JP2017043998A - Resin foam buried body - Google Patents

Resin foam buried body Download PDF

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JP2017043998A
JP2017043998A JP2015168142A JP2015168142A JP2017043998A JP 2017043998 A JP2017043998 A JP 2017043998A JP 2015168142 A JP2015168142 A JP 2015168142A JP 2015168142 A JP2015168142 A JP 2015168142A JP 2017043998 A JP2017043998 A JP 2017043998A
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foamed resin
embedded body
particles
resin foam
resin embedded
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JP6555686B2 (en
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直人 松岡
Naoto Matsuoka
直人 松岡
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Kumagai Gumi Co Ltd
Fatec Co Ltd
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Kumagai Gumi Co Ltd
Fatec Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a resin foam buried body capable of effectively preventing generation of foam from the resin foam buried body.SOLUTION: Polyisocyanate as a permeation type adhesive 13 is impregnated up to the depth of D=3 mm-10 mm from a surface 10a of a resin foam buried body 10 between particles 11 of the resin foam buried body 10 constituted of styrene foam and buried in a slab composed of reinforced-concrete, and generation of foam from the surface of the resin foam buried body 10 is prevented by blocking up a passage of air of existing in a clearance 12 between the particles 11 of the resin foam buried body 10.SELECTED DRAWING: Figure 1

Description

本発明は、中空コンクリートスラブ工法において、スラブ内に埋設されて発泡樹脂埋設体に関するものである。   The present invention relates to a foamed resin embedded body embedded in a slab in a hollow concrete slab method.

鉄筋コンクリートから成るスラブ内にポリスチレン等の発泡樹脂から成るブロック(以下、発泡樹脂埋設体という)を埋設した中空コンクリートスラブは、従来のスラブに対して高い剛性を有し、かつ、遮音性能にも優れるとともに、小梁のない広い区間を確保できることから、近年、広く用いられるようになってきている(例えば、特許文献1参照)。   A hollow concrete slab in which a block made of foamed resin such as polystyrene (hereinafter referred to as foamed resin embedded body) is embedded in a slab made of reinforced concrete has higher rigidity than conventional slabs and has excellent sound insulation performance. At the same time, since a wide section without a small beam can be secured, it has been widely used in recent years (see, for example, Patent Document 1).

ところで、コンクリート打設後には、周囲のコンクリートの上下の圧力差により、発泡樹脂埋設体内部の空気が押し出され、気泡として外部に出てくるため、コンクリート表面に気泡痕が残り、その結果、残留した気泡痕から水が浸入して、コンクリートの強度が低下するおそれがあった。
上記の特許文献1では、発泡樹脂埋設体の表面に、ポリエチレンやポリプロピレン等のポリオレフィン系樹脂から成る気密性の高い合成樹脂層を形成することで、気泡の発生を抑制するようにしている(例えば、特許文献1参照)。
By the way, after the concrete is placed, the air inside the foamed resin embedded body is pushed out by the pressure difference between the surrounding concrete and comes out as air bubbles, leaving air bubble marks on the concrete surface. There was a risk that the water might infiltrate from the bubble marks and the strength of the concrete would decrease.
In Patent Document 1 described above, the formation of bubbles is suppressed by forming a highly airtight synthetic resin layer made of a polyolefin-based resin such as polyethylene or polypropylene on the surface of the foamed resin embedded body (for example, , See Patent Document 1).

特開2006−322136号公報JP 2006-322136 A

しかしながら、上記従来の方法では、形成する合成樹脂層の厚さにムラがあったり、表面が傷付いたりして発泡樹脂の一部が表面に露出してしまった場合には、露出している部分からコンクリート内に気泡が出てきてしまうため、合成樹脂層の厚さをある程度(例えば、0.5mm程度)以上の厚さにする必要があった。
そのため、発泡樹脂埋設体へ塗布する合成樹脂の量が膨大になってしまっていた。
However, in the above conventional method, when the thickness of the synthetic resin layer to be formed is uneven or the surface is scratched and part of the foamed resin is exposed on the surface, it is exposed. Since air bubbles emerge from the portion into the concrete, it is necessary to make the thickness of the synthetic resin layer a certain level (for example, about 0.5 mm) or more.
Therefore, the amount of the synthetic resin applied to the foamed resin embedded body has become enormous.

