JP2014522885A - 断熱特性が改善されたイソシアネート系ポリマー発泡体 - Google Patents
断熱特性が改善されたイソシアネート系ポリマー発泡体 Download PDFInfo
- Publication number
- JP2014522885A JP2014522885A JP2014516149A JP2014516149A JP2014522885A JP 2014522885 A JP2014522885 A JP 2014522885A JP 2014516149 A JP2014516149 A JP 2014516149A JP 2014516149 A JP2014516149 A JP 2014516149A JP 2014522885 A JP2014522885 A JP 2014522885A
- Authority
- JP
- Japan
- Prior art keywords
- side component
- component
- carbon black
- isocyanate
- polymer foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000006260 foam Substances 0.000 title claims abstract description 84
- 239000012948 isocyanate Substances 0.000 title claims abstract description 70
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 67
- 229920000642 polymer Polymers 0.000 title claims abstract description 41
- 238000009413 insulation Methods 0.000 title claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 71
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000000203 mixture Substances 0.000 claims description 53
- 229920005862 polyol Polymers 0.000 claims description 42
- 150000003077 polyols Chemical class 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- 229910052731 fluorine Inorganic materials 0.000 claims description 22
- 239000011737 fluorine Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000004604 Blowing Agent Substances 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 15
- 239000004088 foaming agent Substances 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 12
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 10
- 239000011541 reaction mixture Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000004970 Chain extender Substances 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 239000003063 flame retardant Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000002667 nucleating agent Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 239000002216 antistatic agent Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical group CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 239000002981 blocking agent Substances 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 239000012783 reinforcing fiber Substances 0.000 claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 claims description 4
- 125000000524 functional group Chemical group 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000002516 radical scavenger Substances 0.000 claims description 4
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 claims description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 claims description 3
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 229920000582 polyisocyanurate Polymers 0.000 abstract description 2
- 239000011495 polyisocyanurate Substances 0.000 abstract description 2
- 229920002635 polyurethane Polymers 0.000 abstract description 2
- 239000004814 polyurethane Substances 0.000 abstract description 2
- -1 aliphatic isocyanates Chemical class 0.000 description 22
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 19
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 238000009472 formulation Methods 0.000 description 16
- 229920001228 polyisocyanate Polymers 0.000 description 16
- 239000005056 polyisocyanate Substances 0.000 description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 210000004027 cell Anatomy 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 229910001868 water Inorganic materials 0.000 description 7
