JP2732324B2 - Paint-coated glass plate - Google Patents
Paint-coated glass plateInfo
- Publication number
- JP2732324B2 JP2732324B2 JP3305376A JP30537691A JP2732324B2 JP 2732324 B2 JP2732324 B2 JP 2732324B2 JP 3305376 A JP3305376 A JP 3305376A JP 30537691 A JP30537691 A JP 30537691A JP 2732324 B2 JP2732324 B2 JP 2732324B2
- Authority
- JP
- Japan
- Prior art keywords
- paint
- glass plate
- group
- coated glass
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
Description
【０００１】[0001]
【産業上の利用分野】本発明は塗料被膜ガラスに関し、
特に建築美粧用及び着色水銀灯用に適したオルガノポリ
シロキサン系塗料被覆ガラス板に関する。BACKGROUND OF THE INVENTION The present invention relates to paint-coated glass.
More particularly, the present invention relates to an organopolysiloxane-based paint-coated glass plate suitable for architectural cosmetics and colored mercury lamps.
【０００２】[0002]
【従来の技術】一般に、建築美粧用ガラス板は、ガラス
板の裏面に接着力の強いエポキシ系塗料が塗布されてな
り、ガラス自身が着色している色ガラスに比較して安価
である上、どんな色にでも着色できる等の利点がある。
しかしながら、水銀灯に使用されるガラスには、水銀灯
の発する非常に強い紫外線に耐えられる塗料がないので
塗料被覆ガラス板を使用することができず、高価な色ガ
ラスが使用される。2. Description of the Related Art In general, an architectural glass plate is formed by applying an epoxy paint having a strong adhesive force to the back surface of the glass plate, and is inexpensive as compared with colored glass in which the glass itself is colored. It has the advantage that it can be colored in any color.
However, since the glass used for the mercury lamp has no paint that can withstand the very strong ultraviolet rays emitted by the mercury lamp, a paint-coated glass plate cannot be used, and expensive colored glass is used.
【０００３】所で、エポキシ樹脂系塗料を塗布したガラ
ス板は耐候性及び耐熱性に乏しく、直射日光が当たる場
合は勿論のこと、直射日光が当たらなくても、蛍光灯や
反射太陽光等が当たることにより褪色して短時間に美粧
性が失われるという欠点があった。更に、長時間の太陽
光に暴露された場合には、塗膜が剥離することがあると
いう欠点があった。A glass plate coated with an epoxy resin paint has poor weather resistance and heat resistance, so that it is not only exposed to direct sunlight but also to a fluorescent lamp or reflected sunlight even if it is not exposed to direct sunlight. There was a drawback that, upon contact, the color faded and the cosmetics were lost in a short time. Furthermore, when exposed to sunlight for a long period of time, there is a disadvantage that the coating film may peel off.
【０００４】一方、耐候性の良い溶剤可溶型フッ素樹脂
系塗料を塗布することにより、長期にわたって塗料被覆
ガラス板に耐候性を保持させることも行われているが、
フッ素樹脂が高価であるために塗料被覆ガラス板が高価
となり、建築内外装用途としての汎用性が乏しくなると
いう欠点があった。又、直射日光の当たる場所にのみ、
これらフッ素樹脂系塗料被覆ガラス板を施工することも
行われているが、施工が煩雑となるという欠点があっ
た。On the other hand, by applying a solvent-soluble fluororesin paint having good weather resistance, it is also possible to maintain the weather resistance of a paint-coated glass plate for a long time.
Since the fluororesin is expensive, the paint-coated glass plate becomes expensive, and the versatility for building interior / exterior use is poor. Also, only in places exposed to direct sunlight,
Although these fluororesin paint-coated glass sheets are also constructed, there is a drawback that the construction is complicated.
【０００５】[0005]
【発明が解決しようとする課題】そこで、本発明者等は
上記欠点を解決するために鋭意検討した結果、有機樹脂
系塗料にシリコーンを添加した塗料又は変性シリコーン
を主成分とする塗料をガラス板に塗布硬化させることに
より良好な結果が得られるということを見出し本発明に
到達した。従って、本発明の目的は耐候性、耐熱性及び
褪色防止性に優れると共に、経済性に優れた塗料被覆ガ
ラス板を提供することにある。The inventors of the present invention have conducted intensive studies to solve the above-mentioned drawbacks, and as a result, have found that a paint obtained by adding silicone to an organic resin paint or a paint containing modified silicone as a main component is coated on a glass plate. The present inventors have found that good results can be obtained by coating and curing the same, and have reached the present invention. Accordingly, an object of the present invention is to provide a paint-coated glass plate which is excellent in weather resistance, heat resistance and anti-fading properties, and which is excellent in economic efficiency.
