JP2020083764A - 皮膚洗浄剤組成物 - Google Patents
皮膚洗浄剤組成物 Download PDFInfo
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- JP2020083764A JP2020083764A JP2018214968A JP2018214968A JP2020083764A JP 2020083764 A JP2020083764 A JP 2020083764A JP 2018214968 A JP2018214968 A JP 2018214968A JP 2018214968 A JP2018214968 A JP 2018214968A JP 2020083764 A JP2020083764 A JP 2020083764A
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- component
- fatty acid
- skin cleansing
- cleansing composition
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- Prior art date
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Landscapes
- Cosmetics (AREA)
Abstract
Description
〔1〕成分Aおよび成分Bを含有する皮膚洗浄剤組成物:前記成分Aは、平均粒子径が15〜50μmの活性炭、前記成分Bは、ポリグリセリン脂肪酸エステル、モノグリセリン脂肪酸エステルの誘導体、ポリグリセリン脂肪酸エステルの誘導体およびポリグリセリルアルキルエーテルからなる群から選ばれる少なくとも1種の成分。
〔2〕さらに、成分Cとして前記成分B以外の界面活性剤を含む、〔1〕に記載の皮膚洗浄剤組成物。
〔3〕前記成分Bは、少なくともポリグリセリルアルキルエーテルを含む、〔1〕または〔2〕に記載の皮膚洗浄剤組成物。
〔4〕平均粒子径が100μm以上である粒子を実質的に含まない、〔1〕〜〔3〕の何れか1つに記載の皮膚洗浄剤組成物。
〔5〕前記皮膚洗浄剤組成物100質量%中、前記成分Aの含有量は0.1質量%〜25.0質量%である、〔1〕〜〔4〕の何れか1つに記載の皮膚洗浄剤組成物。
〔6〕前記皮膚洗浄剤組成物100質量%中、前記成分Bの含有量は0.01質量%〜10.0質量%である、〔1〕〜〔5〕の何れか1つに記載の皮膚洗浄剤組成物。
本発明者らが検討したところ、上述の特許文献1および2に開示された皮膚洗浄剤組成物は、皮脂除去力の面で改善の余地があることがわかった。一方、特許文献3に開示されているようなスクラブ剤を含有する皮膚洗浄用組成物は、皮膚をスクラブにより擦るものであるため、皮脂除去力には優れる。しかし、皮膚をスクラブにより研磨するものであるため、皮膚に大きな負担がかかるという問題があることがわかった。
本発明の一実施形態に係る皮膚洗浄剤組成物は、成分Aおよび成分Bを含有し、前記成分Aは、平均粒子径が15〜50μmの活性炭であり、前記成分Bは、ポリグリセリン脂肪酸エステル、モノグリセリン脂肪酸エステルの誘導体、ポリグリセリン脂肪酸エステルの誘導体およびポリグリセリルアルキルエーテルからなる群から選ばれる少なくとも1種の成分である。
成分Aは、平均粒子径が15〜50μmである活性炭である。上述のとおり、成分Aは、成分Bにより溶解された皮脂を吸着する成分といえる。なお、一般的に、スクラブ剤は、平均粒子径が100μm以上であるとされる。一方、本皮膚洗浄剤組成物に含まれる成分Aである活性炭は、平均粒子径が50μm以下である。このため、成分Aはスクラブ剤としての機能は有さず、スクラブ剤とは見做されない。
成分Bは、ポリグリセリン脂肪酸エステル、モノグリセリン脂肪酸エステルの誘導体、ポリグリセリン脂肪酸エステルの誘導体およびポリグリセリルアルキルエーテルからなる群から選ばれる少なくとも1種である。上述したとおり、成分Bは、皮脂を溶解させる成分といえる。
ポリグリセリン脂肪酸エステルは、化学式HO−(CH2−CH(OH)−CH2−O)m−H(式中mは2以上の整数)で表されるポリグリセリンと1つ以上の脂肪酸とからなるエステルである。
本明細書において、「モノグリセリン脂肪酸エステル」とは、化学式HO−CH2−CH(OH)−CH2−OHで表されるグリセリンおよび1つ以上の脂肪酸からなるエステルを意図する。モノグリセリン脂肪酸エステルの誘導体は、モノグリセリン脂肪酸エステルと1つ以上の任意の化合物とが結合(例えば付加重合または縮合)したものである。また、ポリグリセリン脂肪酸エステルの誘導体は、前記(ポリグリセリン脂肪酸エステル)の項で説明したポリグリセリン脂肪酸エステルと1つ以上の任意の化合物とが結合(例えば付加重合または縮合)したものである。前記任意の化合物としては、ヒドロキシ基を有するアルコール、化学式H−(OCH2CH2)n−OH(式中nは2以上の整数)で表されるポリオキシエチレンなどの酸化エチレンなどが挙げられる。アルコールの価数は特に限定されず、2価アルコールであるグリコールであってもよく、多価アルコールであってもよい。ポリオキシエチレンはポリエチレングリコールと称される場合もあり、2価アルコールでもある。
