JP2749284B2 - Flocked cloth and manufacturing method thereof - Google Patents

Flocked cloth and manufacturing method thereof

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Publication number
JP2749284B2
JP2749284B2 JP7128261A JP12826195A JP2749284B2 JP 2749284 B2 JP2749284 B2 JP 2749284B2 JP 7128261 A JP7128261 A JP 7128261A JP 12826195 A JP12826195 A JP 12826195A JP 2749284 B2 JP2749284 B2 JP 2749284B2
Authority
JP
Japan
Prior art keywords
cloth
flocking
fibers
treatment
flocks
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP7128261A
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Japanese (ja)
Other versions
JPH08318207A (en
Inventor
豊彦 彦田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHUBU PAIRU KOGYOSHO KK
Original Assignee
CHUBU PAIRU KOGYOSHO KK
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Filing date
Publication date
Application filed by CHUBU PAIRU KOGYOSHO KK filed Critical CHUBU PAIRU KOGYOSHO KK
Priority to JP7128261A priority Critical patent/JP2749284B2/en
Publication of JPH08318207A publication Critical patent/JPH08318207A/en
Application granted granted Critical
Publication of JP2749284B2 publication Critical patent/JP2749284B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、繊維素繊維独特の優れ
た風合を有し、しかもしわと毛羽立ちの目立たない布
帛、その製品およびその製造方法に関する。ここに、繊
維素繊維とは、セルロースを有機溶剤に溶解し、湿式紡
糸により製造した繊維をいう。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric having an excellent feeling unique to fibrous fibers and less noticeable wrinkles and fluffs, a product thereof, and a method for producing the same. Here, the fibrous fibers refer to fibers produced by dissolving cellulose in an organic solvent and wet-spinning.

【0002】[0002]

【従来の技術】繊維素繊維は、別名精製セルロース繊
維、またはリヨセル(欧州化繊協会がレーヨンと混同し
ないように付した名称)ともいい、テンセル(登録商
標;コートルズ株式会社)の名で呼ばれることもある。
この繊維は、ソフトでコシが強く、乾燥状態のみならず
湿潤状態でも強度が高く、吸湿性に優れ、取扱いが容易
などの優れた性質を有しており、その製品は独特の優れ
た風合を呈するので、衣料用織編物や内装材などに広く
用いられている。しかし、繊維素繊維は結晶化度が高い
ため、フィブリル化しやすく、特に水に濡れて擦れると
フィブリル化し、その製品には毛羽やしわが発生しやす
いという欠点がある。その対策として、製品化する前に
フィブリル化処理および酵素処理を施すことが行われて
いる。
2. Description of the Related Art Cellulosic fiber is also called purified cellulose fiber or lyocell (a name given by the European Chemical Fibers Association so as not to be confused with rayon), and is sometimes called Tencel (registered trademark; Coatles Co., Ltd.). is there.
This fiber is soft and stiff, has high strength not only in the dry state but also in the wet state, has excellent hygroscopicity, and has excellent properties such as easy handling, and its product has a unique excellent texture. It is widely used for woven and knitted clothing and interior materials. However, since fibrous fibers have a high degree of crystallinity, they tend to fibrillate, particularly when wet and rubbed with water, and the product has a drawback that fluff and wrinkles are likely to occur. As a countermeasure, a fibrillation treatment and an enzyme treatment are performed before commercialization.

【0003】フィブリル化処理は、好ましくは湿潤状態
で、繊維素繊維に人為的に摩擦を与えて繊維のフィブリ
ル化を促進する処理である。酵素処理は、発生した細繊
維を酵素で分解除去する処理をいい、一般に、酵素、例
えば、セルライザー(ナガセ生化学工業(株)製)、セ
ルソフトプラスL(ノボノルディスクバイオインダスト
ー(株)製)、エチロンCM−40L(洛東化成
(株)製)がセルロースを分解する作用を利用する。ま
た、しわの発生を防いで風合を改善するために、他の繊
維を混紡や交織などすることが行われている。しかし、
例えばレーヨンやポリノジックと混紡や交織などする
と、繊維素繊維独特の風合を損なわないものの、しわの
防止効果が小さいし、酵素により分解されて製品の耐久
性が低下しやすい。一方、酵素により分解されない繊
維、例えば、ポリエステルやナイロンと混紡や交織した
繊維製品は、耐久性に優れるものの、繊維素繊維独特の
風合に乏しくなる。
The fibrillation treatment is a treatment for imparting artificial friction to fibrous fibers, preferably in a wet state, to promote fibrillation of the fibers. The enzyme treatment refers to a treatment for decomposing and removing the generated fine fibers with an enzyme. Generally, an enzyme such as a cell riser (manufactured by Nagase Seikagaku Co., Ltd.), Cell Soft Plus L (Novo Nordisk Bioindustry) > made rie (Ltd.)), manufactured by Echiron CM-40L (Rakuto Kasei Co., Ltd.) is to use the action to degrade cellulose. Further, in order to prevent wrinkles from occurring and improve the feeling, blending or weaving of other fibers is performed. But,
For example, blending or interweaving with rayon or polynosic does not impair the unique feel of fibrous fibers, but has a small effect of preventing wrinkles and is easily decomposed by enzymes to reduce the durability of the product. On the other hand, fibers which are not decomposed by enzymes, for example, a fiber product mixed or woven with polyester or nylon, are excellent in durability, but have a poor texture unique to fibrous fibers.

