JP2021014526A - Steam distillation method using high-humidity steam - Google Patents

Steam distillation method using high-humidity steam Download PDF

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JP2021014526A
JP2021014526A JP2019129902A JP2019129902A JP2021014526A JP 2021014526 A JP2021014526 A JP 2021014526A JP 2019129902 A JP2019129902 A JP 2019129902A JP 2019129902 A JP2019129902 A JP 2019129902A JP 2021014526 A JP2021014526 A JP 2021014526A
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steam
steam distillation
flavor
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kettle
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博文 荻田
Hirofumi Ogita
博文 荻田
久典 釼持
Hisanori Kenmochi
久典 釼持
晃典 長田
Akinori Osada
晃典 長田
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Ogawa and Co Ltd
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  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
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Abstract

To provide a steam distillation method that prevents sticking of a heating odor and yields a flavor enhancing component having an original flavor of a natural material and a strong titer.SOLUTION: The present invention provides a method for separating or purifying a useful component from a natural material by steam distillation, the method being characterized by using a high-humidity steam.SELECTED DRAWING: None

Description

本発明は、天然素材から有用成分を分離又は精製する水蒸気蒸留において、水蒸気として多湿水蒸気を用いることを特徴とする方法であり、特に、当該方法によって天然素材から異臭が付着していない香味増強成分を得る方法、並びに当該香味増強成分からなる香味増強剤に関する。 The present invention is a method characterized by using high-humidity steam as steam in steam distillation for separating or purifying useful components from a natural material, and in particular, a flavor-enhancing component to which an offensive odor is not attached to the natural material by the method. The present invention relates to a method for obtaining the above, and a flavor enhancer comprising the flavor enhancer.

水蒸気蒸留は、天然素材から有用成分を分離・精製するとき用いられる方法であり、古典的には、スパイスやハーブ等の天然素材から精油やハーブ水などを得るために用いられてきている。加熱によって発生する高温な水蒸気(気体)を加熱源として原料に当て、必要とする高沸点物質の沸点を下げて留出させる方法である。実際の沸点よりも低温で留出分離が可能となり、高温による分解や変質を少なくすることができるので、植物から精油などを得る際に頻繁に利用される蒸留法である。 Steam distillation is a method used to separate and purify useful components from natural materials, and has been classically used to obtain essential oils, herbal water, etc. from natural materials such as spices and herbs. This is a method in which high-temperature steam (gas) generated by heating is applied to a raw material as a heating source to lower the boiling point of a required high boiling point substance and distill it. Distillation separation is possible at a temperature lower than the actual boiling point, and decomposition and alteration due to high temperature can be reduced. Therefore, this distillation method is frequently used when obtaining essential oils from plants.

しかし、古典的な水蒸気蒸留では、水を沸騰させて発生させた水蒸気を用いていたため、水蒸気蒸留に時間がかかり、水蒸気蒸留に供される天然素材あるいは得られる水層部や精油の劣化を生じさせることがあった。
そのため、現在では使用する水蒸気として、ボイラーで発生させた加圧高温の乾燥した水蒸気を用いることが一般的となっている。
しかしながら、水蒸気蒸留を短時間で終了させることができるが、高温で加熱されることによる加熱臭が付着し、天然素材本来の香味を強調する香味増強成分を得ることが難しいという問題点を有していた。
However, in classical steam distillation, since steam generated by boiling water is used, steam distillation takes time, and the natural materials used for steam distillation or the obtained aqueous layer and essential oil are deteriorated. I had something to do.
Therefore, at present, it is common to use pressurized, high-temperature, dried steam generated in a boiler as the steam to be used.
However, although steam distillation can be completed in a short time, there is a problem that it is difficult to obtain a flavor-enhancing component that emphasizes the original flavor of the natural material due to the adhesion of a heated odor due to heating at a high temperature. Was there.

ボイラーで発生させた加圧高温の乾燥水蒸気を使用した場合でも、水蒸気蒸留を減圧下で行えば、加熱臭の発生を防ぐことができることは知られているが、減圧水蒸気蒸留の場合、得られた香味増強成分からなる香味増強剤の力価が弱いという指摘がされていた。
従って、水蒸気蒸留によって得られる香味増強成分からなる香味増強剤に、蒸れ臭や焦げ臭などの加熱臭が付着されない方法が望まれていた。
It is known that even when pressurized high-temperature dry steam generated in a boiler is used, it is possible to prevent the generation of a heated odor by performing steam distillation under reduced pressure, but it is obtained in the case of reduced pressure steam distillation. It has been pointed out that the potency of a flavor enhancer consisting of a flavor enhancer is weak.
Therefore, there has been a demand for a method in which a heating odor such as a stuffy odor or a burning odor is not attached to a flavor enhancing agent composed of a flavor enhancing component obtained by steam distillation.

そのため、蒸れ臭や焦げ臭などの加熱臭を付着させないことを目的とした水蒸気蒸留法の改良方法がこれまで検討され、報告されている。
例えば、茶類を水蒸気蒸留して得られる留出液を茶葉と接触させ、該留出液中の加熱蒸留臭を除去することを特徴とする茶類フレーバーの製造方法(特許文献1)が提案されている。
また、インスタント紅茶組成物を得るために、減圧下で水蒸気蒸留を行う製造方法(特許文献2)が提案されている。
Therefore, an improved method of the steam distillation method for the purpose of preventing the attachment of a heated odor such as a stuffy odor or a burnt odor has been studied and reported.
For example, a method for producing a tea flavor (Patent Document 1) has been proposed, which comprises contacting a distillate obtained by steam distillation of tea with tea leaves to remove the heat-distilled odor in the distillate. Has been done.
Further, in order to obtain an instant black tea composition, a production method (Patent Document 2) in which steam distillation is performed under reduced pressure has been proposed.

しかしながら、水蒸気蒸留を行う際に発生する特有の加熱臭を十分に除去することは容易ではなく、上記方法においても、望ましい結果を得ることは困難であった。
従って、水蒸気蒸留において蒸れ臭や焦げ臭などの加熱臭を発生させず、且つ、強い力価を有する有効成分、特に香味増強成分を得るための方法が求められていた。
However, it is not easy to sufficiently remove the peculiar heated odor generated when steam distillation is performed, and it is difficult to obtain a desired result even with the above method.
Therefore, there has been a demand for a method for obtaining an active ingredient, particularly a flavor-enhancing ingredient, which does not generate a heated odor such as a stuffy odor or a burnt odor in steam distillation and has a strong titer.

特開平8−116882公報Japanese Unexamined Patent Publication No. 8-116882 特公昭48−18834号公報Tokukousho 48-18834

ボイラーで発生させた加圧高温水蒸気を用いる水蒸気蒸留であっても、水蒸気蒸留を行う際に蒸れ臭や焦げ臭などの加熱臭が付着せず、原料である天然素材の本来の香味を有し、且つ、強い力価を有する有効成分、特に香味増強成分を得ることができる水蒸気蒸留法、並びに当該香味増強成分からなる香味増強剤を提供することである。 Even in steam distillation using pressurized high-temperature steam generated in a boiler, heated odors such as stuffy odor and burnt odor do not adhere when steam distillation is performed, and it has the original flavor of the natural material that is the raw material. In addition, it is an object of the present invention to provide an active ingredient having a strong titer, particularly a steam distillation method capable of obtaining a flavor enhancing ingredient, and a flavor enhancing agent composed of the flavor enhancing ingredient.

上記課題を解決すべく、本発明者らは鋭意検討した結果、ボイラーで発生させた加圧高温の乾燥水蒸気を、水と接触させて発生させた、圧力が1〜1.1気圧、温度が95〜105℃の湿気を含んだ多湿水蒸気を天然素材に適用することで課題を解決できることを見出し、本発明を完成させた。
すなわち本発明は次の構成によるものである。
As a result of diligent studies to solve the above problems, the present inventors have generated pressurized high-temperature dry steam generated in a boiler in contact with water, and the pressure is 1 to 1.1 atm and the temperature is high. We have found that the problem can be solved by applying high-humidity steam containing moisture at 95 to 105 ° C. to a natural material, and completed the present invention.
That is, the present invention has the following configuration.

