JP3273573B2 - Two-phase cosmetics - Google Patents
Two-phase cosmeticsInfo
- Publication number
- JP3273573B2 JP3273573B2 JP18819792A JP18819792A JP3273573B2 JP 3273573 B2 JP3273573 B2 JP 3273573B2 JP 18819792 A JP18819792 A JP 18819792A JP 18819792 A JP18819792 A JP 18819792A JP 3273573 B2 JP3273573 B2 JP 3273573B2
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Description
【０００１】[0001]
【産業上の利用分野】本発明は二相型化粧料に関し、更
に詳しくは皮膚上でのべとつき、てかり、化粧くずれ等
の不快感を防ぐことのできる二相型化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a two-phase cosmetic, and more particularly, to a two-phase cosmetic capable of preventing stickiness, shininess, makeup loss and the like on the skin.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
皮膚上でのべとつきや油っぽさを防止するために、収斂
剤や無機粉体を配合した水白粉、カラミンローション等
のいわゆる二相型化粧料が開発されている。2. Description of the Related Art
In order to prevent stickiness and oiliness on the skin, so-called two-phase cosmetics such as water-white powder and calamine lotion containing an astringent or inorganic powder have been developed.
【０００３】しかし、二相型化粧料においては、上記収
斂剤を配合しただけでは皮膚上での良好な感触が得られ
ないこと、一方、無機粉体を配合した場合、水系では該
無機粉体が凝集し再分散しにくいため商品形態として好
ましくないこと、該無機粉体の表面が親水性であるため
油処理能力（吸油能）を失なうこと及び皮膚上でのきし
み感やべとつき感をもたらすこと等により満足のいくも
のは未だ得られていない。更に、一般に吸油能が高いと
される樹脂を配合した場合でも、水系では安定に配合す
ることが困難であり、また良好に分散しうる樹脂を用い
た場合でも、得られる二相型化粧料の多くは良好な使用
感をもたらすものではない。[0003] However, in a two-phase type cosmetic, a good feel on the skin cannot be obtained only by blending the above-mentioned astringent. Is not desirable as a commercial form because of the difficulty of coagulation and re-dispersion. The surface of the inorganic powder is hydrophilic, so that it loses its oil treatment ability (oil absorption ability) and has a squeaky and sticky feeling on the skin. Satisfactory results have not yet been obtained. Furthermore, even when a resin which is generally considered to have high oil-absorbing ability is blended, it is difficult to blend it stably in an aqueous system, and even when a resin which can be dispersed well is used, the obtained two-phase cosmetic Many do not provide good feel.
【０００４】そこで、粉体の分散性が良好で、油処理能
力に優れ、かつ良好な使用感の得られる二相型化粧料の
開発が望まれていた。[0004] Therefore, there has been a demand for the development of a two-phase cosmetic which has good dispersibility of the powder, excellent oil processing ability, and a good feeling of use.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、かかる実
情に鑑み鋭意検討した結果、樹脂表面を無機物で覆って
なる粉体の水系分散液が良好な分散性を示し、しかも皮
膚上でのべとつきやてかりを生じないことを見出し、本
発明を完成するに至った。Means for Solving the Problems The inventors of the present invention have conducted intensive studies in view of such circumstances, and as a result, have found that an aqueous dispersion of a powder in which the resin surface is covered with an inorganic substance has a good dispersibility, and that the powder has an excellent dispersibility on the skin. The present inventors have found that stickiness and shimmer do not occur, and have completed the present invention.
【０００６】すなわち、本発明は、平均粒径０．０１〜
５００μmの樹脂粒子の表面を、酸化亜鉛、タルク、酸
化チタン、セリサイト及びシリカから選ばれる平均粒径
０．０１〜５００μmの無機物により被覆してなる粉
体、及び水性媒体を含有することを特徴とする二相型化
粧料を提供するものである。That is, the present invention provides an average particle size of 0.01 to
It is characterized by containing a powder obtained by coating the surface of 500 μm resin particles with an inorganic substance having an average particle diameter of 0.01 to 500 μm selected from zinc oxide, talc, titanium oxide, sericite and silica, and an aqueous medium. And a two-phase cosmetic.