【0004】また、従来、接着剤を塗布した基布に、振
動あるいは高電圧の静電気を利用して、フロック(パイ
ルともいう)を散布あるいは吹付けて固着した、比較的
経済的な植毛布が、絨毯や家具などに用いる内装材や衣
服などに使われている。この植毛布のフロックは、一般
に、レーヨン、ナイロン、綿などの繊維からなってい
る。しかし、例えば、レーヨンの植毛布は、吸湿性や染
色性に優れるものの、繊維強度が、特に湿潤時に十分で
なく、安物のイメージが強かった。一方、例えばナイロ
ンの植毛布は、耐久性に優れるものの、吸湿性や風合に
劣っていた。結局、従来の植毛布では、弾力に富むふか
ふかした感触やリッチな風合と耐久性とを十分に兼備し
たものは得られておらず、用途も限られていた。
[0004] Conventionally, a relatively economical flocking cloth is used in which flocks (also referred to as piles) are fixed to a base cloth coated with an adhesive by using vibration or high-voltage static electricity by spraying or spraying. It is used for interior materials and clothes used for carpets and furniture. The flocks of this flocking cloth are generally made of fibers such as rayon, nylon and cotton. However, for example, a flocked cloth made of rayon is excellent in hygroscopicity and dyeing properties, but has insufficient fiber strength, especially when wet, and has a strong image of a cheap material. On the other hand, for example, a nylon flocking cloth is excellent in durability, but inferior in moisture absorption and feeling. As a result, conventional flocking cloths have not been able to provide a soft and fluffy feel that is rich in elasticity, a rich texture and sufficient durability, and their uses are limited.

【0005】[0005]

【発明が解決しようとする課題】本発明者は、前記の問
題に鑑み、繊維素繊維の優れた性質と風合とを生かしつ
つ、その欠点である毛羽やしわを解消した製品を提供
し、一方、感触や吸湿性、風合と耐久性とに優れ、高級
感のある植毛布を提供することを目的に研究を行い、本
発明の植毛布およびその製造方法に到達した。
SUMMARY OF THE INVENTION In view of the above problems, the present inventor has provided a product which utilizes the excellent properties and feel of fibrous fibers while eliminating the disadvantages of fluff and wrinkles. On the other hand, a study was conducted for the purpose of providing a high-quality flocked cloth excellent in feel, moisture absorption, feeling and durability, and reached the flocked cloth of the present invention and a method for producing the same.

【0006】[0006]

【課題を解決する手段】本発明は、前記の目的を達成す
るために、フィブリル化処理と酵素処理とが施されてい
る繊維素繊維のフロックを基布に固着した植毛布を提供
する。この本発明が提供する植毛布は、シルキーでリッ
チな風合に富み、衣料や、インテリア、車両の内装など
に用いる内装材に好適である。
According to the present invention, in order to achieve the above object, a fibrillation treatment and an enzyme treatment are performed.
A flocking cloth in which flocks of fibrous fibers are fixed to the base cloth
I do. The flocking cloth provided by the present invention is rich in silky and rich feeling, and is suitable for clothing, interior materials, and interior materials used for vehicle interiors.

【0007】さらに、本発明は、繊維素繊維のフロック
をフロック加工により基布に固着した後、繊維素繊維に
フィブリル化処理と酵素処理とを施すことを特徴とする
植毛布の製造方法を提供する。また、フィブリル化処理
と酵素処理とを施した繊維素繊維のフロックを製造し、
フロック加工によりフロックを基布に固着することを特
徴とする植毛布の製造方法を提供する。
Further, the present invention provides a method for producing a flocked fabric, comprising the steps of: fixing a floc of fibrous fibers to a base fabric by flocking, and then subjecting the fibrous fibers to a fibrillation treatment and an enzyme treatment. I do. In addition, to produce fibril-treated and enzymatically treated flocks of fibrous fibers,
Provided is a method for manufacturing a flocking cloth, wherein the flocking is fixed to a base cloth by flocking.

