JP2016505700A - 発泡性ホットメルト接着剤組成物およびその使用 - Google Patents
発泡性ホットメルト接着剤組成物およびその使用 Download PDFInfo
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- JP2016505700A JP2016505700A JP2015555170A JP2015555170A JP2016505700A JP 2016505700 A JP2016505700 A JP 2016505700A JP 2015555170 A JP2015555170 A JP 2015555170A JP 2015555170 A JP2015555170 A JP 2015555170A JP 2016505700 A JP2016505700 A JP 2016505700A
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- foamed
- hot melt
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Abstract
Description
Claims (20)
- (a)約90から約99.9wt%のホットメルト接着剤と、
(b)約0.1から約10wt%の、剛性および弾性セグメントの交互ブロックを含有するブロックコポリマーと
(c)場合により、約0.05から約10wt%の発泡セル形成剤と
を含み、発泡性接着剤組成物の全重量が合計で100wt%である発泡性接着剤組成物であって、前記発泡性接着剤組成物の発泡時に、発泡した接着剤が約20から約80V/V%の体積パーセントを有する、発泡性接着剤組成物。 - ブロックコポリマーが、オレフィンブロックコポリマー、直鎖状ゴム系コポリマー、放射状ゴム系コポリマーおよびこれらの混合物からなる群から選択される、請求項1に記載の発泡性接着剤組成物。
- オレフィンブロックコポリマーが、ASTM D1238に従って測定される5g/10分以上のメルトインデックスと、100℃を超えるDSC融点とを有する、請求項1または2に記載の発泡性接着剤組成物。
- ゴム系コポリマーが、SIS、SES、SEBS、SBS、SIBS、SEPSおよびこれらの混合物からなる群から選択される、請求項1または2に記載の発泡性接着剤組成物。
- ホットメルト接着剤が、ポリマーならびに場合によりワックス、粘着付与剤、可塑剤および添加剤を含む、請求項1〜4に記載の発泡性接着剤組成物。
- ポリマーが、約5%から約60%の結晶化度範囲を有する、請求項5に記載の発泡性接着剤組成物。
- ポリマーが、非晶質αポリオレフィン、結晶性ポリオレフィン、エチレン酢酸ビニル、エチレン酢酸ブチル、プロピレン−ヘキセンコポリマー、エチレン−プロピレンコポリマーおよびこれらの混合物からなる群から選択される、請求項5または6に記載の発泡性接着剤組成物。
- ポリマーが、メタロセンまたは非メタロセン触媒を用いて調製される、請求項5〜7に記載の発泡性接着剤組成物。
- ホットメルト接着剤のポリマーの、ブロックコポリマーに対する比が、約20:1から2:1の範囲である、請求項1〜8に記載の発泡性接着剤組成物。
- 発泡体が、気体、発泡セル形成剤または複数のミクロスフェアを用いて生成される、請求項1〜9に記載の発泡性接着剤組成物。
- 発泡セル形成剤が、アゾジカルボンアミド、オキシビス(ベンゼンスルホニルヒドラジド)、トルエンスルホニルヒドラジド、ジフェニルスルホン−3,3’−ジスルホヒドラジド、トリヒドラジノトリアジン、p−トルエンスルホニルセミカルバジド、5−フェニルテトラゾール、無水イサト酸、炭酸水素ナトリウム、クエン酸およびこれらの混合物からなる群から選択される、請求項1〜10に記載の発泡性接着剤組成物。
- 発泡した接着剤が、約20から約80V/V%の体積V/V/%を有する、請求項1〜11に記載の発泡性接着剤組成物。
- 請求項1から12に記載の発泡した接着剤。
- ブロックコポリマーを用いていない発泡した接着剤組成物より50%速い硬化時間と50%高い接着性とを有する、請求項13に記載の発泡した接着剤。
- 請求項13または14に記載の発泡した接着剤を含む、物品。
- 段ボール箱、袋、本、グラフィックアート、トレーおよびカートン、シーラーまたは積層体である、請求項15に記載の物品。
- 発泡性接着剤組成物を発泡させる方法であって、
(a)ホットメルト接着剤と、剛性および弾性セグメントの交互ブロックを含有するブロックコポリマーとを含む発泡性接着剤組成物を調製するステップと、
(b)発泡性接着剤組成物を溶融状態に加熱するステップと、
(c)気体を、溶融した発泡性接着剤組成物中に機械的に混合して、マトリックス中に発泡体を生成するステップと、
(d)発泡した接着剤組成物を基材に塗布するステップと
を含む、方法。 - 発泡性接着剤組成物を発泡させる方法であって、
(a)ホットメルト接着剤と、剛性および弾性セグメントの交互ブロックを含有するブロックコポリマーと、発泡セル形成剤とを含む発泡性接着剤組成物を調製するステップと、
(b)発泡性接着剤組成物をT1に加熱するステップと、
(c)発泡性接着剤組成物をT2に加熱するステップであって、発泡セル形成剤がT1を超える温度で活性化され、これにより発泡性接着剤が発泡するステップと、
(d)発泡した接着剤組成物を基材に塗布するステップと
を含み、T2がT1よりも高い、方法。 - 発泡セル形成剤が、アゾジカルボンアミド、オキシビス(ベンゼンスルホニルヒドラジド)、トルエンスルホニルヒドラジド、5−フェニルテトラゾール、炭酸水素ナトリウム、クエン酸、アクリルコポリマーおよびこれらの混合物からなる群から選択される、請求項18に記載の発泡性接着剤組成物を発泡させる方法。
- 発泡性接着剤組成物を発泡させる方法であって、
(a)ホットメルト接着剤と、剛性および弾性セグメントの交互ブロックを含有するブロックコポリマーと、複数の膨張性ミクロスフェアとを含む発泡性接着剤組成物を調製するステップと、
(b)発泡性接着剤組成物をT2に加熱するステップであって、膨張性ミクロスフェアがT1を超える温度で活性化され、これにより発泡性接着剤が発泡するステップと、
(c)膨張したミクロスフェアを有する接着剤を基材に塗布するステップと
を含み、T2がT1より高く、T1において接着剤が本質的にゼロの膨張したミクロスフェアを含む、方法。
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PCT/US2013/078446 WO2014116395A1 (en) | 2013-01-24 | 2013-12-31 | Foamable hot melt adhesive compositions and use thereof |
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EP (1) | EP2948512B1 (ja) |
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US10336920B2 (en) | 2019-07-02 |
BR112015017383A2 (pt) | 2017-07-11 |
CN105308140B (zh) | 2019-11-05 |
JP6443634B2 (ja) | 2018-12-26 |
KR102181725B1 (ko) | 2020-11-24 |
EP2948512A1 (en) | 2015-12-02 |
RU2015135327A (ru) | 2017-03-03 |
KR20160006660A (ko) | 2016-01-19 |
CA2899313A1 (en) | 2014-07-31 |
CN105308140A (zh) | 2016-02-03 |
EP2948512B1 (en) | 2023-07-05 |
CA2899313C (en) | 2021-02-02 |
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