JP2014532784A - キレート官能性を有するポリマー - Google Patents
キレート官能性を有するポリマー Download PDFInfo
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- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
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- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
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- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
- C08F20/64—Acids; Metal salts or ammonium salts thereof
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- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
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- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1458—Monomers containing nitrogen
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- C08F220/12—Esters of monohydric alcohols or phenols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
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- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
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- C08F12/22—Oxygen
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- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
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Abstract
Description
2gのエチレンジアミンを30mlの脱イオン水に添加し、続いて8gの50%NaOH水溶液を添加した。このエチレンジアミン−NaOH溶液の温度を50℃まで上昇させた。9.45gのクロロ酢酸を、この加熱された溶液に1時間かけて添加した。全てのクロロ酢酸を添加した後、温度を70℃まで5時間にわたって上昇させ、反応の間、50%NaOHの添加によりpHを9〜10に維持した。得られた生成物は以下の化合物を記載の割合で含有していた:エチレンジアミン二酢酸(3.1%)、エチレンジアミン三酢酸(36.1%)及びエチレンジアミン四酢酸(60.3%)。
メカニカルスターラ、加熱マントル、熱電対、コンデンサ並びにモノマー、開始剤及び鎖調節剤添加用の注入口を備えた3リットル丸底フラスコに、57gのED3A−AGE未精製溶液(37.5%活性)及び60.6gの脱イオン水を投入した。溶液を撹拌し、溶液のpHが3.0未満になるまで10.9gの硫酸をゆっくりと添加した。撹拌溶液を92℃(±2℃)まで加熱した。その間に、フラスコに加えるために、203.63gの氷アクリル酸のモノマー溶液をメスシリンダーに入れた。5.01gの過硫酸ナトリウムの開始剤溶液を45gの脱イオン水に溶解させ、ケトルに加えるためにシリンジに入れた。67.5gの脱イオン水に溶解させた20.86gの次亜リン酸ナトリウムの鎖調節剤溶液を、ケトルに加えるためにシリンジに入れた。0.75gの0.15%硫酸鉄七水和物溶液のプロモーター溶液をバイアルに入れ、取り置いた。
メカニカルスターラ、加熱マントル、熱電対、コンデンサ並びにモノマー、開始剤及び鎖調節剤添加用の注入口を備えた3リットル丸底フラスコに、30gのED3A−AGE未精製溶液(37.5%活性)及び60.6gの脱イオン水を投入した。溶液を撹拌し、溶液のpHが3.0未満になるまで10.9gの硫酸をゆっくりと添加した。撹拌溶液を92℃(±2℃)まで加熱した。その間に、フラスコに加えるために、213.75gの氷アクリル酸のモノマー溶液をメスシリンダーに入れた。5.01gの過硫酸ナトリウムの開始剤溶液を45gの脱イオン水に溶解させ、ケトルに加えるためにシリンジに入れた。16.69gの脱イオン水に溶解させた20.86gの次亜リン酸ナトリウムの鎖調節剤溶液を、ケトルに加えるためにシリンジに入れた。0.75gの0.15%硫酸鉄七水和物溶液のプロモーター溶液をバイアルに入れ、取り置いた。
メカニカルスターラ、加熱マントル、熱電対、コンデンサ並びにモノマー、開始剤及び鎖調節剤添加用の注入口を備えた3リットル丸底フラスコに、39.86gのED3A−AGE未精製溶液(37.5%活性)、17.75gの無水マレイン酸及び100mLの脱イオン水を投入した。溶液を撹拌し、溶液のpHが3.0未満になるまで3.1gの硫酸をゆっくりと添加した。撹拌溶液を78℃(±2℃)まで加熱した。その間に、フラスコに加えるために、270gの氷アクリル酸のモノマー溶液をメスシリンダーに入れた。6.66gの過硫酸ナトリウムの開始剤溶液を20gの脱イオン水に溶解させ、ケトルに加えるためにシリンジに入れた。120gの脱イオン水に溶解させた54.05gのメタ重亜硫酸ナトリウムの鎖調節剤溶液を、ケトルに加えるためにシリンジに入れた。1gの0.15%硫酸鉄七水和物溶液のプロモーター溶液をバイアルに入れ、取り置いた。
メカニカルスターラ、加熱マントル、熱電対、コンデンサ並びにモノマー、開始剤及び鎖調節剤添加用の注入口を備えた3リットル丸底フラスコに、54gのED3A−AGE未精製溶液(37.5%活性)及び127.5gの脱イオン水を投入した。溶液を撹拌し、溶液のpHが3.0未満になるまで10.6gの硫酸をゆっくりと添加した。撹拌溶液を78℃(±2℃)まで加熱した。その間に、フラスコに加えるために、148.5gの氷アクリル酸のモノマー溶液及び112.5gの2−アクリルアミド−2−メチルプロパンスルホン酸(AMPS)をメスシリンダーに入れた。5.01gの過硫酸ナトリウムの開始剤溶液を45gの脱イオン水に溶解させ、ケトルに加えるためにシリンジに入れた。93gの脱イオン水に溶解させた28.35gのメタ重亜硫酸ナトリウムの鎖調節剤溶液を、ケトルに加えるためにシリンジに入れた。0.75gの0.15%硫酸鉄七水和物溶液のプロモーター溶液をバイアルに入れ、取り置いた。
Claims (9)
- 前記一価又は多価カチオンが、Na+、K+、NH4 +、有機アンモニウムイオン、Ca2+及びMg2+から成る群から選択され得る、請求項1に記載のポリマー。
- (b)1種以上のエチレン性不飽和モノマー
由来の単位を更に含む、請求項1に記載のポリマー。 - 前記1種以上のエチレン性不飽和モノマーが、カルボン酸、カルボン酸のエステル、カルボン酸無水物、イミド、アミド、スチレン、スルホン酸及びこれらの組み合わせから成る群から選択される、請求項7に記載のポリマー。
