JP2503303B2 - Oil-based batting pen type eye liner-cosmetics - Google Patents
Oil-based batting pen type eye liner-cosmeticsInfo
- Publication number
- JP2503303B2 JP2503303B2 JP2312917A JP31291790A JP2503303B2 JP 2503303 B2 JP2503303 B2 JP 2503303B2 JP 2312917 A JP2312917 A JP 2312917A JP 31291790 A JP31291790 A JP 31291790A JP 2503303 B2 JP2503303 B2 JP 2503303B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- eyeliner
- iron oxide
- oil
- batting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
- A61K2800/872—Pencils; Crayons; Felt-tip pens
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は油性中綿ペン型アイライナー化粧料に関す
る。TECHNICAL FIELD The present invention relates to an oil-based batting pen type eyeliner cosmetic.
中綿式サインペン構造のアイライナー容器は、従来の
ボトル型のアイライナーに比べ、簡便で、細い線が描き
易く、アイライナーに好適な容器である。The eyeliner container with a batting felt-tip pen structure is simpler than conventional bottle-type eyeliner and is easy to draw fine lines, and is a suitable container for the eyeliner.
従来より、この中綿式サインペン構造のアイライナー
は市販されているが、全て水性化粧料を用いている。Conventionally, an eyeliner having a batting felt-tip pen structure has been commercially available, but all of them use an aqueous cosmetic composition.
この従来の中綿式アイライナーに用いられている水性
化粧料は、構造が許す範囲の粘度（50cps以下）であ
り、顔料分散安定のため0.1μｍ以下の粒径の顔料が配
合されているものもあるが水性化粧料であるので総じて
耐水性、固着性、防腐性に劣っている。The water-based cosmetics used in this conventional batting type eyeliner have a viscosity (50 cps or less) within the range allowed by the structure, and some also contain pigments with a particle size of 0.1 μm or less to stabilize the pigment dispersion. However, since it is an aqueous cosmetic, it is generally inferior in water resistance, stickiness and antiseptic property.
中綿式サインペン構造に用いられているスライバー繊
維（すき毛様繊維）のペン芯は元来防腐剤が効きにく
く、水性化粧料でこの問題を解決しようとすると、いき
おい防腐剤の配合量を増さなければならず、皮膚への刺
激、感作の可能性が高くなる。The sliver fiber (plow hair-like fiber) pen core used in the batting felt-tip pen structure originally has a poor antiseptic effect, and when trying to solve this problem with aqueous cosmetics, the amount of viscous antiseptic added increases. It must be done, and the possibility of skin irritation and sensitization increases.
耐水性、固着性を良くするためにO/W（水中油分散
型）乳化物や樹脂エマルジョンを添加する手法が、中綿
式を除くアイライナーで利用されているが、前者では粘
度を50cps以下にできず、後者な中綿、ペン芯のような
表面積の多い部品を用いる中綿式アイライナーには不向
きである。The method of adding an O / W (oil-in-water dispersion type) emulsion or resin emulsion to improve water resistance and adhesion is used for eyeliners other than batting type, but in the former case, the viscosity is less than 50 cps. This is not possible, and is not suitable for the batting type eyeliner that uses parts with a large surface area such as batting and pen cores.
無機顔料は、総じて安全性が高く、アイライナーに好
適な着色料であるが、ほとんどが金属酸化物であり、水
性化粧料中で長期間水と接すると、酸化還元による原子
価変化により変色が起り易い問題点がある。Inorganic pigments are highly safe as a whole and are suitable colorants for eyeliners, but most of them are metal oxides, and when they are in contact with water for a long time in an aqueous cosmetic composition, discoloration occurs due to a change in valence due to redox. There are problems that are likely to occur.
本発明の目的は、従来の水性中綿ペン型アイライナー
よりも、防腐性、耐水性、皮膚刺激性、色相安定性にお
いて優れた油性中綿ペン型アイライナー化粧料を提供す
ることにある。An object of the present invention is to provide an oil-based batting pen type eyeliner cosmetic composition which is more excellent in antiseptic properties, water resistance, skin irritation and hue stability than conventional aqueous batting pen type eyeliner.