【0008】[0008]

【作用】以下、本発明についてさらに詳細に説明する。
本発明者は、前記の目的、特に、繊維素繊維の長所を十
分に生かしつつその欠点をカバーするには、繊維素繊維
をフロックに用いて植毛布とすれば、各種の用途に極め
て好ましく用いることができることを見出だした。ま
た、その植毛布は、優れた風合と吸湿性や感触の良さに
加え、従来のレーヨンなどの植毛布では得られない耐久
性と高級感とを有することを見出だした。すなわち、繊
維素繊維を0.1〜5mm程度の短繊維に加工したフロ
ックを、例えばポリエステル織物のようにしわが発生し
にくい基布にフロック加工した植毛布は、表面に繊維素
繊維の風合を持ち、しわが発生しくく、耐久性のある素
材として各種用途に用いることができる。
Hereinafter, the present invention will be described in more detail.
The inventor of the present invention has found that the above-mentioned objects, in particular, in order to cover the drawbacks while making full use of the advantages of the fibrous fibers, if the fibrous fibers are used as flocks for flocking, they are very preferably used for various purposes. I found that I can do it. In addition, it has been found that the flocked cloth has excellent feeling, hygroscopicity, and good feel, and also has durability and high-grade feeling that cannot be obtained with a flocked cloth such as conventional rayon. That is, a flocking obtained by processing a floc obtained by processing fibrous fibers into short fibers of about 0.1 to 5 mm to a base cloth such as a polyester woven fabric that is unlikely to generate wrinkles has a texture of fibrous fibers on the surface. It can be used for various purposes as a durable, durable and durable material.

【0009】本発明に係る植毛布の基布に固着されてい
るフロックには、繊維素繊維のフロックが含まれてい
る。使用目的により、全てを繊維素繊維としても、ま
た、繊維素繊維以外の繊維とブレンドしたフロックとし
ても良い。用途によりブレンドの比率を調整することが
できる。全フロック中に、繊維素繊維を少なくとも50
重量%含ませることにより、繊維素繊維独特の風合と性
質とが発揮され、衣料、インテリアや車両の内装などに
用いる内装材、あるいは研磨布としても好適な植毛布を
製造することができる。また、ブレンドに用いる他の繊
維としては、風合の面からは、例えばアクリル繊維が、
また、耐久性の面からは、例えばナイロン繊維が好まし
い。
The flocks fixed to the base cloth of the flocking cloth according to the present invention include flocks of fibrous fibers. Depending on the purpose of use, all may be fibrous fibers, or may be a floc blended with fibers other than fibrous fibers. The blend ratio can be adjusted depending on the application. At least 50 fibrous fibers should be used during all flocks.
By incorporating the content by weight, the feeling and properties unique to the fibrous fibers are exhibited, and a flocking cloth suitable as an interior material used for clothing, interiors and vehicle interiors, or a polishing cloth can be produced. In addition, as other fibers used for blending, for example, acrylic fibers are used in terms of feeling,
From the viewpoint of durability, for example, nylon fibers are preferable.

【0010】植毛布は、もともとしわの目立ちにくい布
帛であるが、さらにしわ防止を要求される用途には、基
布にしわが発生しにくい布帛、例えばポリエステル布帛
を用いると良い。基布を構成する繊維の種類は、使用目
的に応じて選択すれば良く、とくに限定されない。繊維
素繊維やその他の繊維を、単一または適当な比率でブレ
ンドして用いることができる。繊維素繊維を基布に50
重量%以上含ませておくと、植毛布に好ましい反発力を
付与することができる。他の繊維として、例えば、ポリ
エステル繊維を用いるとしわになりにくいので、衣料や
内装材に好適な植毛布を得ることができる。また、レー
ヨンなどとは異なり、湿潤状態と乾燥状態とで特性がほ
ぼ変わらず耐久性に優れているので、研磨布などにも好
適である。
[0010] The flocking cloth is originally a cloth in which wrinkles are hardly noticeable, but for applications requiring further prevention of wrinkles, a cloth in which wrinkles are hardly generated in the base cloth, for example, a polyester cloth may be used. The type of fiber constituting the base fabric may be selected according to the purpose of use, and is not particularly limited. Cellulose fibers and other fibers can be used singly or by blending in an appropriate ratio. 50 on fibrous base fabric
If it is contained in an amount of not less than% by weight, favorable resilience can be imparted to the flocking cloth. For example, if polyester fiber is used as the other fiber, wrinkling hardly occurs, so that a flocking cloth suitable for clothing and interior materials can be obtained. Further, unlike rayon or the like, since the characteristics are almost the same between a wet state and a dry state and the durability is excellent, it is also suitable for a polishing cloth or the like.

