CN103860396B - Oil-in-water type emulsion solid, cosmetic - Google Patents
Oil-in-water type emulsion solid, cosmetic Download PDFInfo
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- CN103860396B CN103860396B CN201310682654.2A CN201310682654A CN103860396B CN 103860396 B CN103860396 B CN 103860396B CN 201310682654 A CN201310682654 A CN 201310682654A CN 103860396 B CN103860396 B CN 103860396B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The present invention relates to oil-in-water type emulsion solid, cosmetic.Specifically, the present invention provides solid-state oil-in-water emulsion type cosmetic preparation, usability with water profit refrigerant sense of the solid-state oil-in-water emulsion type cosmetic preparation with the characteristic for oil-in-water emulsion type cosmetic preparation, skin attachment are excellent, simultaneously for makeup application body access it is good, there is smooth use feeling, and shape keeping property height, the Portability when being used continuously are excellent.The oil-in-water type emulsion solid, cosmetic of the present invention contains (a) agar of the mass % of 1.0 mass %~3.5 and (b) acrylic amide water-soluble thickener of the mass % of 0.05 mass %~1.0.
Description
Technical field
The present invention relates to solid-state oil-in-water emulsion type cosmetic preparation, the solid-state oil-in-water emulsion type cosmetic preparation is so-called water bag
The characteristic of oil type emulsification cosmetic has the usability of water profit refrigerant sense, skin attachment excellent, is applied simultaneously for cosmetics
The access of applying body is good, has smooth use feeling, and shape keeping property height, the Portability when being used continuously are excellent.
Background technology
In the past, the aqueous cosmetic of oil-in-water emulsion type cosmetic preparation etc. was as with so-called water profit, frank refrigerant sense
Usability, the excellent State of cosmetics of naturality of decoration is widely used and comes.
Form as conventional oil-in-water emulsion type cosmetic preparation generally has emulsion form or liquid, white shape etc..Also, its
Container form is mostly the ampuliform form or tube-like condition sealed with lid, is not square from the viewpoint of usability or Portability
Just.In recent years, except these cosmetics forms, offer is provided and is made using the water soluble solid agent of agar or gelatin
The technology of solid oil-in-water emulsion type cosmetic preparation（See, for example patent document 1）.
Such solid-state oil-in-water emulsion type cosmetic preparation is that the usability with water profit refrigerant sense is excellent, and Portability is good
Good cosmetics.However, when compared with identical solid-state water-in-oil emulsified cosmetic, when with so-called finger or coating work
When the applicator of tool takes cosmetics, have the shortcomings that applicator slip over cosmetics surface cosmetics access it is poor.Therefore, it is
So that the access of oil-in-water type emulsion solid, cosmetic well needs to take many time.For example, as described in Patent Document 2,
Disclose the oil-in-water cosmetic being packed into container and water-retaining property flaky material is attached at cosmetics surface before curing, it is cold
But after curing, water-retaining property flaky material is peeled off and removes one layer of surface, so that the technology that the access of cosmetics is good.
[prior art literature]
[patent document]
[patent document 1] Japanese Unexamined Patent Publication 5-178723
[patent document 2] Japanese Unexamined Patent Publication 7-17828
The content of the invention
[problems to be solved by the invention]
However, using the technology for peeling off the water-retaining property flaky material that cosmetics surface attaches of patent document 2, although can
It is how many to improve the easiness of taking for beginning to use new product cosmetics initial stages, but for peeling off after water-retaining property flaky material repeatedly
Easiness is taken during using cosmetics, it cannot be said that its improvement is sufficient.Further, since the access of cosmetics is not filled
Point, need to apply strong strength if more cosmetics are taken on finger or coating tool, when Reusability cosmetics
The problem of splitting, destroy with solid cosmetics etc., it is impossible to while meet the so-called usability for taking easiness and resistance to
By the opposite characteristic of the hardness of Reusability or Portability.
Therefore, there is an urgent need to solid-state oil-in-water emulsion type cosmetic preparation, the solid-state oil-in-water emulsion type cosmetic preparation, which has, is
The characteristic of oil-in-water emulsion type cosmetic preparation has the usability of water profit refrigerant sense, skin attachment excellent, simultaneously for makeup
The access of product applicator is good, has smooth use feeling, and shape keeping property height, the Portability during continuous use are excellent.
