JP2016124839A - Solid powder cosmetic - Google Patents
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- JP2016124839A JP2016124839A JP2015000937A JP2015000937A JP2016124839A JP 2016124839 A JP2016124839 A JP 2016124839A JP 2015000937 A JP2015000937 A JP 2015000937A JP 2015000937 A JP2015000937 A JP 2015000937A JP 2016124839 A JP2016124839 A JP 2016124839A
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- 239000000843 powder Substances 0.000 title claims abstract description 42
- 239000002537 cosmetic Substances 0.000 title claims abstract description 41
- 239000007787 solid Substances 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 45
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
- 235000011837 pasties Nutrition 0.000 claims abstract description 6
- 241001237961 Amanita rubescens Species 0.000 claims description 6
- 210000004709 eyebrow Anatomy 0.000 claims description 6
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims description 4
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 claims description 4
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 235000019271 petrolatum Nutrition 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 3
- 239000004264 Petrolatum Substances 0.000 claims description 2
- 241000276425 Xiphophorus maculatus Species 0.000 claims description 2
- 229940066842 petrolatum Drugs 0.000 claims description 2
- 238000011161 development Methods 0.000 abstract description 23
- 238000004519 manufacturing process Methods 0.000 description 24
- 238000011156 evaluation Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 238000003825 pressing Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000010298 pulverizing process Methods 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000003892 spreading Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- -1 isostearyl Chemical group 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本願発明は、固形粉末化粧料に関するものであり、さらに詳しくは、塗布時の彩度・発色が高く、のびのなめらかな使用感を付与し、耐衝撃性に優れ、使用時にケーキングが起こらない固形粉末化粧料に関する。 The present invention relates to a solid powder cosmetic, and more specifically, a high degree of saturation and color development at the time of application, giving a smooth and smooth feeling of use, excellent impact resistance, and no caking during use. It relates to powder cosmetics.
従来から固形粉末化粧料としては、例えばアイシャドウやファンデーション等が知られている。固形粉末化粧料は主に色材を含む粉体や油剤で構成されており、様々な使用感や機能性の効果を得るために、これらの成分の種類や配合量の検討がなされている。その検討の中で、特にメイクアップ化粧料においては、塗布時の彩度・発色が高いこと、のびのなめらかさが重要である。また、携帯性がよいコンパクト容器に装着する化粧料であるため耐衝撃性にも優れる必要があるが、耐衝撃性を高めるために固形粉末化粧料の硬度を上げると使用時に化粧料の表面でケーキングが生じ易くなることが一般に知られている。そのため、耐衝撃性に優れ、なおかつ使用時にケーキングが起こらないことも重要な品質として求められている。 Conventionally, as a solid powder cosmetic, for example, eye shadow, foundation and the like are known. Solid powder cosmetics are mainly composed of powders and oils containing color materials, and in order to obtain various effects on use and functionality, the types and blending amounts of these components have been studied. Among these considerations, especially in makeup cosmetics, high saturation and color development at the time of application and smooth smoothness are important. In addition, since it is a cosmetic that can be attached to a compact container with good portability, it needs to have excellent impact resistance. However, if the hardness of the solid powder cosmetic is increased to increase the impact resistance, It is generally known that caking tends to occur. Therefore, it is required as an important quality that it is excellent in impact resistance and does not cause caking during use.
そこでこれまでは、塗布部位に高い彩度を付与するために、着色された、屈折率の異なる２種以上の高分子化合物を含む干渉繊維を配合した技術（特許文献１）、耐衝撃性に優れた固形粉末化粧料にするために、化粧料基材と薄片状シリカ分散液を混合した技術（特許文献２）が知られている。 So far, in order to impart high saturation to the application site, a technique (patent document 1) in which colored interference fibers containing two or more kinds of polymer compounds having different refractive indexes are blended and impact resistance is improved. In order to make an excellent solid powder cosmetic, a technique (Patent Document 2) in which a cosmetic base material and a flaky silica dispersion are mixed is known.
しかしながら、上記記載の方法でも、使用感と機能性の両立は難しく、いまだに満足のいく固形粉末化粧料を得られていない。 However, even with the above-described method, it is difficult to achieve both usability and functionality, and a satisfactory solid powder cosmetic has not yet been obtained.
本願発明は、かかる事情を鑑みてなされたものであり、その目的は、塗布時の彩度・発色が高く、のびのなめらかな使用感を付与し、耐衝撃性に優れ、使用時にケーキングが起こらない固形粉末化粧料を提供することにある。 The present invention has been made in view of such circumstances, and its purpose is to provide high saturation and color development at the time of application, to give a smooth and smooth feeling of use, excellent impact resistance, and caking during use. There is no solid powder cosmetic to provide.