本発明の多湿水蒸気による水蒸気蒸留法によって、天然素材から得られる有用成分、特に香味増強成分は、原料である天然素材の本来の香味を有し、且つ、当該香味増強成分からなる香味増強剤は強い力価を有する。
本発明において、熱源のボイラーで発生させた加圧高温の乾燥水蒸気を使用する工程はそのまま残し、乾燥水蒸気の多湿化(湿潤化)工程を新たに追加するだけであり、水蒸気蒸留プロセスや設備全体を大きく変える技術ではない。従って、設備やプロセス変更に伴うコスト増を極力抑えることができ、経済的に有利である。
The useful component obtained from the natural material by the steam distillation method using the humid steam of the present invention, particularly the flavor enhancing component, has the original flavor of the natural material as the raw material, and the flavor enhancing agent composed of the flavor enhancing component is Has a strong potency.
In the present invention, the step of using the pressurized high-temperature dry steam generated in the boiler of the heat source is left as it is, and only a new step of humidifying (wetting) the dry steam is added, and the steam distillation process and the entire equipment are provided. It is not a technology that changes the situation significantly. Therefore, the cost increase due to equipment and process changes can be suppressed as much as possible, which is economically advantageous.

〔A〕多湿水蒸気による水蒸気蒸留法
本発明でいう多湿水蒸気は、ボイラーで発生させた加圧高温の乾燥した水蒸気を、一度水に通し、そこから発生させた、圧力が1〜1.1気圧、温度が95〜105℃の湿気を含んだ水蒸気をいう。
具体的には、ボイラーで発生させた加圧高温乾燥水蒸気を、水蒸気蒸留に付される天然素材と接触させる前に水の層と接触させたときの水の沸騰による二次的に発生させた水蒸気である。
なお、上記の多湿水蒸気を発生させる際に、多孔板を通過させることで、より一定した多湿水蒸気を使用することができる。
[A] Steam distillation method using high-humidity steam The high-humidity steam referred to in the present invention is obtained by passing pressurized high-temperature dried steam generated in a boiler through water once and then generating a pressure of 1 to 1.1 atm. , Refers to water vapor containing moisture having a temperature of 95 to 105 ° C.
Specifically, the pressurized high-temperature dried steam generated in the boiler was secondarily generated by boiling water when it was brought into contact with a layer of water before it was brought into contact with a natural material to be subjected to steam distillation. It is steam.
When the above-mentioned high-humidity steam is generated, a more constant high-humidity steam can be used by passing it through a perforated plate.

こうした多湿水蒸気は、水蒸気蒸留装置の底部に水層を設け、そこにボイラー蒸気を吹き込むことで得られるが、市販の装置を用いて簡便に得ることもできる。例えば、業務用蒸し装置のスチームチェンヂャーは、高温高圧乾燥蒸気を低圧多湿蒸気に変換する湿式蒸気減圧装置であり、かまぼこ等の「蒸しもの」食品の製造や食品の殺菌に使用されている装置である。 Such humid steam can be obtained by providing an aqueous layer at the bottom of the steam distillation apparatus and blowing boiler steam into the aqueous layer, but it can also be easily obtained by using a commercially available apparatus. For example, a steam changer for a commercial steaming device is a wet steam decompression device that converts high-temperature, high-pressure dry steam into low-pressure, high-humidity steam, and is used for manufacturing "steamed foods" such as kamaboko and sterilizing foods. is there.

本発明でいう水蒸気蒸留は、香料の製造において周知・慣用技術であり(例えば、特許庁公報 周知・慣用技術集(香料)第I部 香料一般 平成11年1月29日発行 第63頁参照)、水を混合しない物質に水蒸気を通じて蒸留すると、その物質の蒸気の分圧と水蒸気の分圧との和が大気圧と等しくなる温度で沸騰することを利用した分離方法である。
すなわち、香料の原料である植物体(花、葉、茎、根又は全草)に水蒸気を通気し、水蒸気に伴われて留出してくる香気成分を水蒸気とともに凝縮させる方法である。
The steam distillation referred to in the present invention is a well-known and commonly used technique in the production of fragrances (for example, refer to the Patent Office Gazette, well-known and commonly used technique collection (fragrance), Part I, fragrance general, p. 63, published on January 29, 1999). This is a separation method that utilizes the fact that when steam is distilled through a substance that does not mix water, the sum of the partial pressure of the steam and the partial pressure of the steam of that substance boils at a temperature equal to the atmospheric pressure.
That is, it is a method of aerating water vapor through a plant (flower, leaf, stem, root or whole plant) which is a raw material of a fragrance, and condensing the aroma component distilled out with the water vapor together with the water vapor.

本発明における水蒸気蒸留法は、加圧水蒸気蒸留、常圧水蒸気蒸留、減圧水蒸気蒸留のいずれの蒸留方法も採用できるが、その中でも常圧水蒸気蒸留が最も望ましい。
また、本発明で使用する水蒸気蒸留装置は、蒸留釜(原材料を仕込んだ仕込み部に釜底部から水蒸気を吹き込み、釜上部から留出させる構造)と釜に接続された冷却器(留出蒸
気を冷却することにより揮発性香気成分を含有する留出液を捕集する)を備えていれば、構造や材質などにかかわらず広く使用することができる。
As the steam distillation method in the present invention, any of pressure steam distillation, atmospheric pressure steam distillation, and reduced pressure steam distillation can be adopted, but atmospheric steam distillation is the most preferable.
Further, the steam distillation apparatus used in the present invention has a distillation kettle (a structure in which steam is blown from the bottom of the kettle into a preparation section in which raw materials are charged and distilled from the top of the kettle) and a cooler connected to the kettle (distilled steam). If it is equipped with a distillate containing a volatile aroma component by cooling), it can be widely used regardless of its structure or material.

本発明においては、水蒸気蒸留は常圧すなわち1気圧で行うときに最もその効果を発揮することができる。水蒸気の供給流速は限定されるものではなく、通常は空間速度(SV)50〜1600h-1の範囲で行われるが、SV100〜1000h-1の範囲で行うのがより好ましく、また、留出量を測定し、分画できる構造の蒸留装置を用いることが好ましい。 In the present invention, steam distillation can exert its effect most when it is carried out at normal pressure, that is, at 1 atm. Feed flow rate of steam is not limited, but usually is carried out in the range of the space velocity (SV) 50~1600h -1, more preferably in a range of SV100~1000h -1, also, distillate volume It is preferable to use a distillation apparatus having a structure capable of measuring and fractionating.