[solution to the problem]
The actual conditions are used for reference, the present inventor is repeated attentively studying as a result, it is a discovery of the invention that will be used as water-soluble
Property curing agent agar and acrylic amide water-soluble thickener combination obtained from oil-in-water type emulsion solid, cosmetic, have
Water moistens the usability of refrigerant sense, good for the access of makeup application body, and skin attachment is high and has smooth use
Property, and shape keeping property during continuous use is high, Portability is also excellent.
Further, find as the acrylic amide water-soluble thickener used in the present invention, preferably comprise with propylene
Material of the acyl dimethyltaurate as the copolymer of construction unit, further preferably from acryloyl dimethyltaurate
With hydroxy-ethyl acrylate and/or acrylates as the one or more selected in the copolymer of construction unit, thus, it is possible to
Shape keeping property when taking easiness and continuous use for makeup application body is enough significantly improved, until completing this
Invention.
That is, the present invention is a kind of oil-in-water type emulsion solid, cosmetic, it is characterised in that containing following (a)~(c) into
Point：
(a) agar of the mass % of 1.0 mass %~3.5,
(b) acrylic amide water-soluble thickener of the mass % of 0.05 mass %~1.0,
(c) finish.
Further, above-mentioned oil-in-water type emulsion solid, cosmetic, it is characterised in that water-soluble as (b) acrylic amide
Property thickener, preferably comprises copolymer of the acryloyl dimethyltaurate as construction unit, it is further preferred that from acryloyl two
Methyl tauride and hydroxy-ethyl acrylate and/or acrylates as selected in the copolymer of construction unit it is one or two kinds of with
On.
[invention effect]
Oil-in-water type emulsion solid, cosmetic according to the present invention is capable of providing, and has the usability of water profit refrigerant sense, right
Good in the access of makeup application body, skin attachment is high and has smooth use feeling, and form during continuous use
Retentivity is high, the excellent solid-state oil-in-water emulsion type cosmetic preparation of Portability.
Embodiment
In the following, the preferred embodiment for the oil-in-water type emulsion solid, cosmetic that the present invention will be described in detail.
The present invention is a kind of solid-state oil-in-water emulsion type cosmetic preparation, it is characterised in that containing 1.0 mass %~3.5 mass %
(a) agar and the mass % of 0.05 mass %~1.0 (b) acrylic amide water-soluble thickener and (c) finish, it moistens with water
The usability of refrigerant sense, good for the access of makeup application body, skin attachment is high and has smooth use feeling, and
Shape keeping property during continuous use is high, and Portability is excellent.
In the present invention, in order to cure oil-in-water emulsion type cosmetic preparation, assign the hardness of tolerance usability and Portability and make
With water soluble solid agent.As water soluble solid agent, consider from using sense of touch, particularly preferred (a) agar.(a) agar can be with
Enumerate, for example, the ウ Le ト ラ agar AX-200 as commercially available product（Ina Food Industry Co., Ltd.'s system）Deng.
The content of (a) agar used in the oil-in-water type emulsion solid, cosmetic of the present invention, is preferably oil-in-water type breast
Change the mass % of 1.0 mass %~3.5 in solid, cosmetic total amount.During less than 1.0 mass %, kept from form during continuous use
Without preferred from the viewpoint of property and crushing strength.Moreover, during more than 3.5 mass %, from it is so-called take easiness, attach sense,
Without tight feeling（Star ッ パ リ feel）（Smooth usability）Use sense of touch, from the viewpoint of shape keeping property during continuous use and
It is not preferred.
(b) acrylic amide water-soluble thickener used in oil-in-water type emulsion solid, cosmetic as the present invention,
It can enumerate, for example, (hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate) copolymer, (sodium acrylate/acryloyl diformazan
Base sodium taurocholate) copolymer, (ammonium acryloyldime-thyltaurate/VP) copolymer, (ammonium acryloyldime-thyltaurate methyl-prop
Olefin(e) acid behenyl alcohol polyethers -25) cross-linked polymer etc..Wherein, particularly preferably, (hydroxy-ethyl acrylate/acryloyldimethyl taurine
Sodium) copolymer, (sodium acrylate/sodium acryloyldimethyl taurate) copolymer, can increase from aforesaid propylene amide-type is water-soluble
One or more kinds of use is selected in thick dose.