【０００７】本発明に好ましく使用される樹脂として
は、例えば、以下の（ａ）〜（ｉ）に示すものが挙げら
れる。The resins preferably used in the present invention include, for example, those shown in the following (a) to (i).
【０００８】（ａ）「トレフィルＥ−５００」、「トレ
フィルＥ−５０１」（以上、東レダウシリコーン社製）
等のジメチルポリシロキサン重合体。 （ｂ）下記一般式（１）及び（２）で表わされる構造単
位を有するアクリレート共重合体。(A) "Trefill E-500", "Trefill E-501" (from Toray Dow Silicone Co., Ltd.)
Dimethylpolysiloxane polymer. (B) An acrylate copolymer having structural units represented by the following general formulas (1) and (2).
【０００９】[0009]
【化１】 Embedded image
【００１０】上記アクリレート共重合体の特に好ましい
例としては、「ＰＯＬＹＴＲＡＰ」（ダウ・コーニング
社製）が挙げられる。 （ｃ）多孔性ビニル系ポリマーであって溶解度パラメー
タが７〜１０のビニル系モノマーの一種又は二種以上を
重合し、更に多孔質化して得られるもの。具体例として
は、特開昭６３−３１６７１５号公報に記載のものが挙
げられる。 （ｄ）シロキサン結合が三次元的に延びた網状構造中の
ケイ素原子に１個のメチル基が結合した無機と有機との
中間構造を有するポリメチルセスキオキサン。ポリメチ
ルセスキオキサンの特に好ましい例としては「トスパー
ル２４０」、「トスパール１２０」、「トスパール１３
０」、「トスパール１４０」（以上、東芝シリコーン社
製）等が挙げられる。 （ｅ）「マイクロスフェアーＭ」、「マイクロスフェア
Ｍ−１００」、「マイクロスフェアＭ−３００」、「マ
イクロスフェアＭ−４００」（以上、松本油脂社製）等
のポリメチルメタクリレート。 （ｆ）「ＳＰ−５００」（東レ社製）等のナイロンパウ
ダー。 （ｇ）「ファインパールＳＰ−３０００」（住友化学社
製）等の架橋ポリスチレンパウダー。 （ｈ）「フローピーズＣＬ−４０８０Ｆ」（製鉄化学社
製）等のポリエチレンパウダー。 （ｉ）「アミホープＬＬ」（味の素社製）等のラウロイ
ルリジン。A particularly preferred example of the acrylate copolymer is "POLYTRAP" (manufactured by Dow Corning). (C) A porous vinyl-based polymer obtained by polymerizing one or more vinyl-based monomers having a solubility parameter of 7 to 10 and further making the polymer porous. Specific examples include those described in JP-A-63-316715. (D) Polymethylsesquioxane having an intermediate structure between inorganic and organic in which one methyl group is bonded to a silicon atom in a network structure in which a siloxane bond extends three-dimensionally. Particularly preferred examples of polymethyl sesquioxane include “Tospearl 240”, “Tospearl 120”, and “Tospearl 13”.
0 "and" Tospearl 140 "(all manufactured by Toshiba Silicone Co., Ltd.). (E) Polymethyl methacrylate such as "Microsphere M", "Microsphere M-100", "Microsphere M-300", "Microsphere M-400" (all manufactured by Matsumoto Yushi Co., Ltd.). (F) Nylon powder such as "SP-500" (manufactured by Toray Industries, Inc.). (G) Crosslinked polystyrene powder such as "Fine Pearl SP-3000" (manufactured by Sumitomo Chemical Co., Ltd.). (H) Polyethylene powder such as "Floppys CL-4080F" (manufactured by Iron and Steel Chemical Co., Ltd.). (I) Lauroyl lysine such as "Amihope LL" (manufactured by Ajinomoto Co.).