かかる課題を解決するために、本願発明者らは、鋭意研究を行った結果、下記成分（ａ）〜（ｃ）を含有することによって、塗布時の彩度・発色が高く、のびのなめらかな使用感を付与し、耐衝撃性に優れ、使用時にケーキングが起こらない固形粉末化粧料を提供することができることを見出した。すなわち本願発明は、次の成分（ａ）〜（ｃ）を含有することを特徴とする固形粉末化粧料である。（ａ）酸化鉄４０重量％以上、（ｂ）非晶質板状シリカ、（ｃ）３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油及び／又は２５℃においてペースト状である油性成分から選ばれる１種又は２種以上。 In order to solve such problems, the inventors of the present invention have conducted intensive research, and as a result, by containing the following components (a) to (c), the saturation and color development at the time of coating are high, and it is smooth and smooth. It has been found that a solid powder cosmetic that gives a feeling of use, is excellent in impact resistance, and does not cause caking during use can be provided. That is, this invention is solid powder cosmetics characterized by containing the following component (a)-(c). (A) Iron oxide 40% by weight or more, (b) amorphous plate-like silica, (c) a hydrocarbon oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s and / or a paste at 25 ° C. 1 type (s) or 2 or more types chosen from an oil-based component.
以下、本願発明について記述する。 Hereinafter, the present invention will be described.
本願発明においては、酸化鉄及び非晶質板状シリカを含む粉体を均一に混合した混合粉体物に、油性成分を加えて均一に混合し、金皿にプレスすることにより、固形粉末化粧料を構成する。また、混合粉体物と油性成分とを揮発性溶媒又は水に添加してスラリー化し、スラリーの状態で金皿に充填した後、真空吸引などで溶媒を除去しながらプレスし、乾燥させることにより、固形粉末化粧料を構成しても良い。 In the present invention, a solid powder makeup is obtained by adding an oil component to a mixed powder obtained by uniformly mixing powder containing iron oxide and amorphous plate-like silica, and mixing the mixture uniformly and pressing it into a metal pan. Make up the fee. Also, by adding the mixed powder and oil component to a volatile solvent or water to make a slurry, filling the metal plate in the slurry state, pressing while removing the solvent by vacuum suction etc., and drying A solid powder cosmetic may be constituted.
本願発明の前記成分（ａ）である酸化鉄は、本願発明において固形粉末化粧料の色材として含有されており、塗布時に高い彩度・発色の効果を有する。 The iron oxide which is the component (a) of the present invention is contained as a coloring material for solid powder cosmetics in the present invention, and has a high chroma / coloring effect when applied.
本願発明の前記成分（ａ）である酸化鉄は、酸化鉄であれば特に限定されないが、黒酸化鉄、黄酸化鉄、赤酸化鉄等を用いることができる。また、これらは必要に応じて１種又は２種以上を用いることができる。さらには、シリコーン等で表面処理されていても良い。 The iron oxide as the component (a) of the present invention is not particularly limited as long as it is iron oxide, but black iron oxide, yellow iron oxide, red iron oxide, and the like can be used. Moreover, these can use 1 type (s) or 2 or more types as needed. Furthermore, it may be surface-treated with silicone or the like.
本願発明の前記成分（ａ）である酸化鉄の含有量は、特に限定されないが、塗布時に高い彩度・発色の効果を有する点で４０重量％以上であり、好ましくは５０〜７０重量％である。前記成分（ａ）が４０重量％未満では塗布時の彩度・発色が低くなり、また、７０重量％を超えるとケーキングを生じる場合もある。 The content of the iron oxide which is the component (a) of the present invention is not particularly limited, but is 40% by weight or more, preferably 50 to 70% by weight in terms of having a high chroma / coloring effect at the time of application. is there. If the component (a) is less than 40% by weight, the saturation and color development at the time of application are low, and if it exceeds 70% by weight, caking may occur.
本願発明の前記成分（ｂ）である非晶質板状シリカは、本願発明において塗布時に酸化鉄の高い彩度・発色を保ったまま、のびのなめらかさを付与し、また耐衝撃性及び使用時のケーキングを防ぐ効果を有する。 The amorphous plate-like silica which is the component (b) of the invention of the present application imparts a smoothness of stretch while maintaining high chroma and coloration of iron oxide at the time of application in the present invention, and also has impact resistance and use. It has the effect of preventing time caking.
本願発明の前記成分（ｂ）である非晶質板状シリカは、葉片状（薄片状）の非晶質含水二酸化ケイ素である。その中でも粘土鉱物を強度に酸処理することにより、粘土鉱物が有する葉片形態を保持したままシリカ成分を純粋に抽出した非晶質板状シリカが好ましく、さらには、含水二酸化ケイ素が極薄片状に積み重なり、厚さ０．５μｍ以下、面方向４〜３０μｍの葉片状の非晶質板状シリカが最も好ましい。 The amorphous plate-like silica which is the component (b) of the present invention is a leaf-like (flaky) amorphous hydrous silicon dioxide. Among them, amorphous plate-like silica obtained by purely extracting the silica component while retaining the leaf piece form possessed by the clay mineral by strongly acid-treating the clay mineral is preferable, and further, the hydrous silicon dioxide is in the form of ultrathin flakes. Most preferred is a leaf-like amorphous plate-like silica which is stacked and has a thickness of 0.5 μm or less and a surface direction of 4 to 30 μm.
本願発明の前記成分（ｂ）である非晶質板状シリカは通常化粧料に使用されるものであればいずれのものも使用することができる。市販品としては、例えば、シルリーフ（水澤化学工業社製）等が例示できる。 Any amorphous platy silica as the component (b) of the present invention can be used as long as it is usually used in cosmetics. Examples of commercially available products include Silleaf (manufactured by Mizusawa Chemical Industry Co., Ltd.).