本発明者は、前記課題を解決するため鋭意研究を行っ
た結果、溶剤として軽質流動イソパラフィンを使用し、
分散剤として脂肪族カルボン酸、顔料として微粒子の無
機顔料を使用し、粘度を50cps以下とすることによっ
て、解決することを見い出し、本発明を完成した。The present inventor, as a result of intensive research to solve the above problems, using light liquid isoparaffin as a solvent,
The inventors have found that the problem can be solved by using an aliphatic carboxylic acid as a dispersant, a fine-particle inorganic pigment as a pigment, and a viscosity of 50 cps or less, and completed the present invention.
即ち、本発明は、炭素数８〜15の軽質流動イソパラフ
ィン、粒径0.1μｍ以下の無機顔料、炭素数12〜22の脂
肪族カルボン酸を必須成分として含む、粘度を50cps以
下である油性中綿ペン型容器で使用するアイライナー化
粧料である。さらに、好ましくは、炭素数８〜15の軽質
流動イソパラフィンを25〜90重量％、粒径0.1μｍ以下
の無機顔料を８〜60重量％、炭素数12〜22の脂肪族カル
ボン酸を２〜40重量％含むものである。That is, the present invention relates to an oil-filled pen having a viscosity of 50 cps or less, which contains light liquid isoparaffin having 8 to 15 carbon atoms, an inorganic pigment having a particle size of 0.1 μm or less, and an aliphatic carboxylic acid having 12 to 22 carbon atoms as essential components. An eyeliner cosmetic used in a mold container. Further, preferably, 25 to 90% by weight of light liquid isoparaffin having 8 to 15 carbon atoms, 8 to 60% by weight of inorganic pigment having a particle size of 0.1 μm or less, and 2 to 40% of aliphatic carboxylic acid having 12 to 22 carbon atoms. It contains the weight%.
無機顔料としては、粒径0.1μｍ以下の黒酸化鉄、茶
酸化鉄、ベンガラ、黄酸化鉄、酸化クロム、水酸化クロ
ムよりなる群より選ばれた少なくとも１種の顔料が好ま
しい。As the inorganic pigment, at least one pigment selected from the group consisting of black iron oxide, brown iron oxide, red iron oxide, yellow iron oxide, chromium oxide, and chromium hydroxide having a particle size of 0.1 μm or less is preferable.
次に本発明を詳細に説明する。 Next, the present invention will be described in detail.
主溶剤としては炭素数８〜15の軽質流動イソパラフィ
ンを使用する。As the main solvent, light liquid isoparaffin having 8 to 15 carbon atoms is used.
軽質流動イソパラフィンは、乾燥性の面で流動パラフ
ィンより優れている。C8より炭素数が少ないと刺激性が
あり、C15より炭素数が多いと乾燥性が悪い。Light liquid isoparaffin is superior to liquid paraffin in terms of drying property. When the carbon number is lower than that of C 8, it is irritating, and when the carbon number is higher than that of C 15 , the drying property is poor.
特にC10〜C11の流動イソパラフィンが最も好ましい。Particularly, C 10 to C 11 liquid isoparaffin is most preferable.
配合量は25〜90重量％である。 The compounding amount is 25 to 90% by weight.
25重量％未満であると、粘度が50cpsより高くなり、9
0重量％を超えると色が薄くなりすぎる。If it is less than 25% by weight, the viscosity will be higher than 50 cps and
If it exceeds 0% by weight, the color becomes too light.
顔料は粒径0.1μｍ以下の無機顔料を使用する。黒酸
化鉄、茶酸化鉄、ベンガラ、黄酸化鉄、酸化クロム、水
酸化クロムの単独または混合物を使用する。As the pigment, an inorganic pigment having a particle diameter of 0.1 μm or less is used. Black iron oxide, brown iron oxide, red iron oxide, yellow iron oxide, chromium oxide, chromium hydroxide are used alone or in a mixture.