【００１１】これら樹脂粒子の平均粒径は０．０１〜５
００μm が好ましい。The average particle size of these resin particles is 0.01 to 5
00 μm is preferred.
【００１２】本発明に使用される無機物としては、通
常、化粧品、医薬部外品、外用医薬品等に使用される金
属酸化物又は粘土鉱物等の無機粉体が好ましく、具体的
には以下の（イ）〜（ホ）に示すものが挙げられる。The inorganic substance used in the present invention is preferably an inorganic powder such as a metal oxide or a clay mineral which is usually used in cosmetics, quasi-drugs, topical medicines and the like. (A) to (e).
【００１３】（イ）酸化亜鉛： 具体例としては「微細亜鉛華」（０．２６μ）、「ＳＦ
−１５」（０．１８μ）、「Ｆｉｎｅｘ−２５」（０．
０４μ）、「Ｆｉｎｅｘ−５０」（０．０２μ）（以
上、堺化学工業社製）等が挙げられ、更に微粒子酸化亜
鉛としては特開平１−１７５９２１号公報に記載のもの
が、また薄片状酸化亜鉛としては特開平１−１７５９２
１号公報に記載のものが挙げられる。 （ロ）タルク： 具体例としては「タルクＳＷ特」、「タルクＪＡ−４６
Ｒ」（以上、浅田製粉社製）等が挙げられる。 （ハ）酸化チタン： 具体例としては「ＭＴ−５００Ｂ」、「ＭＴ−６００
Ｂ」（帝国化工社製）等が挙げられ、また微粒子酸化チ
タンとしては、特公平１−１３５１１号公報に記載のも
の（例；「タイペーク」（石原産業社製））等が挙げら
れる。 （ニ）セリサイト： 具体例としては「エイトパール３００Ｓ」（角八魚鱗箔
社製）等が挙げられる。 （ホ）シリカ： 具体例としては「シリカマイクロビードＰ−４００」、
「シリカマイクロビードＰ−１５００」（以上、触媒化
学工業社製）、「エスクォーツＭ−１」（新日鉄化学社
製）、「シルデックスＨ−３１」（旭硝子社製）等が挙
げられる。(A) Zinc oxide: Specific examples include “fine zinc white” (0.26 μm) and “SF
-15 "(0.18μ)," Finex-25 "(0.
04μ), “Finex-50” (0.02μ) (all manufactured by Sakai Chemical Industry Co., Ltd.) and the like. Further, as the fine particle zinc oxide, those described in JP-A-1-175921, and flaky oxide are used. As zinc, JP-A-1-17592
No. 1 publication. (B) Talc: Specific examples are “Talc SW” and “Talc JA-46”
R "(all manufactured by Asada Flour Milling Co., Ltd.) and the like. (C) Titanium oxide: As specific examples, “MT-500B” and “MT-600”
B "(manufactured by Teikoku Chemical Industry Co., Ltd.) and the like, and examples of the fine particle titanium oxide include those described in Japanese Patent Publication No. 1-151111 (eg," Taipek "(manufactured by Ishihara Sangyo Co., Ltd.)). (D) Sericite: Specific examples include "Eight Pearl 300S" (manufactured by Kakuhachi Fish Foil). (E) Silica: As specific examples, “Silica microbead P-400”,
"Silica microbead P-1500" (the above, manufactured by Catalyst Chemical Industry Co., Ltd.), "Esquartz M-1" (manufactured by Nippon Steel Chemical Co., Ltd.), "Sildex H-31" (manufactured by Asahi Glass Co., Ltd.) and the like.
【００１４】上記無機粉体粒子の平均粒径は０．０１〜
５００μm が好ましい。The inorganic powder particles have an average particle size of 0.01 to
500 μm is preferred.