本願発明の前記成分（ｂ）である非晶質板状シリカの含有量は、特に限定されないが、のびのなめらかさを付与し、耐衝撃性及びケーキングの無い効果を有する点で２〜２０重量％が好ましい。より好ましくは５〜１５重量％であり、さらに好ましくは８〜１２重量％の範囲である。また、前記成分（ｂ）が２重量％未満ではのびのなめらかさが低下する場合やケーキングが生じる場合がある。また、２０重量％を超えるとのびのなめらかさが低下する場合や耐衝撃性が低下する場合がある。 The content of the amorphous plate-like silica as the component (b) of the present invention is not particularly limited, but it imparts a smooth and smooth effect, and has an impact resistance and no caking effect in the range of 2 to 20 weights. % Is preferred. More preferably, it is 5-15 weight%, More preferably, it is the range of 8-12 weight%. On the other hand, when the component (b) is less than 2% by weight, the smoothness of the spread may be reduced or caking may occur. On the other hand, if it exceeds 20% by weight, the smoothness of the stretch may be reduced or the impact resistance may be lowered.
本願発明の前記成分（ｃ）である３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油及び／又は２５℃においてペースト状である油性成分の少なくとも１種は、のびのなめらかさを付与し、また耐衝撃性に優れた効果を発揮させるために用いる。 The component (c) of the present invention, which is a hydrocarbon oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s or more and / or an oily component that is pasty at 25 ° C., has a smooth and smooth texture. It is used for imparting and exhibiting an effect excellent in impact resistance.
３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油としては、特に限定されないが、重質流動イソパラフィン又はポリブテン等を用いることができる。また、これらは必要に応じて１種又は２種以上を用いることができる。 The hydrocarbon oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s or more is not particularly limited, and heavy fluid isoparaffin or polybutene can be used. Moreover, these can use 1 type (s) or 2 or more types as needed.
前述の重質流動イソパラフィン又はポリブテンとは、イソブテンとｎ−ブテンを共重合した後、水素添加して得られる側鎖を有する炭化水素油の混合物である。 The aforementioned heavy liquid isoparaffin or polybutene is a mixture of hydrocarbon oils having side chains obtained by copolymerizing isobutene and n-butene and then hydrogenating.
具体的には、市販品として、例えば、パールリーム１８、パールリーム２４、パールリーム４６（日本油脂社製）等が例示できる。その中でも特に、パールリーム１８、パールリーム２４が好ましい。また、これらを必要に応じて１種又は２種以上を用いることができる。 Specific examples of commercially available products include Pearl Ream 18, Pearl Ream 24, Pearl Ream 46 (manufactured by NOF Corporation), and the like. Of these, Pearl Ream 18 and Pearl Ream 24 are particularly preferable. Moreover, 1 type, or 2 or more types can be used for these as needed.
２５℃でペースト状である油性成分とは、２５℃で高い粘性を示す半固形の油性成分であり、医薬部外品原料規格２００６（薬事日報社刊）記載の、一般試験法、融点測定法（第２法）によって、融点が２５℃よりも高いと測定された油性成分をさす。 An oily component that is pasty at 25 ° C. is a semi-solid oily component that exhibits high viscosity at 25 ° C., and is a general test method and melting point measurement method described in the Quasi-drug Raw Material Standard 2006 (published by Yakuji Nippo). It refers to an oily component measured by (second method) as having a melting point higher than 25 ° C.
本願発明の前記成分（ｃ）中の２５℃においてペースト状である油性成分としては通常化粧料に使用されるものであればいずれのものも使用することができる。中でもワセリン、マカデミアナッツ脂肪酸フィトステリル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、ダイマージリノール酸（フィトステリル／イソステアリル／セチル／ステアリル／ベヘニル）、ダイマージリノール酸ダイマージリノレイルビス（ベヘニル／イソステアリル／フィトステリル）が好ましく、その中でも特にワセリン、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチルが特に好ましい。市販品としては、例えば、クロラータムＶ（クローダジャパン社製）、ＹＯＦＣＯＭＡＳ（日本精化社製）、コスモール１６８ＡＲＶ（日清オイリオ社製）、Ｐｌａｎｄｏｏｌ−Ｈ（日本精化社製）、ノムコートＷ（日清オイリオ社製）、等が例示できる。また、これらは必要に応じて１種又は２種以上を用いることができる。 Any oily component that is pasty at 25 ° C. in the component (c) of the present invention can be used as long as it is usually used in cosmetics. Among them, petroleum jelly, macadamia nut fatty acid phytosteryl, hexa (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl, dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer linoleyl bis (behenyl / Isostearyl / phytosteryl) is preferable, and petrolatum, hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl is particularly preferable among them. Commercially available products include, for example, Chloratum V (manufactured by Croda Japan), YOFCOMAS (manufactured by Nippon Seika Co., Ltd.), Cosmol 168ARV (manufactured by Nisshin Oilio Co., Ltd.), Plandool-H (manufactured by Nippon Seika Co., Ltd.), Nom Cote W (Nissei) For example, a product made by Kiyo Oilio Co., Ltd. Moreover, these can use 1 type (s) or 2 or more types as needed.