- 229920005830 Polyurethane Foam Polymers 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 239000011496 polyurethane foam Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 150000001414 amino alcohols Chemical class 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000003682 fluorination reaction Methods 0.000 description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 4
- 239000004811 fluoropolymer Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 3
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000012970 tertiary amine catalyst Substances 0.000 description 3
- YZXSQDNPKVBDOG-UHFFFAOYSA-N 2,2-difluoropropane Chemical compound CC(C)(F)F YZXSQDNPKVBDOG-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
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- VEAZEPMQWHPHAG-UHFFFAOYSA-N n,n,n',n'-tetramethylbutane-1,4-diamine Chemical compound CN(C)CCCCN(C)C VEAZEPMQWHPHAG-UHFFFAOYSA-N 0.000 description 2
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- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
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- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 description 1
- XXSZLFRJEKKBDJ-UHFFFAOYSA-N 1-chloro-1,1,2,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)Cl XXSZLFRJEKKBDJ-UHFFFAOYSA-N 0.000 description 1
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/6705—Unsaturated polymers not provided for in the groups C08G18/671, C08G18/6795, C08G18/68 or C08G18/69
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
- B29K2105/045—Condition, form or state of moulded material or of the material to be shaped cellular or porous with open cells
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
- B29K2105/046—Condition, form or state of moulded material or of the material to be shaped cellular or porous with closed cells
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- C08G2110/00—Foam properties
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Abstract
Description
(I)形成工程であって、
(A)(i)有機イソシアネートを含むA側成分と、
(B)(ii)イソシアネート反応成分、
(iii)発泡剤、及び
(iv)触媒、核生成剤、界面活性剤、架橋剤、鎖延長剤、難燃剤、充填材、
着色剤、顔料、帯電防止剤、補強繊維、酸化防止剤、保存剤、
赤外線阻止剤、又は酸スカベンジャーの中から選択される1種又は
複数種の追加成分
を含むB側成分と、
(C)3〜7部のカーボンブラック成分であって、
(v)炭素に対するフッ素のモル比(F/C)が少なくとも10/90である
フッ素化カーボンブラックを50〜100重量%含み、ここで、部は、
B側成分(B)の重量に基づいた重量部であり、また、該成分(C)は、
そのすべてがA側成分(A)にあっても、B側成分(B)にあっても、
一部がA側成分にあり一部がB側成分にあってもよい、
前記カーボンブラック成分と、
を形成する工程;
(II)反応配合物を形成するために、前記A側成分(A)と前記B側成分(B)を共に混合する工程であって、前記A側成分(A)及び前記B側成分(B)の一方又は両方が前記成分(C)を含む、前記混合する工程;並びに
(III)断熱特性が改善された硬質イソシアネート系ポリマー発泡体を形成するために、得られた前記反応配合物を、該反応配合物が硬化するのに十分な条件下に曝す工程
の各工程によって、断熱特性が改善された硬質イソシアネート系ポリマー発泡体を製造する方法である。
OH価=ヒドロキシル価
PO系=オキシプロピレンポリエーテルポリオール
FCB=フッ素化カーボンブラック
F/C=炭素に対するフッ素のモル比
CB=未処理(すなわち未フッ化)カーボンブラック
Claims (8)
- 改善された断熱特性を有する硬質イソシアネート系ポリマー発泡体であって、
(A)(i)有機イソシアネートを含むA側成分と、
(B)B側成分であって、
(ii)イソシアネート反応成分、
(iii)発泡剤、及び
(iv)触媒、核生成剤、界面活性剤、架橋剤、鎖延長剤、難燃剤、充填材、
着色剤、顔料、帯電防止剤、補強繊維、酸化防止剤、保存剤、
赤外線阻止剤、又は酸スカベンジャーの中から選択される1種又は複数種
の追加成分
を含む、前記B側成分と、
(C)3〜7部のカーボンブラック成分であって、
(v)炭素に対するフッ素のモル比(F/C)が少なくとも10/90である
フッ素化カーボンブラックを50〜100重量%含み、ここで、部は、
B側成分(B)の重量に基づいた重量部であり、また、該成分(C)は、
そのすべてがA側成分(A)にあっても、B側成分(B)にあっても、
一部がA側成分にあり一部がB側成分にあってもよい、
前記カーボンブラック成分と、
