JP2017538021A - 耐衝撃性改良剤及びそれを含むポリマー組成物 - Google Patents
耐衝撃性改良剤及びそれを含むポリマー組成物 Download PDFInfo
- Publication number
- JP2017538021A JP2017538021A JP2017531859A JP2017531859A JP2017538021A JP 2017538021 A JP2017538021 A JP 2017538021A JP 2017531859 A JP2017531859 A JP 2017531859A JP 2017531859 A JP2017531859 A JP 2017531859A JP 2017538021 A JP2017538021 A JP 2017538021A
- Authority
- JP
- Japan
- Prior art keywords
- acrylate
- weight
- impact modifier
- derived units
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 229920000642 polymer Polymers 0.000 title claims abstract description 36
- 239000004609 Impact Modifier Substances 0.000 title claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 41
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 29
- -1 acrylate free radical Chemical class 0.000 claims abstract description 18
- 230000009257 reactivity Effects 0.000 claims abstract description 16
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 230000008961 swelling Effects 0.000 claims abstract description 9
- 125000002348 vinylic group Chemical group 0.000 claims abstract description 7
- 229920005601 base polymer Polymers 0.000 claims description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims description 11
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 10
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical group C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 7
- 230000009477 glass transition Effects 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920000193 polymethacrylate Polymers 0.000 claims description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000005060 rubber Substances 0.000 description 9
- 239000004971 Cross linker Substances 0.000 description 8
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 6
- 239000003999 initiator Substances 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- TUXCFTFFNGQODI-UHFFFAOYSA-N 1,5-dimethylpiperazin-2-one Chemical compound CC1CN(C)C(=O)CN1 TUXCFTFFNGQODI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HVVPYFQMCGANJX-UHFFFAOYSA-N 2-methylprop-2-enyl prop-2-enoate Chemical compound CC(=C)COC(=O)C=C HVVPYFQMCGANJX-UHFFFAOYSA-N 0.000 description 1
- AKSBCQNPVMRHRZ-UHFFFAOYSA-N 2-prop-2-enoxyethyl prop-2-enoate Chemical compound C=CCOCCOC(=O)C=C AKSBCQNPVMRHRZ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 241000285023 Formosa Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- PCVSIMQAFWRUEC-UHFFFAOYSA-N N2-[1-[methyl-(phenylmethyl)amino]-3-(2-naphthalenyl)-1-oxopropan-2-yl]-N1-(2-nitrophenyl)pyrrolidine-1,2-dicarboxamide Chemical compound C=1C=C2C=CC=CC2=CC=1CC(NC(=O)C1N(CCC1)C(=O)NC=1C(=CC=CC=1)[N+]([O-])=O)C(=O)N(C)CC1=CC=CC=C1 PCVSIMQAFWRUEC-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 244000125380 Terminalia tomentosa Species 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DSSYKIVIOFKYAU-UHFFFAOYSA-N camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- BLYOHBPLFYXHQA-UHFFFAOYSA-N n,n-bis(prop-2-enyl)prop-2-enamide Chemical compound C=CCN(CC=C)C(=O)C=C BLYOHBPLFYXHQA-UHFFFAOYSA-N 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
試験方法は以下を含む。
THF中に5重量%のポリマーを溶解することにより膨潤比を測定する。次いで溶液を遠心分離して不溶解部分を分離する。その後、不溶解部分を計量し乾燥させて、次に再度計量し、湿潤重量の乾燥重量に対する比として膨潤比を定義する。
Claims (5)
- 耐衝撃性改良剤組成物であって、
98〜99.9重量%の1つ以上のアクリレートモノマー由来単位と、0.8〜1.2のアクリレートフリーラジカル反応性比を有するビニル性不飽和部分及び1を超えるアクリレートフリーラジカル反応性比を有する1つ以上の非アクリレートビニル性不飽和部分を含有する架橋剤に由来する0.1〜2重量%の単位とを有する架橋コアであって、7〜15のTHF中における膨潤比と10℃以下のガラス転移温度Tgとを有する、架橋コアと、