本発明は、従来の問題点に鑑みてなされたもので、発泡樹脂埋設体からの気泡の発生を効果的に防止できることのできる発泡樹脂埋設体を提供することを目的とする。   This invention is made | formed in view of the conventional problem, and it aims at providing the foaming resin embedding body which can prevent generation | occurrence | production of the bubble from a foaming resin embedding body effectively.

本発明者は、鋭意検討の結果、気泡は、発泡樹脂の粒子内に存在する空気ではなく、粒子間の空隙に存在する空気が、空隙を通って発泡樹脂埋設体表面に押し出されることが原因で発生するので、粒子間に浸透型接着剤を含浸させて空隙を塞ぐようにすれば、少ない塗布量で、気泡の発生を確実に防止できることを見出し本発明に至ったものである。
すなわち、本発明は、鉄筋コンクリートから成るスラブ内に埋設される発泡樹脂埋設体であって、前記発泡樹脂埋設体の粒子間に浸透型接着剤が含浸されていることを特徴とするものである。
これにより、気泡発生の原因となるる空気の通路が、粒子間に浸透した浸透型接着剤により塞がれるので、空気が発泡樹脂埋設体表面に押し出されることを効果的にかつ確実に防止することができる。
また、浸透型接着剤は、粒子間に含浸されていればよく、発泡樹脂埋設体の表面を覆う必要がないので、少ない塗布量で、気泡の発生を防止することができる。
また、前記発泡樹脂埋設体を発泡スチロールから構成し、前記浸透型接着剤をポリイソシアネートとしたので、浸透型接着剤を発泡樹脂埋設体の粒子間へ速やかにかつ確実に含浸させることができる。
また、前記ポリイソシアネートを、前記発泡スチロールの表面から少なくとも3mm以上の深さまで含浸させたので、気泡の発生を確実に防止することができる。
As a result of intensive studies, the inventor found that the bubbles are not the air present in the foamed resin particles, but the air present in the voids between the particles is pushed out to the surface of the foamed resin embedded body through the voids. Thus, the present inventors have found that the generation of bubbles can be reliably prevented with a small amount of application by impregnating a permeable adhesive between the particles to close the voids.
That is, the present invention is a foamed resin embedded body embedded in a slab made of reinforced concrete, wherein a penetrating adhesive is impregnated between particles of the foamed resin embedded body.
As a result, the air passage that causes the generation of bubbles is blocked by the permeable adhesive that has penetrated between the particles, so that the air is effectively and reliably prevented from being pushed out to the surface of the foamed resin embedded body. be able to.
Moreover, since the penetration type | mold adhesive should just be impregnated between particle | grains and it is not necessary to cover the surface of a foaming resin embedding body, generation | occurrence | production of a bubble can be prevented with a small application amount.
Further, since the foamed resin embedded body is made of foamed polystyrene and the permeable adhesive is polyisocyanate, the permeable adhesive can be impregnated quickly and reliably between the particles of the foamed resin embedded body.
In addition, since the polyisocyanate is impregnated to a depth of at least 3 mm or more from the surface of the expanded polystyrene, the generation of bubbles can be reliably prevented.

なお、前記発明の概要は、本発明の必要な全ての特徴を列挙したものではなく、これらの特徴群のサブコンビネーションもまた、発明となり得る。   The summary of the invention does not list all necessary features of the present invention, and sub-combinations of these feature groups can also be the invention.

本発明の実施の形態に係わる発泡樹脂埋設体の模式図である。It is a schematic diagram of the foaming resin embedding body concerning embodiment of this invention. 発泡樹脂埋設体の設置例を示す図である。It is a figure which shows the example of installation of a foaming resin embedding body. 従来の発泡樹脂埋設体の模式図である。It is a schematic diagram of the conventional foaming resin embedding body.