【0011】基布に固着されている繊維素繊維のフロッ
クは、使用目的により、フィブリル化処理と酵素処理
(以下両処理という)とが施されていても、また施され
ていなくても、いずれでもよい。毛羽やピリングの発生
を抑制し、優れた風合を追及する用途には、両処理が施
されている方が好ましい。しかし、基布を構成する繊維
は、必ずしも前記処理が施されていなくてもよい。繊維
素繊維を基布に用いる場合には、前記と同様の理由によ
り、繊維素繊維に両処理が施されている方が好ましい場
合がある。また、フィブリル化処理だけでなく染色加工
によっても毛羽が発生するので、酵素処理は、染色加工
の後に行うことが好ましい。
The flocs of the fibrous fibers fixed to the base cloth may be subjected to a fibrillation treatment and an enzymatic treatment (hereinafter referred to as both treatments) depending on the purpose of use. May be. For the purpose of suppressing the generation of fluff and pilling and pursuing an excellent feeling, it is preferable that both treatments are performed. However, the fibers constituting the base fabric do not necessarily have to be subjected to the treatment. When using fibrous fibers for the base fabric, it may be preferable that both treatments are performed on the fibrous fibers for the same reason as described above. Further, since the fluff is generated not only by the fibrillation treatment but also by the dyeing process, the enzyme treatment is preferably performed after the dyeing process.

【0012】フィブリル化処理および酵素処理は、フロ
ック加工の後であれば植毛布全体に、フロック加工の前
であれば繊維素繊維そのものか、または基布自体と固着
前のフロックとに別々に施しても、いずれでも良い。し
かし、繊維素繊維およびセルロースを主成分とする繊
維、例えば、レーヨン、ポリノジック、キュプラは、酵
素処理による繊度の低下と目減りのおそれがあるので留
意する必要がある。繊度の低下と目減りは、フロックで
は強度が低下して弾力がなくなり、風合いに乏しくなる
傾向を生じることがあるし、基布においては耐久性の低
下や、しわの発生を招きやすくなることがある。従っ
て、目減りのおそれがある場合には、フロックおよび基
布に用いる繊維の種類や繊度を考慮し、両処理を施す段
階と処理程度を決めると良い。また、フロックや基布
に、合成繊維、動物繊維、鉱物繊維、無機繊維など、セ
ルロースを主成分としない繊維を用いると、一般に、酵
素処理による繊度の低下や目減りのおそれが小さい。
The fibrillation treatment and the enzymatic treatment are separately applied to the entire flocked cloth after the flocking, or to the fibrous fibers themselves or the base cloth itself and the flocs before fixing before the flocking. Or any of them. However, it is necessary to pay attention to fibrous fibers and fibers containing cellulose as a main component, for example, rayon, polynosic, and cupra, because the fineness may be reduced and reduced due to the enzyme treatment. Decrease and decrease in fineness may cause a tendency for the strength to be reduced and the elasticity to be lost in the flock and the texture to be poor, and for the base cloth to be reduced in durability and to cause the generation of wrinkles. . Therefore, when there is a risk of loss, it is advisable to determine the stage and degree of the two treatments in consideration of the type and fineness of the fibers used for the floc and the base cloth. In addition, when fibers that do not contain cellulose as a main component, such as synthetic fibers, animal fibers, mineral fibers, and inorganic fibers, are used for the flocks and the base fabrics, generally, there is little fear that the fineness is reduced or reduced due to the enzyme treatment.