上記黒酸化鉄は、（１−ｎ）FeO−ｎ−Fe2O3で示され
るフェライト類であり、茶酸化鉄は、γ−Fe2O3で示さ
れるγ−ヘマタイトである。The black iron oxide are ferrites represented by (1-n) FeO-n -Fe 2 O 3, brown iron oxide is a γ- hematite represented by γ-Fe 2 O 3.
粒径が0.1μｍを越えると、顔料の沈降分離が中綿、
ペン芯内で発生し、塗布時の色相変化を起こす。If the particle size exceeds 0.1 μm, sedimentation and separation of the pigment will cause batting,
It occurs inside the pen core and causes a hue change during application.
配合量は８〜60重量％である。 The compounding amount is 8 to 60% by weight.
配合量が８重量％より少ないと、色が薄すぎ、60重量
％を越えると粘度が50cps以上と高くなりすぎる。If the blending amount is less than 8% by weight, the color is too light, and if the blending amount exceeds 60% by weight, the viscosity becomes too high at 50 cps or more.
分散剤としては、炭素数12〜22の脂肪族カルボン酸が
使用され、ラウリル酸、ステアリン酸、ベヘリン酸等の
直鎖の飽和脂肪族カルボン酸、イソステアリン酸等の分
枝の飽和脂肪族カルボン酸、リノール酸、リノレン酸、
オレイン酸、エルカ酸等の不飽和脂肪族カルボン酸が用
いられる。上記直鎖の飽和脂肪族カルボン酸は、融点が
高く固化（結晶化）し易いため、単独で用いることは難
しく、他のカルボン酸と併用することがのぞましい。As the dispersant, an aliphatic carboxylic acid having a carbon number of 12 to 22 is used, and a linear saturated aliphatic carboxylic acid such as lauric acid, stearic acid and behenic acid, and a branched saturated aliphatic carboxylic acid such as isostearic acid. , Linoleic acid, linolenic acid,
Unsaturated aliphatic carboxylic acids such as oleic acid and erucic acid are used. The above linear saturated aliphatic carboxylic acid has a high melting point and is easily solidified (crystallized), so that it is difficult to use it alone, and it is desirable to use it in combination with another carboxylic acid.
C12より炭素数が少ないと、刺激性があり、分散性も
悪い。When the carbon number is lower than that of C 12 , it is irritating and has poor dispersibility.
C22より炭素数が多いと、分散後の粘度が高くなり、
又低温時にゲル化を起こす場合があり好ましくない。If the carbon number is higher than that of C 22 , the viscosity after dispersion becomes high,
In addition, gelation may occur at low temperatures, which is not preferable.
配合量は３〜40重量％である。配合量が３重量％より
少ないと、顔料分散剤としての充分な効果がみられず、
40重量％より多くなると、分散剤としての効果は飽和し
て、それ以上の効果がないばかりでなく、経済的でな
く、かつ粘度が高くなる。The compounding amount is 3 to 40% by weight. If the blending amount is less than 3% by weight, no sufficient effect as a pigment dispersant can be seen,
When it is more than 40% by weight, the effect as a dispersant is saturated and not only there is no further effect, but it is not economical and the viscosity becomes high.
その他の配合成分としては、分散安定性や粘度に問題
がなければ、酸化防止剤、粘度調整剤、皮膚の保護剤等
の添加剤を任意に添加することができる。As other compounding ingredients, additives such as an antioxidant, a viscosity modifier and a skin protector can be optionally added as long as there is no problem in dispersion stability and viscosity.
製造方法としては、軽質流動イソパラフィンに脂肪族
カルボン酸（分散剤）を攪拌溶解し、それに顔料を加
え、ボールミル、サンドミル等の分散機またはホモミキ
サーで攪拌、分散して分散液を得る。As a production method, an aliphatic carboxylic acid (dispersant) is dissolved in light liquid isoparaffin with stirring, a pigment is added thereto, and the mixture is stirred and dispersed with a disperser such as a ball mill or a sand mill or a homomixer to obtain a dispersion liquid.
