JP2014527553A - 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 - Google Patents
1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 Download PDFInfo
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- JP2014527553A JP2014527553A JP2014523063A JP2014523063A JP2014527553A JP 2014527553 A JP2014527553 A JP 2014527553A JP 2014523063 A JP2014523063 A JP 2014523063A JP 2014523063 A JP2014523063 A JP 2014523063A JP 2014527553 A JP2014527553 A JP 2014527553A
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- Prior art keywords
- foam
- chloro
- trifluoropropene
- building
- trans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims abstract description 134
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 42
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 64
- 239000004604 Blowing Agent Substances 0.000 claims description 49
- 229920005862 polyol Polymers 0.000 claims description 41
- 150000003077 polyols Chemical class 0.000 claims description 40
- 229920002635 polyurethane Polymers 0.000 claims description 22
- 239000004814 polyurethane Substances 0.000 claims description 22
- 229920000582 polyisocyanurate Polymers 0.000 claims description 21
- 239000011495 polyisocyanurate Substances 0.000 claims description 21
- 238000012360 testing method Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 15
- 230000004580 weight loss Effects 0.000 claims description 12
- 238000010276 construction Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 3
- 239000011496 polyurethane foam Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 description 33
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 19
- -1 but not limited to Chemical compound 0.000 description 17
- 229920001228 polyisocyanate Polymers 0.000 description 17
- 239000005056 polyisocyanate Substances 0.000 description 17
- 229920001296 polysiloxane Polymers 0.000 description 16
- 239000004094 surface-active agent Substances 0.000 description 15
- 238000009413 insulation Methods 0.000 description 13
- 210000004027 cell Anatomy 0.000 description 12
- 239000012948 isocyanate Substances 0.000 description 12
- 238000009472 formulation Methods 0.000 description 10
- 150000002513 isocyanates Chemical class 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 7
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 5
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical class FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 4
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 4
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 4
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 4
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 4
- 210000000497 foam cell Anatomy 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical class COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- 239000011493 spray foam Substances 0.000 description 4
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 4
- FYIRUPZTYPILDH-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)C(F)(F)F FYIRUPZTYPILDH-UHFFFAOYSA-N 0.000 description 3
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 3
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical class CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920005903 polyol mixture Polymers 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000005829 trimerization reaction Methods 0.000 description 3