【００１５】上記樹脂粒子表面を無機粉体粒子で被覆す
るには、各種ボールミル、オングミル、スクリーンミ
ル、ポットミル、乳鉢、アトライター、ハイブリダイザ
ー（高速気流中衝撃法を用いる混合器（「粉体工学会
誌」２４巻、Ｎｏ．９、２５〜３１頁、１９８７年）、
具体例；「ＮＨＳ−１」（奈良機械製作所製））等に予
め十分に混合した樹脂粒子及び無機粉体粒子を仕込み、
被覆処理を行う。被覆処理時の周速は２０〜１５０ｍ／
秒が好ましく、被覆処理時間は１〜３０分間が好まし
い。In order to coat the surface of the resin particles with inorganic powder particles, various types of ball mills, ong mills, screen mills, pot mills, mortars, attritors, hybridizers (mixers using a high-speed air-flow impact method ("Powder Engineering") Journal, Vol. 24, No. 9, pages 25-31, 1987),
Specific examples; "NHS-1" (manufactured by Nara Machinery Works)) and the like are charged with resin particles and inorganic powder particles sufficiently mixed in advance,
A coating process is performed. The peripheral speed during the coating process is 20 to 150 m /
Seconds are preferable, and the coating time is preferably 1 to 30 minutes.
【００１６】樹脂粒子表面は完全に被覆されることが好
ましい。なお、被覆の程度は電子顕微鏡により観察する
ことが可能であり、目的に応じた最適な被覆状態を決定
することができる。It is preferable that the surface of the resin particles is completely covered. In addition, the degree of coating can be observed with an electron microscope, and an optimum coating state according to the purpose can be determined.
【００１７】樹脂粒子と無機粉体粒子との混合比率は、
該樹脂粒子に対し無機粉体粒子が０．５〜１０００重量
％（以下、単に％という）であることが好ましく、１〜
５００％であることが更に好ましい。The mixing ratio between the resin particles and the inorganic powder particles is as follows:
It is preferable that the inorganic powder particles be 0.5 to 1000% by weight (hereinafter, simply referred to as%) based on the resin particles,
More preferably, it is 500%.
【００１８】かくして得られる樹脂粒子表面を無機物で
被覆した粒子（以下、複合粉体ということがある）の平
均粒径は０．０１〜５００μm が好ましく、０．０２〜
１００μm が更に好ましい。The average particle diameter of the particles obtained by coating the surface of the resin particles thus obtained with an inorganic substance (hereinafter sometimes referred to as composite powder) is preferably 0.01 to 500 μm, and 0.02 to 500 μm.
100 μm is more preferred.
【００１９】本発明に使用される水性媒体としては、水
並びに水とメタノール、エタノール、イソプロパノール
等の一価アルコール、グリセリンなどとの混合物が挙げ
られる。Examples of the aqueous medium used in the present invention include water and a mixture of water and a monohydric alcohol such as methanol, ethanol and isopropanol, and glycerin.
【００２０】本発明の二相型化粧料は、常法に従い、上
記複合粉体を水性媒体に分散することにより製造するこ
とができる。複合粉体の本発明化粧料への配合量は０．
１〜５０％が好ましく、１〜２５％が更に好ましい。The two-phase cosmetic of the present invention can be produced by dispersing the above composite powder in an aqueous medium according to a conventional method. The compounding amount of the composite powder in the cosmetic of the present invention is 0.1.
Preferably it is 1 to 50%, more preferably 1 to 25%.
【００２１】本発明の二相型化粧料には、上記複合粉体
に加え、他の同程度の平均粒径を有する粉体、例えばマ
イカ、タルク、セリサイト、カオリン、酸化亜鉛、ナイ
ロンパウダー、ポリメチルシルセスキオキサン等のシリ
コーンパウダー、アクリレート共重合体、ポリエチレン
パウダー、ポリエステルパウダー、ポリスチレンパウダ
ー、エポキシパウダー等を併用することができる。In the two-phase cosmetic of the present invention, in addition to the above composite powder, other powders having the same average particle size, for example, mica, talc, sericite, kaolin, zinc oxide, nylon powder, Silicone powder such as polymethylsilsesquioxane, acrylate copolymer, polyethylene powder, polyester powder, polystyrene powder, epoxy powder and the like can be used in combination.
