was directly formed on the surface of a cured epoxy particle having an average particle diameter of 5 μm, a connecting member was obtained in the same manner as in Example 1 below. Evaluation was performed in the same manner.
Due to variations in connection conditions, the distance between the electrodes varies from 4 to 15 μm and the variation range of the connection resistance is large. For practical application, it is necessary to strictly control the connection conditions within a very narrow temperature and pressure range.
[0028]
Example 2
Using conductive Ni particles (melting point: 1455 ° C.) obtained by the carbonyl method having an average particle diameter of 3 μm as nuclei, conductive particles having the structure shown in FIG. 1B were obtained in the same manner as in Example 1. The connection member was obtained in the same manner as in Example 1 and the same evaluation was performed. However, the surface of the electrode was changed from Sn to a thin solder layer of Sn / Pb = 10/90.
[0029]
As in Example 1, good connection reliability was obtained under a wide range of connection conditions, and the distance between the electrodes was controlled to 3 μm, which is the average particle size of the nuclei. In this example, since the hard core is made of metal particles having a high melting point, even if the surface of the electrode is an oxide material such as solder, a good connection is obtained in a form that bites into the oxide layer.
[0030]
Example 3
The conductive particles obtained in Example 1 are treated with an alcohol solution of nylon (glass transition point 110 ° C.), dried at 60 ° C., and a nylon layer having a thickness of 1 to 2 μm on the surface is shown in FIG. Conductive particles having a structure were obtained. 6% by volume of the conductive particles were mixed and dispersed in the same adhesive component as in Example 1, and the same evaluation was performed.
[0031]
Also in this case, good connection reliability was obtained under a wide range of connection conditions, and the distance between the electrodes was controlled to 3 μm, which is the average particle size of the nuclei. In this example, although the blending amount of the conductive particles was increased to 6% by volume, the insulation in the adjacent direction was good.
[0032]
Example 4 and Comparative Example 2
Using the connection members of Example 1 and Comparative Example 1, the substrate and the connection conditions were changed. That is, one circuit board was replaced with a 1.1 mm thick glass, and a 0.2 mm thick polyethylene terephthalate film substrate was used. Since the heat resistance of the film substrate is significantly different from that of glass, the connection was similarly evaluated with the connection conditions set at 130 ° C., 1 MPa, and 30 seconds.
[0033]
In the case of Example 4 (connection member of Example 1), the distance between the electrodes was controlled to 3 μm, which is the average particle diameter of the core, and good connection reliability was exhibited. On the other hand, in the case of the comparative example 2 (connection member of the comparative example 1), the crack generate | occur | produced in the ITO circuit on a film substrate.
[0034]
From the comparison between the two, in the case of Example 4, the polystyrene-based soft layer acts as an impact buffering material at the time of connection, and the maximum deformation amount was controlled by the particle size of the hard core, so that no crack was generated in the ITO circuit. On the other hand, in Comparative Example 2, the difference between the connection temperature and the glass transition point of the particles is large, and it is considered that the cracks occurred in the form that the hard nuclei bite into the ITO circuit on the soft film.
[0035]
Therefore, by using the connection member using the conductive particles of the present invention, for example, in the case of so-called soft and lightweight plastic substrates having no heat resistance, such as polyethylene phthalate, polycarbonate, polyethersulfone, polyarylate, etc. It became possible to obtain a good connection.
[0036]
【The invention's effect】
As described above in detail, according to the present invention, stable connection reliability can be obtained under a wide range of connection conditions, and it is possible to obtain an electrode connection structure of a connection member using conductive particles that are easier to use.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of conductive particles used in the present invention.
FIG. 2 is a cross-sectional view of an electrode connection structure showing an embodiment of the present invention.
[Explanation of symbols]
DESCRIPTION OF
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003047434A JP3748108B2 (en) | 2003-02-25 | 2003-02-25 | Electrode connection structure of connection member using conductive particles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003047434A JP3748108B2 (en) | 2003-02-25 | 2003-02-25 | Electrode connection structure of connection member using conductive particles |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19436293A Division JPH0750104A (en) | 1993-08-05 | 1993-08-05 | Conductive particle and connection member using conductive particle |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2003309341A JP2003309341A (en) | 2003-10-31 |
JP3748108B2 true JP3748108B2 (en) | 2006-02-22 |
Family
ID=29398122
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003047434A Expired - Lifetime JP3748108B2 (en) | 2003-02-25 | 2003-02-25 | Electrode connection structure of connection member using conductive particles |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3748108B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4026812B2 (en) * | 2002-07-15 | 2007-12-26 | 宇部日東化成株式会社 | Conductive particles and method for producing the same |
CN1317752C (en) * | 2004-08-30 | 2007-05-23 | 友达光电股份有限公司 | Method and structure for detecting anisotropic conductive rubber conductive particle deformation content |
-
2003
- 2003-02-25 JP JP2003047434A patent/JP3748108B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2003309341A (en) | 2003-10-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4814277B2 (en) | Bonded body, method for manufacturing the bonded body, and anisotropic conductive film used for the bonded body | |
KR101193757B1 (en) | Anisotropic conductive film, method for producing the same, and joined structure using the same | |
WO2014045931A1 (en) | Anisotropic conductive film, connection method, and assembly | |
KR101162890B1 (en) | Conductive particle, conductive particle manufacturing method, anisotropic conductive material, and connection structure | |
JP4605225B2 (en) | Circuit connection material, circuit member connection structure using the same, and manufacturing method thereof | |
JPH0750104A (en) | Conductive particle and connection member using conductive particle | |
JP3280139B2 (en) | Display panel | |
JP3775598B2 (en) | Electrode connection structure | |
JP4428400B2 (en) | Electrode connection structure | |
JP4014111B2 (en) | Electrode connection structure | |
JP3748108B2 (en) | Electrode connection structure of connection member using conductive particles | |
KR100845875B1 (en) | Insulation-coated electroconductive particles | |
JP4466570B2 (en) | Conductive particles for electrode connection | |
JP3944849B2 (en) | Connecting member | |
JP2006199833A (en) | Anisotropic conductive adhesive | |
KR101157599B1 (en) | Conductive particle for anisotropic conductive film and anisotropic conductive film including the conductive particle | |
JP4031545B2 (en) | adhesive | |
CN101390174A (en) | Circuit connecting material, connection structure for circuit member using the same, and method for producing such connection structure | |
JPH09306231A (en) | Conductive particulate and substrate | |
WO2017047671A1 (en) | Connection material | |
JPH11134936A (en) | Conductive fine grains, anisotropic conductive adhesive, and conductive connecting structure | |
KR100764570B1 (en) | Bonding structure of pattern electrodes formed by using laser and method for bonding the same | |
KR102545861B1 (en) | Conductive material | |
KR20080098815A (en) | Insulated conductive ball and anisotropic electricconnection material comprising the same | |
KR20050026327A (en) | Conductive silicon powder and method for making the same and anisotropic conductive film and conductive paste using the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20050303 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050428 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20050616 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050810 |
|
A911 | Transfer of reconsideration by examiner before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20050920 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20051110 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20051123 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091209 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101209 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101209 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111209 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111209 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20121209 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20121209 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131209 Year of fee payment: 8 |
|
EXPY | Cancellation because of completion of term |