〔B〕天然素材
本発明で用いられる天然素材は、一般に、動植物資源であり、特に限定されるものではないが、具体的には、以下の通り例示することができる。
アイスランドモス、アカヤジオウ、アケビ、アサ、アサフェチダ、アジアンタム、アジョワン、アズキ、アスパラサスリネアリス、アップルミント、アーティチョーク、アニス、アボカド、アマチャ、アマチャズル、アミガサユリ、アミリス、アーモンド、アリタソウ、アルカンナ、アルテミシア、アルニカ、アルファルファ、アロエ、アンゴスツラ、アンゴラウィード、アンズ、アンズタケ、アンゼリカ、アンバー、アンバーグリス、アンブレット、イカ、イカリソウ、イグサ、イースト、イタドリ、イチゴ、イチジク、イチョウ、イノコヅチ、イランイラン、イワオウギ、インペラトリア、インモルテル、
[B] Natural Material The natural material used in the present invention is generally an animal and plant resource, and is not particularly limited, but can be specifically exemplified as follows.
Iceland Moss, Akayaziou, Akevi, Asa, Asafetida, Asian Tam, Ajowan, Azuki, Asparasas Line Alice, Apple Mint, Artichoke, Anise, Avocado, Amacha, Jiaogulan, Amigasayuri, Amiris, Almond, Aritasou, Arcanna, Artemisia Alfarfa, Aloe, Angostura, Angolaweed, Apricot, Anisetake, Angelica, Amber, Ambergris, Ambret, Squid, Ikarisou, Igusa, East, Itadori, Strawberry, Iran, Ginkgo, Inokozuchi, Iran Iran, Iwaougi, Imperatoria ,

ウィンターグリーン、ウォータークレス、ウコギ、ウコン、ウスバサイシン、ウッドラフ、ウニ、ウメ、ウーロンチャ、エゴマ、エノキダケ、エビ、エビスグサ、エリゲロン、エルダー、エレウテロコック、エレカンペン、エレミ、エンゴサク、エンジュ、エンダイブ、欧州アザミ、オウレン、オオバコ、オカゼリ、オキアミ、オーク、オークモス、オケラ、オスマンサス、オポポナックス、オミナエシ、オモダカ、オランダセンニチ、オリガナム、オリス、オリバナム、オリーブ、オールスパイス、オレンジ、オレンジフラワー、カイ、カイニンソウ、カカオ、カキ、カサイ、カシューナッツ、カスカラ、カスカリラ、カストリウム、カタクリ、カツオブシ、カッシー、カッシャフィスチュラ、カテキュ、 Winter Green, Water Cress, Ukogi, Ukon, Usbasaishin, Woodruff, Sea Urchin, Ume, Uroncha, Egoma, Enokitake, Shrimp, Ebisugusa, Eligeron, Elder, Eleuterocock, Elecampen, Elemi, Engosaku, Enju, Endive, European Zami, Ouren , Obako, Okazeri, Krill, Oak, Oak Moss, Okera, Ottomansus, Opoponax, Ominaeshi, Omodaka, Paracress, Olganum, Olis, Olivernum, Olive, Allspice, Orange, Orange Flower, Kai, Kaininsou, Cacao, Kaki, Kasai , Cashew nuts, Cascara, Cascarilla, Castorium, Katakuri, Krill, Cassie, Cascha fistula, Catecuse,

カニ、カーネーション、カノコソウ、カモミル、カヤプテ、カラシ、カラスウリ、カラスビシャク、ガラナ、カラムス、ガランガ、カーラント、カリッサ、カリン、カルダモン、ガルバナム、カレー、カワミドリ、カンゾウ、ガンビア、カンラン、キウィーフルーツ、キカイガラタケ、キキョウ、キク、キクラゲ、キササゲ、ギシギシ、キダチアロエ、キナ、キハダ、キバナオウギ、ギボウシ、ギムネマシルベスタ、キャットニップ、キャラウェイ、キャロップ、キュウリ、キラヤ、キンミズヒキ、グァバ、グァヤク、クコ、クサスギカズラ、クサボケ、クズ、クスノキ、クスノハガシワ、グーズベリー、クチナシ、クベバ、クマコケモモ、グミ、クミン、グラウンドアイビー、クララ、クラリセージ、クランベリー、クリ、クルミ、クリーム、グレインオブパラダイス、クレタディタニー、グレープフルーツ、クローバー、クローブ、クロモジ、クロレラ、クワ、 Crab, carnation, kanokosou, camo mill, kayapte, mustard, crow squirrel, crow squirrel, galana, columnus, galanga, carrant, carissa, karin, cardamom, galvanum, curry, kawamidori, kanzo, gambia, canlan, kiwi fruit, kikaigaratake , Kikurage, Kisage, Gishigishi, Kidachi Aloe, Kina, Kihada, Kibana Ougi, Giboshi, Gymnema Sylvestre, Catnip, Caraway, Carop, Cucumber, Kiraya, Kinmizuhiki, Guaba, Guayaku, Kuco, Kusasugi Kazura , Kuchinashi, Kubeba, Kuma Kokemomo, Gumi, Cumin, Ground Ivy, Clara, Clarisage, Cranberry, Chrysanthemum, Walnut, Cream, Grain of Paradise, Crete Ditany, Grapefruit, Clover, Clove, Chromoji, Chlorella, Kwa,

クワッシャ、ケイパー、ゲットウ、ケード、ケブラコ、ゲルマンダー、ケンチュール、ケンポナシ、ゲンノショウコ、コウジ、コウダケ、コウチャ、コウホネ、コカ、コガネバナ、コクトウ、コクルイ、ココナッツ、ゴシュユ、コショウ、コスタス、コストマリー、コパイパ、コーヒー、コブシ、ゴボウ、ゴマ、コーラ、コリアンダー、コルツフート、ゴールデンロッド、コロンボ、コンサイ、コンズランゴ、コンフリー、サイプレス、魚、サクラ、サクランボ、ザクロ、サケカス、ササ、ササクサ、サーチ、サッサフラス、サフラン、サポジラ、サボテン、サラシナショウマ、サルサパリラ、サルシファイ、サルノコシカケ、サンザシ、サンシュユ、サンショウ、サンタハーブ、サンダラック、サンダルウッド、サンダルレッド、シイタケ、ジェネ、シダー、シトラス、シトロネラ、 Kwasha, Caper, Getto, Cade, Kebraco, Germander, Kentur, Kemponashi, Gennoshoko, Koji, Kodake, Kocha, Kouhone, Coca, Koganebana, Kokuto, Kokurui, Coconut, Goshuyu, Kosho, Costas, Costmary, Kopaipa , Pepper, Gobo, Sesame, Coke, Coriander, Coltshoot, Golden Rod, Colombo, Consai, Conslango, Comfrey, Cypress, Fish, Sakura, Cherry, Pomegranate, Sakekas, Sasa, Sasakusa, Search, Sassafras, Safran, Saposira, Cactus , Actaea simplex, sarsaparilla, salsify, coriander, sassafras, cornel, cornel, santa herb, sandalak, sandalwood, sandal red, shiitake, gene, cedar, citrus, citronella,

シヌス、シベット、シマルーバ、シメジ、シャクヤク、ジャスミン、ジャノヒゲ、ジャボランジ、シャロット、シュクシャ、ジュニパーベリー、ショウガ、ショウユ、ショウユカス、ジョウリュウシュ、ショウロ、シロタモギタケ、ジンセン、シンナモン、酢、スイカ、スイセン、スギ、スターアニス、スターフルーツ、スチラックス、スッポン、スッポンタケ、ズドラベッツ、スネークルート、スパイクナード、スプルース、スペアミント、スベリヒユ、スローベリー、セイボリー、セキショウ、セージ、ゼドアリー、セネガ、ゼラニウム、セロリー、センキュウ、センタウリア、センゲン、セントジョーンズウォルト、センナ、ソース、ダイオウ、ダイズ、タイム、タケノコ、タコ、タデ、ダバナ、タマゴ、タマゴタケ、タマネギ、タマリンド、ダミアナ、タモギタケ、 Sinus, Civet, Simaluba, Shimeji, Shakuyaku, Jasmine, Janohige, Jaborangi, Sharot, Sukusha, Juniper berry, Ginger, Shoyu, Shoyucas, Joryushu, Shouro, Shirotamogitake, Jinsen, Shinnamon, Vinegar, Watermelon, Suisen, Sugi Star anise, star fruit, stilax, sponge, sponge mushroom, zudrabets, snake root, spikenard, spruce, spearmint, sberghiyu, slowberry, savory, sekisho, sage, zedary, senega, geranium, celery, senkyu, centauria, sengen, cent Jones Walt, Senna, Sauce, Daiou, Soybean, Thyme, Takenoko, Octopus, Tade, Davana, Tamago, Tamagotake, Onion, Tamalindo, Damiana, Tamogitake,