本願発明の前記成分（ｃ）である３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油及び／又は２５℃においてペースト状である油性成分の少なくとも１種の含有量は、特に限定されないが、のびのなめらかさを付与する点で１〜１０重量％が好ましい。より好ましくは２〜８重量％であり、さらに好ましくは４〜６重量％の範囲である。１重量％未満の含有量では耐衝撃性が低下する場合がある。一方、１０重量％を超えると、のびのなめらかさが低下する場合やケーキングが起こる場合がある。 The content of at least one kind of the hydrocarbon oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s or more and / or an oily component in a paste form at 25 ° C., which is the component (c) of the present invention, is particularly limited. However, it is preferably 1 to 10% by weight in terms of imparting smooth and smooth. More preferably, it is 2-8 weight%, More preferably, it is the range of 4-6 weight%. If the content is less than 1% by weight, the impact resistance may be lowered. On the other hand, if it exceeds 10% by weight, the smoothness of the spread may decrease or caking may occur.
本願発明の固形粉末化粧料は、上記成分の他、本願発明の効果を損なわない範囲で、化粧料一般に使用される成分を含有することができる。例えば、体質粉体、有機色材、無機色材等の粉体、炭化水素油、高級アルコール、高級脂肪酸等の油剤、界面活性剤、保湿剤、水溶性高分子、抗酸化剤、水溶性紫外線吸収剤、キレート剤、防腐剤、香料、ビタミン類、植物抽出液、無機塩等を用いることができ、これらは１種又は２種以上含有してもよい。 The solid powder cosmetic of the present invention can contain components commonly used in cosmetics in addition to the above components, as long as the effects of the present invention are not impaired. For example, powders such as extender powders, organic color materials, inorganic color materials, oils such as hydrocarbon oils, higher alcohols, higher fatty acids, surfactants, humectants, water-soluble polymers, antioxidants, water-soluble ultraviolet rays Absorbers, chelating agents, preservatives, fragrances, vitamins, plant extracts, inorganic salts and the like can be used, and these may be used alone or in combination of two or more.
本願発明の固形粉末化粧料としては、ファンデーション、アイブロウ、アイシャドウ、アイライナー、頬紅、ボディパウダー等が挙げられる。この中でも、アイブロウ、アイシャドウ、アイライナー、頬紅等のポイントメイクアップ製品が、本願発明の効果がより発揮しやすい化粧料である。 Examples of the solid powder cosmetic of the present invention include foundation, eyebrow, eye shadow, eyeliner, blusher, body powder and the like. Among these, point makeup products such as eyebrow, eyeshadow, eyeliner, blusher, and the like are cosmetics that can more easily exert the effects of the present invention.
本願発明は、塗布時の彩度・発色が高く、のびのなめらかな使用感を付与し、耐衝撃性に優れ、使用時にケーキングが起こらない固形粉末化粧料を提供できることを特徴とする。 The present invention is characterized by providing a solid powder cosmetic that has high saturation and color development at the time of application, gives a smooth and smooth feeling of use, is excellent in impact resistance, and does not cause caking during use.
以下に、実施例をあげて、本願発明をより詳細に説明するが、本願発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
（製造例１〜２７）アイライナー
本願発明の固形粉末化粧料を以下の実施例１〜３の製造例１〜２７を用いて説明する。本願発明のアイライナーを実際に人の顔に塗布した際の彩度・発色、のびのなめらかさ、耐衝撃性及びケーキングの無さについて検討するため、各実施例に対応する表１〜３に示す処方及び下記製法により、アイライナーを調製し、以下に示す評価方法及び判定基準により評価し、その結果も併せて表１〜３に示した。
(Production Examples 1 to 27) Eyeliner The solid powder cosmetic of the present invention will be described using Production Examples 1 to 27 of Examples 1 to 3 below. Tables 1 to 3 corresponding to each example are used to examine the saturation / color development, the smoothness of spreading, the impact resistance and the absence of caking when the eyeliner of the present invention is actually applied to a human face. An eyeliner was prepared according to the formulation shown and the following production method, and evaluated according to the evaluation method and criteria described below. The results are also shown in Tables 1 to 3.
（塗布時の彩度・発色の評価）
製造例、比較例に示した固形粉末化粧料を専門評価者２０名に使用させ、塗布時の彩度・発色について目視観察し、以下の評価基準に従って判定した。
＜評価基準＞
◎：１５名以上が彩度・発色が高いと評価した。
○：１０〜１４名が彩度・発色が高いと評価した。
△：５〜９名が彩度・発色が高いと評価した。
×：４名以下が彩度・発色が高いと評価した。
(Evaluation of saturation and color development during application)
The solid powder cosmetics shown in the production examples and comparative examples were used by 20 professional evaluators, visually observed for saturation and color development at the time of application, and judged according to the following evaluation criteria.
<Evaluation criteria>
A: 15 or more people evaluated that the saturation and color development were high.
A: 10 to 14 people evaluated that the saturation and color development were high.