他の方法としては、アルカリ性水溶液に分散剤として
脂肪族カルボン酸の塩を溶解し、顔料を加えて、攪拌
し、中和により顔料の分散剤吸着物を凝集させる。この
凝集物を分散させるには、凝集物に溶剤としての軽質流
動イソパラフィンを加えて攪拌し、分散剤を吸着した顔
料を溶剤層に移行させた後分離した水層を除去する方
法、また凝集物を水により洗浄し、余分なカルボン酸や
塩類をとり除いた後乾燥脱水し、溶剤としての軽質流動
イソパラフィンに添加する方法がある。いずれの方法
も、若干含まれている水を、加熱、減圧等を行ってとり
除かれる。As another method, a salt of an aliphatic carboxylic acid as a dispersant is dissolved in an alkaline aqueous solution, a pigment is added, and the mixture is stirred to neutralize the dispersant adsorbed product of the pigment. In order to disperse the aggregate, a method of adding light liquid isoparaffin as a solvent to the aggregate and stirring the mixture to transfer the pigment adsorbing the dispersant to the solvent layer and then removing the separated aqueous layer, or the aggregate Is washed with water to remove excess carboxylic acid and salts, dried and dehydrated, and then added to light liquid isoparaffin as a solvent. In any of the methods, a small amount of water is removed by heating, depressurizing or the like.
特に水溶液中で処理された微粒子顔料を用いる場合に
は、連続的に上記脱水方法を実施する方が容易に分散液
が得られる。いずれの方法共、粗大粒子が含まれている
場合には遠心分離により粗大粒子をとり除き、顔料粒子
径を0.1μｍ以下になるようにしなければならない。Particularly when a fine particle pigment treated in an aqueous solution is used, it is easier to obtain the dispersion liquid by continuously carrying out the dehydration method. In either method, when coarse particles are contained, the coarse particles must be removed by centrifugation so that the pigment particle diameter becomes 0.1 μm or less.
これらの操作により得られた精製分散液を必要に応じ
て、濃縮、希釈による濃度調整を行い、その後必要に応
じて、酸化防止剤、粘度調整剤等を添加し、攪拌してア
イライナー液を得る。If necessary, the purified dispersion obtained by these operations is subjected to concentration adjustment by concentration and dilution, after which, if necessary, an antioxidant, a viscosity adjusting agent, etc. are added, and the eyeliner liquid is stirred to form an eyeliner liquid. obtain.
本発明のアイライナー液は、溶剤に軽質流動イソパラ
フィンを用いているため、特に防腐剤を添加しなくて
も、良好な防腐性が得られ、従って防腐剤配合による刺
激や感作等の弊害もない。Since the eyeliner liquid of the present invention uses light liquid isoparaffin as a solvent, good antiseptic property can be obtained without addition of an antiseptic agent, and therefore, adverse effects such as irritation and sensitization due to the antiseptic compounding can be obtained. Absent.
また分散剤として脂肪酸類を使用することで、耐水性
が良好なものとなり、顔料粒径を0.1μｍ以下とするこ
とで、分散安定性が良好なものとなる。全体の系が非水
系であるため、顔料の原子価変化による色相変化も少な
い。Further, when fatty acids are used as the dispersant, the water resistance becomes good, and when the pigment particle size is 0.1 μm or less, the dispersion stability becomes good. Since the entire system is non-aqueous, there is little change in hue due to changes in the valence of the pigment.
粘度が50cps以下にできるので中綿ペン型アイライナ
ー化粧料容器による使用が可能である。Since the viscosity can be 50 cps or less, it can be used with a batting pen type eyeliner cosmetic container.
以下に実施例により、本発明を更に具体的に説明する
が、本発明は、この実施例によって何等限定されるもの
ではない。Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
（実施例１） 黒酸化鉄（三菱金属製マグネタイト） 35.0重量％ イソステアリン酸 35,0重量％ 軽質流動イソパラフィン（日本シェル化学シェルゾール
71L） 残 量 合計100重量％ 軽質流動イソパラフィンにイソステアリン酸を加え、
充分攪拌、混合した後、黒酸化鉄を加えて、ボールミル
で一週間攪拌してアイライナー原液を得た。これを遠心
分離して、粘度25cps、黒酸化鉄30重量％、イソステア
リン酸20重量％のアイライナー液を得た。この時の顔料
の平均粒径は0.067μｍであった。(Example 1) Black iron oxide (Magnetite manufactured by Mitsubishi Metals) 35.0% by weight Isostearic acid 35,0% by weight Light liquid isoparaffin (Nippon Shell Chemical Shell Sole
71L) Total amount 100% by weight Add isostearic acid to light liquid isoparaffin,
After thoroughly stirring and mixing, black iron oxide was added, and the mixture was stirred for 1 week in a ball mill to obtain an eyeliner stock solution. This was centrifuged to obtain an eyeliner liquid having a viscosity of 25 cps, black iron oxide 30% by weight, and isostearic acid 20% by weight. The average particle size of the pigment at this time was 0.067 μm.