タラゴン、タラノキ、タンジー、タンジェリン、タンポポ、チェリモラ、チェリーローレル、チェリーワイルド、チガヤ、チコリ、チーズ、チチタケ、チャイブ、チャービル、チャンパカ、チュベローズ、チョウセンゴミシ、チラータ、ツクシ、ツケモノ、ツタ、ツバキ、ツユクサ、ツリガネニンジン、ツルドクダミ、ディアタング、ティスル、ディタニー、ディル、デーツ、テンダイウヤク、テンマ、トウガラシ、トウキ、ドウショクブツタンパクシツ、ドウショクブツユ、トウミツ、トウモロコシ、ドクダミ、トチュウ、ドッググラス、トマト、ドラゴンブラッド、ドリアン、トリュフ、トルーバルサム、トンカ、ナギナタコウジュ、ナシ、ナスターシャム、ナッツ、ナットウ、ナツメ、ナツメグ、 Tarragon, Taranoki, Tanji, Tangerine, Dandelion, Cherimora, Cherry Laurel, Cherry Wild, Chigaya, Chicoli, Cheese, Chichitake, Chives, Chervil, Champaka, Tuberose, Chosen Gomishi, Chirata, Tsukushi, Tsukemono, Tsuta, Tsubaki, Tsuyukusa, Tsurigane , Tuld Kudami, Diatang, Tisle, Ditany, Dill, Dates, Tendai Uyaku, Tenma, Togarashi, Touki, Doshokubutsu Protein Shitsu, Doshokubutsuyu, Toumitsu, Corn, Dokudami, Tochu, Doggrass, Tomato, Dragon Blood, Dorian, Truffle Balsam, Tonka, Naginatakouju, Pear, Nastarsham, Nuts, Natto, Natsume, Nutmeg,

ナデシコ、ナメコ、ナラタケ、ニアウリ、ニュウサンキンバイヨウエキ、ニンジン、シンニク、ネズミモチ、ネットル、ネムノキ、ノットグラス、バイオレット、パイナップル、ハイビスカス、麦芽、ハコベ、バジル、ハス、ハスカップ、パースカップ、パセリ、バター、バターオイル、バターミルク、バーチ、ハチミツ、パチュリー、ハッカ、バックビーン、ハッコウシュ、ハッコウニュウ、ハッコウミエキ、パッションフルーツ、ハツタケ、バッファローベリー、ハトムギ、ハナスゲ、バナナ、バニラ、ハネーサックル、パパイヤ、バーベリー、ハマゴウ、ハマスゲ、ハマナス、ハマボウフウ、ハマメリス、バラ、パルマローザ、パンダナ、バンレイシ、ヒキオコシ、ヒシ、ピスタチオ、ヒソップ、 Nadeshiko, Nameko, Naratake, Niauri, Nyusankinbaiyoueki, Carrot, Shinnik, Mouse Mochi, Nettle, Nemunoki, Knotgrass, Violet, Pineapple, Hibiscus, Malt, Hakobe, Basil, Has, Hascup, Perthcup, Parsley, Butter, Butter Oil, buttermilk, birch, honey, patchouli, honeysuckle, back bean, honeysuckle, honeysuckle, honeysuckle, passion fruit, honeysuckle, buffalo berry, honeysuckle, honeysuckle, banana, vanilla, honeysuckle, papaya, barberry, honeysuckle, honeysuckle , Hamabofu, Hamamelis, Rose, Palmarosa, Pandana, Buttermilk, Hikiokoshi, Hishi, Pistachio, Hisop,

ヒッコリー、ピーナッツ、ヒノキ、ヒバ、ピプシシワ、ヒメハギ、ヒヤシンス、ヒラタケ、ビワ、ビンロウ、フェイジョア、フェネグリーク、フェンネル、フジバカマ、フジモドキ、フスマ、フーゼルユ、プチグレイン、ブチュ、ブドウ、ブドウサケカス、フトモモ、ブナ、ブナハリタケ、ブラックキャラウェイ、ブラックベリー、プラム、ブリオニア、プリックリーアッシュ、プリムローズ、プルネラ、ブルーベリー、ブレッドフルーツ、ヘイ、ベイ、ヘーゼルナッツ、ベチバー、ベーテル、ベニバナ、ペニーロイヤル、ペパーミント、ヘビ、ペピーノ、ペプトン、ベルガモット、ベルガモットミント、ペルーバルサム、ベルベナ、ベロニカ、ベンゾイン、ボアドローズ、ホアハウンド、ホウ、ホウキタケ、ホウショウ、ボウフウ、ホエイ、ホオノキ、ホースミント、ホースラディッシュ、ボタン、ホップ、ポピー、ポプラ、ポポー、ホホバ、ホヤ、ボルドー、 Hickory, peanuts, hinoki, hiba, pipshi wrinkles, himehagi, hyacinth, hiratake, biwa, binrou, feijoa, phenegreak, fennel, fujibakama, fujimodoki, fusuma, fuselyu, petit grain, butchu, grapes, grape salmon, futomomo, beech Black Caraway, Blackberry, Plum, Brionia, Prickly Ash, Primrose, Prunella, Blueberry, Breadfruit, Hay, Bay, Hazelnut, Vetiba, Bethel, Benibana, Pennyroyal, Peppermint, Snake, Pepino, Peptone, Bergamotte, Bergamot Mint, Peruvian Sam, Belbena, Veronica, Benzoin, Boad Rose, Hoa Hound, Hou, Houkitake, Hosho, Bowfu, Whey, Hoonoki, Horsemint, Horseradish, Button, Hop, Poppy, Poplar, Popo, Hohoba, Hoya, Bordeaux,

ボロニア、マイタケ、マグウォルト、マシュマロー、マジョラム、マスティック、マソイ、マタタビ、マチコ、マツ、マツオウジ、マッシュルーム、マツタケ、マツブサ、マツホド、マテチャ、マメ、マリーゴールド、マルバダイオウ、マルメロ、マレイン、マロー、マンゴー、マンゴスチン、ミカン、ミシマサイコ、ミソ、ミツマタ、ミツロウ、ミート、ミモザ、ミョウガ、ミルク、ミルテ、ミルフォイル、ミルラ、ミロバラン、ムギチャ、ムスク、ムラサキ、メスキート、メドウスィート、メハジキ、メープル、メリッサ、メリロット、メロン、モウセンゴケ、モニリアバイヨウエキ、モミノキ、モモ、モロヘイヤ、ヤクチ、ヤマモモ、ユーカリ、ユキノシタ、ユズ、ユッカ、ユリ、ヨウサイ、ヨロイグサ、ライオンズフート、ライチ、ライフエバーラスティングフラワー、ライム、 Boronia, Maitake, Magwalt, Marshmallow, Majorum, Mastic, Masoi, Matatabi, Machiko, Matsu, Matsuouji, Mushroom, Matsutake, Matsubusa, Matsuhodo, Matecha, Mame, Marigold, Marubadaiou, Marumero, Marein, Mallow, Mango Mangosteen, Mikan, Mishima Psycho, Miso, Mitsumata, Mitsurou, Meat, Mimosa, Myoga, Milk, Mirute, Milfoil, Mirula, Mirobaran, Mugicha, Musk, Murasaki, Mesquito, Medous Sweet, Mehajiki, Maple, Melissa, Melissa, Melon, Melon , Monilia bayoueki, mominoki, peach, moroheiya, yakuchi, yamamomo, eucalyptus, yukinoshita, yuzu, yukka, lily, yosai, yoroigusa, lions foot, lychee, life everlasting flower, lime,

ライラック、ラカンカ、ラカンショウ、ラズベリー、ラタニア、ラディッシュ、ラブダナ
ム、ラベンダー、ラングウォルト、ラングモス、ランブータン、リキュール、リーク、リツェア、リナロエ、リュウガン、リョウフンソウ、リョクチャ、リンゴ、リンデン、リンドウ、ルー、ルリジサ、レセダ、レモン、レモングラス、レンギョウ、レンゲ、レンブ、ローズマリー、ロベージ、ローレル、ロンゴザ、ワサビ、ワタフジウツギ、ワームウッド、ワームシード、ワラビ、ワレモコウ。
Lilac, Luo Han Guo, Lacan Show, Raspberry, Latania, Radish, Rabdanum, Lavender, Langwalt, Langmos, Rambutan, Liqueur, Leak, Rizea, Linaroe, Longan, Ryofunsou, Ryokucha, Apple, Linden, Lindou, Lou, Borage, , Lemon, Lemongrass, Longan, Ranger, Apple, Rosemary, Lovage, Laurel, Longoza, Wasabi, Watafuji Utsugi, Wormwood, Wormseed, Warabi, Waremokou.