Δ: Five to nine people evaluated high saturation and color development.
X: Four or less people evaluated that saturation and color development were high.
（肌へののびのなめらかさの評価）
製造例、比較例に示した固形粉末化粧料を専門評価者２０名に使用させ、肌へののびのなめらかさについて官能評価し、以下の評価基準に従って判定した。
＜評価基準＞
◎：１５名以上がのびのなめらかさがあると評価した。
○：１０〜１４名がのびのなめらかさがあると評価した。
△：５〜９名がのびのなめらかさがあると評価した。
×：４名以下がのびのなめらかさがあると評価した。
(Evaluation of smoothness on skin)
Twenty professional evaluators were allowed to use the solid powder cosmetics shown in the production examples and comparative examples, and the sensory evaluation was performed on the smoothness of spreading on the skin, and the determination was made according to the following evaluation criteria.
<Evaluation criteria>
A: 15 or more people evaluated that there was a smooth and smooth.
A: 10 to 14 people evaluated that there was a smooth and smooth.
(Triangle | delta): Five to nine people evaluated that there was smooth and smooth.
X: Four or less people evaluated that there was smooth and smooth.
（耐衝撃性の評価）
製造例、比較例に示した固形粉末化粧料を各５枚について、５０ｃｍの高さから塩ビ板上に水平に落下させた。これをひびや割れが生じるまで繰り返し、ひびや割れが生じるまでの落下回数について５枚で平均をとり、以下の判定基準に従って判定した。
＜評価基準＞
◎：４回以上
○：２以上４回未満
△：１以上２回未満
×：１回未満
(Evaluation of impact resistance)
For each of the five solid powder cosmetics shown in the production examples and comparative examples, they were dropped horizontally on a PVC plate from a height of 50 cm. This was repeated until cracks and cracks occurred, and the number of drops until cracks and cracks occurred was averaged for 5 sheets, and judged according to the following criteria.
<Evaluation criteria>
A: 4 times or more
○: 2 or more and less than 4 times Δ: 1 or more and less than 2 times ×: less than 1 time
（ケーキングの無さの評価）
製造例、比較例に示した固形粉末化粧料を、ウレタン製化粧塗布用チップにて、同一方向に５０回繰り返し擦り取り、ケーキ表面を目視観察し、油性成分の固まり様（ケーキング）が無い効果を以下に示す判定基準に従って判定した。
＜評価基準＞
◎：ケーキングが見られない。
○：ケーキングが見られるが使用性に問題なし。
×：ケーキングが見られ使用性に問題がある。
(Evaluation of absence of caking)
The solid powder cosmetics shown in the production examples and comparative examples are repeatedly scraped 50 times in the same direction with a urethane cosmetic coating chip, and the cake surface is visually observed, and there is no caking of oily components (caking) Was determined according to the following criteria.
<Evaluation criteria>
A: No caking is seen.
○: Caking is observed but there is no problem in usability.
X: A caking is seen and there exists a problem in usability.
実施例１として表１に示す製造例１〜９及び比較例１により、アイライナーを下記製法にて調製し、前記の使用試験方法、評価項目及び評価基準に基づいて評価した。なお、表中※印のついた成分は、下記市販原料である。 The eyeliner was prepared by the following manufacturing method according to Production Examples 1 to 9 and Comparative Example 1 shown in Table 1 as Example 1, and evaluated based on the above-described use test method, evaluation items, and evaluation criteria. The components marked with * in the table are the following commercially available raw materials.
※２ パールリーム１８（日本油脂社製）
※３ パールリームＥＸ（日本油脂社製）
* 2 Pearl Dream 18 (Nippon Yushi Co., Ltd.)
* 3 Pearl Ream EX (manufactured by NOF Corporation)
（製法）
成分（１）〜（７）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（７）の混合粉砕物と、予め加熱混合しておいた成分（８）〜（１０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイライナーを得た。
(Manufacturing method)
Components (1) to (7) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (7) and the components (8) to (10) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After atomizer pulverization, the mixture is passed through a sieve. The eyeliner was obtained by pressing into a metal pan.
表１の結果から明らかなように、製造例１〜９のアイライナーは塗布時の彩度・発色が高く良好であった。それに対し、比較例１は塗布時の彩度・発色が十分に得られなかった。この結果から、成分（ａ）の酸化鉄の含有量は４０重量％以上が好ましいことが明らかとなった。 As is clear from the results in Table 1, the eye liners of Production Examples 1 to 9 were good because of high saturation and color development during coating. In contrast, Comparative Example 1 did not provide sufficient saturation and color development during coating. From this result, it became clear that the content of iron oxide of component (a) is preferably 40% by weight or more.
実施例２として表２に示す製造例１０〜１５及び比較例２〜４により、アイライナーを下記製法にて調製し、前記の使用試験方法、評価項目及び評価基準に基づいて評価した。なお、表中※印のついた成分は、下記市販原料である。 According to Production Examples 10 to 15 and Comparative Examples 2 to 4 shown in Table 2 as Example 2, an eyeliner was prepared by the following production method and evaluated based on the above-described use test method, evaluation items, and evaluation criteria. The components marked with * in the table are the following commercially available raw materials.