（実施例２） ベンガラ（大東化成製No.217） 40.0重量％ オレイン酸ナトリウム 30.0重量％ 精製水 残 量 合計100.0重量％ 精製水にオレイン酸ナトリウムを加え、攪拌溶解した
後、ベンガラを加えて、ホモミキサーで２時間攪拌し
た。(Example 2) Bengal (No.217 manufactured by Daito Kasei) 40.0% by weight Sodium oleate 30.0% by weight Purified water residual amount 100.0% by weight Sodium oleate was added to the purified water and dissolved with stirring, and then red iron oxide was added, The mixture was stirred with a homomixer for 2 hours.
この後、少量の塩酸を加えて、pHを5.5とし、ベンガ
ラのオレイン酸吸着物を凝集沈降させ、水洗５回を行
い、減圧濾過により、凝集物を回収した。After that, a small amount of hydrochloric acid was added to adjust the pH to 5.5, the oleic acid adsorbate of red iron oxide was aggregated and precipitated, washed with water 5 times, and the aggregate was recovered by vacuum filtration.
この凝集物の固形分は60重量％であり、そのうちベン
ガラが33重量％、オレイン酸が27重量％であった。The solid content of this aggregate was 60% by weight, of which red iron oxide was 33% by weight and oleic acid was 27% by weight.
この凝集物を用いて、次の配合によりアイライナー液
を得た。Using this aggregate, an eyeliner liquid was obtained by the following formulation.
凝集物 70重量％ 軽質流動イソパラフィン 30重量％ 合計100重量％ 先づ、凝集物に軽質流動イソパラフィンを加えて、軽
く攪拌した後、70℃付近で加熱し、メタノールを除去し
た後、徐々に加熱し110℃で30分加熱して水分を除去し
た。これを遠心分離して、粘度32cps、ベンガラ27重量
％、オレイン酸22重量％のアイライナー液を得た。この
ときの顔料の平均粒径は0.076μｍであった。Aggregate 70 wt% Light liquid isoparaffin 30 wt% Total 100 wt% Light liquid isoparaffin was added to the agglomerate first, stirred lightly, then heated at around 70 ° C to remove methanol and then gradually heated. Water was removed by heating at 110 ° C for 30 minutes. This was centrifuged to obtain an eyeliner liquid having a viscosity of 32 cps, red iron oxide 27% by weight, and oleic acid 22% by weight. The average particle size of the pigment at this time was 0.076 μm.
（比較例１） 1.黒酸化鉄 25重量％ 2.イソステアリン酸 25重量％ 3.ポリオキシエチレン（重合度20）オレイルエーテル20
重量％ 4.精製水 残 量 合計100重量％ 上記2,3,4を充分攪拌し、混合し、１を加えて、ボー
ルミルで一週間攪拌して、これを遠心分離し、アイライ
ナー水性原液を得た。(Comparative Example 1) 1. Black iron oxide 25% by weight 2. Isostearic acid 25% by weight 3. Polyoxyethylene (degree of polymerization: 20) oleyl ether 20
% By weight 4. Total residual amount of purified water 100% by weight The above 2,3,4 are thoroughly stirred, mixed, 1 is added, and the mixture is stirred for 1 week in a ball mill, and this is centrifuged to remove the aqueous eyeliner stock solution. Obtained.