【０００６】[0006]
【課題を解決するための手段】本発明の上記の目的は、
下記化３SUMMARY OF THE INVENTION The above objects of the present invention are as follows.
Following 3
【化３】Ｒ１ ａＳｉＸｂＯ（４−ａ−ｂ）／２ で表されるオルガノポリシロキサン、及び、エポキシ樹
脂、アクリル樹脂、ポリエステル樹脂、アルキッド樹脂
又はウレタン樹脂の中から選択される１種若しくは２種
以上の樹脂と前記化３で表されるオルガノポリシロキサ
ンとの変性物の中の少なくとも１種を主成分とする塗料
をガラス板に塗布硬化せしめてなることを特徴とする塗
料被覆ガラス板によって達成された。Embedded image R1 aSixbO(4-ab) / 2 And an organopolysiloxane represented by the formula:
Fat, acrylic resin, polyester resin, alkyd resin
Or one or two selected from urethane resins
The above resin and the organopolysiloxane represented by the above formula (3)
Containing at least one of the modified products
Coated on a glass plate and cured
This was achieved with a coated glass plate.
【０００７】化３におけるＲ1 は炭素数１〜１０の置換
若しくは非置換の炭化水素基であり、その具体例として
はメチル基、エチル基、プロピル基、ブチル基、フェニ
ル基、トリフルオロプロピル基等を挙げることができる
が、特にメチル基或いはフェニル基が工業的に有利であ
る。R 1 in Chemical Formula 3 is a substituted or unsubstituted hydrocarbon group having 1 to 10 carbon atoms, and specific examples thereof include a methyl group, an ethyl group, a propyl group, a butyl group, a phenyl group and a trifluoropropyl group. And the like, and particularly, a methyl group or a phenyl group is industrially advantageous.
【０００８】化３におけるＸは、硬化時にシロキサン骨
格或いは有機樹脂の官能基と反応して結合するものであ
り、水酸基、炭素数１〜６のアルコキシ基或いはアルケ
ノキシ基、アセトキシ基又はケトキシム基である。又、
化３におけるａ及びｂは、０．８＜ａ＜１．８、０＜ｂ
＜３及び０．８＜ａ＋ｂ＜４の関係を満足する正数であ
るが、良好な硬化皮膜を形成せしめるという観点から０
＜ｂ＜２であることが好ましい。X in the chemical formula (3) is a compound which reacts with a siloxane skeleton or a functional group of an organic resin to be bonded during curing, and is a hydroxyl group, an alkoxy group having 1 to 6 carbon atoms, an alkenoxy group, an acetoxy group or a ketoxime group. . or,
A and b in Chemical formula 3 are 0.8 <a < 1.8 , 0 <b
<3 and 0 . 8 is a positive number satisfying the relationship of <a + b <4, but is 0 from the viewpoint of forming a favorable cured film.
It is preferable that <b <2.
【０００９】Ｘが水酸基であるオルガノポリシロキサン
である場合には、単に該オルガノポリシロキサンを加熱
することにより脱水縮合反応を行わさせることができ、
これによって塗膜を硬化させることができるが、更に
鉄、スズ、アルミニウム、チタニウム、コバルト、鉛等
又はそれらの化合物の触媒を添加して塗膜の硬化を促進
させることもできる。又、この場合、水酸基を有する有
機樹脂を併用することにより、該有機樹脂の水酸基とＸ
のシラノール基とを脱水縮合反応させて架橋させること
により塗膜を硬化させることができる。When X is an organopolysiloxane having a hydroxyl group, the dehydration condensation reaction can be carried out simply by heating the organopolysiloxane,
By this, the coating film can be cured. However, a catalyst of iron, tin, aluminum, titanium, cobalt, lead or the like or a compound thereof can be added to accelerate the curing of the coating film. In this case, by using an organic resin having a hydroxyl group in combination, the hydroxyl group of the organic resin and X
The coating film can be cured by causing a dehydration-condensation reaction with the silanol groups of the above to crosslink.