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical class CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 2
- 229940051271 1,1-difluoroethane Drugs 0.000 description 2
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical class O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 2
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 210000003850 cellular structure Anatomy 0.000 description 2
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 2
- 229940099364 dichlorofluoromethane Drugs 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical class COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000012757 flame retardant agent Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000011900 installation process Methods 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical class Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 2
- 229940029284 trichlorofluoromethane Drugs 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- DHNUXDYAOVSGII-UHFFFAOYSA-N tris(1,3-dichloropropyl) phosphate Chemical compound ClCCC(Cl)OP(=O)(OC(Cl)CCCl)OC(Cl)CCCl DHNUXDYAOVSGII-UHFFFAOYSA-N 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 1
- VCXFUFLOPQBNOT-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane 1,1,1,2,2-pentafluoropropane Chemical class FC(C(F)(F)F)(C)F.FC(CC(F)(F)F)(F)F VCXFUFLOPQBNOT-UHFFFAOYSA-N 0.000 description 1
- NLOLSXYRJFEOTA-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)C=CC(F)(F)F NLOLSXYRJFEOTA-UHFFFAOYSA-N 0.000 description 1
- OTPDWCMLUKMQNO-UHFFFAOYSA-N 1,2,3,4-tetrahydropyrimidine Chemical compound C1NCC=CN1 OTPDWCMLUKMQNO-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- WCFAPJDPAPDDAQ-UHFFFAOYSA-N 1,2-dihydropyrimidine Chemical compound C1NC=CC=N1 WCFAPJDPAPDDAQ-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical class O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
- DTZHXCBUWSTOPO-UHFFFAOYSA-N 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(CC=2C=C(C)C(N=C=O)=CC=2)=C1 DTZHXCBUWSTOPO-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- MELCWEWUZODSIS-UHFFFAOYSA-N 2-[2-(diethylamino)ethoxy]-n,n-diethylethanamine Chemical compound CCN(CC)CCOCCN(CC)CC MELCWEWUZODSIS-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- CJWBPEYRTPGWPF-UHFFFAOYSA-N 2-[bis(2-chloroethoxy)phosphoryloxy]ethyl bis(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCOP(=O)(OCCCl)OCCCl CJWBPEYRTPGWPF-UHFFFAOYSA-N 0.000 description 1
- CCJKFLLIJCGHMO-UHFFFAOYSA-N 2-[diethoxyphosphorylmethyl(2-hydroxyethyl)amino]ethanol Chemical compound CCOP(=O)(OCC)CN(CCO)CCO CCJKFLLIJCGHMO-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- ZWXQPERWRDHCMZ-UHFFFAOYSA-N 2-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)NC(C)(C)C ZWXQPERWRDHCMZ-UHFFFAOYSA-N 0.000 description 1
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
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- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- BZVJOYBTLHNRDW-UHFFFAOYSA-N triphenylmethanamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(N)C1=CC=CC=C1 BZVJOYBTLHNRDW-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- KVMPUXDNESXNOH-UHFFFAOYSA-N tris(1-chloropropan-2-yl) phosphate Chemical compound ClCC(C)OP(=O)(OC(C)CCl)OC(C)CCl KVMPUXDNESXNOH-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