5.アイライナー水性原液 92.7重量％ 6.1,3−ブチレングリコール 7.0重量％ 7.パラオキシ安息香酸メチル 0.2重量％ 8.パラオキシ安息香酸プロピル 0.1重量％ 合計100 重量％ 上記6,7,8を充分攪拌、混合した後、５を加え、１時
間攪拌して水性アイライナー液を得た。5. Aqueous solution of eyeliner 92.7% by weight 6.1,3-butylene glycol 7.0% by weight 7. Methyl paraoxybenzoate 0.2% by weight 8. Propyl paraoxybenzoate 0.1% by weight Total 100% by weight The above 6,7,8 are thoroughly stirred, After mixing, 5 was added and stirred for 1 hour to obtain an aqueous eyeliner liquid.
このアイライナー液の粘度は21cps、黒酸化鉄28重量
％、イソステアリン酸及びポリオキシエチレン（20）オ
レイルエーテル34重量％、平均粒径は0.061μｍであっ
た。The viscosity of this eyeliner solution was 21 cps, black iron oxide 28% by weight, isostearic acid and polyoxyethylene (20) oleyl ether 34% by weight, and the average particle size was 0.061 μm.
（比較例２） 実施例２と同様の方法で、顔料の凝集物を得、次の配
合によりアイライナー原液を得た。(Comparative Example 2) In the same manner as in Example 2, a pigment aggregate was obtained, and an eyeliner stock solution was obtained by the following formulation.
1.凝集物 60重量％ 2.ポリオキシエチレン（20）オレイルエーテル10重量％ 3.精製水 30重量％ 2,3を充分攪拌した後、１を加え、２時間攪拌後、遠
心分離によりアイライナー原液を得た。1. Aggregate 60% by weight 2. Polyoxyethylene (20) oleyl ether 10% by weight 3. Purified water 30% by weight After thoroughly stirring 2,3, add 1 and stir for 2 hours, then centrifuge for eyeliner A stock solution was obtained.
さらに次の配合により、水性アイライナー液を得た。 Furthermore, an aqueous eyeliner liquid was obtained by the following formulation.
4.アイライナー原液 92.7重量％ 5.1,3ブチレングリコール 7.0重量％ 6.パラオキシ安息香酸メチル 0.2重量％ 7.パラオキシ安息香酸プロピル 0.1重量％ 5,6,7を充分攪拌、混合した後、４を加え、１時間攪
拌し、水性アイライナー液を得た。4. Eyeliner stock solution 92.7% by weight 5.1,3 butylene glycol 7.0% by weight 6. Methyl paraoxybenzoate 0.2% by weight 7. Propyl paraoxybenzoate 0.1% by weight 5,6,7 are thoroughly stirred and mixed, and then 4 is added. The mixture was stirred for 1 hour to obtain an aqueous eyeliner liquid.
このアイライナーの粘度は23cps、ベンガラ25重量
％、オレイン酸及びポリオキシエチレン（20）オレイル
エーテル36重量％、平均粒径は0.081μｍであった。The eyeliner had a viscosity of 23 cps, red iron oxide 25% by weight, oleic acid and polyoxyethylene (20) oleyl ether 36% by weight, and an average particle size of 0.081 μm.
以上の実施例、比較例で製造したアイライナー液を用
いて USPXXI準拠の防腐効力試験。Antiseptic efficacy test according to USP XXI using the eyeliner solutions produced in the above Examples and Comparative Examples.
中綿式アイライナー容器で、２週間使用後のペン先
菌数測定。Measurement of the number of pen nibs after 2 weeks of use in a batting type eyeliner container.
耐水性（手の甲に塗布し、耐水性を発揮するまでの
時間により評価）。Water resistance (applied to the back of the hand and evaluated by the time it takes to exhibit water resistance).
皮膚刺激性（20人によるモニターテスト、分子は20
人中刺激を感じた人数）。Skin irritation (monitor test by 20 people, molecule is 20
The number of people who felt irritation).
色相変化（50℃環境下で、１ヶ月静置した後の色相
変化）。Hue change (hue change after standing for 1 month at 50 ° C environment).
について評価検討を行った。第１表にその結果を示す。Was evaluated and examined. Table 1 shows the results.