【００１０】前記アルコキシ基、アルケノキシ基又はケ
トキシム基の具体例としては、メトキシ基、エトキシ
基、イソプロポキシ基、ブトキシ基、イソブトキシ基、
メトキシエトキシ基、エトキシエトキシ基、フェノキシ
基、ビニロキシ基、イソプロペニルオキシ基、アリロキ
シ基、メチルエチルケトキシム基、ジメチルケトキシム
基、メチルイソブチルケトキシム基等を挙げることがで
きる。これらの中でも、工業生産に適しているという観
点から、メトキシ基、エトキシ基及びメチルエチルケト
キシム基が特に好ましい。アセトキシ基も同様な観点か
ら好ましい。Specific examples of the alkoxy, alkenoxy or ketoxime groups include methoxy, ethoxy, isopropoxy, butoxy, isobutoxy,
Examples include a methoxyethoxy group, an ethoxyethoxy group, a phenoxy group, a vinyloxy group, an isopropenyloxy group, an allyloxy group, a methylethylketoxime group, a dimethylketoxime group, and a methylisobutylketoxime group. Among these, a methoxy group, an ethoxy group and a methylethylketoxime group are particularly preferred from the viewpoint of being suitable for industrial production. An acetoxy group is also preferred from a similar viewpoint.
【００１１】これらのアルコキシ基、アルケノキシ基、
アセトキシ基或いはケトキシム基は、室温における湿気
硬化反応によってシロキサンを形成するので、これによ
り塗膜が硬化される。この場合、硬化を促進させるため
に、有機チタネート、アルミニウムキレート、有機スズ
触媒又はアミノシラン類等の硬化触媒を使用しても良
い。These alkoxy groups, alkenoxy groups,
The acetoxy group or ketoxime group forms a siloxane by a moisture curing reaction at room temperature, whereby the coating film is cured. In this case, a curing catalyst such as an organic titanate, an aluminum chelate, an organotin catalyst, or an aminosilane may be used to promote the curing.
【００１２】本発明においては、更に、前記化３で表さ
れるオルガノポリシロキサンと、官能基として主に水酸
基或いはカルボキシル基を含有するエポキシ樹脂、アク
リル樹脂、ポリエステル樹脂、アルキッド樹脂又はウレ
タン樹脂（有機樹脂という）の１種又は２種以上との変
性物を使用することができる。In the present invention, furthermore, the organopolysiloxane represented by the above formula (3) and an epoxy resin, an acrylic resin, a polyester resin, an alkyd resin or a urethane resin containing mainly a hydroxyl group or a carboxyl group as a functional group (an organic resin) Modified with one or more resins).
【００１３】上記変性物即ち変性シリコーン樹脂は、Ｘ
を水酸基或いはアルコキシ基とした前記化３のオルガノ
ポリシロキサンと有機樹脂の水酸基或いはカルボキシル
基とを、有機チタネート触媒の存在下或いは加熱するこ
とによって脱水縮合反応若しくは脱アルコール反応をさ
せることにより容易に得ることができる。The modified product, that is, the modified silicone resin, is represented by X
Can be easily obtained by subjecting the organopolysiloxane of the above formula (3) to a hydroxyl group or an alkoxy group to a hydroxyl group or a carboxyl group of the organic resin in the presence of an organic titanate catalyst or by heating to cause a dehydration condensation reaction or a dealcoholization reaction. be able to.
【００１４】これらの変性シリコーン樹脂は、一般に、
加熱されることにより被膜を形成する。特に塗膜の耐候
性の観点から、アクリル変性シリコーン樹脂やポリエス
テル変性シリコーン樹脂を使用することが好ましい。[0014] These modified silicone resins are generally
A film is formed by heating. In particular, from the viewpoint of the weather resistance of the coating film, it is preferable to use an acrylic-modified silicone resin or a polyester-modified silicone resin.