【0013】例えば、繊維素繊維のみでフロックを、合
成繊維のみで基布を構成した植毛布は、酵素処理により
基布が分解されるおそれが少ないので、植毛布全体に対
して両処理を行うと、フロックと基布とに同時に染色加
工を施すことができる。基布に用いる合成繊維の染色性
が、繊維素繊維と同程度である場合に好適である。ま
た、例えば、繊維素繊維のみでフロックを、ポリノジッ
クで基布を構成する場合は、フロック加工に先だって処
理済のフロックを製造しておくと、酵素処理により基布
が目減りすることがなく、植毛布の耐久性を維持しやす
い。
For example, in a flocking cloth composed of flocks only with fibrous fibers and a base cloth only with synthetic fibers, both treatments are performed on the entire flocking cloth because the base cloth is less likely to be decomposed by the enzyme treatment. And the flocking and the base cloth can be simultaneously dyed. It is suitable when the dyeability of synthetic fibers used for the base fabric is comparable to that of fibrous fibers. In addition, for example, when the flocks are formed of only fibrous fibers and the base fabric is formed of polynosic, if the treated flocks are manufactured before the flocking, the base fabrics are not reduced by enzymatic treatment, and the planting is performed without loss. Easy to maintain blanket durability.

【0014】[0014]

【実施例】以下、本発明を、実施例によりさらに具体的
に説明する。 実施例1 0.6mmにカットした繊度1.5デニールのテンセル
50Kgを、容量1000リットルの染色釜に入れ、7
50リットルの水を加え、300rpmの攪拌機で攪拌
しながら、フロックにフィブリル化処理および酵素処理
を施した。酵素剤にはセルソフトプラスL(ノボノルデ
ィスクバイオインダストリー(株)製,0.4%ow
f)を用い、処理液をpH5.5〜6.5に保ち、40
〜50℃で60分間処理した。しかる後、温度を80℃
まで上昇させて5分間保持し、酵素作用を止めた。その
後、水洗、脱水した。
EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. Example 1 50 kg of Tencel having a denier of 1.5 denier cut into 0.6 mm was put into a dyeing pot having a capacity of 1000 liters,
50 liters of water was added, and the floc was subjected to a fibrillation treatment and an enzyme treatment while stirring with a stirrer at 300 rpm. Cellulose Plus L (manufactured by Novo Nordisk Bioindustry, 0.4% ow)
Using f), the treatment solution was maintained at pH 5.5 to 6.5,
Treated at 5050 ° C. for 60 minutes. Thereafter, the temperature is raised to 80 ° C.
And kept for 5 minutes to stop the enzymatic action. Then, it was washed with water and dehydrated.

【0015】フィブリル化および酵素処理を施したフロ
ックを、電着溶液(スノーテックスO;日産化学(株)
製,2%ows、塩化アンモニウム;1%ows、アル
ミナゾル100;0.2%ows)に浸漬した後、脱
水、乾燥し、植毛用フロックを得た。経糸緯糸ともに3
0番手のテンセル織物(縦90本、緯65本、2/1綾
織組織)に接着剤をコーティングした後、前記のフロッ
クを静電気方式により植毛した。
The floc that has been subjected to fibrillation and enzyme treatment is applied to an electrodeposition solution (Snowtex O; Nissan Chemical Co., Ltd.)
2% ows, ammonium chloride; 1% ows, alumina sol 100; 0.2% ows), dehydrated and dried to obtain flocking flocks. 3 for both warp and weft
After coating the adhesive on the 0th-number Tencel fabric (90 vertical, 65 weft, 2/1 twill weave structure), the flock was implanted by electrostatic method.

【0016】得られた植毛布は、従来のレーヨンなどの
植毛布と比較して感触も光沢も優れたものであった。し
かも、水洗いした後に乾燥すると、従来のフロックは寝
てしまい立毛状態が非常に悪かったが、本発明の植毛布
は水洗いの前後で立毛状態が全く変わらず良好な風合を
保っており、家具、カーテン、絨毯、車両の座席などに
用いる内装材や研磨布として好適であった。
The obtained flocking cloth was excellent in feel and gloss as compared with a conventional flocking cloth such as rayon. In addition, when dried after washing with water, the conventional flocks fell asleep and the napped state was very poor, but the flocked cloth of the present invention maintained a good texture without any change in the napped state before and after washing. It was suitable as an interior material or polishing cloth used for curtains, carpets, vehicle seats, and the like.

【0017】実施例2 1mmにカットした繊度3.0デニールのテンセルを、
サンモールBK−90NM(日華化学(株)製,1cc
/l)およびソーダ灰2g/lを用い、浴比1:30、
60〜70℃で60分間精練処理を行い、水洗、脱水し
た。次に、スノーテックスO(日産化学(株)製,2%
ows)と塩化アンモニウム0.5%owsとを用いた
溶液に、フロックを浸漬して電着処理を施し、脱水し、
乾燥して植毛用フロックを得た。
Example 2 Tencel having a fineness of 3.0 denier cut into 1 mm was
Sun Mall BK-90NM (Nichika Chemical Co., Ltd., 1cc
/ L) and 2 g / l of soda ash, at a bath ratio of 1:30,
A scouring treatment was performed at 60 to 70 ° C. for 60 minutes, followed by washing and dehydration. Next, Snowtex O (Nissan Chemical Co., Ltd., 2%
ows) and a solution of 0.5% ows of ammonium chloride, immersed in flocks, subjected to electrodeposition, dehydrated,
It was dried to obtain flocks for flocking.