※５ サイリシア５５０（富士シリシア社製）
* 5 Silysia 550 (Fuji Silysia)
（製法）
成分（１）〜（７）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（７）の混合粉砕物と、予め加熱混合しておいた成分（８）〜（１０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイライナーを得た。
(Manufacturing method)
Components (1) to (7) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (7) and the components (8) to (10) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After atomizer pulverization, the mixture is passed through a sieve. The eyeliner was obtained by pressing into a metal pan.
表２の結果から明らかなように、製造例１０〜１５の固形粉末化粧料はのびのなめらかさ、耐衝撃性及びケーキングの無さが良好であった。それに対し、非晶質板状シリカを含有していない比較例２はのびのなめらかさが無く、またケーキングを生じ十分な効果を得られなかった。非晶質板状シリカ以外のシリカを含有した比較例３及び４では塗布時の彩度・発色、耐衝撃性について十分な効果を得られなかった。この結果から、成分（ｂ）の非晶質板状シリカを使用する必然性があり、さらに含有量は２〜２０重量％が好ましく、より好ましくは５〜１５重量％であり、さらに好ましくは８〜１２重量％であることが明らかとなった。 As is apparent from the results in Table 2, the solid powder cosmetics of Production Examples 10 to 15 were good in smoothness, impact resistance, and no caking. On the other hand, Comparative Example 2 which does not contain amorphous plate-like silica has no smoothness and caking, and a sufficient effect cannot be obtained. In Comparative Examples 3 and 4 containing silica other than the amorphous plate-like silica, sufficient effects were not obtained with respect to the saturation, color development and impact resistance at the time of coating. From this result, it is necessary to use the amorphous plate-like silica of the component (b), and the content is preferably 2 to 20% by weight, more preferably 5 to 15% by weight, still more preferably 8 to It was found to be 12% by weight.
実施例３として表３に示す製造例１６〜２７及び比較例５により、アイライナーを下記製法にて調製し、前記の使用試験方法、評価項目及び評価基準に基づいて評価した。なお、表中※印のついた成分は、下記市販原料である。 According to Production Examples 16 to 27 and Comparative Example 5 shown in Table 3 as Example 3, an eyeliner was prepared by the following production method and evaluated based on the use test method, evaluation items, and evaluation criteria. The components marked with * in the table are the following commercially available raw materials.
※７ コスモール１６８ＡＶＲ（日清オイリオグループ社製）
※８ クロラータムＶ（クローダジャパン社製）
* 7 Cosmall 168AVR (Nisshin Oillio Group)
* 8 Chloratum V (manufactured by Croda Japan)
（製法）
成分（１）〜（５）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（５）の混合粉砕物と、予め加熱混合しておいた成分（６）〜（１１）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイライナーを得た。
(Manufacturing method)
Components (1) to (5) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (5) and the components (6) to (11) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eyeliner was obtained by pressing into a metal pan.
表３の結果から明らかなように、製造例１６〜２７のアイライナーはのびのなめらかさ、耐衝撃性及びケーキングの無さが良好であった。それに対し、比較例５は耐衝撃性が弱く、塗布時の彩度・発色が低く十分な効果を得られなかった。この結果から、成分（ｃ）３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油及び／又は２５℃においてペースト状である油性成分の少なくとも１種の含有量が１〜１０重量％が好ましく、より好ましくは２〜８重量％であり、さらに好ましくは４〜６重量％であることが明らかとなった。 As is clear from the results in Table 3, the eye liners of Production Examples 16 to 27 had good smoothness, impact resistance, and no caking. On the other hand, Comparative Example 5 had a low impact resistance, and the saturation and color development at the time of coating were low, so that sufficient effects could not be obtained. From this result, the content of at least one component (c) a hydrocarbon oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s or more and / or an oily component that is pasty at 25 ° C. is 1 to 10% by weight. It was found that the content is preferably 2 to 8% by weight, more preferably 4 to 6% by weight.
（製造例２８）アイライナー
（成分） 含有量（重量％）
１．タルク ５．０
２．セリサイト ５．７
３．シリコーン処理黒酸化鉄 ※９ ５０．０
４．酸化チタン １５．０
５．非晶質板状シリカ ※１ １０．０
６．パラベン ０．２
７．重質流動イソパラフィン ※２ ６．０
８．イソノナン酸イソトリデシル １．０
９．フェニル変性シリコーン ※１０ ７．０
１０．香料 ０．１
※９ ジメチルポリシロキサン３％処理
※１０ ＫＦ−５６Ａ（信越化学工業株式会社製）
（製法）
成分（１）〜（６）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（６）の混合粉砕物と、予め加熱混合しておいた成分（７）〜（１０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイライナーを得た。
(Production Example 28) Eyeliner (component) Content (% by weight)
1. Talc 5.0
2. Sericite 5.7
3. Silicone-treated black iron oxide * 9 50.0
4). Titanium oxide 15.0
5). Amorphous plate-like silica * 1 10.0
6). Paraben 0.2
7). Heavy liquid isoparaffin * 2 6.0
8). Isotridecyl isononanoate 1.0
9. Phenyl-modified silicone * 10 7.0
10. Fragrance 0.1
* 9 Treatment with 3% dimethylpolysiloxane * 10 KF-56A (Shin-Etsu Chemical Co., Ltd.)
(Manufacturing method)
Components (1) to (6) were mixed uniformly with a Henschel mixer and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (6) and the components (7) to (10) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eyeliner was obtained by pressing into a metal pan.
実施例４について、実施例１〜３で使用した評価方法と同様に評価を行った結果、塗布時の彩度・発色、肌へののびのなめらかさ、耐衝撃性、ケーキングの無さに優れたアイライナーを得た。 About Example 4, as a result of evaluating in the same manner as the evaluation method used in Examples 1 to 3, it was excellent in saturation and color development at the time of application, smoothness of spreading on the skin, impact resistance, and no caking. Got an eyeliner.
アイブロウ
（成分） 含有量（重量％）
１．タルク １４．０
２．セリサイト １５．８
３．赤酸化鉄 １０．０
４．黄酸化鉄 １０．０
５．黒酸化鉄 ３０．０
６．酸化チタン ５．０
７．非晶質板状シリカ ※１ ８．０
８．パラベン ０．２
９．ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル ※７ ４．０
１０．イソノナン酸イソトリデシル ３．０
（製法）
成分（１）〜（８）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（８）の混合粉砕物と、予め加熱混合しておいた成分（９）〜（１０）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスしてアイブロウを得た。
Eyebrow (component) Content (wt%)
1. Talc 14.0
2. Sericite 15.8
3. Red iron oxide 10.0
4). Yellow iron oxide 10.0
5). Black iron oxide 30.0
6). Titanium oxide 5.0
7). Amorphous plate-like silica * 1 8.0
8). Paraben 0.2
9. Hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl * 7 4.0
10. Isotridecyl isononanoate 3.0
(Manufacturing method)
Components (1) to (8) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (8) and the components (9) to (10) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eyebrow was obtained by pressing on a metal plate.
実施例５について、実施例１〜３で使用した評価方法と同様に評価を行った結果、塗布時の彩度・発色、肌へののびのなめらかさ、耐衝撃性、ケーキングの無さに優れたアイブロウを得た。 About Example 5, as a result of evaluating in the same manner as the evaluation method used in Examples 1 to 3, it was excellent in saturation and color development at the time of application, smoothness of spreading to the skin, impact resistance, and no caking. Got an eyebrow.
アイシャドウ
（成分） 含有量（重量％）
１．タルク ８．０
２．セリサイト ９．８
３．赤酸化鉄 ５．０
４．黄酸化鉄 ５．０
５．黒酸化鉄 ４０．０
６．酸化チタン ５．０
７．非晶質板状シリカ ※１ ８．０
８．雲母チタン ５．０
９．酸化鉄被覆雲母チタン ７．０
１０．パラベン ０．２
１１．重質流動イソパラフィン ※２ ４．０
１２．イソノナン酸イソトリデシル ３．０
（製法）
成分（１）〜（１０）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（１０）の混合粉砕物と、予め加熱混合しておいた成分（１１）〜（１２）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、プレスして圧縮成型する前のアイシャドウ粉末を得た。次いで湿式プレスを行うために、アイシャドウ粉末に揮発性溶媒又は水を添加してスラリー化し、スラリーの状態で金皿に充填した後、真空吸引などで溶媒を除去しながらプレスし、乾燥させてアイシャドウを得た。
Eye shadow (component) Content (wt%)
1. Talc 8.0
2. Sericite 9.8
3. Red iron oxide 5.0
4). Yellow iron oxide 5.0
5). Black iron oxide 40.0
6). Titanium oxide 5.0
7). Amorphous plate-like silica * 1 8.0
8). Mica titanium 5.0
9. Iron oxide coated mica titanium 7.0
10. Paraben 0.2
11. Heavy liquid isoparaffin * 2 4.0
12 Isotridecyl isononanoate 3.0
(Manufacturing method)
Components (1) to (10) were uniformly mixed with a Henschel mixer, and pulverized with an atomizer. Furthermore, the mixed pulverized product of components (1) to (10) and the components (11) to (12) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. The eye shadow powder before pressing and compression molding was obtained. Next, in order to perform wet pressing, a volatile solvent or water is added to the eye shadow powder to form a slurry, and after filling the metal plate in the slurry state, the solvent is removed by vacuum suction or the like and dried. I got an eye shadow.
実施例６について、実施例１〜３で使用した評価方法と同様に評価を行った結果、塗布時の彩度・発色、肌へののびのなめらかさ、耐衝撃性、ケーキングの無さに優れたアイシャドウを得た。 About Example 6, as a result of evaluating in the same manner as the evaluation method used in Examples 1 to 3, it was excellent in saturation and color development at the time of application, smoothness of spreading to the skin, impact resistance, and no caking. Got eyeshadow.