【００１５】[0015]
【００１６】[0016]
【００１７】[0017]
【００１８】[0018]
【００１９】[0019]
【００２０】[0020]
【００２１】本発明においては、前記化３で表されるオ
ルガノポリシロキサン、該オルガノポリシロキサンとエ
ポキシ樹脂等の変性物を適宜混合して用いても良い。本
発明において使用する塗料は、以上のオルガノポリシロ
キサン或いはその変性物等に、着色剤として各種の有機
顔料や無機顔料、体質顔料、ようへん剤、紫外線吸収
剤、増粘剤、レベリング剤等を添加し混合分散する公知
の塗料製造方法により容易に製造することができる。In the present invention, the organopolysiloxane represented by the formula (3), the organopolysiloxane and a modified product such as an epoxy resin may be appropriately mixed and used. The paint used in the present invention, the above-mentioned organopolysiloxane or a modified product thereof, various organic pigments and inorganic pigments as a colorant, extender pigments, odorant, ultraviolet absorber, thickener, leveling agent, etc. It can be easily manufactured by a known coating manufacturing method of adding, mixing and dispersing.
【００２２】上記塗料は、無溶剤で使用することもでき
るが、塗装の作業性、粘度調節性等の観点から、各種の
有機溶剤を用いて希釈することが好ましく、特にトルエ
ン、キシレン等の芳香族系溶剤を使用することが工業生
産に適するので好ましい。又、塗装のレベリング性を向
上させる観点から、ポリエーテル変性シリコーン化合
物、シリコーンオイル系レベリング剤或いはフッ素系レ
ベリング剤を上記レベリング剤として使用することが好
ましい。The above-mentioned paint can be used without a solvent, but it is preferable to dilute it with various organic solvents from the viewpoint of workability of coating and viscosity controllability. It is preferable to use a group-based solvent because it is suitable for industrial production. From the viewpoint of improving the leveling property of the coating, it is preferable to use a polyether-modified silicone compound, a silicone oil-based leveling agent or a fluorine-based leveling agent as the leveling agent.
【００２３】本発明の塗料被覆ガラス板は、ガラス板の
面に上記塗料をスプレー、浸漬、刷毛或いはロール法等
の公知の塗工方法によって塗布硬化させることにより容
易に製造される。上記塗工方法の中でも、スプレー法が
塗料被覆ガラス板の生産性向上の観点から好ましい。本
発明に使用するガラス板は、特に限定されるものではな
く、並ガラス板その他の公知の建築用ガラス板を使用す
ることができる。The paint-coated glass plate of the present invention can be easily produced by coating and curing the above-mentioned paint on the surface of the glass plate by a known coating method such as spraying, dipping, brushing or a roll method. Among the above coating methods, the spray method is preferable from the viewpoint of improving the productivity of the paint-coated glass plate. The glass plate used in the present invention is not particularly limited, and a regular glass plate and other known architectural glass plates can be used.
【００２４】[0024]
【発明の効果】 本発明の塗料被覆ガラス板は、化学的
に安定で且つ比較的安価な変性シリコーンを主成分とす
る塗料又は有機樹脂系塗料にシリコーンを添加した変性
物を主成分とする塗料をガラス板の裏面に塗布硬化させ
ているので、耐候性、耐熱性及び褪色防止性に優れると
共に、経済性にも優れている。EFFECT OF THE INVENTION The paint-coated glass plate of the present invention is a paint mainly composed of a chemically stable and relatively inexpensive modified silicone-based paint or a modified resin obtained by adding silicone to an organic resin-based paint. Is applied and cured on the back surface of the glass plate, so that it is excellent in weather resistance, heat resistance and anti-fading properties, and also excellent in economic efficiency.
【００２５】[0025]
【実施例】以下実施例に従って本発明を更に詳述する
が、本発明はこれによって限定されるものではない。
尚、配合量を示す「部」は、全て「重量部」を示すEXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the present invention is limited thereto.
In addition, “parts” indicating the blending amounts all indicate “parts by weight”.