- (a)0.5〜99.5重量%の前記エチレン性不飽和アミノカルボキシレートモノマー及び(b)99.5〜0.5重量%の前記1種以上のエチレン性不飽和モノマーをポリマーの総重量を基準として含む、請求項7に記載のポリマー。
Applications Claiming Priority (3)
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US201161553642P | 2011-10-31 | 2011-10-31 | |
US61/553,642 | 2011-10-31 | ||
PCT/US2012/062681 WO2013066934A1 (en) | 2011-10-31 | 2012-10-31 | Polymers having chelating functionality |
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JP2014532784A true JP2014532784A (ja) | 2014-12-08 |
JP6196226B2 JP6196226B2 (ja) | 2017-09-13 |
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JP2014539152A Active JP6196226B2 (ja) | 2011-10-31 | 2012-10-31 | キレート官能性を有するポリマー |
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US (1) | US9346899B2 (ja) |
EP (1) | EP2751148B1 (ja) |
JP (1) | JP6196226B2 (ja) |
KR (1) | KR102053472B1 (ja) |
CN (1) | CN104024288A (ja) |
AR (1) | AR088496A1 (ja) |
AU (1) | AU2012332652B2 (ja) |
BR (1) | BR112014009324A2 (ja) |
MX (1) | MX343901B (ja) |
TW (1) | TWI490239B (ja) |
WO (1) | WO2013066934A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2018090786A (ja) * | 2016-11-28 | 2018-06-14 | 株式会社日本触媒 | カルボキシル基含有共重合体 |
JP2018131603A (ja) * | 2017-02-15 | 2018-08-23 | 株式会社日本触媒 | カルボキシル基含有共重合体の製造方法 |
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AR088494A1 (es) * | 2011-10-31 | 2014-06-11 | Rohm & Haas | Monomeros de vinilo con funcionalidad quelante |
WO2013130357A1 (en) | 2012-02-28 | 2013-09-06 | Rohm And Haas Company | Coating compositions having chelant functionality |
CN104284953B (zh) | 2012-03-07 | 2016-09-07 | 罗门哈斯公司 | 具有螯合剂官能团的涂料组合物 |
CN104870627A (zh) * | 2012-12-19 | 2015-08-26 | 罗门哈斯公司 | 自动餐具洗涤剂 |
WO2015034766A2 (en) * | 2013-09-05 | 2015-03-12 | Rohm And Haas Company | Automatic dishwashing detergent with synergistic scale inhibition |
CN105169954A (zh) * | 2015-09-10 | 2015-12-23 | 韩功篑 | 一种海水淡化用反渗透阻垢剂及其制备方法 |
WO2018097206A1 (ja) | 2016-11-28 | 2018-05-31 | 株式会社日本触媒 | カルボキシル基含有共重合体及びその製造方法 |
CN107043433A (zh) * | 2017-03-22 | 2017-08-15 | 中国市政工程中南设计研究总院有限公司 | 一种重金属废水处理树脂及其制备方法和应用 |
CN108793440A (zh) * | 2017-05-04 | 2018-11-13 | 中国石油化工股份有限公司 | 一种循环冷却水低温阻垢剂组合物及其应用 |
CN110526424A (zh) * | 2019-09-10 | 2019-12-03 | 上海丰信环保科技有限公司 | 一种无磷阻垢缓蚀剂及其制备方法 |
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JP2018090786A (ja) * | 2016-11-28 | 2018-06-14 | 株式会社日本触媒 | カルボキシル基含有共重合体 |
JP7125194B2 (ja) | 2016-11-28 | 2022-08-24 | 株式会社日本触媒 | カルボキシル基含有共重合体 |
JP2018131603A (ja) * | 2017-02-15 | 2018-08-23 | 株式会社日本触媒 | カルボキシル基含有共重合体の製造方法 |
JP7125203B2 (ja) | 2017-02-15 | 2022-08-24 | 株式会社日本触媒 | カルボキシル基含有共重合体の製造方法 |
Also Published As
Publication number | Publication date |
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KR102053472B1 (ko) | 2019-12-06 |
US9346899B2 (en) | 2016-05-24 |
TWI490239B (zh) | 2015-07-01 |
CN104024288A (zh) | 2014-09-03 |
TW201321421A (zh) | 2013-06-01 |
AU2012332652B2 (en) | 2016-03-17 |
EP2751148A1 (en) | 2014-07-09 |
JP6196226B2 (ja) | 2017-09-13 |
AR088496A1 (es) | 2014-06-11 |
EP2751148B1 (en) | 2017-06-28 |
AU2012332652A1 (en) | 2014-04-24 |
BR112014009324A2 (pt) | 2017-04-11 |
US20140303337A1 (en) | 2014-10-09 |
KR20140087033A (ko) | 2014-07-08 |
MX2014005286A (es) | 2014-05-30 |
WO2013066934A1 (en) | 2013-05-10 |
MX343901B (es) | 2016-11-28 |
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