- E04B1/941—Building elements specially adapted therefor
- E04B1/942—Building elements specially adapted therefor slab-shaped
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/20—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
- E04C2/205—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics of foamed plastics, or of plastics and foamed plastics, optionally reinforced
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
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- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249954—With chemically effective material or specified gas other than air, N, or carbon dioxide in void-containing component
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- Health & Medical Sciences (AREA)
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- Polymers & Plastics (AREA)
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- Electromagnetism (AREA)
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- Finishing Walls (AREA)
Abstract
Description
本発明は、比較的高いレベルの断熱値及び安全性/耐燃焼性を有する、フォーム及び建物外皮などの物品を形成する方法に関する。
ジモルホリノジエチルエーテル;
N−エチルモルホリン;
N−メチルモルホリン;
ビス(ジメチルアミノエチル)エーテル;
イミジゾール;
n−メチルイミダゾール;
1,2−ジメチルイミダゾール;
ジモルホリノジメチルエーテル;
N,N,N’,N’,N”,N”−ペンタメチルジエチレントリアミン;
N,N,N’,N’,N”,N”−ペンタエチルジエチレントリアミン;
N,N,N’,N’,N”,N”−ペンタメチルジプロピレントリアミン;
ビス(ジエチルアミノエチル)エーテル;
ビス(ジメチルアミノプロピル)エーテル;
が挙げられる。
R(NCO)z
(式中、Rは、脂肪族、アラルキル、芳香族、又はこれらの混合物である多価有機基であり、zはRの価数に対応する整数であり、少なくとも2である)
に対応する。本発明において意図する有機ポリイソシアネートの代表例としては、例えば、2,4−トルエンジイソシアネート、2,6−トルエンジイソシアネート、2,4−及び2,6−トルエンジイソシアネートの混合物、粗トルエンジイソシアネート、メチレンジフェニルジイソシアネート、粗メチレンジフェニルジイソシアネートなどのような芳香族ジイソシアネート;4,4’,4”−トリフェニルメタントリイソシアネート、2,4,6−トルエントリイソシアネートのような芳香族トリイソシアネート;4,4’−ジメチルジフェニルメタン−2,2’,5,5’−テトライソシアネートなどのような芳香族テトライソシアネート;キシリレンジイソシアネートのようなアリールアルキルポリイソシアネート;ヘキサメチレン−1,6−ジイソシアネート、リシンジイソシアネートメチルエステルなどのような脂肪族ポリイソシアネート;並びにこれらの混合物;が挙げられる。他の有機ポリイソシアネートとしては、ポリメチレンポリフェニルイソシアネート、水素化メチレンジフェニルイソシアネート、m−フェニレンジイソシアネート、ナフチレン−1,5−ジイソシアネート、1−メトキシフェニレン−2,4−ジイソシアネート、4,4’−ビフェニレンジイソシアネート、3,3’−ジメトキシ−4,4’−ビフェニルジイソシアネート、3,3’−ジメチル−4,4’−ビフェニルジイソシアネート、及び3,3’−ジメチルジフェニルメタン−4,4’−ジイソシアネートが挙げられ;代表的な脂肪族ポリイソシアネートは、トリメチレンジイソシアネート、テトラメチレンジイソシアネート、及びヘキサメチレンジイソシアネート、イソホレンジイソシアネート、4,4’−メチレンビス(シクロヘキシルイソシアネート)などのようなアルキレンジイソシアネートであり;代表的な芳香族ポリイソシアネートとしては、m−及びp−フェニレンジイソシアネート、ポリメチレンポリフェニルイソシアネート、2,4−及び2,6−トルエンジイソシアネート、ジアニシジンジイソシアネート、ビトイレンイソシアネート、ナフチレン−1,4−ジイソシアネート、ビス(4−イソシアナトフェニル)メテン、ビス(2−メチル−4−イソシアナトフェニル)メタンなどが挙げられる。好ましいポリイソシアネートは、ポリメチレンポリフェニルイソシアネート、特に、約30〜約85重量%のメチレンビス(フェニルイソシアネート)を含み、混合物の残りが2より高い官能価のポリメチレンポリフェニルポリイソシアネートを含む混合物である。これらのポリイソシアネートは、当該技術において公知の通常の方法によって製造される。本発明においては、約0.9〜約5.0の範囲のNCO/OH化学量論比を与える量のポリイソシアネート及びポリオールを用いる。本発明においては、NCO/OH当量比は、好ましくは約1.0以上で約3.0以下であり、理想的な範囲は約1.1〜約2.5である。特に好適な有機ポリイソシアネートとしては、ポリメチレンポリフェニルイソシアネート、メチレンビス(フェニルイソシアネート)、トルエンジイソシアネート、又はこれらの組み合わせが挙げられる。
実施例1:フォーム配合物。
用いたフォーム配合物はより高い指数の配合物であった。これは、同じ配合物中で発泡剤の比較をすることができるジェネリックな配合物であり、下記において表1に与える。
実施例1にしたがってフォームを製造した。モービル45°試験によってこれらを燃焼性に関して試験した。より具体的には、1.3cm(1/2インチ)の寸法に沿って平行なフォームライズを有する5.1cm×21.6cm×1.3cm(2インチ×8.5インチ×1/2インチ)の寸法の少なくとも3つの試験片を準備した。それぞれの試料を0.01g(0.0004オンス)の単位まで秤量してW0として記録した。
重量損失%=(W0−W1)/W0)×100
のようにして損失%を算出して記録した。
実施例1にしたがってフォームを製造した。ASTM−E84によってこれらを燃焼性に関して試験した。
上記の実施例1及び表1において規定する成分及び量を用いて、1つは発泡剤として1233zdを有し、他方はHFC−245faを有する2つの試料フォームのA側及びB側のプレミックスを調製した。A側の部分はイソシアネート成分を含み、B側の部分は、ポリオール混合物界面活性剤、触媒、難燃剤、及び発泡剤(1233zd(E)又はHFC−245fa)を含んでいた。実施例1及び表2に規定する装置及び方法を用いて、A側成分とB側成分の1233zdプレミックス及びHFC−245faプレミックスを独立して混合し、建物外皮の骨組構造体(合板製のスタッド及び外壁を有する構造体)中に噴霧し、硬化させた。30℃及び30%の湿度においてフォームを形成した。