【００２６】実施例１．不揮発分５０重量％のフェニル
メチルシリコーン樹脂（ＫＲ−２８２：信越化学工業株
式会社製の商品名）１００部、酸化チタン（タイペーク
Ｒ−８２０：石原産業株式会社製の商品名）２０部及び
鉄分８重量％のオクチル酸鉄０．４部をボールミルで分
散して塗料を調製した。得られた塗料を乾燥後の膜厚が
約２０μｍになるように並ガラス板にスプレーにより塗
布し、次いで２００℃で６０分間加熱し、焼き付けして
シリコーン塗料被覆ガラス板を作製した。Embodiment 1 FIG. 100 parts of a phenylmethylsilicone resin (KR-282: trade name, manufactured by Shin-Etsu Chemical Co., Ltd.) having a nonvolatile content of 50% by weight, 20 parts of titanium oxide (Taipaque R-820, trade name, manufactured by Ishihara Sangyo Co., Ltd.) and iron 8 A coating material was prepared by dispersing 0.4 parts by weight of iron octylate in a ball mill. The obtained paint was applied to a glass plate by spraying so that the film thickness after drying was about 20 μm, then heated at 200 ° C. for 60 minutes and baked to prepare a silicone paint-coated glass plate.
【００２７】実施例２．不揮発分５０重量％のアクリル
変性シリコーン樹脂（ＫＲ−９７０６：信越化学工業株
式会社製の商品名）１００部、酸化チタン（タイペーク
Ｒ−８２０）２０部、硬化剤（ＣＡＴ−ＡＣ：信越化学
工業株式会社製の商品名）３部をボールミルで分散して
塗料（白色）を調製した。得られた塗料を実施例１と全
く同様にして並ガラス板に塗布し、次いで１８０℃、２
０分加熱し、焼き付けしてシリコーン塗料被覆ガラス板
を作製した。Embodiment 2 FIG. 100 parts of an acrylic-modified silicone resin having a nonvolatile content of 50% by weight (KR-9706: trade name, manufactured by Shin-Etsu Chemical Co., Ltd.), 20 parts of titanium oxide (Taipec R-820), and a curing agent (CAT-AC: Shin-Etsu Chemical Co., Ltd.) A paint (white) was prepared by dispersing 3 parts (trade name of a company) in a ball mill. The obtained paint was applied to a flat glass plate in the same manner as in Example 1,
It was heated for 0 minutes and baked to produce a silicone-coated glass plate.
【００２８】[0028]
【００２９】実施例３． 実施例２で使用した１００部のＫＲ−９７０６及び硬化
剤（ＣＡＴ−ＡＣ）３部の代わりに、夫々、ポリエステ
ル変性シリコーン樹脂（ＫＲ−５２２１：信越化学工業
株式会社製商品名）を８３．３部及び硬化剤（ＣＡＴ−
ＳＢ：信越化学工業株式会社製の商品名）２．５部を用
いた他は全く実施例２と同様にして、シリコーン塗料被
覆ガラス板を作製した。Embodiment 3 FIG. Instead of KR-9706 and a curing agent (CAT-AC) 3 parts of 100 parts used in Example 2, respectively, polyethylene scan Te <br/> Le-modified silicone resin (KR-5221: manufactured by Shin-Etsu Chemical Co., Ltd. 83.3 parts and a curing agent (CAT-
(SB: trade name, manufactured by Shin-Etsu Chemical Co., Ltd.) A silicone paint-coated glass plate was prepared in the same manner as in Example 2 except that 2.5 parts were used.
【００３０】実施例４． 実施例１で使用した、１００部のＫＲ−２８２の代わり
に、アルキッド変性シリコーン樹脂（ＫＲ−５２０６：
信越化学工業株式会社製商品名：不揮発分５０％）６０
部及びＫＲ−２８２を４０部混合して用いた他は実施例
１と全く同様にしてシリコーン塗料被覆ガラス板を作製
した。Embodiment 4 FIG. Instead of 100 parts of KR-282 used in Example 1, an alkyd-modified silicone resin (KR-5206:
Shin-Etsu Chemical Co., Ltd. product name: Non-volatile content 50%) 60
Parts and KR-282 were mixed in the same manner as in Example 1 except that 40 parts of KR-282 were mixed to prepare a silicone-coated glass sheet.
【００３１】比較例１ 加熱硬化型エポキシ樹脂系塗料塗布ガラス板（ビトロカ
ラー・アイボリーホワイトＶＣ１Ｗ：旭硝子株式会社製
建材用ガラス板の商品名）を用いた。Comparative Example 1 A heat-curable epoxy resin paint-coated glass plate (Vitrocolor Ivory White VC1W: trade name of glass plate for building materials manufactured by Asahi Glass Co., Ltd.) was used.