〔発明の効果〕 本発明のアイライナー液は、粘度50cps以下、顔料の
粒径を0.1μｍ以下とすることで、顔料分散安定性、筆
記性の点で中綿ペン型アイライナー容器に好適な化粧料
となる。 [Effects of the Invention] The eyeliner liquid of the present invention has a viscosity of 50 cps or less and a pigment particle size of 0.1 μm or less, so that it is suitable for a batting pen type eyeliner container in terms of pigment dispersion stability and writability. It becomes a fee.
特に、軽質流動イソパラフィンと脂肪酸類と無機顔料
の組合わせと顔料粒径を0.1μｍ以下にすることで顔料
分散安定性を確保している。In particular, the pigment dispersion stability is ensured by combining light liquid isoparaffin, fatty acids, and an inorganic pigment and setting the pigment particle size to 0.1 μm or less.
軽質流動イソパラフィンを主溶剤とし、分散剤に脂肪
酸類を使用したことによって、ペン容器での防腐効力、
耐水性、色相変化に優れ、特に防腐剤を使用しないこと
で、皮膚刺激性が殆んどないという効果を奏しており、
中綿ペン型容器で使用するのに優れたアイライナー化粧
料である。By using light liquid isoparaffin as the main solvent and fatty acids as the dispersant, the antiseptic effect in the pen container,
Excellent in water resistance and hue change, and by not using a preservative, it has the effect of having almost no skin irritation.
It is an excellent eyeliner cosmetic for use in batting pen type containers.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭61−60605（ＪＰ，Ａ) 特開 昭61−87616（ＪＰ，Ａ) 特開 昭60−255714（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP 61-60605 (JP, A) JP 61-87616 (JP, A) JP 60-255714 (JP, A)
Claims (3)
粒径0.1μｍ以下の無機顔料、炭素数12〜22の脂肪族カ
ルボン酸を必須成分として含む粘度が50cps以下である
油性中綿ペン型容器で使用するアイライナー化粧料。1. A light liquid isoparaffin having 8 to 15 carbon atoms,
An eyeliner cosmetic for use in an oil-filled pad pen type container having an inorganic pigment having a particle diameter of 0.1 μm or less and an aliphatic carboxylic acid having 12 to 22 carbon atoms as an essential component and having a viscosity of 50 cps or less.
機顔料を８〜60重量％、脂肪族カルボン酸を３〜40重量
％含有する請求項（１）記載の油性中綿ペン型容器で使
用するアイライナー化粧料。2. An oil-based batting pen container according to claim 1, containing 25 to 90% by weight of light liquid isoparaffin, 8 to 60% by weight of inorganic pigment, and 3 to 40% by weight of aliphatic carboxylic acid. Eyeliner cosmetics.
ラ、黄酸化鉄、酸化クロム、水酸化クロムよりなる群よ
り選ばれた少なくとも１種である請求項（１）又は
（２）記載の油性中綿ペン型容器で使用するアイライナ
ー化粧料。3. The inorganic pigment is at least one selected from the group consisting of black iron oxide, brown iron oxide, red iron oxide, yellow iron oxide, chromium oxide, and chromium hydroxide. An eyeliner cosmetic for use in the described oil-based filling pen type container.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2312917A JP2503303B2 (en) | 1990-11-20 | 1990-11-20 | Oil-based batting pen type eye liner-cosmetics |
| CA 2055372 CA2055372A1 (en) | 1990-11-20 | 1991-11-13 | Reservoir pen type oily eyeliner cosmetic |
| GB919124540A GB9124540D0 (en) | 1990-11-20 | 1991-11-19 | Oily cosmetic composition |
| FR9114219A FR2669223B1 (en) | 1990-11-20 | 1991-11-19 | OILY COSMETIC PRODUCT FOR EYELID EYE STRAPPING DEVICE, PARTICULARLY OF THE FIBER POINTED TYPE. |
| KR1019910020741A KR970009878B1 (en) | 1990-11-20 | 1991-11-20 | Reservoir pen type oily eyeliner cosmetic |
| DE19914138325 DE4138325C2 (en) | 1990-11-20 | 1991-11-21 | Oily eyeliner cosmetic filler type |