図1(a),(b)は、本実施の形態に係わる発泡樹脂埋設体10の模式図で、(a)は斜視図、(b)図は縦断面図である。
本例の発泡樹脂埋設体10は、発泡樹脂から成るブロックの上面10a及び4つの側面10bに、浸透性接着剤を塗布し、発泡樹脂の粒子11間の隙間12に浸透性接着剤13を含浸させたもので、底面10cには浸透性接着剤13を塗布していない。なお、符号10hは位置決め用の貫通孔である。
発泡樹脂としては、発泡スチロールが好適に用いられ、浸透性接着剤13としては、ポリイソシアネートが好適に用いられる。
ポリイソシアネートは、粘度が低くかつ硬化するまでの時間が長い(塗布後約3日間は乾かない)ので、塗布後には、発泡樹脂埋設体10の表面から内部の粒子11間の隙間12に深く浸透して、粒子11間を接着固定することができる。
これにより、空気の通路である粒子11間の隙間12が硬化した浸透性接着剤13により塞がるので、図1(b)の白丸で示す、粒子11間の隙間12に存在する空気が発泡樹脂埋設体10の表面から押し出されることを抑制することができる。
特に、発泡樹脂が発泡スチロールの場合には、他の発泡樹脂に比較して浸透力が大きいので、発泡樹脂と浸透性接着剤の組み合わせとしては、発泡スチロールとポリイソシアネートを組み合わせることが好ましい。
なお、ポリイソシアネートは、そのまま、もしくは、酢酸エチルやMEKなどのウレタン用薄め液で、粘度を調整したものを塗布する。また、塗布方法としては、コーター、ハケ、ディッピングなどによる塗布方法が用いられるが、本例では、ハケを用いた。
1A and 1B are schematic views of a foamed resin embedded body 10 according to the present embodiment, in which FIG. 1A is a perspective view and FIG. 1B is a longitudinal sectional view.
In the foamed resin embedded body 10 of this example, a permeable adhesive is applied to the upper surface 10a and the four side surfaces 10b of the block made of the foamed resin, and the permeable adhesive 13 is impregnated in the gaps 12 between the particles 11 of the foamed resin. The permeable adhesive 13 is not applied to the bottom surface 10c. Reference numeral 10h denotes a positioning through hole.
As the foamed resin, polystyrene foam is preferably used, and as the permeable adhesive 13, polyisocyanate is suitably used.
Since polyisocyanate has a low viscosity and a long time to cure (it does not dry for about 3 days after application), after application, the polyisocyanate penetrates deeply from the surface of the foamed resin embedded body 10 into the gaps 12 between the internal particles 11. Thus, the particles 11 can be bonded and fixed.
As a result, the gaps 12 between the particles 11 that are air passages are closed by the cured permeable adhesive 13, so that the air present in the gaps 12 between the particles 11 shown by white circles in FIG. Extrusion from the surface of the body 10 can be suppressed.
In particular, when the foamed resin is a polystyrene foam, the penetrating power is larger than that of other foamed resins. Therefore, it is preferable to combine foamed polystyrene and polyisocyanate as a combination of the foamed resin and the permeable adhesive.
The polyisocyanate is applied as it is or with a viscosity-adjusted urethane thinning solution such as ethyl acetate or MEK. As a coating method, a coating method using a coater, brush, dipping, or the like is used. In this example, a brush is used.

硬化後のポリイソシアネートの含浸深さDとしては、3mm〜10mmとすることが好ましい。
これは、含浸深さDが3mm以上であれば、発泡樹脂埋設体10の表面付近の粒子11間の隙間12を全て塞ぐことができるので、空気が発泡樹脂埋設体10の表面から押し出されることを確実に抑制することができるからである。
また、含浸深さDが10mmを超えても、浸透性接着剤13の塗布量が増えるだけで、気泡抑制効果があまり変わらないので、含浸深さDとしては10mm以下で十分である。
一方、浸透性接着13剤を含浸させない場合には、図2に示すように、白丸で示す、粒子11間の隙間12にある空気が、隙間12を通って発泡樹脂埋設体10の表面から押し出されるので、従来のように、発泡樹脂埋設体10の表面に気密性のある合成樹脂層50を形成しないと、気泡の発生を抑制することが困難である。
このように、内部で気泡抑制する方が、従来のように表面で気泡抑制するよりも少ない塗布量で高い気泡抑制効果を得ることができる。
The impregnation depth D of the polyisocyanate after curing is preferably 3 mm to 10 mm.
If the impregnation depth D is 3 mm or more, all the gaps 12 between the particles 11 near the surface of the foamed resin embedded body 10 can be closed, so that air is pushed out from the surface of the foamed resin embedded body 10. It is because it can suppress reliably.
Further, even if the impregnation depth D exceeds 10 mm, only the amount of the permeable adhesive 13 applied increases, and the bubble suppression effect does not change much, so that the impregnation depth D is 10 mm or less.
On the other hand, when the permeable adhesive 13 agent is not impregnated, as shown in FIG. 2, the air in the gaps 12 between the particles 11 indicated by white circles is pushed out from the surface of the foamed resin embedded body 10 through the gaps 12. Therefore, unless the synthetic resin layer 50 having airtightness is formed on the surface of the foamed resin embedded body 10 as in the prior art, it is difficult to suppress the generation of bubbles.
As described above, the method of suppressing bubbles inside can obtain a higher bubble suppression effect with a smaller coating amount than the conventional method of suppressing bubbles on the surface.