【００２２】更に、本発明の二相型化粧料には、上記必
須成分等の他、本発明の効果を損なわない範囲で、消炎
剤、酸化防止剤、防腐剤、紫外線吸収剤、香料等の通常
化粧料に配合される成分を配合することができる。Further, the two-phase cosmetic of the present invention may further contain, in addition to the above essential components, an anti-inflammatory agent, an antioxidant, an antiseptic, an ultraviolet absorber, a fragrance, etc. within a range that does not impair the effects of the present invention. Ingredients usually blended in cosmetics can be blended.
【００２３】[0023]
【発明の効果】本発明の二相型化粧料は、皮脂によるべ
とつき、てかり、化粧くずれ等の防止効果に優れるもの
であり、しかも当該効果が比較的長期間にわたり持続す
るものである。Industrial Applicability The two-phase cosmetic of the present invention has an excellent effect of preventing stickiness, shining, and makeup loss due to sebum, and the effect lasts for a relatively long time.
【００２４】[0024]
【実施例】以下に本発明を実施例により具体的に説明す
るが、本発明はこれらに限定されるものではない。EXAMPLES The present invention will be described below in more detail with reference to examples, but the present invention is not limited to these examples.
【００２５】製造例１〜５ 表１に示す樹脂粒子と無機粉体粒子とを十分に混合した
後、表１記載の製造装置に仕込み、表１記載の製造条件
によりそれぞれ複合粉体を製造した（製造例１〜５）。Production Examples 1 to 5 After sufficiently mixing the resin particles and the inorganic powder particles shown in Table 1, they were charged into the production apparatus shown in Table 1, and composite powders were produced under the production conditions shown in Table 1. (Production Examples 1 to 5).
【００２６】[0026]
【表１】 [Table 1]
【００２７】得られた複合粉体はいずれも、その表面が
無機粉体により完全に被覆されていることが電子顕微鏡
観察により確認された。Observation with an electron microscope confirmed that the surface of each of the obtained composite powders was completely covered with the inorganic powder.
【００２８】実施例１〜５及び比較例１〜２ 表２に組成を示す二相型化粧料を常法に従い製造した。
得られた各試料について、分散状態、再分散性及び使用
感（べとつき、きしみ、化粧くずれ等）を下記基準によ
りそれぞれ評価した。なお、使用感については１０名の
専門パネリストが官能評価したものの平均値を採用し
た。評価結果を併せて表２に示す。Examples 1 to 5 and Comparative Examples 1 and 2 Two-phase cosmetics having the compositions shown in Table 2 were produced according to a conventional method.
For each of the obtained samples, the dispersion state, redispersibility, and feeling of use (stickiness, creaking, makeup loss, etc.) were evaluated according to the following criteria. In addition, about the feeling of use, the average value of what was sensory-evaluated by ten expert panelists was adopted. Table 2 also shows the evaluation results.