〔C〕香味増強剤
本発明でいう香味増強剤は、上記の天然素材を多湿水蒸気による水蒸気蒸留で留出する水層画分と油層画分、もしくはそれらの各々に含まれる香味増強に寄与する種々の有効成分からなる。
香味増強剤は、飲食品の香味または香粧品の香り(両者を纏めて単に「香味」という)の増強用に幅広く用いることができる。
[C] Flavor enhancer The flavor enhancer referred to in the present invention contributes to the flavor enhancement contained in the aqueous layer fraction and the oil layer fraction obtained by steam distillation of the above-mentioned natural material with high-humidity steam, or each of them. It consists of various active ingredients.
Flavor enhancers can be widely used for enhancing the flavor of foods and drinks or the aroma of cosmetics (collectively referred to as "flavors").

本発明の香味増強剤には、既存の香料を添加して香料組成物として使用することも有用である。そのような公知香料としては、例えば、「特許庁公報 周知慣用技術集(香料)
第II部 食品用香料」(平成12(2000)年1月14日発行、日本国特許庁)や、「特許庁公報 周知慣用技術集(香料) 第III部 香粧品用香料」(平成13(2001)年6月15日発行、日本国特許庁)等に記載された香料(精油、エッセンス、コンクリート、アブソリュート、エキストラクト、オレオレジン、レジノイド、回収フレーバー、炭酸ガス抽出精油、単離香料、合成香料などが挙げられる。
It is also useful to add an existing fragrance to the flavor enhancer of the present invention and use it as a fragrance composition. Examples of such known fragrances include "Patent Office Gazette Well-known Common Techniques (Fragrances)".
Part II Food Fragrances (issued January 14, 2000, Japan Patent Office) and Patent Agency Gazette Well-known Common Techniques (Fragrances) Part III Cosmetic Fragrances (2001 (2001) Perfume (essential oil, essence, concrete, absolute, extract, oleoledin, resinoid, recovered flavor, carbon dioxide extracted essential oil, isolated fragrance, synthetic) described in June 15, 2001 (issued on June 15, 2001, Japan Patent Office), etc. Examples include fragrances.

また、香料組成物中の本発明で得られた香味増強剤の含有量は、通常は0.001〜100.0質量%、好ましくは0.005〜95.0質量%、より好ましくは0.01〜90.0質量%、特に好ましくは0.05〜80.0質量%、最も好ましくは0.1〜70.0質量%で用いられる。 The content of the flavor enhancer obtained in the present invention in the flavor composition is usually 0.001 to 100.0% by mass, preferably 0.005 to 95.0% by mass, and more preferably 0. It is used in an amount of 01 to 90.0% by mass, particularly preferably 0.05 to 80.0% by mass, and most preferably 0.1 to 70.0% by mass.

上記の香味増強剤や香料組成物は、そのままあるいはエタノール等の溶媒で希釈したものを飲食品や香粧品に添加して賦香することができるが、界面活性剤ともに乳化した乳化香料として使用する態様、さらには賦形剤(加工デンプン、サイクロデキストン等)と混合した後、乾燥(噴霧乾燥、凍結乾燥等)することにより粉末香料として使用する態様も好適である。 The above-mentioned flavor enhancer and flavor composition can be used as they are or diluted with a solvent such as ethanol and added to foods and drinks and cosmetics to perfume, but they are used as emulsified flavors together with a surfactant. It is also preferable to mix it with an excipient (processed starch, cyclodextone, etc.) and then dry it (spray drying, freeze drying, etc.) to use it as a powder flavor.

本発明の香味増強剤は、果汁飲料類、果実酒類、乳飲料類、炭酸飲料類のごとき飲料類;アイスクリーム類、シャーベット類、アイスキャンディー類のごとき冷菓類;ヨーグルト類、チーズ類のごとき発酵乳製品;和洋菓子類、焼菓子類、ジャム類、チューインガム類、パン類、コーヒー、ココア、紅茶、お茶、タバコのごとき嗜好品類;プリン類、ゼリー類、ババロア類、ムース類のごときデザート類;和風スープ類、洋風スープ類のごときスープ類;風味調味料;各種インスタント飲料乃至食品類、各種スナック食品類などに添加することにより、その優れた香気香味が付与された飲食品類を提供することができる。 The flavor enhancer of the present invention is a beverage such as fruit juice beverage, fruit liquor, dairy beverage, carbonated beverage; cold confectionery such as ice cream, sherbet, ice candy; fermentation such as yogurt and cheese. Dairy products; Japanese and Western confectionery, baked confectionery, jams, chewing gums, breads, coffee, cocoa, tea, tea, tobacco and other luxury items; puddings, jellies, bavarois, mousse and other desserts; Soups such as Japanese-style soups and Western-style soups; flavor seasonings; by adding to various instant beverages and foods, various snack foods, etc., it is possible to provide foods and drinks with their excellent aroma and flavor. it can.

本発明の香味増強剤は、飲食品に添加する場合は通常0.0001質量%〜2.0質量%の添加率で用いられ、好ましくは0.001質量%〜1.0質量%の添加率で用いられ、より好ましくは0.01質量%〜0.5質量%の添加率で用いられる。添加率が0.0001質量%未満の場合は添加効果が十分でない場合があり、添加率が2.0質量%を超えた場合は、香味の自然さがやや欠ける可能性がある。 When added to foods and drinks, the flavor enhancer of the present invention is usually used at an addition rate of 0.0001% by mass to 2.0% by mass, preferably 0.001% by mass to 1.0% by mass. It is more preferably used at an addition rate of 0.01% by mass to 0.5% by mass. If the addition rate is less than 0.0001% by mass, the addition effect may not be sufficient, and if the addition rate exceeds 2.0% by mass, the natural flavor may be slightly lacking.

本発明の香味増強剤は各種香粧品に特に制限なく使用することができ、例えば化粧品、トイレタリー製品、ハウスホールド、雑貨などの多くの香粧品に適用可能である。具体的には、シャンプー類、ヘアクリーム類、ポマード類、その他の毛髪用化粧料、白粉、口紅、その他の化粧料、洗濯用洗剤類、消毒用洗剤類、室内芳香剤その他各種の保健・衛生材
料類、医薬品の服用を容易にするための矯味、付香剤などの保健・衛生・医薬品類などに広く使用することができる。
The flavor enhancer of the present invention can be used in various cosmetics without particular limitation, and can be applied to many cosmetics such as cosmetics, toiletry products, households, and miscellaneous goods. Specifically, shampoos, hair creams, pomades, other hair cosmetics, white powder, lipstick, other cosmetics, laundry detergents, disinfectant detergents, indoor fragrances, and various other health and hygiene products. It can be widely used for materials, flavoring to facilitate the administration of medicines, health / hygiene such as fragrances, and medicines.

本発明の香味増強剤を、上記目的で添加する場合は通常0.0001質量%〜2.0質量%の添加率で用いられ、好ましくは0.001質量%〜1.0質量%の添加率で用いられ、より好ましくは0.01質量%〜0.5質量%の添加率で用いられる。
添加率が0.0001質量%未満の場合は添加効果が十分でない場合があり、添加率が2.0質量%を超えた場合は、香気の自然さがやや欠ける可能性がある。
When the flavor enhancer of the present invention is added for the above purpose, it is usually used at an addition rate of 0.0001% by mass to 2.0% by mass, preferably 0.001% by mass to 1.0% by mass. It is more preferably used at an addition rate of 0.01% by mass to 0.5% by mass.
If the addition rate is less than 0.0001% by mass, the addition effect may not be sufficient, and if the addition rate exceeds 2.0% by mass, the naturalness of the aroma may be slightly lacking.