【００３２】実施例１〜４及び比較例１に係る塗料被覆
ガラス板を用いて、下記の耐候性及び耐熱性試験を行
い、評価した。結果は表１に示した通りである。Using the paint-coated glass plates according to Examples 1 to 4 and Comparative Example 1, the following weather resistance and heat resistance tests were performed and evaluated. The results are as shown in Table 1.
【００３３】又、色差計（日本電色株式会社製）を用
い、上記試験前と試験後の各塗料被覆ガラス板の被覆し
た面と反対の面（裏面）から、変色の差ΔＥを測定し
た。更に、前記試験前と試験後の各塗料被覆ガラス板の
密着性について、ＪＩＳＫ−５４００第６〜１５項に基
づくセロテープ剥離テストを行い、比較した。耐熱性試験 ２００℃の恒温室で２００時間暴露した後、上記耐候性
試験と同様にして、褪色性、変色及び密着性を測定し
た。Further, using a color difference meter (manufactured by Nippon Denshoku Co., Ltd.), the difference ΔE in discoloration was measured from the surface (back surface) opposite to the coated surface of each paint-coated glass plate before and after the test. . Furthermore, the adhesiveness of each paint-coated glass plate before and after the test was compared with a cellophane tape peeling test based on JISK-5400, paragraphs 6 to 15. Heat resistance test After exposure in a constant temperature room at 200 ° C. for 200 hours, discoloration, discoloration and adhesion were measured in the same manner as in the above weather resistance test.
【表１】 [Table 1]
Claims (1)
換の炭化水素基であり、Ｘは水酸基、炭素数１〜６のア
ルコキシ基、アルケノキシ基、アセトキシ基又はケトキ
シム基である。ａ及びｂは０．８＜ａ＜１．８、０＜ｂ
＜３、０．８＜ａ＋ｂ＜４の関係を満たす正数であ
る。）で表されるオルガノポリシロサン、及びエポキシ
樹脂、アクリル樹脂、ポリエステル樹脂、アルキッド樹
脂又はウレタン樹脂の中から選択される１種若しくは２
種以上の樹脂と前記化１で表されるオルガノポリシロキ
サンとの変性物の中の少なくとも１種を主成分とする塗
料を、ガラス板に塗布硬化せしめてなることを特徴とす
る塗料被覆ガラス板。[Claim 1] R 11 aSixbO(4-ab) / 2 (Where R1Is substituted or unsubstituted having 1 to 10 carbon atoms
X is a hydroxyl group, an alkyl group having 1 to 6 carbon atoms.
Lucoxy, alkenoxy, acetoxy or ketoki
It is a shim group. a and b are0.8 <a <1.8, 0 <b
<3.0.8Is a positive number satisfying the relationship of <a + b <4
You. ) Organopolysilosane and epoxy
Resin, acrylic resin, polyester resin, alkyd
One or two selected from fats or urethane resins
Or more resins and an organopolysiloxane represented by the above formula (1)
A coating mainly composed of at least one of denatured products with sun
Material is applied to a glass plate and cured.
Paint-coated glass plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3305376A JP2732324B2 (en) | 1991-10-24 | 1991-10-24 | Paint-coated glass plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3305376A JP2732324B2 (en) | 1991-10-24 | 1991-10-24 | Paint-coated glass plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05116990A JPH05116990A (en) | 1993-05-14 |
| JP2732324B2 true JP2732324B2 (en) | 1998-03-30 |
Family
ID=17944376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3305376A Expired - Fee Related JP2732324B2 (en) | 1991-10-24 | 1991-10-24 | Paint-coated glass plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2732324B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4803342B2 (en) * | 2004-10-19 | 2011-10-26 | 信越化学工業株式会社 | Silicone coating composition for forming scratch-resistant surface film and coated article using the same |
| DE102012111836A1 (en) * | 2012-12-05 | 2014-06-05 | Schott Ag | Coating material and substrate with a semi-transparent coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU602672B2 (en) * | 1986-01-21 | 1990-10-25 | Peter Brown | Silicone rubber compositions |
-
1991
- 1991-10-24 JP JP3305376A patent/JP2732324B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05116990A (en) | 1993-05-14 |
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