【0018】ポリエステルの丸編ニットの基布(フロン
ト75d/36フィラメント、バック20d/1フィラ
メント、コース40、ウェール37)に、ヨドソールA
A80(カネボウエヌエスシー(株)製)を主体として
調整した接着剤をドクターナイフでコーティングし、静
電気方式により植毛した。90〜100℃で乾燥後、1
40℃で5分間キュアーして植毛布を得た。得られた植
毛布を、セルライザー(ナガセ生化学工業(株)製,
0.3%owf)を用い、酢酸−酢酸ソーダの緩衝液で
pH5.0に保った45〜50℃の溶液で60分間処理
し、フィブリル化および酵素処理を施した。その後、水
洗、乾燥して本発明にかかる植毛布を得た。得られた植
毛布は、シルキーな感触とテンセル特有の風合を有しな
がらもしわになりにくく、衣料用布帛として好評であっ
た。テンセルの減量率は、約3〜5重量%であった。
Yodosole A is applied to a base fabric of a circular knitted polyester knit (front 75d / 36 filament, back 20d / 1 filament, course 40, wale 37).
An adhesive prepared mainly with A80 (manufactured by Kanebouenusc Co., Ltd.) was coated with a doctor knife, and the hair was implanted by an electrostatic method. After drying at 90-100 ° C, 1
Curing was performed at 40 ° C. for 5 minutes to obtain a flocked cloth. The obtained flocking cloth was treated with a cell riser (manufactured by Nagase Seikagaku Corporation,
Using 0.3% owf), the mixture was treated for 60 minutes with a solution at 45 to 50 ° C. maintained at pH 5.0 with an acetic acid-sodium acetate buffer solution, followed by fibrillation and enzyme treatment. Thereafter, the fabric was washed with water and dried to obtain a flocked cloth according to the present invention. The obtained flocking cloth had a silky feel and a texture peculiar to Tencel, but did not easily wrinkle, and was popular as a cloth for clothing. The weight loss of Tencel was about 3 to 5% by weight.

【0019】実施例3 実施例2と同様にフロックおよび基布を準備し、実施例
1と同様にフロック加工し、乾燥して植毛布を製造し
た。実施例2で用いたものと同様の溶液、ただしセルラ
イザーの濃度が0.1%owfおよび0.4%owfの
2種類を用い、得られた植毛布にフィブリル化および酵
素処理を施し、本発明にかかる植毛布を得た。
Example 3 A floc and a base cloth were prepared in the same manner as in Example 2, flocked and dried in the same manner as in Example 1 to produce a flocking cloth. Using the same solution as that used in Example 2 except that the concentration of the cell riser is 0.1% owf and 0.4% owf, the obtained flocking cloth is subjected to fibrillation and enzyme treatment. A flocking cloth according to the invention was obtained.

【0020】得られた植毛布は、共に柔軟でシルクライ
クな感触と、しわや毛羽立ちのないリッチな風合とを有
していた。また、0.4%owfの溶液で処理した植毛
布は、0.1%owfの溶液で処理したものよりも一層
風合が改善されていた。ただし、基布がテンセルである
ため酵素処理により脆化していた。表1に、得られた植
毛布について、エレメンドルフ型引裂試験機で引裂強度
を測定した結果を示す。酵素で分解される基布を用いる
場合は、予め、分解されても十分な耐久性を維持できる
ように基布を準備することが好ましい。これらの植毛布
は、高級感のある衣料用布帛として好適であった。
Both of the obtained flocking cloths had a soft and silky feel and a rich feeling without wrinkles or fluff. The flocked cloth treated with the 0.4% owf solution had a further improved feeling than that treated with the 0.1% owf solution. However, since the base fabric was Tencel, it was embrittled by the enzyme treatment. Table 1 shows the results of measuring the tear strength of the obtained flocking cloth with an Elmendorf-type tear tester. When using a base cloth that can be decomposed by an enzyme, it is preferable to prepare the base cloth in advance so that sufficient durability can be maintained even when decomposed. These flocking cloths were suitable as high-quality clothing fabrics.

【0021】[0021]

【表1】 処理液濃度 植毛布の引裂強度(Kg) 引裂強度劣化率 (%owf) (処理前1.9) (%) 0.1 1.45 23.7 0.4 0.55 71.1参考例1 実施例1と同様に製造した電着処理前のフロックに、染
色処理を、カヤラスライト レッドF5G(日本化薬
(株)製,3%owf)およびボウ硝10%owfを用
い、浴比1:30、90〜95℃で60分間施した。水
洗後、染色堅牢度を高めるためにフィックス処理を、含
銅ポリアミン系フィックス剤2g/lを用い、浴比1:
20、60℃で20分間行った後、水洗し、脱水した。
得られたフロックに、実施例1と同様に電着処理を施し
た。一方、1.5デニールのナイロンを0.6mmにカ
ットし、染色処理を、カヤノールブルーNR(日本化薬
(株)製,0.8%owf),蟻酸(85重量%)2%
owf、90〜95℃で40分間行った後、水洗、脱水
した。次いで、電着処理を、スノーテックス(日産化学
(株)製,3%ows)、塩化ナトリウム0.5%ow
s,レオミンKP(ヘキスト(株)製,0.1%ow
s)で施した。前記2種のフロックを、テンセル:ナイ
ロンの重量比が60:40の割合で混合して植毛用フロ
ックを準備した。準備した植毛用フロックを、実施例1
と同様に準備した基布に、実施例1と同じ方法で植毛し
た。得られた植毛布は、テンセル特有の風合とナイロン
の優れた耐久性とを兼備し、内装材や研磨布として好適
であった。
Table 1 Concentration of treatment liquid Tear strength of flocking cloth (Kg) Tear strength deterioration rate (% owf) (1.9 before treatment) (%) 0.1 1.45 23.7 0.4 0.55 71. 1 Reference Example 1 Dyeing treatment was performed on flocks before electrodeposition treatment manufactured in the same manner as in Example 1 using KYARAS LIGHT RED F5G (3% owf, manufactured by Nippon Kayaku Co., Ltd.) and 10% owf of borate nitrate. The application was performed at a ratio of 1:30 at 90 to 95 ° C. for 60 minutes. After washing with water, a fix treatment was carried out to enhance the color fastness, using a copper-containing polyamine-based fix agent 2 g / l, and a bath ratio of 1:
After 20 minutes at 20, 60 ° C., it was washed with water and dehydrated.
The obtained floc was subjected to an electrodeposition treatment in the same manner as in Example 1. On the other hand, 1.5 denier nylon was cut into 0.6 mm, and the dyeing treatment was performed using Kayanol Blue NR (manufactured by Nippon Kayaku Co., Ltd., 0.8% owf) and formic acid (85% by weight) 2%.
After performing owf at 90 to 95 ° C. for 40 minutes, the resultant was washed with water and dehydrated. Next, the electrodeposition treatment was performed using Snowtex (Nissan Chemical Co., Ltd., 3% ows) and sodium chloride 0.5% ow.
s, Reomin KP (Hoechst Co., Ltd., 0.1% ow)
s). The two kinds of flocks were mixed at a weight ratio of Tencel: nylon of 60:40 to prepare flocks for flocking. The prepared flocking floc was used in Example 1
The base cloth prepared in the same manner as in Example 1 was planted in the same manner as in Example 1. The obtained flocking cloth had both the feel unique to Tencel and the excellent durability of nylon, and was suitable as an interior material or a polishing cloth.

【0022】[0022]