次に実施例を示して本発明をさらに具体的に説明するが、本発明は、これらの実施例に限定されるものではない。
[実施例1]
水蒸気蒸留装置の蒸留釜内に天然素材として緑茶の茶葉(市販品)2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気をスチームチェンヂャー(丸高工業株式会社製の「スチームチェンヂャー SC−200型」(商品名))に導入して得られた多湿水蒸気を水蒸気蒸留装置の釜内に供給して茶葉に接触させた。
多湿水蒸気の供給流速はSV426h-1であり、水蒸気蒸留装置の釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、茶葉から香味増強成分を留出させ、これを本発明の香味増強剤とした。
Next, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
[Example 1]
2 kg of green tea leaves (commercially available) were charged as a natural material in the distillation pot of the steam distillation apparatus.
Next, the dry steam generated from the boiler was introduced into a steam changer (“Steam changer SC-200 type” (trade name) manufactured by Marutaka Kogyo Co., Ltd.), and the humid steam obtained was introduced into the kettle of the steam distillation apparatus. Was supplied to the tea leaves and brought into contact with the tea leaves.
The supply flow velocity of the humid steam was SV426h -1 , and steam distillation was carried out under the conditions that the temperature inside the kettle of the steam distillation apparatus was 100 ° C. and the pressure was 1 atm.
Steam distillation was performed until 1 kg of the condensate in the aqueous layer portion of the cooling section was obtained, and the flavor enhancing component was distilled from the tea leaves, which was used as the flavor enhancing agent of the present invention.

[実施例2]
水蒸気蒸留装置の蒸留釜内に天然素材として実施例1と同様の緑茶の茶葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を水蒸気蒸留装置の釜内底部の水層中に吹き込んで湿分に富んだ多湿水蒸気を発生させ、この多湿水蒸気を茶葉に接触させた。
多湿水蒸気の供給流速はSV426h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、茶葉から香味増強成分を留出させ、これを本発明の香味増強剤とした。
[Example 2]
In the distillation pot of the steam distillation apparatus, 2 kg of green tea leaves similar to those in Example 1 were charged as a natural material.
Next, the dry steam generated from the boiler was blown into the water layer at the bottom of the kettle of the steam distillation apparatus to generate moist steam rich in moisture, and the moist steam was brought into contact with the tea leaves.
The supply flow velocity of the humid steam was SV426h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 1 kg of the condensate in the aqueous layer portion of the cooling section was obtained, and the flavor enhancing component was distilled from the tea leaves, which was used as the flavor enhancing agent of the present invention.

[比較例1]
水蒸気蒸留装置の釜内に天然素材として実施例1と同様の緑茶の茶葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV426h-1)。
釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、茶葉から香味増強成分を留出させ、比較例1の香味増強剤とした。
[Comparative Example 1]
As a natural material, 2 kg of green tea leaves similar to those in Example 1 were charged into the kettle of the steam distillation apparatus.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV426h -1 ).
Steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 1 kg of the condensate in the aqueous layer portion of the cooling portion was obtained, and the flavor enhancing component was distilled off from the tea leaves to obtain a flavor enhancing agent of Comparative Example 1.

[試験例1] (官能評価)
水に実施例1、2と比較例1で得られた香味増強剤を0.5%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、比較例1の評価品をコントロールとしたときの7段階評価である。
[Test Example 1] (Sensory evaluation)
0.5% of the flavor enhancers obtained in Examples 1 and 2 and Comparative Example 1 were added to water to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method is a 7-step evaluation when the evaluation product of Comparative Example 1 is used as a control.

〔評価点ポイント〕
非常に強い : 7ポイント
強い : 6ポイント
やや強い : 5ポイント
コントロール : 4ポイント
やや弱い : 3ポイント
弱い : 2ポイント
非常に弱い : 1ポイント
[Evaluation point points]
Very strong: 7 points Strong: 6 points Slightly strong: 5 points Control: 4 points Slightly weak: 3 points Weak: 2 points Very weak: 1 point

Figure 2021014526
Figure 2021014526

表1に示した通り、本発明の実施例1と2は、水蒸気蒸留特有の加熱臭が弱く、且つ緑茶特徴を強く有していたのに対し、比較例1は水蒸気蒸留特有の加熱臭が強い評価結果であった。 As shown in Table 1, Examples 1 and 2 of the present invention had a weak heating odor peculiar to steam distillation and had a strong green tea characteristic, whereas Comparative Example 1 had a heating odor peculiar to steam distillation. It was a strong evaluation result.

[実施例3]
水蒸気蒸留装置の蒸留釜内に天然素材としてペパーミント葉(市販品)2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気をスチームチェンヂャーに導入して得られた多湿水蒸気を水蒸気蒸留装置の釜内に供給してペパーミント葉に接触させた。
多湿水蒸気の供給流速はSV232h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、ペパーミント葉から香味増強成分を留出させ、これを本発明の香味増強剤とした。
[Example 3]
2 kg of peppermint leaves (commercially available) was charged as a natural material into the distillation pot of the steam distillation apparatus.
Next, the dry steam generated from the boiler was introduced into the steam changer, and the humid steam obtained was supplied into the kettle of the steam distillation apparatus and brought into contact with the peppermint leaves.
The supply flow velocity of the humid steam was SV232h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
The flavor-enhancing component was distilled from the peppermint leaves by steam distillation until 1 kg of the condensate in the aqueous layer portion of the cooling portion was obtained, and this was used as the flavor-enhancing agent of the present invention.

[実施例4]
水蒸気蒸留設備の蒸留釜内に天然素材として実施例3と同様のペパーミント葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を水蒸気蒸留装置の釜内底部の水層中に吹き込んで湿分に富んだ多湿水蒸気を発生させ、この多湿水蒸気をペパーミント葉に接触させた。
多湿水蒸気の供給流速はSV232h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、ペパーミント葉から香味増強成分を留出させ、これを本発明の香味増強剤とした。
[Example 4]
2 kg of peppermint leaves similar to those in Example 3 were charged as a natural material in a distillation pot of a steam distillation facility.
Next, the dry steam generated from the boiler was blown into the water layer at the bottom of the kettle of the steam distillation apparatus to generate humid steam, and the steam was brought into contact with the peppermint leaves.
The supply flow velocity of the humid steam was SV232h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
The flavor-enhancing component was distilled from the peppermint leaves by steam distillation until 1 kg of the condensate in the aqueous layer portion of the cooling portion was obtained, and this was used as the flavor-enhancing agent of the present invention.

[比較例2]
水蒸気蒸留装置の釜内に天然素材として実施例3と同様のペパーミント葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV232h-1)。
釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、ペパーミント葉から香
味増強成分を留出させ、比較例2の香味増強剤とした。
[Comparative Example 2]
As a natural material, 2 kg of peppermint leaves similar to those in Example 3 were charged into the kettle of the steam distillation apparatus.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV232h -1 ).
Steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
The flavor-enhancing component was distilled off from the peppermint leaves by steam distillation until 1 kg of the condensate in the aqueous layer portion of the cooling portion was obtained, and this was used as the flavor-enhancing agent of Comparative Example 2.

[試験例2] (官能評価)
水に実施例3、4と比較例2で得られた香味増強剤を0.1%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、試験例1と同じ方法で実施した(比較例2の評価品がコントロール、7段階評価)。
[Test Example 2] (Sensory evaluation)
0.1% of the flavor enhancers obtained in Examples 3 and 4 and Comparative Example 2 were added to water to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method was the same as that of Test Example 1 (the evaluation product of Comparative Example 2 was controlled, and was evaluated on a 7-point scale).