図3(a),(b)に示すように、発泡樹脂埋設体10は、スラブ型枠1上にスラブ型枠1から所定の間隔をおいて格子状に結合された下側鉄筋2上に、公知の方法で位置決めされ配置される。位置決め方法としては、例えば、下側鉄筋2に位置決め用突起3を設けるとともに、スラブ型枠1に上部に突出するロッド4を設け、発泡樹脂埋設体10の中心に、ロッド4を通すための貫通孔10hを設け、突起3で発泡樹脂埋設体10を下側から支持するとともに、ロッド4の上端にて、押え板材5を介して、ロッド4と発泡樹脂埋設体10とを連結して発泡樹脂埋設体10の浮きを防止するなどすればよい。
発泡樹脂埋設体10の設置後には、上側鉄筋6を配置し、コンクリートを打設して、中空コンクリートスラブを構築する。
本例では、スラブの遮音性能を考慮して、図1(a)の斜め上に向かう矢印で示す縦方向に垂直な断面が波状で、左から右に向かう矢印で示す横に垂直な断面が長方形状であるようなブロック形状としたが、ブロック形状としては、球状、あるいは、サイコロ状のものを用いてもよい。なお、位置決め方法は、ブロック形状により適宜変更すればよい。
As shown in FIGS. 3 (a) and 3 (b), the foamed resin embedded body 10 is placed on the lower rebar 2 connected in a grid pattern from the slab mold 1 at a predetermined interval on the slab mold 1. And is positioned and arranged in a known manner. As a positioning method, for example, a positioning projection 3 is provided on the lower rebar 2, a rod 4 protruding upward is provided on the slab mold 1, and a penetration for passing the rod 4 through the center of the foamed resin embedded body 10 is performed. A hole 10h is provided, and the foamed resin embedded body 10 is supported from below by the protrusion 3, and at the upper end of the rod 4, the rod 4 and the foamed resin embedded body 10 are connected via the presser plate material 5 to provide the foamed resin. What is necessary is just to prevent the embedded body 10 from floating.
After the foamed resin embedded body 10 is installed, the upper rebar 6 is arranged, concrete is placed, and a hollow concrete slab is constructed.
In this example, in consideration of the sound insulation performance of the slab, the vertical cross section indicated by the arrow heading diagonally upward in FIG. 1A is wavy and the horizontal vertical cross section indicated by the arrow heading from left to right is Although the block shape is rectangular, the block shape may be spherical or dice. Note that the positioning method may be appropriately changed depending on the block shape.

[実験例1]
ポリイソシアネートの気泡抑制効果を表1に示す。
本実験では、発泡樹脂埋設体を構成する樹脂としては発泡スチロールを用いるとともに、表1の薬剤(浸透型接着剤)として、ポリイソシアネートを主成分とする1液湿気硬化型接着剤ボンドKU662(商品名;コニシ株式会社製)を用いた。
ボンドKU662の粘度は100〜250mPa・s、比重は1.23である。
また、発泡スチロールへのポリイソシアネートの浸透深さは4mm〜10mmである。
気泡抑制効果は、30℃及び40℃の温水に、それぞれ1分間入れたときの気泡の発生数で評価した。
表1に示すように、薬剤を塗布していない発泡樹脂埋設体では、温水温度が30℃の場合には35個、40℃の場合には109個の気泡が発生した。
これに対して、上面及び側面に薬剤を塗布した発泡樹脂埋設体では、気泡発生数が、温水温度が30℃の場合には3個、40℃の場合には20個と、大幅に減少していることから、発泡樹脂埋設体の粒子間に浸透型接着剤を含浸させることで、気泡の発生を大幅に低減できることが確認された。
なお、全面に薬剤を塗布したものでは、気泡の発生は更に低減していることがわかる。
[Experiment 1]
Table 1 shows the bubble suppression effect of the polyisocyanate.
In this experiment, polystyrene foam is used as the resin constituting the foamed resin embedded body, and the one-component moisture curable adhesive bond KU662 (trade name) mainly composed of polyisocyanate is used as the agent (penetrating adhesive) in Table 1. ; Manufactured by Konishi Co., Ltd.).
The viscosity of the bond KU662 is 100 to 250 mPa · s, and the specific gravity is 1.23.
Moreover, the penetration depth of the polyisocyanate into the polystyrene foam is 4 mm to 10 mm.
The bubble suppression effect was evaluated by the number of bubbles generated when each was placed in warm water at 30 ° C. and 40 ° C. for 1 minute.
As shown in Table 1, in the foamed resin embedded body to which no chemical was applied, 35 bubbles were generated when the hot water temperature was 30 ° C. and 109 bubbles were generated when the temperature was 40 ° C.
On the other hand, in the foamed resin embedded body in which the medicine is applied to the upper surface and the side surface, the number of bubbles generated is greatly reduced to 3 when the hot water temperature is 30 ° C. and 20 when the hot water temperature is 40 ° C. Therefore, it was confirmed that the generation of bubbles can be significantly reduced by impregnating the permeable adhesive between the particles of the foamed resin embedded body.
In addition, it turns out that generation | occurrence | production of a bubble is further reduced in what apply | coated the chemical | medical agent to the whole surface.