【発明の効果】本発明の植毛布は、例えば実施例1ない
し3に示されたように、フィブリル化および酵素処理さ
れた繊維素繊維をフロックに用いることにより、繊維素
繊維の有する風合と性質とを持ちつつ、しわ、毛羽やピ
リングの発生を防止することができる。それとともに、
従来の植毛布では得られないリッチで自然な風合と耐久
性とを兼備した植毛布を実現することができる。フロッ
クとして使用する繊維素繊維のフィブリル化および酵素
処理の程度を調整し、あるいは他の繊維と混合すること
により、用途に応じた任意の風合を得ることができる。
一方で研磨布に用いる場合、フィブリル化および酵素処
理を全く施さないこともあり得る。また、しわなどの発
生を防止するためには、基布に用いる素材やその加工方
法を工夫することにより広い範囲で対応できる。このよ
うにして得られた本願発明の植毛布は、たとえフロック
がフィブリル化してもフロックが基布に固着されてお
り、繊維長が短いので、毛羽やピリングの発生を有効に
防止できる。フロックの繊度や長さの選択、フロックや
基布に用いる繊維の種類や混合の比率、あるいは植毛布
の製造方法に工夫を凝らすことにより、目的とする用途
に対応して、耐久性に優れ、洗濯などの取扱いが容易な
多種類の植毛布を製造することができる。
The flocking cloth of the present invention does not include , for example, Example 1.
As shown in FIG.
The the cellulose fibers by using the flock, while maintaining the feeling and properties possessed by the cellulose fibers, wrinkles, it is possible to prevent the occurrence of fluff or pilling. With it,
It is possible to realize a flocking cloth having both a rich, natural feel and durability that cannot be obtained with a conventional flocking cloth. By adjusting the degree of fibrillation and enzymatic treatment of the fibrous fibers used as flocks, or by mixing them with other fibers, an arbitrary feeling according to the intended use can be obtained.
On the other hand, when used for a polishing cloth, fibrillation and enzyme treatment may not be performed at all. In addition, in order to prevent the occurrence of wrinkles and the like, a wide range can be dealt with by devising a material used for the base cloth and a processing method thereof. The flocked cloth of the present invention obtained in this manner has the flock fixed to the base cloth even if the flock is fibrillated, and the fiber length is short, so that generation of fluff and pilling can be effectively prevented. By devising the fineness and length of the flock, the type and mixing ratio of the fibers used for the flock and the base fabric, or the method of manufacturing the flocked fabric, it has excellent durability in response to the intended use, Many kinds of flocking cloths that can be easily handled such as washing can be manufactured.

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】フィブリル化処理と酵素処理とが施されて
いる繊維素繊維のフロックが、基布に固着されているこ
とを特徴とする植毛布。
1. A flocking cloth characterized in that flocks of fibrous fibers which have been subjected to a fibrillation treatment and an enzyme treatment are fixed to a base cloth.
【請求項2】請求項1に記載の植毛布を用いた衣料。2. Clothing using the flocking cloth according to claim 1 . 【請求項3】請求項1に記載の植毛布を用いた内装材。3. An interior material using the flocking cloth according to claim 1 . 【請求項4】繊維素繊維のフロックをフロック加工によ
り基布に固着した後、繊維素繊維にフィブリル化処理と
酵素処理とを施すことを特徴とする、植毛布の製造方
法。
4. A method for producing a flocking fabric, comprising: after fixing flocks of fibrous fibers to a base fabric by flocking, subjecting the fibrous fibers to a fibrillation treatment and an enzyme treatment.
【請求項5】フィブリル化処理と酵素処理とを施した繊
維素繊維のフロックを製造し、フロック加工によりフロ
ックを基布に固着することを特徴とする、植毛布の製造
方法。
5. A method for producing a flocking cloth, comprising producing flocks of fibrous fibers which have been subjected to a fibrillation treatment and an enzyme treatment, and fixing the flocs to a base fabric by flocking.
JP7128261A 1995-05-26 1995-05-26 Flocked cloth and manufacturing method thereof Expired - Fee Related JP2749284B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7128261A JP2749284B2 (en) 1995-05-26 1995-05-26 Flocked cloth and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7128261A JP2749284B2 (en) 1995-05-26 1995-05-26 Flocked cloth and manufacturing method thereof

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Publication Number Publication Date
JPH08318207A JPH08318207A (en) 1996-12-03
JP2749284B2 true JP2749284B2 (en) 1998-05-13

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KR20020074355A (en) * 2001-03-20 2002-09-30 김선한 Enzyme washing wrinkle free processing of fabrics
JP4642457B2 (en) * 2004-12-24 2011-03-02 株式会社中部パイル工業所 Laminated flock processing method and laminated flock processed product
KR101134198B1 (en) * 2009-06-29 2012-04-06 김순동 tensional method in a natural fiber
BR112013014582A2 (en) * 2010-12-14 2016-09-20 3M Innovative Properties Co one-piece fibrous polishing article
JP5995965B2 (en) * 2011-06-14 2016-09-21 スリーエム イノベイティブ プロパティズ カンパニー Built-in fiber buffing article

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JPS61160445A (en) * 1985-01-07 1986-07-21 東レ株式会社 Pile raw yarn for processing flock and flock processed product and its production
JPH0734319A (en) * 1993-07-15 1995-02-03 Mitsubishi Rayon Co Ltd Cellulose acetate yarn having high coloring property

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