Figure 2021014526
Figure 2021014526

表2に示した通り、本発明の実施例3と4は、水蒸気蒸留特有の加熱臭が弱く、特に実施例3は非常に弱かった。また、且つペパーミントの特徴を強く有していたのに対し、比較例2は水蒸気蒸留特有の加熱臭が強い評価結果であった。 As shown in Table 2, Examples 3 and 4 of the present invention had a weak heating odor peculiar to steam distillation, and Example 3 in particular was very weak. Moreover, while it had a strong characteristic of peppermint, Comparative Example 2 had a strong evaluation result of a heated odor peculiar to steam distillation.

[実施例5]
水蒸気蒸留装置の蒸留釜内に天然素材として焙煎コーヒー豆(市販品)2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気をスチームチェンヂャーに導入して得られた多湿水蒸気を水蒸気蒸留装置の釜内に供給して焙煎コーヒー豆に接触させた。
多湿水蒸気の供給流速はSV380h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、焙煎コーヒー豆から香味増強成分を留出させ、これを本発明の香味増強剤とした。
[Example 5]
2 kg of roasted coffee beans (commercially available) was charged as a natural material in the distillation pot of the steam distillation apparatus.
Next, the dry steam generated from the boiler was introduced into the steam changer, and the humid steam obtained was supplied into the kettle of the steam distillation apparatus and brought into contact with the roasted coffee beans.
The supply flow velocity of the humid steam was SV380h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 1 kg of the condensate in the aqueous layer portion of the cooling section was obtained, and the flavor enhancing component was distilled from the roasted coffee beans, which was used as the flavor enhancing agent of the present invention.

[比較例3]
水蒸気蒸留装置の釜内に天然素材として実施例5と同様の焙煎コーヒー豆2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV380h-1)。
釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
水層部分の凝縮液が1kg得られるまで水蒸気蒸留し、焙煎コーヒー豆から香味増強成分を留出させ、比較例3の香味増強剤とした。
[Comparative Example 3]
In the kettle of the steam distillation apparatus, 2 kg of roasted coffee beans similar to those in Example 5 were charged as a natural material.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV380h -1 ).
Steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 1 kg of the condensate of the aqueous layer portion was obtained, and the flavor enhancing component was distilled from the roasted coffee beans to obtain the flavor enhancing agent of Comparative Example 3.

[試験例3] (官能評価)
水に実施例5と比較例3で得られた香味増強剤を0.1%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、試験例1と同じ方法で実施した(比較例3の評価品がコントロール、7段階評価)。
[Test Example 3] (Sensory evaluation)
0.1% of the flavor enhancers obtained in Example 5 and Comparative Example 3 were added to water to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method was the same as that of Test Example 1 (the evaluation product of Comparative Example 3 was controlled, and was evaluated on a 7-point scale).

Figure 2021014526
Figure 2021014526

表3に示した通り、本発明の実施例5は、水蒸気蒸留特有の加熱臭が弱く、且つコーヒーの特徴を強く有していたのに対し、比較例3は水蒸気蒸留特有の加熱臭が強い評価結果であった。 As shown in Table 3, Example 5 of the present invention had a weak heated odor peculiar to steam distillation and had strong characteristics of coffee, whereas Comparative Example 3 had a strong heated odor peculiar to steam distillation. It was an evaluation result.

[実施例6]
水蒸気蒸留装置の蒸留釜内に天然素材として実施例3と同様のペパーミント葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気をスチームチェンヂャーに導入して得られた多湿水蒸気を水蒸気蒸留装置の釜内に供給してペパーミント葉に接触させた。
多湿水蒸気の供給流速はSV232h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の凝縮液が1kg得られるまで水蒸気蒸留し、ペパーミント葉から香味増強成分を留出させた。
1kgの凝縮液から28.6gの油層部分を回収し、本発明の香味増強剤とした。
[Example 6]
In the distillation pot of the steam distillation apparatus, 2 kg of peppermint leaves similar to those in Example 3 were charged as a natural material.
Next, the dry steam generated from the boiler was introduced into the steam changer, and the humid steam obtained was supplied into the kettle of the steam distillation apparatus and brought into contact with the peppermint leaves.
The supply flow velocity of the humid steam was SV232h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
The flavor-enhancing component was distilled off from the peppermint leaves by steam distillation until 1 kg of the condensate in the cooling section was obtained.
28.6 g of an oil layer portion was recovered from 1 kg of the condensate to prepare the flavor enhancer of the present invention.

[比較例4]
水蒸気蒸留装置の釜内に天然素材として実施例3と同様のペパーミント葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV232h-1)。
釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の凝縮液が1kg得られるまで水蒸気蒸留し、ペパーミント葉から香味増強成分を留出させた。
1kgの凝縮液から27.3gの油層部分を回収し、比較例4の香味増強剤とした。
[Comparative Example 4]
As a natural material, 2 kg of peppermint leaves similar to those in Example 3 were charged into the kettle of the steam distillation apparatus.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV232h -1 ).
Steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
The flavor-enhancing component was distilled off from the peppermint leaves by steam distillation until 1 kg of the condensate in the cooling section was obtained.
27.3 g of the oil layer portion was recovered from 1 kg of the condensate and used as the flavor enhancer of Comparative Example 4.

[試験例4] (官能評価)
水飴に実施例4と比較例4で得られた香味増強剤を0.05%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、試験例1と同じ方法で実施した(比較例4の評価品がコントロール、7段階評価)。
[Test Example 4] (Sensory evaluation)
0.05% of the flavor enhancers obtained in Example 4 and Comparative Example 4 were added to starch syrup to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method was the same as that of Test Example 1 (the evaluation product of Comparative Example 4 was controlled, and the evaluation was performed on a 7-point scale).

Figure 2021014526
Figure 2021014526

表4に示した通り、本発明の実施例6は、水蒸気蒸留特有の加熱臭が非常に弱く、且つペパーミントの特徴を強く有していたのに対し、比較例4は水蒸気蒸留特有の加熱臭が強い評価結果であった。 As shown in Table 4, Example 6 of the present invention had a very weak heating odor peculiar to steam distillation and had a strong characteristic of peppermint, whereas Comparative Example 4 had a heating odor peculiar to steam distillation. Was a strong evaluation result.

[実施例7]
水蒸気蒸留装置の蒸留釜内に天然素材としてレモン果皮(市販品)1kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気をスチームチェンヂャーに導入して得られた多湿水蒸気を水蒸気蒸留装置の釜内に供給してレモン果皮に接触させた。
多湿水蒸気の供給流速はSV887h-1であり、釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の凝縮液が0.5kg得られるまで水蒸気蒸留し、レモン果皮から香味増強成分を留出させた。
0.5kgの凝縮液から31.9gの油層部分を回収し、本発明の香味増強剤とした。
[Example 7]
1 kg of lemon peel (commercially available) was charged as a natural material into the distillation pot of the steam distillation apparatus.
Next, the dry steam generated from the boiler was introduced into the steam changer, and the humid steam obtained was supplied into the kettle of the steam distillation apparatus and brought into contact with the lemon peel.
The supply flow velocity of the humid steam was SV887h -1 , and steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 0.5 kg of the condensate in the cooling section was obtained, and the flavor-enhancing component was distilled off from the lemon peel.
31.9 g of an oil layer portion was recovered from 0.5 kg of the condensate to prepare the flavor enhancer of the present invention.