(b) acrylic amide water-soluble thickener can use commercially available product.For example, as (hydroxy-ethyl acrylate/acryloyl
Dimethyltaurine sodium) copolymer commercially available product, can enumerate, SEPINOV EMT10, SIMULGEL NS（It is SEPPIC above
Society's system）Deng.In addition, the commercially available product as (sodium acrylate/sodium acryloyldimethyl taurate) copolymer, can enumerate,
SIMULGEL EG（SEPPIC societies system）Deng.As (ammonium acryloyldime-thyltaurate/VP）The commercially available product of copolymer, Ke Yiju
Go out Aristoflex AVC（Clariant societies system）Deng as (ammonium acryloyldime-thyltaurate methacrylic acid behenyl alcohol gathers
Ether -25) cross-linked polymer commercially available product, Aristoflex HMB can be enumerated（Clariant societies system）Deng.
In the present invention, the content of above-mentioned (b) acrylic amide water-soluble thickener, preferably oil-in-water type emulsion solid cosmetic
The mass % of 0.05 mass % in product total amount~1.0.During less than 0.05 mass %, from form when taking easiness and continuous use
It is not preferred from the viewpoint of retentivity.Also, during more than 1.0 mass %, from so-called no tight feeling（Smooth usability）Make
With sense of touch, without preferred from the viewpoint of crushing strength.
(c) finish used in the oil-in-water type emulsion solid, cosmetic of the present invention is for so-called moisturizing sense（エ
モ リ エ Application ト feels）, attach sense the purpose using sense of touch conditioning agent etc. and the material that uses, have no particular limits, can make
Fluid oil, solid oil, the semisolid oil used in ordinary cosmetics.
As the fluid oil that can be compounded in the present invention, as long as it is the ordinary cosmetics of the oil of liquid at normal temperatures
The middle material used, has no particular limits, and can specifically enumerate, the hydrocarbon-type oil of atoleine, saualane etc., and malic acid two is different
Stearyl, isopropyl myristate, 2 ethyl hexanoic acid cetyl ester, isopropyl palmitate, ethylhexyl palmitate, three
Miglyol 812（ト リ カ プ リ Le カ プ リ Application acid グ リ セ リ Le）, three -2 ethyl hexanoic acid glyceride etc. Esters oil, olive
The vegetable oil of olive oil, castor oil, macadimia nut oil, SIMMONDSIA CHINENSIS SEED OIL etc., oleyl alcohol, octyldodecanol, i-octadecanol etc. it is advanced
The higher fatty acids of alcohol, isostearic acid, oleic acid etc., dimethyl polysiloxane, methyl phenyl silicone, decamethyl pentamethylene silicon
Silicone oil of oxygen alkane etc. etc..The one or more of these liquid oil components can be used.
As solid oil, the semisolid oil that can be compounded in the present invention, as long as the material used in ordinary cosmetics,
Have no particular limits, can specifically enumerate, the hydro carbons of vaseline, solid paraffin, microwax, polyethylene etc., rilanit special,
Hydrogenate the grease of the plant origin of SIMMONDSIA CHINENSIS SEED OIL, Brazil wax, rice bran wax etc., tribehenin acid glyceride, Cholesteryl fatty acids
The higher alcohols of the higher aliphatic acids of the esters of ester etc., stearic acid, behenic acid etc., stearyl alcohol, behenyl alcohol etc., alkyl-modified silicon
Silicone of ketone, acrylic modified silicone etc. etc..Can use these solid oils, semisolid oil component it is one or two kinds of with
On.
In the oil-in-water type emulsion solid, cosmetic of the present invention, effect of the present invention can not also damaged as needed
In the range of, be suitably compounded used in the ordinary cosmetics in addition to the required constituent of above-mentioned (a)~(c) it is other into
Point, for example, powdered ingredients, moisturizer, surfactant, ultra-violet absorber, film forming agent, preservative, vitamins, beauty into
Point, antioxidant, spices etc..