20〜100重量%の1つ以上の(メタ)アクリレートモノマー由来単位を有し、20℃を超えるTgを有するシェルと、を含む1つ以上のコア/シェルポリマーを含む、耐衝撃性改良剤組成物。 - 前記架橋剤が、アリルアクリレートである、請求項1に記載の耐衝撃性改良剤組成物。
- 前記架橋コアが、98〜99.9重量%のブチルアクリレート由来単位と、0.1〜2重量%のアリルアクリレート由来単位と、を含む、請求項1または2に記載の耐衝撃性改良剤組成物。
- 前記架橋コアが、99.1〜99.8重量%のブチルアクリレート由来単位と、0.2〜0.9重量%のアリルアクリレート由来単位と、を含む、請求項1〜3のいずれか一項に記載の耐衝撃性改良剤組成物。
- ポリマー組成物であって、
請求項1〜4のいずれか一項に記載の0重量%超、50重量%以下である1つ以上の耐衝撃性改良剤組成物と、
ポリエステル、スチレン系ポリマー、ポリメタクリレート、ポリ塩化ビニル、ポリカーボネート、ポリアミド、コポリマー、ならびにそれらのブレンド及びそれらの組み合わせからなるが、これらに限定されない群から選択される50以上100重量%未満の任意の構造ベースポリマーと、を含む、ポリマー組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462095301P | 2014-12-22 | 2014-12-22 | |
US62/095,301 | 2014-12-22 | ||
PCT/US2015/066230 WO2016106055A1 (en) | 2014-12-22 | 2015-12-17 | An impact modifier and a polymer composition comprising the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017538021A true JP2017538021A (ja) | 2017-12-21 |
JP6655621B2 JP6655621B2 (ja) | 2020-02-26 |
Family
ID=55229821
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017531859A Active JP6655621B2 (ja) | 2014-12-22 | 2015-12-17 | 耐衝撃性改良剤及びそれを含むポリマー組成物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US10316126B2 (ja) |
EP (1) | EP3259291B1 (ja) |
JP (1) | JP6655621B2 (ja) |
KR (1) | KR102480143B1 (ja) |
CN (1) | CN107001543B (ja) |
BR (1) | BR112017012913B1 (ja) |
WO (1) | WO2016106055A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020528094A (ja) * | 2017-07-21 | 2020-09-17 | ローム アンド ハース カンパニーRohm And Haas Company | ポリ(メチルメタクリレート)樹脂組成物 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110684155A (zh) * | 2018-07-04 | 2020-01-14 | 中国石油天然气股份有限公司 | 丙烯酸酯类抗冲改性剂的制备方法及由其制备的丙烯酸酯类树脂 |
KR102363986B1 (ko) | 2018-11-16 | 2022-02-16 | 주식회사 엘지화학 | 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 |
WO2020101342A1 (ko) * | 2018-11-16 | 2020-05-22 | 주식회사 엘지화학 | 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5182339A (en) * | 1974-12-27 | 1976-07-19 | Mitsubishi Rayon Co | Enkabinirukeijushisoseibutsu |
JPH08100095A (ja) * | 1994-09-08 | 1996-04-16 | Rohm & Haas Co | 耐衝撃性が改良されたポリ塩化ビニル |
JPH11209545A (ja) * | 1997-12-30 | 1999-08-03 | Rohm & Haas Co | 改良された低温融解を示す耐衝撃性改良ポリ(塩化ビニル) |
JP2005515280A (ja) * | 2002-01-25 | 2005-05-26 | エルジー ケミカル エルティーディー. | 多段重合により製造されたアクリル系強度改質剤及びその製造方法 |
JP2006249307A (ja) * | 2005-03-11 | 2006-09-21 | Mitsubishi Rayon Co Ltd | グラフト共重合体、樹脂組成物および成形品 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4195134A (en) * | 1978-12-21 | 1980-03-25 | Gaf Corporation | Polyester resin with improved retention of properties |
CN1186822A (zh) * | 1996-12-30 | 1998-07-08 | 罗姆和哈斯公司 | 具有改进的低温熔融性的冲击改性的聚氯乙烯 |
EP0850740B1 (en) * | 1996-12-30 | 2001-08-22 | Rohm And Haas Company | Impact-modified poly(vinyl chloride) exhibiting improved low-temperature fusion |
KR100428637B1 (ko) | 2000-12-13 | 2004-04-30 | 주식회사 엘지화학 | 아크릴계 충격보강제의 제조방법 |
KR100548630B1 (ko) | 2003-09-04 | 2006-01-31 | 주식회사 엘지화학 | 아크릴계 공중합체 조성물, 이를 제조하는 방법 및 이를포함하는 염화비닐계 수지 조성물 |
KR100548626B1 (ko) | 2003-10-29 | 2006-01-31 | 주식회사 엘지화학 | 고무라텍스 및 이의 제조방법 |
BRPI0716858A2 (pt) | 2006-09-20 | 2013-10-01 | Basf Se | uso de dispersÕes polimÉricas, e, mÉtodo para melhorar a resistÊncia Às manchas d´Água precoces de revestimentos de substratos |
BR112013000373A2 (pt) | 2010-07-08 | 2021-03-09 | Dow Global Technologies Llc | Composição termoplástica, método para produzir uma composição termoplástica, artigo e método para formar um artigo |
-
2015