[実験例2]
本発明による発泡樹脂埋設体と、表面に合成樹脂層が形成された従来の発泡樹脂埋設体との気泡抑制効果を比較した結果を表2に示す。
本発明による発泡樹脂埋設体は、発泡スチロールの上面と側面とにポリイソシアネートを塗布して含浸させたもので、ポリイソシアネートの浸透深さは4mm〜10mmである。
また、従来の発泡樹脂埋設体は、発泡スチロールの上面と側面とにそれぞれウレタン樹脂及びアクリル樹脂塗布して合成樹脂層を形成したものである。
なお、合成樹脂層が形成された従来の発泡樹脂埋設体では、発泡スチロール粒子間の空隙への合成樹脂の浸透は皆無であった。
気泡抑制効果は、30℃及び40℃の温水に、本発明による発泡樹脂埋設体と従来の発泡樹脂埋設体とを、それぞれ1分間入れたときの気泡の発生数で評価した。
表2に示すように、合成樹脂としてウレタン樹脂を用いた場合には、気泡の発生数が温水温度が30℃の場合には1個、40℃の場合には73個で、アクリル樹脂を用いた場合には、温水温度が30℃の場合には0個、40℃の場合には42個であった。しかしながら、表面(上面と側面)の合成樹脂層を除去すると、ウレタン樹脂の場合もアクリル樹脂の場合も、樹脂気泡の発生数が大幅に増加していることがわかる。合成樹脂層を除去した場合の気泡の発生数は、前記の表1に示した薬剤を塗布していない発泡樹脂埋設体とほぼ同等である。
一方、本発明による発泡樹脂埋設体では、発泡樹脂埋設体の表面(上面と側面)のポリイソシアネートをヤスリで除去して、発泡スチロールの面を表面に露出させても、気泡の発生数は、温水温度が30℃の場合には0個、40℃の場合には22個と、前記の表1に示した上面と側面とにポリイソシアネートを塗布して含浸させたものとほぼ同等の気泡抑制効果があることがわかった。
これにより、気泡の発生は、発泡樹脂埋設体の粒子間の隙間に存在する空気が、周囲の圧力差により発泡樹脂埋設体表面から外に表面に押し出されるという気泡発生の原理だけでなく、発泡樹脂埋設体の粒子間の隙間に浸透型接着剤を含浸させて空気の通路を塞ぐことで、気泡の発生を抑制しているという、浸透型接着剤の機能についても確認された。
[Experiment 2]
Table 2 shows the results of comparing the bubble suppression effect of the foamed resin embedded body according to the present invention and the conventional foamed resin embedded body having a synthetic resin layer formed on the surface thereof.
The foamed resin embedded body according to the present invention is obtained by applying and impregnating polyisocyanate on the top and side surfaces of a polystyrene foam, and the penetration depth of the polyisocyanate is 4 mm to 10 mm.
Moreover, the conventional foaming resin embedding body forms a synthetic resin layer by apply | coating a urethane resin and an acrylic resin to the upper surface and side surface of a polystyrene foam, respectively.
In addition, in the conventional foamed resin embedding body in which the synthetic resin layer was formed, there was no penetration of the synthetic resin into the voids between the polystyrene foam particles.
The bubble suppression effect was evaluated by the number of bubbles generated when the foamed resin embedded body according to the present invention and the conventional foamed resin embedded body were respectively placed in warm water at 30 ° C. and 40 ° C. for 1 minute.
As shown in Table 2, when a urethane resin is used as the synthetic resin, the number of bubbles generated is 1 when the hot water temperature is 30 ° C. and 73 when 40 ° C., and acrylic resin is used. When the temperature was 30 ° C., the temperature was 0, and when the temperature was 40 ° C., the number was 42. However, when the synthetic resin layer on the surface (upper surface and side surface) is removed, it can be seen that the number of resin bubbles generated is greatly increased in both the urethane resin and the acrylic resin. The number of bubbles generated when the synthetic resin layer is removed is substantially the same as the foamed resin embedded body to which the chemicals shown in Table 1 are not applied.
On the other hand, in the foamed resin embedded body according to the present invention, even if the polyisocyanate on the surface (upper surface and side surface) of the foamed resin embedded body is removed with a file and the surface of the expanded polystyrene is exposed to the surface, When the temperature is 30 ° C., the number of bubbles is 0, and when the temperature is 40 ° C., the number of bubbles is 22; I found out that
As a result, the generation of bubbles is not limited to the principle of bubble generation in which the air existing in the gaps between the particles of the foamed resin embedded body is pushed out of the surface of the foamed resin embedded body due to the pressure difference of the surroundings. It was also confirmed that the function of the permeable adhesive was to suppress the generation of bubbles by impregnating the permeable adhesive in the gaps between the particles of the resin embedded body to block the air passage.