の混合物を含む反応配合物から製造された、前記硬質イソシアネート系ポリマー発泡体。 - 前記有機イソシアネートが、2,4−トルエンジイソシアネート(TDI)、2,6−トルエンジイソシアネート、又はこれらの混合物; 2,4’−ジフェニルメタンジイソシアネート(MDI)、2,2’−ジフェニルメタンジイソシアネート、4,4’−ジフェニルメタンジイソシアネート、又はこれらの混合物; 2個より多いイソシアネート官能基を有し、粗MDI又は高分子のMDIとして当技術分野で知られている、ジフェニルメタンジイソシアネートとそのオリゴマーの混合物; 又は、ウレタン基、アロファネート基、尿素基、ビウレット基、カルボジイミド基、ウレトニミン基、及び/又はイソシアネート基を含むMDIである、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 前記イソシアネート反応成分が、2〜8個の官能基と100〜850のヒドロキシル価を有するポリエーテルポリオールである、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 前記発泡剤が、物理発泡剤、化学発泡剤、又はこれらの組み合わせである、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 前記カーボンブラック成分(C)が、100%フッ素化されたカーボンブラック(v)である、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 前記フッ素化カーボンブラックの平均粒径が5nm〜500nmである、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 前記発泡体は、ISO 12939−01に従って求めた発泡体のk−ファクターが、フッ素化カーボンブラックを省いたこと以外は同じ発泡体形成組成物から調製された対応する発泡体のk−ファクターよりも、少なくとも0.2mW/mK小さい、請求項1に記載の硬質イソシアネート系ポリマー発泡体。
- 改善された断熱特性を有する硬質イソシアネート系ポリマー発泡体の製造方法であって、
(I)形成工程であって、
(A)(i)有機イソシアネートを含むA側成分と、
(B)(ii)イソシアネート反応成分、
(iii)発泡剤、及び
(iv)触媒、核生成剤、界面活性剤、架橋剤、鎖延長剤、難燃剤、充填材、
着色剤、顔料、帯電防止剤、補強繊維、酸化防止剤、保存剤、
赤外線阻止剤、又は酸スカベンジャーの中から選択される1種又は
複数種の追加成分
を含むB側成分と、
(C)3〜7部のカーボンブラック成分であって、
(v)炭素に対するフッ素のモル比(F/C)が少なくとも10/90である
フッ素化カーボンブラックを50〜100重量%含み、ここで、部は、
B側成分(B)の重量に基づいた重量部であり、また、該成分(C)は、
そのすべてがA側成分(A)にあっても、B側成分(B)にあっても、
一部がA側成分にあり一部がB側成分にあってもよい、
前記カーボンブラック成分と、
を形成する工程;
(II)反応配合物を形成するために、前記A側成分(A)と前記B側成分(B)を共に混合する工程であって、前記A側成分(A)及び前記B側成分(B)の一方又は両方が前記成分(C)を含む、前記混合する工程; 並びに
(III)断熱特性が改善された硬質イソシアネート系ポリマー発泡体を形成するために、得られた前記反応配合物を、該反応配合物が硬化するのに十分な条件下に曝す工程
の各工程によって製造する、前記製造方法。
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WO2019117292A1 (ja) * | 2017-12-15 | 2019-06-20 | 株式会社イノアックコーポレーション | ポリウレタンフォームの製造方法 |
US11753495B2 (en) | 2017-12-15 | 2023-09-12 | Inoac Corporation | Method for producing polyurethane foam |
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CA2919162C (en) * | 2013-07-26 | 2021-08-10 | Basf Se | Isocyanate-epoxy-foam system |
EP3226805B1 (en) | 2014-12-02 | 2021-06-30 | Bard Shannon Limited | Muscle wall defect prosthesis and deployment system |
WO2017074003A1 (ko) | 2015-10-27 | 2017-05-04 | 한국과학기술원 | 유연 열전소자 및 이의 제조방법 |
KR101907915B1 (ko) | 2018-01-31 | 2018-10-15 | 이광진 | 건축 구조물의 옥상 보강 구조 및 공법 |
CN109251513A (zh) * | 2018-09-17 | 2019-01-22 | 深圳市心版图科技有限公司 | 一种抗红外辐射的聚氨酯泡沫材料及其加工方法 |
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- 2011-06-21 ES ES11868078T patent/ES2702109T3/es active Active
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JP2011084748A (ja) * | 1999-01-20 | 2011-04-28 | Cabot Corp | 結合したポリマー基を有する凝集体およびポリマー発泡体 |
JP2011084444A (ja) * | 2009-10-17 | 2011-04-28 | Univ Of Fukui | フッ素化炭素微粒子分散液 |
JP2011084443A (ja) * | 2009-10-17 | 2011-04-28 | Univ Of Fukui | フッ素化炭素微粒子 |
Cited By (3)
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CN108475718A (zh) * | 2015-10-27 | 2018-08-31 | 韩国科学技术院 | 柔性热电元件及其制造方法 |
WO2019117292A1 (ja) * | 2017-12-15 | 2019-06-20 | 株式会社イノアックコーポレーション | ポリウレタンフォームの製造方法 |
US11753495B2 (en) | 2017-12-15 | 2023-09-12 | Inoac Corporation | Method for producing polyurethane foam |
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CN103619954B (zh) | 2016-09-14 |
CN103619954A (zh) | 2014-03-05 |
RU2014101621A (ru) | 2015-07-27 |
EP2723814A4 (en) | 2015-04-15 |
WO2012174710A1 (en) | 2012-12-27 |
EP2723814A1 (en) | 2014-04-30 |
JP5820065B2 (ja) | 2015-11-24 |
EP2723814B1 (en) | 2018-10-17 |
US9267035B2 (en) | 2016-02-23 |
MX347427B (es) | 2017-04-26 |
ES2702109T3 (es) | 2019-02-27 |
US20140117270A1 (en) | 2014-05-01 |
MX2013014876A (es) | 2014-03-26 |
RU2560552C2 (ru) | 2015-08-20 |
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