ポリグリセリルアルキルエーテルは、ポリグリセリンと1つのアルキルとがエーテル結合されたものである。ポリグリセリルアルキルエーテルは、具体的には以下の一般式(1)を有する:
得られる皮膚洗浄剤組成物が、皮膚低刺激効果および製剤安定性により優れることから、R1におけるアルキル基は、炭素数6〜22のアルキル基であることが好ましく、炭素数8〜18のアルキル基であることがより好ましく、炭素数8〜16のアルキル基であることがさらに好ましい。前記アルキル基は直鎖であってもよく、分岐鎖であってもよく、環状であってもよい。前記アルキルは、その一部が置換されていてもよく、非置換であってもよい。前記アルキルの一部が置換されている場合、置換基としては、ヒドロキシ基およびアミノ基などが挙げられる。
本皮膚洗浄剤組成物は、さらに、成分Cとして前記成分B以外の界面活性剤を含むことが好ましい。本皮膚洗浄剤組成物がさらに成分Cを含むことにより、当該皮膚洗浄剤組成物によって適度な硬さを有するクリーム形状の泡を作ることができ、さらに当該泡を安定に保持できる。また洗浄力も向上する。
本皮膚洗浄剤組成物は、さらに、成分Dとして多価アルコールを含むことが好ましい。本皮膚洗浄剤組成物は、さらに成分D(多価アルコール)を含むことにより、洗浄後の皮膚を保湿し得る保湿効果を有するものとなる。
本皮膚洗浄剤組成物は、上記成分A〜成分D以外に、本発明の一実施形態に係る効果を損なわない範囲で、その他の成分を含んでいてもよい。
本皮膚洗浄剤組成物において、上述した各成分以外の残部には水が用いられる。水は、洗浄剤原料として使用できるものであれば特に限定されないが、通常、精製水が用いられる。本発明の一実施形態において、皮膚洗浄剤組成物100質量%中、水の含有量は、50質量%〜89質量%であることが好ましく、60質量%〜80質量%であることがより好ましい。
器またはジャー容器等に充填した商品形態とすることができる。これらの中でも、ジェル状の組成物の吐出性に優れるチューブ容器による商品形態が好ましい。
活性炭(商品名「クラレコール(登録商標)」;クラレケミカル株式会社製;平均粒子径、35.40μm)
[成分B]
ポリグリセリル−4ラウリルエーテル(商品名「サンイーサーL−4」、太陽化学株式会社製)
カプリル酸ポリグリセリル−3(太陽化学株式会社製)
ラウリン酸ポリグリセリル−10(商品名「サンソフトM−12J」、太陽化学株式会社製)
イソステアリン酸PEG−10グリセリル
イソステアリン酸PEG−20グリセリル
[成分C]
ラウリン酸(炭素数=12)
ミリスチン酸(炭素数=14)
パルミチン酸(炭素数=16)
ステアリン酸(炭素数=18)
[成分D]
ポリエチレングリコール(数平均分子量、190〜210)
[その他の成分]
ポリオキシエチレンラウリルエーテル硫酸ナトリウム(商品名「エマール125HP」、花王株式会社製)
ジオレス−8リン酸ナトリウム(ポリオキシエチレンオレイルエーテルリン酸ナトリウム)(商品名「NIKKOL DOP−8NV」、日光ケミカルズ株式会社製)
グリセリン
モノステアリン酸グリセリル
水酸化カリウム
[水]
精製水。
脂肪酸、脂質およびスクワレンなどを配合してモデル皮脂を調製した。モデル皮脂10モデル皮脂における脂肪酸の割合は、モデル皮脂100質量%に対して、30質量%とした。モデル皮脂1000質量部に対し0.1質量部の赤色染色液(Oil Red O Solution、コスモ・バイオ株式会社製)を加えて、モデル皮脂を赤色に染色した。次に、モデル皮脂を60℃に加温して液化させ、液化したモデル皮脂にケラチン布(15mm×15mm)を1秒間浸漬させた。次に、モデル皮脂に浸漬した後のケラチン布を35℃で12時間以上静置させて、乾燥した。
◎ケラチン布面積の90%以上が白い
○ケラチン布面積の50%以上90%未満が白い
×ケラチン布面積の50%超が赤い。
表1に記した組成に従い、各成分を配合し、実施例1〜10並びに比較例1および2の皮膚洗浄剤組成物を調製した。各皮膚洗浄剤組成物について、後述する皮脂汚れ落ち評価を行った。評価結果を、それぞれ表1に示す。
表2に記した組成に従い、各成分を配合し、実施例11〜13並びに比較例3および4の皮膚洗浄剤組成物を調製した。各皮膚洗浄剤組成物について、後述する皮脂汚れ落ち評価を行った。評価結果を、それぞれ表2に示す。
Claims (6)
- 成分Aおよび成分Bを含有する皮膚洗浄剤組成物:
前記成分Aは、平均粒子径が15〜50μmの活性炭、
前記成分Bは、ポリグリセリン脂肪酸エステル、モノグリセリン脂肪酸エステルの誘導体、ポリグリセリン脂肪酸エステルの誘導体およびポリグリセリルアルキルエーテルからなる群から選ばれる少なくとも1種の成分。 - さらに、成分Cとして前記成分B以外の界面活性剤を含む、請求項1に記載の皮膚洗浄剤組成物。
- 前記成分Bは、少なくともポリグリセリルアルキルエーテルを含む、請求項1または2に記載の皮膚洗浄剤組成物。
- 平均粒子径が100μm以上である粒子を実質的に含まない、請求項1〜3の何れか1項に記載の皮膚洗浄剤組成物。
- 前記皮膚洗浄剤組成物100質量%中、前記成分Aの含有量は0.1質量%〜25.0質量%である、請求項1〜4の何れか1項に記載の皮膚洗浄剤組成物。
- 前記皮膚洗浄剤組成物100質量%中、前記成分Bの含有量は0.01質量%〜10.0質量%である、請求項1〜5の何れか1項に記載の皮膚洗浄剤組成物。
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