JP2018524152A - ポリマー表面を金属化する方法 - Google Patents
ポリマー表面を金属化する方法 Download PDFInfo
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- JP2018524152A JP2018524152A JP2017561401A JP2017561401A JP2018524152A JP 2018524152 A JP2018524152 A JP 2018524152A JP 2017561401 A JP2017561401 A JP 2017561401A JP 2017561401 A JP2017561401 A JP 2017561401A JP 2018524152 A JP2018524152 A JP 2018524152A
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
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Abstract
Description
Claims (20)
- 物品のポリマー表面を金属化する方法であって、当該方法は、前記ポリマー表面に金属粒子または金属に見える粒子の懸濁液を含む液体担体を適用することを含み、前記ポリマー表面および前記液体担体は、前記液体担体と前記ポリマー表面との間の濡れ角が実質的に90°以上であるものであり、前記粒子および前記ポリマー表面は、前記粒子が、相互にまたは前記液体よりも、前記ポリマー表面に対してより大きな親和性を有するようなものであり、それによって、前記液体中に懸濁した粒子が前記液体と前記ポリマー表面との間の界面に移動し、前記ポリマー表面上に粒子の単層コーティングを形成する、方法。
- 前記粒子が、平らな小板として成形されている、請求項1に記載の方法。
- 前記平らな小板が、それらの平均直径よりも5、10、20または100倍小さい厚みを有する、請求項2に記載の方法。
- 前記粒子が、1マイクロメートル未満、800nm未満、600nm未満、500nm未満、400nm未満、350nm未満、300nm未満、250nm未満、200nm未満、175nm未満、150nm未満、125nm未満、100nm未満、または80nm未満の厚みを有し;前記厚みが任意に少なくとも5nm、少なくとも7nm、少なくとも10nm、少なくとも15nm、少なくとも20nm、少なくとも25nm、少なくとも30nm、少なくとも40nm、または少なくとも50nmである、請求項1〜3のいずれか一項に記載の方法。
- 前記粒子が、10nmと600nmの間、20nmと500nmの間または20と400nmの間の厚みを有する、請求項1〜4のいずれか一項に記載の方法。
- 金属化される前記表面が、適切なポリマー材料から成形された物品のそれである、請求項1〜5のいずれか一項に記載の方法。
- 前記表面が、金属粒子または金属に見える粒子によってコーティングされる前に、ポリマーベースコーティングが、前記物品に適用される、請求項1〜6のいずれか一項に記載の方法。
- 前記金属粒子または金属に見える粒子の液体担体が、水性であり、前記物品または前記ベースコーティングのポリマー材料は、場合によっては、疎水性であるように選択される、請求項1〜7のいずれか一項に記載の方法。
- 前記ポリマー材料の疎水性が、ポリマー組成物中に添加剤を含むことに起因する、請求項8に記載の方法。
- 前記添加剤が、合成油、天然油、植物油または鉱油、ワックス、可塑剤およびシリコーン添加剤からなる群より選択される、請求項9に記載の方法。
- 前記粒子が、アルミニウム、銅、金、鉄、ニッケル、スズ、チタン、銀および亜鉛を含む群から選択される金属;またはスチール、真鍮およびブロンズを含む群から選択される合金;または雲母を含む群から選択される金属様の反射率を有する材料;またはこれらの組み合わせである、請求項1〜10のいずれか一項に記載の方法。
- 前記粒子が、表面コーティングを有する、請求項11に記載の方法。
- 前記粒子の表面コーティングが、カルボン酸または脂肪酸を含む、請求項12に記載の方法。
- 前記ポリマー材料が、ポリウレタン、ポリウレタン−シリコーンコポリマー、ポリエステルまたはアクリルポリマーである、請求項1〜13のいずれか一項に記載の方法。
- 前記粒子が、前記ポリマー表面上に層を形成し、当該層が、前記ポリマー表面へのその適用中または適用後に磨かれる、請求項1〜14のいずれか一項に記載の方法。
- 透明なワニスコーティングが粒子の前記単層コーティング上に適用される、請求項1〜15のいずれか一項に記載の方法。
- 前記ワニスコーティングが着色剤を含む、請求項16に記載の方法。
- 粒子の前記単層コーティングが、それが適用されるポリマー表面の面積の少なくとも80%、または90%、または95%、または97%、または99%を覆う、請求項1〜17のいずれか一項に記載の方法。
- 粒子の前記単層コーティングが、約10nmと約1μmとの間の厚みを有し、粒子の前記単層コーティングの厚みが、任意に、最大500nm、最大250nm、最大200nm、最大150nm、最大100nm、最大50nmである、請求項1〜18のいずれか一項に記載の方法。
- 前記単層が、光沢、輝き、艶消し、煌めき、光沢、真珠光沢、玉虫色および金属光沢を含む群から選択される視覚効果をポリマー表面に適用する、請求項1〜19のいずれか一項に記載の方法。
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GBGB1602420.0A GB201602420D0 (en) | 2015-05-27 | 2016-02-10 | Process for metallising a surface |
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GB201509080D0 (en) | 2015-05-27 | 2015-07-08 | Landa Labs 2012 Ltd | Coating apparatus |
US11701684B2 (en) | 2015-05-27 | 2023-07-18 | Landa Labs (2012) Ltd. | Method for coating a surface with a transferable layer of thermoplastic particles and related apparatus |
US11740532B2 (en) | 2018-12-17 | 2023-08-29 | Viavi Solutions Inc. | Article including light valves |
US11118061B2 (en) * | 2018-12-17 | 2021-09-14 | Viavi Solutions Inc. | Article including at least one metal portion |
US11701802B2 (en) | 2019-11-05 | 2023-07-18 | GM Global Technology Operations LLC | Enthalpy-driven self-hardening process at the polymeric/metal layer interface with an interdiffusion process |
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RU2017138081A3 (ja) | 2019-08-26 |
GB201509082D0 (en) | 2015-07-08 |
KR20180012275A (ko) | 2018-02-05 |
ES2929104T3 (es) | 2022-11-24 |
AU2016268515A1 (en) | 2017-11-16 |
JP6807872B2 (ja) | 2021-01-06 |
AU2016268515B2 (en) | 2020-03-05 |
BR112017025317A2 (pt) | 2018-07-31 |
MX2017015242A (es) | 2018-03-16 |
CA2986534C (en) | 2023-02-07 |
EP3302999B1 (en) | 2022-10-12 |
RU2017138081A (ru) | 2019-08-26 |
WO2016189514A1 (en) | 2016-12-01 |
IL255915A (en) | 2018-01-31 |
KR102356267B1 (ko) | 2022-01-26 |
BR112017025317B1 (pt) | 2022-10-25 |
US20180133753A1 (en) | 2018-05-17 |
US10272469B2 (en) | 2019-04-30 |
RU2709559C2 (ru) | 2019-12-18 |
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CN107666969B (zh) | 2021-05-14 |
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