As the powdered ingredients that can be compounded in the present invention, as long as the material used in ordinary cosmetics, does not have
It is special to limit, it can specifically enumerate, mica, kaolin, synthetic mica, silica, calcium carbonate, magnesium carbonate, aluminium oxide, three
Aoxidize two iron, yellow iron oxide, iron oxide black, cobalt oxide, ultramarine, Prussian blue, titanium oxide, zinc oxide, pearl pigment（Mica
Titanium, fish scale pool, bismoclite etc.）, boron nitride, organic pigment（No. 228 red, No. 226 red, blueness No. 404 etc.）, polyethylene
Powder, polymethyl methacrylate, organopolysiloxane elastomers etc..It can also be used two or more in these powder is compound
Material, in addition, it is possible to use, using known method, closed with silicone compounds, metal soap, amino-acid compound, fluorination
The material that the implementations such as thing are surface-treated.It is diversified in order to obtain to use sense of touch, and make up as cosmetic
During material, desired tone, can use one kind or two or more in these powder in order to obtain.
As the moisturizer that can be compounded in the present invention, as long as the material used in ordinary cosmetics, without special
Restriction, can specifically enumerate, glycerine, propane diols, 1,3-BDO, dipropylene glycol, polyethylene glycol etc..
As the purposes of the oil-in-water type emulsion solid, cosmetic of the present invention, there is no particular limitation, for example, can conduct
The cosmetics of skin care use, cosmetic, Hair grooming etc. use.It is preferably suitable for foundation cream, eye shadow, blush, eyebrow pencil, eyeliner, eyelashes
Cream, lipstick, adornment foremilk etc..
[embodiment]
In the following, enumerating embodiment illustrates the present invention, but it does not limit the present invention to any degree.In embodiment
Explanation in, the effect test method that uses in the explanation present invention first.
<The evaluation method of oil-in-water type emulsion solid, cosmetic>
[usability test]
Please 10 cosmetics specialty judge personnel using embodiment and the oil-in-water type emulsion solid, cosmetic of comparative example, it is right
In " taking easiness（Taken for the cosmetics of applicator）", " attach sense（It is attached at skin）", " no tight feeling（Smoothly
Usability）" each assessment item, respectively according to following evaluation criterion, give 5 grades of scoring, will further obtain
The scoring equalization of each member, judges each project respectively based on the average mark and following criterion with 4 grades.
[evaluation criterion]
Scoring；
5 points：It is very good
4 points：It is good
3 points：It is neither better nor worse
2 points：It is slightly worse
1 point：Difference
[criterion]
◎：Average mark is more than 4.5 points
○：Average mark is more than 3.5 points and less than 4.5 points
△：Average mark is more than 1.5 points and less than 3.5 points
×：Average mark is less than 1.5 points
[shape keeping property during continuous use]
Please the continuous 50 times oil-in-water type emulsion solid-states using embodiment and comparative example of 10 cosmetics professional evaluators
Whether cosmetics, cosmetics keep the scoring that thing block form gives 5 grades according to following evaluation criterion respectively, will further obtain
The scoring equalization of each member, is judged based on the average mark and following criterion with 4 grades.
[evaluation criterion]
Scoring；
5 points：It is very good
4 points：Slight split occurs for thing block
3 points：Thing block splits, and thing block comes off into fritter
2 points：Thing block integrally produces cracking, and thing block is blocking to come off
1 point：Thing block integrally produces cracking, and thing block integrally comes off from container
[criterion]
◎：Average mark is more than 4.5 points
○：Average mark is more than 3.5 points and less than 4.5 points
△：Average mark is more than 1.5 points and less than 3.5 points
×：Average mark is less than 1.5 points
[crushing strength]
Based on following evaluation criterion, with 4 grades of evaluations so that the oil-in-water type emulsion solid, cosmetic of embodiment and comparative example
Fall back to the thing block shape keeping property on the glued board of thickness 15mm after 5 times from the height of 50cm.
[evaluation criterion]
◎：Completely without the destruction of thing block
○：Thing block surface slight damage
△：Thing block partial destruction
×：Thing block integrally destroys
[ageing stability]
The oil-in-water type emulsion solid, cosmetic of embodiment and comparative example is stood in 40 DEG C of thermostat, observes 3
Apparent condition after month, is evaluated based on following evaluation criterion.