[比較例5]
水蒸気蒸留装置の釜内に天然素材として実施例7と同様のレモン果皮1kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV887h-1)。
釜内温度100℃、圧力は1気圧の条件で水蒸気蒸留を実施した。
冷却部の凝縮液が0.5kg得られるまで水蒸気蒸留し、レモン果皮から香味増強成分を留出させた。
0.5kgの凝縮液から31.9gの油層部分を回収し、比較例5の香味増強剤とした。
[Comparative Example 5]
As a natural material, 1 kg of lemon peel as in Example 7 was charged into the kettle of the steam distillation apparatus.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV887h -1 ).
Steam distillation was carried out under the conditions of a kettle temperature of 100 ° C. and a pressure of 1 atm.
Steam distillation was performed until 0.5 kg of the condensate in the cooling section was obtained, and the flavor-enhancing component was distilled off from the lemon peel.
31.9 g of an oil layer portion was recovered from 0.5 kg of the condensate and used as a flavor enhancer of Comparative Example 5.

[試験例4] (官能評価)
水飴に実施例7と比較例5で得られた香味増強剤を0.05%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、試験例1と同じ方法で実施した(比較例5の評価品がコントロール、7段階評価)。
[Test Example 4] (Sensory evaluation)
0.05% of the flavor enhancers obtained in Example 7 and Comparative Example 5 were added to starch syrup to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method was the same as that of Test Example 1 (the evaluation product of Comparative Example 5 was controlled, and was evaluated on a 7-point scale).

Figure 2021014526
Figure 2021014526

表5に示した通り、本発明の実施例7は、水蒸気蒸留特有の加熱臭が弱く、且つレモンの特徴を強く有していたのに対し、比較例5は水蒸気蒸留特有の加熱臭が強い評価結果であった。 As shown in Table 5, Example 7 of the present invention had a weak heating odor peculiar to steam distillation and had a strong lemon characteristic, whereas Comparative Example 5 had a strong heating odor peculiar to steam distillation. It was an evaluation result.

[比較例6]
水蒸気蒸留装置の釜内に天然素材として実施例1と同様の緑茶の茶葉2kgを仕込んだ。
次いで、ボイラーから発生した乾燥水蒸気を直接、水蒸気蒸留装置の釜内に供給した(供給流速はSV775h-1)。
蒸気温度が80℃になるように釜内を減圧し、冷却部の水層部分の凝縮液が1.0kg得られるまで水蒸気蒸留を実施して、茶葉から香味増強成分を留出させた。これを、比較例6の香味増強剤とした。
[Comparative Example 6]
As a natural material, 2 kg of green tea leaves similar to those in Example 1 were charged into the kettle of the steam distillation apparatus.
Next, the dry steam generated from the boiler was directly supplied into the kettle of the steam distillation apparatus (supply flow rate is SV775h -1 ).
The inside of the kettle was depressurized so that the steam temperature became 80 ° C., and steam distillation was carried out until 1.0 kg of the condensate in the aqueous layer portion of the cooling section was obtained to distill off the flavor-enhancing component from the tea leaves. This was used as the flavor enhancer of Comparative Example 6.

[試験例6] (官能評価)
水に実施例1、2と比較例6で得られた香味増強剤を0.5%添加して評価品を作成し、それを専門パネラーが官能評価した。
評価方法は、試験例1と同じ方法で実施した(比較例6の評価品がコントロール、7段階評価)。
[Test Example 6] (Sensory evaluation)
0.5% of the flavor enhancers obtained in Examples 1 and 2 and Comparative Example 6 were added to water to prepare an evaluation product, which was sensory-evaluated by a specialized panelist.
The evaluation method was the same as that of Test Example 1 (the evaluation product of Comparative Example 6 was controlled, and was evaluated on a 7-point scale).

Figure 2021014526
Figure 2021014526

表6に示した通り、本発明の実施例1と2は、緑茶の特徴を強く有していたのに対し、比較例6は、加熱臭は弱いものの、緑茶全体の特徴が非常に弱い評価結果であった。 As shown in Table 6, Examples 1 and 2 of the present invention had strong characteristics of green tea, whereas Comparative Example 6 had a weak heating odor, but the characteristics of green tea as a whole were very weak. It was a result.

本発明の多湿水蒸気による水蒸気蒸留によれば、水蒸気蒸留によって得られる天然素材の香味成分に蒸れ臭や焦げ臭などの異臭が付着せず、原料である天然素材の本来の香味を
有しており、且つ、強い力価を有する香味増強剤を得ることができる。各種の天然素材に広く適用が可能なので、工業的な意義が大きい。
According to the steam distillation using high-humidity steam of the present invention, offensive odors such as stuffy odor and burnt odor do not adhere to the flavor components of the natural material obtained by steam distillation, and the natural material as a raw material has the original flavor. Moreover, a flavor enhancer having a strong titer can be obtained. Since it can be widely applied to various natural materials, it has great industrial significance.

Claims (6)

水蒸気蒸留によって天然素材から有用成分を分離又は精製する方法において、水蒸気として多湿水蒸気を用いることを特徴とする分離又は精製方法。 A method for separating or purifying useful components from a natural material by steam distillation, which comprises using humid steam as steam. 多湿水蒸気を空間速度(SV)50〜1600h-1の流速で供給し、1〜1.1気圧、95〜105℃の条件下で、水蒸気蒸留を行うことを特徴とする請求項1に記載の方法。 The first aspect of the present invention, wherein the humid steam is supplied at a flow rate of 50 to 1600 h -1 in space velocity (SV), and steam distillation is performed under the conditions of 1 to 1.1 atm and 95 to 105 ° C. Method. 請求項1又は2に記載の水蒸気蒸留により、天然素材から分離又は精製された香味増強成分からなることを特徴とする香味増強剤。 A flavor enhancer comprising a flavor enhancer separated or purified from a natural material by steam distillation according to claim 1 or 2. 請求項3に記載の香味増強剤を添加したことを特徴とする飲食物。 A food or drink characterized by adding the flavor enhancer according to claim 3. 請求項3に記載の香味増強剤を添加したことを特徴とする香粧品。 A cosmetic product to which the flavor enhancer according to claim 3 is added. 天然素材由来の香味増強成分からなる香味増強剤の製造方法において、多湿水蒸気を用いる水蒸気蒸留によって天然素材から香味増強成分を分離又は精製する工程を含むことを特徴とする、香味増強剤の製造方法。 A method for producing a flavor enhancer composed of a flavor enhancer derived from a natural material, which comprises a step of separating or purifying the flavor enhancer from the natural material by steam distillation using humid steam. ..
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54107568A (en) * 1977-10-27 1979-08-23 Procter & Gamble Removing and separating method for aromatic taste concentrate
JPS5537193A (en) * 1978-06-22 1980-03-15 Procter & Gamble Improved coffee like instant coffee grain beverage
JPS63137646A (en) * 1986-11-29 1988-06-09 エス・カー・ヴエー・トローストベルク・アクチエンゲゼルシヤフト Method for removing aroma from tea or green tea and continuously again adding the same thereto
JP2012135246A (en) * 2010-12-27 2012-07-19 Ogawa & Co Ltd Lemon grass extraction
US20160316802A1 (en) * 2013-12-27 2016-11-03 Suntory Holdings Limited Method for recovering preferable aroma from biomaterial
JP2018191606A (en) * 2017-05-19 2018-12-06 卜部産業株式会社 Oyster extract and manufacturing method therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54107568A (en) * 1977-10-27 1979-08-23 Procter & Gamble Removing and separating method for aromatic taste concentrate
JPS5537193A (en) * 1978-06-22 1980-03-15 Procter & Gamble Improved coffee like instant coffee grain beverage
JPS63137646A (en) * 1986-11-29 1988-06-09 エス・カー・ヴエー・トローストベルク・アクチエンゲゼルシヤフト Method for removing aroma from tea or green tea and continuously again adding the same thereto
JP2012135246A (en) * 2010-12-27 2012-07-19 Ogawa & Co Ltd Lemon grass extraction
US20160316802A1 (en) * 2013-12-27 2016-11-03 Suntory Holdings Limited Method for recovering preferable aroma from biomaterial
JP2018191606A (en) * 2017-05-19 2018-12-06 卜部産業株式会社 Oyster extract and manufacturing method therefor

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