重量損失%=(W0−W1)/W0)×100
のようにして損失%を算出して記録した。
重量損失%=(W0−W1)/W0)×100
のようにして損失%を算出して記録した。
Claims (20)
- (a)建物外皮の基材又は構成要素として含ませる物品を準備し;
(b)かかる物品から建物外皮の少なくとも一部を形成し;
(c)工程(b)の前又は後のいずれかにおいて、気泡の少なくとも一部の中にトランス−1−クロロ−3,3,3−トリフルオロプロペン(1233zd(E))を含む気体材料を有する独立気泡ポリマー構造体を含むフォームを物品の上及び/又は中に施工する;
ことを含む建物外皮を形成する方法。 - 施工工程が、1233zd(E)を含む発泡剤を含むポリオールフォームプレミックス組成物を与え、かかるポリオールフォームプレミックス組成物を物品上に噴霧することを含む、請求項1に記載の方法。
- 施工工程を形成工程(b)の後に行う、請求項2に記載の方法。
- 施工工程を形成工程(b)の前に行う、請求項2に記載の方法。
- 施工工程が、フォームパネル又はボードを形成し、かかるパネル又はボードの少なくとも一部を物品に取り付けることを含む、請求項1に記載の方法。
- 施工工程を形成工程(b)の後に行う、請求項5に記載の方法。
- 施工工程を形成工程(b)の前に行う、請求項5に記載の方法。
- 物品が建物外皮の表面又は中空部の一部を構成する、請求項1に記載の方法。
- 独立気泡フォームが、モービル45°試験を用いて試験して1.0%未満の重量損失を示す、請求項1に記載の方法。
- 独立気泡フォームが、モービル45°試験を用いて試験して0.5%未満の重量損失を示す、請求項1に記載の方法。
- 気泡の大部分がトランス−1−クロロ−3,3,3−トリフルオロプロペンを含む気体を含む、請求項1に記載の方法。
- 気泡内の気体が少なくとも50体積%のトランス−1−クロロ−3,3,3−トリフルオロプロペンを含む、請求項11に記載の方法。
- 気泡内の気体が少なくとも70体積%のトランス−1−クロロ−3,3,3−トリフルオロプロペンを含む、請求項11に記載の方法。
- (a)発泡剤としてトランス−1−クロロ−3,3,3−トリフルオロプロペン(1233zd(E))を含む発泡性組成物を与え;
(b)発泡性組成物を成形型中又はコンベヤー上に注ぎ入れてフォームパネル又はボードを形成し;
(c)発泡性組成物を硬化させて、気泡内に1233zd(E)を含む気体材料を有する気泡を含む独立気泡ポリウレタンフォームを形成し;そして
(d)かかるパネル又はボードを含む建物外皮を形成する;
ことを含む、ポリウレタン又はポリイソシアヌレートフォームパネル又はボードを建物外皮に施工する方法。 - 形成工程が、パネル又はボードを建物外皮内の壁、床、又は天井の中空部中に挿入することを含む、請求項14に記載の方法。
- 独立気泡フォームが、モービル45°試験を用いて試験して1.0%未満の重量損失を示す、請求項15に記載の方法。
- 独立気泡フォームが、モービル45°試験を用いて試験して0.5%未満の重量損失を示す、請求項15に記載の方法。
- 気泡内の気体が少なくとも50体積%のトランス−1−クロロ−3,3,3−トリフルオロプロペンを含む、請求項17に記載の方法。
- 気泡内の気体が少なくとも70体積%のトランス−1−クロロ−3,3,3−トリフルオロプロペンを含む、請求項17に記載の方法。
- 請求項19に記載の方法にしたがって製造される住居、商業ビル、オフィスビル、又は船舶。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161512742P | 2011-07-28 | 2011-07-28 | |
US61/512,742 | 2011-07-28 | ||
PCT/US2012/048538 WO2013016632A2 (en) | 2011-07-28 | 2012-07-27 | Foams and flame resistant articles made from foams containing 1-chloro-3,3,3-trifluoropropene (1233zd) |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017064112A Division JP2017141465A (ja) | 2011-07-28 | 2017-03-29 | 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 |
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JP2014523063A Withdrawn JP2014527553A (ja) | 2011-07-28 | 2012-07-27 | 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 |
JP2017064112A Pending JP2017141465A (ja) | 2011-07-28 | 2017-03-29 | 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 |
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JP2017064112A Pending JP2017141465A (ja) | 2011-07-28 | 2017-03-29 | 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 |
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Country | Link |
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US (1) | US20140220333A1 (ja) |
EP (1) | EP2737006A4 (ja) |
JP (2) | JP2014527553A (ja) |
KR (1) | KR20140053212A (ja) |
CN (1) | CN103814108B (ja) |
AU (1) | AU2012286730B2 (ja) |
BR (1) | BR112014002096A2 (ja) |
CA (1) | CA2843012A1 (ja) |
ES (1) | ES2529170T1 (ja) |
MX (1) | MX353653B (ja) |
RU (2) | RU2016137830A (ja) |
WO (1) | WO2013016632A2 (ja) |
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WO2019005837A1 (en) | 2017-06-27 | 2019-01-03 | Albemarle Corporation | FLAME RETARDED POLYURETHANE FOAM |
ES2966321T3 (es) | 2017-09-28 | 2024-04-19 | Albemarle Corp | Pirorretardante bromado y su aplicación en espumas de poliuretano |