[evaluation criterion]
○：It is without exception（The separation of water or oil, ooze out droplet, powder aggegation etc.）
×：There is exception（The separation of water or oil, ooze out droplet, powder aggegation etc.）
（Embodiment 1~10 and comparative example 1~11）
With the formula shown in following Tables 1 and 2s, oil-in-water type emulsion solid, cosmetic is modulated（Blush）.For what is obtained
Composition（Evaluate sample）, based on above-mentioned evaluation method, implement the evaluation of each project.Its result is merged and is shown in table 1 and table
2。
In addition, in table 1, table 2（Note 1）~（Note 5）Each raw material, this Shi Yong following commercially available products.Also, table 1
Quality % is expressed as with the compounding amount numerical value in table 2.
（Note 1）SEPINOV EMT10；SEPPIC societies system
（Note 2）SIMULGEL EG；SEPPIC societies system
（Note 3）Aristoflex AVC；Clariant societies system
（Note 4）Aristoflex HMB；Clariant societies system
（Note 5）ウ Le ト ラ agar AX-200；Ina Food Industry Co., Ltd.'s system.
[table 1]
（Modulation method）The composition of embodiment 1~5 and comparative example 1~5 is modulated using the following method.Each original of compounding 1~16
After material, aqueous portion is made in heating, dissolving 15 and 16.The oil phase part that each raw material for being compounded 17~29 is obtained and above-mentioned water phase
Part is compounded, emulsification.Then, the thing block of generation is packed into container, is allowed to cool, cures, obtained oil-in-water type emulsion and consolidate
State cosmetics.
[table 2]
（Modulation method）The composition of embodiment 6~10 and comparative example 6~11 is modulated using the following method.Each original of compounding 1~9
After material, aqueous portion is made in heating, dissolving 7~9.The oil phase part and above-mentioned water phase portion that each raw material for being compounded 10~22 is obtained
Distribution is mixed, emulsification.Then, the thing block of generation is packed into container, is allowed to cool, cures, obtain oil-in-water type emulsion solid-state
Cosmetics.
As indicated in Tables 1 and 2, as the embodiment 1~10 of the embodiment of the present invention, easiness, patch are being taken
It is attached sense, without tight feeling, continuous use when shape keeping property, crushing strength, ageing stability whole assessment items in, have
Good result.On the other hand, it is unsatisfactory for assessment item of the comparative example 1~11 it is impossible to meet whole of the composition of the present invention.
Specifically, comparative example 1~6 and 11 lacks any the one of the component of (a)~(c) as essential component of the present invention
It is a.In comparative example 1, due to lacking the acrylic amide water-soluble thickener as (b) component, easiness and continuous is taken
There are problem for shape keeping property during use.Use the comparative example 2~5 of the thickener beyond acrylic amide water-soluble thickener
In, in the shape keeping property, ageing stability when taking easiness, attaching sense, continuous use, compared with embodiment 1~10
Compared with the result being mutually on duty.Particularly, it is impossible to which shape keeping property when obtaining taking easiness and continuous use carries
Good result that is high, meeting both opposite characteristics.
In addition, in the comparative example 6 as the water soluble solid agent beyond the agar of (a) component is used, take easiness,
Adhesion, continuous use when shape keeping property, there are problem for ageing stability.In comparative example 11, (c) is used as due to lacking
The finish of component, therefore attaching is felt, without tight feeling, there are problem.
In the following, other Formulation Examples of the embodiment 11~13 as the present invention are shown.
[embodiment 11：Foundation cream]
（Compounding ingredients）（Quality %）
（1）Butanediol 15.0
（2）Glycerine 6.0
（3）Preservative qs
（4）Water surplus
（5）Sodium Hyaluronate（1 mass % aqueous solutions） 2.0
（6）（Hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate）Copolymer（Note 1） 0.3
（7）Xanthans 0.05
（8）Agar（Note 5） 1.5
（9）Gellan gum 0.15
（10）PEG-60 rilanit specials 1.2
（11）Saualane 1.0
（12）Vaseline 1.0
（13）Brazil wax 0.2
（14）Isostearic acid sorbitan ester 0.1
（15）Cyclopentasiloxane 1.0
（16）Trimethylsiloxy silicic acid 1.0
（17）Ethylhexyl methoxy cinnamate 4.0
（18）Octocrylene 2.0
（19）The own ester 1.0 of diethylamino hydroxybenzoyl benzoyl benzoic acid
（20）Natural VE 0.02
（21）The titanium oxide 7.0 of silicone-treated
（22）The yellow iron oxide 2.4 of silicone-treated
（23）The iron oxide red 0.36 of silicone-treated
（24）The iron oxide black 0.18 of silicone-treated
（25）The mica 1.0 of silicone-treated
（26）Silica 2.0
（27）Hydrolecithin 1.9.