- 2015-12-17 US US15/536,145 patent/US10316126B2/en active Active
- 2015-12-17 JP JP2017531859A patent/JP6655621B2/ja active Active
- 2015-12-17 KR KR1020177017905A patent/KR102480143B1/ko active IP Right Grant
- 2015-12-17 EP EP15828592.4A patent/EP3259291B1/en active Active
- 2015-12-17 CN CN201580066997.3A patent/CN107001543B/zh active Active
- 2015-12-17 BR BR112017012913-2A patent/BR112017012913B1/pt active IP Right Grant
- 2015-12-17 WO PCT/US2015/066230 patent/WO2016106055A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5182339A (en) * | 1974-12-27 | 1976-07-19 | Mitsubishi Rayon Co | Enkabinirukeijushisoseibutsu |
JPH08100095A (ja) * | 1994-09-08 | 1996-04-16 | Rohm & Haas Co | 耐衝撃性が改良されたポリ塩化ビニル |
JPH11209545A (ja) * | 1997-12-30 | 1999-08-03 | Rohm & Haas Co | 改良された低温融解を示す耐衝撃性改良ポリ(塩化ビニル) |
JP2005515280A (ja) * | 2002-01-25 | 2005-05-26 | エルジー ケミカル エルティーディー. | 多段重合により製造されたアクリル系強度改質剤及びその製造方法 |
JP2006249307A (ja) * | 2005-03-11 | 2006-09-21 | Mitsubishi Rayon Co Ltd | グラフト共重合体、樹脂組成物および成形品 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020528094A (ja) * | 2017-07-21 | 2020-09-17 | ローム アンド ハース カンパニーRohm And Haas Company | ポリ(メチルメタクリレート)樹脂組成物 |
JP7305615B2 (ja) | 2017-07-21 | 2023-07-10 | ローム アンド ハース カンパニー | ポリ(メチルメタクリレート)樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP3259291A1 (en) | 2017-12-27 |
EP3259291B1 (en) | 2021-07-14 |
CN107001543A (zh) | 2017-08-01 |
KR102480143B1 (ko) | 2022-12-21 |
BR112017012913B1 (pt) | 2022-04-19 |
BR112017012913A2 (pt) | 2018-03-13 |
US20170362367A1 (en) | 2017-12-21 |
US10316126B2 (en) | 2019-06-11 |
WO2016106055A1 (en) | 2016-06-30 |
JP6655621B2 (ja) | 2020-02-26 |
KR20170101220A (ko) | 2017-09-05 |
CN107001543B (zh) | 2019-10-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3723576B2 (ja) | 低いヘイズ値を有する熱可塑性の成形用材料 | |
JP6655621B2 (ja) | 耐衝撃性改良剤及びそれを含むポリマー組成物 | |
JP2000290321A (ja) | プラスチゾル製造用のコポリマー及びその使用 | |
CN102807721B (zh) | 具有优异的抗冲击强度和透明度的用于聚甲基丙烯酸甲酯树脂的抗冲改性剂及其制备方法 | |
JP6247317B2 (ja) | Pvcのグラフト共重合体由来の透明物品 | |
JP6259837B2 (ja) | Pvcのグラフト共重合体由来の透明物品 | |
JP3198075B2 (ja) | 多層構造アクリル重合体、およびそれを用いたメタクリル樹脂組成物 | |
JP6333295B2 (ja) | Pvcのグラフト共重合体由来の可塑剤フリー物品 | |
US4035443A (en) | Polyvinyl chloride resin composition having transparency, high gloss, impact and weather resistance | |
JP7227213B2 (ja) | 耐衝撃性改良剤、それを製造する方法及びそれを含むポリマー組成物 | |
JP2018537567A (ja) | 潤滑性を有する溶融強度加工助剤として多段コポリマーを含有する熱可塑性組成物 | |
JPH02225559A (ja) | 多相耐衝撃性改良剤を内部に有するポリカーボネート組成物 | |
JPH0524926B2 (ja) | ||
CN107001534B (zh) | 用于制备(甲基)丙烯酸酯添加剂的方法,改善聚烯烃的抗下垂性的方法和抗下垂聚烯烃 | |
JPS6272710A (ja) | アクリル酸エステル系ポリマ−コンポジツトの製造法 | |
JPS6354017B2 (ja) | ||
JPS58213009A (ja) | 架橋塩化ビニル樹脂の製法 | |
JPH1180282A (ja) | 塩化ビニル樹脂組成物およびその製造法 | |
JP2006083332A (ja) | 塩化ビニル系共重合樹脂及びその製造方法並びにその樹脂組成物 | |
JP2002128979A (ja) | 塩化ビニル系樹脂、その製造方法及び成形体 | |
JPH064744B2 (ja) | 塩化ビニル系樹脂組成物 | |
JPH08337622A (ja) | 合成樹脂成形品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20170628 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20170920 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20181029 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190909 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190912 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20191209 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200109 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200203 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6655621 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |