JP2014524418A - 水溶性界面活性剤の処理に有用な液液抽出組成物 - Google Patents
水溶性界面活性剤の処理に有用な液液抽出組成物 Download PDFInfo
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- JP2014524418A JP2014524418A JP2014524071A JP2014524071A JP2014524418A JP 2014524418 A JP2014524418 A JP 2014524418A JP 2014524071 A JP2014524071 A JP 2014524071A JP 2014524071 A JP2014524071 A JP 2014524071A JP 2014524418 A JP2014524418 A JP 2014524418A
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005862 polyol Chemical group 0.000 description 1
- 150000003077 polyols Chemical group 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical group 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229910001432 tin ion Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940072029 trilaureth-4 phosphate Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0403—Solvent extraction of solutions which are liquid with a supercritical fluid
- B01D11/0407—Solvent extraction of solutions which are liquid with a supercritical fluid the supercritical fluid acting as solvent for the solute
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/08—Sulfation or sulfonation products of fats, oils, waxes, or higher fatty acids or esters thereof with monovalent alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/14—Derivatives of phosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/18—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/03—Liquid compositions with two or more distinct layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cosmetics (AREA)
- Extraction Or Liquid Replacement (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
a.組成物の約5重量%〜約60重量%の水溶性界面活性剤;
b.組成物の約10重量%〜約90重量%の水;
c.組成物の約10重量%〜約90重量%の抽出溶媒;
d.組成物の少なくとも0.01重量%の望ましくない非極性材料;を含有し、
抽出溶媒は、約15〜約17(MPa)0.5の範囲の分散力成分(δD)、0〜約9(MPa)0.5の範囲の極性成分(δP)、及び0〜約11(MPa)0.5の範囲の水素結合成分(δH)の、個々のハンセン溶解度パラメーターを有する溶媒から選択される。
本発明の組成物は、組成物の約5重量%〜約60重量%の水溶性界面活性剤を含有する。一実施形態では、本発明の組成物は、組成物の約10重量%〜約50重量%、あるいは約20重量%〜約30重量%の水溶性界面活性剤を含有する。
場合により、1つ以上のホスフェート基で置換され、n及びmは、個々に及び別々に2〜4であり、a及びbは、個々に及び別々に0〜20であり、Z2及びZ3は、同一であっても又は異なってもよく、それぞれ水素、アルカリ金属、アンモニウム、プロトン化アルキルアミン若しくはアルカノールアミンなどのプロトン化官能性アルキルアミン、又はR1−(OCnH2n)a(OCmH2m)b−基を表す。好適な作用剤の例としては、アルキル及びアルキル(ポリ)アルコキシホスフェート、例えばリン酸ラウリル;PPG5セテアレス−10ホスフェート;ラウレス−1ホスフェート;ラウレス−3ホスフェート;ラウレス−9ホスフェート;トリラウレス−4ホスフェート;C12〜18のPEG 9ホスフェート;ジラウレス−10リン酸ナトリウムが挙げられる。一実施形態では、アルキルホスフェートは高分子である。高分子アルキルホスフェートの例としては、高分子部分としての反復アルコキシ基、具体的には、3個以上のエトキシ基、プロポキシイソプロポキシ基又はブトキシ基を含むものが挙げられる。
本発明の組成物は、組成物の約10重量%〜約90重量%の水を含有する。一実施形態では、組成物は、組成物の約30重量%〜約90重量%の水を含有する。一実施形態では、本発明の組成物は、組成物の約50重量%〜約90重量%、あるいは約50重量%〜約70重量%の水を含有する。
本明細書の組成物は、組成物の約10重量%〜約90重量%の抽出溶媒を含有する。一実施形態では、組成物は、組成物の約20重量%〜約80重量%の抽出溶媒、あるいは約30重量%〜約70重量%の抽出溶媒を含有する。
本発明の組成物は、少なくとも0.01%の望ましくない非極性材料を含有する。一実施形態では、組成物は、組成物の約0.01重量%〜約20重量%の望ましくない非極性材料を含有する。一実施形態では、組成物は、全て組成物の重量により約0.01%〜約10%、あるいは約0.01%〜約7%、あるいは約0.1%〜約5%の望ましくない非極性材料を含有する。
本明細書で使用されるとき、溶媒抽出及び分割としても既知の液液抽出は、2つの異なる不混和性液体、本明細書では水及び溶媒中での化合物の相対的な溶解度に基づいて該化合物を分離する標準的な方法を指す。これは一つの液相から他の液相中への物質の抽出である。「液液」相は、抽出手順の一部として混合される、2つの異なる不混和性液体を指す。本明細書で使用されるとき、不混和性とは、液体が互いに混合された際に少なくとも2層を形成する能力を指す。層は2つの液体が混合され、不定期間静置された後に形成され得、又は場合によっては、2つの液体の混合物が遠心分離され及び/若しくは室温未満に冷却されて分離を補助する。
本明細書に開示した組成物は、水溶性界面活性剤と、1つ以上の望ましくない非極性材料とを含有する。本明細書で有用な、望ましくない非極性材料を含む水溶液中の水溶性界面活性剤には、Rhodia(Spartanburg,South Carolina,USA所在)、Stepan(Metamoros,Mexico及びWinder,Georgia,USA所在)、Croda(Edison,New Jersey,USA所在)及びClariant(Charlotte,North Carolina,USA所在などの供給元から市販されているものが挙げられる。
本明細書で使用されるとき、「水相」は、水、水溶性界面活性剤、及び他の水溶性材料を含有する本明細書の組成物の一部分を指す。
本明細書で使用されるとき、「溶媒相」は、抽出溶媒、望ましくない非極性材料、及び他の水−不溶性材料を含有する本明細書の組成物の一部分を指す。
MAP L213/S界面活性剤を含有する組成物
本発明による組成物は、Rhodiaにより供給され、かつ望ましくない非極性材料及び水を含むMAP L213/Sモノアルキルホスフェート界面活性剤を、抽出溶媒としての酢酸エチル(Honeywell Burdick & Jackson,Muskegon MI,USAにより供給)と組み合わせることにより作製した。
ココアミドプロピルベタイン界面活性剤を含有する組成物
本発明による組成物は、Stepan,Mexico SA DE CV(Matamoros,MX)により供給され、かつ望ましくない非極性材料及び水を含むココアミドプロピルベタイン界面活性剤を、抽出溶媒としての酢酸エチル(Honeywell Burdick & Jackson,Muskegon,MI,USAにより供給)と組み合わせることにより作製した。
ラウリルベタイン界面活性剤を含有する組成物
本発明による組成物は、Mason Chemical Company(Arlington Heights,IL,USA)により供給され、かつ望ましくない非極性材料及び水を含むラウリルベタイン界面活性剤を、抽出溶媒としての酢酸エチル(Honeywell Burdick & Jackson,Muskegon,MI,USAにより供給)と組み合わせることにより作製した。
ラウリル硫酸ナトリウム界面活性剤を含有する組成物
本発明による組成物は、Stepan(Winder,GA,USA)により供給され、かつ望ましくない非極性材料及び水を含むラウリル硫酸ナトリウム界面活性剤を、抽出溶媒としての酢酸エチル(Honeywell Burdick & Jackson,Muskegon,MI,USAにより供給)と組み合わせることにより作製した。
Claims (10)
- 水溶性界面活性剤の味を改善する液液抽出プロセスにて有用な組成物であって、
a.前記組成物の5重量%〜60重量%の水溶性界面活性剤;
b.前記組成物の10重量%〜90重量%の水;
c.前記組成物の10重量%〜90重量%の抽出溶媒;
d.前記組成物の少なくとも0.01重量%の望ましくない非極性材料;を含有し、
前記抽出溶媒が、15〜17(MPa)0.5の範囲の分散力成分(δD)、0〜9(MPa)0.5の範囲の極性成分(δP)、及び0〜11(MPa)0.5の範囲の水素結合成分(δH)の、個々のハンセン溶解度パラメーターを有する溶媒から選択される、組成物。 - 水相及び溶媒相を含む、請求項1に記載の組成物。
- 前記水相が、前記水溶性界面活性剤及び水を含む、請求項2に記載の組成物。
- 前記溶媒相が、前記抽出溶媒及び少なくとも1つの望ましくない非極性材料を含む、請求項2又は請求項3に記載の組成物。
- 前記水溶性界面活性剤が、陰イオン性界面活性剤、双性イオン性界面活性剤、両性界面活性剤、及びこれらの混合物から選択され、かつ少なくとも30%水溶性である、請求項1〜4のいずれか一項に記載の組成物。
- 前記水溶性界面活性剤が、アルキルホスフェート界面活性剤、アルキルホスフェートエトキシル化界面活性剤、ラウリルサルフェート界面活性剤、ベタイン界面活性剤、ベタインエトキシル化界面活性剤、アミンオキシド界面活性剤、及びこれらの混合物から選択され、好ましくはココアミドプロピルベタイン、アルキルエトキシル化ホスフェート、モノアルキルホスフェート、及びこれらの混合物から選択される、請求項1又は請求項5に記載の組成物。
- 前記抽出溶媒が、酢酸エチル、水−飽和酢酸エチル、プロピオン酸エチル、酪酸エチル、吉草酸エチル、カプロン酸エチル、カプリル酸エチル、ペラルゴン酸エチル酢酸メチル、プロピオン酸メチル、酪酸メチル、短鎖エステル、超臨界二酸化炭素、及びこれらの混合物から選択される、請求項1〜6のいずれか一項に記載の組成物。
- 塩、pH調節剤、及びこれらの混合物から選択される相分離増強剤を更に含有する、請求項1〜7のいずれか一項に記載の組成物。
- a.前記組成物の30重量%〜60重量%の水溶性界面活性剤;
b.20重量%〜80重量%の水;
c.20重量%〜80重量%の酢酸エチル;
d.0.01重量%〜20重量%の望ましくない非極性材料から本質的になる、請求項1に記載の組成物。 - 液液抽出プロセスにおける請求項1に記載の組成物の使用。
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US201161514203P | 2011-08-02 | 2011-08-02 | |
US61/514,203 | 2011-08-02 | ||
PCT/US2012/049314 WO2013019940A2 (en) | 2011-08-02 | 2012-08-02 | Liquid-liquid extraction composition useful in processing water-soluble surfactants |
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- 2012-08-02 US US13/564,841 patent/US10413844B2/en not_active Expired - Fee Related
- 2012-08-02 AU AU2012290069A patent/AU2012290069B2/en not_active Ceased
- 2012-08-02 BR BR112014001841A patent/BR112014001841A2/pt not_active IP Right Cessation
- 2012-08-02 WO PCT/US2012/049314 patent/WO2013019940A2/en active Application Filing
- 2012-08-02 KR KR1020147002604A patent/KR20140027540A/ko not_active Application Discontinuation
- 2012-08-02 CN CN201280036653.4A patent/CN103717283B/zh not_active Expired - Fee Related
- 2012-08-02 MX MX2014001097A patent/MX2014001097A/es unknown
- 2012-08-02 RU RU2014101945/04A patent/RU2014101945A/ru not_active Application Discontinuation
- 2012-08-02 JP JP2014524071A patent/JP2014524418A/ja active Pending
- 2012-08-02 CA CA2843605A patent/CA2843605C/en not_active Expired - Fee Related
- 2012-08-02 EP EP12746234.9A patent/EP2739359A2/en not_active Withdrawn
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MX2014001097A (es) | 2014-02-27 |
WO2013019940A2 (en) | 2013-02-07 |
US20130032748A1 (en) | 2013-02-07 |
CA2843605C (en) | 2017-07-04 |
RU2014101945A (ru) | 2015-09-10 |
BR112014001841A2 (pt) | 2017-02-21 |
KR20140027540A (ko) | 2014-03-06 |
CN103717283A (zh) | 2014-04-09 |
WO2013019940A3 (en) | 2013-06-13 |
AU2012290069A1 (en) | 2014-02-20 |
EP2739359A2 (en) | 2014-06-11 |
CN103717283B (zh) | 2016-10-12 |
CA2843605A1 (en) | 2013-02-07 |
US10413844B2 (en) | 2019-09-17 |
AU2012290069B2 (en) | 2015-08-27 |
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