（Preparation method）In compounding blending constituent（1）~（9）Afterwards, heat, dissolving（8）With（9）Aqueous portion is made.Will compounding
（10）~（27）Obtained oil phase part is compounded with above-mentioned aqueous portion, emulsification.Then the thing block of generation is packed into container,
It is allowed to cool, cures, obtains foundation cream.
The foundation cream of above-described embodiment 11 is the usability with water profit refrigerant sense, skin attachment is excellent, for cosmetics
The access of applicator is good, has the high foundation cream of shape keeping property when smooth use feeling and continuous use.
[embodiment 12：Eye shadow]
（Compounding ingredients）（Quality %）
（1）Butanediol 6.0
（2）Glycerine 3.0
（3）Preservative qs
（4）Water surplus
（5）（Hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate）Copolymer（Note 1） 0.2
（6）Xanthans 0.1
（7）Agar（Note 5） 2.1
（8）Gellan gum 0.1
（9）PEG-60 rilanit specials 1.2
（10）Thylhexoic acid cetyl ester 5.0
（11）Dimethyl silicone polymer 0.5
（12）Natural VE 0.02
（13）Isostearic acid sorbitan ester 0.2
（14）The yellow iron oxide 0.15 of silicone-treated
（15）The iron oxide red 0.12 of silicone-treated
（16）It is No. 226 0.12 red
（17）The mica 1.5 of silicone-treated
（18）The glass powder 12.0 of titanium-oxide-coated
（19）The mica 3.0 of titanium-oxide-coated
（20）Hydrolecithin 0.5.
（Preparation method）In compounding blending constituent（1）~（8）Afterwards, heat, dissolving（7）With（8）Aqueous portion is made.Will compounding
（9）~（20）Obtained oil phase part is compounded with above-mentioned aqueous portion, emulsification.Then the thing block of generation is packed into container,
It is allowed to cool, cures, obtains eye shadow.
The eye shadow of above-described embodiment 12 is, have the usability of water profit refrigerant sense, skin attachment it is excellent, for cosmetics
The access of applicator is good, has the high eye shadow of shape keeping property when smooth use feeling and continuous use.
[embodiment 13：Eye cream]
（Compounding ingredients）（Quality %）
（1）Butanediol 4.0
（2）Glycerine 6.0
（3）Dipropylene glycol 3.0
（4）Sodium Hyaluronate（The aqueous solution of 1 mass %） 2.0
（5）Preservative qs
（6）Water surplus
（7）（Hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate）Copolymer（Note 1） 0.6
（8）Agar（Note 5） 3.0
（9）Gellan gum 0.3
（10）PEG-60 rilanit specials 1.0
（11）Thylhexoic acid cetyl ester 2.0
（12）SIMMONDSIA CHINENSIS SEED OIL 1.0
（13）Saualane 3.0
（14）Cetostearyl alcohol 0.5
（15）Natural VE 0.01.
（Preparation method）In compounding blending constituent（1）~（9）Afterwards, heat, dissolving（8）With（9）Aqueous portion is made.Will compounding
（10）~（15）Obtained oil phase part is compounded with above-mentioned aqueous portion, emulsification.Then the thing block of generation is packed into container,
It is allowed to cool, cures, obtains eye cream.
The eye cream of above-described embodiment 13 is, has water profit refrigerant sense usability, skin attachment be excellent, for cosmetics
The access of applicator is good, has the high eye cream of shape keeping property when smooth use feeling and continuous use.
Claims (2)
- A kind of 1. oil-in-water type emulsion solid, cosmetic, it is characterised in that the component containing following (a)~(c)：(a) agar of the mass % of 1.0 mass %~3.5,(b) acrylic amide water-soluble thickener of the mass % of 0.05 mass %~1.0,(c) finish；The component (b) is to contain copolymer of the acryloyl dimethyltaurate as construction unit.