| GB9201977A GB2263634A (en) | 1990-11-20 | 1992-01-30 | Reservoir pen type oily eyeliner cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2312917A JP2503303B2 (en) | 1990-11-20 | 1990-11-20 | Oil-based batting pen type eye liner-cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04187621A JPH04187621A (en) | 1992-07-06 |
| JP2503303B2 true JP2503303B2 (en) | 1996-06-05 |
Family
ID=18035022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2312917A Expired - Lifetime JP2503303B2 (en) | 1990-11-20 | 1990-11-20 | Oil-based batting pen type eye liner-cosmetics |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP2503303B2 (en) |
| KR (1) | KR970009878B1 (en) |
| CA (1) | CA2055372A1 (en) |
| DE (1) | DE4138325C2 (en) |
| FR (1) | FR2669223B1 (en) |
| GB (2) | GB9124540D0 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2503303B2 (en) * | 1990-11-20 | 1996-06-05 | 三菱鉛筆株式会社 | Oil-based batting pen type eye liner-cosmetics |
| JP3037521B2 (en) * | 1992-11-04 | 2000-04-24 | 三菱鉛筆株式会社 | Cosmetics |
| JP4493449B2 (en) * | 2004-09-02 | 2010-06-30 | 三菱鉛筆株式会社 | Eye makeup cosmetics |
| JP5526690B2 (en) * | 2009-10-06 | 2014-06-18 | 堺化学工業株式会社 | Dispersion containing zinc oxide or titanium oxide |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL266499A (en) * | 1960-07-08 | |||
| JPS5852362A (en) * | 1981-09-22 | 1983-03-28 | Fuji Photo Film Co Ltd | Production of aqueous dispersion of carbon black |
| JPS60255714A (en) * | 1984-05-31 | 1985-12-17 | Pola Chem Ind Inc | Nonaqueous makeup cosmetic |
| JPS6130512A (en) * | 1984-07-20 | 1986-02-12 | Yoshiaki Koike | Cosmetic ink composition |
| JPS6160605A (en) * | 1984-08-30 | 1986-03-28 | Shiseido Co Ltd | Cosmetic |
| JPS6187616A (en) * | 1984-10-05 | 1986-05-06 | Pola Chem Ind Inc | Non-aqueous eye-make |
| JPH03294212A (en) * | 1990-04-13 | 1991-12-25 | Kao Corp | Solid oily cosmetic |
| JPH0441410A (en) * | 1990-06-05 | 1992-02-12 | Kao Corp | Cosmetic composition |
| JP2503303B2 (en) * | 1990-11-20 | 1996-06-05 | 三菱鉛筆株式会社 | Oil-based batting pen type eye liner-cosmetics |
-
1990
- 1990-11-20 JP JP2312917A patent/JP2503303B2/en not_active Expired - Lifetime
-
1991
- 1991-11-13 CA CA 2055372 patent/CA2055372A1/en not_active Abandoned
- 1991-11-19 FR FR9114219A patent/FR2669223B1/en not_active Expired - Lifetime
- 1991-11-19 GB GB919124540A patent/GB9124540D0/en active Pending
- 1991-11-20 KR KR1019910020741A patent/KR970009878B1/en not_active IP Right Cessation
- 1991-11-21 DE DE19914138325 patent/DE4138325C2/en not_active Expired - Fee Related
-
1992
- 1992-01-30 GB GB9201977A patent/GB2263634A/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| KR970009878B1 (en) | 1997-06-19 |
| DE4138325C2 (en) | 1997-12-18 |
| CA2055372A1 (en) | 1992-05-21 |
| FR2669223A1 (en) | 1992-05-22 |
| GB9124540D0 (en) | 1992-01-08 |
| GB9201977D0 (en) | 1992-03-18 |
| FR2669223B1 (en) | 1995-05-12 |
| JPH04187621A (en) | 1992-07-06 |
| KR920009384A (en) | 1992-06-25 |
| DE4138325A1 (en) | 1992-05-21 |
| GB2263634A (en) | 1993-08-04 |
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