CN108192065A (zh) * | 2017-12-28 | 2018-06-22 | 青岛海尔股份有限公司 | 聚氨酯硬质泡沫塑料及其制备方法 |
US11299882B2 (en) | 2018-12-03 | 2022-04-12 | Johns Manville | Foam insulation with improved low temperature properties using polyol additives |
CA3127217A1 (en) * | 2019-02-01 | 2020-08-06 | Honeywell International Inc. | Thermosetting foams having improved insulating value |
US11732081B2 (en) | 2021-06-08 | 2023-08-22 | Covestro Llc | HCFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams |
US11905707B2 (en) | 2021-06-29 | 2024-02-20 | Covestro Llc | Foam wall structures and methods for their manufacture |
US11767394B2 (en) | 2021-12-09 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
US11767407B1 (en) | 2022-04-21 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
US11827735B1 (en) | 2022-09-01 | 2023-11-28 | Covestro Llc | HFO-containing isocyanate-reactive compositions, related foam-forming compositions and flame retardant PUR-PIR foams |
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2012
- 2012-07-27 KR KR20147004414A patent/KR20140053212A/ko not_active Application Discontinuation
- 2012-07-27 AU AU2012286730A patent/AU2012286730B2/en not_active Ceased
- 2012-07-27 JP JP2014523063A patent/JP2014527553A/ja not_active Withdrawn
- 2012-07-27 RU RU2016137830A patent/RU2016137830A/ru not_active Application Discontinuation
- 2012-07-27 RU RU2014106349/03A patent/RU2014106349A/ru not_active Application Discontinuation
- 2012-07-27 CN CN201280046427.4A patent/CN103814108B/zh not_active Expired - Fee Related
- 2012-07-27 MX MX2014000883A patent/MX353653B/es active IP Right Grant
- 2012-07-27 ES ES12818430.6T patent/ES2529170T1/es active Pending
- 2012-07-27 CA CA 2843012 patent/CA2843012A1/en not_active Abandoned
- 2012-07-27 WO PCT/US2012/048538 patent/WO2013016632A2/en active Application Filing
- 2012-07-27 EP EP12818430.6A patent/EP2737006A4/en not_active Withdrawn
- 2012-07-27 BR BR112014002096A patent/BR112014002096A2/pt not_active Application Discontinuation
- 2012-07-27 US US14/233,929 patent/US20140220333A1/en not_active Abandoned
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2017
- 2017-03-29 JP JP2017064112A patent/JP2017141465A/ja active Pending
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JP2021155757A (ja) * | 2016-12-20 | 2021-10-07 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、裏込め注入用硬質ポリイソシアヌレートフォーム及び裏込め注入工法 |
JP7268090B2 (ja) | 2016-12-20 | 2023-05-02 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、及び裏込め注入用硬質ポリイソシアヌレートフォーム |
JP7509950B2 (ja) | 2016-12-20 | 2024-07-02 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、及び裏込め注入用硬質ポリイソシアヌレートフォーム |
Also Published As
Publication number | Publication date |
---|---|
AU2012286730A1 (en) | 2014-02-13 |
MX353653B (es) | 2018-01-23 |
MX2014000883A (es) | 2014-03-27 |
RU2014106349A (ru) | 2015-09-10 |
BR112014002096A2 (pt) | 2017-06-13 |
CA2843012A1 (en) | 2013-01-31 |
EP2737006A4 (en) | 2015-11-04 |
RU2016137830A (ru) | 2018-12-12 |
AU2012286730B2 (en) | 2017-04-20 |
WO2013016632A2 (en) | 2013-01-31 |
EP2737006A2 (en) | 2014-06-04 |
JP2017141465A (ja) | 2017-08-17 |
KR20140053212A (ko) | 2014-05-07 |
CN103814108B (zh) | 2016-08-24 |
CN103814108A (zh) | 2014-05-21 |
WO2013016632A3 (en) | 2013-04-25 |
ES2529170T1 (es) | 2015-02-17 |
US20140220333A1 (en) | 2014-08-07 |
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