- 2. oil-in-water type emulsion solid, cosmetic according to claim 1, it is characterised in that the component (b) be from Acryloyl dimethyltaurate and hydroxy-ethyl acrylate and acrylates for the copolymer of construction unit, with acryloyldimethyl Taurate and hydroxy-ethyl acrylate are the copolymer of construction unit, using acryloyl dimethyltaurate and acrylates as knot The one or more selected in the copolymer of structure unit.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012274591A JP6082981B2 (en) | 2012-12-17 | 2012-12-17 | Oil-in-water emulsified solid cosmetic |
| JP2012-274591 | 2012-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103860396A CN103860396A (en) | 2014-06-18 |
| CN103860396B true CN103860396B (en) | 2018-04-17 |
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| JP (1) | JP6082981B2 (en) |
| KR (1) | KR101967901B1 (en) |
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| JP6009373B2 (en) * | 2013-02-28 | 2016-10-19 | 日本メナード化粧品株式会社 | Oil-in-water powder cosmetic |
| KR101997584B1 (en) * | 2017-07-14 | 2019-07-08 | 코스맥스 주식회사 | Method for molding solid cosmetic composition including gelling agents |
| JP7284092B2 (en) | 2017-10-31 | 2023-05-30 | 株式会社 資生堂 | Oil-in-water emulsified solid cosmetics |
| WO2019188795A1 (en) * | 2018-03-30 | 2019-10-03 | 株式会社マンダム | Gel cosmetic |
| JP7313860B2 (en) * | 2019-03-29 | 2023-07-25 | 花王株式会社 | Oil-in-water emulsified cosmetic |
| KR102294392B1 (en) * | 2019-08-29 | 2021-08-27 | 주식회사 코리아나화장품 | All-in-one Cosmetic Composition With Balm Type for Cooling Skin Temperature |
| JP2021130625A (en) * | 2020-02-19 | 2021-09-09 | 株式会社トキワ | Oil-in-water type solid cosmetic and cosmetic |
| JP2021138621A (en) * | 2020-03-02 | 2021-09-16 | 花王株式会社 | Oil-in-water-type emulsified cosmetic material |
| CN111419739A (en) * | 2020-04-09 | 2020-07-17 | 丽鑫生技化妆品（上海）有限公司 | Cool air cushion foundation and preparation method thereof |
| FR3117016A1 (en) * | 2020-12-07 | 2022-06-10 | ABC Texture | Cosmetic composition for sun protection in the form of a solid emulsion. |
| WO2024014279A1 (en) * | 2022-07-11 | 2024-01-18 | 株式会社資生堂 | Oil-in-water emulsion composition |
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| EP0615744A2 (en) * | 1993-03-10 | 1994-09-21 | Kose Corporation | Solid oil in water type cosmetic composition |
| CN101057815A (en) * | 2006-04-18 | 2007-10-24 | 株式会社资生堂 | Cosmetic product for skin |
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| JP3242137B2 (en) * | 1991-12-27 | 2001-12-25 | 株式会社コーセー | Oil-in-water solid cosmetics |
| JP3442108B2 (en) * | 1993-06-29 | 2003-09-02 | 株式会社コーセー | Oil-in-water solid cosmetics |
| JPH10236919A (en) * | 1997-02-26 | 1998-09-08 | Shiseido Co Ltd | Oil-in-water type solid cosmetic |
| JP3531735B2 (en) * | 2000-01-11 | 2004-05-31 | 株式会社資生堂 | Method for producing thickener and cosmetic |
| JP2003300856A (en) * | 2002-04-05 | 2003-10-21 | Fancl Corp | Cosmetic composition |
| JP4401875B2 (en) * | 2004-06-24 | 2010-01-20 | 株式会社資生堂 | Oil-in-water emulsion composition |
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| JP4341983B2 (en) * | 2007-12-07 | 2009-10-14 | 株式会社資生堂 | Topical skin preparation |
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| JP5851722B2 (en) * | 2011-05-24 | 2016-02-03 | 花王株式会社 | Makeup cosmetics |
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| EP0615744A2 (en) * | 1993-03-10 | 1994-09-21 | Kose Corporation | Solid oil in water type cosmetic composition |
| CN101057815A (en) * | 2006-04-18 | 2007-10-24 | 株式会社资生堂 | Cosmetic product for skin |
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| KR20140078572A (en) | 2014-06-25 |
| JP6082981B2 (en) | 2017-02-22 |
| JP2014118386A (en) | 2014-06-30 |
| CN103860396A (en) | 2014-06-18 |
| KR101967901B1 (en) | 2019-04-10 |
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