【００２９】（評価基準） （１）粉体の分散状態（静置状態）： ○；静置状態で粉体が液中に均一に分散もしくは沈降、 △；粉体が一部浮上、 ×；粉体が浮上する。 （２）粉体の再分散性： ○；容器を数回振とうすると粉体が均一に分散、 △；容器を数回振とうしても粉体が一部凝集、 ×；容器を数回振とうしても粉体が凝集する。 （３）べとつき感： ○；肌に塗布したときべとつかない、 △；肌に塗布したときややべとつく、 ×；肌に塗布したときべとつく。 （４）きしみ感： ○；肌に塗布したとききしまない、 △；肌に塗布したときややきしむ、 ×；肌に塗布したとききしむ。 （５）化粧くずれ： （顔に塗布後化粧をして通常の作業を半日行ったときの
感触） ○；化粧くずれなし、 △；化粧くずれやや有り、 ×；化粧くずれ有り。(Evaluation Criteria) (1) Dispersion state of powder (static state): ；: powder is uniformly dispersed or settled in liquid in the stationary state, Δ: powder partially floats, ×; The powder floats. (2) Redispersibility of powder: ○: powder is uniformly dispersed when the container is shaken several times, Δ: powder partially aggregates even when the container is shaken several times, ×: the container is shaken several times The powder agglomerates even when shaken. (3) Feeling of stickiness: ；: non-sticky when applied to skin, △: slightly sticky when applied to skin, ×: sticky when applied to skin. (4) Squeaking feeling: ○: not squeaky when applied to skin, △: squeaky slightly when applied to skin, ×: squeaky when applied to skin. (5) Makeup loss: (Feeling when makeup is applied to the face and normal work is performed for half a day) ○: No makeup loss, △: Slight makeup loss, ×: Makeup loss.
【００３０】[0030]
【表２】 [Table 2]
【００３１】表２に示すように、本発明品（実施例１〜
５）は、粉体としてジメチルポリシロキサン重合体粒子
のみを使用したもの（比較例１）及び酸化亜鉛粒子のみ
を使用したもの（比較例２）に比べ、分散状態及び使用
感においてはるかに優れたものであることがわかる。As shown in Table 2, the products of the present invention (Examples 1 to 3)
5) is much better in dispersion state and feeling in use than those using only dimethylpolysiloxane polymer particles as the powder (Comparative Example 1) and those using only zinc oxide particles (Comparative Example 2). It turns out to be something.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/00 - 7/50 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/ 00-7/50
Claims (1)
子の表面を、酸化亜鉛、タルク、酸化チタン、セリサイ
ト及びシリカから選ばれる平均粒径０．０１〜５００μ
mの無機物により被覆してなる粉体、及び水性媒体を含
有することを特徴とする二相型化粧料。1. The surface of a resin particle having an average particle size of 0.01 to 500 μm is coated with an average particle size of 0.01 to 500 μm selected from zinc oxide, talc, titanium oxide, sericite and silica.
m. A two-phase cosmetic comprising a powder coated with an inorganic substance and an aqueous medium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18819792A JP3273573B2 (en) | 1992-07-15 | 1992-07-15 | Two-phase cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18819792A JP3273573B2 (en) | 1992-07-15 | 1992-07-15 | Two-phase cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0632725A JPH0632725A (en) | 1994-02-08 |
| JP3273573B2 true JP3273573B2 (en) | 2002-04-08 |
Family
ID=16219474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18819792A Expired - Fee Related JP3273573B2 (en) | 1992-07-15 | 1992-07-15 | Two-phase cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3273573B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08259419A (en) * | 1995-03-17 | 1996-10-08 | Shiseido Co Ltd | Cosmetic |
| JP4550335B2 (en) * | 2001-09-27 | 2010-09-22 | 花王株式会社 | Modified powder and cosmetics |
| DE10235422A1 (en) * | 2002-08-02 | 2004-02-12 | Beiersdorf Ag | Two-phase cosmetic or dermatological composition comprises an aqueous phase containing an alcohol and one or more alkali(ne earth) metal salts and a lipid phase with a defined interfacial tension |
| JP2006257075A (en) * | 2005-02-17 | 2006-09-28 | Shiseido Co Ltd | Silicone elastomer composite powder, method for producing silicone elastomer composite powder and cosmetic |
| JP6210680B2 (en) * | 2009-08-04 | 2017-10-11 | ロレアル | Composite pigment and preparation method thereof |
| KR20210151877A (en) | 2019-04-15 | 2021-12-14 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Silica-coated particles and method for producing the same |
-
1992
- 1992-07-15 JP JP18819792A patent/JP3273573B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0632725A (en) | 1994-02-08 |
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