頬紅
（成分） 含有量（重量％）
１．タルク ４．５
２．セリサイト ４．３
３．赤酸化鉄 ３０．０
４．黄酸化鉄 １０．０
５．酸化チタン ２５．０
６．非晶質板状シリカ ※１ １０．０
７．雲母チタン ３．０
８．酸化鉄被覆雲母チタン ５．０
９．パラベン ０．２
１０．ワセリン ※８ ４．０
１１．イソノナン酸イソトリデシル ４．０
（製法）
成分（１）〜（９）をヘンシェル型ミキサーにて均一に混合し、アトマイザーにて粉砕を行った。さらに、成分（１）〜（９）の混合粉砕物と、予め加熱混合しておいた成分（１０）〜（１１）をヘンシェル型ミキサーに加えて均一に混合し、アトマイザー粉砕後、ふるいを通し、金皿にプレスして頬紅を得た。
Blusher (ingredient) Content (wt%)
1. Talc 4.5
2. Sericite 4.3
3. Red iron oxide 30.0
4). Yellow iron oxide 10.0
5). Titanium oxide 25.0
6). Amorphous plate-like silica * 1 10.0
7). Mica titanium 3.0
8). Iron oxide coated mica titanium 5.0
9. Paraben 0.2
10. Vaseline * 8 4.0
11. Isotridecyl isononanoate 4.0
(Manufacturing method)
Components (1) to (9) were mixed uniformly with a Henschel mixer and pulverized with an atomizer. Further, the mixed pulverized product of components (1) to (9) and the components (10) to (11) that have been heated and mixed in advance are added to a Henschel mixer and mixed uniformly. After pulverizing the atomizer, the mixture is passed through a sieve. , Pressed on a gold plate to get blusher.
実施例７について、実施例１〜３で使用した評価方法と同様に評価を行った結果、塗布時の彩度・発色、肌へののびのなめらかさ、耐衝撃性、ケーキングの無さに優れた頬紅を得た。 About Example 7, as a result of evaluating in the same manner as the evaluation method used in Examples 1 to 3, it was excellent in saturation and color development at the time of application, smoothness of spreading on the skin, impact resistance, and no caking. Got blusher.
本願発明は、固形粉末化粧料において特定の成分を組合せ、特定量含有することにより、塗布時の彩度・発色が高く、のびのなめらかさが良好であり、また耐衝撃性に優れ、さらに使用時にケーキングを防ぐ技術である。したがって、この技術を活用すれば医薬品の錠剤成型等、固まりやすさや、崩壊をコントロールしなければならないような固形粉末製品に広く応用可能である。
The invention of the present application combines specific components in a solid powder cosmetic and contains a specific amount, so that the saturation and color development at the time of application is high, the smoothness is good, the impact resistance is excellent, and further use It is a technology that sometimes prevents caking. Therefore, if this technology is utilized, it can be widely applied to solid powder products in which the ease of solidification and disintegration must be controlled, such as tableting of pharmaceuticals.
Claims (7)
（ａ）酸化鉄４０重量％以上
（ｂ）非晶質板状シリカ
（ｃ）３０℃における動粘度が１０，０００ｍｍ２／ｓ以上の炭化水素油及び／又は２５℃においてペースト状である油性成分から選ばれる１種又は２種以上 A solid powder cosmetic comprising the following components (a) to (c):
(A) Iron oxide 40% by weight or more (b) Amorphous platy silica (c) Hydrodynamic oil having a kinematic viscosity at 30 ° C. of 10,000 mm 2 / s and / or an oily component pasty at 25 ° C. One or more selected from
The solid powder cosmetic according to any one of claims 1 to 6, wherein the solid powder cosmetic is eyebrow, eye shadow, eyeliner, and blusher.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019138793A1 (en) * | 2018-01-09 | 2019-07-18 | 株式会社トキワ | Solid powder cosmetic and method for producing solid powder cosmetic |
| CN112842939A (en) * | 2019-11-28 | 2021-05-28 | 株式会社常盘 | Method for producing solid powder cosmetic |
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| JP2005289975A (en) * | 2004-03-11 | 2005-10-20 | Kose Corp | Production method for solid powder cosmetic agent and solid powder cosmetic agent obtained through the production method |
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| JP2004217567A (en) * | 2003-01-15 | 2004-08-05 | Kose Corp | Solid powdery eye shadow |
| JP2005289975A (en) * | 2004-03-11 | 2005-10-20 | Kose Corp | Production method for solid powder cosmetic agent and solid powder cosmetic agent obtained through the production method |
| JP2005306847A (en) * | 2004-03-26 | 2005-11-04 | Kose Corp | Cake powder cosmetic |
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| WO2019138793A1 (en) * | 2018-01-09 | 2019-07-18 | 株式会社トキワ | Solid powder cosmetic and method for producing solid powder cosmetic |
| JP2019119716A (en) * | 2018-01-09 | 2019-07-22 | 株式会社トキワ | Solid powder cosmetic and method for producing solid powder cosmetic |
| JP7081784B2 (en) | 2018-01-09 | 2022-06-07 | 株式会社トキワ | Manufacturing method of solid powder cosmetics and solid powder cosmetics |
| CN112842939A (en) * | 2019-11-28 | 2021-05-28 | 株式会社常盘 | Method for producing solid powder cosmetic |
| KR20210066728A (en) | 2019-11-28 | 2021-06-07 | 가부시키가이샤 도끼와 | Method for producing solid powder cosmetic |
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