10 発泡樹脂埋設体、10a 上面、10b 側面、10c 底面、
10h 位置決め用の貫通孔、11 発泡樹脂の粒子、12 隙間、
13 浸透性接着剤。
10 Foamed resin embedded body, 10a upper surface, 10b side surface, 10c bottom surface,
10h positioning through-hole, 11 foamed resin particles, 12 gap,
13 Penetration adhesive.

Claims (3)

鉄筋コンクリートから成るスラブ内に埋設される発泡樹脂埋設体であって、
前記発泡樹脂埋設体の粒子間に浸透型接着剤が含浸されていることを特徴とする発泡樹脂埋設体。
A foamed resin embedded body embedded in a slab made of reinforced concrete,
A foamed resin embedded body, wherein a penetrating adhesive is impregnated between particles of the foamed resin embedded body.
前記発泡樹脂埋設体が発泡スチロールから構成され、
前記浸透型接着剤がポリイソシアネートであることを特徴とする請求項1に記載の発泡樹脂埋設体。
The foamed resin embedded body is composed of expanded polystyrene,
2. The foamed resin embedded body according to claim 1, wherein the permeable adhesive is polyisocyanate.
前記ポリイソシアネートが、前記発泡スチロールの表面から少なくとも3mm以上の深さまで含浸されていることを特徴とする請求項2に記載の発泡樹脂埋設体。   The foamed resin embedded body according to claim 2, wherein the polyisocyanate is impregnated to a depth of at least 3 mm or more from the surface of the polystyrene foam.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5398470A (en) * 1991-04-23 1995-03-21 Avi Alpenlandische Veredelungs-Industrie Gesellschaft M.B.H. Reinforcement body for a floor slab
JP2006322136A (en) * 2005-05-17 2006-11-30 Jsp Corp Foaming synthetic resin embedded body used for hollow concrete slab construction method
JP4136472B2 (en) * 2002-06-07 2008-08-20 三井化学ポリウレタン株式会社 Polyisocyanate for water-based coating agent and method for surface treatment of porous substrate using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5398470A (en) * 1991-04-23 1995-03-21 Avi Alpenlandische Veredelungs-Industrie Gesellschaft M.B.H. Reinforcement body for a floor slab
JP4136472B2 (en) * 2002-06-07 2008-08-20 三井化学ポリウレタン株式会社 Polyisocyanate for water-based coating agent and method for surface treatment of porous substrate using the same
JP2006322136A (en) * 2005-05-17 2006-11-30 Jsp Corp Foaming synthetic resin embedded body used for hollow concrete slab construction method

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